A rod end bearing comprising a body comprising a ring portion and a rod portion. The ring portion comprises a ring having an opening, the opening having a center axis. The rod portion comprises a first rod extending radially from the ring in a direction perpendicular to the center axis. The opening having a geometry sufficient to support a substantially spherical ball bearing, and permit rotation of the ball bearing inside the ring. The inner periphery of the ring is in contact with the ball bearing and includes a wear coating. An antifriction coating is disposed on a surface selected from the group consisting of a surface of the wear coating, a surface of the ball bearing and combinations thereof. The antifriction coating maintains a coefficient of friction between the wear coating and the ball bearing of up to about 0.95 in atmospheres substantially devoid of water vapor.
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1. A rod end bearing comprising:
a body comprising a ring portion and a rod portion;
the ring portion comprising a ring having an opening and a center axis;
the rod portion comprising a first rod extending radially from the ring in a direction perpendicular to the center axis;
the opening having a geometry sufficient to support a ball bearing, and permitting rotation of the ball bearing inside the ring, the ball bearing being substantially spherical and being capable of attachment to a second rod;
an inner periphery of the ring being in contact with the ball bearing;
a wear coating on at least a portion of the inner periphery of the ring; and
an antifriction coating disposed on a surface selected from the group consisting of a surface of the wear coating, a surface selected from the group consisting of a surface of the wear coating, a surface of the ball bearing and combinations thereof, the antifriction coating maintaining a coefficient of friction between the wear coating and the ball bearing of up to about 0.95 atmospheres substantially devoid of water vapor.
2. The rod end bearing of
3. The rode end bearing of
4. The rod end bearing of
5. The rod end bearing of
7. The rod end bearing of
9. The rod end bearing of
11. The rod end bearing of
12. The rod end bearing of
14. The rod end bearing of
15. The rod end bearing of
16. The rod end bearing of
17. The rod end bearing of
18. The rod end bearing of
19. The rod end bearing of
20. The rod end bearing of
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This invention relates generally to rod end bearing assemblies for use in high temperature, high altitude applications. In particular, the invention relates to rod end bearings for use in gas turbine engines.
In a gas turbine engine, air is drawn into the front of the engine, compressed by a shaft-mounted compressor, and mixed with fuel. The compressor is made up of several rows or stages of compressor stator vanes and corresponding rows or stages of compressor rotor blades therebetween. The stator vane rows are situated between the rotor blade rows and direct airflow toward downstream rotor blades on the rotor blade row. After leaving the compressor, the air/fuel mixture is combusted, and the resulting hot combustion gases are passed through the turbine section of the engine. The flow of hot combustion gases turn the turbine by contacting an airfoil portion of the turbine blade, which in turn rotates the shaft and provides power to the compressor. The hot exhaust gases exit from the rear of the engine, driving the engine forward. Optionally, a bypass fan driven by a shaft extending from the turbine section, which forces air around the center core of the engine and provides additional thrust to the engine.
Rod end bearings are bearing structures that connect together two rods, components or assemblies with a spherical or ball type joint. One type of rod known in the art, as described in U.S. Pat. No. 6,352,368, is a rod end bearing having an outer shell and having a spherical inner surface. Inside the outer shell there is a ball part. Between the ball part and the outer shell there is a bearing race. The outer shell and ball are fabricated from steel and the bearing is fabricated from polyurethane. Alternatively, rod end bearings having a molded race situated between the outer shell part and the inner ball part fabricated from injection molded reinforced nylon.
A number of structures in the gas turbine engine utilize rod end bearings. The rod end bearings include rod end bearings connecting the actuator mechanism to the variable stator vane. Additional structures in the gas turbine engine are subject to wear, including variable geometry exhaust actuating mechanisms. Each of the rod end bearing applications is subjected to conditions of wear at temperatures ranging from low temperatures to highly elevated temperatures. In addition, the rod end bearings are subject to high altitude atmospheres. In addition to low temperatures, high altitude atmosphere includes little or no water vapor. Water vapor is required for conventional graphite containing lubricants to maintain lubricity.
Wear occurs when contacting surfaces of two components rub against each other. Typical results from wear include scoring of one or both surfaces, and/or material removal from one or both surfaces. In rod end bearings used in the gas turbine engine, scoring may occur on one or both of the surface of the ball and the surface of the bearing casing, both of which are expensive to repair and/or replace. As the surfaces are damaged, they become even more susceptible to the effects of wear as their effective coefficients of friction rise and wear increases the clearance between the wearing surfaces, so that loads are more concentrated and causes undue motions, so the wear damage accelerates with increasing time in service. Wear debris, which may include material removed from the wearing surfaces due to wear, or may include foreign particles, such as dust or debris from the air traveling through the engine can further accelerate wear. In addition to the damage to the ball and the bearing casing, the coefficient of friction between the ball and the bearing casing increase, thereby increasing the amount of force required to move the rod and bearing. Therefore, as the rod end bearing wears, increased force is needed from an attached actuator to move the bearing during operation. The increased force requirement causes additional strain on the actuator and/or results in the need for a larger actuator.
To increase the operating capacity of the compressor, at least some of the compressor stator vane rows are designed with vanes that can rotate around an axis that is in its longitudinal direction to adjust the angular orientation of the vane with respect to the airflow traveling through the compressor. The adjustment of the angular orientation allows control of the amount of air flowing through the compressor. Variable stator vane designs typically allow for about 45° rotation of the stator vane to optimize compressor performance over the operating envelope of a gas turbine engine. The variable stator vane structures include an outer trunnion disposed in a complementary mounting boss in the stator casing for allowing rotation of the vane relative to the casing. A lever arm is fixedly joined to a coaxial stem extending outwardly from the vane trunnion. The distal end of the lever arm is operatively joined to an actuation ring that controls the angle of the vane. All of the vane lever arms in a single row are joined to a common actuation ring for ensuring that all of the variable vanes are positioned relative to the airflow in the compressor stage at the same angular orientation.
When a rod end bearing fails due to excessive wear, malfunctions in the gas turbine engine compressor may occur. The failure of the rod end bearing may create an increase in force required by the actuator to move the bearing and/or the attached system. In addition, the failure may result in a loss of control of the system connected to the bearing.
One known material for fabrication of wear surfaces for variable stator vane assemblies is a specially developed composite of carbon fiber reinforcing rods in a polyimide resin matrix manufactured by E. I. Du Pont De Nemours and Company of Wilmington, Del. The material is commonly known as VESPEL® CP™. VESPEL® and CP™ are trademarks that are owned by E. I. DuPont DeNemours and Company. The polyimide resin used in VESPEL® CP™ is commonly known as NR150™. The NR150™ trademark is owned by Cytec Technology Group of Wilmington, Del. Although the VESPEL® CP™ material has an extended life at temperatures 450-500° F. (232-260° C.), the VESPEL® CP™ bushing have an upper temperature limit of 600° F. (316° C.). Extended operation at temperatures at or above 600° F. (316° C.) limit their operational life. The material does not withstand the combinations of high temperature and vibrational loading experienced in the operation of the gas turbine engine well, leading to a relatively short part life.
Another known method for reducing wear on the variable stator vane assembly is placing a carbon-containing antifriction coating on sliding surfaces within the variable stator vane assembly. This antifriction coating is a coating fabricated from a material that reduces the coefficient of friction between the ball bearing and the bearing casing. One carbon-containing component known for antifriction coating is graphite. However, graphite has the disadvantage that water vapor is required to maintain lubricity. Atmospheres at aircraft cruise altitudes do not have enough water vapor present for graphite to be lubricious. Graphite also has the disadvantage in that graphite has poor tribological properties in applications that require reciprocating motion. An additional disadvantage of graphite is that graphite begins to oxidize rapidly at temperatures at or greater than 500° C. (932° F.). Some variable stator vane systems may experience temperatures in excess of 500° C. (932° F.). Therefore, a replacement material for graphite in antifriction coating is needed.
There is accordingly a need for an improved approach to the protection of gas turbine components, such as variable vane trunnion surfaces, variable vane casing surface or other surfaces in the gas turbine engine against the damage caused by wear. The present invention fulfills this need, and further provides related advantages.
The present invention is a rod end bearing comprising a body having a ring portion and a rod portion. The ring portion comprises a ring having an opening, the opening having a center axis. The rod portion comprises a first rod extending radially from the ring in a direction perpendicular to the center axis. The opening has a geometry sufficient to support a substantially spherical ball bearing, and permit rotation of the ball bearing inside the ring. The inner periphery of the ring is in contact with the ball bearing and includes a wear coating. An antifriction coating is disposed on a surface selected from the group consisting of a surface of the wear coating, a surface of the ball bearing and combinations thereof. The antifriction coating maintains a coefficient of friction between the wear coating and the ball bearing of up to about 0.95 in atmospheres substantially devoid of water vapor.
The rod end bearing structure according to the present invention has increased performance at higher temperatures, such as the temperatures experienced during gas turbine engine operation. Temperatures experienced during gas turbine engine operation that provide increased performance include temperatures from about room temperature up to about 1200° F. (649° C.). A preferred temperature that provides increase performance includes temperatures from about 400° F. (204° C.) up to about 1200° F. (649° C.). As the temperature of the apparatus rises, the material making up the rings and supporting the ball bearing and the fasteners holding the rings together expand at a rate faster than the material of the ball bearing. The difference in expansion rates result in less force on the sliding surfaces between the rings and the ball bearing and thereby reduces the friction force or load between the rings and the ball bearing.
Another advantage of the rod end bearing structure according to the present invention is subject to reduced wear while having an improved resistance to vibration and improved resistance to elevated temperatures, where the gas turbine engine parts attached to the rod end bearing may be utilized at temperatures greater than about 1000° F. (538° C.), including operational temperatures of greater than about 1200° F. (649° C.).
Another advantage of the rod end bearing structure, according to the present invention, is that the wear coating and antifriction coating combination reduces wear and maintains desirable tribological properties, such as high lubricity, in high altitude atmospheres having little or no water vapor. In particular, the rod end bearing structure maintains desirable tribological properties under conditions experienced by an aircraft gas turbine engine during normal operation.
Another advantage of the rod end bearing structure, according to the present invention, is that the rod end bearing structure provides an efficiency improvement in the gas turbine engine by reducing the friction force or load requirements for the actuator mechanism, thereby reducing the weight of the engine. In addition, the rod end bearing structure is easily serviced and/or replaced, thereby reducing the overhaul costs for the engine.
Another advantage of the rod end bearing according to the present invention, is that the materials used in the rod end bearing of the present invention, including the antifriction coating, can readily withstand the higher temperatures of operation utilized in current advanced engine designs. The materials used in the antifriction coating of the present invention can be utilized at temperatures greater than about 1000° F. (538° C.), including operational temperatures of greater than about 1200° F. (649° C.), without deterioration due to the combined effects of temperature, vibration, and high altitude atmosphere.
Another advantage of the end rod bearing according to the present invention is that the antifriction coating is resilient and regenerates in areas where the antifriction coating is rubbed thin or worn off the wear surface.
Other features and advantages of the present invention will be apparent from the following more detailed description of the preferred embodiment, taken in conjunction with the accompanying drawings which illustrate, by way of example, the principles of the invention.
Wherever possible, the same reference numbers will be used throughout the drawings to refer to the same or like parts.
Each variable stator vane assembly 106 includes a variable vane 114 and a vane stem 116. Vane stem 116 protrudes through an opening 118 in casing 112. Variable vane assemblies 106 further include a lever arm 120 extending from vane stem 116 that are utilized to rotate variable vanes 114. The orientation of variable vanes 114 relative to the flow path through compressor 100 control airflow therethrough. Some variable vane assemblies 106 are secured to shroud 124 by bolts 122.
At the distal end of the lever arm 120 extending away from the variable vane 114, the lever arm 120 includes an actuator pin 126 extending through the lever arm 120. The actuator pin 126 connects the lever arm 120 to an actuator ring 128. The actuator ring 128 connects the variable stator vanes 114 radially about the engine in each stage so that the vanes 114 in each stage can be adjusted in unison. As the actuator ring 128 and the actuator pin 126 rotate, sliding friction occurs between the lever arm 120, the actuator pin 126 and the actuator ring 128.
The first and second lever arms 210 and 212 are fastened together by lever arm fasteners 214. The first and second lever arms 210 and 212 include a ring portion 216, which provides a ring shaped opening for receiving ball bearing 218. The first and second lever arms 210 and 212 may be fabricated from any suitable material, including but not limited to metals and alloys. The first and second lever arms 210 and 212 are preferably fabricated from a metal or alloy having a greater thermal coefficient of expansion than the ball bearing 218. Suitable materials for fabricating the first and second lever arms include, but are not limited to, nickel-based superalloys, titanium alloys, cobalt-based superalloys, iron-based superalloys, stainless steel and combinations thereof.
The first and second lever arms 210 and 212 are fastened together to support the ball bearing 218 within ring portion 216. Lever arm fasteners 214 may be any fastener suitable for fastening together the first and second lever arms 210 and 212. The lever arm fasteners 214 preferably provide an adjustable distance between the first and second lever arms 210 and 212. Suitable fasteners for use as the lever arm fasteners 214 may include adjustable bolts, detachable rivets or set gaps. The fasteners are also preferably fabricated from a material having a greater thermal coefficient of expansion than the ball bearing 218. Ball bearing 218 is permitted to rotate within the ring portion 216 of the first and second lever arms 210 and 212. Ball bearing 218 is preferably fabricated from a material selected from the group consisting of silicon nitride (e.g., Si3N4), tungsten carbide (e.g., WC), titanium carbide (e.g., TiC), cobalt-chromium-molybdenum alloys, zirconium oxide (e.g., ZrO2) and combinations thereof. A preferred material for the ball bearing 218 is silicon nitride. An actuator pin 220 is placed through ball bearing 218 and extends to actuator ring 222. The actuator pin 220 is a rod fabricated from any suitable material, including but not limited to, metals and alloys. Actuator ring 222 connects to an actuator (not shown. Actuator ring 222 provides force to the actuator pin 220, which is then transferred to the first and second lever arm 210 and 212. The first and second lever arms 210 and 212 rotate around the center axis 205 of vane trunnion 204 adjusting the angle of the variable stator vane 202 perpendicular to the center axis 205. While
While the coatings provided in
One embodiment of the present invention includes rod end bearing structure for use in a variable stator vane for a gas turbine engine. The rod end bearings structure includes a first and second lever arms 210 and 212, a ball bearing 218, a wear coating 502 on the first lever arm 210 and an antifriction coating 504 on either or both of the ball bearing 218 and the wear coating 502. The antifriction coating 504 maintains a low coefficient of friction in high altitude atmospheres. The coefficient of friction maintained between the ball bearing 218 and the first and second lever arm 210 and 212 under normal gas turbine engine operating conditions (e.g., high temperature, high vibration, and high altitude atmosphere exposure) is equal to or less than 0.6 and preferably equal or less than 0.4. The coefficient of friction is measured between the two surfaces rubbing against each other within the rod end structure. The embodiment of the present invention shown in
The first and second lever arm 210 and 212 structure, including the ring portion 216 supporting the ball bearing 218, may be fabricated from any suitable material, including but not limited to metals and alloys. Preferred materials include nickel-based superalloys, titanium alloys, cobalt-based superalloys, iron-based superalloys, stainless steel and combinations thereof. The ball bearing 218 may include a material selected from the group consisting of silicon nitride (e.g., Si3N4), tungsten carbide (e.g., WC) titanium carbide (e.g., TiC), cobalt-chromium-molybdenum alloys, zirconium oxide (e.g., ZrO2) and combinations thereof. These ball bearings 218 are made from strong, relatively inflexible material.
Wear coatings 502 are provided on metal or alloy surfaces to provide a surface 506 having desirable wear properties, such as high hardness and wear resistance. Materials used for the first and second lever arms 210 and 212 include materials that are suitable for receiving the wear coating 502. Suitable material for receiving wear coatings may include, but are not limited to, nickel-based superalloys, titanium and its alloys, cobalt-based superalloys, iron-based superalloys and stainless steel. Wear coatings 502 provide a surface 506 that has the properties of being both hard and smooth and capable of receiving an antifriction coating 504. In one embodiment of the present invention, the first and second lever arms 210 and 212 are coated with a cemented tungsten carbide. Cemented tungsten carbides include those tungsten carbides that include a sufficient amount of cobalt to impart wear resistance. Sufficient amounts of cobalt are typically about 6-20% by weight and preferably about 12% by weight. The wear coating 502 may be applied by a plasma spray technique or other suitable method known in the art. A suitable plasma spray technique is high velocity oxy-fuel (HVOF) spraying, although other plasma spray techniques such as low-pressure plasma spray (LPPS) or air plasma spraying (APS) can be used to successfully apply the coating. Alternatively, the first and second lever arms 210 and 212 may be coated with a plasma vapor deposited (PVD) wear coatings 502 of titanium nitride or tungsten carbide. The preferred coating is a relatively thin wear coating 502 of titanium nitride or tungsten carbide applied by PVD. These wear coatings 502 may be applied to a thickness as low as about 0.0002 inches and as high as about 0.010. Preferably, the coating thicknesses are in the range from about 0.001 to about 0.005 inches, including coating thickness of about 0.003 inches. The resultant wear coating 502 is a hard, smooth surface resistant to wear.
The present invention also utilizes an antifriction coating 504 placed between the wear coated lever arms 210 and 212 and the ball bearing 218. The antifriction coating 504 is preferably coated on surface 506 of the wear coating 502. However, the antifriction coating 504 may also be coated on the surface of the ball bearing 218.
The antifriction coating 504 comprises a binder, a friction modifying agent, and, optionally, an additive. The binder of the antifriction coating 504 comprises a material selected from the group consisting of sodium silicate, aluminum phosphate, titanium oxide and combinations thereof. The friction-modifying agent is preferably dispersed substantially uniformly through the binder. The antifriction coating 504 reduces the coefficient of friction between ball bearing 218 and wear coatings 502. Of the antifriction coating binders, aluminum phosphate, titanium oxide and combinations thereof are preferred. In one embodiment, as the variable stator vane bushing assembly 200 operates, the antifriction coating 504 may eventually be consumed. The antifriction coating 504 is resilient and regenerates in areas where the antifriction coating 504 is rubbed thin or worn off the wear coating 502. The antifriction coating 504 is considered to be thin when the thickness on a portion of the surface is insufficient to provide sufficient lubricity to the sliding surfaces to maintain the coefficient of friction at the desired level. During operation, the antifriction coating 504 may migrate from location to location along the wear surface. The migration of the antifriction coating 504 allows areas that have less material or are rubbed completely off to receive antifriction coating 504 material from other locations along the wear surface to regenerate the antifriction coating 504 missing from the area rubbed thin or completely off. In addition, the antifriction coating 504 may migrate between wear coating surface 506 and ball bearing surface 402. Migration of antifriction coating 504 between surfaces can take place due to the rubbing or burnishing of the opposing surfaces.
The binder material for use in the antifriction coating 504 is any binder material that is tribologically compatible with all of the following materials: water, detergents used in the cleaning of gas turbine engine parts, deicers known in the art used to deice aircraft in winter, aircraft fuel, oil and hydraulic fluid. The binder materials are tribologically compatible if the binder material in the antifriction coating 504 maintains tribological properties (e.g., lubricity and wear resistance) of the antifriction coating 504 when in contact with the surfaces subjected to sliding friction and in contact with the materials listed above. Suitable binder materials include, but are not limited to, sodium silicate, aluminum phosphate, titanium oxide and combinations thereof.
In addition to the binder, a friction modifier is also present in the antifriction coating 504. The friction modifier is any material that, when added to the binder, produces a friction coefficient suitable for rotating a stator vane in a variable stator vane assembly, capable of maintaining desirable tribological properties at high altitude atmospheres and and/or high temperatures. The high altitude atmospheres include atmospheres to which aircraft are exposed during flight. The high altitude atmosphere includes atmospheres having reduced water vapor. High temperature exposure is a result of the operation of the gas turbine engine. The compression of the gas and the combustion of the fuel result in high temperatures in gas turbine engines. Parts within the gas turbine engine are subject to high temperatures. The coating system of the present invention may find uses in parts within the gas turbine engine that are exposed to temperatures up to about 1200° F. (649° C.). Desirable tribological properties include, but are not limited to low coefficient of friction between sliding surfaces (i.e., high lubricity) and low wear between sliding surfaces. Suitable friction modifier materials include, but are not limited to, tungsten sulfide (e.g., WS2), bismuth telluride (e.g., Bi2Te3), copper sulfide (e.g., Cu2S), bismuth oxide (e.g., Bi2O3) and combinations thereof. Of the friction modifiers, tungsten sulfide (e.g., WS2), bismuth telluride (e.g., Bi2Te3) and bismuth oxide (e.g., Bi2O3) are preferred.
Table 1 shows examples of antifriction coating materials according to the present invention. The examples shown are merely examples and do not limit the invention to the combinations of binders and friction modifiers shown therein. Examples 1-5, shown in Table 1, include coefficient of friction (COF) results for particular friction modifier and binder combinations. In order to determine the coefficient of friction, the antifriction coating materials are subject to a sliding wear test as known in the art. The tests were conducted with a stroke length of 0.150 inches, at room temperature. Antifriction coating material (i.e., binder and friction modifier) was applied to a thickness of 0.001 inch onto the wear surfaces. The wear surfaces were then subject to a load of 50 lbs. and tested for up to 1 million cycles over a wide temperature range. The coefficients of friction were measured at various temperatures during the test and an average coefficient (i.e., Avg COF) of friction was calculated as the coefficient of friction for the wear system.
TABLE 1
COF
Friction
COF
room
COF at
COF at
Avg
Ex.
Binder
Modifier
Initial
temp.
400° F.
750° F.
COF
1
titanium
tungsten
0.2
0.5
0.4
0.6
0.43
oxide
sulfide
2
titanium
bismuth
0.3
0.7
0.7
0.6
0.58
oxide
telluride
3
titanium
bismuth
0.2
0.7
0.7
0.6
0.55
oxide
oxide
4
titanium
copper
0.3
0.6
0.7
0.6
0.55
oxide
sulfide
5
aluminum
tungsten
0.3
0.4
0.5
0.5
0.43
phosphate
sulfide
The friction modifier is preferably incorporated into the binder in a quantity of about 10% to about 500% by weight. The friction modifier is incorporated into the binder material and is preferably encapsulated in the binder material. Encapsulation may take place using any suitable encapsulation method, including but not limited to powder metallurgical encapsulation methods. The binder incorporated with friction modifier is coated onto the surfaces subject to wear (i.e., wear surface). Suitable methods for coating include, but are not limited to, spraying or dipping the surface to be coated with an antifriction coating 504 and subsequently drying the antifriction coating 504. The dried surface forms an antifriction coating 504 that is tenacious and uniform across the wear surface. Optionally, the antifriction coating 504 may be heated during the drying step.
The end rod bearing structure of the present invention having the wear coating 502 and antifriction coating 504 combination preferably maintains a friction coefficient between the sliding surfaces of the rod end bearing 300 at or below about 0.6 over the entire operating range of a gas turbine engine. For example, a rod end bearing 300 for use in a variable stator vane assembly 200 may experience high altitude atmosphere substantially devoid of water vapor and temperatures up to 1200° F. More preferably, the rod end bearing 300 of the present invention maintains a friction coefficient between the sliding surfaces of below about 0.5 over the entire operating range of the end rod bearing. In particular, the antifriction coating 504 of the present invention preferably maintains a coefficient of friction of less than about 0.5 when in contact with the surface 506 of the wear coating or the surface 402 of the ball bearing 218 in a reciprocating motion under a load at temperatures up to 800° F. (427° C.).
When used in rod end bearings 300 of variable stator vane assemblies 200, the wear coating 502 and antifriction coating 504 combination on the ring portion 216 and the ball bearing 218 is resistant to wear over the entire operating range of the variable stator vane assembly 200, including the operational temperatures of the gas turbine engine and the high altitude atmospheres. In one embodiment of the present invention, the wear coating 502 and antifriction coating 504 combination, according to the present invention, wears less than about 0.005 inches over 2 million reciprocations (i.e., the number of times the surfaces are subject to rubbing friction) at temperatures up to about 800° F.
In another embodiment of the present invention, additives may be included in the antifriction coating 504 to provide additional desirable properties for the coating. The additional additive is an additive that provides desirable properties, such as increased lubricity, increased adhesion, or increased coating uniformity, to the composition. Suitable additional additives include, but are not limited to, polytetrafluoroethylene, adhesion promoters, dispersing agents, graphite, molybdenum sulfide, molybdenum diselenide, copper and combinations thereof.
The combination of the wear coating 502 and antifriction coating 504 of the present invention assure reduced coefficients of friction, in the range of about 0.2 to about 0.6, over the life of the system. Improvements in coefficient of friction permit the reduction in size, and hence weight of the actuation mechanism of the variable guide vanes, including the first and second lever arms 210 and 212.
While the invention has been described with reference to a preferred embodiment, it will be understood by those skilled in the art that various changes may be made and equivalents may be substituted for elements thereof without departing from the scope of the invention. In addition, many modifications may be made to adapt a particular situation or material to the teachings of the invention without departing from the essential scope thereof. Therefore, it is intended that the invention not be limited to the particular embodiment disclosed as the best mode contemplated for carrying out this invention, but that the invention will include all embodiments falling within the scope of the appended claims.
Bruce, Robert William, Schell, Jerry Donald, Beall, Charles J.
Patent | Priority | Assignee | Title |
10670076, | Jun 02 2016 | SCHAEFFLER TECHNOLOGIES AG & CO KG | Rolling bearing having a coating |
11339824, | Feb 20 2018 | THK RHYTHM AUTOMOTIVE GmbH | Ball-and-socket joint for chassis parts of a motor vehicle |
7828482, | Aug 28 2006 | ROLLER BEARING COMPANY OF AMERICA, INC | Tungsten carbide enhanced bearing |
9109623, | Apr 29 2013 | ROLLER BEARING COMPANY OF AMERICA, INC | Integrated cartridge double-row ball bearing for a nuclear reactor control rod drive mechanism |
9206844, | Mar 25 2013 | Daido Metal Company Ltd. | Slide member and method of manufacturing slide member |
9994785, | Apr 02 2014 | Rolls-Royce Corporation | Thermally stable self-lubricating coatings |
Patent | Priority | Assignee | Title |
2827340, | |||
3097005, | |||
3428374, | |||
3528539, | |||
3535006, | |||
3567504, | |||
3601414, | |||
3620799, | |||
3623736, | |||
3623981, | |||
3633926, | |||
3689178, | |||
3695777, | |||
3711171, | |||
3719427, | |||
3725276, | |||
3746408, | |||
3759589, | |||
3764189, | |||
3788763, | |||
3817719, | |||
3821111, | |||
3845994, | |||
3873168, | |||
3879301, | |||
3879831, | |||
3909424, | |||
3966352, | Jun 30 1975 | United Technologies Corporation | Variable area turbine |
3969113, | Oct 28 1971 | Rank Xerox Ltd. | Photosensitive binder layer for xerography containing titanium oxide and a cadmium pigment |
3984158, | Sep 10 1973 | Dresser Industries, Inc. | Journal and pilot bearings with alternating surface areas of wear resistant and anti-galling materials |
4025227, | Jun 30 1975 | United Technologies Corporation | Variable area turbine |
4050844, | Jun 01 1976 | United Technologies Corporation | Connection between vane arm and unison ring in variable area stator ring |
4059316, | Jun 21 1976 | Reed Tool Company | Bearing retaining pin for earth boring drill |
4105263, | Sep 10 1973 | Dresser Industries, Inc. | Journal and pilot bearings with alternating surface areas of wear resistant and anti-galling materials |
4109031, | Dec 27 1976 | United Technologies Corporation | Stress relief of metal-ceramic gas turbine seals |
4140834, | Dec 30 1974 | BALL PACKAGING PRODUCTS, INC BY CHANGE OF NAME FROM BALL BROTHERS SERVICE CORPORATION, A CORP OF IN | Forming a lubricating and release coating on metal mold and treated metal surface |
4163364, | Feb 15 1977 | Mitsui Engineering & Shipbuilding Co., Ltd. | Method for recovering energy possessed by exhaust gas from blast furnace |
4167411, | May 23 1973 | AM International, Inc. | Method for making reproductions of a graphic original from a high output electrostatic reproduction equipment |
4207658, | Sep 10 1973 | Dresser Industries, Inc. | Journal and pilot bearings with alternating surface areas of wear resistant and anti-galling materials |
4221545, | Oct 08 1977 | Sanden Corporation | Support mechanism of a wobble plate in a compressor unit |
4269903, | Sep 06 1979 | CHEMICAL BANK, AS AGENT | Abradable ceramic seal and method of making same |
4302149, | Feb 19 1980 | UNITED STATES OF AMERICA, AS REPRESENTED BY THE UNITED STATES DEPARTMENT OF ENERGY | Ceramic vane drive joint |
4311432, | Nov 20 1979 | United Technologies Corporation | Radial seal |
4314791, | Mar 09 1978 | Motoren- und Turbinen-Union Munchen GmbH | Variable stator cascades for axial-flow turbines of gas turbine engines |
4404263, | Dec 13 1978 | Glyco-Metall-Werke Daelen & Loos GmbH | Laminated bearing material and process for making the same |
4425247, | Aug 18 1981 | Composite self-lubricating material | |
4456266, | Dec 14 1981 | General Electric Company | Throttle bushing |
4492522, | Dec 24 1981 | MTU Motoren-und Turbinen-Union Muenchen GmbH | Blade for a fluid flow engine and method for manufacturing the blade |
4509803, | Nov 08 1982 | Taiho Kogyo Co., Ltd. | Sliding member having a novel pore structure on the sliding surface thereof |
4521496, | Dec 27 1978 | UCAR CARBON TECHNOLOGY CORPORATIONA CORP OF DE | Stress relieved metal/ceramic abradable seals |
4548254, | Jun 30 1983 | ZEZEL CORPORATION | Method of manufacturing a die-cast wobble plate assembly |
4559248, | Nov 12 1982 | Oiles Industry Co., Ltd. | Sliding member |
4618269, | Sep 18 1985 | REEDHYCALOG, L P | Hardened bearing surface and method of forming same |
4619580, | Sep 08 1983 | The Boeing Company | Variable camber vane and method therefor |
4664595, | Sep 30 1983 | Ebara Corporation | Combination of slide members |
4678350, | Jun 02 1986 | Bearing assembly | |
4728448, | May 05 1986 | The United States of America as represented by the Administrator of the | Carbide/fluoride/silver self-lubricating composite |
4733716, | May 30 1984 | Fujikura Ltd. | Bushing in continuous casting dip forming apparatus |
4808069, | Jul 03 1986 | The United States of America as represented by the Secretary of the Air | Anti-rotation guide vane bushing |
4832993, | Mar 09 1987 | Alsthom | Method of applying a protective coating to a titanium alloy blade, and a blade obtained thereby |
4834613, | Feb 26 1988 | United Technologies Corporation | Radially constrained variable vane shroud |
4834622, | Jun 15 1983 | Sundstrand Corporation | Gas turbine engine/load compressor power plants |
4836746, | Apr 03 1987 | GHH BORSIG Turbomaschinen GmbH | Axial flow engine guide vane adjusting device |
4867639, | Sep 22 1987 | ALLIED-SIGNAL INC , A DE CORP | Abradable shroud coating |
4875532, | Sep 19 1988 | Halliburton Energy Services, Inc | Roller drill bit having radial-thrust pilot bushing incorporating anti-galling material |
4879052, | Nov 05 1987 | Akzo America Inc. | High temperature polyol ester/phosphate ester crankcase lubricant composition |
4910086, | Dec 25 1987 | Kureha Kagaku Kogyo K.K. | Resin coated metal body |
4913563, | Nov 07 1988 | WESTINGHOUSE ELECTRIC CO LLC | Hydrodynamic pivoted pad bearing assembly for a reactor coolant pump |
5064727, | Jan 19 1990 | AlliedSignal Inc | Abradable hybrid ceramic wall structures |
5066540, | Jan 23 1987 | Sermatech International, Inc. | Flake materials in coating compositions |
5066546, | Mar 23 1989 | KENNAMETAL INC | Wear-resistant steel castings |
5100848, | May 10 1990 | Agency of Industrial Science and Technology; Ministry of International Trade and Industry | Oxide type solid lubricant containing Cr2 O3 and Na2 ZrO.sub . |
5141656, | Mar 26 1990 | Process for coating machine parts and coated machine parts produced thereby | |
5149250, | Feb 28 1991 | General Electric Company | Gas turbine vane assembly seal and support system |
5161898, | Jul 05 1991 | REEDHYCALOG, L P | Aluminide coated bearing elements for roller cutter drill bits |
5162157, | Feb 27 1990 | Daido Metal Company Ltd. | Sliding material and method of manufacturing the same |
5222360, | Oct 30 1991 | General Electric Company | Apparatus for removably attaching a core frame to a vane frame with a stable mid ring |
5240741, | Dec 20 1991 | United Technologies Corporation | Inhibiting coke formation by coating gas turbine elements with tungsten disulfide |
5244587, | Jul 12 1990 | DAIDO MACHINERY, LTD ,; Daido Tokushuko; KABUSHIKI KAISHA,; UNITIKA LTD , | Forging lubricant and a method for forming a lubricant coat on the surface of a linear material |
5269798, | Feb 19 1992 | Linvatec Corporation | Surgical cutting instrument with movable, inner and outer tubular members |
5277073, | Jan 27 1992 | The Dow Chemical Company | Constant pressure-loaded shaft seal |
5281087, | Jun 10 1992 | General Electric Company | Industrial gas turbine engine with dual panel variable vane assembly |
5294355, | Dec 28 1992 | Desilube Technology, Inc. | Thermally and oxidatively stable solid lubricants |
5308226, | Dec 02 1991 | General Electric Company | Variable stator vane assembly for an axial flow compressor of a gas turbine engine |
5352540, | Aug 26 1992 | AlliedSignal Inc | Strain-tolerant ceramic coated seal |
5364209, | Sep 17 1990 | Kennametal Inc. | CVD and PVD coated cutting tools |
5388866, | Mar 09 1990 | Lourdes Industries | High pressure coupling with provision for preventing separation of parts and with anti-galling provision |
5434210, | Nov 19 1990 | Sulzer Plasma Technik, Inc. | Thermal spray powders for abradable coatings, abradable coatings containing solid lubricants and methods of fabricating abradable coatings |
5458460, | Mar 18 1993 | Hitachi, Ltd. | Drainage pump and a hydraulic turbine incorporating a bearing member, and a method of manufacturing the bearing member |
5459546, | Aug 28 1992 | Method and apparatus for accurate alignment of semiconductor wafers in photo printers | |
5470494, | Sep 07 1994 | Agency of Industrial Science & Technology; Ministry of International Trade & Industry | Oxide type solid lubricant |
5507961, | Jul 18 1994 | The United States of America as represented by the Secretary of the Air | High temperature cesium-containing solid lubricant |
5517817, | Oct 28 1993 | General Electric Company | Variable area turbine nozzle for turbine engines |
5518639, | Aug 12 1994 | Hoeganaes Corp. | Powder metallurgy lubricant composition and methods for using same |
5536022, | Aug 24 1990 | United Technologies Corporation | Plasma sprayed abradable seals for gas turbine engines |
5551853, | Feb 25 1994 | Regi U.S., Inc. | Axial vane rotary device and sealing system therefor |
5554309, | Aug 28 1989 | Alcoa Inc | Lubricants for ceramics at elevated temperatures |
5560991, | May 20 1993 | AlliedSignal Inc. | Process for preparation of metal carbide fibers |
5587217, | Jul 01 1994 | WD MEDIA, INC | Lubricant composition and method |
5589012, | Feb 22 1995 | SYSTEMS INTEGRATION AND RESEARCH, INC | Bearing systems |
5593275, | Aug 01 1995 | General Electric Company | Variable stator vane mounting and vane actuation system for an axial flow compressor of a gas turbine engine |
5622473, | Nov 17 1995 | General Electric Company | Variable stator vane assembly |
5628617, | Aug 12 1996 | Demag Delavel Turbomachinery Corp. TurboCare Division | Expanding bell seal |
5695326, | Jun 05 1995 | Matsushita Electric Industrial Co., Ltd. | Compressor for a refrigeration machine having a thrust bearing |
5714700, | Apr 28 1994 | Nippon Steel Corporation | High strength self-lubricating composite material for high temperature and production method of the same |
5723800, | Jul 03 1996 | NACHI-FUJIKOSHI CORP. | Wear resistant cermet alloy vane for alternate flon |
5725313, | Aug 03 1994 | REEDHYCALOG, L P | Rolling cutter drill bits |
5731045, | Jan 26 1996 | Southwest Research Institute | Application of diamond-like carbon coatings to cobalt-cemented tungsten carbide components |
5747428, | Mar 10 1997 | RACIK, DONNA INDIVIDUALLY | Solid lubricant for low and high temperature applications |
5755817, | Feb 06 1995 | Sundyne Corporation | Hydrostatic seal |
5807072, | Nov 17 1995 | General Electric Company | Variable stator vane assembly |
5813830, | Feb 09 1996 | Rolls-Royce Corporation | Carbon seal contaminant barrier system |
5829881, | Apr 25 1997 | Eastman Kodak Company | Wear resistant apparatus and method for translating a printing element relative to a frame |
5839880, | Mar 18 1992 | Hitachi, Ltd. | Bearing unit, drainage pump and hydraulic turbine each incorporating the bearing unit, and method of manufacturing the bearing unit |
5856378, | Jun 01 1990 | COURTAULDS COATINGS HOLDINGS LIMITED | Powder coating compositions |
5868398, | May 20 1997 | United Technologies Corporation | Gas turbine stator vane seal |
5891522, | Mar 14 1997 | Saint-Gobain Industrial Ceramics, Inc.; SAINT-GOBAIN INDUSTRIAL CERAMICS, INC | Composite article with adherent CVD diamond coating and method of making |
6068813, | May 26 1999 | Hoeganaes Corporation | Method of making powder metallurgical compositions |
6073537, | Aug 08 1996 | Toyota Jidosha Kabushiki Kaisha | Roller bush for fuel injection pump |
6086327, | Jan 20 1999 | General Electric Company | Bushing for a jet engine vane |
6093482, | Dec 16 1998 | DACC CARBON | Carbon-carbon composite for friction products and method of making same |
6102656, | Sep 26 1995 | United Technologies Corporation | Segmented abradable ceramic coating |
6106936, | Jul 08 1995 | FEDERAL-MOGUL WIESBADEN GMBH & CO KG | Overlay material for plain bearing comprising filled fluorothermoplastic material |
6129533, | Apr 11 1998 | Joh. Heinr. Bornemann GmbH | Sealing system for rotating component of a pump |
6135712, | Jan 09 1998 | SAFRAN AIRCRAFT ENGINES | Turbomachine with mutual braking of concentric shafts |
6139261, | Apr 16 1999 | General Electric Company | Bushing assembly with removable wear sleeve |
6142060, | May 19 1997 | Honda Giken Kogyo Kabushiki Kaisha | High pressure fuel pump having a bellows sealing arrangement |
6146093, | Dec 16 1998 | General Electric Company | Variable vane seal and washer |
6164846, | Mar 25 1998 | Eastman Kodak Company | Apparatus and method for transporting a web |
6170990, | Feb 03 1999 | General Electric Company | Trunnion bushing |
6177178, | Nov 30 1995 | Sandvik Intellectual Property Aktiebolag | Coated milling insert and method of making it |
6184333, | Jan 15 1999 | Maverick Corporation | Low-toxicity, high-temperature polyimides |
6190124, | Nov 26 1997 | United Technologies Corporation | Columnar zirconium oxide abrasive coating for a gas turbine engine seal system |
6192585, | Nov 04 1998 | VALEO ELECTRICAL SYSTEMS, INC | Ball nut and method of high volume manufacturing of same |
6209206, | May 15 1998 | CREDIT SUISSE, AS ADMINISTRATIVE AGENT | Method of producing split composite spherical bearing |
6210106, | Apr 30 1999 | General Electric Company | Seal apparatus for gas turbine engine variable vane |
6264369, | Jan 29 1999 | General Electric Company | Variable vane seal and washer materials |
6331509, | Jan 31 1997 | POLYGUARD PRODUCTS, INC | Corrosion resistant lubricants, greases, and gels |
6350060, | Mar 02 2000 | BEECHCRAFT CORPORATION | Dual load path spherical bearing and a method of coupling along a dual load path |
6352368, | Dec 18 1998 | MEDWAY UK LTD | Rod end bearing |
6358002, | Jun 18 1998 | United Technologies Corporation | Article having durable ceramic coating with localized abradable portion |
6368672, | Sep 28 1999 | General Electric Company | Method for forming a thermal barrier coating system of a turbine engine component |
6386763, | Jan 20 1999 | General Electric Company | Bushing for a jet engine vane |
6440580, | Dec 01 1998 | PPG Industries Ohio, Inc | Weldable, coated metal substrates and methods for preparing and inhibiting corrosion of the same |
6451454, | Jun 29 1999 | General Electric Company | Turbine engine component having wear coating and method for coating a turbine engine component |
6472075, | Sep 08 1999 | NGK SPARK PLUG CO , LTD | Sintered silicon nitride member and ceramic ball |
6474941, | Dec 08 2000 | General Electric Company | Variable stator vane bushing |
6481960, | Mar 30 2001 | General Electric Co. | Variable gas turbine compressor vane structure with sintered-and-infiltrated bushing and washer bearings |
6485830, | Sep 30 1999 | Kabushiki Kaisha Toshiba | Material for ceramic ball and method of manufacturing ceramic ball |
6508619, | Jul 06 2001 | Atlas Copco Energas GmbH | Expansion turbine for low-temperature applications |
6511945, | Oct 12 2001 | Höganäs AB | Lubricant powder for powder metallurgy |
6517583, | Jan 30 2000 | DIMICRON, INC | Prosthetic hip joint having a polycrystalline diamond compact articulation surface and a counter bearing surface |
6582190, | May 22 2000 | MITSUBISHI HEAVY INDUSTRIES ENGINE & TURBOCHARGER, LTD | Variable-capacity turbine |
6605160, | Aug 21 2000 | Repair of coatings and surfaces using reactive metals coating processes | |
6613462, | Jul 16 1997 | Dow Global Technologies, Inc | Method to form dense complex shaped articles |
6638609, | Nov 08 2000 | Sandvik Intellectual Property Aktiebolag | Coated inserts for rough milling |
6655845, | Apr 22 2001 | DIMICRON, INC | Bearings, races and components thereof having diamond and other superhard surfaces |
6660133, | Mar 14 2002 | Kennametal Inc.; KENNAMETAL INC | Nanolayered coated cutting tool and method for making the same |
6660405, | May 24 2001 | General Electric | High temperature abradable coating for turbine shrouds without bucket tipping |
6667262, | Sep 07 2001 | The United States of America as represented by the Secretary of the Navy | Self-lubricating ceramic composites |
6675478, | Nov 22 1999 | Minebea Co., Ltd. | Free spherical ball bearing |
6696392, | Mar 10 1999 | Rolls-Royce Corporation | Silicone resin bonded dry film lubricants |
6734147, | Jun 07 1995 | LCC County Mosquito Control | Lubricant compositions and methods |
20010016091, | |||
20010022934, | |||
20020058143, | |||
20020071760, | |||
20020154991, | |||
20020189722, | |||
20040037622, | |||
20040161639, | |||
20040217215, | |||
EP207915, | |||
EP286127, | |||
EP520520, | |||
EP620286, | |||
EP1336764, | |||
GB2421057, | |||
JP10008182, | |||
JP10130625, | |||
JP11131107, | |||
JP11242985, | |||
JP2000102630, | |||
JP2001044204, | |||
JP2001276523, | |||
JP2002270055, | |||
JP2003042354, | |||
JP2233575, | |||
JP4308328, | |||
JP4341503, | |||
JP5312168, | |||
JP5336693, | |||
JP59128992, | |||
JP60255255, | |||
JP7057748, | |||
JP7247487, | |||
JP8281332, | |||
JP9323191, | |||
WO100402, | |||
WO146324, | |||
WO9712999, | |||
WO9916565, |
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