A packaging system and method utilizes a modified atmosphere package including a first package and a second package. The first package includes a non-barrier portion substantially permeable to oxygen, while the second package is substantially impermeable to oxygen. After a food product such as raw meat is placed within the first package, the first package is sealed and then inserted into the second package without sealing the second package so as to create a pocket between the first and second packages. The system and method first employ an oxygen reduction technique such as evacuation, gas flushing, and/or scavenging to quickly reduce the oxygen level in the pocket to a first non-zero level, and then employ an activated oxygen scavenger to further reduce the oxygen level to zero percent after the package is sealed. The oxygen scavenger is activated with an oxygen uptake accelerator to increase the rate at which the oxygen is absorbed. The oxygen scavenger is positioned external to the first package to aggressively absorb any residual oxygen within the pocket and the first package and absorb any oxygen that might seep into the modified atmosphere package.

Patent
   6103281
Priority
Oct 08 1998
Filed
Oct 08 1998
Issued
Aug 15 2000
Expiry
Oct 08 2018
Assg.orig
Entity
unknown
0
191
EXPIRED
14. A system for removing oxygen from a modified atmosphere package including a first package and a second package, said first package containing a retail cut of raw meat and including a non-barrier portion substantially permeable to oxygen, said second package covering said first package and being substantially impermeable to oxygen, said second package creating a pocket between said first and second packages, said system comprising:
means for removing oxygen from said pocket prior to sealing said second package so as to reduce an oxygen level therein to a non-zero level; and
an oxygen scavenger, positioned external to said first package and activated with an oxygen scavenger accelerator, for aggressively absorbing any residual oxygen in said modified package after sealing said second package so as to reduce the oxygen level from said non-zero level to approximately zero percent.
10. A method for removing oxygen from a modified atmosphere package including a first package and a second package, said first package containing a retail cut of raw meat and including a non-barrier portion substantially permeable to oxygen, said second package covering said first package and being substantially impermeable to oxygen, said second package creating a pocket between said first and second packages, said method comprising:
supplying an oxygen scavenger;
activating said oxygen scavenger with an oxygen scavenger accelerator;
positioning said oxygen scavenger external to said first package such that said oxygen scavenger is capable of absorbing oxygen within said pocket;
removing oxygen from said pocket so as to reduce an oxygen level therein to a non-zero level; and
sealing said second package, said activated oxygen scavenger aggressively absorbing any residual oxygen in said modified atmosphere package so as to reduce the oxygen level from said non-zero level to approximately zero percent.
1. A method of manufacturing a modified atmosphere package, comprising:
supplying a first package including a non-barrier portion substantially permeable to oxygen;
placing a retail cut of raw meat within said first package;
sealing said first package;
supplying a second package substantially impermeable to oxygen;
covering said first package with said second package without sealing said second package so as to create a pocket between said first and second packages;
supplying an oxygen scavenger;
activating said oxygen scavenger with an oxygen scavenger accelerator;
positioning said oxygen scavenger external to said first package such that said oxygen scavenger is capable of absorbing oxygen within said pocket;
removing oxygen from said pocket so as to reduce an oxygen level therein to a non-zero level; and
sealing said second package, said activated oxygen scavenger aggressively absorbing any residual oxygen in said modified atmosphere package so as to reduce the oxygen level from said non-zero level to approximately zero percent.
2. The method of claim 1, wherein said non-zero oxygen level within said pocket is no less than about 0.1 percent oxygen.
3. The method of claim 1, wherein said step of removing oxygen from said pocket includes evacuating said pocket.
4. The method of claim 3, wherein said step of evacuating said pocket is performed using a vacuum device having a probe and a pair of clamping members, said step of evacuating said pocket including inserting said probe into an unsealed end of said second package, closing said clamping members to clamp said unsealed end of said second package with said probe disposed between said clamping members, and drawing oxygen out of said pocket via said probe.
5. The method of claim 3, wherein said step of removing oxygen from said pocket includes flushing said pocket with one or more gases.
6. The method of claim 5, wherein said steps of evacuating said pocket and flushing said pocket are performed using a vacuum/flushing device having a probe and a pair of clamping members, said steps of evacuating said pocket and flushing said pocket including inserting said probe into an unsealed end of said second package, closing said clamping members to clamp said unsealed end of said second package with said probe disposed between said clamping members, drawing oxygen out of said pocket via said probe, and introducing one or more gases into said pocket via said probe.
7. The method of claim 4, wherein said step of sealing said second package is performed using said vacuum device, said vacuum device including a heated seal bar housed within one of said clamping members, said step of sealing said second package including actuating said seal bar to press against the other of said clamping members with said unsealed end of said second package disposed therebetween and then retracting said seal bar away from said other of said clamping members.
8. The method of claim 6, wherein said step of sealing said second package is performed using said vacuum/flushing device, said vacuum/flushing device including a heated seal bar housed within one of said clamping members, said step of sealing said second package including actuating said seal bar to press against the other of said clamping members with said unsealed end of said second package disposed therebetween and then retracting said seal bar away from said other of said clamping members.
9. The method of claim 1, wherein said activated oxygen scavenger reduces the oxygen level within said modified atmosphere package from said non-zero level to approximately zero percent in less than about 24 hours.
11. The method of claim 10, wherein said non-zero oxygen level within said pocket is no less than about 0.1 percent oxygen.
12. The method of claim 10, wherein said step of removing oxygen from said pocket includes evacuating said pocket.
13. The method of claim 12, wherein said step of removing oxygen from said pocket includes flushing said pocket with one or more gases.
15. The system of claim 14, wherein said non-zero oxygen level within said pocket is no less than about 0.1 percent oxygen.
16. The system of claim 14, wherein said means for removing oxygen from said pocket includes means for evacuating said pocket.
17. The system of claim 16, wherein said means for evacuating said pocket includes a probe and a pair of clamping members, and wherein to operate said evacuating means, said probe is inserted into an unsealed end of said second package, said clamping members are closed to clamp said unsealed end of said second package with said probe disposed between said clamping members, and said evacuating means is activated to draw oxygen out of said pocket via said probe.
18. The system of claim 16, wherein said means for removing oxygen from said pocket includes means for flushing said pocket with one or more gases.
19. The system of claim 18, wherein said evacuating means and said flushing means include a vacuum/flushing device having a probe and a pair of clamping members, and wherein to operate said vacuum/flushing device, said probe is inserted into an unsealed end of said second package, said clamping members are closed to clamp said unsealed end of said second package with said probe disposed between said clamping members, said vacuum/flushing device is activated to draw oxygen out of said pocket via said probe, and said vacuum/flushing device is activated to introduce one or more gases into said pocket via said probe.
20. The system of claim 17, further including means for sealing said second package, said evacuating means including said sealing means, said sealing means including a heated seal bar housed within one of said clamping members, and wherein to operate said sealing means, said seal bar is first actuated to press against the other of said clamping members with said unsealed end of said second package disposed therebetween and is then retracted away from said other of said clamping members.
21. The system of claim 19, further including means for sealing said second package, said vacuum/flushing device including said sealing means, said sealing means including a heated seal bar housed within one of said clamping members, and wherein to operate said sealing means, said seal bar is first actuated to press against the other of said clamping members with said unsealed end of said second package disposed therebetween and is then retracted away from said other of said clamping members.
22. The system of claim 14, wherein said activated oxygen scavenger reduces the oxygen level within said modified atmosphere package from said non-zero level to approximately zero percent in less than about 24 hours.

The present invention relates generally to systems and methods of making modified atmosphere packages for extending the shelf life of raw meats or other food. More particularly, the invention relates to such a system and method that is significantly faster than prior art techniques.

Containers have long been employed to store and transfer perishable food prior to presenting the food at a market where it will be purchased by the consumer. After perishable foods, such as meats, fruits, and vegetables, are harvested, they are placed into containers to preserve those foods for as long as possible. Maximizing the time in which the food remains preserved in the containers increases the profitability of all entities in the chain of distribution by minimizing the amount of spoilage.

The environment around which the food is preserved is a critical factor in the preservation process. Not only is maintaining an adequate temperature important, but the molecular and chemical content of the gases surrounding the food is significant as well. By providing an appropriate gas content to the environment surrounding the food, the food can be better preserved when maintained at the proper temperature or even when it is exposed to variations in temperature. This gives the food producer some assurance that after the food leaves his or her control, the food will be in an acceptable condition when it reaches the consumer.

Modified atmosphere packaging systems for one type of food, raw meats, exposes these raw meats to either extremely high levels or extremely low levels of oxygen (O2). Packaging systems which provide extremely low levels of oxygen are generally preferable because it is well known that the fresh quality of meat can be preserved longer under anaerobic conditions than under aerobic conditions. Maintaining low levels of oxygen minimizes the growth and multiplication of aerobic bacteria. Heretofore, low-level oxygen systems, such as the systems proposed in U.S. Pat. No. 3,574,642 to Weinke and U.S. Pat. No. 5,115,624 to Garwood, have obtained extremely low levels of oxygen by relying solely upon oxygen evacuation techniques to initially reduce the oxygen level around the raw meat to approximately zero percent.

In typical prior art systems, a package composed of flexible or rigid gas barrier materials is loaded into an evacuation chamber. The package in the evacuation chamber is subjected to a vacuum which reduces the oxygen level to approximately zero percent. After the package is evacuated, the raw meat either can be maintained in a "zero" atmosphere environment (commonly referred to as vacuum packaging) or can be refilled with a gas or mixture of gases to provide a modified atmosphere environment. To provide a modified atmosphere environment, the air-evacuated package is typically filled with a mixture of gases consisting of about 30 percent carbon dioxide (CO2) and 70 percent nitrogen (N2). Refilling the air-evacuated package with such a mixture of gases is believed to suppress the growth of aerobic bacteria. At this point the package is sealed. The meat in the modified atmosphere package takes on a less desirable purple-red color which few consumers would associate with freshness. This purple-red color, however, quickly "blooms" to a bright red color generally associated with freshness when the package is opened to oxygenate the fresh meat by exposure to air. The package is typically opened immediately prior to display of the fresh meat to consumers so as to induce blooming of the fresh meat just prior to display to the consumers.

Low-level oxygen systems relying solely upon evacuation techniques to diminish the oxygen level to approximately zero percent suffer from several disadvantages. For example, such systems operate at exceptionally slow speeds because they rely solely upon the use of an evacuation device along the packaging line to reduce the oxygen level to zero percent. The evacuation process is time-consuming, and the manufacture of the package cannot be completed until after the package has been fully evacuated. Furthermore, the evacuation techniques render it difficult to remove any oxygen within a previously wrapped package, such as an overwrapped meat tray, without creating vents in the package to allow the oxygen to escape. Trapped oxygen raises the residual oxygen level in the package and can also cause billowing and subsequent damage to the package during evacuation.

A need therefore exists for a system and method of making a modified atmosphere package which overcomes the aforementioned shortcomings associated with existing techniques of making those packages.

Accordingly, the present invention is directed to a system and method of making a modified atmosphere package which is significantly faster than prior art techniques. The packaging system effectively extends the allowable time period between cutting and purchase of retail cuts of raw meat. The raw meat can be cut and packaged several weeks prior to being purchased at the store and yet remains fresh during this time period.

To achieve the foregoing objectives, the packaging system and method utilizes a modified atmosphere package including a first package and a second package. The first package includes a non-barrier portion substantially permeable to oxygen, while the second package is substantially impermeable to oxygen. After a food product such as raw meat is placed within the first package, the first package is sealed and then inserted into the second package without sealing the second package so as to create a pocket between the first and second packages. Next, the oxygen level in the pocket is reduced to a first level greater than zero percent using one or more techniques, including but not limited to evacuation, gas flushing, and oxygen scavenging. The pocket is preferably flushed with one or more gases to create a modified atmosphere therein suitable for suppressing the growth of aerobic bacteria.

To reduce the oxygen level in the pocket from the first level to approximately zero percent, an oxygen scavenger is positioned to absorb any residual oxygen within the package. The oxygen scavenger is activated with an oxygen uptake accelerator to increase the rate at which the oxygen is absorbed. The activated oxygen scavenger aggressively absorbs any residual oxygen within the package after it is sealed.

The above system and method of making a modified atmosphere package is advantageous because it does not rely solely upon time-consuming evacuation techniques to reduce the oxygen level to zero percent. Rather, an oxygen reduction technique such as evacuation, gas flushing, and/or scavenging is only used to quickly reduce the oxygen level to the first non-zero level, while an activated oxygen scavenger is used to further reduce the oxygen level to zero percent. By activating the oxygen scavenger, the scavenger has the aggressiveness required to rapidly move the oxygen level in the package through the pigment sensitive oxygen range of about 0.05 percent to two percent oxygen. In this pigment sensitive range, metmyoglobin can form very quickly. Metmyoglobin is a substance that causes meat to change to an undesirable brown color. Metmyoglobin forms very slowly at oxygen levels above about two percent and below about 0.05 percent but very quickly between these oxygen levels. Accordingly, it is important to pass the meat in the package through the pigment sensitive range very quickly. Activation of the oxygen scavenger insures that such rapid passage through the pigment sensitive range is achieved, thereby preventing discoloration of the meat.

It has been found that the use of evacuation for only part, but not all, of the oxygen reduction process significantly increases the throughput of the manufacturing process relative to prior art systems. The manufacturing process of the present invention is completed after the package is sealed. The oxygen scavenger essentially operates outside the manufacturing process because it continues to absorb oxygen after the package is sealed. As the oxygen scavenger absorbs oxygen in one package, additional packages can be manufactured.

In contrast, in prior art systems that rely solely upon time-consuming evacuation techniques to reduce the oxygen level in the package to about zero percent, the manufacture of the package cannot be completed until after the package is fully evacuated. Additional packages cannot be manufactured on the same manufacturing line until after the package is fully evacuated. Thus, evacuation controls the timing of the manufacturing process. Since evacuation is time-consuming, prior art systems experience a relatively low throughput relative to the system and method of the present invention.

The above summary of the present invention is not intended to represent each embodiment, or every aspect of the present invention. This is the purpose of the figures and detailed description which follow.

Other objects and advantages of the invention will become apparent upon reading the following detailed description and upon reference to the drawings in which:

FIG. 1 is an isometric view of a modified atmosphere package embodying the present invention;

FIG. 2 is a section view taken generally along line 2--2 in FIG. 1;

FIG. 3 is an enlarged view taken generally along circled portion 3 in FIG. 2;

FIG. 4 is a diagrammatic side view of a system for making the modified atmosphere package in FIG. 1;

FIG. 5 is an isometric view of an apparatus for evacuating and/or flushing the modified atmosphere package in FIG. 1;

FIGS. 6a-d are cross-sectional views of the apparatus in FIG. 5 showing a method of operation thereof; and

FIG. 7 is an isometric view of a modified atmosphere package akin to that shown in FIG. 1 except that the modified atmosphere package includes a plurality of meat-filled inner packages.

While the invention is susceptible to various modifications and alternative forms, certain specific embodiments thereof have been shown by way of example in the drawings and will be described in detail. It should be understood, however, that the intention is not to limit the invention to the particular forms described. On the contrary, the intention is to cover all modifications, equivalents, and alternatives falling within the spirit and scope of the invention as defined by the appended claims.

Turning now to the drawings, FIGS. 1-3 depict a modified atmosphere package 10 including a master outer package 12 and an inner package 14. The term "package" as used herein shall be defined as any means for holding raw meat, including a container, carton, casing, parcel, holder, tray, flat, bag, film envelope, etc. At least a portion of the inner package 14 is permeable to oxygen. The inner package 14 includes a conventional semi-rigid plastic tray 16 thermoformed from a sheet of polymeric material which is substantially permeable to oxygen. Exemplary polymers which may be used to form the non-barrier tray 16 include polystyrene foam, cellulose pulp, polyethylene, polypropylene, etc. In a preferred embodiment, the polymeric sheet used to form the tray 16 is substantially composed of polystyrene foam and has a thickness ranging from about 100 mils to about 300 mils. The use of a common polystyrene foam tray 16 is desirable because it has a high consumer acceptance. The inner package 14 further includes a stretch film wrapping or cover 18 substantially composed of a polymeric material, such as polyvinyl chloride (PVC), which is substantially permeable to oxygen. In a preferred embodiment, the stretch film used to form the cover 18 contains additives which allow the film to cling to itself, has a thickness ranging from about 0.5 mil to about 1.5 mils, and has a rate of oxygen permeability greater than about 1000 cubic centimeters per 100 square inches in 24 hours. Preferably, the film has a rate of oxygen permeability greater than about 7000 cubic centimeters per 100 square inches in 24 hours and, most preferably, the film has a rate of oxygen permeability greater than about 10,000 cubic centimeters per 100 square inches in 24 hours. To help attain this high rate of permeability, small holes may be punched into the film. Other techniques for increasing the oxygen permeability of the inner package 14 may be used. Such techniques are disclosed in U.S. application Ser. No. 09/054,907 entitled "Modified Atmosphere Package With Accelerated Reduction of Oxygen Level in Meat Compartment," filed Apr. 3, 1998, and incorporated herein by reference in its entirety. One preferred stretch film is Resinite™ meat film commercially available from Borden Packaging and Industrial Products of North Andover, Mass.

The tray 16 is generally rectangular in configuration and includes a bottom wall 20, a continuous side wall 22, and a continuous rim or flange 24. The continuous side wall 22 encompasses the bottom wall 20 and extends upwardly and outwardly from the bottom wall 20. The continuous rim 24 encompasses an upper edge of the continuous side wall 22 and projects laterally outwardly therefrom. A food item such as a retail cut of raw meat 26 is located in a rectangular compartment defined by the bottom wall 20 and continuous side wall 22. The raw meat may be any animal protein, including beef, pork, veal, lamb, chicken, turkey, venison, fish, etc. The tray 16 is manually or automatically wrapped with the cover 18. The cover 18 is wrapped over the retail cut of raw meat 26 and about both the side wall 22 and bottom wall 20 of the tray 16. The free ends of the cover 18 are overlapped along the underside of the bottom wall 20 of the tray 16, and, due to the cling characteristic inherent in the cover 18, these overlapping free ends cling to one another to hold the cover 18 in place. If desired, the overwrapped tray 16, i.e., the inner package 14, may be run over a hot plate to thermally fuse the free ends of the cover 18 to one another and thereby prevent these free ends from potentially unraveling.

The master outer package 12 is preferably a flexible polymeric bag composed of a single or multilayer plastics material which is substantially impermeable to oxygen. The master bag 12 may, for example, include a multilayer coextruded film containing ethylene vinyl chloride (EVOH), or include an oriented polypropylene (OPP) core coated with an oxygen barrier coating such as polyvinylidene chloride and further laminated with a layer of sealant material such as polyethylene to facilitate heat sealing. In a preferred embodiment, the polymeric bag 12 is composed of a coextruded barrier film commercially available as product no. 325C44-EX861B from PrintPack, Inc. of Atlanta, Ga. The coextruded barrier film has a thickness ranging from about 2 mils to about 6 mils, and has a rate of oxygen permeability less than about 0.1 cubic centimeters per 100 square inches in 24 hours.

Prior to sealing the master bag 12, the inner package 14 is placed within the polymeric bag 12 wthout sealing the bag 12 so as to create a pocket 13 between the inner and outer packages 14 and 12. An oxygen scavenger/absorber 28 is then placed in the bag 12 external to the sealed inner package 14. The oxygen scavenger 28 is activated with an oxygen uptake accelerator to increase the rate at which the oxygen is absorbed. The oxygen uptake accelerator is preferably selected from the group consisting of water or aqueous solutions of acetic acid, citric acid, sodium chloride, calcium chloride, magnesium chloride and copper. The non-barrier portion of the inner package 14 allows any oxygen within the inner package 14 to flow into the pocket 13 for absorption by the oxygen scavenger 28.

Further information concerning the oxygen scavenger 28, the oxygen uptake accelerator, and the means for introducing the oxygen uptake accelerator to the oxygen scavenger 28 may be obtained from application Ser. No. 08/856,448 filed May 14, 1997, entitled "Oxygen Scavenger Accelerator," and incorporated herein by reference in its entirety. In the drawings, the oxygen scavenger 28 is illustrated as a packet or label which is inserted into the bag 12 prior to sealing the bag 12. Alternatively, an oxygen scavenging material may be added to the polymer or polymers used to form the outer package 12 so that the oxygen scavenging material is integrated into the outer package 12 itself.

Next, the oxygen level in the pocket 13 is reduced to a first level greater than zero percent. This reduction in the oxygen level may be accomplished using one or more techniques, including but not limited to evacuation, gas flushing, and oxygen scavenging. In a preferred embodiment, the bag 12 is subjected to evacuation and gas flushing cycles to initially reduce the oxygen level in the pocket 13, prior to any equilibration, to no less than about 0.1 percent. Taking into account any oxygen disposed within the the inner package 14, i.e., oxygen disposed within the meat 26 itself, the wall of the tray 16, and the free space beneath the stretch film 18, the oxygen level in the pocket 13 of no less than about 0.1 percent corresponds to an "equilibrium" oxygen level in the entire package 10 of no less than about one to two percent. During the gas flushing process, an appropriate mixture of gases is preferably introduced into the pocket 13 to create a modified atmosphere therein suitable for suppressing the growth of aerobic bacteria. In a preferred embodiment, this mixture of gases consists of about 30 percent carbon dioxide and about 70 percent nitrogen. The master bag 12 is then sealed.

After the master bag 12 is sealed, the activated oxygen scavenger 28 reduces the oxygen level throughout the package 10, including the pocket 13 and the inner package 14, to approximately zero percent in a time period of less than about 24 hours. The oxygen scavenger accelerator insures that the oxygen scavenger 28 has the aggressiveness required to rapidly move the oxygen level in the package 10 and around the meat through the pigment sensitive oxygen range of about 0.05 to two percent. The oxygen scavenger 28 absorbs any residual oxygen in the pocket 13 and the inner package 14 and any oxygen that might seep into the package 10 from the ambient environment.

The retail cut of raw meat 26 within the modified atmosphere package 10 takes on a purple-red color when the oxygen is removed from the interior of the package 10. The meat-filled modified atmosphere package 10 may now be stored in a refrigeration unit for several weeks prior to being offered for sale at a grocery store. A short time (e.g., less than one hour) prior to being displayed at the grocery store, the inner package 14 is removed from the polymeric bag 12 to allow oxygen from the ambient environment to permeate the non-barrier tray 16 and non-barrier cover 18. The purple-red color of the raw meat 26 quickly changes or "blooms" to a generally acceptable bright red color when the raw meat 26 is oxygenated by exposure to air.

FIG. 4 illustrates a modified atmosphere packaging system used to produce the modified atmosphere package 10 in FIGS. 1-3. The packaging system integrates several disparate and commercially available technologies to provide a modified atmosphere for retail cuts of raw meat. The basic operations performed by the packaging system are described below in connection with FIG. 4.

The packaging process begins at a thermoforming station 30 where a tray 16 is thermoformed in conventional fashion from a sheet of polystyrene or other non-barrier polymer using conventional thermoforming equipment. The thermoforming equipment typically includes a male die member 30a and a female die cavity 30b. As is well known in the thermoforming art, the tray 16 is thermoformed by inserting the male die member 30a into the female die cavity 30b with the polymeric sheet disposed therebetween.

The thermoformed tray 16 proceeds to a goods loading station 32 where the tray 16 is filled with a food product such as a retail cut of raw meat 26. The meat-filled tray 16 is then manually carried or transported on a conveyor 34 to a conventional stretch wrapping station 36 where a stretch film 18 is wrapped about the tray 16 to enclose the retail cut of meat 26 therein. The overwrapped tray 16 forms the inner package 14. The stretch wrapping station 36 may be implemented with a compact stretch semi-automatic wrapper commercially available from Hobart Corporation of Troy, Ohio. The inner package 14 may be transported to the location of the master bag 12 by a conveyor 38.

Next, the sealed inner package 14 and the oxygen scavenger 28 are inserted into a master outer bag 12. As shown in FIG. 7, the master bag 12 may be sized to accommodate multiple meat-filled inner packages 14 instead of a single inner package 14. Prior to sealing the master bag 12, the oxygen scavenger 28 is activated with the oxygen scavenger accelerator and then placed in the master bag external to the sealed inner package 14. Although the oxygen scavenger 28 is depicted in the drawings as a packet or label inserted into the master bag 12, an oxygen scavenger may alternatively be integrated into the polymers used to form the bag 12. One preferred oxygen scavenger is a FreshPax™ oxygen absorbing packet commercially available from MultiSorb Technologies, Inc. (formerly Multiform Desiccants Inc.) of Buffalo, N.Y.

Next, the oxygen level in the pocket 13 (FIG. 2) between the inner and outer packages 14 and 12 is reduced to the first level of no less than about 0.1 percent using one or more techniques, including but not limited to evacuation, gas flushing, and oxygen scavenging. As stated above, taking into account any oxygen disposed within the the inner package 14, i.e., oxygen disposed within the meat 26 itself, the wall of the tray 16, and the free space beneath the stretch film 18, this oxygen level in the pocket 13 of no less than about 0.1 percent corresponds to an "equilibrium" oxygen level in the entire package 10 of no less than about one to two percent. In a preferred embodiment, the master bag 12 and the inner package 14 contained therein are conveyed to a vacuum and gas flushing machine 60 that may be implemented with a Corr-vac® machine commercially available from M-Tek Incorporated of Elgin, Ill.

FIGS. 5 and 6a-d illustrate some details of the machine 60. The machine 60 includes an extendable snorkel-like probe 62, a movable seal clamp 64, a stationary seal bar housing 66, and an extendable heated seal bar 68 (FIGS. 6a-d). The probe 62 is disposed adjacent to the seal bar housing 66 and extends between the clamp 64 and the housing 66. The probe 62 is mounted to the machine 60 for movement between an extended position and a retracted position. The probe 62 is connected by piping 69 to both a conventional vacuum pump (not shown) and a gas tank (not shown). A conventional valve is used to select which of the two sources, the pump or the gas tank, is connected to the probe 62. The probe 62 may be open-faced or closed in the form of a tube or pipe. The seal clamp 64 includes a pair of rubber gaskets 70 and 72 and is pivotally movable between an open position spaced away from the seal bar housing 66 and a closed position alongside the seal bar housing 66. The seal bar 68 is situated within the seal bar housing 66 and is connected to an air cylinder 74 used to move the seal bar 68 between a retracted position and an extended sealing position. In its retracted position, the seal bar 68 is hidden within the seal bar housing 66 and is spaced away from the seal clamp 64. In its extended position, the seal bar 68 projects from the seal bar housing 66 applies pressure to the seal clamp 64.

The operation of the machine 60 is described below with reference to FIGS. 6a-d. As shown in FIG. 6a, the bag loading position requires the probe 62 to be in its retracted position, the seal clamp 64 to be in the open position, and the seal bar 66 to be in its retracted position. To load the master bag 12 on the machine 60, the master bag 12 is positioned such that an unsealed end of the bag 12 is disposed between the open seal clamp 64 and the seal bar housing 66 and such that the retracted probe 62 extends into the bag 12 via its unsealed end. Referring to FIG. 6b, using the handle 76 (FIG. 5), the seal clamp 64 is manually moved to its closed position such that the unsealed end of the bag 12 is secured between the seal clamp 64 and the seal bar housing 66.

Referring to FIG. 6c, with the seal clamp 64 still closed, the probe 62 is moved to its extended position such that the probe 62 projects deeper into the bag 12 via its unsealed end. The gasket 70 is interrupted at the location of the probe 62 to accommodate the probe 62 and, at the same time, prevent air from the ambient environment from entering the bag 12. After the probe 62 is moved to its extended position, the master bag 12 is subjected to evacuation and gas flushing cycles to reduce the oxygen level within the pocket 13 (FIG. 2) to no less than about 0.1 percent, which, as stated above, corresponds to an "equilibrium" oxygen level in the entire package 10 of no less than about one to two percent. The master bag 12 is first partially evacuated by connecting the probe 62 to the vacuum pump (not shown) and operating the vacuum pump. The machine 60 is preferably programmed to achieve a vacuum level of approximately 11 to 13 inches of mercury on the mercury scale. For the sake of comparison, a full vacuum corresponds to approximately 28 to 30 inches of mercury. Once the master bag 12 reaches the programmed vacuum level, the machine 60 triggers a gas flushing cycle in which the probe 62 is connected to the gas tank (not shown) and a mixture of gases is introduced into the master bag 12. The gas mixture preferably consists of about 30 percent carbon dioxide and about 70 percent nitrogen. The gas mixture creates a modified atmosphere in the pocket 13 (FIG. 2) suitable for suppressing the growth of aerobic bacteria.

Referring to FIG. 6d, after subjecting the master bag 12 to evacuation and gas flushing cycles, the probe 62 is retracted and the air cylinder 74 is actuated to move the seal bar 68 to its extended position. The heated seal bar 68 presses the unsealed end of the master bag 12 against the rubber gasket 72 for an amount of time sufficient to thermally fuse the opposing films of the bag 12 together and thereby seal the bag 12. The seal bar 68 is then retracted into the seal bar housing 66 and the clamp 64 is opened to release the sealed bag 12.

After the bag 12 is sealed, the activated oxygen scavenger 28 within the sealed bag 12 continues to absorb any residual oxygen within the modified atmosphere package 10 until the oxygen level with the package 10 is reduced to approximately zero percent. In particular, the oxygen scavenger 28 absorbs (1) any residual oxygen remaining in the pocket 13 after the master bag 12 is subjected to the evacuation and gas flushing cycles applied by the machine 60 in FIGS. 5 and 6a-d; (2) any oxygen entering the pocket 13 from the inner package 14; and (3) any oxygen from the ambient environment that might permeate the master bag 12. Activation of the oxygen scavenger 28 insures that the oxygen level is reduced to approximately zero percent at a rate sufficent to suppress the growth of metmyoglobin, thereby preventing the discoloration of the raw meat within the inner package 14. As stated above, the pigment sensitive oxygen range in which the growth of metmyoglobin is accelerated is from about 0.05 percent to two percent oxygen. Activation of the oxygen scavenger 28 allows the scavenger 28 to rapidly pass the oxygen level through this pigment sensitive range and then lower the oxygen level in the modified atmosphere package 10 to approximately zero percent in less than about 24 hours.

The modified atmosphere packaging system in FIG. 4 can produce the modified atmosphere packages 10 at cycle rates ranging from about three to six packages per minute, where the master bag 12 in each package 10 contains one to twelve inner packages 14. The maximum cycle rates which can be attained by the system in FIG. 4 are significantly higher than the cycle rates which can be achieved by prior art systems. The attainment of high cycle rates is largely due to the fact that the packaging system in FIG. 4 relies upon evacuation or other oxygen reduction equipment to remove most, but not all, of the oxygen from the package, and then relies upon the activated oxygen scavenger to absorb any residual oxygen in the package after the manufacture thereof has been completed. In contrast, prior art systems rely solely upon evacuation equipment to reduce the oxygen level to zero percent. The manufacture of prior art packages cannot be completed until after the evacuation equipment has completed its cycle. Reducing oxygen levels in the modified atmosphere package 10 of the present invention by first reducing the oxygen level in the package 10 using evacuation, flushing, and/or some other oxygen reduction technique and then subsequently reducing the oxygen level to zero percent using the activated oxygen scavenger 28 is significantly faster than the prior art's reliance upon slow evacuation techniques to carry out the entire oxygen reduction process.

While the present invention has been described with reference to one or more particular embodiments, those skilled in the art will recognize that many changes may be made thereto without departing from the spirit and scope of the present invention. Each of these embodiments and obvious variations thereof is contemplated as falling within the spirit and scope of the claimed invention, which is set forth in the following claims.

Deyo, Alan E., Luthra, Vinod K., DelDuca, Gary R., Wu, Wen P.

Patent Priority Assignee Title
Patent Priority Assignee Title
4083372, May 24 1976 Cigarette-simulating inhaler
4127503, Jul 15 1976 MITSUBISHI GAS CHEMICAL COMPANY, INC Oxygen absorbent
4141487, Mar 29 1977 VISKASE CORPORATION, A CORP OF PA Disposable food package
4166807, Dec 08 1976 Mitsubishi Gas Chemical Company, Inc. Oxygen absorbent
4192773, Aug 24 1977 Mitsubishi Gas Chemical Company, Inc. Oxygen absorbent
4201030, Aug 05 1977 Mahaffy & Harder Engineering Co. Packaging apparatus and techniques for forming closure tops
4230595, Mar 13 1978 Teijin Limited Oxygen scavenging and heat-generating compositions, and deoxygenating and heat-generating structures
4242659, Oct 15 1979 Leeds & Northrup Company Thin film resistance thermometer detector probe assembly
4299719, Oct 23 1978 Mitsubishi Kasei Corporation Deoxidizer
4308711, Aug 05 1977 Mahaffy & Harder Engineering Co. Packaging apparatus and techniques for forming closure-tops
4317742, Feb 24 1978 Teijin Limited Oxygen scavenger composition, heat-generating composition and heat-generating structure
4337276, Nov 21 1977 Toppan Printing Company, Limited Method for storing produce and container and freshness keeping agent therefore
4340138, Aug 05 1980 Multiple compartment multiple seal container
4349999, Sep 24 1969 Mahaffy & Harder Engineering Co. Packaging techniques for semi-rigid packages
4366179, Mar 17 1980 Mitsubishi Gas Chemical Company, Inc. Oxygen and carbon dioxide absorbent and process for storing coffee by using the same
4384972, Jun 21 1977 Toppan Printing Co., Ltd. Foodstuff freshness keeping agents
4406813, Aug 21 1980 Disoxidant and process for preparing same
4411122, May 23 1980 Kraft Foods, Inc Apparatus and method for pressure resizing of products
4411918, Mar 26 1980 Kontek - Tecnologie della Conservazione - S.R.L. Apparatus for preserving food by generating preservative gas
4424659, Jan 16 1980 Metal Box Limited Method and apparatus for producing a sterilizable package of a product, and the packaged product
4454945, Sep 10 1982 OWENS-ILLINOIS PLASTIC PRODUCTS INC , A CORP OF DE Multiwall container
4510162, Mar 07 1983 Creative Research & Development, Inc. Composition for absorbing oxygen and carrier therefore
4517206, Sep 19 1979 Fishery Products International Limited Food package and storage unit
4524015, Aug 09 1982 Mitsubishi Gas Chemical Company, Inc. Oxygen absorbent
4536409, Jan 23 1981 PECHINEY PLASTIC PACKAGINC, INC Oxygen scavenger
4543770, Mar 02 1982 Hassia Verpackungsmaschinen GmbH Apparatus for producing and charging containers in a sterile atmosphere
4564054, Mar 03 1983 Fluid transfer system
4574174, May 21 1984 Convenience dinner container and method
4579223, Jan 28 1983 Mitsubishi Gas Chemical Company Inc Oxygen absorbent packet
4581764, May 03 1983 ROVEMA VERPACKUNGSMASCHINEN GMBH, Sack, and a method and apparatus for filling, removing air from, and closing the sack
4588561, Jul 06 1984 Becton, Dickinson and Company Package for removing oxygen from a gaseous mixture
4593816, Sep 03 1985 Container for storing and transporting letter mail and other flat articles
4622229, May 21 1984 Kyoei Co., Ltd. Process for preserving apples in a package containing an ethylene absorbent and deoxidant
4622239, Feb 18 1986 AT&T Technologies, Inc. Method and apparatus for dispensing viscous materials
4642239, Jan 09 1984 PLM REDFEARN FLEXPACK LIMITED Packaging of fresh meat
4645073, Apr 02 1985 MERIDAN MEDICAL TECHNOLOGIES, INC Anti-contamination hazardous material package
4657610, Mar 06 1985 Mitsubishi Gas Chemical Company, Inc. Method for manufacturing gas permeable packaging material
4661326, Feb 25 1985 AMERICAN CONTAINER TECHNOLOGY, INC Sterilization container
4683139, Jul 11 1985 Chemical Bank Process for prepacking fresh meat
4683702, May 23 1984 WHIRLPOOL INTERNATIONAL B V Method for vacuum-packaging finely divided materials, and a bag for implementing the method
4685274, Jul 12 1983 SEAWELL CORPORATION N V Packaging foodstuffs
4704254, Nov 05 1984 Steris INC Filtered port suitable for medical sterilization containers and method or use thereof
4711741, Jul 26 1983 Disoxidant composition
4728504, Nov 05 1984 Steris INC Stackable medical instrument sterilizer container
4737389, Jan 31 1986 AMOCO CORPORATION, A CORP OF INDIANA Dual ovenable frozen food tray/cookware formed from a lainate containing a polymer that is crystallizable at use temperature
4740402, Nov 08 1985 Nippon Steel Corporation; Suntory Limited; Kansai Paint Co., Ltd. Materials having a deoxidation function and a method of removing oxygen in sealed containers
4756436, Nov 28 1986 Mitsubishi Gas Chemical Company, Inc. Oxygen scavenger container used for cap
4762722, Apr 16 1984 Mitsubishi Gas Chemical Company, Inc. Sealed package of raw meat or fish and method of preserving raw meat or fish
4765499, Dec 29 1987 Filter cap
4769175, Jun 26 1985 Mitsubishi Gas Chemical Company, Inc. Sheet-like, oxygen-scavenging agent
4783321, Dec 18 1984 Instrumed, Inc. Sterlization container system
4818548, Jul 11 1985 Chemical Bank Method of treating fresh meat cuts
4820442, Dec 26 1985 Freund Industrial Co., Ltd. Preservative composition
4830855, Nov 13 1987 Landec Corporation Temperature-controlled active agent dispenser
4830863, Sep 23 1986 KONINKLIJKE EMBALLAGE INDUSTRIE VAN LEER B V , A COMPANY OF THE NETHERLANDS Packaging
4836952, Apr 16 1986 Nippon Kayaku Kabushiki Kaisha Deoxygenating composition
4840271, Nov 14 1985 SEAWELL NORTH AMERICA INC , A CORP OF DE Improved thermoplastic skin packing means
4842875, Oct 06 1986 APPLIED EXTRUSION TECHNOLOGIES, INC Controlled atmosphere package
4876146, May 01 1986 Toyo Boseki Kabushiki Kaisha Anti-fogging multilayered film and bag produced therefrom for packaging vegetables and fruits
4877664, Nov 08 1985 NIPPON STEEL CORPORATION, 2-6-3, OTE-MACHI, CHIYODA-KU, TOKYO, JAPAN; SUNTORY LIMITED, 2-1-40, DOJIMAHAMA, KITA-KU, OSAKA, JAPAN; KANSAI PAINT CO , LTD , 33-1, KANZAKI-CHO, AMAGASAKI-SHI, HYOGO-KEN, JAPAN Materials having a deoxidation function and a method of removing oxygen in sealed containers
4897274, Oct 29 1986 CRYOVAC, INC Multi-layer highly moisture and gas permeable packaging film
4908151, Feb 14 1987 MITSUBISHI GAS CHEMICAL COMPANY, INC , A CORP OF JAPAN Oxygen absorbent
4910032, Nov 16 1988 APPLIED EXTRUSION TECHNOLOGIES, INC Water-permeable controlled atmosphere packaging device from cellophane and microporous film
4923703, Mar 14 1988 APPLIED EXTRUSION TECHNOLOGIES, INC Container comprising uniaxial polyolefin/filler films for controlled atmosphere packaging
4928474, Sep 21 1988 CRYOVAC, INC Oxygen-barrier retort pouch
4942048, Oct 29 1985 Nippon Kayaku Kabushiki Kaisha Process for preserving food and deoxygenating composition
4943440, Oct 22 1986 General Mills, Inc. Controlled atmosphere cut vegetable produce package and method
4949847, Apr 07 1986 Matsushita Refrigeration Company Storage receptacle
4952451, Nov 17 1988 CRYOVAC, INC Stretch/shrink film with improved oxygen transmission
4956209, May 01 1986 Toyo Boseki Kabushiki Kaisha Anti-fogging multilayered film and bag produced therefrom for packaging vegetables and fruits
4992410, Feb 17 1989 MULTISORB TECHNOLOGIES, INC Oxygen-absorbing package, composition and method of formulation thereof
4996068, Dec 02 1987 Mitsubishi Gas Chemical Company Methods for treating food and a deoxodizer package in a microwave oven
5019212, Apr 27 1987 Mitsubishi Gas Chemical Co. Method for producing gas-permeable parcelling film
5021515, Jul 27 1987 CONSTAR INTERNATIONAL INC Packaging
5025611, Nov 14 1985 Garwood Ltd. Thermoplastic skin packing means
5045331, Aug 14 1987 RIVER RANCH FRESH FOODS, LLC Container for controlled atomsphere packaging
5049624, Mar 12 1988 CONSTAR INTERNATIONAL INC Packaging
5064698, Feb 16 1989 WM WRIGLEY JR COMPANY, A CORP OF DE Food packaging improvements
5085878, Dec 02 1987 Mitsubishi Gas Chemical Company Deoxidizer package
5096724, Jun 03 1988 W R GRACE & CO -CONN Methods, compositions, and systems for ligand extraction
5101611, Feb 24 1987 LAWSON MARDON GROUP U K LIMITED Method and apparatus for forming thermally insulative and shock resistant food packaging
5103618, Aug 04 1986 Seawell Corporation N.V. Packaging
5108649, Nov 08 1989 Nippon Kayaku Kabushiki Kaisha Preserving agent, method and container for preserving fresh marine product
5108656, Jun 07 1988 American Air Liquide; Liquid Air Corporation Method for preservation of fresh fish or sea-food
5110677, Oct 01 1990 CRYOVAC, INC Lettuce packaging film
5112674, Nov 07 1989 Exxon Chemical Patents INC Cling packaging film for wrapping food products
5115624, Nov 14 1985 Seawell Corporation N.V. Thermoplastic skin packing means
5116660, Sep 08 1988 Mitsubishi Gas Chemical Company, Inc. Deoxidizer film
5120349, Dec 07 1990 Landec Corporation Microcapsule having temperature-dependent permeability profile
5120585, Oct 12 1990 Pall Corporation Package for preservative agent
5124164, Nov 16 1988 Nippon Kayaku Kabushiki Kaisha Method for preserving fresh marine products with use of a deoxidant
5128060, May 16 1990 K.K. Ueno Seiyaku Oyo Kenkyujo Oxygen absorbent
5129512, Jun 28 1989 Seawell North America, Inc. Packaging
5132151, Nov 07 1990 Tredegar Industries, Inc. Multi-layer cover
5135787, Aug 14 1990 INVISTA NORTH AMERICA S A R L Iced food shipping container with aqueous liquid absorbing pad
5143763, Jul 13 1990 Toray Industries, Inc. Oxygen scavenger
5143769, Sep 22 1988 Mitsubishi Gas Chemical Company, Inc. Deoxidizer sheet
5145950, Aug 31 1988 DOW CHEMICAL COMPANY, THE, 50% Method of storing food or plant materials by wrapping with a stretched syndiotactic polystyrene film
5151331, Aug 10 1990 E. I. du Pont de Nemours and Company Solvent blockers and multilayer barrier coatings for thin films
5153038, Apr 30 1988 Toyo Seikan Kaisha, Ltd. Plastic multi-layer vessel
5155974, Sep 03 1986 Seawell North America, Inc. Food packaging with gas between tensioned film & lid
5158537, Oct 29 1990 ALZA Corporation Iontophoretic delivery device and method of hydrating same
5171593, Oct 15 1991 INTERFLEX GROUP, INC , THE Ventilated produce package, and method of making the same
5176849, Apr 15 1992 W R GRACE & CO -CONN Composition and method for scavenging oxygen
5176930, Apr 15 1991 Sealed Air Corporation Food package and absorbent pad with edge wicking
5194315, Feb 15 1990 Kabushiki-Kaisha Taihei-Sansho Packing sheet
5202052, Sep 12 1990 W R GRACE & CO -CONN Amino polycarboxylic acid compounds as oxygen scavengers
5204389, Feb 10 1988 W. R. Grace & Co.-Conn. Sealed containers and sealing compositions for them
5207943, Jan 07 1991 MULTISORB TECHNOLOGIES, INC Oxygen absorber for low moisture products
5211875, Jun 27 1991 CRYOVAC, INC Methods and compositions for oxygen scavenging
5223146, Oct 09 1991 W R GRACE & CO -CONN Dispersion of iron (III) oxides using certain dihydroxaromatic compounds
5226531, Sep 26 1986 Elonex IP Holdings LTD Food packaging with gas between tensioned film and lid
5226735, Aug 28 1991 Perforated plastic bag for packaging fruits or vegetables
5227411, Feb 10 1988 W. R. Grace & Co.-Conn. Sealed containers and sealing compositions for them
5236617, May 16 1990 K.K. Ueno Seiyaku Oyo Kenkyujc Oxygen absorbent
5239016, Mar 23 1989 CONSTAR INTERNATIONAL L L C ; Constar International LLC Process for production of a wall for a package
5241149, Oct 15 1990 Mitsubishi Gas Chemical Company, Inc. Food packing body for heat and microwave treatment
5242111, Aug 13 1992 SCOTT FETZER COMPANY, THE Wick type liquid dispensing device for the slow controlled dispensing and diffusion of liquids over an extended period of time
5244600, Mar 02 1992 W R GRACE & CO -CONN Method of scavenging oxygen in aqueous systems
5247746, Jun 04 1992 CRYOVAC, INC Tray sealing and gas flush apparatus
5250310, Nov 02 1989 Japan Vilene Company, Ltd. Method for packing and storing meat
5254354, Dec 07 1990 Landec Corporation Food package comprised of polymer with thermally responsive permeability
5258537, Feb 18 1992 Shin-Etsu Chemical Co., Ltd. Method for preparing organomonochlorosilane
5262375, May 26 1992 MULTISORB TECHNOLOGIES, INC Oxygen absorber
5270337, Sep 25 1987 General Mills Cereals, LLC Oxygen removal
5284871, Sep 25 1987 General Mills Cereals, LLC Oxygen removal
5286407, Apr 25 1990 Mitsubishi Gas Chemical Company, Inc. Oxygen absorbent composition and method of preserving article with same
5288907, Dec 14 1987 W. R. Grace & Co.-Conn. Hydrogenation of nitroalkanes to hydroxylamines
5290268, Nov 16 1992 Diaper and pouch construction
5296291, May 05 1989 CRYOVAC, INC Heat resistant breathable films
5310497, Oct 01 1992 CRYOVAC, INC Oxygen scavenging compositions for low temperature use
5320598, Oct 29 1990 ALZA Corporation Iontophoretic delivery device and method of hydrating same
5323590, Sep 03 1986 Seawell North America, Inc. Method of producing food packaging with gas between tensioned film and lid
5332590, May 26 1992 MULTISORB TECHNOLOGIES, INC Method of absorbing oxygen by employing a particulate annealed electrolytically reduced iron
5334405, May 20 1993 CRYOVAC, INC Method of packaging food product
5346312, Jun 07 1993 FLEXO TRANSPARENT, INC Bags for maintaining crispness of cooked foodstuff
5346644, Apr 02 1991 CRYOVAC, INC Compositions, articles & methods for scavenging oxygen
5348752, May 20 1993 Bakery Holdings LLC Dual state food packaging
5350622, Apr 02 1991 CRYOVAC, INC Multilayer structure for a package for scavenging oxygen
5364555, Apr 30 1991 W R GRACE & CO -CONN Polymer compositions containing salicylic acid chelates as oxygen scavengers
5364669, Sep 28 1990 Daicel Chemical Industries, Ltd. Composite films
5378428, Apr 25 1990 Mitsubishi Gas Chemical Company, Inc. Method of preserving article with an oxygen absorbent composition
5384103, Mar 17 1992 Micromedics, Inc. Instrument tray
5390475, Apr 28 1992 Mitsubishi Gas Chemical Company, Inc. Packaging method and apparatus therefor
5399289, Oct 01 1992 CRYOVAC, INC Compositions, articles and methods for scavenging oxygen which have improved physical properties
5409126, Oct 13 1993 Storage container with reversible lid
5425896, Jun 27 1991 CRYOVAC, INC Methods and compositions for oxygen scavenging
5443727, Oct 30 1990 Minnesota Mining and Manufacturing Company Articles having a polymeric shell and method for preparing same
5445607, Oct 23 1989 WATSON LABORATORIES, INC - UTAH; WATSON PHARMACEUTICALS, INC Iontophoresis device and method using a rate-controlling electrically sensitive membrane
5491019, Mar 28 1994 CRYOVAC, INC Oxygen-permeable multilayer film
5492705, Apr 27 1992 S C JOHNSON HOME STORAGE INC Vegetable containing storage bag and method for storing same
5492742, Apr 30 1991 W R GRACE & CO -CONN Packages and containers comprising salicylic acid chelates as oxygen scavengers
5498364, Jun 27 1991 CRYOVAC, INC Methods and compositions for oxygen scavenging by a rigid semi-rigid article
5501525, Feb 24 1994 Winpak Films, Inc. Bone-guard bag
5507379, May 14 1990 Cummins-Allison Corp Coin handling system with coin sensor discriminator
5510166, Jan 23 1989 Mitsubishi Gas Chemical Company, Inc. Inhibitor parcel and method for preserving electronic devices or electronic parts
5514392, Aug 30 1989 Seawell Corporation N.V. Packaging for perishable goods
5529833, Jul 19 1991 CRYOVAC, INC Multilayer structure for a package for scavenging oxygen
5560182, Jan 19 1990 Seawell North America Inc. Packaging method
5564974, Sep 06 1994 Cummins-Allison Corp. Coin sorting system with touch screen device
5580573, Feb 01 1991 CONVATEC TECHNOLOGIES INC Temperature activated controlled release
5585129, Feb 09 1995 Dixie Consumer Products LLC Process of using a perforated package of a composite integral material
5603413, Sep 01 1994 JOHNSONVILLE ACQUISITION COMPANY LLC Sortation method for transparent optically active articles
5608643, Sep 01 1994 General Programming Holdings, Inc.; GENERAL PROGRAMMING HOLDINGS, INC System for managing multiple dispensing units and method of operation
5631036, Dec 07 1993 CRYOVAC, INC Peelable vacuum skin package with barrier foam tray
5638660, Mar 28 1994 CRYOVAC, INC Packaging process using oxygen-permeable multilayer film
5639815, Jul 27 1987 CONSTAR INTERNATIONAL INC Packaging
5643625, Mar 23 1993 General Mills, Inc Method for packaging refrigeratable yeast leavened doughs
5648020, Oct 01 1992 CRYOVAC, INC Oxygen scavenging composition for low temperature use
5660761, Feb 15 1995 CRYOVAC, INC Multi-component oxygen scavenger system useful in film packaging
5665822, Oct 07 1991 Landec Corporation Thermoplastic Elastomers
5667827, Oct 16 1995 TRANSHUMANCE HOLDING COMPANY, INC Process of packaging fresh meat
5667863, Jan 07 1991 MULTISORB TECHNOLOGIES, INC Oxygen-absorbing label
5672406, Mar 25 1991 British Technology Group Limited Material having a thermally expandable passage
5686126, Jun 06 1995 CRYOVAC, INC Dual web package having improved gaseous exchange
5686127, Jun 06 1995 CRYOVAC, INC Dual web package having improved gaseous exchange
5698250, Apr 03 1996 PACTIV LLC Modifield atmosphere package for cut of raw meat
5700554, Apr 02 1991 CRYOVAC, INC Packaging articles suitable for scavenging oxygen
5711978, Oct 16 1995 TRANSHUMANCE HOLDING COMPANY, INC Fresh meat packaging
5715169, Mar 07 1994 CSK Research Institute Corp.; Sega Enterprises, Ltd. Software rental method and apparatus, and circulating medium therefor
5811142, Apr 03 1996 PACTIV LLC Modified atmosphere package for cut of raw meat
5866184, Mar 12 1997 Bakery Holdings LLC Method of packaging a food product in a ventable package
5916613, Jun 30 1994 CRYOVAC, INC Barrier package for fresh meat products
5916615, Jun 18 1997 CRYOVAC, INC Case-ready packages having smooth, gas-permeable substrates on the bottoms thereof to reduce or prevent discoloration when placed in a stack
5948457, Apr 03 1996 PACTIV LLC Modified atmosphere package
EP457457A2,
EP468880A1,
EP547761A1,
GB1556853,
JP6278774,
JP6343815,
/
Executed onAssignorAssigneeConveyanceFrameReelDoc
Oct 08 1998Tenneco Packaging Inc.(assignment on the face of the patent)
Date Maintenance Fee Events


Date Maintenance Schedule
Aug 15 20034 years fee payment window open
Feb 15 20046 months grace period start (w surcharge)
Aug 15 2004patent expiry (for year 4)
Aug 15 20062 years to revive unintentionally abandoned end. (for year 4)
Aug 15 20078 years fee payment window open
Feb 15 20086 months grace period start (w surcharge)
Aug 15 2008patent expiry (for year 8)
Aug 15 20102 years to revive unintentionally abandoned end. (for year 8)
Aug 15 201112 years fee payment window open
Feb 15 20126 months grace period start (w surcharge)
Aug 15 2012patent expiry (for year 12)
Aug 15 20142 years to revive unintentionally abandoned end. (for year 12)