A polarized lens of plastic lamination is provided, which lens is of high quality and highly durable in use while being inexpensively and stably producible without inconsistency in quality.
The issues of the prior polarized plastic lens as produced by the blanking and hot machining method, the injection mold-heat bonding method or the sandwiching method are solved by making the most of the ductility and casting performance inherent in diethylene glycol bis(allyl carbonate) and combining therewith the optical characteristics of a polarized film made of poly(vinyl alcohol) resin as well as transparency and durability inherent in a polycarbonate resin plate so as to produce a polarized lens of plastic lamination.
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1. A polarized lens of plastic lamination wherein a concave side surface of a polarized film layer 1 made from poly(vinyl alcohol) resin is laminated through a polymerization setting layer 3 made from diethylene glycol bis(allyl carbonate) onto a convex side surface of a lens matrix layer 2 made from polycarbonate resin while on a convex side surface of said polarized film layer 1 a polymerization setting layer 4 made from ethylene glycol bis(allyl carbonate) is formed so as to provide a polarized lens of lamination structure.
5. A method for producing a polarized lens of plastic lamination comprising the steps of dropping a casting resin r of low viscosity essentially consisting of ethylene glycol bis(allyl carbonate) into a concave cavity c of a casting die D; overlaying a convex side surface of a polarized film 1' made from poly(vinyl alcohol) resin onto said concave cavity c that corresponds to said convex side surface of said polarized film 1' so as to uniformly spread and attach said casting resin r on said convex side surface of said polarized film 1'; dropping said casting resin r into a concave side surface of said polarized film 1' and overlaying a convex side surface of a lens matrix plate 2' made from polycarbonate resin onto said concave side surface of said polarized film 1' with said casting resin r thereon so as to uniformly spread and attach said casting resin r on said convex side surface of said lens matrix plate 2'; polymerizing and setting said casting resin r as uniformly spread and attached on said convex side surfaces of said polarized film 1' and said lens matrix plate 2' under heat treatment so as to obtain an integral polarized lens prototype lb; and performing finishing operation on said prototype lb so as to produce a polarized lens l.
2. A polarized lens of plastic lamination according to
3. A polarized lens of plastic lamination according to
4. A polarized lens of plastic lamination according to
6. A method for producing a polarized lens of plastic lamination according to
7. A method for producing a polarized lens of plastic lamination according to
8. A method for producing a polarized lens of plastic lamination according to
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This application claims the priority of Japanese Patent Application No. 2002-79167 filed on Mar. 20, 2002, which application is incorporated herein by reference.
1. Technical Field
The present invention relates to a polarized lens of plastic lamination and the production method thereof, in more details, pertaining to such polarized plastic lens as being highly consistent in quality and excellent in durability in comparison with the prior counterparts and the method for producing the same lens in an efficient and economical manner.
2. Prior Art
Conventionally, the following three methods of producing a polarized plastic lens that is used for shading the sunlight or protecting the eyes of the operators working in harsh environments and conditions are known.
(1) A blanking and hot machining method wherein a polarized film made from poly (vinyl alcohol) whose surfaces are coated with an adhesive is interposed for pasting between two synthetic resin thin plates, and the plastic polarized article as obtained is subjected to blanking operation so as to be formed into a circular shape, which article is subjected to vacuum forming operation within an electric furnace so as to produce a polarized lens with curvature.
(2) An injection mold-heat bonding method wherein a synthetic resin, from which resin a lens matrix layer is molded, is injected into a metallic mold and a polarized plate made from polycarbonate resin is press-bonded onto the convex surface of the matrix layer while the synthetic resin as injected is still sticky under heat so as to produce a polarized lens.
(3) A sandwiching method wherein a polarized film made from poly (vinyl alcohol) whose surfaces are coated with an adhesive is sandwiched between two plastic lens plates with curvature so as to produce a polarized lens. To note, hard-coating treatment by such conventional method as dip coating is performed on the surfaces of the polarized lens as produced by the above three methods.
However, as to the above blanking and hot machining method, the circular polarized plastic article is subjected to high-temperature molding heat during the vacuum forming operation so as to tend to bring the quality of the finished products into inconsistency, in addition to which the curvature of the lens as formed by the vacuum forming operation chronologically fails and there arises distortion on the surface thereof as well as the polarized lens as obtained is easily subjected to aberration owing to residual stress.
As to the above injection mold-heat bonding method, the synthetic resin polarized plate does not just fit the surface of the matrix layer so as to allow air bubbles to occur at the interface thereof while as to the above sandwiching method, it allows air bubbles to occur at the interface between the polarized film and the respective plastic lens plates so as to make the hue of the polarized lens as obtained inconsistent. Any of the conventional polarized lenses as mentioned above lacks uniformity in quality and is poor at yielding, which results in the increase of the number of defects as well as the production cost. Thus, a plastic polarized lens of higher quality and reasonable price is hoped for.
In view of the above inconveniences encountered with the conventional plastic polarized lens as adopted for sunglasses and eyes-protection glasses, the present invention is firstly to provide a plastic polarized lens that is highly consistent in quality and excellent in durability in comparison with such prior polarized lens as produced by the above methods (1), (2) and (3).
Further, the present invention is secondly to provide a method for efficiently producing a high-quality plastic polarized lens wherein the adoption of a casting resin essentially consisting of diethylene glycol bis(allyl carbonate) having lower viscosity and higher ductility prevents distortion or air bubbles from occurring at the interfaces between the respective plastic laminations.
Further, the present invention is thirdly to provide a method for economically producing a high-quality plastic polarized lens free from such quality problems as aberration by restraining the occurrence of defects almost to none.
The means to solve the above issues is described below with reference to the accompanying drawings.
The first issue of the present invention is solved by laminating the concave side surface of the polarized film layer 1 made from poly (vinyl alcohol) resin onto the convex side surface of the lens matrix layer 2 made from polycarbonate resin through the polymerization setting layer 3 made from diethylene glycol bis(allyl carbonate) resin and forming the polymerization setting layer 4 made from ethylene glycol bis(allyl carbonate) resin on the convex side surface of the polarized film layer 1 so as to provide the plastic polarized lens of an integrally laminated structure comprising the respective layers 1, 2, 3 and 4.
The second and third issues of the present invention are solved by adopting a method comprising the steps of dropping a casting resin R of lower viscosity essentially consisting of ethylene glycol bis(allyl carbonate) into a concave cavity C of a casting die D; overlaying a convex side surface of a polarized film 1' made from poly(vinyl alcohol) resin, which side surface corresponds to the concave surface of the cavity C, onto the cavity C so as to uniformly spread and attach the casting resin R onto the convex side surface of the polarized film 1'; dropping the casting resin R into the concave side surface of the polarized film 1' and overlaying a convex side surface of a lens matrix plate 2' made from polycarbonate resin onto said concave side surface of said polarized film 1' with said casting resin R thereon so as to uniformly spread and attach the casting resin R onto the convex side surface of the lens matrix plate 2'; polymerizing and setting the casting resin R as uniformly spread and attached on said convex side surfaces of said polarized film 1' and said lens matrix plate 2' under heat treatment so as to obtain an integral polarized lens prototype Lb; and performing finishing operation on said prototype Lb so as to produce a polarized lens L of plastic lamination.
Hereinafter, the preferred embodiments of the polarized lens of plastic lamination and the production method thereof according to the present invention are described below with reference to the accompanying drawings.
(First Embodiment)
The polarized lens (non-prescription lens with the focal length of ∞) of plastic lamination according to the present embodiment as shown in
(Second Embodiment)
(Third Embodiment)
Hereinafter, the production method of the polarized lens of plastic lamination according to the above first embodiment is described with reference to
In
For the production of the polarized lens of the first embodiment, 0.4 cc of a casting resin R is dropped into the central portion of the cavity C, which resin is a solution prepared by mixing 60 wt. % of diethylene glycol bis(allyl carbonate) monomer that is produced by Nihon Yushi Kabushiki Kaisha under the trade name of `RAV-7AT` with an initiator or 6 wt. % of diisopropyl peroxydicarbonate produced by Nihon Yushi Kabushiki Kaisha under the trade name of `RAV-7BT`, the viscosity of which solution amounts to 13.5 cps under the temperature of 25°C C.
Then, a polarized film 1' made from poly(vinyl alcohol) resin and having 1 mm in thickness is overlaid onto the casting resin R as dropped into the cavity C of the die D such that the convex side surface of the film concentrically aligns with the cavity C, which allows the resin R to be uniformly spread onto the convex side surface of the film 1' so as to form a resin portion 4'. To note, polyvinyl butyral is coated beforehand onto the respective side surfaces of the film 1' as an adhesive.
Then, as shown in
Initial polymerization operation is performed on the respective components 1', 2', 3' and 4' as integrally laminated on the casting die D, as shown in
At the completion of the polymerization reaction, the casting die D is taken out of the heater H. On the cavity C of the die D, the diethylene glycol bis(allyl carbonate) monomer as polymerized and set is integrated with the other components so as to be formed into a polarized prototype lens Lb. This prototype Lb is attached onto the cavity C, but is easy to detach from the glass surface thereof so that it is detached therefrom without difficulty by striking lightly the backside surface of the die D, as shown in FIG. 8.
The prototype lens Lb as detached from the die D is subjected to such finishing operation as removing burrs from and cleansing the same so as to be provided to the market as a polarized lens L.
The preferred embodiments of the present invention are substantially described above, but it is not limited to them, which may be modified into various manners within the scope of the accompanying patent claims.
For instances, in the above embodiments and production example, it is exemplified that polyvinyl butyral resin is coated as an adhesive onto the respective side surfaces of the polarized film made from poly(vinyl alcohol) resin upon the lamination of the film onto the casting resin, which adhesive does not necessarily intervene in the interfaces of the laminated layers. Further, any adhesive will do as far as it is good at transparency and compatible with diethylene glycol bis(allyl carbonate). The poly(vinyl alcohol) resin may be adopted for the adhesive, which modification also belongs to the technical scope of the present invention.
The polarized lens may be produced by mixing various kinds of pigments, photochromics, an ultraviolet rays absorbent or an infrared rays absorbent with the diethylene glycol bis(allyl carbonate) monomer adopted for the casting resin in the present invention or by combining some of them to be mixed therewith, which modification also belongs to the technical scope of the present invention.
As described above, the polarized lens of plastic lamination according to the present invention is produced by making the most use of the ductility and casting performance inherent in diethylene glycol bis(allyl carbonate) and combining therewith the optical characteristics of the polarized film made from poly(vinyl alcohol) resin as well as the transparency and durability of the polycarbonate resin, which solves the pending issues altogether that are unavoidable in the prior counterparts as produced by the blanking and hot machining method, the injection mold-heat bonding method and the sandwiching method as exemplified above.
The above production arrangement allows a high-quality polarized plastic lens free from quality problems such as aberration and highly durable in use to be realized and a high-performance polarized lens of plastic lamination, in the interfaces of which lamination there occurs neither distortion nor air bubbles, to be produced in an efficient manner with the occurrence of defects restrained almost to none.
In view of the foregoing, the polarized lens of plastic lamination of the present invention is epoch-making and the production method thereof is highly efficient and economical, the industrial applicability of which is very high.
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