A method for fabricating a gate stack of a semiconductor device comprises forming a first dielectric layer over a channel region of the device, depositing a first nitride layer on exposed portions of the first dielectric layer, depositing a scavenging layer on the first nitride layer, forming a capping layer over the scavenging layer, removing portions of the capping layer, the scavenging layer, and the first nitride layer to expose a portion of the first dielectric layer in an n-type field effect transistor (nFET) region of the gate stack, forming a barrier layer over the first dielectric layer and the capping layer, forming a first gate metal layer over the barrier layer, depositing a second nitride layer on the first gate metal layer, and depositing a gate electrode material on the second nitride layer.
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1. A method for fabricating a gate stack of a semiconductor device, the method comprising:
forming a first dielectric layer over a common substrate comprising a n-type field effect transistor (nFET) region arranged directly adjacent to a p-type field effect transistor (pfet) region;
forming a weak oxygen-scavenging stack on the first dielectric layer, the weak oxygen-scavenging stack comprising a strong oxygen-scavenging layer comprising NbAlC formed on a first nitride layer;
forming a capping layer comprising tin directly on the weak oxygen-scavenging stack arranged on both the nFET region and the pfet region;
removing portions of the capping layer and the weak oxygen-scavenging stack to expose a portion of the first dielectric layer in the nFET region, the capping layer and the weak oxygen-scavenging stack remaining on the pfet region, and a vertical sidewall formed by the capping layer and the weak oxygen scavenging stack between the nFET region and the pfet region;
forming a barrier layer directly on a surface of the first dielectric layer in the nFET region, directly on a surface of the capping layer in a pfet region, and directly on the vertical sidewall formed by the capping layer and the weak oxygen scavenging stack, the barrier layer in the pfet region arranged higher with respect to a vertical direction than in the nFET region;
forming a single first gate metal layer over the barrier layer in both the nFET and pfet regions;
depositing a second nitride layer on the first gate metal layer; and
depositing a gate electrode material on the second nitride layer;
wherein a thickness of the weak oxygen-scavenging stack is selected to adjust a threshold voltage in the pfet region and to ensure that the weak oxygen-scavenging stack is relatively weaker than a strong oxygen scavenging stack in the nFET region.
10. The method of
11. The method of
forming a sacrificial gate stack over the channel region of the device;
forming a spacer along sidewalls of the sacrificial gate stack;
forming a source/drain region of the device adjacent to the sacrificial gate stack;
forming a layer of insulator material around the spacer; and
removing the sacrificial gate stack to expose the channel region of the device.
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The present invention generally relates to semiconductor devices, and more specifically, to metal-oxide-semiconductor field effect transistor (MOSFET) gates.
The MOSFET is a transistor used for amplifying or switching electronic signals. The MOSFET has a source, a drain, and a metal oxide gate electrode. The metal gate is electrically insulated from the main semiconductor n-channel or p-channel by a thin layer of insulating material, for example, silicon dioxide or glass, which makes the input resistance of the MOSFET relatively high. The gate voltage controls whether the path from drain to source is an open circuit (“off”) or a resistive path (“on”).
N-type field effect transistors (nFET) and p-type field effect transistors (pFET) are two types of complementary MOSFETs. The nFET uses electrons as the current carriers and with n-doped source and drain junctions. The pFET uses holes as the current carriers and with p-doped source and drain junctions.
According to an embodiment of the present invention, a method for fabricating a gate stack of a semiconductor device comprises forming a first dielectric layer over a channel region of the device, depositing a first nitride layer on exposed portions of the first dielectric layer, depositing a scavenging layer on the first nitride layer, forming a capping layer over the scavenging layer, removing portions of the capping layer, the scavenging layer, and the first nitride layer to expose a portion of the first dielectric layer in an n-type field effect transistor (nFET) region of the gate stack, forming a barrier layer over the first dielectric layer and the capping layer, forming a first gate metal layer over the barrier layer, depositing a second nitride layer on the first gate metal layer, and depositing a gate electrode material on the second nitride layer.
According to another embodiment of the present invention, a semiconductor device comprises a gate stack arranged over a channel region of the device, the gate stack comprising an n-type field effect transistor (nFET) portion comprising a dielectric layer arranged on a substrate, a barrier layer arranged on the dielectric layer, a first gate metal layer arranged on the barrier layer, a first nitride layer arranged on the first gate metal layer, and a gate electrode arranged on the second nitride layer.
According to yet another embodiment of the present invention, a semiconductor device comprises a gate stack arranged over a channel region of the device, the gate stack comprising an n-type field effect transistor (nFET) portion comprising a dielectric layer arranged on a substrate a barrier layer arranged on the dielectric layer, a first gate metal layer arranged on the barrier layer, a first nitride layer arranged on the first gate metal layer, and a gate electrode arranged on the second nitride layer, and a p-type field effect transistor (pFET) portion comprising the dielectric layer arranged on the substrate, a second nitride layer arranged on the dielectric layer, a scavenging layer arranged on the second nitride layer, a capping layer arranged on the scavenging layer, a barrier layer arranged on the capping layer, the first gate metal layer arranged on the barrier layer, the first nitride layer arranged on the first gate metal layer, and the gate electrode arranged on the second nitride layer.
The methods and embodiments described herein provide a robust tunable nFET gate stack in a MOSFET device. In FET devices, metal nitrides such as, for example, TiN and TaN provide a good work function material in the gate stacks to achieve a desired threshold voltage (Vt) in pFET devices. As the scaling of FET devices continues to decrease, multi-gate devices such as finFETs are used to achieve performance goals. Atomic layer deposition (ALD) is used to deposit a uniform layer of the work function metal to reduce Vt variation and control the Vt of the FET devices. Changing the characteristics of work function metals in a replacement metal gate fabrication process using ALD has become more challenging.
Through experimentation, it has been found that the pVt has become less stable and the Vt has become difficult to control when untreated TiN or TaN is used as the work function metal of pFET devices because the response of oxygen vacancy in high-k dielectric materials with respect to the thermal budget in the replacement metal gate fabrication process.
The performance and reliability of nFET devices may be improved using a D2 or high pressure annealing process. However, the process may lead to unstable pVt when the pFET includes a conventional work function metal such as, for example, TiN.
The methods and embodiments described herein provide for a gate stack with a relatively weak oxygen-scavenge stack to define and adjust the pVt as opposed to a single metal nitride layer such as, for example, TiN and TaN. The weak oxygen-scavenge stack may be formed by deposition or integration, and may include, for example, a barrier layer such as, TiN or TaN and a strong oxygen-scavenge material such as TiAlC, TiAl, Al, Ti, NbAl, and TaAlC.
The following definitions and abbreviations are to be used for the interpretation of the claims and the specification. As used herein, the terms “comprises,” “comprising,” “includes,” “including,” “has,” “having,” “contains” or “containing,” or any other variation thereof, are intended to cover a non-exclusive inclusion. For example, a composition, a mixture, process, method, article, or apparatus that comprises a list of elements is not necessarily limited to only those elements but can include other elements not expressly listed or inherent to such composition, mixture, process, method, article, or apparatus.
As used herein, the articles “a” and “an” preceding an element or component are intended to be nonrestrictive regarding the number of instances (i.e. occurrences) of the element or component. Therefore, “a” or “an” should be read to include one or at least one, and the singular word form of the element or component also includes the plural unless the number is obviously meant to be singular.
As used herein, the terms “invention” or “present invention” are non-limiting terms and not intended to refer to any single aspect of the particular invention but encompass all possible aspects as described in the specification and the claims.
As used herein, the term “about” modifying the quantity of an ingredient, component, or reactant of the invention employed refers to variation in the numerical quantity that can occur, for example, through typical measuring and liquid handling procedures used for making concentrates or solutions. Furthermore, variation can occur from inadvertent error in measuring procedures, differences in the manufacture, source, or purity of the ingredients employed to make the compositions or carry out the methods, and the like. In one aspect, the term “about” means within 10% of the reported numerical value. In another aspect, the term “about” means within 5% of the reported numerical value. Yet, in another aspect, the term “about” means within 10, 9, 8, 7, 6, 5, 4, 3, 2, or 1% of the reported numerical value.
It will also be understood that when an element, such as a layer, region, or substrate is referred to as being “on” or “over” another element, it can be directly on the other element or intervening elements may also be present. In contrast, when an element is referred to as being “directly on” or “directly over” another element, there are no intervening elements present, and the element is in contact with another element.
It will also be understood that when an element is referred to as being “connected” or “coupled” to another element, it can be directly connected or coupled to the other element or intervening elements may be present. In contrast, when an element is referred to as being “directly connected” or “directly coupled” to another element, there are no intervening elements present.
In the illustrated embodiment, the fins 112 and 114 are arranged on the substrate 102 that includes an insulator layer such that a semiconductor on insulator (SOI) substrate may be used. Alternate exemplary embodiments may form fins on a bulk semiconductor substrate.
In
In the exemplary method, the nFET stack is formed prior to forming the pFET stack. The nFET stack includes a strong oxygen-scavenge stack, while the subsequently formed pFET stack includes a weak oxygen-scavenge stack.
One difference between nFET strong oxygen-scavenge stack and the pFET if a single metal layer is used is that the enthalpy change to form metal oxide is much higher for nFET than that for pFET. For example, Al is used for nFET and Ni is used for pFET. In another hand, the oxygen-scavenge stack can be formed by same materials and the same structure but with different film thickness or different film composition. For example, TiN/TiAl/TiN stack is used as oxygen-scavenge stack. If the layers are similar except for the TiAl thickness, thicker TiAl will form stronger oxygen-scavenge stack, but thinner TiAl will form the weak oxygen-scavenge stack. Another hand, if the TiAl thickness and top TiN thickness are same, the bottom TiN difference can also form stronger oxygen-scavenge stack by using thinner bottom TiN and weaker oxygen-scavenge stack by using thicker bottom TiN.
Referring to
The methods and embodiments described herein provide for a gate stack with a relatively weak oxygen-scavenge stack to define and adjust the pVt as opposed to a single metal nitride layer such as, for example, TiN and TaN. The weak oxygen-scavenge stack may be formed by deposition or integration, and may include, for example, a barrier layer such as, TiN or TaN and a strong oxygen-scavenge material such as TiAlC or TiAl, Ti, Al, TiAlC, NbAlC.
The descriptions of the various embodiments of the present invention have been presented for purposes of illustration, but are not intended to be exhaustive or limited to the embodiments disclosed. Many modifications and variations will be apparent to those of ordinary skill in the art without departing from the scope and spirit of the described embodiments. The terminology used herein was chosen to best explain the principles of the embodiments, the practical application or technical improvement over technologies found in the marketplace, or to enable others of ordinary skill in the art to understand the embodiments disclosed herein.
Narayanan, Vijay, Bao, Ruqiang, Krishnan, Siddarth A., Kwon, Unoh
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