The present invention provides a quantum well device and a method of forming the same. The quantum well device comprises alternately stacked n layers of quantum well layers and n layers of barrier layers, wherein the quantum well layers and barrier layers are alternatively doped with dopant, and n is a positive integer. The dopant of a predetermined concentration is applied to control the breakdown voltage and output intensity of the quantum well device and to consequently avoid artificial and mechanical esd failure.
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4. An algainp quantum well device with an electrostatic discharge (esd) endurance, comprising:
a first conductivity type gaas substrate; a first conductivity type gaas buffer layer formed on the first conductivity type gaas substrate; a first conductivity type algainp lower cladding layer formed on the first conductivity type gaas buffer layer; an algainp lower confining layer formed on the first conductivity type algainp lower cladding layer; an active layer with the esd endurance formed on the algainp lower confining layer, the active layer comprising alternately stacked n layers of algainp quantum well layers and n layers of algainp barrier layers, wherein the algainp quantum well layers are doped with a p-type dopant while the algainp barrier layers are undoped, and n is a positive integer; an algainp upper confining layer formed on the active layer; a second conductivity type algainp upper cladding layer formed on the algainp upper confining layer; and a second conductivity type covering layer formed on the second conductivity type algainp upper cladding layer.
1. An algainp quantum well device with an electrostatic discharge (esd) endurance, comprising:
a first conductivity type gaas substrate; a first conductivity type gaas buffer layer formed on the first conductivity type gaas substrate; a first conductivity type algainp lower cladding layer formed on the first conductivity type gaas buffer layer; an algainp lower confining layer formed on the first conductivity type algainp lower cladding layer; an active layer with the esd endurance formed on the algainp lower confining layer, the active layer comprising alternately stacked n layers of algainp quantum well layers and n layers of algainp barrier layers, wherein the algainp quantum well layers are doped with an n-type dopant while the algainp barrier layers are undoped, and n is a positive integer; an algainp upper confining layer formed on the active layer; a second conductivity type algainp upper cladding layer formed on the algainp upper confining layer; and a second conductivity type covering layer formed on the second conductivity type algainp upper cladding layer.
2. The algainp quantum well device of
3. The algainp quantum well device of
5. The algainp quantum well device of
6. The algainp quantum well device of
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The present invention relates to a quantum well device and a method of forming the same, and more particularly, to a quantum well device with electro-static discharge (ESD) endurance and a method of forming the same.
For recent years, a multiple quantum well structure has been extensively applied in the light emitting semiconductor structure. Various improved multiple quantum well structures have been also researched and developed. A modern multiple quantum well structure is frequently applied to a light emitting diode or a laser diode.
To overcome the above problems, the present invention discloses a quantum well device and a method of forming the same. The quantum well device includes alternately stacked n layers of quantum well layers and n layers of barrier layers, wherein the quantum well layers and barrier layers are alternatively doped with dopant, and n is a positive integer. The quantum well device of the above structure is usually referred to as an active layer in a light emitting device.
The method of forming a quantum well device includes the steps of alternately stacking n layers of quantum well layers and n layers of barrier layers, and during the stacking step, alternatively doping the quantum well layers and barrier layers with dopant, wherein n is a positive integer.
In other embodiments, the quantum well device further includes a substrate, a buffer layer, a lower cladding layer, a lower confining layer, an upper confining layer, an upper cladding layer, and a cover layer.
The dopant of the quantum well device controls the breakdown voltage and output intensity of the quantum well device and consequently avoids artificial and mechanical ESD failure. In embodiments, the dopant is n-type dopant including Te, Se or Si. In another embodiments, the dopant is p-type dopant including Mg, C or Zn. A concentration of the dopant is preferably between 5×106/c.c and 3×1018/c.c.
Please refer to
As indicated above, the quantum well layers and the barrier layers are alternatively doped with dopant. This means that either all the quantum well layers are doped and the barrier layers are undoped, or alternatively the barrier layers are doped and the quantum well layers are undoped. Accordingly, all the layers of one type are doped and all of the layer of the other typed are undoped, so that alternate layers in the stack are doped. Either type of layer can be doped and either n or p-doping can be used.
The dopant is an n-type dopant such as Te, Se or Si, or a p-type dopant such as Mg, C or Zn. A concentration of the dopant is between 5×1016/c.c and 3×1018/c.c. The active layer 38 is made of (AlxGa1-x)0.51In0.49P, wherein x is between 0 and 0.4 and determined by the emitting light wavelength. For example, x is 0.15 if the wavelength of the active layer 38 emitting light is 610 nm.
In other embodiments, the quantum well device 30 further includes a substrate 32. The alternately stacked quantum well layers 42 and barrier layers 44 are disposed on the substrate 32. The substrate 32 is an n-type GaAs substrate or a Ge substrate. Further, the quantum well device 30 includes an n-type lower cladding layer 36 and a p-type upper cladding layer 40. The lower cladding layer 36 is an AlGaInP layer or an AlInP layer being disposed on the substrate 32. The upper cladding layer 40 is an AlGaInP layer or an AlInP layer being disposed on the active layer 38.
The quantum well device 30 further includes a lower confining layer 46 and an upper confining layer 48. The lower confining layer 46 is formed between the lower cladding layer 36 and the active layer 38, and the upper confining layer 48 is formed between the active layer 38 and the upper cladding layer 40. Each one of the lower confining layer 46 and the upper confining layer 48 is an undoped or a doped AlGaInP layer. In the doped AlGaInP layer, the dopant is n-type dopant such as Te, Se or Si, or p-type dopant such as Mg, C or Zn. The dopant concentration is between 5×1016/c.c and 3×1018/c.c.
The quantum well device 30 further includes a buffer layer 34. The buffer layer 34 is an n-type GaAs layer that is formed between the lower cladding layer 36 and the substrate 32.
In the other embodiment, the quantum well device 30 further includes a cover layer 50 on the upper cladding layer 40. The cover layer 50 is a GaP layer or a GaAs layer. For a light emitting diode, the cover layer 50 is a window layer. For a laser diode, the cover layer 50 is an ohmic contact layer.
Please refer to FIG. 5.
Please refer to
Step 111: providing an n-type substrate 32;
Step 112: forming a buffer layer 34 on the substrate 32;
Step 114: forming an n-type lower cladding layer 36 on the buffer layer 34;
Step 116: forming a lower confining layer 46 on the n-type lower cladding layer 36;
Step 118: forming a periodic-delta-doped active layer 38 on the lower confining layer 46;
Step 120: forming an upper confining layer 48 on the active layer 38;
Step 122: forming a p-type upper cladding layer 40 on the upper confining layer 48; and
Step 124: forming a cover layer 50 on the p-type upper cladding layer 40.
The step 118 further comprises the following detailed steps, as shown in FIG. 7:
Detailed step 126A: forming a doped quantum well layer 42 on the lower confining layer 46, wherein the dopant of the quantum well layer 42 is an n-type dopant comprising Te, Se and Si, or a p-type dopant comprising Mg, C and Zn, and the dopant concentration is between 5×1016/c.c and 3×1018/c.c.;
Detailed step 128A: forming a barrier layer 44 on the quantum well layer 42; and
Detailed step 130A: repeating the step 126A to 128A for a plurality of times.
Alternatively, the step 118 may comprise the following detailed steps, as shown in FIG. 7:
Detailed step 126B: forming a quantum well layer 42 on the lower cladding layer 46;
Detailed step 128B: forming a doped barrier layer 44 on the quantum well layer 42, wherein the dopant of the barrier layer 44 is an n-type dopant comprising Te, Se and Si, or a p-type dopant comprising Mg, C and Zn, and the dopant concentration is between 5×1016/c.c and 3×1018/c.c.; and
Detailed step 130B: repeating the detailed steps 126B to 128B for a plurality of times.
Please refer to FIG. 8.
Please refer to FIG. 9.
Please refer to FIG. 10.
Please refer to FIG. 11.
Comparing to the conventional quantum well device 10, the quantum well device 30 of the present invention adopts periodic-delta-doped active layers 38, 68, 84, 92 and 104, wherein a plurality of quantum well layers 42 and a plurality of barrier layers 44 are selectively and alternately doped with an n-type or p-type dopant of a predetermined dopant concentration (5×1016/c.c. to 3×1018/c.c.). Since the n-type or p-type dopant of the predetermined concentration can be applied to control the breakdown voltage and emitting light intensity of the quantum well device 30, failure resulted from ESD of the quantum well device 30 will be greatly reduced under acceptable emitting light intensity and consequently reliability of the quantum well device 30 is enhanced. Further, each structure layer of the quantum well device 30 of the present invention can be grown by adopting the metal organic vapor phase epitaxy (MOVPE) method and the preparation of an ESD passivation layer for avoiding ESD failure is needless. Therefore, the quantum well device 30 of the present invention is relatively simple in process and low in production cost.
The above detailed description of the preferred embodiments is intended to describe features and spirits of the present invention more clearly. However, the disclosed preferred embodiments are not to limit the scope of the invention. On the contrary, the above description and various changes and equivalent arrangements are intended to be protected within the invention. Therefore, the claimed scope of the invention shall be interpreted in a broadest way on the basis of the above description and shall cover all possible equivalent changes and arrangements.
Wu, Jen-Chau, Huang, Pao-i, Tu, Chuan-Cheng, Tang, Shiu-Mu
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