This disclosure related to polymer electrolyte member fuel cells and components thereof.
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29. A polymer electrolyte membrane fuel cell stack, comprising:
an electrochemical package comprising a cathode, an anode, and an polymer membrane interposed between the cathode and the anode;
a first bipolar plate comprising protrusions on both sides;
a second bipolar plate comprising protrusions on both sides; and
wherein the electrochemical package is disposed between the first and the second bipolar plate, the protrusions on the first bipolar plate are in contact with the electrochemical package, the protrusions on the second bipolar plate are in contact with the electrochemical package.
1. A polymer electrolyte membrane fuel cell stack, comprising:
an electrochemical package comprising a cathode, an anode, and an polymer membrane interposed between the cathode and the anode;
a first bipolar plate;
a second bipolar plate comprising a center portion, a peripheral portion, and a recess formed by the center portion of the second bipolar plate receding from the plane where the peripheral portion of the second bipolar plate reside; and
an electrically conductive porous spacer;
wherein
the electrochemical package is disposed between the first and the second bipolar plate,
the porous spacer is interposed between the first bipolar plate and the electrochemical package, and
a first compartment is interposed between the second bipolar plate and the electrochemical package.
22. A bipolar plate assembly, comprising:
a first gasket;
a second gasket; and
a first bipolar plate interposed between the first gasket and the second gasket,
a second bipolar plate comprising a center portion, a peripheral portion, and a recess formed by the center portion of the second bipolar plate receding from the plane where the peripheral portion of the second bipolar plate resides,
wherein the first gasket is interposed between the second bipolar plate and the first bipolar plate, and comprises a peripheral portion and a center cavity, the peripheral portion comprises openings for a fuel gas inlet, a fuel gas outlet, an oxidant gas inlet, an oxidant gas outlet, a cooling fluid inlet, and a cooling fluid outlet reside,
wherein the first gasket further comprises a first channel connecting the fuel gas inlet and a plurality of first slots at an edge of said gasket bordering the center cavity in said gasket, and a second channel connecting the fuel gas outlet and a plurality of second slots at the edge of said gasket bordering the center cavity in said gasket.
2. The fuel cell stack of
3. The fuel cell stack of
5. The fuel cell stack of
6. The fuel cell stack of
7. The fuel cell stack of
8. The fuel cell stack of
wherein the peripheral portion comprises openings for a fuel gas inlet, a fuel gas outlet, an oxidant gas inlet, an oxidant gas outlet, a cooling fluid inlet, and a cooling fluid outlet,
wherein the center cavity is adapted to receive the recess in the second bipolar plate,
wherein the first gasket further comprises a first channel connecting the fuel gas inlet and a plurality of first slots at an edge of said gasket bordering the center cavity in said gasket, one of the first slots is in alignment with one of the first openings in the second bipolar plate; and
a second channel connecting the fuel gas outlet and a plurality of second slots at the edge of said gasket bordering the center cavity in said gasket, one of the second slots is in alignment with one of the second openings in the second bipolar plate.
9. The fuel cell stack of
10. The fuel cell stack of
11. The fuel cell stack of
12. The fuel cell stack of
13. The fuel cell stack of
14. The fuel cell stack of
15. The fuel cell stack of
18. The fuel cell stack of
19. The fuel cell stack of
20. The fuel cell stack of
21. The fuel cell stack of
23. The bipolar plate assembly of
24. The bipolar plate assembly of
25. The bipolar plate assembly of
26. The bipolar plate assembly of
27. The bipolar plate assembly of
28. The bipolar plate assembly of
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This application claims the benefit of U.S. Provisional Application No. 61/074,793, filed Jun. 23, 2008.
The present disclosure is directed to the field of polymer electrolyte membrane fuel cells.
A typical polymer electrolyte membrane (“PEM”) fuel cell has a polymer membrane that serves as an electrolyte, supporting the conduction of protons according to its hydration level. The polymer membrane has two surfaces (or two sides). One surface is in contact with an anode electrode catalyst layer, while the other surface is in contact with a cathode electrode catalyst layer. The anode catalyst effectuates the dissociation of hydrogen into its constituent protons and electrons—the protons migrate through the membrane from its anode side to its cathode side, where they recombine with activated oxygen species to form water in the presence of the cathode catalyst.
The disclosure provides a polymer electrolyte membrane fuel cell stack. The fuel cell stack comprises an electrochemical package having a cathode, an anode, and a polymer membrane interposed between the cathode and the anode. The fuel cell stack also comprises a first bipolar plate, a second bipolar plate, and an electrically conductive porous spacer. In an assembled fuel cell, the electrochemical package is disposed between the first and the second bipolar plate and the porous spacer is interposed between the first bipolar plate and the electrochemical package.
In an embodiment of a fuel cell stack disclosed herein, the second bipolar plate comprises a center portion and a peripheral portion. The center portion is non-flat, for example, comprising features such as protrusions, ridges or grooves, or in general a surface with raised areas and indented areas. The center portion also recedes from the plane where the peripheral portion of the second bipolar plate resides, forming a recess in the second bipolar plate.
In some embodiments, the fuel cell stack further comprises a first compartment interposed between the second bipolar plate and the electrochemical package, which may be formed by placing the electrochemical package over the recess in the second bipolar plate.
In other embodiments, the second bipolar plate comprises a plurality of first openings for introducing a fluid into the first compartment and a plurality of second openings for withdrawing the fluid from the first compartment.
The fuel cell stack disclosed herein may further comprise a first gasket. The first gasket has a peripheral portion and a center cavity. The peripheral portion comprises openings for the fuel gas inlet, the fuel gas outlet, the oxidant gas inlet, the oxidant gas outlet, the cooling fluid inlet, and the cooling fluid outlet, while the center cavity is adapted to receive the recess in the second bipolar plate. The first gasket further comprises a first channel connecting the fuel gas inlet and a plurality of first slots at an edge bordering the center cavity in the gasket. One of the first slots is in alignment with one of the first openings in the second bipolar plate. The first gasket also comprises a second channel connecting the fuel gas outlet and a plurality of second slots at an edge bordering the center cavity in the gasket. One of the second slots is in alignment with one of the second openings in the second bipolar plate.
Also disclosed herein is a bipolar plate assembly, which comprises a first gasket, a second gasket, and a first bipolar plate interposed between the first plate and the second bipolar plate. The first gasket can comprise a peripheral portion and a center cavity, and the peripheral portion can comprise openings for the fuel gas inlet, the fuel gas outlet, the oxidant gas inlet, the oxidant gas outlet, the cooling fluid inlet, and the cooling fluid outlet reside,
The first gasket can further comprise a first channel connecting the fuel gas inlet and a plurality of first slots at an edge of said gasket bordering the center cavity in said gasket, and a second channel connecting the fuel gas outlet and a plurality of second slots at the edge of said gasket bordering the center cavity in said gasket.
In some embodiments of the bipolar plate assembly, wherein the first gasket and the second gasket are attached to the first bipolar plate by adhesion, injection molding, or mechanical fastening. In some other embodiments, the first gasket and the second gasket are attached to the first bipolar plate by overmolding so that the some edges of the bipolar plate, for example, an edge at the outer boundary of the plate, are covered by the gasket material.
In certain other embodiments, the bipolar assembly may also comprise a second bipolar plate interposed between the second bipolar plate and the first bipolar plate. The second bipolar plate may have protrusions what are in contact with the first bipolar plate through the center cavity in the first gasket.
The first bipolar plate disclosed here in can be a flat metal plate or of a non-flat geometric shape, for example, having ridges and grooves, or protrusions and indentations on its surface. The second bipolar plate may have protrusions rising on one side or on both sides.
This disclosure further provides a polymer electrolyte membrane fuel cell stack, which comprises an electrochemical package comprising a cathode, an anode, and an polymer membrane interposed between the cathode and the anode; a first bipolar plate comprising protrusions on both sides; a second bipolar plate comprising protrusions on both sides. The electrochemical package is disposed between the first and the second bipolar plate, the protrusions on the first bipolar plate are in contact with the electrochemical package, the protrusions on the second bipolar plate are in contact with the electrochemical package.
As disclosed herein, a membrane electrode assembly (“MEA”) refers to a polymer membrane that has an anode catalyst on one side and an cathode catalyst on the reverse side. A conducting media known as a gas diffusion layer (“GDL”) can be attached or situated adjacent to either or both of the two sides of the MEA. The gas diffusion layer is made of carbon paper, graphite cloth, or other porous, flexible, and electrically conductive materials, or composite assemblages thereof.
In certain embodiments, the electrode catalyst can be applied directly on the surface of the polymer membrane. In additional embodiments, the electrode catalyst can incorporated into catalyst layer adjacent to the polymer membrane. Alternatively, the catalyst can be applied on a gas diffusion layer, which is then chemically attached, mechanically attached, or placed adjacent to the polymer membrane, with the catalyst interposed between the gas diffusion layer and the polymer membrane. In the former case, the gas diffusion layer is not required for the fuel cell to function. As disclosed herein, an electrochemical package (“ECP”) refers to a component comprising a MEA with gas diffusion layers attached to both sides, or a MEA with only one gas diffusion layer attached to one side, or a MEA without a gas diffusion layer attached to it. Accordingly, the anode of an ECP refers to the side of the ECP that contains the anode catalyst and the cathode of an ECP refers to the side of the ECP that contains the cathode catalyst, with or without a gas diffusion layer attached to it. Therefore, when a fuel cell component is in direct contact with an electrode of the ECP, it can either be in direct contact with the catalyst, the catalyst layer, or in direct contact with the gas diffusion layer.
A fuel gas, e.g., a hydrogen-containing gas, is fed to the anode compartment, which is the space between the anode of the ECP and an electrically conductive (e.g. graphite or metal) gas barrier, i.e., a bipolar plate. An oxidant gas, e.g., an oxygen-containing gas such as air, is fed to the cathode compartment, which is the space between the cathode of the ECP and a bipolar plate. Spacers may be used to create fluid passages in the anode compartment and cathode compartment, respectively. The spacer can be made from a material that is electrically conductive and by design allows fluids to pass through.
In certain embodiments, a single fuel cell comprises an ECP, an anode compartment, a cathode compartment, two bipolar plates, and optionally one or more spacers. A “fuel cell stack” comprises multiple single fuel cells connected electrically in series, usually with a cooling cell interposed between the anode compartment of one fuel cell and the cathode compartment of another fuel cell. A cooling fluid, gaseous or liquid or multiphase, passes through the cooling cell, and exchanges heat with the adjacent anode and cathode compartments to afford control of the temperature therein. In addition or alternatively, a water-based liquid coolant can mix with the anode gas or the cathode gas inside the anode or cathode compartment to accomplish temperature control.
Furthermore, the second bipolar plate (2), the first bipolar plate (1), the first gasket (31), and the second gasket (32) each has multiple openings, including fuel gas inlets (OD), fuel gas outlets (OB), oxidant gas inlets (OA), oxidant gas outlet (OC), coolant fluid inlets (OE), and coolant fluid outlets (OF). When these components are assembled together to form a fuel cell or a fuel cell stack, the same type of openings in different components are in alignment, forming conduits for the fluids in the fuel cell or the fuel cell stack (see
The anode side of the second bipolar plate (2) is shown in
In this embodiment, a porous spacer (4) is placed inside the anode compartment to provide a flow field for the fuel gas as well as to electrically connect the second bipolar plate and the anode of the electrochemical package.
One suitable porous spacer is a perforated metal sheet. A perforated metal sheet has repeated arrays of perforations, e.g., round holes, hexagonal holes, square holes, slotted hole, etc. Before installation as a spacer in a fuel cell compartment, a perforated metal sheet may be processed to form a non-flat geometric shape. For example, it can be stamped to form undulating ridges and grooves, or indentations and protrusions, or other geometric shapes. An example of a perforated metal sheet that is commercially available can be obtained from McNichols Co., Tampa, Fla. When installed between a bipolar plate and an ECP, the perforated metal sheet allow passages of flow along its surfaces as well as through the perforations in the metal sheet.
Another suitable porous spacer is an expanded metal mesh. An expanded metal mesh is made from sheets of solid metal that are uniformly slit and stretched to create openings of certain geometric shapes, e.g., a diamond shape. In a standard expanded metal, each row of diamond-shaped openings is offset from the next, creating an uneven structure. The standard expanded metal sheet can be rolled to produce a flattened expanded metal.
A further suitable porous spacer is a metal wire mesh, which can be made by weaving or welding metal wires together. Both metal wire mesh and expanded metal mesh are commercially available, for example, from Mechanical Metals, Inc. of Newtown, Pa. When used as a spacer, the expanded metal mesh and the metal wire mesh may first be processed to form a non-flat geometric shape.
A piece of metal foam or graphite foam can also be used as a spacer. The foam has a reticulated structure with an interconnected network of ligaments. Because of this unique structure, the foam material in its uncompressed state can have a porosity that reaches 75%, such as greater than 80%, greater than 85%, greater than 90%, greater than 95%, and up to 98%. Metal foams are commercially available, for example, from Porvair Advanced Materials, Inc., Hendersonville, N.C. Graphite foams are also commercially available, for example, from Poco Graphite, Inc., Decatur, Tex.
One aspect of the second bipolar plate (2) is that its center portion (2B) is not flat. Other than having protrusions of various shapes, the center portion may have ridges or grooves, or otherwise features that provides it a raised (or indented) surface. One further aspect of the second bipolar plate (2) is that the plane where the center portion (2B) resides can be parallel or at an angle with the plane where the peripheral portion (2B) resides.
Furthermore, the shortest distance between the plane where the peripheral portion (2A) resides and the plane where the flat area of the center portion (2B) resides is the depth of the recess, which can range from 0.1 to 3 mm, for example, from 0.1 to 2.5 mm, from 0.2 to 2 mm, from 0.4 to 1 mm.
In addition to openings for fluid passage in its peripheral region (2A), the second bipolar plate (2) also has a plurality of first openings (2D) and second openings (2E) arranged in the transition area (2C). These openings are for passages of the fuel gas into and out of the anode compartment.
The black lines on the surface of the first gasket in
When compressed against the second bipolar plate (2), the sealing material ridge forms seals around the openings encircled by the sealing ridge. Note that the sealing material ridge encircles an area that includes the cooling fluid inlets (OE) and outlets (OF), as well as the center cavity. Two sections of the sealing material ridges, one between sections (3A) and (3B) and the other between sections (3C) and (3D), reside on a first plane. Some other sections of the sealing material ridges, such as those at the outmost periphery of the sealing material ridges, can reside on a second plane. In the embodiment according to
Sections (3A), (3B), (3C), and (3D) are transition sections that connect the first and the second planes. Accordingly, the sealing material ridges on sections (3A), (3B), (3C), and (3D) connect the sealing material ridges residing on the first and the second planes. When the first gasket is compressed against a second bipolar plate, the sealing material ridge on the first plane is in contact with the center portion of the second bipolar plate while the sealing material ridge on the second plane is in contact with the peripheral portion of the second bipolar plate. Furthermore, the sealing material ridges seal the fluid in slots (3L) and (3J) from the cooling fluid compartment.
As expressed in
On the other hand, the oxidant gas enters from oxidant gas inlet (OA) in the first gasket (31), passing through openings (3Q) in the first bipolar plate (1) to the cathode side of the first bipolar plate (1). The oxidant gas then flows through channels (3S) and slots (30) into the cathode compartment. A porous spacer resides in the cathode compartment, which is not shown in the drawing for clarity. The oxidant gas exits the cathode compartment through the slots (3R) and channels (3T), crossing the first bipolar plate (3) through the openings (3P) to arrive at the oxidant outlets (OA) in the first gasket (31) (see
The first gasket (31) also has openings (3M) and (3N). In this embodiment, openings (3M) allow the cooling fluid to enter the cooling compartment while openings (3N) are the exits for the cooling fluid (see
In certain embodiments, the second bipolar plate may not have a recess. Instead, the bases of the protrusions are on the same plane where the peripheral portion of the plate resides. Accordingly, when interposed between two flat surfaces, for example, an electrochemical package and a first bipolar plate, protrusions on the anode side of the second bipolar plate contacts the electrochemical package while protrusions on the other side touches the first bipolar plate. Accordingly, the bipolar plate in this embodiment provide flowfields for fuel gas and the cooling fluid. It also connects the first bipolar plate and the electrochemical package. In this embodiment, a porous spacer may not be required either in the cooling fluid compartment or in the anode compartment.
In a further embodiment of this disclosure, the first bipolar plate (1) can have a surface that is non-flat. For instance, it can have undulating ridges and valleys, protrusions, other suitable patterns that create a space between the first bipolar plate and another object.
Furthermore, in all embodiments of the fuel cell disclosed above, the anode compartment can be used as a cathode compartment and vice versa. For example, the reverse can be accomplished by reversing the electrochemical package without further change in the configuration of the fuel cell.
In yet another embodiment, the gaskets (31, 32) can be attached to the first bipolar plate (1) using an adhesive, by injection molding, or by any other known methods to attach a gasket material to a metal surface. For example, the first bipolar plate can undergo an overmolding process to form a single unit having the first bipolar plate with the first gasket (31) on one side and a second gasket (32) on the other side. This single unit may be beneficial since it reduces the total number of components in a fuel cell.
In another embodiment of this disclosure, the first gasket, the second gasket, and the first bipolar plate interposed therebetween can form a bipolar plate assembly. The bipolar plate assembly may be integrated together by adhesion, injection molding, or other known methods for adhering a gasket to a metal surface. In one embodiment, the first and the second gasket can be overmolded on the first bipolar plate. In such an embodiment, the gasket material can be molded around the edges of the first bipolar plate around its outer boundary as well as its openings for various fluids, if desirable.
In addition, a bipolar plate assembly may also comprise the second bipolar plate, which has a raised surface, e.g. ridges and grooves or a plurality of protrusions, in its center portion. The second bipolar plate may be placed adjacent to the first gasket. Its raised surface may be in contact with the first bipolar plate, forming fluid passages inbetween.
It will be apparent to those skilled in the art that various modifications and variations can be made without departing from the spirit of the invention. The present invention covers all such modifications and variations, provided they come within the scope of the claims and their equivalents.
Conti, Amedeo, Blanchet, Scott C., Gambini, Filippo
Patent | Priority | Assignee | Title |
10186717, | Oct 24 2013 | Hyundai Steel Company | Metal separation plate for fuel cell stack and fuel cell stack having the same |
10522850, | Sep 30 2014 | The Government of the United States of America, as represented by the Secretary of the Navy | Three-dimensionally printed bipolar plate for a proton exchange membrane fuel cell |
9005835, | Jun 23 2008 | NUVERA FUEL CELLS, INC | Fuel cell with reduced mass transfer limitations |
9012104, | Jan 25 2010 | Ramot at Tel-Aviv University Ltd. | Bipolar plates and regenerative fuel cell stacks including same |
Patent | Priority | Assignee | Title |
5565072, | Apr 30 1993 | DE NORA ELETTRODI S P A | Electrochemical cell provided with ion exchange membranes and bipolar metal plates |
7189468, | Mar 16 2001 | Creare Inc.; CREARE INC | Lightweight direct methanol fuel cell |
7592088, | Aug 25 2004 | GM Global Technology Operations LLC | Seal configuration for fuel cell stack |
8101319, | May 20 2004 | GM Global Technology Operations LLC | Approach to make a high performance membrane electrode assembly (MEA) for a PEM fuel cell |
20020182472, | |||
20030162077, | |||
20040115510, | |||
20050079400, | |||
20050181264, | |||
20050186459, | |||
20060024561, | |||
20060046128, | |||
20060073373, | |||
20060099480, | |||
20090075134, | |||
20110195329, | |||
WO2007034617, | |||
WO2007129642, |
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Aug 27 2009 | BLANCHET, SCOTT C | NUVERA FUEL CELLS, INC | ASSIGNMENT OF ASSIGNORS INTEREST SEE DOCUMENT FOR DETAILS | 023331 | /0115 | |
Aug 27 2009 | CONTI, AMEDEO | NUVERA FUEL CELLS, INC | ASSIGNMENT OF ASSIGNORS INTEREST SEE DOCUMENT FOR DETAILS | 023331 | /0115 | |
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