anode and cathode separator plates are suitable for use in ion pumps for converting an input stream such as reformate into a pressurized and purified hydrogen-rich gas stream. The plates may include a single cathode outlet opening forming a portion of cathode output gas manifold, an anode inlet opening forming a portion of an inlet gas stream manifold and being sized larger than inlet cathode outlet opening, the distance of the anode inlet opening to an edge of the plate being less than the distance of the cathode outlet opening from an edge of the plate, and the size of the fluid flow channel of the anode separator plate being smaller than the size of the fluid flow channel of the cathode separator plate. Methods for forming the plates and infrastructure systems are also disclosed.
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41. A method for forming an anode separator plate for a hydrogen pump, the method comprising:
providing a planar member;
forming an anode inlet opening extending through the planar member to form a portion of an input stream gas manifold;
forming at least one fluid flow channel on a first surface of the planar member and connectable at one end to the anode inlet opening; and
forming a single cathode gas stream opening means for collecting purified and pressurized hydrogen gas from the input gas stream, the single cathode gas stream opening means extending through the planar member to form a portion of a cathode output manifold for exhausting hydrogen gas.
1. An anode separator plate for use in a hydrogen pump, said anode separator plate comprising:
a planar member comprising:
an anode inlet opening extending through said planar member forming a portion of an input gas stream manifold;
at least one fluid flow channel disposed on a first surface of said planar member and connectable at one end to said anode inlet opening; and
a single cathode gas stream opening means for collecting purified and pressurized hydrogen gas, said single cathode gas stream opening means extending through said planar member and defining a portion of a cathode output manifold for exhausting the purified and pressurized hydrogen gas.
59. A method for forming an anode separator plate for a hydrogen pump, the method comprising:
providing a planar member;
forming an anode inlet opening extending through the planar member and having a first size to form a portion of an input stream gas manifold;
forming an anode outlet opening extending through the planar member having a second size to form a portion of an outlet for discharging the input gas stream;
forming at least one fluid flow channel on a first surface of the planar member and connectable at one end to the anode inlet opening and at an opposite end to the anode outlet opening;
forming a single cathode gas stream opening means for collecting purified and pressurized hydrogen gas, the single cathode gas stream opening means extending through the planar member and having a third size to form a portion of a cathode output manifold for exhausting hydrogen gas, the third size is less than at least one of the first size and the second size;
the forming the anode inlet opening comprising forming the anode inlet opening a first distance from an edge of the planar member, the forming the single cathode gas stream opening means comprises forming the single cathode gas stream opening means a second distance from an edge of the planar member, and wherein the first distance is less than the second distance;
positioning the single cathode gas stream opening means adjacent to a first side of the planar member and positioning the anode inlet adjacent to a side different than the first side; and
forming a plurality of tie bolt openings extending through the planar member.
29. An anode separator plate for use in a hydrogen pump having a low-pressure input gas stream and a high-pressure output hydrogen gas stream, said anode separator plate comprising:
a planar member comprising:
an anode inlet opening extending through said planar member forming a portion of a low-pressure input gas stream manifold;
an anode outlet opening extending through said planar member forming a portion of an outlet for discharging the input gas stream;
at least one fluid flow channel disposed on a first surface of said planar member and connectable at one end to said anode inlet opening and at an opposite end to said anode outlet opening;
a single cathode gas stream opening means for collecting purified and pressurized hydrogen gas from the input gas stream, said single cathode gas stream opening means extending through said planar member and defining a portion of a high-pressure cathode output product gas stream manifold for exhausting the purified and pressurized hydrogen gas;
said anode inlet opening and said anode outlet opening comprising a first size, said cathode gas stream opening means comprising a second size, and wherein said first size being larger than said second size;
said anode inlet opening and said anode outlet opening disposed a first distance from an edge of said planar member, said cathode gas stream opening means disposed a second distance from an edge of said planar member, and wherein said first distance is less than said second distance;
said cathode gas stream opening means being disposed on a first side of said planar member and said anode inlet opening and anode outlet opening being disposed on a side different from said first side of said planar member; and
a plurality of tie bolt openings extending through said planar member.
2. The anode separator plate of
3. A hydrogen pump comprising:
said anode separator plate of
a cathode separator plate means for collecting purified and pressurized product gas;
an anode electrode disposed adjacent to said anode separator plate;
a cathode electrode disposed adjacent to said cathode separator plate;
a proton conducting medium disposed between said anode electrode and said cathode electrode; and
means for applying an electrical potential to the anode electrode and the cathode electrode to effect transfer of protons through said proton conducting medium from said anode electrode to said cathode electrode which protons form the purified and pressurized hydrogen gas.
4. A hydrogen fuel infrastructure system comprising:
said hydrogen pump of
a storage tank for storing purified hydrogen from said hydrogen pump; and
a reformer for supplying reformate to said hydrogen pump.
5. A method for producing pressurized hydrogen, the method comprising:
providing a low-pressure supply containing hydrogen to the hydrogen pump of
applying an electrical potential to the anode electrode and the cathode electrode;
transferring protons through the proton conducting medium from the anode electrode to the cathode electrode; and
receiving a high-pressure supply of purified hydrogen from the ion pump.
6. The method of
7. The ion pump of
8. The anode separator plate of
9. The anode separator plate of
10. The anode separator plate of
11. The anode separator phase of
12. The anode separator plate of
13. A hydrogen pump comprising:
said anode separator plate of
a cathode separator plate means for collecting purified and pressurized hydrogen gas;
an anode electrode disposed adjacent to said anode separator plate;
a cathode electrode disposed adjacent to said cathode separator plate;
a proton conducting medium disposed between said anode electrode and said cathode electrode; and
means for applying an electrical potential to the anode electrode and the cathode electrode to effect transfer of protons through said proton conducting medium from said anode electrode to said cathode electrode which protons form the purified and pressurized hydrogen gas.
14. The hydrogen pump of
a second planar member comprising:
a single cathode gas stream opening means for collecting purified and pressurized hydrogen gas from the input gas stream, said single cathode gas stream opening means extending through said second planar member forming a portion of the cathode output hydrogen gas stream manifold; and
at least one fluid flow channel for receiving purified and pressurized hydrogen gas, said at least one fluid flow channel disposed on a first surface of said second planar member and connectable at one end to said single cathode gas stream opening means.
15. The hydrogen pump of
16. The hydrogen pump of
17. The hydrogen pump of
18. The hydrogen pump of
19. The hydrogen pump of
20. The anode separator plate of
21. The anode separator plate of
22. A hydrogen fuel infrastructure system comprising:
said hydrogen pump of
a storage tank for storing purified hydrogen from said hydrogen pump; and
a reformer for supplying reformate to said hydrogen pump.
23. A method for producing pressurized hydrogen, the method comprising:
providing a low-pressure supply containing hydrogen to the hydrogen pump of
applying an electrical potential to the anode electrode and the cathode electrode;
transferring protons through the proton conducting medium from the anode electrode to the cathode electrode; and
receiving a high-pressure supply of purified hydrogen from the hydrogen pump.
24. The method of
25. The ion pump of
26. The anode separator plate of
27. The anode separator plate of
28. The anode separator plate of
30. A hydrogen pump comprising:
said anode separator plate of
a cathode separator plate means for receiving and collecting purified and pressurized hydrogen gas;
an anode electrode disposed adjacent to said anode separator plate;
a cathode electrode disposed adjacent to said cathode separator plate;
a proton conducting medium disposed between said anode electrode and said cathode electrode; and
means for applying an electrical potential to the anode electrode and the cathode electrode to effect transfer of protons through said proton conducting medium from said anode electrode to said cathode electrode which protons form the purified and pressurized product gas.
31. The hydrogen pump of
a second planar member comprising:
an anode inlet opening extending through said second planar member forming a portion of low-pressure input stream gas manifold;
an anode outlet opening extending through said second planar member forming a portion of an outlet for discharging the input gas stream;
a single cathode gas stream opening means for collecting purified and pressurized hydrogen gas from the input gas stream, said single cathode gas stream opening means extending through said second planar member forming a portion of the high-pressure cathode output hydrogen gas stream manifold for exhausting hydrogen gas;
at least one fluid flow channel for receiving purified and pressurized hydrogen gas, said at least one fluid flow channel disposed on a first surface of said second planar member and connectable at one end to said single cathode gas stream opening means;
said anode inlet opening and said anode outlet opening comprising a first size, said single cathode gas stream opening means comprising a second size, and wherein said first size is larger than said second size;
said anode inlet opening and said anode outlet opening disposed a first distance from an edge of said second planar member, said single cathode gas stream opening means disposed a second distance from an edge of said second planar member, and wherein said first distance is less than said second distance;
said single cathode gas stream opening means being disposed on a first side of said second planar member and said anode inlet opening and anode outlet opening being disposed on a side different from said first side of said second planar member; and
a plurality of tie bolt openings extending through said second planar member.
32. The anode separator plate of
33. The anode separator plate of
34. A hydrogen fuel infrastructure system comprising:
said hydrogen pump of
a storage tank for storing purified hydrogen from said hydrogen pump; and
a reformer for supplying reformate to said hydrogen pump.
35. A method for producing pressurized hydrogen, the method comprising:
providing a low-pressure supply containing hydrogen to the hydrogen pump of
applying an electrical potential to the anode electrode and the cathode electrode;
transferring protons through the proton conducting medium from the anode electrode to the cathode electrode; and
receiving a high-pressure supply of purified hydrogen from the hydrogen pump.
36. The method of
37. The ion pump of
38. The anode separator plate of
39. The anode separator plate of
40. The anode separator plate of
42. The method of
43. The method of
44. The method of
45. The method of
providing a second planar member;
forming an anode inlet opening extending through the second planar member and having a first size to form a portion of the input stream gas manifold;
forming a cathode gas stream opening means for collecting purified and pressurized hydrogen gas from the input gas stream, the single cathode gas stream opening means extending through the second planar member and having a second size to form a portion of the cathode output manifold for exhausting hydrogen gas; and
forming at least one fluid flow channel on a first surface of the second planar member and connectable at one end to the single cathode gas stream opening means.
46. The method of
47. The method of
48. The method of
49. The method of
50. The method of
51. The method of
52. The method of
53. The method of
providing a second planar member;
forming an anode inlet opening extending through the second planar member and having a first size to form a portion of the input stream gas manifold;
forming an anode outlet opening extending through the second planar member having a second size to form a portion of an outlet for discharging the input gas stream;
forming a single cathode gas stream opening means for collecting purified and pressurized hydrogen gas from the input gas stream, said single cathode gas stream opening means extending through the second planar member and having a third size to form a portion of the cathode output manifold for exhausting hydrogen gas, the third size is less than at least one of the first size and the second size;
forming at least one fluid flow channel on a first surface of the second planar member and connectable at one end to the single cathode gas stream opening means;
the forming the anode inlet opening comprising forming the anode inlet opening a first distance from an edge of the second planar member, the forming the single cathode gas stream opening means comprises forming the single cathode gas stream opening means a second distance from an edge of the second planar member, and wherein the first distance is less than the second distance;
positioning the single cathode gas stream opening means adjacent to a first side of the second planar member and positioning the anode inlet adjacent to a side different than the first side; and
forming a plurality of tie bolt openings extending through the second planar member.
54. The method of
55. The method of
56. The method of
57. The method of
58. The method of
60. The method of
61. The method of
62. The method of
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This invention relates generally to ion pumps, and more particularly, to separator plates and ion pumps for generating hydrogen and other gases.
Hydrogen is an important zero emission fuel. Recently, development of hydrogen fuel infrastructure systems has become a priority to support the use of hydrogen as a fuel.
An important part of a hydrogen fuel infrastructure system is generation of hydrogen. Two methods are generally used for generating hydrogen. One method for generating hydrogen includes an electrolysis process, which uses electrical energy to split water molecules into hydrogen and oxygen. Another method for generating hydrogen includes a reforming process, e.g., converting hydrocarbon fuel such as natural gas or propane into a hydrogen-rich gas.
In each of these methods, the product of the generation process is often an impure, low-pressure stream that contains hydrogen gas as one of many constituents. With either method, the hydrogen is often purified, dried, and/or compressed for use or storage.
There is a need for further improvements in separator plates and ion pumps for purifying and pressurizing gases such as hydrogen.
The present invention provides in a first aspect, an anode separator plate for use in an ion pump in which the anode separator plate includes a planar member comprising an anode inlet opening extending through the planar member forming a portion of an input gas stream manifold, at least one fluid flow channel disposed on a first surface of the planar member and connectable at one end to the anode inlet opening, and a single cathode outlet opening extending through the planar member forming a portion of a cathode output manifold.
The present invention provides in a second aspect, an anode separator plate for use in an ion pump having a low-pressure input gas stream and a high-pressure output gas stream in which the anode separator plate includes a planar member having an anode inlet opening extending through the planar member forming a portion of a low-pressure input gas stream manifold, at least one fluid flow channel disposed on a first surface of the planar member and connectable at one end to the anode inlet opening, a cathode outlet opening extending through the planar member forming a portion of a high-pressure cathode output gas stream manifold, and wherein the anode inlet opening comprises a first size, the cathode outlet opening comprises a second size, and the first size being larger than the second size.
The present invention provides in a third aspect, a cathode separator plate for use in an ion pump in which the cathode separator plate includes a planar member having a single cathode outlet opening extending through the planar member forming a portion of a cathode output gas stream manifold, and at least one fluid flow channel disposed on a first surface of the planar member and connectable at one end to the cathode outlet opening.
The present invention provides in a fourth aspect, a cathode separator plate for use in an ion pump having a low-pressure input gas stream and a high-pressure output gas stream in which the cathode separator plate includes a planar member having a cathode outlet opening extending through the planar member forming a portion of a high-pressure cathode output gas stream manifold, at least one fluid flow channel disposed on a first surface of the planar member and connectable at one end to the cathode outlet opening, an anode inlet opening extending through the planar member forming a portion of a low-pressure input gas stream manifold, and wherein the anode inlet opening comprises a first size, the cathode outlet opening comprises a second size, and wherein the first size being larger than the second size.
The present invention provides in a fifth aspect a pair of separator plates for use in an ion pump in which the pair of separator plates includes an anode separator plate and a cathode separator plate. The anode separator plate includes a planar member having an anode inlet opening extending through the planar member forming a portion of an input gas stream manifold, and at least one fluid flow channel disposed on a first surface of the planar member and connectable at one end to the anode inlet opening. The cathode separator plate includes a planar member having a cathode outlet opening extending through the planar member forming a portion of a cathode output gas stream manifold, and at least one fluid flow channel disposed on a first surface of the planar member and connectable at one end to the cathode outlet opening. The at least one fluid flow channel of the anode separator plate comprises a first distance between adjacent lands, the at least one fluid flow channel of the cathode separator plate comprises a second distance between adjacent lands, and wherein the first distance is less than the second distance.
The present invention provides in other aspects, ion pumps and hydrogen fuel infrastructure systems incorporating the above-mentioned plates.
The present invention provides in still other aspects, methods for forming the above-mentioned plates, and methods for producing pressurized hydrogen using ion pumps incorporating the above-mentioned plates.
The subject matter which is regarded as the invention is particularly pointed out and distinctly claimed in the concluding portion of the specification. The invention, however, may best be understood by reference to the following detailed description of various embodiments and accompanying drawings in which:
As described in greater detail below, the hydrogen pump is operable to convert the input stream such as reformate into a pressurized and purified hydrogen-rich gas stream. The pressurized and purified hydrogen-rich gas stream can be used directly in, e.g., a fuel cell (not shown), or can be stored in a pressurized gas container such as hydrogen storage unit 18. While the hydrogen generation system is described in conjunction with use in fuel cells, it will be appreciated by those skilled in the art that the hydrogen generating system may also be used in industrialization of processes which utilize gases (e.g., hydrogen and oxygen) for materials microstructure processing such as in the semiconductor industry.
As also described in greater detail below, the hydrogen pump in accordance with one aspect of the present invention may include anode separator and cathode separator plates having various features which result in a compact, efficient hydrogen pump operable to produce a pressurized and purified hydrogen-rich gas stream.
Hydrogen pump 16 is operable for separating, removing, and/or compressing pure hydrogen from an input supply containing hydrogen such as reformate. Exemplary hydrogen pump 16 may include an end plate 20, insulator plate 22, a collector plate 23, a collector pocket plate 24, a cathode separator plate 26, an electrochemical cell 27, anode support screen 138, an anode separator plate 28, a blind cooler blank plate 29, a collector pocket plate 30, a collector plate 32, an insulator plate 34, and an end plate 36.
With reference to
Anode separator plate 28 includes a fluid flow surface 132 with a plurality of flow channels 134 thereon. Flow channels 134 receive and conduct a low-pressurized input gas stream through an inlet and out an outlet which are in fluid communication with and open onto corresponding manifolds as described in greater detail below. Flow channels 134 may carry, for example, the input gas stream such as reformate, as well as a liquid, e.g., humidification.
Cathode separator plate 26 includes a plurality of flow channels 136 for collecting, for example, a pressurized and purified hydrogen-rich gas stream.
As described in greater detail below, the low-pressure input gas stream is provided to the anode side while the cathode side is driven to a higher pressure. To prevent the anode gas diffusion layer 126 from being crushed into the fluid flow channel 134, anode support screen 138, as shown in
Gaskets 128 and 129 may be employed to seal the electrical chemical cell from the various openings forming manifolds in the separator plates. Additional gaskets, shown in
With reference to
The fluid flow surface of anode separator plate 28 may include a plurality of serpentine flow channels 134 having equal length to result in an equal pressure drop during operation. A plurality of dive-through holes 212 and 222 may be provided to connect the anode inlet opening and the anode outlet opening, respectively, to the flow channels. Dive-through holes are described in U.S. Pat. No. 6,500,580 to Marvin, et al., entitled “Fuel Cell Fluid Flow Plate for Promoting Fluid Service”, the entire subject matter of which is incorporated herein by reference. The opposite side of the anode separator plate may be relatively flat, e.g., not including fluid flow channels.
With reference to
As there is only an output of product gas, a cathode inlet opening is not needed, i.e., only a single opening forming a portion of a manifold for the product gas stream is needed. One advantage of a single cathode outlet opening is that it results in an increase in the ratio of active area of the cathode separator plate compared to the total surface area of the cathode separator plate.
The cathode separator plate may also include straight parallel flow channels which cover the active area of the electrical chemical cell, and a dive-through hole region 332 (
The opposite side of cathode separator plate 26, best shown in
The various manifolds may be arranged with the cathode outlet manifold physically separated from the other manifolds to reduce the likelihood of the cathode outlet manifold leaking into the coolant or the input gas manifolds. In addition, leakage from the cathode outlet manifold, which is separated from the other manifolds, may be more easily detected. For example, for a generally square or rectangular separator plate, the cathode outlet opening may be positioned adjacent to one side of the separator plate and the anode inlet opening or anode outlet opening may be positioned adjacent to a different side, e.g., opposite sides, or on sides generally 90-degrees from each other.
From the present description, it will be appreciated by those skilled in the art that other configurations of the separator plates, manifolds, and flow channels may also be suitably employed which incorporate the features of the present invention. For example, coolant fluid flow channels may be provided on the rear side of the anode separator plate. In addition, the features of the present invention may be incorporated in bipolar separator plate, e.g., where the separator plate includes anode fluid flow channels on one side and cathode fluid flow channels on the other side. If radiative cooling is used, then coolant channels and manifolds may not be needed.
With reference again to
The end plates, for example, may be flat and about 1-inch or thicker. In addition, the end plate may be pre-stressed or pre-bended such that when the stack is at pressure, the end plate bends so that the surface presented to the inner side of the end plate is essentially flat. It is also possible that the end plates may contain a bladder device to create compression in a planar fashion. An example, of a suitable end plate is disclosed in U.S. Pat. No. 6,200,698 to Carlstrom, Jr., entitled “End Plate Assembly having a Two-Phase Fluid-Filled Bladder and Method for Compressing a Fuel Cell Stack,” the entire subject matter of which is incorporated herein by reference. Another option is to make the end plates large and place the tie bolts outside the plates, e.g., not through the plates.
The hydrogen pump may be operated with the input gas stream and the coolant maintained at low pressure and having a low pressure drop across the inlets and outlets thereby allowing use of a low energy blower for the input gas and a low energy pump for the coolant fluid.
In addition to the anode inlet opening and anode outlet opening being sized larger than the cathode outlet opening, due to the pressure difference between the low pressure anode input gas stream and high pressure output product gas stream, the anode separator plate (or at least the portion near the opening) need not be as strong as the cathode separator plate (or at least the portion near the cathode outlet opening). For example, the distance from the anode inlet and outlet openings to the edge of the anode separator plate may be less than the distance from the cathode output opening to the edge of the cathode separator plate. In one embodiment, the distance from the anode inlet and outlet openings to the edge of the anode separator plate may be about ½-inch or less and include a groove disposed therebetween for receiving a sealing gasket. The distance from the relatively small-sized cathode output opening to the edge of the cathode separator plate may be about 1-inch including a groove disposed therebetween for receiving a sealing gasket. As noted above, the cathode fluid flow channels from the cathode outlet opening to the cathode dive through holds may be narrower and shallower to reduce stress in this region of the cathode separator plate.
Advantages of the present invention also include achieving a smaller footprint or physical size for the hydrogen pump compared to conventional hydrogen pumps. For example, a hydrogen pump in accordance with the present invention was made with an active area of 353 cm2 having the same footprint as a conventional PEM fuel cell stack having an active area of 262 cm2. Thus, since the active area may be made larger, fewer plates are required, thereby reducing the material and labor in assembling fewer plates, gaskets, etc. compared to conventional hydrogen pumps. In addition, tests of the cathode separator plate formed from a compression molded material resulted in the shallow narrow fluid flow channels (
In operation of the hydrogen pump, the anode input gas stream may be provided at about 1 psi to 2 psi and with the coolant fluid provided at about 10 psi. A pressurized and purified hydrogen-rich gas stream may be provided at 600 psi. The PEM-type hydrogen pump is desirably suitably cooled to operate at a temperature between about 20 degrees Celsius, i.e., ambient, and about 110 degrees Celsius, and preferably between about 70 degrees Celsius and about 110 degrees Celsius.
A hydrogen pump in accordance with the present invention was tested with a cathode pressure of 400 psi. It was noted that a conventional stack design having a 262 cm2 active area is operable to only about 250 psi without additional clamping. The hydrogen pump also exhibited higher failure pressures of 25 percent to 110 percent than the failure pressures of a conventional hydrogen pump having a 262 cm2 active area. The hydrogen pump also withstood higher loading forces without breakage of the plates due to the tie bolts passing through the plates and reducing bending moments which normally occur if the tie bolts are disposed outside the plates.
When the proton conducting electrochemical cell is operated in a hydrogen pumping mode, an input supply containing hydrogen is supplied to the anode side and a voltage potential is applied to the electrodes to cause proton pumping across the proton conducting medium. Hydrogen moves from the input stream to the porous hydrogen permeable anode electrode where the hydrogen gas forms protons (H+) and electrons. It is believed that the protons are then driven across the proton conducting medium and conducted through the nonporous hydrogen permeable cathode electrode. Molecular hydrogen is then generated in a relatively pure form on the cathode side, i.e., the output side of the electrode.
In an alternative embodiment of the present invention, a solid oxide electrolyte (e.g., zirconium oxide) may be used for the electrochemical cell. In this embodiment, the ion pump would operate in pumping oxygen and/or purifying oxygen.
In addition to the proton conducting medium including a proton exchange membrane (PEM) such as a NAFION perfluorosulfonic acid polymer membrane (available from E. I. DuPont de Nemours and Co., Wilmington, Del., USA), other proton conducting mediums may be employed such as a polybenzimidazole (PBI) polymer membrane, a polyetheretherketones (PEEK), sulfonated polysulfones, a polyimide, a hydrocarbon membrane, a polytrifluoro-styrenesulfonic acid, variations of perfluorosulfonic acid membranes, other polymeric or non-polymeric proton conductors including any strong acids. The proton conducting medium may also include solid anhydrous (e.g., not having water) proton conducting mediums, for example, solid state conductors such as inorganic and ceramic based systems, perovskite ceramics, solid-acids such as cesium dihydrogen phosphate (CsH2PO4), or other suitable solid anhydrous proton conducting mediums. Depending on the proton conducting membrane, humidification of the input gas steam may not be required. Also, depending on the proton conducting medium, the resulting pressurized and purified hydrogen-rich gas stream may also be dry as well, e.g., not contain water.
Still other alternative embodiments may include positioning a cathode outlet opening (and manifold) in the center of the separator plate to capture over-board leakage. In addition, the anode side of the cell may be operable with an input gas stream in a gas phase and provided with features to prevent blockage of water. The cathode side of the cell may be a “gas evolution” electrode.
While various embodiments of the present invention have been illustrated and described, it will be appreciated by those skilled in the art that many further changes and modifications may be made thereunto without departing from the spirit and scope of the invention.
McElroy, James F., Ballantine, Arne W., Gordon, Michael P., Kirchhoff, David C.
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Sep 28 2004 | Honda Motor Co., Ltd. | (assignment on the face of the patent) | / | |||
Feb 23 2005 | KIREHHOFF, DAVID C | HONDA MOTOR CO , LTD | ASSIGNMENT OF ASSIGNORS INTEREST SEE DOCUMENT FOR DETAILS | 015894 | /0205 | |
Feb 23 2005 | MCELROY, JAMES F | HONDA MOTOR CO , LTD | ASSIGNMENT OF ASSIGNORS INTEREST SEE DOCUMENT FOR DETAILS | 015894 | /0205 | |
Feb 23 2005 | GORDON, MICHAEL P | HONDA MOTOR CO , LTD | ASSIGNMENT OF ASSIGNORS INTEREST SEE DOCUMENT FOR DETAILS | 015894 | /0205 | |
Mar 03 2005 | BALLANTINE, ARNE W | HONDA MOTOR CO , LTD | ASSIGNMENT OF ASSIGNORS INTEREST SEE DOCUMENT FOR DETAILS | 015894 | /0205 |
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