A method and composite produced by depositing particulate material on a planular surface, contacting the surface and the particulate material with a gas-curable resin and curing the resin to adhere the particulate matter to the surface.

Patent
   4791022
Priority
Nov 07 1983
Filed
Dec 21 1984
Issued
Dec 13 1988
Expiry
Dec 13 2005
Assg.orig
Entity
Large
21
26
EXPIRED
12. A method of producing a decorative surface having a high profile facing which comprises depositing a particulate material on a planular surface of a fiberglass wall board or ceiling board, positioning an acid gas-curable resin in contact with the surface and the particulate material and contacting the resin with an acid gaseous curing agent to cure the resin and adhere said particulate material to said surface.
20. A method of producing a decorative surface having a high profile facing which comprises depositing a particulate material on a planular surface of a fiberglass wall board or ceiling board, positioning an acid gas-curable resin and a hardener in contact with the surface and the particulate material and contacting the resin with an acid gaseous curing agent to cure the resin and adhere said particulate material to said surface.
1. A method of producing a decorative surface having a high profile facing which comprises depositing a particulate material on a planular surface of a fiberglass wall or ceiling board, positioning a gas-curable resin consisting of furfuryl alcohol or an oligomeric acrylate in contact with the surface and the particulate material and contacting the resin with a gaseous curing agent to cure the resin and adhere said particulate material to said surface.
2. The method of claim 1 in which said planular surface comprises fiber glass board, said particulate material is mineral, and said curing agent is gaseous sulfur dioxide.
3. The method of claim 1 in which said planular surface is self-supporting and has a substantially smooth surface.
4. The method of claim 1 in which said particulate material is selected from the group consisting of sand, gravel, marble, glass, mica and wood chips.
5. The method of claim 1 in which said particulate material is positioned on said substrate and rearranged after said positioning.
6. The method of claim 1 in which said particulate material is pre-coated prior to said depositing.
7. The method of claim 1 in which said particulate material is coated after said depositing.
8. The method of claim 1 in which said curable resin is contacted with said gaseous curing agent as said surface, having the particulate material and resin thereon, is moved through a chamber.
9. The composite produced by the method of claim 1.
10. The method of claim 1 in which said particulate material is mineral.
11. The method of claim 1 in which said curing agent is gaseous sulfur dioxide.
13. The method of claim 12 in which said acid gaseous curing agent is selected from the group consisting of sulfur dioxide, hydrogen chloride and sulfur trioxide.
14. The method of claim 12 in which said acid gas-curable resin is selected from the group consisting of a urea formaldehyde, a phenol-formaldehyde and a furan copolymer and said acid gaseous curing agent is selected from the group consisting of sulfur dioxide, hydrogen chloride and sulfur trioxide.
15. The method of claim 12 wherein said particulate material is selected from the group consisting of sand, gravel, marble, glass, mica and wood chips.
16. The method of claim 12 in which said particulate material is positioned on said substrate and rearranged after said positioning.
17. The method of claim 12 in which said particulate material is pre-coated prior to said depositing.
18. The method of claim 12 in which said particulate material is coated after said depositing.
19. The method of claim 12 in which said curable resin is contacted with said gaseous curing agent as said surface, having the particulate material and resin thereon, is moved through a member.
21. The method of claim 20 in which said acid gaseous curing agent is selected from the group consisting of sulfur dioxide, hydrogen chloride and sulfur trioxide.
22. The method of claim 20 in which said acid gas-curable resin consists of a furan resin, said hardener consists of a ring-substituted aralkyl or alkyl hydroperoxide and said acid gaseous curing agent is selected from the group consisting of sulfur dioxide, hydrogen chloride and sulfur trioxide.
23. The method of claim 20 in which said acid gas-curable resin is selected from the group consisting of a urea formaldehyde, a phenol-formaldehyde and a furan copolymer; said hardener consists of a hydroperoxide and said acid gaseous curing agent is selected from the group consisting of sulfur dioxide, hydrogen chloride and sulfur trioxide.
24. The method of claim 20 in which said particulate material is selected from the group consisting of sand, gravel, marble, glass, mica and wood chips.
25. The method of claim 20 in which said particulate material is positioned on said substrate and rearranged after said positioning.
26. The method of claim 20 in which said particulate material is pre-coated prior to said depositing.
27. The method of claim 20 in which said particulate material is coated after said depositing.
28. The method of claim 20 in which said curable resin is contacted with said gaseous curing agent as said surface, having the particulate material and resin thereon, is moved through a chamber.
29. The composite produced by the method of claim 20.

This application is a continuation of application Ser. No. 549,049, filed 11/7/83, now abandoned.

This invention relates to the production of decorative panels such as ceiling board, wall board, and the like.

In one of its more specific aspects, this invention relates to a method and the production of random, high profile board.

The production of decorative panels is well known. Generally, there is formed a substrate of fiberboard, glass fibers, glass wool or the like over which there is placed one, or more, finishing coats. Usually such substrates are of sufficient composition, stiffness and strength that they are self-supporting over their width. Any of a number of individual materials, or combination of materials, can be deposited on the surface, adhered there by adhesive and have a finish applied thereover.

The limitations involved with such methods are that they subsequently require costly and time-consuming procedures for drying the finished product. The method of this invention is directed to the solution of that problem.

According to this invention, there is provided a method of producing a board having a decorative surface comprising a high profile facing which comprises depositing a particulate material on a planular surface, coating the particulate material and the planular surface with a gaseous curable resin and contacting the coated surface with a gaseous curing agent to cure the curable resin and adhere the particulate material to the planular surface.

In a preferred embodiment of the invention, the planular surface is fiber glass board, the particulate material is mineral, the curable resin is furfuryl alcohol or an oligomeric acrylate and the curing agent is gaseous sulfur dioxide.

The method of this invention is applicable to the production of any decorative surfaces including those used for wall board, ceiling board and decorative panels. The unprocessed boards can be of any desired thickness, whether or not self-supporting and, preferably, will have one substantially smooth surface on which the particulate material is deposited.

The particulate material can be of any suitable size, shape and density such that the cured resin can hold the particulate material to the surface of the board in whatever position the board is placed. The particulate material can include sand, gravel, marble, glass, mica and the like, of mineral or non-mineral character, such as wood chips, and the like, and mixtures thereof. In general, the particles can be within the size of from about 40 mesh to about 1/4" in diameter, or a mixture thereof.

The particles can be distributed on the substrate board in any suitable manner, in random or orderly arrangement, over any portion of the substrate. The particles can be retained in their initial position as deposited or can be arranged thereafter by vibrating the substrate or by a brushing action which distributes the particles into any desired pattern.

The particles can be coated at any time. They can be pre-coated and deposited on the planular surface thereafter or, they can be coated after deposition thereon, or both.

The particles can be coated in any manner, including dipping, spraying, and the like. Similarly, they can be coated to any extent, that is, to provide partial or complete coverage of the particle. In any instance, they will be coated to an extent sufficient to provide adherence between the particles and the substrate. Or, should it be desired that a second deposition of particles be superimposed over, or between, the particles of the first deposition, sufficient resin can be applied in one, or more, applications to provide therefore.

Any gaseous curable resin can be employed. Such resins can be comprised of systems such as an acid curing resin system, with or without a pigment, such as furfuryl alcohol or an oligometric acrylate and sulfur dioxide curing gas; and a resin component and hardener such as a furan resin and a ring-substituted aralkyl or alkyl hydroperoxide, or urea formaldehydes, phenol-formaldehydes or furan copolymers, in conjunction with a hydroperoxide and their corresponding curing gases including, sulfur dioxide, hydrogen chloride, and sulfur trioxide.

The curing gas can be introduced into contact with the gaseous curable resin in any suitable manner. Preferably, the gaseous contact will be made within a substantially leak-proof chamber as the substrate, with the particulate matter and curable resin positioned thereon, is passed through in continuous fashion.

The resin is maintained in contact with the gaseous curing agent for a time sufficient to cure the resin. This period of time is usually from about 5 seconds to about 30 seconds, after which the substrate, with the particulate matter adhering thereto, can be subjected to further processing such as, for example, trimming, sub-dividing, waterproofing, painting, and the like.

It will be evident from the foregoing that various modifications can be made to this invention. Such, however, are considered as being within the scope of the invention.

Graham, W. David

Patent Priority Assignee Title
5154959, Jun 16 1989 SOCIETA ITALIANA VETRO - SIV - S P A Process for the manufacture of a decorative product formed of glass beads and/or chips bound together between a pair of transparent sheets
5204055, Dec 08 1989 MASSACHUSETTS INSTITUTE OF TECHNOLOGY, A CORP OF MA Three-dimensional printing techniques
5213854, Mar 30 1989 Articles with stone-like surfaces, and method of manufacture therefor
5340656, Dec 08 1989 Massachusetts Institute of Technology Three-dimensional printing techniques
5380552, Aug 24 1992 Minnesota Mining and Manufacturing Company; MINNESOTA MINING AND MANUFACTURING COMPANY, A CORP OF DE Method of improving adhesion between roofing granules and asphalt-based roofing materials
5387380, Dec 08 1989 Massachusetts Institute of Technology Three-dimensional printing techniques
5490882, Nov 30 1992 Massachusetts Institute of Technology Process for removing loose powder particles from interior passages of a body
5516573, Aug 24 1992 Minnesota Mining and Manufacturing Company Roofing materials having a thermoplastic adhesive intergace between coating asphalt and roffing granules
5660621, Dec 29 1995 Massachusetts Institute of Technology Binder composition for use in three dimensional printing
5775402, Oct 31 1995 Massachusetts Institute of Technology Enhancement of thermal properties of tooling made by solid free form fabrication techniques
5807437, Dec 08 1989 Massachusetts Institute of Technology Three dimensional printing system
5814161, Nov 30 1992 Massachusetts Institute of Technology Ceramic mold finishing techniques for removing powder
5851465, Dec 29 1995 Massachusetts Institute of Technology Binder composition for use in three dimensional printing
6036777, Dec 08 1989 Massachusetts Institute of Technology Powder dispensing apparatus using vibration
6109332, Nov 30 1992 Massachusetts Institute of Technology Ceramic mold finishing
6112804, Oct 31 1995 Massachusetts Institute of Technology Tooling made by solid free form fabrication techniques having enhanced thermal properties
6146567, Feb 18 1993 Massachusetts Institute of Technology Three dimensional printing methods
6354361, Oct 31 1995 Massachusetts Institute of Technology Tooling having advantageously located heat transfer channels
7294363, Dec 19 2002 Owens Corning Intellectual Capital, LLC Methods of forming decorative veils
9909313, Jan 19 2017 Composite materials, methods of making composite materials, and enclosures constructed from composite materials
D392327, Feb 25 1997 Decoration
Patent Priority Assignee Title
3008205,
3145438,
3312650,
3549404,
3577257,
3639654,
3734936,
3822226,
3836491,
3879339,
3886021,
3899612,
3917558,
4017461, Jan 02 1976 QO CHEMICALS INC CHICAGO ILLINOIS Method for manufacturing liquid resinous furan-formaldehyde condensation products
4033925, Jul 12 1976 QO CHEMICALS INC CHICAGO ILLINOIS Monomeric furfuryl alcohol-resorcinol foundry binders
4083817, Jun 15 1977 QO CHEMICALS INC CHICAGO ILLINOIS Blends of furan-aldehyde resins with phenolic resins and molded articles produced therefrom
4108826, Jun 20 1977 QO CHEMICALS INC CHICAGO ILLINOIS Furfuryl alcohol-hexaalkoxymethylmelamine foundry binders
4175067, Aug 17 1977 QO CHEMICALS INC CHICAGO ILLINOIS Curable binder for large foundry sand shapes
4215206, Mar 16 1978 ASHLAND INC A KENTUCKY CORPORATION Furan binder composition
4311627, Oct 29 1980 ADIRONDACK FOUNDARIES, INC Process for curing foundry cores and molds
4320043, Jan 12 1981 PENN SPECIALTY CHEMICALS, INC Furfuryl alcohol-dialdehyde foundry binders
4366193, Apr 10 1981 SHERWIN-WILLIAMS COMPANY Catechol-based vapor permeation curable coating compositions
4371648, May 12 1980 ASHLAND INC A KENTUCKY CORPORATION Composition containing furfuryl alcohol and use thereof in foundry binders
4405657, Feb 24 1981 Armstrong World Industries, Inc. Non-skid plastic flooring product and method of manufacture
4516996, Apr 07 1983 Owens-Corning Fiberglas Technology Inc Formation of molded glass fiber parts from glass fiber blankets and product
GB2066714,
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Executed onAssignorAssigneeConveyanceFrameReelDoc
Dec 21 1984Owens-Corning Fiberglas Corporation(assignment on the face of the patent)
Nov 03 1986Owens-Corning Fiberglas CorporationWilmington Trust CompanySECURITY INTEREST SEE DOCUMENT FOR DETAILS 0046520351 pdf
Nov 03 1986Owens-Corning Fiberglas CorporationWADE, WILLIAM, J SECURITY INTEREST SEE DOCUMENT FOR DETAILS 0046520351 pdf
Jul 30 1987WILMINGTON TRUST COMPANY, A DE BANKING CORPORATIONOWENS-CORNING FIBERGLAS CORPORATION, A CORP OF DE TERMINATION OF SECURITY AGREEMENT RECORDED NOV 13, 1986 REEL 4652 FRAMES 351-4200049030501 pdf
Jul 30 1987WADE, WILLIAM J TRUSTEES OWENS-CORNING FIBERGLAS CORPORATION, A CORP OF DE TERMINATION OF SECURITY AGREEMENT RECORDED NOV 13, 1986 REEL 4652 FRAMES 351-4200049030501 pdf
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