A shield encircles a sputtering target that faces a substrate support in a substrate processing chamber. The shield comprises an outer band having a diameter sized to encircle the sputtering target, the outer band having upper and bottom ends, and the upper end having a tapered surface extending radially outwardly and adjacent to the sputtering target. A base plate extends radially inward from the bottom end of the outer band. An inner band joined to the base plate at least partially surrounds a peripheral edge of a substrate support. The shield can also have a heat exchanger comprising a conduit with an inlet and outlet to flow heat exchange fluid therethrough.

Patent
   11658016
Priority
Oct 31 2005
Filed
May 10 2019
Issued
May 23 2023
Expiry
Apr 08 2027
Extension
163 days
Assg.orig
Entity
Large
0
414
currently ok
13. A heat exchanger that integrates a source coil and cools an upper end of a shield that encircles a sputtering surface of a sputtering target that faces a substrate support in a substrate processing chamber, the heat exchanger comprising:
(a) a plate comprising an inner perimeter that is a circular aperture shaped and sized to fit around the shield, an outer perimeter that is a polygon with a plurality of sides, and a fastener to fasten the shield to the heat exchanger; and
(b) a polygon conduit to flow heat exchange fluid in the plate, the polygon conduit comprising (i) a plurality of legs that are interconnected in a polygonal pattern around the aperture, (ii) a plurality of channels that are each covered by a cover plate, and (iii) an inlet and outlet to flow the heat exchange fluid therethrough.
16. A shield assembly encircling a sputtering target that faces a substrate support in a substrate processing chamber, the shield assembly comprising:
(a) a shield comprising:
(i) an outer band having a diameter sized to encircle the sputtering target, the outer band having upper and bottom ends, the upper end tapering in thickness in the direction of the bottom end, and the upper end having a tapered surface extending radially outwardly and adjacent to the sputtering target;
(ii) a base plate extending radially inward from the bottom end of the outer band;
(iii) an inner band joined to the base plate and at least partially surrounding a peripheral edge of the substrate support; and
(iv) a ledge having an opening adapted to allow a fastener to pass therethrough to fasten the shield to the heat exchanger;
(b) a heat exchanger having a plate with an inner perimeter comprising a circular aperture sized to fit around the shield, the plate comprising a conduit therein with an inlet and outlet to flow heat exchange fluid therethrough; and
(c) a fastener shaped and sized to pass through the opening in the ledge of the shield to fasten the shield to the heat exchanger.
1. A shield assembly encircling a sputtering target that faces a substrate support in a substrate processing chamber, the shield assembly comprising:
(i) a shield comprising:
(a) an outer band having a diameter sized to encircle the sputtering target, the outer band having upper and bottom ends, the upper end tapering in thickness in the direction of the bottom end, and the upper end having a tapered surface extending radially outwardly and adjacent to the sputtering target;
(b) a base plate extending radially inward from the bottom end of the outer band;
(c) an inner band joined to the base plate and at least partially surrounding a peripheral edge of the substrate support; and
(d) a ledge having a first opening; and
(ii) a heat exchanger having a plate having (i) an inner perimeter comprising a circular aperture sized to fit around the shield, (ii) an outer perimeter comprising a plurality of sides, (iii) a conduit therein with an inlet and outlet to flow heat exchange fluid therethrough, and (iv) a second opening aligned with the first opening of the ledge of the shield, to allow a fastener to pass through the first and second openings to fasten the shield to the heat exchanger.
2. A shield assembly according to claim 1 wherein the outer and inner bands are cylindrical.
3. A shield assembly according to claim 1 wherein the outer band, base plate and inner band comprise a unitary monolith.
4. A shield assembly according to claim 3 wherein the unitary monolith has a continuous surface without interfaces.
5. A shield assembly according to claim 1 wherein the sputtering target has a sloped peripheral surface, and the radially outwardly extending tapered surface of the upper end of the outer band is adjacent to the sloped peripheral surface to form a contoured gap therebetween.
6. A shield assembly according to claim 1 wherein the height of the inner band is smaller than the height of the outer band.
7. A shield assembly according to claim 6 wherein the height of the inner band is 0.8 times smaller than the height of the outer band.
8. A shield assembly according to claim 1 comprising a gap between the inner and outer bands that is capable of hindering ingress of plasma species into this region.
9. A shield assembly according to claim 1 wherein the heat exchanger conduit is a polygon conduit having a plurality of legs interconnected in a polygonal pattern.
10. A shield assembly according to claim 9 wherein the heat exchanger plate comprises an outer perimeter that is a polygon.
11. A shield assembly according to claim 1 further comprising the fastener shaped and sized to pass through the first and second openings to fasten the shield to the heat exchanger.
12. A shield assembly according to claim 1 wherein the heat exchanger comprises an integrated source coil capable of generating a plasma in the chamber.
14. A heat exchanger according to claim 13 wherein each leg of the conduit extends at an angle of from about 20 to about 45° from a side of the outer perimeter.
15. A heat exchanger according to claim 13 further comprising the integrated source coil that is capable of generating a plasma in the chamber.
17. A shield assembly according to claim 16 comprising at least one of the following:
(a) the outer and inner bands are cylindrical;
(b) the outer band, base plate and inner band comprise a unitary monolith;
(c) the height of the inner band is smaller than the height of the outer band;
(d) the height of the inner band is 0.8 times smaller than the height of the outer band; and
(e) comprising a gap between the inner and outer bands.
18. A shield assembly according to claim 16 wherein the sputtering target has a sloped peripheral surface, and the radially outwardly extending tapered surface of the upper end of the outer band is adjacent to the sloped peripheral surface to form a contoured gap therebetween.
19. A shield assembly according to claim 16 wherein the heat exchanger comprises at least one of the following:
(a) the conduit is a polygon conduit having a plurality of legs interconnected in a polygonal pattern;
(b) the plate comprises an outer perimeter that is a polygon; and
(c) an integrated source coil capable of generating a plasma in the chamber.
20. A shield assembly according to claim 16 wherein the conduit of the heat exchanger comprises (i) a plurality of legs that are interconnected in a polygonal pattern, and (ii) a plurality of channels that are each covered by a cover plate.

This application claims priority from U.S. Pat. No. 10,347,475, U.S. patent application Ser. No. 14/846,951, filed on Sep. 7, 2015, which claims priority from U.S. Pat. No. 9,127,362, U.S. patent application Ser. No. 11/553,982, filed on Oct. 27, 2006, which claims priority from U.S. Provisional Patent Application No. 60/732,324, filed on Oct. 31, 2005, all of which are incorporated herein by reference in their entireties.

Embodiments of the present invention relate to holding assemblies, shields, process kits and targets for a substrate processing chamber.

In the processing of substrates, such as semiconductor wafers and displays, a substrate is placed in a process chamber and processing conditions are set in the chamber to deposit or etch material on the substrate. A typical process chamber comprises chamber components that include an enclosure wall that encloses a process zone, a gas supply to provide a gas in the chamber, a gas energizer to energize the process gas to process the substrate, a substrate support to hold the substrate, and a gas exhaust to remove spent gas and maintain a gas pressure in the chamber. Such chambers can include, for example, CVD, PVD and etching chambers. In a PVD chamber, a target is sputtered to cause sputtered target material to deposit on a substrate facing the target. In the sputtering process, an inert or reactive gas is supplied into the chamber, the target is typically electrically biased, and the substrate maintained at an electrical floating potential, to generate a plasma in the chamber which causes sputtering of the target.

The PVD chamber can include a process kit comprising chamber components which are positioned the substrate support to reduce the formation of PVD deposits on the interior chamber walls or other regions. A typical PVD chamber process kit can include, for example, deposition, cover, and/or shadow rings, all of which are located about the periphery of the substrate. Various configurations of rings are arranged to receive sputtering deposits, which would otherwise accumulate on the side surfaces of the support or on the exposed backside surfaces of the substrate. The process kit can also include chamber shields and liners which protect the sidewalls of the chamber by serving as a receiving surface to receive PVD sputtering deposits which would otherwise deposit on the sidewalls of the chamber. The process kit components also reduce the accumulation of sputtered deposits on these surfaces, which would otherwise eventually flake off to form contaminant particles that deposit on the substrate. The kit components also reduce erosion of the internal chamber structures by the energized plasma. They can also be designed to be easily removable for cleaning of accumulated deposits. After processing of a batch of substrates, for example, 1000 substrates, the process kit components are typically removed and cleaned with an acidic solution comprising for example, HF and HNO3, to remove the sputtered deposits accumulated on the kit components during the substrate process cycles.

It is desirable to have a process kit comprising components that are shaped and arranged in relationship to one another to reduce the amounts of sputtered deposits formed on the internal walls of the chamber. Reducing the accumulated deposits allows a greater number of substrates to be sequentially processed in the chamber without requiring shutdown or dismantling of the chamber for cleaning. Each time the chamber requires cleaning, the resultant downtime of the chamber increases the cost of processing the substrate. Thus it is desirable to maximize the amount of time the chamber can be operated to sputter material onto the substrate without shutting down the chamber to clean its internal surfaces.

Furthermore, in certain PVD processes, such as for example, aluminum PVD processes, the sputtered aluminum deposits accumulate in the gaps between the various deposition, cover, and other rings around the periphery of the substrate, and also form on the backside of the substrate. The accumulated sputtered deposits cause the substrate to stick to the deposition ring causing substrate damage when the substrate is attempted to be removed from the support. It is desirable to have rings which can reduce deposition on the backside of the substrate and side surface of the support without accumulating deposits on portions of the rings that cause the substrate to stick to the rings. It is also desirable to prevent a partially stuck deposition ring to rise with the substrate when the substrate is lifted from the support to reduce damage to the substrate and/or deposition ring.

Another problem arises when the liners and shields surrounding the substrate heat up with exposure to the sputtering plasma in the chamber. Typically, the shields and liners do not exchange a sufficient amount of heat with their surrounding chamber components in the low pressure environment within the chamber to lower the temperature of these components to acceptable levels. Excessive heating of these components is detrimental because thermal expansion of the components causes thermal stresses that result in peeling or spalling of the sputtered deposits formed on the shields and liners after a process cycle is completed. Thus, it is desirable to maintain the shields and liners at reduced or low temperatures during processing of the substrate.

A shield encircles a sputtering target that faces a substrate support in a substrate processing chamber. The shield comprises an outer band having a diameter sized to encircle the sputtering target, the outer band having upper and bottom ends, and the upper end having a tapered surface extending radially outwardly and adjacent to the sputtering target. A base plate extends radially inward from the bottom end of the outer band. An inner band joined to the base plate at least partially surrounds a peripheral edge of a substrate support.

A heat exchanger can be used for cooling the shield. The heat exchanger comprises a plate comprising an aperture shaped and sized to fit around the shield, and a polygon conduit in the plate, the polygon conduit comprising a plurality of legs that are interconnected in a polygonal pattern around the aperture, and the polygonal conduit comprising an inlet and outlet to flow heat exchange fluid therethrough.

A sputtering target is capable of fitting within a shield and resting on an isolator in a substrate processing chamber. The sputtering target comprises a sputtering plate composed of a sputtering material to be sputtered onto the substrate, the sputtering plate comprising a sloped edge. A backing plate is provided for supporting the sputtering plate, the backing plate comprising a peripheral ledge which extends beyond the sloped edge of the sputtering plate, the peripheral ledge comprising a footing which rests on the isolator in the chamber, and an inner bump which is shaped and sized to reduce deposition of sputtering deposits on the isolator and shield.

These features, aspects and advantages of the present invention will become better understood with regard to the following description, appended claims, and accompanying drawings, which illustrate examples of the invention. However, it is to be understood that each of the features can be used in the invention in general, not merely in the context of the particular drawings, and the invention includes any combination of these features, where:

FIG. 1 is a schematic sectional side view of a substrate processing chamber having an embodiment of the process kit;

FIG. 2 is a sectional side view of the process kit shown in FIG. 1;

FIG. 3 is a perspective view of the process kit of FIG. 2;

FIG. 4A is a perspective view of the retaining bracket for the anti-lift bracket;

FIG. 4B is a perspective view of the backside of the support showing the positioned retaining bracket for the anti-lift bracket;

FIG. 5 is a perspective view of the anti-lift bracket sliding onto the holding post in a recessed pocket on a deposition ring which surrounds the substrate support;

FIG. 6 is a perspective view of the anti-lift bracket after it is fitted onto the holding post of the deposition ring which is around the substrate support;

FIG. 7 is an exploded perspective view of the anti-lift bracket sliding onto a ceramic isolator which couples to a prong of the restraint beam with a pin holding the assembly together;

FIG. 8 is a perspective view of the anti-lift bracket, ceramic isolator, pin, and restraint beam, as assembled onto a substrate support;

FIG. 9 is a top sectional view of a heat exchanger showing the polygonal conduit therein; and

FIG. 10 is a graph of modeling results obtained for a scaled geometry of the process kit showing the thickness of deposits formed on the components as a function of distance from the substrate and support.

An example of a suitable process chamber 100 capable of processing a substrate 104 is shown in FIG. 1. The chamber 100 comprises enclosure walls 108 that enclose a process zone 106, the walls 108 including sidewalls 116, a bottom wall 120, and a ceiling 124. The chamber 100 can be a part of a multi-chamber platform (not shown) having a cluster of interconnected chambers connected by a robot arm mechanism that transfers substrates 104 between the chambers 106. In the version shown, the process chamber 100 comprises a sputter deposition chamber, also called a physical vapor deposition or PVD chamber, which is capable of sputter depositing material on a substrate 104, such as one or more of tantalum, tantalum nitride, titanium, titanium nitride, copper, tungsten, tungsten nitride and aluminum.

The chamber 100 comprises a substrate support 130 to support the substrate 104 which comprises a pedestal 134. The pedestal 134 has a substrate receiving surface 138 that receives and supports the substrate 104 during processing, and may include an electrostatic chuck or a heater, such as an electrical resistance heater or heat exchanger (not shown). In operation, a substrate 104 is introduced into the chamber 100 through a substrate loading inlet (not shown) in the sidewall 116 of the chamber 100 and placed on the substrate support 130. The support 130 can be lifted or lowered by support lift bellows and/or a lift finger assembly (not shown) can be used to lift and lower the substrate onto the support 130 during placement of a substrate 104 on the support 130. The pedestal 134 can be maintained at an electrically floating potential or grounded during plasma operation.

The chamber 100 further comprises a sputtering target 140 comprising a sputtering surface 142 facing the substrate 104, which comprises the material to be sputtered onto the substrate 104. The target 140 is electrically isolated from the chamber 100 by an isolator 144 which is typically made from a dielectric or insulator material. The target 140 is connected to a target power supply 148 which applies a bias voltage to the target 140 relative to a shield 150 which is in front of the walls of the chamber components, and/or the support 130 which is electrically floated. The target 140, shield 150, support 130, and other chamber components connected to the target power supply 148 operate as a gas energizer 152 to form a plasma of the sputtering gas. The gas energizer 152 can also include a source coil 153 which is used to generate a plasma in the chamber 100 by application of a current through the coil. The generated plasma energetically impinges upon and bombards the sputtering surface 142 of the target 140 to sputter material off the surface 142 onto the substrate 104.

The sputtering gas is introduced into the chamber 100 through a gas delivery system 160 provides gas from a gas supply 162 via conduits 164 having gas flow control valves 166, such as a mass flow controllers, to pass a set flow rate of the gas therethrough. The gases are fed to a mixing manifold (also not shown) in which the gases are mixed to from a desired process gas composition and fed to a gas distributor 168 having gas outlets in the chamber 100. The process gas may comprise a non-reactive gas, such as argon or xenon, which is capable of energetically impinging upon and sputtering material from a target. The process gas may also comprise a reactive gas, such as one or more of an oxygen-containing gas and a nitrogen-containing gas, that are capable of reacting with the sputtered material to form a layer on the substrate 104. Spent process gas and byproducts are exhausted from the chamber 100 through an exhaust 170 which includes exhaust ports 172 that receive spent process gas and pass the spent gas to an exhaust conduit 174 having a throttle valve 176 to control the pressure of the gas in the chamber 100. The exhaust conduit 174 is connected to one or more exhaust pumps 178. Typically, the pressure of the sputtering gas in the chamber 100 is set to sub-atmospheric levels, such as a vacuum environment, for example, gas pressures of 1 mTorr to 400 mTorr.

The chamber 100 is controlled by a controller 180 that comprises program code having instruction sets to operate components of the chamber 100 to process substrates 104 in the chamber 100. For example, the controller 180 can comprise program code that includes a substrate positioning instruction set to operate the substrate support 130 and substrate transport; a gas flow control instruction set to operate gas flow control valves to set a flow of sputtering gas to the chamber 100; a gas pressure control instruction set to operate the exhaust throttle valve to maintain a pressure in the chamber 100; a gas energizer control instruction set to operate the gas energizer to set a gas energizing power level; a temperature control instruction set to control a temperature control system to set temperatures of various components in the chamber 100; and a process monitoring instruction set to monitor the process in the chamber 100.

The chamber comprises a process kit 200 comprising various components that can be easily removed from the chamber 100, for example, to clean sputtering deposits off the component surfaces, replace or repair eroded components, or to adapt the chamber for other processes. In one version, the process kit 200 comprises a ring assembly 202 for placement about a peripheral wall 204 of the substrate support 130 that terminates before an overhanging edge 206 of the substrate. The ring assembly 202 comprises a deposition ring 208 and a cover ring 212 that cooperate with one another to reduce formation of sputter deposits on the peripheral walls 204 of the support 130 or the overhanging edge 206 of the substrate 104.

The deposition ring 208 comprises an annular band 216 that extends about and surrounds the peripheral wall 204 of the support 130 as shown in FIGS. 2 and 3. The annular band 216 comprises an inner lip 218 which extends transversely from the band and is substantially parallel to the peripheral wall 204 of the support 130. The inner lip 218 terminates immediately below the overhanging edge 206 of the substrate 104. The inner lip 218 defines an inner perimeter of the deposition ring 208 which surrounds the periphery of the substrate 104 and support 130 to protect regions of the support 130 that are not covered by the substrate 104 during processing. For example, the inner lip 218 surrounds and at least partially covers the peripheral wall 204 of the support 130 that would otherwise be exposed to the processing environment to reduce or even entirely preclude deposition of sputtering deposits on the peripheral wall 204. Advantageously, the deposition ring 208 can be easily removed to clean sputtering deposits from the exposed surfaces of the ring so that the support 130 does not have to be dismantled to be cleaned. The deposition ring 208 can also serve to protect the exposed side surfaces of the support 130 to reduce their erosion by the energized plasma species. The deposition ring 208 is typically made from a metal, such as stainless steel or aluminum, or can be made from a ceramic material, such as aluminum oxide.

In the version shown in FIGS. 2 and 3, the annular band 216 of the deposition ring 208 has a raised ridge 224 that extends along the central portion of the band 216. The raised ridge 224 has a flat top surface 228 which is spaced apart from the cover ring 212 to form a convoluted gap 229 therebetween which acts an a labyrinth to reduce penetration of plasma species into the convoluted gap. An open inner channel 230 lies between the inner lip 218 and the raised ridge 224. The open inner channel 230 extends radially inward to terminate at least partially below the overhanging edge 206 of the substrate 104. The inner channel 230 has a first rounded corner 232 joining to the inner lip 218 and a gently sloped surface 234 joining to the raised ridge 224. The smooth corner 232 and sloped surface 234 facilitate the removal of sputtering deposits from these portions during cleaning of the deposition ring 208. The deposition ring 208 also has a ledge 236 which is located radially outward of the raised ridge 224 and serves to support the cover ring 212. In addition, a U-shaped channel 237 is provided between the raised ridge 224 and the ledge 236 to form a convoluted passageway therebetween which further prevents the flow the passage of plasma or gaseous species though the passageway thereby reducing the deposition of process deposits in the regions radially outward of the passageway. Thus the contour and profile of the deposition ring is shaped to reduce passage of process deposits through these regions. Unlike prior art designs, pins are not needed in the deposition ring 208 to retain the substrate 104 in the event that the substrate 104 slides or is misplaced in the chamber 100, due to accurate positioning of the substrate in the chamber during its transportation into the chamber.

The cover ring 212 of the ring assembly 202 encircles and at least partially covers the deposition ring 208 to receive, and thus, shadow the deposition ring 208 from the bulk of the sputtering deposits. The cover ring 212 is fabricated from a material that can resist erosion by the sputtering plasma, for example, a metallic material such as stainless steel, titanium or aluminum, or a ceramic material, such as aluminum oxide. In one version, the cover ring 212 is fabricated from titanium. The cover ring 212 comprises an annular wedge 244 which has a footing 246 which rests on the ledge 236 of the deposition ring 208 to support the cover ring 212. The footing 246 extends downwardly from the wedge 244 to press against the deposition ring 208 substantially without cracking or fracturing the ring 208.

The annular wedge 244 of the cover ring 212 has an inclined surface 248 that serves as a boundary to contain the sputtering plasma within the process zone between the target and the support 130. The inclined surface 248 provides a smooth and continuous surface on which sputtering deposits can deposit and be easily removed. In one version, the inclined surface 248 is inclined at an angle relative to an axis which is perpendicular to the flat plane formed by the processing surface of the substrate 104. In one version, the angle is at least about 60°, and can be even from about 65 to about 85°, or even about 80°. The angle of the inclined surface of the cover ring 212 is designed to minimize the buildup of sputter deposits nearest to the overhanging edge 206 of the substrate 104, which would otherwise negatively impact the deposition uniformity obtained across the substrate 104.

The wedge 244 tapers to the projecting brim 252 which overlies the inner channel 230 of the deposition ring 208. The projecting brim 252 terminates in a rounded edge 256 and has a planar bottom surface 268. The projecting brim 252 reduces deposition of sputtering deposits on the open inner channel of the deposition ring 208. Advantageously, the projecting brim 252 projects a distance corresponding to at least about half the width of the open inner channel of the deposition ring 208. For example, if the inner channel 230 has a width of at least about 12 mm, the projecting brim 252 has a width of at least about 6 mm. The projecting brim 252 projects over the open inner channel 230 of the deposition ring 208 to reach closer to the peripheral edge 206 of the substrate cover a portion of the open inner channel 230 of the deposition ring 208. In addition, the projecting brim 252 has a raised ridge 253 which extends downwardly and has an external shape with a profile which matches and follows the contour of the surface 234 of the underlying deposition ring 208. This shaped and closely matching contoured features inhibit the deposition of sputtering deposits on the peripheral overhang edge 206 of the substrate and also reduces deposits on the peripheral walls 204 of the support 130. They also force deposition to occur in the surface of the channel 230 by inhibiting the flow of gaseous plasma species and sputtered deposits over the peripheral edge 204. Thus, the contour of the raised ridge of the projecting brim 252 is sized, shaped, and positioned to cooperate with and complement the open inner channel 230 of the deposition ring 208 to form a convoluted and constricted flow path between the cover ring 212 and deposition ring 208 to inhibit the flow of process deposits onto the peripheral edge 204. The constricted flow path also restricts the build-up of low-energy sputter deposits on the mating surfaces of the deposition ring 208 and cover ring 212, which would otherwise cause them to stick to one another or to the peripheral overhang edge 206 of the substrate 104. The open inner channel 230 of the deposition ring 208 which extends underneath the substrate overhang edge 206 is designed in conjunction with shadowing from the projecting brim 252 of the cover ring 208 to collect, for example, a minimum of 3900 μm of aluminum sputter deposits in an aluminum sputtering chamber 100, while reducing or even substantially precluding sputter deposition on the mating surfaces of the two rings 208, 212.

The cover ring 212 also has a pair of cylindrical walls 260 that extend downwardly from the annular wedge 244. The cylindrical walls 260 are located radially outward of the footing 246 of the wedge 244. The cylindrical walls 260 comprise an inner wall 260a and the outer wall 260b, the inner wall 260a having a smaller height than the outer wall 260b. The radially internal surface 262 of the inner wall 260a is sloped to match a slope angle of the radially outer surface 264 of the deposition ring 208 to form yet another convoluted pathway 266 which impedes travel of plasma species and glow discharges to the surrounding area. Typically, the height of the outer wall 260a is at least about 1.2 times the height of the inner wall 260b. For example, for a cover ring 212 having an inner radius of about 154 mm, the height of the outer wall 160a is from about 25 mm, and the height of the inner wall 260b is from about 19 mm.

In another version, the process kit 200 also includes an anti-lift bracket 270 is used to retain the deposition ring 208 about the periphery of the substrate support 130 in the chamber 100, as shown in FIGS. 3-6. The anti-lift bracket 270 cooperates with additional structural features of the deposition ring 208 and support 130. For example, the deposition ring 208 comprises two peripheral recessed pockets 274 with holding posts 278 extending out from the pockets 274 to receive a pair of anti-lift brackets 270 on either side, one side being shown in FIG. 5. The pairs of pockets are located diametrically opposing one another across the support 130. In this version, a restraint beam 280 is also mounted on a backside surface 276 of the support 130 to hold onto the anti-lift bracket 270, as shown in FIGS. 4A and 4B. The restraint beam 280 comprises two opposing flat prongs 282a,b which extend radially outward of a circular ring 284 in the backside surface 276 of the support 130. The two opposing flat prongs 282a,b are mounted on the vertical arms 286a,b which are joined to the circular ring 284. The circular ring 284 is shaped and sized to fit into a recess 287 in the backside of the support 130.

The anti-lift bracket 270 comprises a block 290 comprising a through-channel 294 which receives a prong end 282a of the restraint beam 280 as shown in FIGS. 5 and 6. The through-channel 294 comprises an oval shaped slot 296 sized larger than the prong 282a of the restraint beam 280. A retaining hoop 298 attached to the block 290 is sized to slide over a holding post 278 in a recessed pocket 274 of the deposition ring 208. During assembly, the anti-lift bracket 270 is brought alongside the outer periphery of the deposition ring 208 and the slot 296 of the through-channel 294 is slid onto a prong 282 of the restraint beam 280 as shown by the arrows 283 so that the access hole 299 of the retaining hoop 298 is directly above the holding post 278 as shown in FIG. 5. The anti-lift bracket 274 is then lowered, as shown by the arrow 285, so that the retaining hoop 298 drops down and encircles the holding post 278 allowing the weight of the block 290 of the bracket 270 to stably hold down the deposition ring 208 as shown in FIG. 6. The anti-lift bracket 270 only engages the restraint beam 280 when the deposition ring 208 is pulled upwards, for example, when the deposition ring becomes stuck to the substrate 104. This design minimizes the thermal and mechanical strain on the ceramic deposition ring 208 and cover ring 212 in normal use.

Another version of an assembly comprising the anti-lift bracket 270 which is used to retain the deposition ring 208 about the periphery of the substrate support 130 in the chamber 100, is shown in FIGS. 7 and 8. In this version, the anti-lift bracket 270 is attached to a ceramic isolator 400 which then couples to a flat prongs 282a,b of the restraint beam 280. The anti-lift bracket 270 slides onto a ledge 402 which extends out of a block 404 of the ceramic isolator 400. The ceramic isolator 400 serves to electrically isolate the restraint beam 280 from the other components by providing an insulating member in the electrical pathway between the support 130 and the deposition ring 208. When the deposition ring 208 is made from a metal, interrupting the electrical pathway, serves to reduce electrical interference between these two structures. The block 404 of the ceramic isolator 400 also has a recessed surface 408 for resting the restraint beam 280. A through-hole 410 in the block 404 is provided for the pin 414 to connect the ceramic isolator 400 to the matching holes 422a,b in the facing and parallel extensions 420a,b of the prong 282a of the restraint beam 280. The pin 414 has two reduced diameter posts 418a,b which are passed through the through hole and a flat edge which rests against the surface of the parallel extensions 420a,b of the prong 282a. The pin 414 can be made from a metal, such as stainless steel. The ledge 402 of the ceramic isolator extends radially outward from the block 404 and has a protrusion 424 which acts as a stop against a receiving surface 430 of the anti-lift bracket 270. The ceramic isolator 400 is typically machine from a ceramic, such as aluminum oxide. It should be noted that while one ceramic structure is described, other ceramic structures blocks can also be placed in the pathway between the restraint beam 280 and the anti-lift bracket 270 to further isolate the structures, such as a ceramic block (not shown) placed between the beam 280 and the substrate support 130 at their interface.

The process kit 200 also includes a unitary cylindrical shield 150 that encircles the sputtering surface 142 of a sputtering target 140 that faces the substrate support 130, and the outer periphery of the substrate support 130, and shadows the sidewalls 116 of the chamber 100. The shield 150 serves to reduce deposition of sputtering deposits originating from the sputtering surface 142 of the sputtering target 140 onto the surfaces of support 130, and the sidewalls 116 and bottom wall 120 of the chamber 100. The shield 150 comprises a cylindrical outer band 314 having a diameter sized to encircle the sputtering surface 142 of the sputtering target 140 and the substrate support 130. The outer band 314 has an upper end 316 and a bottom end 318. The upper end 316 tapering in thickness in the direction of the bottom end 318, and having a radially outwardly tapered surface 320 adjacent to a sloped peripheral surface 322 of the sputtering target 140. The shield 150 further comprises a base plate 324 extending radially inward from the bottom end 318 of the outer band 314 to join a cylindrical inner band 328 that at least partially surrounds the peripheral edge 204 of the substrate support 130. The inner band 328 comprises a height that is smaller than the outer band 314, for example, the inner band 328 has a height which is 0.8 times smaller than the height of the outer band 314. The gaps between the inner and outer bands 328, 314, respectively, and the outer wall 260b and inner wall 260a of the cover ring 212 again serve to hinder and impede ingress of plasma species into this region.

The outer band 314, base plate 324 and inner band 328 of the unitary shield 150 comprise a unitary monolith structure that is a single piece. For example, the entire shield 150 can be made from 300 series stainless steel. This is advantageous over prior shields which included multiple components, often two or three separate pieces to make up the complete shield, which made it more difficult and laborious to remove the shield for cleaning. Also, the single piece shield 150 has a continuous surface 326 exposed to the sputtering deposits without interfaces or corners that are more difficult to clean out. Also, the single piece shield 150 is more thermally uniform than multiple shields, both for heating during periodic maintenance as well as cooling during processes in which a plasma is heating the shield. The single piece shield 150 has only one thermal interface to the heat exchanger 330. The single piece shield 150 also shields the chamber walls 108 from sputter deposition during process cycles. The shield 150 also creates a contoured gap in the region of the target 140 referred to as the “darkspace” to help shape the plasma while preventing arcing between target 140 and chamber 100.

A heat exchanger 330 was used to cool the shield 150 to reduce the thermal expansion stresses. Portions of the shield 150 can become excessively heated by exposure to the plasma formed in the substrate processing chamber. Excessive heating of the shield 150 results in its thermal expansion which causes sputtering deposits formed on the shield 150 to flake off from the shield to fall upon and contaminate the substrate 104. The heat exchanger 330 comprises a plate 332 made of metal, such as stainless steel. The plate 332 has an inner perimeter 335 comprising a circular aperture 336 sized to fit around the cylindrical shield 150, and an outer perimeter 338 comprising a polygon with a plurality of sides 340, as shown in FIG. 9.

The heat exchanger 330 has a polygon conduit 334 to flow heat exchange fluid from a fluid source (not shown) therethrough to cool the plate 332. The polygon conduit 334 comprises a plurality of legs 344a-h interconnected in a polygonal pattern around the circular aperture 336. The legs 344a-h are each drilled at an acute angle starting from a side 340 of the outer perimeter of the plate 332, the acute angles being from about 20 to about 45°. The conduit 334 also comprises channels 342a-c that are each covered by a cover plate 345a-c which has an oval O-ring 347a-c in a groove 349a-c in the plate 345a-c to seal the interface. The polygonal conduit 334 also has an inlet 346 and outlet 348 to receive and pass out the heat exchange fluid. The inlet and outlet 346, 348 comprise channels 352a,b that feed into a manifold 350.

The heat exchange fluid is flowed through the polygonal conduit 334 to exchange heat with the shield 150 and control its temperature. A suitable heat exchange fluid may be, for example, water. Controlling the temperature of the shield 150 reduces expansion of the shield in the plasma environment limiting the flaking of the sputtering deposits from the shield. Fastening the shield 150 to the heat exchanger 330 provides better heat transfer between the shield 150 and the heat exchanger plate 332. The shield 150 is fastened to the heat exchanger by a fastener 358, and in this version, the shield comprises a ledge 360 having a substantially vertical opening 362 extending therethrough. The fastener 358 is shaped and sized to pass through the opening 362 in the ledge 360 to fasten the shield 150 to the heat exchanger 330. Advantageously, the heat exchanger 330 integrates the source coil 153 and target 140 to the chamber 100 while also holding the shield 150. Water-cooling also provides greater thermal stability of the single piece shield 150 during the process.

The sputtering target 140 comprises a backing plate 370, typically made from a high strength aluminum alloy, which supports a sputtering plate 374 comprising the sputtering surface 142. The backing plate 370 of the target 140 is separated and the electrically isolated from the chamber 100 by the isolator 144 which is typically a ring made from a ceramic material, such as aluminum oxide. The sputtering plate 374 is composed of a high purity sputtering material to be sputtered onto the substrate 104, such as for example, aluminum, tantalum, titanium, and other such metals, typically at a purity of 99.99% or higher. The sputtering plate 374 comprises a perimeter with a sloped edge 322 adjacent to, and matching the contour of, the sloped surface 320 of the shield 150, which defines a gap 380 having a uniform thickness therebetween which serves as another plasma retarding convoluted labyrinth.

In one version, the backplate of the target 140 comprises a peripheral ledge 390 which extends beyond the radius of the sputtering plate 374. The peripheral ledge 390 supports the target 140 by resting on the isolator 144 and can be fastened to the isolator 144 or the chamber sidewall 116. The peripheral ledge 390 extends beyond the sloped edge 322 of the sputtering plate 374 and comprises an outer footing section 392 which rests on the isolator 144 in the chamber 100. The peripheral ledge 390 comprises an inner bump 394 which is shaped and sized to reduce deposition of sputtering deposits on the isolator 144 and shield 150. The bump 394 in combination with an immediately abutting and preceding groove 396 reduces plasma formation and the deposition of sputtering process deposits on undesired areas of the chamber walls 108, isolator 144 and heat exchanger 330. The bump 394 and groove 396 are shaped, sized and positioned to inhibit the flow or migration of plasma and sputtered species through the gap between the target 140 and the isolator 144. In particular, the bump 394 impedes the penetration of low-angle sputtered deposits into the gap between the target and the isolator. The bump 394 comprises a curved cross-section with a height of from about 1.5 to about 2 mm.

The various components of the process kit 200 and the target 140 significantly increase the number of process cycles and process on-time that the process kit can be used in the chamber without removing the process kit for cleaning. This is accomplished by reducing the amount of sputtering deposits formed on the components around the substrate which are difficult to clean. The components of the process kit 200 and target 140 are designed to allow increased power and pressure in the sputtering zone 106 to yield higher deposition throughput by reducing the temperature in the darkspace region which is near the upper end 316 of the shield 150 and near the target 140. It also improves the thermal uniformity of the shield 150 using the heat exchanger 330. In addition, the process kit 200 is designed to allow at least 85% more aluminum to be deposited in the chamber 100 before the kit 200 has to be changed to perform a maintenance cycle. This is a significant improvement in the uptime of the chamber and also increases process throughput.

FIG. 10 is a graph of modeling results obtained for a scaled geometry of the process kit in aluminum sputter deposition showing the thickness of deposits formed on the deposition ring 208 and cover ring 212 as a function of distance from the substrate 104 and support 130. The modeling program was PVD Pro™ program and it uses parameters for the type of metal being deposited as well as the geometry of the target and other chamber components. The model allowed the comparison of several different configurations for the features of, and position of the cover ring 212 and deposition ring 208. This allowed optimization for minimum buildup of aluminum deposits on the surfaces of the groove 230 in the deposition ring 208, as well as in the line of sight of the edge 252 of the cover ring 212. The modeling accuracy was determined with a test run of prototype hardware, and also by modeling geometry of known performance, to obtain the designs presented herein. It is seen that changing the shape and design configurations of the chamber components and the spaces and gaps therebetween, significantly changed the thickness of deposition material on the surfaces of the components. Further, the rate of increase in the amount of deposition on the deposition ring remained at about the same for increasing distance from the substrate center as shown by the same angle of the linear sections of the graph between 0.5 and 1.5 on the x-axis. There is a vertical change in the net amount of deposition for different configurations, but the shape of the curve remains essentially the same.

The present invention has been described with reference to certain preferred versions thereof; however, other versions are possible. For example, the process kit 200 and ring assembly 202 can be used in other types of applications, as would be apparent to one of ordinary skill, for example, etching, CVD and etching chambers. Other shapes and configurations of the deposition ring 208, cover ring 212, shield 150 and anti-lift bracket 270 can also be used. Therefore, the spirit and scope of the appended claims should not be limited to the description of the preferred versions contained herein.

Yoshidome, Goichi, Allen, Adolph Miller, Flanigan, Michael Allen, Scheible, Kathleen, Pavloff, Cristopher

Patent Priority Assignee Title
Patent Priority Assignee Title
3482082,
3679460,
3716462,
3725220,
3748253,
4374722, Aug 08 1980 JACKSON TUBE SERVICE, INC Cathodic sputtering target including means for detecting target piercing
4384918, Sep 30 1980 Fujitsu Limited Method and apparatus for dry etching and electrostatic chucking device used therein
4412133, Jan 05 1982 Applied Materials, Inc Electrostatic cassette
4415421, Mar 05 1982 Citizen Watch Co., Ltd. Process for manufacturing ornamental parts and ion plating apparatus to be used therefor
4419201, Aug 24 1981 CHASE MANHATTAN BANK, AS ADMINISTRATIVE AGENT, THE Apparatus and method for plasma-assisted etching of wafers
4430173, Jul 24 1981 Rhone-Poulenc Specialties Chimiques Additive composition, bath and process for acid copper electroplating
4480284, Feb 03 1982 Tokyo Shibaura Denki Kabushiki Kaisha Electrostatic chuck plate
4491496, Jan 05 1983 COMMISSARIAT A L ENERGIE ATOMIQUE Enclosure for the treatment, and particularly for the etching of substrates by the reactive plasma method
4505947, Jul 14 1982 The Standard Oil Company (Ohio) Method for the deposition of coatings upon substrates utilizing a high pressure, non-local thermal equilibrium arc plasma
4545882, Sep 02 1983 BOC GROUP PLC, THE, CHERTSEY ROAD, WINDLESHAM SURREY, ENGLAND GU20 6HJ, A CORP OF GREAT BRITAIN Method and apparatus for detecting sputtering target depletion
4606802, Dec 21 1983 Hitachi, Ltd. Planar magnetron sputtering with modified field configuration
4645218, Jul 31 1984 Kabushiki Kaisha Shibaura Seisakusho Electrostatic chuck
4665463, Sep 30 1983 U.S. Philips Corporation Electrostatic chuck
4717462, Oct 25 1985 Hitachi, Ltd. Sputtering apparatus
4832781, Jan 07 1988 Varian Semiconductor Equipment Associates, Inc Methods and apparatus for thermal transfer with a semiconductor wafer in vacuum
4872250, Sep 18 1986 Ernst Grob AG Method for fabricating a dished hollow body possessing a linear or helical inner toothing
4872964, Aug 02 1985 Fujitsu Limited Planar magnetron sputtering apparatus and its magnetic source
4905886, Jul 20 1988 VOUGHT AIRCRAFT INDUSTRIES, INC Method for diffusion bonding of metals and alloys using thermal spray deposition
4913784, Jul 04 1985 LICENTIA PATENT-VERWALTUNGS GMBH, THEODOR-STERN-KAI 1, D-6000 FRANKFURT AM MAIN 70, FED REP OF GERMANY Process for metallizing a ceramic substrate
4924436, Jun 22 1987 Energy Conversion Devices, Inc. Data storage device having a phase change memory medium reversible by direct overwrite and method of direct overwrite
4983269, Dec 23 1986 Balzers Aktiengesellschaft Method for erosion detection of a sputtering target and target arrangement
4995958, May 22 1989 Varian Semiconductor Equipment Associates, Inc Sputtering apparatus with a rotating magnet array having a geometry for specified target erosion profile
5041194, May 18 1989 MITSUBISHI PETROCHEMICAL CO , LTD ; NISSHIN STEEL CO , LTD Aluminum electroplating method
5055964, Sep 07 1990 DORSEY GAGE CO , INC Electrostatic chuck having tapered electrodes
5064511, Jun 05 1989 Diaprint S.r.l. Electrochemical graining of aluminum or aluminum alloy surfaces
5104834, Apr 26 1988 TOTO LTD , A JAPAN CORP Dielectric ceramics for electrostatic chucks and method of making them
5117121, Apr 25 1989 Toto Ltd. Method of and apparatus for applying voltage to electrostatic chuck
5151845, Sep 19 1988 Toto Ltd. Electrostatic chuck
5166758, Jan 18 1991 Ovonyx, Inc Electrically erasable phase change memory
5166856, Jan 31 1991 International Business Machines Corporation Electrostatic chuck with diamond coating
5191506, May 02 1991 DORSEY GAGE CO , INC Ceramic electrostatic chuck
5215639, Oct 09 1984 AIXTRON, INC Composite sputtering target structures and process for producing such structures
5258047, Nov 30 1990 Renesas Electronics Corporation Holder device and semiconductor producing apparatus having same
5270266, Dec 13 1991 Tokyo Electron Limited Method of adjusting the temperature of a semiconductor wafer
5275683, Oct 24 1991 Tokyo Electron Limited Mount for supporting substrates and plasma processing apparatus using the same
5280156, Dec 25 1990 NGK Insulators, Ltd. Wafer heating apparatus and with ceramic substrate and dielectric layer having electrostatic chucking means
5314597, Mar 20 1992 Novellus Systems, Inc Sputtering apparatus with a magnet array having a geometry for a specified target erosion profile
5315473, Jan 21 1992 APPLIED MATERIALS, INC A CORP OF DELAWARE Isolated electrostatic chuck and excitation method
5324053, Feb 20 1992 Shin-Etsu Chemical Co., Ltd. Electrostatic chuck
5325261, May 17 1991 HORWITZ, CHRISTOPHER MAX Electrostatic chuck with improved release
5342496, May 18 1993 Tosoh SMD, Inc. Method of welding sputtering target/backing plate assemblies
5350479, Dec 02 1992 Applied Materials, Inc Electrostatic chuck for high power plasma processing
5356723, Dec 18 1991 Sumitomo Metal Industries, Ltd.; Sumitomo Light Metal Industries, Ltd. Multilayer plated aluminum sheets
5382469, Jun 26 1992 Shin-Etsu Chemical Co., Ltd. Ceramic-titanium nitride electrostatic chuck
5391275, Mar 02 1990 Applied Materials, Inc. Method for preparing a shield to reduce particles in a physical vapor deposition chamber
5401319, Aug 27 1992 Applied Materials, Inc Lid and door for a vacuum chamber and pretreatment therefor
5407551, Jul 13 1993 Von Ardenne Anlagentechnik GmbH; Applied Films Corporation Planar magnetron sputtering apparatus
5409590, Apr 17 1989 Tokyo Electron Limited Target cooling and support for magnetron sputter coating apparatus
5429711, Sep 18 1992 Sumco Corporation Method for manufacturing wafer
5433835, Nov 24 1993 Applied Materials, Inc Sputtering device and target with cover to hold cooling fluid
5435965, Feb 19 1991 Mitsubishi Materials Corporation Sputtering target and method for manufacturing same
5458759, Aug 02 1991 Anelva Corporation Magnetron sputtering cathode apparatus
5460694, Jun 17 1992 CFPI Industries Process for the treatment of aluminum based substrates for the purpose of anodic oxidation, bath used in said process and concentrate to prepare the bath
5463526, Jan 21 1994 Lam Research Corporation Hybrid electrostatic chuck
5474649, Mar 08 1994 Applied Materials, Inc Plasma processing apparatus employing a textured focus ring
5487822, Nov 24 1993 APPLIED MATERIALS, INC LEGAL AFFAIRS DEPARTMENT Integrated sputtering target assembly
5487823, Apr 28 1993 Japan Energy Corporation Sputtering targets having life alarm function
5490913, May 04 1993 Oerlikon Trading AG, Trubbach Magnetic field enhanced sputtering arrangement with vacuum treatment apparatus
5512078, Mar 24 1994 Innovaquartz Incorporated Apparatus for making linearly tapered bores in quartz tubing with a controlled laser
5518593, Apr 29 1994 APPLIED KOMATSU TECHNOLOGY Shield configuration for vacuum chamber
5538603, May 19 1993 Applied Materials, Inc. Apparatus and process for increasing uniformity of sputtering rate in sputtering apparatus
5542559, Feb 16 1993 Tokyo Electron Kabushiki Kaisha Plasma treatment apparatus
5549802, May 17 1993 Applied Materials, Inc. Cleaning of a PVD chamber containing a collimator
5565071, Nov 24 1993 Applied Materials, Inc. Integrated sputtering target assembly
5587039, Jan 09 1992 Varian Semiconductor Equipment Associates, Inc Plasma etch equipment
5595337, Nov 24 1993 Applied Materials, Inc. Sputtering device and target with cover to hold cooling fluid
5595938, Dec 28 1993 Mitsubishi Denki Kabushiki Kaisha Method of manufacturing semiconductor device
5628889, Sep 06 1994 International Business Machines Corporation High power capacity magnetron cathode
5643422, Dec 29 1994 NEC Electronics Corporation Reactive sputtering system for depositing titanium nitride without formation of titanium nitride on titanium target and process of depositing titanium nitride layer
5684669, Jun 07 1995 Applied Materials, Inc Method for dechucking a workpiece from an electrostatic chuck
5685914, Apr 05 1994 Applied Materials, Inc Focus ring for semiconductor wafer processing in a plasma reactor
5685959, Oct 25 1996 WD MEDIA, INC Cathode assembly having rotating magnetic-field shunt and method of making magnetic recording media
5690795, Jun 05 1995 Applied Materials, Inc Screwless shield assembly for vacuum processing chambers
5693203, Sep 29 1992 JX NIPPON MINING & METALS CORPORATION Sputtering target assembly having solid-phase bonded interface
5695825, May 31 1995 LIQUIDMETAL COATINGS, LLC Titanium-containing ferrous hard-facing material source and method for hard facing a substrate
5700179, Jul 28 1996 SHIN-ETSU HANDOTAI CO , LTD ; TOYO ADVANCED TECHNOLOGIES, CO , LTD Method of manufacturing semiconductor wafers and process of and apparatus for grinding used for the same method of manufacture
5714768, Oct 24 1995 OVONYX MEMORY TECHNOLOGY, LLC Second-layer phase change memory array on top of a logic device
5720818, Apr 26 1996 Applied Materials, Inc Conduits for flow of heat transfer fluid to the surface of an electrostatic chuck
5762748, Aug 27 1992 Applied Materials, Inc Lid and door for a vacuum chamber and pretreatment therefor
5772858, Jul 24 1995 Applied Materials, Inc.; Applied Materials, Inc Method and apparatus for cleaning a target in a sputtering source
5789717, Apr 26 1996 AICHI SANGYO CO , LTD Semi-automatic TIG welding apparatus
5792562, Jan 12 1995 Applied Materials, Inc Electrostatic chuck with polymeric impregnation and method of making
5798029, Jul 06 1995 Applied Materials, Inc. Target for sputtering equipment
5799860, Aug 07 1995 Applied Materials, Inc.; Applied Materials, Inc Preparation and bonding of workpieces to form sputtering targets and other assemblies
5800725, Jan 31 1996 Shin-Etsu Handotai Co., Ltd. Method of manufacturing semiconductor wafers
5803342, Dec 26 1996 Honeywell International Inc Method of making high purity copper sputtering targets
5808270, Feb 14 1997 Ford Global Technologies, Inc Plasma transferred wire arc thermal spray apparatus and method
5812362, Jun 14 1996 Applied Materials, Inc. Method and apparatus for the use of diamond films as dielectric coatings on electrostatic chucks
5821166, Dec 12 1996 KOMATSU ELECTRONIC METALS CO , LTD Method of manufacturing semiconductor wafers
5824197, Jun 05 1996 Applied Materials, Inc Shield for a physical vapor deposition chamber
5830327, Oct 02 1996 Intevac, Inc Methods and apparatus for sputtering with rotating magnet sputter sources
5858100, Apr 06 1994 Semiconductor Process Co., Ltd.; Canon Sales Co., Inc.; Alcan-Tech Co., Inc. Substrate holder and reaction apparatus
5876573, Jul 10 1996 CVC, INC , A CORPORATION OF DELAWARE; CVC PRODUCTS, INC High magnetic flux cathode apparatus and method for high productivity physical-vapor deposition
5879523, Sep 29 1997 Applied Materials, Inc. Ceramic coated metallic insulator particularly useful in a plasma sputter reactor
5879524, Feb 29 1996 PRAXAIR S T TECHNOLOGY, INC Composite backing plate for a sputtering target
5886863, May 19 1995 Kyocera Corporation Wafer support member
5887481, Feb 13 1996 Aluminum Pechiney Cathode sputtering targets with a low level of particle emission, precursors of these targets, and processes for obtaining them
5903428, Sep 25 1997 Applied Materials, Inc. Hybrid Johnsen-Rahbek electrostatic chuck having highly resistive mesas separating the chuck from a wafer supported thereupon and method of fabricating same
5910338, Apr 26 1996 Applied Materials, Inc. Surface preparation to enhance adhesion of a dielectric layer
5914018, Aug 23 1996 Applied Materials, Inc.; Applied Materials, Inc Sputter target for eliminating redeposition on the target sidewall
5916378, Mar 11 1997 Silicon Valley Group, Thermal Systems LLC Method of reducing metal contamination during semiconductor processing in a reactor having metal components
5916454, Aug 30 1996 Lam Research Corporation Methods and apparatus for reducing byproduct particle generation in a plasma processing chamber
5919345, Sep 27 1994 Applied Materials, Inc. Uniform film thickness deposition of sputtered materials
5920764, Sep 30 1997 International Business Machines Corporation Process for restoring rejected wafers in line for reuse as new
5942041, Sep 16 1996 Promos Technologies Inc Non-sticking semi-conductor wafer clamp and method of making same
5942089, Apr 22 1996 Northwestern University Method for sputtering compounds on a substrate
5942445, Mar 25 1996 SHIN-ETSU HANDOTAI CO , LTD Method of manufacturing semiconductor wafers
5948288, May 28 1996 Komag, Incorporated Laser disk texturing apparatus
5951374, Jan 31 1996 SHIN-ETSU HANDOTAI CO , LTD Method of polishing semiconductor wafers
5953827, Nov 05 1997 Applied Materials, Inc. Magnetron with cooling system for process chamber of processing system
5963778, Feb 13 1997 Tosoh SMD, Inc. Method for producing near net shape planar sputtering targets and an intermediate therefor
5976327, Dec 12 1997 Applied Materials, Inc Step coverage and overhang improvement by pedestal bias voltage modulation
6001426, Jul 25 1996 Utron Kinetics, LLC High velocity pulsed wire-arc spray
6010583, Sep 09 1997 PRAXAIR S T TECHNOLOGY, INC Method of making unreacted metal/aluminum sputter target
6015465, Apr 08 1998 Applied Materials, Inc Temperature control system for semiconductor process chamber
6024852, Dec 04 1996 Dexerials Corporation Sputtering target and production method thereof
6026666, Dec 28 1994 Dynamit Nobel Aktiengesellschaft Method for manufacturing internally geared parts
6040545, Jun 10 1997 Kabushiki Kaisha Toshiba TIG welding method and welding apparatus
6042706, Jan 14 1997 Applied Materials, Inc.; Applied Materials, Inc Ionized PVD source to produce uniform low-particle deposition
6051114, Jun 23 1997 Applied Materials, Inc Use of pulsed-DC wafer bias for filling vias/trenches with metal in HDP physical vapor deposition
6051122, Aug 21 1997 Applied Materials, Inc Deposition shield assembly for a semiconductor wafer processing system
6059945, Aug 23 1996 Applied Materials, Inc. Sputter target for eliminating redeposition on the target sidewall
6071323, Mar 07 1997 TDKCorporation Alloy target, its fabrication, and regeneration processes
6071389, Aug 21 1998 Tosoh SMD, Inc. Diffusion bonded sputter target assembly and method of making
6073830, Apr 21 1995 PRAXAIR S T TECHNOLOGY, INC Sputter target/backing plate assembly and method of making same
6086735, Jun 01 1998 PRAXAIR S T TECHNOLOGY, INC Contoured sputtering target
6108189, Apr 26 1996 Applied Materials, Inc Electrostatic chuck having improved gas conduits
6120640, Dec 19 1996 Applied Materials, Inc Boron carbide parts and coatings in a plasma reactor
6139701, Nov 26 1997 Applied Materials, Inc.; Applied Materials Inc Copper target for sputter deposition
6143432, Jan 09 1998 L. Pierre, deRochemont Ceramic composites with improved interfacial properties and methods to make such composites
6146509, Jun 11 1999 SciVac Inverted field circular magnetron sputtering device
6149776, Nov 12 1998 Applied Materials, Inc. Copper sputtering target
6149784, Oct 22 1999 Applied Materials, Inc.; Applied Materials, Inc Sputtering chamber shield promoting reliable plasma ignition
6150762, Jan 26 1998 Samsung Electronics Co., Ltd. Method of manufacturing cathode for plasma etching apparatus using chemical surface treatment with potassium hydroxide (KOH), and cathode manufactured thereby
6152071, Dec 11 1996 Canon Kabushiki Kaisha High-frequency introducing means, plasma treatment apparatus, and plasma treatment method
6159299, Feb 09 1999 Applied Materials, Inc.; Applied Materials, Inc Wafer pedestal with a purge ring
6162297, Sep 05 1997 Applied Materials, Inc. Embossed semiconductor fabrication parts
6170429, Sep 30 1998 Lam Research Corporation Chamber liner for semiconductor process chambers
6179973, Jan 05 1999 Novellus Systems, Inc Apparatus and method for controlling plasma uniformity across a substrate
6183614, Feb 12 1999 Applied Materials, Inc. Rotating sputter magnetron assembly
6183686, Aug 04 1998 Tosoh SMD, Inc. Sputter target assembly having a metal-matrix-composite backing plate and methods of making same
6187682, May 26 1998 Freescale Semiconductor, Inc Inert plasma gas surface cleaning process performed insitu with physical vapor deposition (PVD) of a layer of material
6190513, May 14 1997 Applied Materials, Inc Darkspace shield for improved RF transmission in inductively coupled plasma sources for sputter deposition
6190516, Oct 06 1999 PRAXAIR S T TECHNOLOGY, INC High magnetic flux sputter targets with varied magnetic permeability in selected regions
6198067, Dec 28 1998 Nippon Mektron, Ltd. Plasma processing device for circuit supports
6199259, Nov 24 1993 Applied Komatsu Technology, Inc. Autoclave bonding of sputtering target assembly
6221217, Jul 10 1995 CVC, INC Physical vapor deposition system having reduced thickness backing plate
6227435, Feb 02 2000 FORD GLOBAL TECHNOLOGIES, LLC ONE-HALF INTEREST ; JAGUAR CARS LIMITED ONE-HALF INTEREST Method to provide a smooth paintable surface after aluminum joining
6231725, Aug 04 1998 Applied Materials, Inc.; Applied Materials, Inc Apparatus for sputtering material onto a workpiece with the aid of a plasma
6238528, Oct 13 1998 Applied Materials, Inc. Plasma density modulator for improved plasma density uniformity and thickness uniformity in an ionized metal plasma source
6244121, Mar 06 1998 Applied Materials, Inc. Sensor device for non-intrusive diagnosis of a semiconductor processing system
6248667, Mar 18 1999 Samsung Electronics Co., Ltd. Chemical mechanical polishing method using double polishing stop layer
6250251, Mar 31 1998 Canon Kabushiki Kaisha Vacuum processing apparatus and vacuum processing method
6251242, Jan 21 2000 Applied Materials, Inc Magnetron and target producing an extended plasma region in a sputter reactor
6267851, Oct 28 1999 Applied Komatsu Technology, Inc. Tilted sputtering target with shield to block contaminants
6269670, Jul 09 1998 LEIFELD METAL SPINNING GMBH Method for forming a workpiece by flow-forming
6274008, Mar 02 2000 Applied Materials, Inc. Integrated process for copper via filling
6276997, Dec 23 1998 Use of chemical mechanical polishing and/or poly-vinyl-acetate scrubbing to restore quality of used semiconductor wafers
6277249, Jan 21 2000 Applied Materials, Inc Integrated process for copper via filling using a magnetron and target producing highly energetic ions
6277263, Mar 20 1998 Applied Materials Inc Apparatus and method for electrolytically depositing copper on a semiconductor workpiece
6283357, Aug 03 1999 PRAXAIR S T TECHNOLOGY, INC Fabrication of clad hollow cathode magnetron sputter targets
6284093, Nov 29 1996 Applied Materials, Inc. Shield or ring surrounding semiconductor workpiece in plasma chamber
6284628, Apr 23 1998 Shin-Etsu Handotai Co., Ltd. Method of recycling a delaminated wafer and a silicon wafer used for the recycling
6287437, May 05 2000 Alcatel Recessed bonding of target for RF diode sputtering
6299740, Jan 19 2000 VEECO INSTRUMENTS, INC Sputtering assembly and target therefor
6306226, Oct 24 1997 Nihon Papkerizing Co., Ltd.; Denso Corporation Process for surface-treating an aluminum-containing metal
6306498, Dec 22 1997 Asahi Kasei Kabushiki Kaisha Fibers for electric flocking and electrically flocked article
6309556, Sep 03 1998 PRAXAIR S T TECHNOLOGY, INC Method of manufacturing enhanced finish sputtering targets
6337151, Aug 18 1999 International Business Machines Corporation Graded composition diffusion barriers for chip wiring applications
6337453, Jun 25 1999 West Bond, Inc. Method and apparatus for arc-forming a bonding wire ball with attenuated electro-magnetic interference
6338781, Dec 21 1996 SINGULUS TECHNOLOGIES AG Magnetron sputtering cathode with magnet disposed between two yoke plates
6338906, Sep 17 1992 COORSTEK, INC Metal-infiltrated ceramic seal
6340415, Jan 05 1998 Applied Materials, Inc. Method and apparatus for enhancing a sputtering target's lifetime
6344114, Dec 21 1996 SINGULUS TECHNOLOGIES AG Magnetron sputtering cathode with magnet disposed between two yoke plates
6346177, Jan 02 1997 Micron Technology, Inc. Method of in-situ cleaning and deposition of device structures in a high density plasma environment
6365010, Nov 06 1998 WINSKY TECHNOLOGY LIMITED Sputtering apparatus and process for high rate coatings
6372609, Oct 16 1998 Soitec Method of Fabricating SOI wafer by hydrogen ION delamination method and SOI wafer fabricated by the method
6387809, Mar 23 1998 Shin-Etsu Handotai Co., Ltd. Method and apparatus for lapping or polishing semiconductor silicon single crystal wafer
6406599, Nov 01 2000 Applied Materials, Inc Magnetron with a rotating center magnet for a vault shaped sputtering target
6409965, Sep 21 1999 Dexerials Corporation Sputtering target and its manufacturing method
6413382, Nov 03 2000 Applied Materials, Inc. Pulsed sputtering with a small rotating magnetron
6413387, Oct 24 1997 Nanyang Technological University Cathode arc source for metallic and dielectric coatings
6413858, Aug 27 1999 U S BANK NATIONAL ASSOCIATION, AS COLLATERAL AGENT Barrier and electroplating seed layer
6416634, Apr 05 2000 Applied Materials, Inc. Method and apparatus for reducing target arcing during sputter deposition
6419806, Dec 03 1998 Tosoh SMD, Inc. Insert target assembly and method of making same
6423175, Oct 06 1999 Taiwan Semiconductor Manufacturing Co., Ltd Apparatus and method for reducing particle contamination in an etcher
6432203, Mar 17 1997 APPLIED KOMATSU TECHNOLOGY, INC Heated and cooled vacuum chamber shield
6436251, Jan 21 2000 Applied Materials, Inc. Vault-shaped target and magnetron having both distributed and localized magnets
6437383, Dec 21 2000 Intel Corporation Dual trench isolation for a phase-change memory cell and method of making same
6440221, May 13 1996 Applied Materials, Inc Process chamber having improved temperature control
6444104, Jan 21 2000 Applied Materials, Inc. Sputtering target having an annular vault
6451177, Jan 21 2000 Applied Materials, Inc Vault shaped target and magnetron operable in two sputtering modes
6454919, Apr 14 1998 Applied Materials, Inc. Physical vapor deposition apparatus with deposition and DC target power control
6464794, Sep 23 1998 SAMSUNG ELECTRONICS CO , LTD Process chamber used in manufacture of semiconductor device, capable of reducing contamination by particulates
6464889, Jan 22 1996 Etex Corporation Surface modification of medical implants
6475336, Oct 06 2000 Lam Research Corporation Electrostatically clamped edge ring for plasma processing
6475854, Dec 30 1999 Applied Materials, Inc Method of forming metal electrodes
6482302, Oct 13 2000 Honeywell International Inc. Container-shaped physical vapor deposition targets
6487910, Jun 09 1998 Tosoh SMD, Inc. Method and apparatus for quantitative sputter target cleanliness and characterization
6491801, Aug 07 2001 Applied Materials, Inc. Auxiliary vertical magnet outside a nested unbalanced magnetron
6494098, Jan 16 1998 TOSOH SMD, INC Method of ultrasonic on-line texture characterization
6495009, Aug 07 2001 Applied Materials, Inc. Auxiliary in-plane magnet inside a nested unbalanced magnetron
6500321, May 26 1999 Novellus Systems, Inc. Control of erosion profile and process characteristics in magnetron sputtering by geometrical shaping of the sputtering target
6506312, Jan 16 1997 Vapor deposition chamber components and methods of making the same
6507061, Aug 31 2001 U S BANK NATIONAL ASSOCIATION, AS COLLATERAL AGENT Multiple layer phase-change memory
6518086, Nov 16 1999 Alliance for Sustainable Energy, LLC Processing approach towards the formation of thin-film Cu(In,Ga)Se2
6537428, Sep 02 1999 VEECO INSTRUMENTS, INC Stable high rate reactive sputtering
6555471, Feb 18 1997 U S BANK NATIONAL ASSOCIATION, AS COLLATERAL AGENT Method of making a void-free aluminum film
6558505, Nov 30 1998 Kawasaki Microelectronics, Inc. Method and apparatus for processing semiconductor substrates
6576909, Feb 28 2001 GOOGLE LLC Ion generation chamber
6579431, Jan 14 1998 TOSOH SMD, INC Diffusion bonding of high purity metals and metal alloys to aluminum backing plates using nickel or nickel alloy interlayers
6599405, May 30 2001 Praxair S.T. Technology, Inc. Recessed sputter target
6610959, Apr 26 2001 Regents of the University of Minnesota Single-wire arc spray apparatus and methods of using same
6613959, Aug 10 1998 General Hospital Corporation, The Transgenic plants expressing a MAPKKK protein kinase domain
6619537, Jun 12 2000 Tosoh SMD, Inc. Diffusion bonding of copper sputtering targets to backing plates using nickel alloy interlayers
6620296, Jul 17 2000 Applied Materials, Inc Target sidewall design to reduce particle generation during magnetron sputtering
6620736, Jul 24 2001 Tokyo Electron Limited Electrostatic control of deposition of, and etching by, ionized materials in semiconductor processing
6623597, Sep 29 1999 SAMSUNG ELECTRONICS CO , LTD Focus ring and apparatus for processing a semiconductor wafer comprising the same
6623610, Mar 02 2002 Magnetron sputtering target for magnetic materials
6627050, Jul 28 2000 Applied Materials, Inc.; Applied Materials, Inc Method and apparatus for depositing a tantalum-containing layer on a substrate
6635219, Mar 13 2001 Industrial Technology Research Institute Method of regenerating a phase-change sputtering target for optical storage media
6652668, May 31 2002 Praxair S.T. Technology, Inc. High-purity ferromagnetic sputter targets and method of manufacture
6660135, Jun 28 1999 Applied Materials, Inc. Staged aluminum deposition process for filling vias
6677254, Jul 23 2001 Applied Materials, Inc Processes for making a barrier between a dielectric and a conductor and products produced therefrom
6699375, Jun 29 2000 Applied Materials, Inc. Method of extending process kit consumable recycling life
6708870, May 24 2002 Praxair S.T. Technology, Inc. Method for forming sputter target assemblies
6709557, Feb 28 2002 Novellus Systems, Inc. Sputter apparatus for producing multi-component metal alloy films and method for making the same
6716321, Oct 04 2001 Northrop Grumman Systems Corporation Modified electrical properties of sputtered thermal coatings
6730196, Aug 01 2002 Applied Materials, Inc.; Applied Materials, Inc Auxiliary electromagnets in a magnetron sputter reactor
6739196, May 11 2000 Tosoh SMD, Inc. Cleanliness evaluation in sputter targets using phase
6743340, Feb 05 2002 Applied Materials, Inc.; Applied Materials, Inc Sputtering of aligned magnetic materials and magnetic dipole ring used therefor
6743342, Mar 12 2002 Applied Materials, Inc.; Applied Materials, Inc Sputtering target with a partially enclosed vault
6749103, Sep 11 1998 Tosoh SMD, Inc. Low temperature sputter target bonding method and target assemblies produced thereby
6750156, Oct 24 2001 Applied Materials, Inc Method and apparatus for forming an anti-reflective coating on a substrate
6759267, Jul 19 2002 Macronix International Co., Ltd. Method for forming a phase change memory
6776879, Jan 29 2001 Sharp Kabushiki Kaisha Backing plate used for sputtering apparatus and sputtering method
6777045, Jun 27 2001 Applied Materials, Inc Chamber components having textured surfaces and method of manufacture
6797362, Jan 20 2000 Honeywell International Inc. Physical vapor deposition target constructions
6824652, Mar 02 2002 LG DISPLAY CO , LTD Sputtering target assembly and sputtering apparatus using the same
6840427, Sep 11 2000 TOSOH SMD, INC Method of manufacturing sputter targets with internal cooling channels
6841050, May 21 2002 Applied Materials, Inc Small planetary magnetron
6848608, Oct 01 2002 GLOBAL ADVANCED METALS, USA, INC Method of bonding sputtering target materials
6852202, May 21 2002 Applied Materials, Inc.; Applied Materials, Inc Small epicyclic magnetron with controlled radial sputtering profile
6858116, Nov 17 2000 JX NIPPON MINING & METALS CORPORATION Sputtering target producing few particles, backing plate or sputtering apparatus and sputtering method producing few particles
6858277, Mar 15 1999 Panasonic Corporation Information recording medium and method for manufacturing the same
6872284, Apr 24 2001 Tosoh SMD, Inc. Target and method of optimizing target profile
6887356, Nov 27 2000 GLOBAL ADVANCED METALS, USA, INC Hollow cathode target and methods of making same
6916407, Nov 27 2000 Unaxis Trading AG Target comprising thickness profiling for an RF magnetron
6933025, Jun 27 2001 Applied Materials, Inc. Chamber having components with textured surfaces and method of manufacture
6946408, Oct 24 2001 Applied Materials, Inc Method and apparatus for depositing dielectric films
6955852, Sep 11 2000 Tosoh SMD, Inc. Method of manufacturing sputter targets with internal cooling channels
6992261, Jul 15 2003 GLOBAL ADVANCED METALS, USA, INC Sputtering target assemblies using resistance welding
7026009, Mar 27 2002 Applied Materials, Inc Evaluation of chamber components having textured coatings
7037762, May 10 2002 Samsung Electronics Co., Ltd. Phase changeable memory devices having multi-level data storage elements and methods of fabricating the same
7063773, Aug 17 2000 TOSOH SMD, INC High purity sputter targets with target end-of-life indication and method of manufacture
7115193, Mar 14 2001 JX NIPPON MINING & METALS CORPORATION Sputtering target producing very few particles, backing plate or apparatus within sputtering device and roughening method by electric discharge machining
7115927, Feb 24 2003 Samsung Electronics Co., Ltd. Phase changeable memory devices
7131883, Jan 30 2002 Samsung SDI Co., Ltd. Field emission display manufacturing method having integrated getter arrangement
7146703, Dec 18 2000 TOSOH SMD, INC Low temperature sputter target/backing plate method and assembly
7175802, Sep 17 2001 HERAEUS, INC Refurbishing spent sputtering targets
7297247, May 06 2003 Applied Materials, Inc. Electroformed sputtering target
7316763, May 24 2005 Applied Materials, Inc. Multiple target tiles with complementary beveled edges forming a slanted gap therebetween
7331250, Mar 06 1998 Applied Materials, Inc. Sensor device for non-intrusive diagnosis of a semiconductor processing system
7476289, Jun 29 2006 Applied Materials, Inc. Vacuum elastomer bonding apparatus and method
7504008, Mar 12 2004 Applied Materials, Inc. Refurbishment of sputtering targets
7550055, May 31 2005 Applied Materials, Inc Elastomer bonding of large area sputtering target
7550066, Jul 09 2004 Applied Materials, Inc.; Applied Materials, Inc Staggered target tiles
7588668, Sep 13 2005 Applied Materials, Inc. Thermally conductive dielectric bonding of sputtering targets using diamond powder filler or thermally conductive ceramic fillers
7644745, Jun 06 2005 Applied Materials, Inc Bonding of target tiles to backing plate with patterned bonding agent
9127362, Oct 31 2005 Applied Materials, Inc Process kit and target for substrate processing chamber
20010001367,
20010007302,
20010030172,
20010033706,
20010035237,
20010035238,
20010045353,
20020014289,
20020029745,
20020033330,
20020075631,
20020076490,
20020079217,
20020081804,
20020083571,
20020086118,
20020090464,
20020100680,
20020112955,
20020121436,
20020153130,
20030026917,
20030035906,
20030047464,
20030102207,
20030116276,
20030118731,
20030124748,
20030127319,
20030136520,
20030168168,
20030173526,
20030175142,
20030185965,
20030218054,
20040016635,
20040020769,
20040035698,
20040055880,
20040056070,
20040056211,
20040079634,
20040089542,
20040099285,
20040113364,
20040115945,
20040144638,
20040165422,
20040222088,
20040256226,
20040261946,
20050002227,
20050011749,
20050029094,
20050029502,
20050061857,
20050067469,
20050072668,
20050089699,
20050092604,
20050115045,
20050147150,
20050147742,
20050161322,
20050178653,
20050211548,
20050282358,
20060005767,
20060021870,
20060070876,
20060081459,
20060099126,
20060105182,
20060108217,
20060188742,
20060266639,
20060283703,
20060289305,
20070056845,
20070102286,
20070125646,
20070170052,
20070173059,
20070215463,
20070246346,
20080006523,
20080178801,
20080257263,
20080308416,
20090090620,
20090107834,
20090114528,
20090178919,
20090272641,
CN1307143,
DE19719133,
EP239349,
EP439000,
EP601788,
EP635869,
EP791956,
EP818803,
EP838838,
EP1094496,
EP1350861,
GB2049737,
GB2155495,
JP11106904,
JP11137440,
JP1283367,
JP2000265265,
JP2002060935,
JP200269695,
JP200269696,
JP2004132725,
JP2027748,
JP4367247,
JP54162969,
JP58147558,
JP6232243,
JP63290270,
JP7197272,
JP7224377,
JP9017850,
JP9111452,
WO26430,
WO139250,
WO3062491,
WO7037796,
WO2002093624,
WO2004001094,
WO2004010494,
WO200402979,
WO2004033748,
WO2005071137,
WO2006078709,
WO2008079722,
WO2008156794,
WO9917336,
//////
Executed onAssignorAssigneeConveyanceFrameReelDoc
Jan 17 2007FLANIGAN, MICHAEL ALLENApplied Materials, IncASSIGNMENT OF ASSIGNORS INTEREST SEE DOCUMENT FOR DETAILS 0491740607 pdf
Jan 17 2007YOSHIDOME, GOICHIApplied Materials, IncASSIGNMENT OF ASSIGNORS INTEREST SEE DOCUMENT FOR DETAILS 0491740607 pdf
Jan 17 2007ALLEN, ADOLPH MILLERApplied Materials, IncASSIGNMENT OF ASSIGNORS INTEREST SEE DOCUMENT FOR DETAILS 0491740607 pdf
Jan 18 2007SCHEIBLE, KATHLEENApplied Materials, IncASSIGNMENT OF ASSIGNORS INTEREST SEE DOCUMENT FOR DETAILS 0491740607 pdf
Jan 18 2007PAVLOFF, CRISTOPHERApplied Materials, IncASSIGNMENT OF ASSIGNORS INTEREST SEE DOCUMENT FOR DETAILS 0491740607 pdf
May 10 2019Applied Materials, Inc.(assignment on the face of the patent)
Date Maintenance Fee Events
May 10 2019BIG: Entity status set to Undiscounted (note the period is included in the code).


Date Maintenance Schedule
May 23 20264 years fee payment window open
Nov 23 20266 months grace period start (w surcharge)
May 23 2027patent expiry (for year 4)
May 23 20292 years to revive unintentionally abandoned end. (for year 4)
May 23 20308 years fee payment window open
Nov 23 20306 months grace period start (w surcharge)
May 23 2031patent expiry (for year 8)
May 23 20332 years to revive unintentionally abandoned end. (for year 8)
May 23 203412 years fee payment window open
Nov 23 20346 months grace period start (w surcharge)
May 23 2035patent expiry (for year 12)
May 23 20372 years to revive unintentionally abandoned end. (for year 12)