In order to prevent a scintillator of an information reading apparatus from being broken in a bonding step, a protective layer is formed so as to cover the scintillator so that the shape of the scintillator is not broken.
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1. An information reading apparatus comprising a wavelength conversion means having a wavelength conversion member provided on a first substrate, a sensor substrate having a plurality of photoelectric conversion elements arranged on a second substrate, the wavelength conversion means and the sensor substrate being bonded to each other, and a buffer layer provided between the wavelength conversion member and the photoelectric conversion elements, wherein the buffer layer comprises a first protective layer comprised of an organic material for protecting the wavelength conversion member and a second protective layer comprised of an organic material for protecting the plurality of photoelectric conversion elements, and wherein the buffer layer acts as an impact-resistant layer during bonding of the wavelength conversion means and the sensor substrate.
14. A method of producing an information reading apparatus which includes a wavelength conversion means having a wavelength conversion member provided on a first substrate, a sensor substrate having a plurality of photoelectric conversion elements arranged on a second substrate, and a buffer layer provided between the wavelength conversion member and the photoelectric conversion elements, wherein the buffer layer comprises a first protective layer comprised of an organic material for protecting the wavelength conversion member and a second protective layer comprised of an organic material for protecting the plurality of photoelectric conversion elements, comprising the steps of:
forming a resin layer as the first protective layer of the buffer layer on the wavelength conversion means; applying an adhesive to the sensor substrate; and bonding the wavelength conversion means and the sensor substrate to each other such that the wavelength conversion means is located on the adhesive side of the sensor substrate, wherein the buffer layer acts as an impact-resistant layer during the bonding step.
2. The information reading apparatus according to
3. The information reading apparatus according to
4. The information reading apparatus according to
5. The information reading apparatus according to
6. The information reading apparatus according to
7. The information reading apparatus according to
8. The information reading apparatus according to
9. A radiation imaging system comprising the information reading apparatus as set forth in
10. The radiation imaging system according to
11. The radiation imaging system according to
12. The radiation imaging system according to
13. The information reading apparatus according to
15. The method according to
16. The method according to
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1. Field of the Invention
The present invention relates to an information reading apparatus, a method of producing the apparatus, and a radiation imaging system using the apparatus and, more particularly, to an information reading apparatus having a wavelength conversion member such as a scintillator or the like, a production method of the apparatus, and a radiation imaging system using the apparatus.
2. Related Background Art
Under the trend toward filmless roentgenography, some companies have released semiconductor instruments provided with an X-ray area sensor in recent years, and methods thereof are generally classified under two types, a direct system (a type in which X-rays are directly converted into electric signals to be read) and an indirect system (a type in which X-rays are once converted into visible light and the visible light is then converted into electric signals to be read).
When X-rays are incident from the upper part of
Then, most of the light is concentratedly guided to the photosensor portions 402 and TFT switch portions 403 in the lower part of FIG. 1A. Therefore, this structure is able to achieve a high sensitivity and improvement in resolution.
A production method of the information reading device as an X-ray area sensor illustrated in
In order to make the scintillator 412 of the ideal columnar structure of cesium iodide, although the temperature during the vapor deposition is preferably not less than 200°C C., but the temperatures of not less than 200°C C. will deteriorate the photosensor portions 402 and the TFT switch portions 403 already formed, the scintillator 412 has to be formed at a temperature of not more than 200°C C.
After the formation of the scintillator 412 through the vapor deposition, a protective film for moisture resistance is bonded thereonto to form the scintillator protecting layer 413. An aluminum sheet as the reflective substrate 414 is then bonded thereonto, thus completing the X-ray area sensor.
When the scintillator 412 is formed in this way by directly depositing cesium iodide onto the glass substrate 401 having the photosensor portions 402 and TFT switch portions 403 formed thereon, the optically advantageous structure can be provided, but on the other hand the temperature has to be kept not more than 200°C C.
This means that, where the photosensor portions 402 and TFT switch portions 403 are formed of amorphous silicon, optimization has to be implemented within the temperature range such that hydrogen atoms do not become unbound.
For this structure, a gap 650 is created between adjacent area sensors as illustrated in FIG. 2A and the plane of the vapor deposited surfaces of the scintillator is divided near the gap; therefore, the scintillator 412 also grows in the lateral direction in the figure. The crystals of the scintillator near the gap 650 are not formed in the shape of columns perpendicular to the second protective layer 415 when compared with those in the other portions, accordingly.
In
In the information reading device illustrated in
When the part of the reflective substrate 414 and the part of the glass substrate 401 are bonded to each other in this way, it becomes feasible to form the scintillator 412 on the reflective substrate 414 without care on deterioration of the photosensor portions 402, etc. due to the temperature during the vapor deposition of the scintillator 412, and thus to obtain the ideal columnar structure. However, since cesium iodide as the material of the scintillator 412 is brittle, it is necessary in this structure to pay close attention so as not to break the scintillator 412 when bonding the scintillator 412 and the protective layer 511 to each other.
As described above, the information reading device illustrated in
Further, there were desires for further improvement in the sensitivity of the information reading device illustrated in
In the case of the information reading devices illustrated in
Further, with the incidence of X-rays on the information reading device as illustrated in
An object of the present invention is to provide an information reading apparatus capable of preventing the scintillator from being broken during the bonding of the scintillator to the device-side surface, and a radiation imaging system having it.
Another object of the present invention is to provide an information reading apparatus improved in the sensitivity throughout the entire image-receiving area, and a radiation imaging system having it.
Still another object of the present invention is to provide an information reading apparatus capable of reading information with higher quality and without unevenness of sensitivity throughout the entire image-receiving area, and a radiation imaging system having it.
Another object of the present invention is to provide a production method involving no breakage of the wavelength conversion member such as the scintillator or the like.
According to a first aspect of the present invention, there is provided an information reading apparatus comprising a first substrate having a wavelength conversion member formed thereon and a second substrate having a photoelectric conversion portion formed thereon, the first and the second substrates being bonded to each other through an adhesive, wherein a protective layer is formed so as to cover the wavelength conversion member on the first substrate.
According to a second aspect of the present invention, there is provided an information reading apparatus comprising a wavelength conversion means having a wavelength conversion member provided on a substrate, a sensor substrate having a plurality of photoelectric conversion elements arranged on a substrate, and a buffer layer provided between the wavelength conversion member and the photoelectric conversion elements.
According to a third aspect of the present invention, there is provided an information reading apparatus comprising a wavelength conversion means having a wavelength conversion member and a buffer layer provided in the mentioned order on a substrate and a sensor substrate having a plurality of photoelectric conversion elements provided on a substrate, the wavelength conversion means and the sensor substrate being bonded to each other such that a protective layer is located on the side of the wavelength conversion member.
According to a fourth aspect of the present invention, there is provided a radiation imaging system comprising the information reading apparatus described above, a signal processing means for processing a signal from the information reading apparatus, a display means for displaying a signal from the signal processing means, and a radiation source for irradiating the information reading apparatus with radiation.
According to a fifth aspect of the present invention, there is provided a method of producing an information reading apparatus comprising preparing a substrate having a wavelength conversion member and a resin layer in an outermost surface, applying an adhesive to a sensor substrate provided with a photoelectric conversion element, and then bonding the substrate and the sensor substrate to each other such that the wavelength conversion member is located on the adhesive side.
Next, a mask 132 is placed on the edge portions of the reflecting layer 116. Then, the base plate 117 with the mask 132 placed deposited thereon is set in a vacuum chamber of a vapor deposition system (not shown), and thereafter cesium iodide is vapor deposited on only a necessary portion on the reflecting layer 116 while keeping the vapor deposition system at a temperature of not less than 200°C C. (FIG. 5B). Then, the mask 132 and cesium iodide deposited thereon are removed to form the scintillator 115, which will become the image-receiving region (FIG. 5C).
These steps permit cesium iodide to grow in the optically ideal, columnar structure under minimized restriction of use temperature during the vapor deposition. The reflecting layer 116 functions to reflect light, e.g., light resulting from wavelength conversion in the scintillator 115 of the wavelength conversion member and also functions to improve the adhesion between the base plate 117 and the scintillator 115.
In the next step, in order to protect the scintillator 115 from outside water, the scintillator protecting layer 114 comprised of the organic resin is formed, thereby completing the base plate (wavelength conversion means 118) having the scintillator formed on a surface thereof (FIG. 5D). This provides the scintillator 115 with excellent moisture resistance and impact resistance.
On the other hand, the MIS photosensor portions 102 comprised of amorphous silicon, the TFT switch portions 103, and the electrode portion 104 are formed on the glass substrate 101 and the first protective layer 111 comprised of the nitride or the like is formed thereon. At this point, electrical inspection is conducted and only non-defective units are allowed to be supplied to the next step.
In the next step, the second protective layer 112 comprised of the organic material such as PI or the like is formed on the first protective layer 111 (FIG. 5E), and the substrate is cut into the designed size along the dashed lines illustrated in
Further, the scintillator protecting layer 114 comprised of the organic material and/or the second protective layer 112 act as an impact-resistant buffer material for preventing the scintillator 115 from being broken in the bonding step. In the last step, the sealant 121 for preventing water from penetrating the adhesion layer 113 is applied to the periphery with a dispenser (not shown) or the like to seal the side surface portions.
Completed through these steps is the information reading apparatus which is the X-ray area sensor as illustrated in
The present embodiment was described as the example wherein the material of the base plate 117 was glass, and this glass can be, for example, low alkali glass. Since the low alkali glass has a resistance to temperatures as high as 500°C C. or more, it is enough to withstand the temperatures of 100°C C. to 200°C C. encountered during the vapor deposition of the reflecting layer 116 comprised of aluminum and even the temperatures of 250°C C. to 300°C C. encountered during the vapor deposition of cesium iodide.
Further, when the thickness of the base plate 117 comprised of low alkali glass is about 0.05 mm, the transmittance of about 99.5% can be assured even in the case of incidence of X-rays of, for example, 60 keV.
When amorphous carbon is used as a material of the base plate 117, the amorphous carbon has a lower X-ray absorption coefficient, as compared with the low alkali glass (X-ray absorptance of glass is 1.0 cm-1, whereas that of amorphous carbon 0.25 cm-1); and thus demonstrates a high X-ray transmittance. Since the principal component of amorphous carbon is carbon, it is also excellent in heat resistance. Therefore, just as in the case of using the low alkali glass, amorphous carbon poses no problem in heat resistance during the vapor deposition and can assure the X-ray transmittance of about 99.7% even in the thickness of about 0.1 mm of the base plate 117.
Further, the amorphous carbon has the high electric conductivity of 2.4×10-2 Ω-1 cm-1, shows better chemical resistance than glass, and has the coefficient of thermal expansion nearly equivalent to that of glass (the coefficient of thermal expansion of glass is 4-5×10-6, whereas that of amorphous carbon 2-3×10-6). Thus use of amorphous carbon can eliminate the countermeasures against static electricity and the restriction of chemicals used in production.
Further, after the production, it can function as an electrical noise shield, protect cesium iodide from water and impurities in the surroundings, and prevent peeling of bonded portions due to difference in expansion or shrinkage from the sensor glass with a change in temperature. Particularly, even if a thin amorphous carbon sheet is bonded, there is no generation of crumples, as is the case with glass.
On the other hand, when a heat-resistant polyimide sheet is used for the base plate 117, it also functions as a buffer for preventing the scintillator from being broken in the bonding step, and thus can increase the productivity of the apparatuses. Incidentally, the polyimide is not different greatly from the low alkali glass, etc. in terms of the heat resistance and X-ray absorptance.
Further, the scintillator protecting layer 114 may be made of only the organic resin, but the layer needs to be thin enough to prevent optical blurring. If the thickness is too small to prevent penetration of water because of high permeability of water, the penetration of water can be prevented by vapor depositing a metal layer or a metal compound layer between the scintillator 115 and the polymer material.
In
In the bonding step, first, the base plate 117 and the glass substrate 101 are vacuum-chucked to the first stage 231 and to the second stage 234, respectively, and then the glass substrate 101 and the base plate 117 are bonded to each other by the sealant 121. In practice, the sealant 121 is applied between the first protective layer 111 on the glass substrate 101 and the protective layer 114 on the base plate 117 to seal them.
At this time, at least two or more holes are bored as an adhesive filling port and a vacuum port in the sealant 121. Then, the guide tube 242 of the adhesive 213 is connected to one hole and the vacuum tube 243 to the other hole as illustrated in FIG. 8. Under a vacuum through the vacuum tube 243, the adhesive 213 flows from the adhesive tank 241 through the guide tube 242 into a gap between the first protective layer 111 and the scintillator protecting layer 114.
During this operation, the base plate 117 and the glass substrate 101 are kept as chucked to the first stage 231 and to the second stage 234, respectively. In the final step, the adhesive filling port and the vacuum port are sealed, thereby completing the X-ray area sensor illustrated in
In this example, since the base plate 117 and the glass substrate 101 are bonded to each other by the bonding system as illustrated in
The second protective layer 112 comprised of an organic material such as PI or the like is formed on the first protective layer 111 (
Next prepared are four sensor substrates, each including the photosensors, the glass substrates 101, etc. illustrated in
Further, the scintillator protecting layer 114 comprised of the organic resin and/or the second protective layers 112 act as an impact-resistant buffer material for preventing the scintillator 115 from being broken, as described previously. In the final step, the resin for preventing water from penetrating the adhesion layer 113 is then applied with a dispenser (not shown) or the like to all the end surfaces at the periphery of the wavelength conversion means 118.
The X-ray area sensor as illustrated in
As described above, even in cases where a plurality of (for example, four in this example) sensor substrates are tiled in the in-plane direction as in the present example, continuity is also maintained in the scintillator structure at the end surfaces of the respective sensor substrates and thus the apparatus is excellent in the optical sense and in terms of moisture resistance.
Subsequently, an X-ray imaging system provided with the information reading apparatus described above will be described hereinafter.
The other sides of the flexible circuit boards 6010 are connected to either printed-circuit board PCB1 or PCB2. A plurality of such a-Si sensor substrates 6011 are bonded on the substrate 6012. A lead sheet 6013 for protecting memories 6014 in processing unit 6018 from X-rays is mounted on the bottom of the substrate 6012 forming the large information reading apparatus.
The wavelength conversion means 6030 (comprising, e.g., CsI) for converting, e.g., X-rays to visible light is bonded onto the sensor substrates 6011. In the present example the whole apparatus is housed in a case 6020 of carbon fiber, as illustrated in
Further, this information can also be transferred to a distant place through a transmission means such as a telephone network 6090 or the like and can be displayed on a display 6081 in a doctor room or the like where a diagnostician is present or stored in a storage means 6100 such as an optical disk or the like at another place. This allows a diagnostician such as a doctor or the like to make diagnosis at the distant place. The storage means may be recording on a film 6110 by output means such as a film processor or the like.
The present invention was described above with the example of the X-ray imaging system such as the X-ray diagnosis system or the like, but the present invention can also be applied to imaging systems for imaging radiations such as α-, β-, γ-rays or the like except for the X-rays. In this case, the scintillator can be one capable of converting the radiations to electromagnetic waves containing those within the wavelength range that can be detected by photoelectric conversion elements (for example, to the visible light).
As described above, according to the present invention, by forming the protective layer to cover the scintillator formed on the first substrate, it is possible to prevent the scintillator from being broken.
Okada, Satoshi, Mochizuki, Chiori, Morishita, Masakazu
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