Method of forming a ferromagnetic layer on at least one surface of a dielectric material that may be serve as an inductive core on a printed circuit board or a multichip module. Conductive leads can form two separate coils around the core to form a transformer, and a planar conducing sheet can be placed on or between one or more of the dielectric layers as magnetic shielding. The core can be formed at least in part by electroless plating, and electroplating can be used to add a thicker layer of less conductive ferromagnetic material. ferromagnetic layers are formed by dipping the dielectric surface in a solution containing catalytic metal particles having a slight dipole, and placing the surface in a metal salt to cause a layer containing metal to be electrolessly plated upon the dielectric. surface roughening techniques can be used before the dipping to help attract the catalytic particles.
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12. A method of plating metallic material on the surface of a dielectric material, said method comprising the steps of:
plasma etching the surface of the dialectric material to roughen its surface and to create peaks and valleys in the surface of that material which have van der waal forces capable of attracting catalytic particles which have a slight electrostatic dipole;
dipping the surface of the dielectric material in a solution containing catalytic metal particles which have a slight electrostatic dipole when in solution to help those particles attach to the dielectic material's surface; and
placing the surface of the dielectric material in a metal salt solution in metastable equilibrium with a reducing agent so as to cause the metal to be plated upon the surface of the dielectric material containing the catalytic metal particles by a process of electroless plating.
1. A method of forming ferromagnetic inductive cores on a surface of a dielectric material, comprising the steps of:
plasma etching the surface of the dielectric material to roughen its surface and to create peaks and valleys in the surface of that material exhibiting van der waal forces capable of attracting catalytic particles having a slight electrostatic dipole;
dipping the surface of the dielectric material in a solution containing catalytic metal particles having a slight electrostatic dipole moment when in solution to help the particles attach to the surface of the dielectric material; and
placing the surface of the dielectric material in a first metal salt solution in metastable equilibrium with a reducing agent so as to cause a first layer containing metal to be plated upon the surface of the dielectric material containing the catalytic metal particles by a process of electroless plating in order to produce the ferromagnetic inductive cores.
2. The method of
5. The method of
6. The method of
wherein said first layer is thin layer of relatively conductive metallic material used as a seed layer; and
further comprising the step of, after the formation of said seed layer, placing the surface of the dielectric material in a second metal salt solution in metastable equilibrium with a reducing agent which has a higher concentration of non-metal elements than said first solution so as to cause material to be plated upon the seed layer which is a ferromagnetic material having a lower conductivity than the material of said seed layer.
7. The method of
wherein said first layer is thin layer of relatively conductive metallic material used as a seed layer; and
further comprising the step of electroplating less conductive ferromagnetic material onto said seed layer.
8. The method of
9. The method of
10. The method of
11. The method of
13. The method of
14. The method of
15. The method of
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This is a divisional application of U.S. patent application Ser. No. 09/904,014 filed Jul. 12, 2001, now U.S. Pat. No. 6,696,910, the contents of which are incorporated herein by reference.
The present invention relates to planar conductors for use in printed circuit boards, multichip modules, and integrated circuits, and micro electromechanical devices—and methods for making such inductors.
Devices having inductive cores are important in electric and electronic apparatuses. Such devices include transformers, inductors, and electromagnets. In the past it is been relatively difficult and expensive to produce inductive devices of the scale appropriate for use in many printed circuit boards, multichip modules, integrated circuits, or micro electromechanical (“MEM”) devices. In the past such small inductive devices usually have been fabricated using a variety of mechanical operations. These operations have included stamping, or micromachining ferromagnetic materials suitable for use in as cores and then winding primary and/or secondary coils around them. Usually such a prior art inductive devices have been separate units that have to be individually mounted upon printed circuit boards or multichip modules. Such devices are often much larger in volume than many other electronic devices and, thus, it has long been a desire to reduce the size of such inductive devices.
In the prior art there has been some creation of ferromagnetic cores upon integrated circuits for use in the micro electromechanical devices. In the past most such ferromagnetic cores have been deposited on the MEM devices by sputtering, which is a relatively expensive, time-consuming, and high-temperature process. The high-temperature of sputtering processes makes them impossible to use on many types of substrates or dielectrics.
It is an object of the present invention to provide inductive cores for use in inductors, transformers, and electromagnets which can be manufactured inexpensively, which consume relatively little space, and/or which can be formed on many different substrates.
According to a first aspect of the present invention a printed circuit board is provided comprised of two layers of printed circuit board dielectric material; a core made of ferromagnetic material between the two layers; and conductive leads on the opposite side of each dielectric layer from the core which are connected by via holes through both dielectric layers so as to form a conducting coil around the core.
In some embodiments of this aspect of the invention the conductive leads from two separate coils around the same core so that one such coil can act as a primary winding and the other can act as a secondary winding of a transformer.
In some embodiments of this aspect of the invention the conductive leads formfrom two separate coils around the same core so that one such coil can act as a primary winding and the other can act as a secondary winding of a transformer.
In some embodiments the core is formed of two separate layers of ferromagnetic material, each formed at a corresponding location on a facing side of one of said two dielectric layers.
In some embodiments the core has been formed at least in part by electroless plating on one or both of said dielectric layers. In some such embodiments the core has been deposited on one or more of dielectric layers by the following process: dipping the surface of the dielectric material in a solution containing catalytic metal particles which have a slight electrostatic dipole when in solution to help those particles attach to the dielectric material's surface; and placing the surface of the dielectric material in a first metal salt solution in metastable equilibrium with a reducing agent so as to cause a first layer containing metal to be plated upon the surface of the dielectric material containing the catalytic metal particles by a process of electroless plating. The electroless plating process can further include, before dipping the dielectric material in the solution of catalytic metal particles, plasma etching the surface of the dielectric material to roughen its surface and to create peaks and valleys in the surface of that material which have van der Waal forces capable of attracting catalytic particles which have a slight electrostatic dipole. Such etching is not necessary if the surface of the material upon which the cores the deposited already has a texture which generates the appropriate van der Waal forces. For example FR4, in material commonly used makes layers are printed circuit boards usually has a texture which is not require such etching to prepare it for the electroless plating process.
In some embodiments of this aspect of the invention the first layer put down at the start of the electroless plating process is thin layer of relatively conductive metallic material used as a seed layer. This is often done because more metallic, and thus more conducting, materials often, are more easily prompted out of the metastable solution by the catalytic particles.
In such embodiments once such a thin seed layer has been established the surface of the dielectric material can then be placed in a second metal salt solution in metastable equilibrium with a reducing agent which has a higher concentration of non-metal elements than the first solution so as to cause material to be plated upon the seed layer which is a ferromagnetic material having a lower conductivity than the material of the seed layer.
In some embodiments such a relatively conductive seed layer is used as an electrode so that electroplating can be used to plate a thicker layer of less conductive ferromagnetic material onto the seed layer.
According to another aspect of the present invention a method is provided of forming ferromagnetic inductive cores on the surface of a dielectric material. This method comprises the following: dipping the surface of the dielectric material in a solution containing catalytic metal particles which have a slight electrostatic dipole when in solution to help those particles attach to the dielectric material's surface; and placing the surface of the dielectric material in a first metal salt solution in metastable equilibrium with a reducing agent so as to cause a first layer containing metal to be plated upon the surface of the dielectric material containing the catalytic metal particles by a process of electroless plating.
Some embodiments of this method further include, before dipping the dielectric material in the solution of catalytic metal particles, plasma etching the surface of the dielectric material to roughen its surface and to create peaks and valleys in the surface of that material which have van der Waal forces capable of attracting catalytic particles which have a slight electrostatic dipole. As stated above such plasma etching is not always necessary because some materials upon which such cores are deposited already have the proper surface roughness. In other embodiments of the indention where the material needs roughening other methods of roughening the surface can be used including chemical etch and/or mechanical abrasion. When a plasma etch is used for this purpose it is commonly a non-reactive ion etch.
In some embodiments of this method the ferromagnetic material deposited is phosphorous doped nickel. In others the ferromagnetic material is boron doped nickel.
In some embodiments of this method the catalytic particles are particles of one of the following metals: cobalt, palladium, ruthenium, rhodium, platinum, iridium, osmium, nickel, or iron.
According to another aspect of the present invention a method of forming ferromagnetic inductive cores on the surface of a dielectric material is provided. This method comprises the following steps: dipping the surface of the dielectric material in a solution containing catalytic metal particles which have a slight electrostatic dipole when in solution to help those particles attach to the dielectic material's surface; and placing the surface of the dielectric material in a first metal salt solution in metastable equilibrium with a reducing agent so as to cause a first layer containing metal to be plated upon the surface of the dielectric material containing the catalytic metal particles by a process of electroless plating.
Some embodiments of this method further include the plasma etching process described above.
Some embodiments of this method change the metal salt solution used in the electroless plating process after a first relatively conductive thin seed layer has been deposited to one which will cause the subsequently deposited material to have a lower conductivity than the seed layer, as has been discussed above.
Some embodiments of this method used such a thin relatively conductive seed layer as an electrode upon which to plate less conductive from magnetic material, as has also been discussed above.
This method can be used to form an inductor core on or between one or more dielectric layers of a printed circuit board, of a multichip module, of an integrated circuit, or of a micro-electromechanical device in which the inductor is used to provide electromagnetically induced movement to a mechanical element of that device.
These and other aspects of the present invention will become more evident upon reading the following description of the preferred embodiment in conjunction with the accompanying drawings, in which:
In the prototype shown in
Sheets of FR4 material of the type commonly used in many printed circuit boards often have a relatively fine grain roughness on their surface, similar to that represented schematically in
If it is desirous deposit a ferromagnetic planar core upon material, such as, for example, polyimide, Teflon, or latex, which does not have the type of fine grain roughness shown in
In
In many embodiments, such a surface wide conducted seed layer is either unnecessary or undesirable. This is often the case when the ferromagnetic inductive core will be formed entirely through electroless plating. In such cases the ion etching 129, if needed, can be applied through a pattern photolithographic mask 131, as illustrated in
Once all, or desired portions, of the dielectric surface have the appropriate roughness to generate desired van the Waal forces, the surface will be placed in a solution containing metal catalyst particles which will be used to help the electroless plating process.
In other embodiments of the invention the catalytic particles used can be made of any metal in the eighth group on periodic table. This group includes cobalt, palladium, ruthenium, rhodium, platinum, iridium, osmium, nickel, and iron. And in other embodiments other chemicals can be used to keep the catalytic particles from undesirably conglomerating.
Once the surface of the dielectric has been seeded with the metal palladium particles 134, that surface is removed from the solution 133 and placed in a solution 135 shown in
The purity of the metal layer deposited by the process shown in
In other embodiments of the invention other ferromagnetic materials can be deposited by electroless deposition, including nickel boron alloys.
In some embodiments, after a ferromagnetic material has been deposited by electroless plating a postdeposition thermal and/or oxidative treatment might be used to improve the properties of the deposited material.
The inventors have found that it is relatively easy to form ferromagnetic cores, such as ones of a nickel phosphorus alloy, by electroless deposition alone. But in some embodiments of the invention it is desirable to use electroplating. Electroplating has the advantage of plating material at a higher rate than electroless plating, and it can be more easily used to deposit a larger class of possible ferromagnetic materials, including nickel iron and nickel zinc alloys.
This printed circuit board has other portions of circuit wiring 152 which are shielded from the electromagnetic field generated by the transformer 102A by layers of conductive material, such copper, 114A. Strips of conductive material 154 are also placed between the transformer and the other circuitry 152 and a via 156 is connected between them and the shields 114 a so as to further reduce the extent to which electromagnetic field generated by the transformer 102A has any effect upon the other circuitry 152.
In the multichip module of
In other MEM devices planar magnets, such as toroidal magnets, could be used to generate fields that are perpendicular to the surface of the MEM device.
Planar electro magnets and inductors can be used in MEM devices for many purposes, such as to make the windings of tiny electric motors; to change the position of mirrors, receivers, or emitters so as to switch the output of optical signals; to open and shut valves; and to measure magnetic field or current flows, just to name a few.
It should be understood that the foregoing description and drawings are given merely to explain and illustrate and that the invention is not limited thereto except insofar as the interpretation of the appended claims are so limited. Those skilled in the art who have the disclosure before them will be able to make modifications and variations therein without departing from the scope of the invention.
It should be understood that in other embodiments of certain aspects of the present invention the planar inductor cores could be formed by methods other than electroless plating or electroplating.
For example, planar ferromagnetic cores comprised of one or more toroidal or rectangular frames can be punched from a foil of metal alloy that has a high magnetic permeability (including materials such as, or similar to, Permalloy or Superalloy) and then be laminated between dielectric layers, such as those of a printed circuit board or a multichip module.
In other embodiments, ferromagnetic cores comprised of one or more toroidal or rectangular frames made of nickel, iron, or their alloy can be formed via physical or chemical vacuum deposition techniques on one or more dielectric layers.
In other embodiments, the ferromagnetic core can be comprised of one or more toroidal or rectangular frames that have been micromachines from a ferrite type of ceramic material and then placed in between or on the dielectric layer.
Aspects of the present invention make it possible to form ferromagnetic cores on a broad range of dielectric materials, including many smooth dielectric materials on which it has previously been difficult to perform such electroless plating. This includes, to name just a few, FR4, polyimide, BT, Teflon, and latex. The electroless plating method using the catalytic particles discussed with regard
Not only do these aspects of the invention allow metal material to be deposited upon such dielectrics, they also allow this deposition to take place quickly, inexpensively, and at a sufficiently low-temperature to allow it to be used on assemblies containing materials which could not be submitted to such high-temperature metal deposition processes as sputtering. The materials that most printed circuit boards are made of are not suitable to high-temperature processes, such a sputtering, that have often been used in the prior art to form ferromagnetic cores. Many multichip modules also use dielectric layers made of materials that are not well suited for handling the high temperatures required for sputtering. Also dielectric such as polyimide is also commonly used in certain layers of integrated circuits, and thus the low temperature core deposition methods described above also have benefit in forming such circuitry. Such low temperature deposition can also be beneficial in manufacturing MEM devices, particularly those that are composed of materials that are not cable of standing high temperatures, such as plastic.
Those skilled the art will understand that the cores used the present invention can be toroidal, rectangular, or of any other shape appropriate for an inductor or magnetic core. The ferromagnetic cores of the invention can be used not only for transformers, but also for inductive circuit components, and for the cores of electromagnet. The invention's planar inductor's can be used for many of the applications which inductors, transformers, and electromagnets are currently used, including use in providing voltage isolation between various circuits, use in radio frequency mixers, use in Hall effects sensors, use in NMRe/PMR sensors, us in radio frequency ID tags, use in current sensors, use in isolated instrument amplifiers, and use in changing the resonant frequency of antennas.
Kulinets, Joseph M., Nuytkens, Peter R., Popeko, Ilya E.
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