A process and apparatus for making a shingle, together with the shingle made thereby, is provided, in which one or more thermoplastic materials are extruded or co-extruded to form an extrudate, with the extrudate being cut into a preliminary shingle shape, which is allowed to dissipate heat, and then is delivered to a compression mold, wherein the preliminary shingle shape is compression molded to substantially its final dimensions and is then discharged from the mold and allowed to cool.
|
1. A process of making shingle or tile products comprising the steps of:
(a) co-extruding heated, unshaped thermoplastic materials from molten states in a co-extruder and discharging those unshaped thermoplastic materials from a mouth of the co-extruder into a formed, continuous shaped extrudate that includes a core material with a capstock product surfacing material on and adhered directly to at least a portion of a major surface of the core material of the continuous shaped extrudate and then directly cutting the extrudate into a plurality of preliminary product shapes while the preliminary product shapes are above a solidification temperature;
(b) then delivering the preliminary product shapes serially along a path while allowing the preliminary product shapes to cool an amount that maintains the temperature of the preliminary product shapes above a solidification temperature;
(c) then delivering the cooled but still non-solid preliminary, product shapes to a compression mold;
(d) molding the preliminary product shapes in the mold by compression molding the preliminary product shapes to substantially their final product dimensions and controlling internal stress development of the product shapes in the mold by having the capstock product surfacing material being at a greater temperature in the mold than the temperature of the core material in the mold; and
(e) then discharging the molded products from the mold and allowing the molded products to cool to a solid state;
wherein the compression molding step includes causing the capstock product surfacing material to flow over at least one edge of the core material to cover that edge in each molded product.
2. The process of
3. The process of
4. The process of
5. The process of
6. The process of
7. The process of
8. The process of
9. The process of
10. The process of
11. The process of
13. The process of
14. The process of
15. The process of
16. The process of
|
This application is a continuation-in-part of U.S. patent application Ser. No. 10/452,059, filed Jun. 2, 2003, the complete disclosure of which is herein incorporated by reference.
In the art of making roofing shingles and tiles for exterior application in the building industry, various approaches have been made toward making shingles and tiles that are manufactured, but give the appearance of being made of traditional natural materials, such as wood cedar shakes, tiles, slate, etc.
In many instances, such shingles and tiles are made of bitumen coated mat having granules on the exterior surface, with the granules being provided in various designs, shades, color configurations, etc., to yield various aesthetic effects.
It is also known, in making roofing shingles and tiles, to mold them to the desired shape by various molding techniques. The materials that are used in such molding techniques usually include inexpensive filler material, in order to achieve low production costs.
Some such filler materials can be various waste products, such as carbon black, recycled rubber and tire crumb, coal fines, pulp and paper waste and other inexpensive materials.
Such products are often made by molding multi-component formulations, which comprise blends of virgin and recycled polymers and various low-cost fillers.
The use of large quantities of such fillers reduces the mechanical properties of the ultimate product, however. Additionally, the use of large quantities of fillers limits the color variations that are possible in the products and makes the processing of the formulations into shingles and tiles very difficult.
Typically, roofing shingles and tiles made of such material having waste for filler do not provide good weather resistance for the products. Additionally, the warranty periods that can reasonably be provided for such products tend to be short in duration.
Furthermore, such building industry roofing products have relatively low impact strength, especially at low temperatures. Insofar as their available colors are concerned, such tend to be limited to the colors gray and black.
Additionally, molding operations tend to be capital intensive, with relatively high manufacturing costs, although molding techniques do provide a high level of definition or dimension control. Also, there is a disadvantage to molding techniques, in general, in that the length of the cycle for injecting material into the mold, molding to the desired shape, and ejecting the shape from the mold is largely a function of the time required to cool the molten thermoplastic material before it can be removed from the mold. However, the temperature of the thermoplastic material must be sufficiently high that it can flow and fill the cavity within the constraints of the material and equipment (i.e. material characteristics, melt pressures, mold clamping pressures, etc.). While modifications can be made to the materials to help the flow characteristics and thereby lower the required melt temperature, and while improvements can be made to the mold to increase heat transfer and removal, cooling remains the longest part of the cycle for these processes. In order to achieve the necessary cooling, the time required causes a lengthening of the manufacturing cycle, which increases the capital costs of investment in molds and machinery for a required output, thereby substantially increasing manufacturing costs.
The present invention is directed to a process of making a shingle having a desired configuration, by a combination of extruding and molding, in order to reduce the time required for the molding operation. As used throughout the application, “shingle” should be considered to embrace “tile” also.
It is a further object of this invention to accomplish the above object by co-extruding the shingle to include a core material with a shingle capstock material on a major surface.
It is a further object of this invention to accomplish the above objects, in which the extruding step is a continuous process, and in which the extrudate is serially cut into discrete preliminary shingle shapes, prior to molding those shapes into the final shingle shape.
Additional objects of this invention include producing shingles by the processes described above.
Further objects of this invention include providing apparatus for accomplishing the processes for producing shingles as described above.
Other objects and advantages of the present invention will be readily apparent upon a reading of the following brief descriptions of the drawing figures, detailed descriptions of the preferred embodiments, and the appended claims.
Referring now to the drawings in detail, it will be seen that, in accordance with this invention, the shingle or tile will first be pre-shaped by extruding a cross-section that will be generally similar to the finished cross-section of the shingle or tile, with the pre-shaped or preliminary shingle shape then being allowed to cool somewhat prior to placement of it in the mold. By first getting the preliminary shingle shape to conform closely to the final shingle shape before placing it in the mold, long flow distances and hence higher material temperatures are avoided. The material in the mold is then compression molded to achieve its final dimensions. Because significant amounts of heat are removed prior to placement of the preliminary shingle shape into the mold, very short cooling cycles are achieved.
In another embodiment, the amount of cooling is minimized prior to placement in the mold. In this way, significant amounts of heat do not need to be provided, thus the shortened cooling cycle is obtainable. Also, higher molecular weight polymeric materials with higher viscosities and better polymer performance properties, which would not normally be useful in a molding operation such as injection molding, can be used, because the shape of the precursor is close to that of the molded piece and the amount of material flow necessary to produce the desired finished shingle shape is minimal.
Referring now to
It will be seen that in the embodiment of
With reference now to
The other details of the apparatus as shown in
The conveyor will preferably have a take-off speed that is matched to the extrusion speed, such that after extrusion of a given length, the cutting is effected by the guillotine or the like, and the speed of the conveyor can be controlled. Alternatively, two conveyors may be disposed serially, with the speed of the upper run of the first conveyor being accelerated to deliver the shapes to the second conveyor after cutting, with the speed of the first conveyor then being re-set to match the extrusion speed of extrudate leaving the extruder, with the second conveyor being controlled for delivery of the shapes to the mold. Alternatively, rather than having the delivery being automatic, the same could be done manually, if desired.
Thus, with reference to
It will be noted that the preliminary shingle shapes 46 that are co-extruded as shown in
Referring now to
It will be noted that the extrusion and co-extrusion processes described above are continuous processes, and that the severing of the extrudate of whichever form by the guillotine is a serial, or substantially continuous process, and that the delivering of the preliminary shingle shapes from the extruder or co-extruder along the conveyor belt allows for the dissipation of heat resulting from the extrusion process, from the preliminary shingle shapes, in that, by allowing the shapes to substantially cool prior to placing them in the mold, rather than requiring the cooling to take place completely in the mold itself, reduces the required time for residence of the shapes in the mold during the compression process, as will be described hereinafter.
It will also be noted that maintaining the temperature above a melting temperature so that a quick flow of the melt can occur in the mold is desired in some embodiments. This maintaining of temperature above a crystallization or solidification temperature can minimize the development of internal stresses within the preliminary shingle shapes that could be caused by deformation of polymers that have begun to enter the solid state.
As the preliminary shingle shapes approach the right-most end of the conveyor belt as shown in
The mold generally designated 71 in
The closing of the mold can be done, at a force of, for example, 40 tons, in order to cause a material flow out on the edges of the shingle being molded, for 3-4 seconds, with the entire molding process as shown in
The two mold components 68 and 70, when moved from the closed position on table 74 shown at the right end of
The ram mechanism 72, itself, is comprised of a base member 80 and a compression member 81, and the member 81 carries the ram 75. The compression member 81 also moves vertically upwardly and downwardly, via its own set of guide rods 82, in the direction of the double-headed arrow 83, and is suitably driven for such vertical movement by any appropriate means, such as hydraulically, pneumatically, electrically (not shown).
With reference now to
The indexable table 74 is rotatably driven by any suitable means (not shown), to move mold assemblies 71 into position for delivering them to and from the ram station 72 as discussed above. In this regard, the indexable table 74 may be moved in the direction of the arrows 86.
If desired, in order to facilitate cooling, cooling coils may be embedded in, or otherwise carried by the table 74, such coils being shown in phantom in
Similarly, coolant coils are shown in phantom at 91 in
Upon the shapes 33 or 46 entering the mold, they may have a surface temperature of 300° F.-320° F., with the temperature being hotter in the center of the core material. Upon leaving the mold, the surface temperature of the shapes will normally be in the range of 80° F.-85° F.
Within the mold, it is preferable to heat the top mold component 68 (which will preferably engage the capstock material) to a slightly greater temperature than that of the bottom component 70, in order to control internal stress development. For example, the top component 68 may be heated to 120° F., for example, with the bottom component being heated to 70-80° F. The subsequent cooling for the top plate 68 could be a natural cooling by simply allowing heat to dissipate, and the bottom plate can be cooled, for example, by well water, at about 67° F. Alternatively, well water or other coolant could be circulated, first through the bottom component 70 and then to the top component 68, however, in some instances it can be preferable to cool both components 68 and 70 to the same temperature. It will also be understood that various other cooling techniques can be employed to regulate temperature at various locations in the mold, depending upon the thickness of the shingle being molded, in various locations of the shingle being molded, as may be desired.
At one of the stations shown for the indexable table 74, a lifting mechanism 95 may be provided, for opening the molds 71, one at a time. A typical such lifting mechanism may include a hydraulic or pneumatic cylinder 96, provided with fluid via fluid lines 97, 98, for driving a piston 100 therein, which carries a drive shaft 101 that, in turn, carries an electromagnet 102 for engaging the cap 78 of the upper mold component 68, as the drive shaft 101 is moved upwardly or downwardly as shown by the double-headed arrow 103.
The closing of the components 68 and 70 relative to each other could alternatively be done under a force of 30 tons, rather the 40 tons mentioned above, in order to obtain a consistent closing and flow of material. Alternatively, the closing could begin at a high speed, and then gradually slow down, in order get an even flow at an edge of the shape that is being formed into a shingle.
When the mold 71 is in the open position shown in
Similarly, spring pins 104 engage “flashing”, or other material that has been cut away from the periphery of the formed shingle, for pushing the same out of the trench 110 that surrounds the cavity 108 in the lower mold component 70.
As shown in
Both the upper and lower mold cavities 111 and 108 are preferably provided with protrusions 112, 113, respectively, which protrusions will form reduced-thickness nailing or fastening areas in the compression molded shingle, as will be described hereinafter.
With the fully formed shingle as shown in
Thereafter, the indexable table 74 may be moved, for delivery of a next adjacent mold to the station for engagement by the lift mechanism 95, with the table 74, generally being rotatable on a floor 118, as allowed by a number of table-carrying wheels 120.
Referring now to
There are also a plurality of mold recesses or protrusions 127 as may be desired, to build into the shingle 117 the appearance of a natural slate, tile or the like. It will be understood that the number and style of the recesses/protrusions 127 will be varied to yield a natural-appearing shingle having the desired aesthetics.
In the tab or butt portion of the shingle 126, there is a gradually sloped reduced-thickness portion 128 that appears in
With reference to
The spring pins 104, 105, and the trough 110 and mold depression 108, respectively, as described previously, are also shown in
It will thus be seen that the two mold components 68 and 70 are thus adapted to compression mold a shingle such as that which is shown by way of example only, in
The shingle of
It will also be noted that there are nailing or other fastener reduced-thickness portions 136, in the shingle of
With reference now to
It will thus be seen that the skin or capstock material 134 can substantially encapsulate the tab or butt portion of the shingle of
In another embodiment, the skin or capstock material can substantially encapsulate the entire top surface of the shingle 130, the core material comprising a majority of the volume of the shingle 130. In this embodiment portions of an underlying shingle between a pair of adjacent shingles in an overlying course are protected with the more durable skin or capstock material.
It will be understood that the core is preferably constructed of an inexpensive material, and that the capstock is preferably constructed of a material, such as but not limited to, a polymer having a high weather resistance and the ability to be colored in various colors, as well as desirable ultraviolet characteristics. In this case where a capstock also covers the upper portion or headlap area of the top surface of the shingle 130, the capstock on the upper portion may be of the same or different color or appearance as that covering the lower portion 134.
It will also be understood that the shingle 130 may be constructed in various other configurations, to have edges that are segmented, scalloped or the like, or as may be desired. The relief areas 133 may comprise lines, grooves, or seemingly random relief, as may be desired, all to give the appearance of natural material such as slate, tile, cedar shake or the like. It will also be apparent that the shingles or tiles 130 may be constructed of various sizes as may be desired.
With reference to
The core material will generally be of greater thickness than the skin material and will preferably be comprised of a highly filled polymer. The skin material will preferably be comprised of a polymer having high weather resistance and the ability to be colored in various colors as may be demanded by building designers.
The relative thickness of the capstock material to that of the core material can be about 10%, although, if additional capstock thickness is desired, one can increase this relative thickness up to about 20%. The minimum thickness of the capstock material should be on the order of about 4 mils, and the range for the same could be from about 4 mils up to about 10 mils. In some instances, a 5% ratio of capstock material to the total thickness of the shingle can suffice, such that the capstock material would comprise 5% of the total thickness, with the core material comprising 95% of the total thickness of the shingle.
It will also be understood that variations can be made in the mold design, by varying angles, radiuses and the like to avoid excessive thinning of the capstock material, all with a view toward controlling the capstock coverage of the core material, not only on the major surfaces, but also at the edges. Mold design can also be used to provide recesses or indentations in the lower surface of the shingle, thus allowing lesser amounts of material to be used.
By combining a skin material with a core material, such allows an economic advantage in that a greater amount of filler may be used to comprise the core, which will be of less expense than the material that comprises the skin, without providing undesirable surface properties for the skin, and without limiting the aesthetics of the product, because the core is, at least partially, encapsulated in an aesthetically pleasing and weatherable skin. Additionally, the core can be comprised of a foam or microcellular foam material where reduced weight for the product is desired.
In some embodiments the shingle or tile is comprised of a core that is made of a low molecular weight material such as polypropylene filled with 40-80% by weight of recycled ash with suitable functional additives, encapsulated in a skin comprised of a film.
Such fillers for the core material can vary considerably and can be chosen from a group that includes, as examples, treated and untreated ashes from incinerators of power stations, mineral fillers and their waste, pulp and paper waste materials, oil shale, reclaimed acrylic automotive paint and its waste and/or mixtures of any of these, or the like.
The skin can be chemically cross-linked to increase its mechanical properties and weather resistance and/or flame resistance and can contain functional additives such as pigments, UV light stabilizers and absorbers, photosensitizers, photoinitiators etc. The cross-linking may occur during or after processing of the material. Such cross-linking can be effected by means which include, but are not limited to, thermal treatment or exposure to actinic radiation, e.g. ultraviolet radiation, electron beam radiation, gamma radiation, etc.
By way of example, the skin material is selected from a group of thermoplastic materials comprising Polyolefins such as thermoplastic olefins, Polyethylene (PE), Polypropylene (PP), Polymethylpentene (PMP), Ethylene Acrylic Acid (EAA), Ethylene Methacrylic Acid (EMAA), Acrylonitrile Styrene Acrylate (ASA), Acrylonitrile Ethylene Styrene (AES) and Polybutene (PB-1), their copolymers, blends, and filled formulations, other polymers having high weather resistance such as Polyacrylates and fluoropolymers and/or their copolymers blends and filled formulations. The skin material is preferably stabilized for UV-light and weathering resistance by using additives and additive packages known in the state-of-the-art to be efficient. In addition, the skin materials may also contain various additives such as thermal and UV-light stabilizers, pigments, compatibilizers, processing aids, flame retardant additives, and other functional chemicals capable of improving processing of the materials and performance of the product. Foaming agents such as azodicarbonamide may be used to reduce the density of the skin material.
By way of example, the core material may be selected from the group comprising of virgin thermoplastic polymer materials and elastomers and rubber including but not limited to Polyvinylchloride (PVC), Polyethylene (PE), Polypropylene (PP), Polybutene (PB-1), Polymethylpentene (PMP), Polyacrylates (PAC), Polyethyleneterephthalate (PET), Polybutyleneterephthalate (PBT), Polyethylenenaphthalate (PEN), Ethylene-Propylene-Diene Monomer Copolymers (EPDM), Styrene Butadiene Styrene (SBS), Styrene Isoprene Styrene (SIS), Acrylonitrile Butadiene Styrene (ABS), or Nitrile Rubber, their copolymers, binary and ternary blends of the above, and filled formulations based on the above and other thermoplastic materials and elastomers with mineral, organic fillers, nanofillers, reinforcing fillers and fibers as well as recycled materials of the above polymers.
From the cost point of view, recycled and highly filled thermoplastic materials and recycled rubber (for example from tires) are preferable. The content of mineral fillers can be in the weight range from 5% to 80%.
In addition, the core materials may also contain various additives such as thermal and ultraviolet (UV) light stabilizers, pigments, compatibilizers, processing aids, flame retardant additives, and other functional chemicals capable of improving processing of the materials and performance of the product. Some flame retardants known to have negative effects on weather resistance of polymers can still be effectively used in the core material, the skin or capstock layer serving to protect the shingle from the effects of the weather. Chemical foaming agents such as azodicarbonamide may be used to reduce the density of the core material. Physical blowing agents, glass bubbles or expanded polymer microspheres may also be used to adjust the density of the core material.
In making the products of this invention, the single layer 152 of skin or combined upper and lower layers 152 and 153, of the skin may comprise from 1% to 40% of the total thickness of the product, with the core inside the skin being thicker between upper and lower surfaces and comprising the remaining percentage of the total thickness of the product.
Examples of making shingles in accordance with this invention are as follows.
Pellets of a flexibilized polypropylene copolymer, 18S2A, available from Huntsman Chemical, Salt Lake City, Utah, were combined in a Werner Pfleiderer twin screw extruder with calcium carbonate, Hubercarb Q3, available from J. M. Huber Corporation, Atlanta, Ga., and a stabilizer package, FS-811, available from Ciba Specialty Chemicals, Tarrytown, N.Y., using gravimetric feeders to obtain a mixture that was 49.25 wt % polypropylene, 50 wt % calcium carbonate and 0.75% stabilizer package. This mixture was extruded as a strand and chopped into pellets of filled polypropylene for later processing.
Pellets of Example 1 were dried and fed into a single screw extruder, MPM 3.5 inch in diameter, 24:1 L/D, equipped with a flex lip die and extruded to form a sheet. The die was adjusted to produce an extrudate that was about 19 inches in width and having a profile with varying thickness across the sheet ranging from about 0.375 inches to 0.245 inches. The sheet was extruded onto a first conveyor belt having variable speed matched to the extrudate speed. The temperature of the sheet was about 380 F when exiting the die.
When a section of sheet 13 inches in length had been extruded, the sheet was cut from the die lip. While still hot, the section of 19″×13″ sheet was carried to a second conveyor belt and transferred to and centered on the lower plate of a mold having a size of 18″×12″. Infrared lamps were provided above the conveyor to maintain the temperature of the sheet during transfer. On reaching the lower mold plate, the surface temperature was about 300 F. The upper portion of the mold, having a surface texture designed to represent the surface texture of a natural slate, was brought into contact with the sheet on the lower plate and the mold was closed in a platen press with 20 tons pressure to shape and form the sheet, with a slight excess of material being squeezed out of the mold.
Cooling was applied to the mold by means of water circulating cooling lines in the mold plates to cool the formed sheet to a solid state. After about 1 minute, the mold was opened to release a short cycle compression molded synthetic roofing tile. The synthetic roofing tile had cooled to a surface temperature of about 80 F on the side that had been in contact with the bottom plate and to temperature of about 120 F on the surface that had been molded by the top plate of the mold set. Excess material and flashing were cut off of the tile.
Pellets of a flexibilized polypropylene copolymer, 18S2A, available from Huntsman Chemical, Salt Lake City, Utah, were combined in a Werner Pfleiderer twin screw extruder with calcium carbonate, Hubercarb Q3, available from J. M. Huber Corporation, Atlanta, Ga., using gravimetric feeders to obtain a mixture that was 50 wt % polypropylene and 50 wt % calcium carbonate. This mixture was extruded as a strand and chopped into pellets of filled polypropylene for later processing.
Pellets of a flexibilized polypropylene copolymer, 1 8S2A, available from Huntsman Chemical, Salt Lake City, Utah, were combined in a Werner Pfleiderer twin screw extruder with calcium carbonate, Hubercarb Q3, available from J. M. Huber Corporation, Atlanta, Ga., and a stabilizer package, FS-811, available from Ciba Specialty Chemicals, Tarrytown, N.Y., using gravimetric feeders to obtain a mixture that was 79.25 wt % polypropylene, 20 wt % calcium carbonate and 0.75% stabilizer package. This mixture was extruded as a strand and chopped into pellets of filled polypropylene for later processing.
Pellets of filled polypropylene from Example 3 were dried and fed into a first single screw extruder, MPM 3.5 inch in diameter, 24:1 L/D, to provide core material. Separately, dried pellets of filled polypropylene from Example 4 and pellets of gray toner 60Z2274 available from Penn Color, Doylestown, Pa., were fed using gravimetric feeders to obtain a ratio of 2 wt % gray toner to 98 wt % filled polypropylene into a second extruder, Prodex 2.5 inch in diameter 24:1 L/D, to provide capstock material. The output of both extruders was fed through an adapter block and a dual layer coextrusion block to a flex lip die and coextruded to produce a sheet having a core of material from the first extruder bonded with a coextruded capstock provided by the second extruder, with the layer of capstock covering the top surface of the layer of core material.
The die was adjusted to produce an extrudate that was about 19 inches in width and having a profile with varying thickness across the sheet ranging from about 0.375 inches to 0.245 inches. The relative rates of extrusion from the two extruders for the capstock and the core layers were controlled such that the capstock thickness was about 10% of the total thickness of the composite sheet, The sheet was extruded onto a first conveyor belt having variable speed matched to the extrudate speed. The temperature of the sheet was about 380 F when exiting the die,
When a section of sheet 13 inches in length had been extruded, the sheet was cut from the die lip. While still hot, the section of 19″×13″ sheet was carried to a second conveyor belt and transferred to and centered on the lower plate of a mold having a size of 18″×12″. Infrared lamps were provided above the conveyor to maintain the temperature of the sheet during transfer. On reaching the lower mold plate, the surface temperature was about 300 F. The upper portion of the mold, having a surface texture designed to represent the surface texture of a natural slate, was brought into contact with the sheet on the lower plate and the mold was closed in a platen press with 20 tons pressure to shape and form the sheet, with a slight excess of material being squeezed out of the mold. The flow of material at the edges of the mold was such that the capstock thickness at the molded edges of the shape was maintained to be least 4 mils over the entire top surface of the piece, even at the edges.
Cooling was applied to the mold by means of water circulating cooling lines in the mold plates to cool the formed sheet to a solid state. After about 1 minute, the mold was opened to release a short cycle compression molded synthetic roofing tile having a core layer and a capstock layer. The synthetic roofing tile had cooled to a surface temperature of about 80 F on the side that had been in contact with the bottom plate and to temperature of about 120 F on the surface that had been molded by the top plate of the mold set. Excess material and flashing were cut off of the tile.
Dried pellets of filled polypropylene from Example 3 were fed into a first single screw extruder, MPM 3.5 inch in diameter, 24:1 L/D, to provide core material. Separately, dried pellets of filled polypropylene from Example 4, pellets of gray toner 60Z2274 and black accent color pellets 68B282, available from Penn Color, Doylestown, Pa., were fed using gravimetric feeders to obtain a ratio of 2 wt % gray toner, 1 wt % accent color pellet, and 97 wt % filled polypropylene into a second extruder, Prodex 2.5 inch in diameter 24:1 L/D, to provide capstock material. The output of both extruders was fed through an adapter block and a dual layer coextrusion block to a flex lip die and coextruded to produce a sheet having a core of material from the first extruder bonded with a coextruded capstock provided by the second extruder, with the layer of capstock covering the top surface of the layer of core material.
The temperatures in degrees Fahrenheit of the zones of the capstock extruder, the adapter, the coextrusion block and the die are noted below:
Barrel zone
Adapter zone
Co-Ex
Die zone
1
2
3
4
1
2
3
block
1
2
3
320
330
330
330
370
375
375
375
375
375
375
The die was adjusted to produce an extrudate that was about 19 inches in width and having a profile with varying thickness across the sheet ranging from about 0.375 inches to 0.245 inches. The relative rates of extrusion from the two extruders for the capstock and the core layers were controlled such that the capstock thickness was about 10% of the total thickness of the composite sheet. The sheet was extruded onto a first conveyor belt having variable speed matched to the extrudate speed. The temperature of the sheet was about 380 F when exiting the die.
When a section of sheet 13 inches in length had been extruded, the sheet was cut from the die lip. While still hot, the section of 19″×13″ sheet was carried to a second conveyor belt and transferred to and centered on the lower plate of a mold having a size of 18″×12″. Infrared lamps were provided above the conveyor to maintain the temperature of the sheet during transfer. On reaching the lower mold plate, the surface temperature was about 300 F. The upper portion of the mold, having a surface texture designed to represent the surface texture of a natural slate, was brought into contact with the sheet on the lower plate and the mold was closed in a platen press with 20 tons pressure to shape and form the sheet, with a slight excess of material being squeezed out of the mold. The flow of material at the edges of the mold was such that the capstock thickness at the molded edges of the shape was maintained to be least 4 mils over the entire top surface of the piece, even at the edges.
Cooling was applied to the mold by means of water circulating cooling lines in the mold plates to cool the formed sheet to a solid state. After about 1 minute, the mold was opened to release a short cycle compression molded synthetic roofing tile having a core layer and a variegated capstock layer, the capstock having a base gray color with gray-black accent streaks simulating the color appearance of natural slate. The synthetic roofing tile had cooled to a surface temperature of about 80 F on the side that had been in contact with the bottom plate and to temperature of about 120 F on the surface that had been molded by the top plate of the mold set. Excess material and flashing were cut off of the tile.
Example 7 was prepared similarly to Example 6, except that the gray toner 60Z2274 was omitted from the capstock and the capstock composition was metered to include 1 wt % of the accent color pellet and 99 wt % of the filled polypropylene of Example 3. The short cycle compression molded synthetic roofing tile having a core layer and a variegated capstock layer was produced, the capstock having a light color with gray-black accent streaks simulating the color appearance of natural slate.
Example 8 was prepared similarly to Example 6, except that the temperature profile of the capstock extruder was at a slightly higher temperature as shown in the table below.
Barrel zone
Adapter zone
Co-Ex
Die zone
1
2
3
4
1
2
3
block
1
2
3
350
350
350
350
370
375
375
375
375
375
375
The synthetic roofing tile having a core layer and a capstock layer was produced, the capstock having an even gray color, the accent color pellets having melted out into the mixture in the extruder.
Example 9 was prepared similarly to Example 6, except that a different accent color pellet, 60B281, available from Penn Color, was used with a capstock composition metered to 2 wt % gray toner 60Z2274, 2 wt % accent color pellet 60B281 and 96 wt % filled polypropylene of Example 3. The 60B281 had a higher softening temperature than the accent color pellet used in Example 6, so the temperature profile in the capstock extruder was modified as noted in the table below.
Barrel zone
Adapter zone
Co-Ex
Die zone
1
2
3
4
1
2
3
block
1
2
3
390
390
400
380
370
375
375
375
375
375
375
In the synthetic roofing tile of Example 9, having a core layer and a capstock layer, the capstock had a base gray color, but also had gray-black spots where the accent color pellets had not melted sufficiently during the processing to produce the streaking effect.
It will be apparent from the foregoing that various other modifications may be made in the process steps of this invention, in the apparatus, or in the resultant roofing shingle or tile of this invention, all within the spirit and scope of the invention as defined in the appended claims.
MacKinnon, Thomas Kevin, Dodd, Robert E., Kim, Joong Youn, Wylie, Douglas H.
Patent | Priority | Assignee | Title |
10544590, | Mar 15 2013 | CertainTeed Corporation | Synthetic starter tile for an angled roof interface |
7934346, | Mar 29 2007 | CertainTeed Corporation | Process of treating a synthetic shingle and shingle made thereby |
8142587, | May 05 2009 | Sekar Patent Holdings, LLC | Methods for manufacturing a paint roller and component parts thereof |
8623250, | Feb 07 2007 | AISAPACK HOLDING S A | Method for producing a multi-layered object |
8966850, | Jun 25 2010 | CertainTeed Corporation | Roofing products, photovoltaic roofing elements and systems using them |
9579832, | Dec 12 2008 | CertainTeed Corporation | Method of shortening the time to compression mold a roofing shingle or tile and apparatus for facilitating same |
Patent | Priority | Assignee | Title |
2168218, | |||
3669918, | |||
3844701, | |||
4220681, | Nov 28 1978 | Inoue Gomu Kogyo Kabushiki Kaisha | Trim for automobiles |
4238266, | Jul 19 1977 | Allied Chemical Corporation | Process of forming a glass fiber reinforced, stampable thermoplastic laminate |
4332703, | Mar 31 1980 | Shell Oil Company | Plastic bituminous compositions |
4396665, | Jun 16 1980 | W R GRACE & CO -CONN | Self-adhesive roofing laminates having metal layer therein |
4404960, | Apr 17 1979 | Roof skin forming a heat sink | |
4671040, | Sep 29 1982 | Method for flameproofing shingled surfaces | |
5022381, | Sep 18 1989 | Barrel-shaped solar roofing element and method for its assembly | |
5217655, | Jul 09 1991 | ECOTRUST TECHNOLOGIES, INC | Methods for preparation of composite materials |
5318737, | May 25 1990 | Rohm and Haas Company | Feedblock coextrusion of modified acrylic capstock |
5401154, | May 26 1993 | CSP ACQUISITION CORP ; Continental Structural Plastics, Inc | Apparatus for compounding a fiber reinforced thermoplastic material and forming parts therefrom |
5482667, | Aug 11 1993 | SABIC INNOVATIVE PLASTICS IP B V | Extrusion impregnation compression molding process |
5571581, | Jun 14 1991 | Toyoda Gosei Co., Ltd. | Long sandwich molded article |
5615523, | Apr 24 1995 | Owens-Corning Fiberglas Technology, Inc.; Owens-Corning Fiberglas Technology Inc | Roof having resinous shingles |
5630305, | Aug 26 1991 | Surface covering unit methods of use and manufacture | |
5759594, | Jul 27 1995 | Sumitomo Chemical Company, Limited; Kawasaki Steel Corporation; K-Plasheet Corporation | Mold assembly for producing fiber-reinforced thermoplastic resin molded article laminated with skin material |
6303224, | Jun 03 1998 | SABIC INNOVATIVE PLASTICS IP B V | Method for attaching a fluoride-based polymer layer to a polyphenylene ether or polystyrene layer, and related articles |
6349961, | Jun 15 1999 | COLLEY, DAVID | Composite molded snowboard with metal edges |
6368093, | Dec 10 1991 | JOHNSON CONTROL, S P A | Apparatus for manufacturing coinjected panels |
6440524, | Aug 14 1997 | MASSACHUSETTS, UNIVERSITY OF, THE | Process and apparatus for preparing a molded article |
6536177, | Mar 27 2000 | WILTON ACQUISITION, LLC | Composition of a weatherproof roofing material |
20010049918, | |||
20030054148, | |||
20040001938, | |||
20040148874, | |||
20040148895, | |||
20040177596, | |||
20040178532, | |||
20040241476, | |||
20050086907, |
Executed on | Assignor | Assignee | Conveyance | Frame | Reel | Doc |
Aug 10 2005 | KIM, JOONG Y | CertainTeed Corporation | ASSIGNMENT OF ASSIGNORS INTEREST SEE DOCUMENT FOR DETAILS | 017003 | /0039 | |
Aug 22 2005 | MACKINNON, THOMAS K | CertainTeed Corporation | ASSIGNMENT OF ASSIGNORS INTEREST SEE DOCUMENT FOR DETAILS | 017002 | /0567 | |
Aug 22 2005 | DODD, ROBERT E | CertainTeed Corporation | ASSIGNMENT OF ASSIGNORS INTEREST SEE DOCUMENT FOR DETAILS | 017002 | /0567 | |
Sep 14 2005 | WYLIE, DOUGLAS H | CertainTeed Corporation | ASSIGNMENT OF ASSIGNORS INTEREST SEE DOCUMENT FOR DETAILS | 017002 | /0979 | |
Sep 15 2005 | CertainTeed Corporation | (assignment on the face of the patent) | / |
Date | Maintenance Fee Events |
Jan 23 2014 | M1551: Payment of Maintenance Fee, 4th Year, Large Entity. |
Apr 16 2018 | REM: Maintenance Fee Reminder Mailed. |
Oct 08 2018 | EXP: Patent Expired for Failure to Pay Maintenance Fees. |
Date | Maintenance Schedule |
Aug 31 2013 | 4 years fee payment window open |
Mar 03 2014 | 6 months grace period start (w surcharge) |
Aug 31 2014 | patent expiry (for year 4) |
Aug 31 2016 | 2 years to revive unintentionally abandoned end. (for year 4) |
Aug 31 2017 | 8 years fee payment window open |
Mar 03 2018 | 6 months grace period start (w surcharge) |
Aug 31 2018 | patent expiry (for year 8) |
Aug 31 2020 | 2 years to revive unintentionally abandoned end. (for year 8) |
Aug 31 2021 | 12 years fee payment window open |
Mar 03 2022 | 6 months grace period start (w surcharge) |
Aug 31 2022 | patent expiry (for year 12) |
Aug 31 2024 | 2 years to revive unintentionally abandoned end. (for year 12) |