The invention concerns an additive for motive fuel additive, in particular with low sulphur content not more than 500 ppm, consisting for the most part of a combination comprising 5 to 95 wt. % of a glycerol monoester R1--C(O)--O--CH2--CHO--CH2OH or R1--C(O)--O--CH(CH2OH)2, R1 being an alkyl chain containing 8 to 60 carbon atoms, or a monocyclic or polycyclic group comprising 8 to 60 carbon atoms, and from 5 to 95 wt % of a compound of formula R2--C(O)--X, R2 being an alkyl chain containing 8 to 24 carbon atoms, or a monocyclic or polycyclic group comprising 8 to 60 carbon atoms, and X being selected among (i) the groups OR0, R0 being a hydrocarbon radical comprising 1 to 8 carbon atoms, optionally substituted by one or several esters; and (ii) the groups derived from primary or secondary amines and alkanolamines with aliphatic hydrocarbon chain, comprising 1 to 18 carbon atoms.
|
16. A fuel for vehicle engines, wherein the fuel comprises 25 to 2500 ppm of an additive which comprises:
from 5 to 25% by weight of at least one glycerol monoester of formulae (IA) or (IB):
wherein R1 is selected from the group consisting of saturated or unsaturated, linear or slightly branched, alkyl chains comprising from 8 to 24 carbon atoms and cyclic and polycyclic groups comprising from 8 to 60 carbon atoms; from 35 to 75% by weight of at least one compound of formula (II) below:
wherein R2 is a saturated or unsaturated, linear or slightly branched, alkyl chain comprising from 8 to 24 carbon atoms, and X is selected from the group consisting of (i) the groups OR0, wherein R0 is a hydrocarbon residue comprising from 1 to 8 carbon atoms, optionally substituted by one or more ester groups, and (ii) the groups deriving from alkanolamines with a linear or branched aliphatic hydrocarbon chain comprising from 1 to 18 carbon atoms, and from 0.1 to 20% by weight of at least one glycerol diester of formula (IIIA) and/or (IIIB):
wherein R3 and R4 are identical or different and are selected from the group consisting of saturated or unsaturated, linear or slightly branched, alkyl chains comprising from 8 to 24 carbon atoms and cyclic and polycyclic groups comprising from 8 to 60 carbon atoms.
1. A fuel suitable for use in a diesel and/or aviation engine, having a sulphur content of less than or equal to 500 ppm, and comprising an additive which comprises:
from 5 to 25% by weight of at least one glycerol monoester of following formulae (IA) or (IB):
wherein R1 is selected from the group consisting of saturated or unsaturated, linear or slightly branched, alkyl chains comprising from 8 to 24 carbon atoms and cyclic and polycyclic groups comprising from 8 to 60 carbon atoms; from 35 to 75% by weight of at least one compound of formula (II) below:
wherein R2 is a saturated or unsaturated, linear or slightly branched, alkyl chain comprising from 8 to 24 carbon atoms, and X is selected from the group consisting of (i) the groups OR0, wherein R0 is a hydrocarbon residue comprising from 1 to 8 carbon atoms, optionally substituted by one or more ester groups, and (ii) the groups deriving from alkanolamines with a linear or branched aliphatic hydrocarbon chain comprising from 1 to 18 carbon atoms, and from 0.1 to 20% by weight of at least one glycerol diester of formula (IIIA) and/or (IIIB):
wherein R3 and R4 are identical or different and are selected from the group consisting of saturated or unsaturated, linear or slightly branched, alkyl chains comprising from 8 to 24 carbon atoms and cyclic and polycyclic groups comprising from 8 to 60 carbon atoms.
2. The fuel of
3. The fuel of
4. The fuel of
6. The fuel of
7. The fuel of
8. The fuel of
10. The fuel of
11. The fuel of
13. The fuel of
14. The fuel of
|
|||||||||||||||||||||
The present application is a 371 of PCT/FR98/02823 filed Dec. 22, 1998.
Field of the Invention
The present invention relates to a fuel containing a lubricity additive for improving the lubrication properties of fuels, whether ground vehicle engine fuel (diesel) or jet fuel, and more particularly of diesel fuels with a low sulphur content.
It is well known that diesel fuels and jet fuels must have lubricating capabilities, for the protection of pumps, injection systems and any moving part with which these products come into contact in an internal combustion engine. With the intention of employing products which are increasingly pure and non-polluting, in particular devoid of sulphur, the refining industry has been led increasingly to improve its treatment processes for the removal of sulphur compounds. However, it has been observed that on losing sulphur compounds, the aromatic and polar compounds often associated were also lost, which caused a loss in the lubricating power of these fuels. Thus, beyond certain contents, the elimination of sulphur compounds from the composition of these products very substantially promotes the phenomena of wear and of failure of moving components in pumps and in injection systems. As regulations in many countries have imposed a limitation on the acceptable upper content of sulphur compounds in fuels of 0.05% by weight, in order to lower the emissions of polluting combustion gases from cars, lorries or buses, especially in urban built-up areas, these lubricating compounds must be replaced by other compounds which are non-polluting with regard to the environment but exhibit a sufficient lubricating power to avoid the risks of wear.
The literature also mentions that petrol fuels with a low sulphur content have a lubricating power which can prove to be insufficient to ensure good lubrication of the injection systems in new vehicles and can bring about a premature risk of wear.
Several types of additives have already been provided in order to solve this problem. Thus, antiwear additives have been added to diesel fuels, some of these additives being known in the field of lubricants, of the type of unsaturated fatty acid dimers and fatty acid esters, aliphatic amines, esters of fatty acids and of diethanolamine, and long-chain aliphatic monocarboxylic acids, such as described in U.S. Pat. Nos. 2,527,889, 4,185,594, 4,204,481 and 4,208,190. The majority of these additives exhibit a sufficient lubricating power but at concentrations which are much too high, which is very unfavourable economically for purchasing. In addition, additives containing dimeric acids, like those containing trimeric acids, cannot be employed in fuels feeding vehicles in which the fuel can be in contact with the lubricating oil, because these acids form, by chemical reaction with the detergents usually employed in lubricants, deposits which can accelerate the wear processes.
U.S. Pat. No. 4,609,376 recommends the use of antiwear additives obtained from esters of mono- and polycarboxylic acids and of polyhydroxylated alcohols in fuels containing alcohols in their composition.
In Patent GB 2,307,246, the product resulting from the reaction of carboxylic acid containing 10 to 60 carbon atoms, chosen from fatty acids or fatty acid dimers, with an alkanolamine, obtained by condensation of an amine or of a polyamine with an alkylene oxide, is preferred as lubricity additive.
It is preferable, in Patent GB 2,307,247, to employ an acid derivative, substituted by a least one hydroxyl group or one ester of polyols, or alternatively an amide of this acid.
Another route chosen is to introduce vegetable oils or their esters into the fuels, in order to improve their lubricating power or their lubricity. These include rapeseed, linseed, soybean and sunflower oils or their esters (see Patents EP 635,558 and EP 605,857). However, one of the major disadvantages of these esters is their low lubricating power at a concentration of less than 0.5% by weight in the fuels.
The present invention aims to solve the problems encountered with the additives provided by the prior art, that is to say to improve the lubricating power of the desulphurized and partially dearomatized fuels, while remaining compatible with the other additives, in particular detergents, and the lubricating oils, in particular in not forming deposits, and while reducing the cost price, in particular by a lower additive content of markedly less than 0.5.
The subject of the present invention is the use as lubricity additive for improving the lubricating power of diesel and aviation fuels with a low sulphur content, that is to say with a sulphur content of less than or equal to 500 ppm, characterized in that the additive is composed of:
1) from 5 to 25% by weight of at least one glycerol monoester of following formula (IA) or (IB):
with R1 chosen saturated or unsaturated, linear or slightly branched, alkyl chains comprising from 8 to 24 carbon atoms and cyclic and polycyclic groups comprising from 8 to 60 carbon atoms;
2) from 35 to 75% by weight of at least one compound of formula (II) below:
R2 is a saturated or unsaturated, linear or slightly branched, alkyl chain comprising from 8 to 24 carbon atoms or a cyclic or polycyclic group comprising from 8 to 60 carbon atoms and X is chosen from (i) the groups OR0, wherein R0 being a hydrocarbon residue comprising from 1 to 8 carbon atoms, optionally substituted by one or more ester groups, and (ii) the groups deriving from primary and/or secondary amines or from alkanolamines with a linear or branched aliphatic hydrocarbon chain comprising from 1 to 18 carbon atoms, and
3) from 0.1 to 20% by weight, preferably from 5 to 20% by weight, of at least one glycerol diester of formula (IIIA) and/or (IIIB):
in which R3 and R4, which are identical or different, are chosen saturated or unsaturated, linear or slightly branched, alkyl chains comprising from 8 to 24 carbon atoms and cyclic and polycyclic groups comprising from 8 to 60 carbon atoms.
Preference is given, among the glycerol monoesters of formula (I) and the diesters of formula (III) with, respectively, R1 or R3 and R4 consisting of an alkyl chain, to the monoesters and diesters obtained from the oils of the group composed of lauryl oils originating from copra or palm, which are rich in saturated alkyl chains containing 12 to 14 carbon atoms, palmitic oils resulting from palm, lard or tallow, containing a major amount of saturated alkyl chains containing 16 carbon atoms, linoleic oils resulting from sunflower, maize or rape, containing a high content of linoleic acid, linolenic oils from linseed, comprising significant contents of triunsaturated alkyl chains containing from up to 18 carbon atoms, and ricinoleic oils resulting from the castor oil plant.
Among the glycerol monoesters and diesters obtained from polycyclic acids, the preferred monoesters and diesters comprise an R1 or R3 and/or R4 composed of at least two rings, each formed of 5 to 6 atoms, at most one of which is optionally a heteroatom, such as nitrogen or oxygen, and the others are carbon atoms, these two rings additionally having two carbon atoms in common, preferably vicinal, these said rings being saturated or unsaturated. These are preferably glycerol monoesters of natural resin acids obtained from the residues from the distillation of natural oils extracted from resinous trees, in particular resinous conifers.
Among these esters of resin acids according to the invention, preference is given to esters of abietic acid, of dihydroabietic acid, of tetrahydroabietic acid, of dehydroabietic acid, of neoabietic acid, of pimaric acid, of laevopimaric acid and of parastrinic acid.
By adjusting the operating conditions for partial hydrolysis of these oils, it is possible directly to obtain the mixture of glycerol monoalkyl esters/dialkyl esters.
According to another form of the invention, it is possible to prepare glycerol alkyl esters by an esterification reaction between the carboxylic acids described above and glycerol.
The esters and the amides of formula (II) can be easily obtained by reaction of an alcohol, amine and/or alkanolamine compound with an organic acid, such as oleic acid, or a simple ester, such as methyl oleate, the reaction being carried out under the conditions known per se by a person skilled in the art for esterification and amidation processes.
In a first embodiment, the alcohols used to obtain the compound (II) are chosen from the group composed of methanol, ethanol, propanol, isopropanol, butanol, isobutanol, pentanol or 2-ethylhexanol, and/or oxyalkylated alcohols of formula R(O--CH2--CHR')n--OH, in which R is an alkyl group containing 1 to 6 carbon atoms, R' is hydrogen or an alkyl group containing 1 to 4 carbon atoms and n an integer varying from 1 to 5, such as methyl cellosolve, butyl cellosolve, butyl digol and 1-butoxypropanol.
In a second embodiment, the primary or secondary amines used to obtain the compound (II) are chosen from the group composed of methylamine, ethylamine, propylamine, butylamine, isobutylamine, 2-ethylhexylamine, decylamine, dodecylamine, stearylamine and oleylamine, N,N-diethylamine, N,N-dipropylamine, N,N-dibutylamine, N,N-di(2-ethylhexyl)amine, methyldecylamine, N-methyldodecylamine and N-methyloleylamine.
In a third embodiment, for the compound (II), use is made of alkanolamines chosen from amines containing 1 to 18 carbon atoms substituted by at least one hydroxylated, hydroxymethylated, hydroxyethylated or hydroxypropylated group, such as ethanolamine, diethanolamine, triethanolamine, isopropanolamine, diisopropanolamine, triisopropanolamine, N-methylethanolamine, tris(hydroxymethyl)aminomethane, (N-hydroxyethyl)methylimidazoline or (N-hydroxyethyl)heptadecenylimidazoline.
The additives obtained by physical mixing according to the invention are used to improve the lubricating power of diesel fuels for ground vehicle engines, optionally as a mixture with at least one oxygen-containing compound chosen from the group formed by alcohols, ethers and esters, as well as with any additive used to improve the quality of fuel, such as detergent, dispersing, antioxidizing and antifoaming additives or even biofuel.
A second subject of the invention corresponds to the fuels containing between 25 and 2500 ppm and preferably from 100 to 1000 ppm by weight of at least one additive used according to the invention dispersed in a diesel fuel which are defined by ASTM standard D-975.
The examples below are given by way of illustration of the invention but do not limit the scope thereof.
The object of the present example is to compare the lubricating power of the lubricity additives according to the invention with that of the known lubricity additives with regard to wear under the HFRR (High Frequency Reciprocating Rig) test conditions, as is described by the standardized procedure CEC-F06-A96 in the SAE 932692 article by J. W. Hadley of the University of Liverpool.
The additives according to the invention will be referenced Xi, while the comparative additives will be referenced Ti.
A first additive T1 is the product of the reaction of oleic acid with diethanolamine. This reaction is carried out in a 500 ml four-necked round-bottomed flask into which are introduced first 84.6 g of oleic acid and 105.3 g of xylene and then 31.5 g of diethanolamine over a period of 10 minutes. The entire mixture is subsequently maintained under reflux in xylene for 6 hours in order to remove 6.4 ml of water. The final product obtained contains 50% of active material with an orangey-yellow colour. Analysis by infrared spectroscopy exhibits absorption bands at 3500 cm-1, at 1730 cm-1 and at 1650 cm-1, corresponding respectively to the hydroxyl, ester and amide functional groups.
The second additive T2 is the product of the reaction of a tall-oil acid and of diethanolamine. The tall-oil acid used is a combination of 70% of a mixture of fatty acids (55% oleic acid, 38% linoleic acid, 5% palmitic acid and 2% of linolenic acid) and of 30% of resin acids exhibiting an acid number of 185 mg of KOH per gram. The reaction is carried out as for T1 by introducing 80 g of tall-oil acid, 28.2 g of diethanolamine and 98.6 g of xylene successively into the round-bottomed flask and by maintaining reflux in xylene for 6 hours. The final reaction product is a clear, viscous, orangey-yellow liquid having a residual acid number of 0.21 mg of KOH per gram.
The third additive T3 is a mixture of glycerol alkyl esters, mono-, di- and trialkyl esters, mainly comprising glycerol monooleate.
The first additive according to the invention X1 is a physical mixture of 2 g of the additive T2 and 1 g of the additive T3.
The second additive according to the invention X2 is a physical mixture of 2 g of the additive T1 and 1 g of the additive T3.
The additive T4 is the glycerol trioleate sold by the company Fluka.
The third additive according to the invention X3 is the product of the reaction of gylcerol trioleate T4 with diethanolamine. The reaction is carried out in a four-necked round-bottomed flask, as for T1, by mixing 80 g of glycerol trioleate and 18.5 g of diethanolamine and by then heating the entire mixture at 150°C C. for 4 hours.
The additive T5 is a soybean triglyceride oil with an average molecular mass of approximately 870, composed of 28% of oleic acid, 50% of linoleic acid, 8% of linolenic acid, 3% of stearic acid, 10% of palmitic acid and 1% of arachidic acid.
The fourth additive according to the invention X4 is the product of the reaction of 87 g of T4 with 21 g of diethanolamine, the mixture being kept stirred at 150°C C. for 6 hours. The additive X4 is a fluid, orangey-yellow liquid exhibiting, by infrared spectrometry, the absorption bands characteristic of the alcohol, ester and amide functional groups.
The fifth additive according to the invention X5 is obtained under the same conditions as the additive X4 but by using 87 g of T4 and 15.75 g of diethanolamine.
The sixth additive according to the invention X6 is obtained under the same conditions as the additive X4 but by using 27 g of the additive T5 and 26 g of diethanolamine.
The seventh additive according to the invention X7 is obtained under the same conditions as the additive X4 but by replacing diethanolamine by 24 g of tris(hydroxymethyl)aminomethane.
The eighth additive according to the invention X8 is obtained under the same conditions as the additive X4 but by using, as triglyceride, castor oil with an average molecular mass of approximately 927 composed of 87% of ricinoleic acid, 7% of oleic acid and 3% of stearic acid.
Each of the additives described above is introduced into three different diesel oils A, B and C, the characteristics of which are given in Table I below, at a content of 100 ppm of active material.
| TABLE I | |||||
| Diesel | Diesel | Diesel | |||
| oil A | oil B | oil C | |||
| Distillation (NFM 07-022) | 183 | 165 | 168.5 | ||
| Point, initial | |||||
| Point at | 10% volume | 227 | 208.5 | 208 | |
| 20% volume | 247 | 227.5 | 226 | ||
| 50% volume | 290 | 276 | 274.5 | ||
| 80% volume | 334 | 317.5 | 317 | ||
| 90% volume | 354 | 334 | 336 | ||
| Point, final | 373 | 357.5 | 364 | ||
| Density at 15°C C. | 0.8508 | 0.8360 | 0.8364 | ||
| (NFT 60-172) | |||||
| Calculated cetane number | 51.3 | 50 | 53 | ||
| (ASTM D4737) | |||||
| % Sulphur (ppm) | 480 | 270 | 455 | ||
| HFRR lubricating power | 425 | 772 | 550 | ||
| (CEC F06A96) (μm) | |||||
The diesel oils A, B and C, thus treated with additives, were subjected to the HFRR test, which consists in jointly applying, to a steel ball in contact with a motionless metal plate, a pressure corresponding to a weight of 200 g and an alternating movement of 1 mm at a frequency of 50 Hz. The moving ball is lubricated by the test composition. The temperature is maintained at 60°C C. throughout the duration of the test, that is to say 75 min. The lubricating power is expressed by the mean value of the diameters of the wear imprint of the ball on the plate. A small wear diameter indicates a good lubricating power; conversely, a large wear diameter expresses a power which becomes increasingly insufficient as the wear diameter increases.
| TABLE II | ||||||
| DIESEL OIL 1 | DIESEL OIL 2 | DIESEL OIL 3 | ||||
| Wear | Wear | Wear | ||||
| diameter | Gain | diameter | Gain | diameter | Gain | |
| ADDITIVES | (μm) | (%) | (μm) | (%) | (μm) | (%) |
| Without | 425 | 712 | 550 | |||
| additive | ||||||
| T1 | 335 | 21 | 618 | 20 | 456 | 17 |
| T2 | 320 | 25 | 695 | 10 | 470 | 15 |
| T3 | 360 | 15 | 633 | 18 | 430 | 22 |
| X1 | 301 | 29 | 525 | 32 | 396 | 28 |
| X2 | 299 | 30 | 553 | 28 | 439 | 20 |
| T4 | 420 | 1 | 820 | -6 | -- | -- |
| X3 | 304 | 28 | 526 | 32 | 435 | 21 |
| T5 | 410 | 4 | 750 | 3 | 545 | 1 |
| X4 | 291 | 32 | 501 | 35 | 405 | 26 |
| X5 | 308 | 28 | -- | -- | 442 | 20 |
| X6 | 258 | 39 | 562 | 27 | 409 | 26 |
| X7 | 331 | 22 | 444 | 42 | 440 | 20 |
| X8 | 300 | 30 | 526 | 32 | 404 | 26 |
It is found, from this Table II, that the physical mixtures according to the invention, such as X1 and X2, have wear characteristics which are smaller and thus clearly better than those of T1, T2 and T3, which expresses the synergistic effect obtained by combination of the predominant components of the lubricity additive according to the invention. X3 corresponds to the reaction product obtained according to the process of the invention from diethanolamine with glycerol trioleate. As above, the advantage of the additive thus obtained with regard to the wear characteristics obtained with T4 is perceived.
The performances of the additives X4, X5, X6 and X7 are to be compared with those of the starting oil T5. As above, the combination of the reaction products limits the wear phenomena observed in the case of the oil alone.
Germanaud, Laurent, Maldonado, Paul, Eber, Daniele
| Patent | Priority | Assignee | Title |
| 10167435, | Feb 08 2011 | TOTAL MARKETING SERVICES | Liquid compositions for marking liquid hydrocarbon motor fuels and other fuels, motor fuels and other fuels containing them and process for detecting the markers |
| 10273421, | Aug 05 2008 | Spirit of the 21st Century Group, LLC | Modified fuels and methods of making and using thereof |
| 10767128, | Jul 21 2016 | TOTAL MARKETING SERVICES | Copolymer suitable for use as a detergent additive for fuel |
| 11060043, | Jun 02 2017 | Hindustan Petroleum Corporation Limited | Formulation for enhancing lubricity of fuels |
| 6743266, | Mar 31 2000 | Texaco, Inc. | Fuel additive composition for improving delivery of friction modifier |
| 6793696, | Nov 24 2000 | CLARIANT PRODUKTE DEUTSCHLAND GMBH | Enhanced lubricity fuel oil compositions comprising salts of fatty acids with short chain oil-soluble amines |
| 7357819, | May 07 2001 | Victorian Chemicals International Pty Ltd | Fuel blends |
| 7626063, | May 11 2007 | PHILLIPS 66 COMPANY | Propane utilization in direct hydrotreating of oils and/or fats |
| 8316768, | Feb 06 2004 | ARCTOS RESEARCH LLC | Linear incendiary strand and method for prescribed fire ignition |
| 8444720, | Sep 21 2006 | AFTON CHEMICAL CORPORATION | Alkanolamides and their use as fuel additives |
| 8790423, | Aug 05 2008 | Spirit of the 21st Century Group, LLC | Modified fuels and methods of making and using thereof |
| 8835663, | Aug 22 2011 | Korea Institute of Petroleum Management | Lubricity improver |
| 9017430, | Sep 21 2006 | AFTON CHEMICAL CORPORATION | Alkanolamides and their use as fuel additives |
| 9102767, | Mar 25 2009 | Total Raffinage Marketing | Low molecular weight (meth)acrylic polymers, free of sulphur-containing, metallic and halogenated compounds and with low residual monomer content, method for preparing the same and uses thereof |
| 9169452, | Dec 23 2010 | Total Raffinage Marketing | Modified alkyl-phenol-aldehyde resins, use thereof as additives for improving the properties of liquid hydrocarbon fuels in cold conditions |
| 9534183, | Jun 19 2012 | TOTAL MARKETING SERVICES | Additive compositions and use thereof for improving the cold properties of fuels and combustibles |
| 9587193, | Feb 17 2012 | TOTAL MARKETING SERVICES | Additives for improving the resistance to wear and to lacquering of diesel or biodiesel fuels |
| 9657250, | Dec 23 2010 | Total Raffinage Marketing | Modified alkyl-phenol-aldehyde resins, use thereof as additives for improving the properties of liquid hydrocarbon fuels in cold conditions |
| 9663736, | Apr 25 2013 | TOTAL MARKETING SERVICES | Additive for improving the oxidation and/or storage stability of motor fuels or liquid hydrocarbon-containing fuels |
| Patent | Priority | Assignee | Title |
| 2363778, | |||
| 3133104, | |||
| 3969233, | May 26 1970 | Biodegradable internal combustion engine lubricants and motor fuel compositions | |
| 4308200, | Jul 10 1980 | Champion International Corporation | Extraction of coniferous woods with fluid carbon dioxide and other supercritical fluids |
| 4344771, | Aug 13 1976 | Phillips Petroleum Company | Fuel and lubricant additives from acid treated mixtures of vegetable oil derived amides and esters |
| 4504280, | Aug 17 1983 | Phillips Petroleum Company | Fuel additives from SO2 treated mixtures of amides and esters derived from vegetable oil, tall oil acid, or aralkyl acid |
| 4617026, | Mar 28 1983 | Exxon Research and Engineering Company | Method for improving the fuel economy of an internal combustion engine using fuel having hydroxyl-containing ester additive |
| 4634452, | Apr 12 1985 | CANADIAN PATENTS AND DEVELOPMENT LIMITED SOCIETE CANADIENNE DES BREVETS ET D EXPLOITATION LIMITEE, OTTAWA, ONTARIO, CANADA | Preparation of tall oil fuel blend |
| 4810262, | Apr 26 1985 | EXXON CHEMICAL PATENTS, INC , A DE CORP | Fuel compositions |
| 5000759, | Aug 03 1989 | Texaco Inc. | Stable middle distillate fuel-oil compositions |
| 5454842, | Dec 02 1994 | Exxon Research & Engineering Co. | Cetane improver compositions comprising nitrated fatty acid derivatives |
| 5578090, | Jun 07 1995 | BRI | Biodiesel fuel |
| 5705722, | Jun 30 1994 | HER MAJESTY IN RIGHT OF CANADA AS REPRESENTED BY THE MINISTER OF NATURAL RESOURCES CANADA | Conversion of biomass feedstock to diesel fuel additive |
| JP6065528, | |||
| WO9618706, |
| Executed on | Assignor | Assignee | Conveyance | Frame | Reel | Doc |
| Oct 07 1999 | EBER, DANIELE | Elf Antar France | ASSIGNMENT OF ASSIGNORS INTEREST SEE DOCUMENT FOR DETAILS | 013556 | /0818 | |
| Oct 07 1999 | GERMANAUD, LAURENT | Elf Antar France | ASSIGNMENT OF ASSIGNORS INTEREST SEE DOCUMENT FOR DETAILS | 013556 | /0818 | |
| Oct 07 1999 | MALDONADO, PAUL | Elf Antar France | ASSIGNMENT OF ASSIGNORS INTEREST SEE DOCUMENT FOR DETAILS | 013556 | /0818 | |
| Oct 28 1999 | Elf Antar France | (assignment on the face of the patent) | / |
| Date | Maintenance Fee Events |
| Jun 29 2006 | M1551: Payment of Maintenance Fee, 4th Year, Large Entity. |
| Jul 05 2006 | ASPN: Payor Number Assigned. |
| Jul 05 2006 | RMPN: Payer Number De-assigned. |
| Jun 30 2010 | M1552: Payment of Maintenance Fee, 8th Year, Large Entity. |
| Sep 05 2014 | REM: Maintenance Fee Reminder Mailed. |
| Jan 28 2015 | EXP: Patent Expired for Failure to Pay Maintenance Fees. |
| Date | Maintenance Schedule |
| Jan 28 2006 | 4 years fee payment window open |
| Jul 28 2006 | 6 months grace period start (w surcharge) |
| Jan 28 2007 | patent expiry (for year 4) |
| Jan 28 2009 | 2 years to revive unintentionally abandoned end. (for year 4) |
| Jan 28 2010 | 8 years fee payment window open |
| Jul 28 2010 | 6 months grace period start (w surcharge) |
| Jan 28 2011 | patent expiry (for year 8) |
| Jan 28 2013 | 2 years to revive unintentionally abandoned end. (for year 8) |
| Jan 28 2014 | 12 years fee payment window open |
| Jul 28 2014 | 6 months grace period start (w surcharge) |
| Jan 28 2015 | patent expiry (for year 12) |
| Jan 28 2017 | 2 years to revive unintentionally abandoned end. (for year 12) |