A chlorine-generating apparatus is herein disclosed which uses softened household water and salt. The apparatus includes a freestanding brine tank to hold salt and softened household water. The brine tank includes a submerged chlorine-generating cell, an improved chlorine-generating cell container, and a cell-cleaning reservoir. The brine tank also includes a precipitation tank to help remove minerals from the incoming household water. The chlorine-generating apparatus generates sodium hypochlorite, sodium hydroxide, as well as other sanitizing chemicals. The chlorine-generating apparatus also incorporates an improved method for controlling pH. A water-cooled power supply independently delivers power to the chlorine-generating cell.
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18. A chlorine-generating and infusion apparatus, comprising:
an inlet port capable of receiving household water;
a precipitation tank capable of removing minerals from the household water so as to provide softened water;
a brine tank capable of containing a solution of salt in the softened water, the brine tank including:
a chlorine-generating cell submerged in the softened water, the chlorine-generating cell providing at least sodium hypochlorite and sodium hydroxide,
a power supply for providing power to the chlorine-generating cell,
a chlorine-generating cell container having a sealed cap at its bottom of the pipe and at least one hole along its side, the hole preventing un-dissolved salt from entering the chlorine-generating cell container, and
a cell-cleaning reservoir connected to the chlorine-generating cell; and
a reverse osmosis system, connected to the brine tank, the reverse osmosis system including:
a reverse osmosis housing connected to the brine tank,
a pre-sediment filter connected to the reverse osmosis housing,
a reverse osmosis cartridge disposed within the reverse osmosis housing, and
an inline restrictor connected to the reverse osmosis housing,
wherein household water enters the pre-sediment filter, and then flows into the reverse osmosis housing where the reverse osmosis cartridge serves to separate the water so that a more mineral-free water enters the precipitation tank, and so that the mineral laden water exits the reverse osmosis cartridge through the inline restrictor and into a sealed mixing chamber.
1. A chlorine-generating and infusion apparatus comprising:
an inlet port capable of receiving household water;
a precipitation tank capable of removing minerals from the household water so as to provide softened water; and
a brine tank capable of containing a solution of salt in the softened water, the brine tank including:
a chlorine-generating cell submerged in the softened water, the chlorine-generating cell providing at least sodium hypochlorite and sodium hydroxide;
a power supply for providing power to the chlorine-generating cell,
a chlorine-generating cell container with a sealed cap at its bottom and at least one hole along its side, the hole preventing un-dissolved salt from entering the chlorine-generating cell container; and
a cell-cleaning reservoir connected to the chlorine-generating cell,
wherein the chlorine-generating cell container includes the chlorine-generating cell and:
separates the un-dissolved salt in the bottom of the brine tank from the brine water, while allowing the brine water to enter an intake of an anode electrode chamber of the chlorine generating cell, the intake being located in the bottom portion of the chlorine-generating cell container, thereby preventing un-dissolved salt from entering the intake of the anode electrode chamber of the chlorine-generating cell;
allows softened mild salt water at the top of the chlorine-generating cell container to be directed to an intake of a cathode electrode chamber of the chlorine-generating cell; and
has a series of small holes in its side wall, and is sealed at the bottom so as to form a pocket that discourages chlorinated brine water returning from a dewatering device from migrating throughout the bottom of the brine tank, thereby improving efficiency of production of chlorine gas delivered to the dewatering device, and thereby minimizing the amount of chlorine fumes escaping from the brine tank.
2. The apparatus of
3. The apparatus of
apparatus for controlling pH, connected to the brine tank.
5. The apparatus of
6. The apparatus of
an outer shell for storing salt and water; and
an un-dissolved salt indicator capable of indicating a level of un-dissolved salt.
7. The apparatus of
the cathode electrode chamber containing softened household water,
the anode electrode chamber containing softened water and being separated from the cathode electrode chamber by an ion selective membrane, and
the ion selective membrane keeping chlorine and oxygen gases produced in the anode electrode chamber separate from sodium and hydrogen gas produced in the cathode electrode chamber.
8. The apparatus of
9. The apparatus of
10. The apparatus of
the dewatering device being attached directly to the intake of the anode electrode chamber,
the dewatering device being capable of separating chlorine gas from the brine water after the brine water has been pumped from the anode electrode chamber, and
the dewatering device also being capable of directing the chlorine gas to a mixing chamber, while the unused brine water is returned to the intake of the anode electrode chamber, thereby minimizing the amount of chlorine fumes escaping the brine tank, while also increasing the efficiency of chlorine production by returning discharge from the sealed dewatering device to the intake of the anode side of the chlorine-generating cell.
11. The apparatus of
the chlorine-generating cell,
a mixing chamber, and
plumbing going to a body of water to be treated.
12. The apparatus of
the cell cleaning reservoir having an air injection fitting that can be used to attach a compressed air source that can be used to empty the cell-cleaning reservoir of solution by injecting compressed air.
13. The apparatus of
the chlorine-generating cell,
the mixing chamber,
and the plumbing going to the body of water to be treated.
14. The apparatus of
power supply with thermal protection that incorporates full voltage regulation, such that when the acidic solution is injected into the chlorine-generating cell, the acid will not cause an electrical overload.
15. The apparatus of
16. The apparatus of
an optional circuit having a 24-hour programmable timer; and
a pulsating circuit controlling device adapted to power an ionizing copper/silver cell installed in a circulating system of the body of water being treated.
17. The apparatus of
a check valve, installed in a chlorine exit line connected to the chlorine-generating cell, the check valve preventing back-up water from back-flowing into the chlorine-generating cell when the same line for delivering make up water is used for adding chlorine from the chlorine-generating cell.
19. The apparatus of
the brine tank includes the sealed mixing chamber, and
a by-pass stream exiting the reverse osmosis system enters the inline restrictor and is then directed to the top of the sealed mixing chamber where the by-pass stream efficiently combines with chlorine gas and forms a chlorinated liquid that is then directed to the water being treated.
20. The apparatus of
21. The apparatus of
wherein a more mineral-free water that has exited the reverse osmosis cartridge is mixed with a high pH liquid that is pumped from a cathode electrode chamber of the chlorine-generating cell, thereby causing additional minerals in the more mineral-free water to precipitate to the bottom of the precipitation tank, resulting in a much softer water that then flows into the brine tank.
22. The apparatus of
23. The apparatus of
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The present invention generally relates to on-site chlorine generation from brine water, and particularly to on-site chlorine generating and infusion systems for swimming pools and other bodies of water needing sanitation.
Known methods of on-site chlorine generation have proven relatively suitable, although there have been problems relating to chlorine generating units for residential swimming pools and small to medium bodies of water (under 40,000 gallons). For the most part, known methods of on-site chlorine generation have not been adequate for treating large commercial swimming pools or large bodies of water.
Swimming pools, as well as certain other bodies of water, must be sanitized in order to be safe for use. Lack of proper sanitization results in damaged equipment, damaged pool surfaces, and allows water to become a breeding ground for disease and algae.
Swimming pool owners generally take care of the chemistry of the pool water in one of the following ways:
The residential pool owner hires a pool service company to come out once a week and bring the chemicals necessary to keep the water safe and sanitized.
The Board of Health will not allow a “once a week” treatment for commercial pools. The Board of Health requires that any commercial or public pool have some means on-site for automatically dispensing sanitizing chemicals into the pool water.
Common on-site chemical dispensing devices are: an adjustable liquid pump that takes liquid chlorine from a storage vat, and injects it into the pool's return line; a chlorine tablet holder that is installed into the return line that allows the tablets to be dissolved at an adjustable rate; and a powdered chlorine dispenser that automatically dumps powder into a container that has pool water circulating through it.
Some problems with these devices are that, because they are mechanical and exposed to the corrosive nature of pool chemicals, they are not very reliable, and require frequent service or replacement. Often the owner/operator resorts to adding chlorine into the pool by hand.
Another method for dispensing chlorine that has become accepted in recent years is to add salt to the pool and then to install an in-line chlorine-generating cell that will produce chlorine from the salt in the pool water.
Two of the Many Problems with this Type of Device are:
1. The amount of chlorine produced is too small to adequately deliver the amount of chlorine needed during a heavy swim load. As a result, it is a common practice to have a liquid chlorine dispenser as a backup; and
2. Since pool water commonly has a high amount of dissolved solids, the inline cells become fouled with hard water deposits, and consequently require frequent cleaning, service, and/or replacing.
Bromine dispensers are another method for dispensing sanitizing chemicals into a pool to be sanitized. Bromine is an accepted product for sanitizing pool water and can be provided as a tablet, or in stick form. Dispensed into the pool water, bromine will kill algae and bacteria, but is far more expensive than chlorine.
Another method, which has been outlawed in some areas because of extreme hazards associated therewith, is to have a pool service bring compressed chlorine gas to a pool site, and then to dispense it into the pool water. This is accomplished by submerging a manifold in the deep end of the pool, and then bubbling chlorine gas into the water from a portable gas cylinder. In addition to the danger of having compressed chlorine gas in a neighborhood, the addition of chlorine gas to pool water makes an acid that must be neutralized with a base product, such as soda ash. With this method, the extreme vacillation of pH and chlorine, from high to low, adversely affects the swimmer's health and safety, as well as causing bleaching of suntan, swimwear, and towels, and leads to green hair, irritated skin, and irritated eyes.
In addition, when the pH is below 7, and there is any copper in the pool's plumbing, copper oxide is formed, which causes a blue-green stain on the pool finish. When the pH of the pool rises above 8, minerals in the pool water deposit on the pool finish. These variations in pool water chemistry shorten the life of the pool's plumbing, equipment, and plaster finish.
In addition to the above problems, when concentrated commercial chemicals are used, it is easy to over-treat the pool water, and to get the chemistry out of balance. Out-of-balance pool water is the culprit that causes most surface-staining of plasters, and causes discomfort to swimmers.
Over the years, there have been a number of other devices and methods that have been marketed to assist in the sanitation of pool water.
For example, ultraviolet light is a sanitizing method which uses a clear plastic or glass cell containing an ultraviolet (UV) light. When the filtered pool water passes through the cell on its way back to the pool, the water is exposed to UV rays that can kill bacteria. The problem with this system is that it leaves no residual protection in the water. Consequently, if the water becomes contaminated after it leaves the ultraviolet light cell, bacteria in the water will not be killed until the water again passes through the cell. Chlorine is usually still used to provide the residual bacteria kill needed. The basic claim of the ultraviolet light system is that it will reduce the amount of chlorine needed to sanitize a pool.
Ozonators are another device for sanitizing pool water. This type of device uses high voltage to create ozone from the air, which is then injected into the pool water before returning it via the return line of the pool. Ozone kills bacteria, but does not stay in the water after the water is returned to the pool. It will reduce the amount of chlorine needed, but is not accepted by the Board of Health as a sole means of sanitizing pool water, because it doesn't leave a residual disinfectant or sanitizing agent in the pool water for a long enough time.
Copper/Sliver ionization is another method of sanitization. Copper and silver ions cannot remove organic matter, such as skin tissue, hair, urine, and skin flakes from water. Thus, another disinfectant, such as chlorine, needs to be used in addition to the copper and silver ions. Chlorine demand can be reduced by as much as 80% with the addition of copper and silver ions. In addition, copper and silver ions will stay in the water longer than most other sanitizing products, and are not affected by pH, heat, or sun. However, the process of killing bacteria and algae using copper and silver ions is slower than with other pool water sanitization methods. Copper/silver ions and chlorine make a good combination of sterilizing agents, but copper/silver ions are not sufficient as a sole agent for sterilizing pool water.
Commercial Chlorine Products:
Powder and Tablet Forms of Chlorine:
These forms of chlorine usually contain cyanuric acid, commonly called pool stabilizer. After the chlorine delivered by these products has dissipated from the pool water, the stabilizer remains. The effect of stabilizer is to slow down the reaction of chlorine so as to make the chlorine last longer in the pool. Too much stabilizer can inhibit the chlorine's ability to kill bacteria fast enough for the pool water to be safe for swimmers. Therefore, the Board of Health states that stabilizer concentrations over 75 ppm are unsafe, because such concentrations make the reaction of chlorine too slow to kill bacteria. This law prevents commercial pool owners from using pill, powder, and tablet forms of chlorine as the sole method for sanitation.
Another problem using commercial chlorine in the form of tablets and powders is that as much as 95% of the “chlorine” that is purchased is not chlorine, but instead consists of inert ingredients that the manufacturers add to their product to stabilize the chlorine and to give it shelf life. This can add a large amount of undesirable dissolved solids into the pool water, which can eventually cause staining of the pool finish, discomfort for swimmers, and can shorten the life of the filtering equipment.
The chemicals used in treating pool water are manufactured off-site, usually in a rural area away from the heavily populated cities. Products such as salt, stabilizer, calcium, soda ash, etc., must be transported to the chemical factory. After the pool chemicals are manufactured, they must be put in bottles or other suitable containers, labeled as “hazardous products”, and then shipped into cities and towns to be stored in warehouses. The products are then shipped in smaller amounts to the retail stores where they are purchased by the service companies or by the end user, and then are transported to the pool site where they are stored until they are used. A vehicle accident while transporting concentrated pool chemicals, or the improper storage of these chemicals, has resulted in the chemicals getting wet or mixed, which has caused fires, explosions, and the emitting of dangerous deadly gases often endangering children as well as adults.
Inline Chlorine Generators:
Over the years, there have been many attempts to generate chlorine at the pool site. Most of these devices require salt to be added to the pool water. Then, when the pool filter system is running, the salted pool water is directed through either an inline chlorine-generating cell, or a by-pass chlorine-generating cell.
To manufacture chlorine from pool water, hundreds of pounds of salt must be poured into the pool. Doing so raises the total dissolved solids, which can lead to deposits being precipitated out of the water onto the tile and pool finish.
When a saltwater pool is drained, or when water from the pool is backwashed into the sewer system, it makes the discharge water too: salty. This causes problems at the treatment plant, and it is now illegal to discharge water from salt-water pools into the sewer system, or to discharge into the drain gutters in some counties.
When an electric potential (also called “electrolysis”) is present in the pool water, the increased conductivity due to the salt in the pool water can lead to excessive corrosion on all metal parts of the pool circulating system. Most pool water has a higher amount of dissolved minerals than does tap water. This is due to the inert ingredients left over from pool chemicals that have been put into the pool, and to the evaporation of tap water which also leaves minerals in the pool water, resulting in “hard water”. When this hard water flows through chlorine-generating cells, the calcium and magnesium dissolved therein form deposits inside the cell on the cathode (the negative electrode). This reduces the efficiency of the cell, and necessitates cleaning of the cell by the operator, which is difficult and time consuming. If the cell is not cleaned, the build-up will continue to lower the efficiency of the cell, shorten its life, and eventually destroy it.
Another problem with this type of system is that, to make chlorine, the entire filtering system must be running to provide large amounts of constant water flow through the cell. This wastes a great deal of electricity, and does not give the operator the option of filtering less and chlorinating more.
Another problem with in-line chlorine generators is that when pool water temperature drops below 60°, the chlorine production is drastically reduced or terminated with an inline system.
Another problem with in-line chlorine generators is that the efficiency of an electronic cell operating in a mild salt solution is far less than the same electrolytic cell operating in saturated softened brine water.
Another problem with in-line chlorine generators is that when the pool owner changes the valves on his filtering system to use and heat his spa and forgets to shut “off” the inline chlorinator, all the chemicals being manufactured for the pool are directed to the spa, which only contains 500 to 800 gallons of water. In short order, the spa can become dangerously over-chlorinated and out of balance.
Still another problem with in-line chlorine generators is that in the event the filter pump stops, or for any reason the flow of water stops going across the inline chlorine generator's electrodes and the unit is still running, an accumulation of hydrogen gas is created. This pocket of hydrogen gas is extremely dangerous, and can be ignited by sunlight or by the electrodes themselves, resulting in a powerful explosion.
Considering the need for daily chlorination and the increasing cost of energy, as well as the problems caused by adding large amounts of salt to the pool water, these inline chlorine generators are neither able to provide the maximum protection, nor are they cost effective.
U.S. Pat. No. 4,500,404, issued Feb. 19, 1985 to Daniel Tucker, also the inventor of the present invention, is a patent for an early predecessor of the present invention. In this first patent, a chlorine-generating device was claimed for a tank containing sodium chloride and a submerged electrolytic cell. The electrolytic cell contained an ion-selective membrane separating anode and cathode compartments. The anode compartment contains the brine solution. The device contains a water softening device to provide soft water to both compartments, a source of direct electrical current with the positive output directed to the anode electrode and compartment, and the negative current connected to the cathode electrode and compartment.
U.S. Pat. No. 4,693,806, issued Sep. 15, 1987 to Daniel Tucker, also the present inventor, is a patent for a successor to the device in U.S. Pat. No. 4,500,404, wherein the tank containing sodium chloride and a submerged electrolytic cell is submerged in a larger tank filled with water such that the cathode compartment of the electrolytic cell communicates directly with the water in the larger tank. The ion-selective membrane passes only hydrogen and sodium ions from the anode compartment to the cathode compartment, thus converting the water in the larger tank to a sodium hydroxide solution. The sodium hydroxide solution causes the hardness minerals contained in the incoming water to be precipitated out. In addition, an isolation valve is disclosed to control the flow of sodium hypochlorite into the main pool system using the main filter pump.
U.S. Pat. No. 4,781,810, issued Nov. 1, 1988 to Daniel Tucker, also the present inventor, is a patent for a successor to the device in U.S. Pat. No. 4,693,806, wherein the chlorine generating cell incorporates a chemical pump for forcibly urging the resulting product to the pool without the use of mechanical pumps or membranes. New methods of reducing maintenance and increasing reliability are also disclosed.
When the above described invention was manufactured and put into the field, a number of problems developed that required field service and re-designing to make the unit more reliable.
The pipe containing the power leads to the submerged electrodes would fill, over time, with condensation, causing the electrical connections to corrode and fail.
The customer would forget to recharge the water softener, and then hard water would enter the brine tank and cell, thereby causing the cell to fail.
The customer would not acid-clean the electronic cell and, in hard water areas, the mineral deposited on the submerged cell would cause it to fail.
The cell was not able to produce enough chlorine to offset the heavy swim load and temperature of commercial swimming pools.
The pH of the pool water would rise on the alkalinity side, and the device for pH control in the above patent was too complicated and didn't work adequately.
The customers would put too much salt in the unit and cause the unit to fail.
The unit was difficult and time-consuming to install because the power supply was separated from the brine tank.
The power supply was inefficient and wasteful of electricity.
The pumping action of the submerged cell was compromised by the impurities in the brine water and the complicated plumbing.
The concentration of the chlorinated liquid returned to the bottom of the brine tank caused failure of the brine tank itself, and caused excessive corrosion of metal parts.
Chlorine fumes were common around the top of the brine tank.
The prior art could not produce enough sanitizing agents to sanitize large commercial pools without installing multiple units.
The invention solves the problems of the prior art so as to improve reliability, reduce cost, reduce service problems, and increase productivity.
The invention installs easily and can be operated by a normal unskilled pool operator. It provides far less undesirable inert products to the body of water being treated. The invention saves electricity by requiring less filter time, and eliminates wasted energy used in the manufacturing, transporting, packaging, storing and delivering hazardous commercial chemicals.
The invention provides, at a low cost and high reliability, a combination of sanitizing chemicals by using a small amount of softened household water being delivered to a self standing brine tank which contains salt and a submerged electronic cell.
The invention provides internal protection for the cell so that it can operate efficiently and not become fouled with un-dissolved salt or mineral deposits.
The invention provides automatic treatment for incoming water so that the submerged cell is exposed to a minimum amount of hardness minerals thus minimizing hardness build-up on the electrodes.
The invention provides a convenient, easy method for cleaning the cell either automatically or manually by activating an electronic circuit.
The invention provides encapsulated electrical leads within a PVC pipe that goes to the submerged cell so as to avoid condensation in the PVC pipe which can lead to failure of the electrical connections.
The invention provides an easy, convenient method to force the liquid out of the cell-cleaning reservoir so the cell-cleaning reservoir can be recharged with fresh acid.
The invention provides a unit that has a minimal amount of moving parts and is easy to install.
The invention provides a unit wherein the pH of the liquid leaving the unit can be easily adjusted to assist the pool operator in controlling the pH of the water being treated,
The invention provides a unique way of mixing the filtered incoming water from the RO unit with the discharge from the cathode side of the submerged cell in such a way as to efficiently cause minerals to precipitate to the bottom of the precipitation tank.
The invention provides a cell container that delivers mild salt water to the intake of the cathode side of the cell and, at the same time, provide brine water to the intake of the anode side of the cell.
The invention provides a cell container that allows brine water to enter the cell but prevents un-dissolved salt from entering and fouling the cell.
The invention provides a cell container that is sealed at the bottom which directs heavily chlorinated water back through the cell, making the cell more efficient, and, at the same time, reducing the amount of chlorine fume exiting the brine tank.
The invention provides a unit that can efficiently mix or combine chlorine gas, sodium hydroxide and other chemicals into a liquid form and deliver it to the water being treated without using any moving parts.
The invention provides a unit in which the improved pumping action of the cell allows it to deliver the liquid and chemicals generated in each of the electrode compartments to separate areas of the unit for proper mixing which minimizes chlorine fumes.
The invention provides an efficient mixing chamber filled with a media that will combine the chemicals with water and deliver the mixture to the water being treated.
The invention provides a unit designed in such a way that all incoming and exit fittings are installed above the water level in the brine tank which eliminates leaks.
The invention provides a sealed, water cooled, weather protected cabinet that encloses a solid-state power supply and other electronic parts.
The invention provides a water-cooled, thermally protected, voltage regulated power supply that can deliver low voltage power efficiently to a chlorine generating cell and optionally to a copper/silver ionizing cell.
The invention provides a unit that can be more easily shipped, installed, and serviced.
The invention provides a complete unit for sanitizing water using the basic elements of salt, water, and acid, also requiring very little maintenance, using very little power, and having the option of significantly increasing the amount of sanitizing agents by the addition of a copper/silver cell.
The water level in the brine tank is maintained by local utility water, which is notably softer than pool water. The water enters the unit through a pre-sediment filter, which will remove foreign particles. The water then is directed through the unit's solenoid valve. When the power supply turns the unit on, the water leaves the solenoid valve and is directed through an aluminum heat exchanger or heat sink. The water then enters a reverse osmoses unit, which separates the water into two streams.
One stream (about 25% of the water) goes through a reverse osmosis filter, which removes 80% to 90% of the hardness minerals. The other stream (about 75%) by-passes the filter, picks up the mineral laden water from the reverse osmosis unit, and carries it to a sealed mixing chamber where chlorine gas and sodium hydroxide are combined with other chemicals to form a chlorinated liquid that is then delivered to the pool through the chlorine exit port of the unit. The smaller (reduced mineral) stream (25%) is directed into a precipitation tank where it is mixed with the effluent from the cathode side of the submerged cell. Because of the caustic (alkaline, high pH, or basic) nature of that water, most of the remaining hardness contained in the incoming water will precipitate to the bottom of the precipitation tank.
Water, almost mineral free, then overflows onto the surface of the brine tank. When this liquid dissolves the salt at the bottom of the tank and goes through the submerged chlorine-generating cell, the amount of mineral build up on the cathode side of the chlorine-generating cell is greatly reduced. The submerged chlorine-generating cell is enclosed in its own cell container that protects the chlorine-generating cell from being fouled by un-dissolved salt and also keeps chlorinated liquid from migrating throughout the bottom of the brine tank.
To further protect the chlorine-generating cell and keep the chlorine-generating cell clean, a sealed acid-cleaning reservoir, filled with acidic solution, is provided inside the brine tank. A second solenoid valve is provided and is connected to household water. When that valve is activated, either manually or electronically, water is injected into the top of the reservoir thereby forcing a small amount of acid out of the bottom. A portion of the acid is directed to the cathode side of the cell, and a portion is directed to the mixer, thereby cleaning the unit and its plumbing of hardness build-up, and keeping it working at peak efficiency, as well as extending its service life. Since the acid used for cleaning eventually ends up being delivered to the pool, this process also aids in controlling the pH of the pool water.
Mounted on top of the brine tank is a sealed aluminum cabinet containing a solid-state power supply. A digital timer is mounted on the front of the aluminum cabinet.
A general aspect of the invention is a chlorine-generating and infusion apparatus. The apparatus includes: an inlet port capable of receiving household water; a precipitation tank capable of removing minerals from the household water so as to provide softened water; and a brine tank capable of containing a solution of salt in the softened water. The brine tank includes: a chlorine-generating cell submerged in the softened water, the chlorine-generating cell providing at least sodium hypochlorite and sodium hydroxide; and a water-cooled power supply for providing power to the chlorine-generating cell. The apparatus also includes: a cell container having a PVC pipe with a sealed cap at the bottom of the pipe and at least one hole along a side of the pipe, the hole preventing un-dissolved salt from entering the cell container; and a cell-cleaning reservoir connected to the chlorine-generating cell.
In a preferred embodiment, the chlorine-generating cell also generates hypochlorous acid, oxygen, and sodium hydroxide.
In another preferred embodiment, the apparatus further includes apparatus for controlling pH, connected to the brine tank.
In another preferred embodiment, the brine tank is freestanding.
In still another preferred embodiment, the power supply and the brine tank are integrated as one unit.
In yet another preferred embodiment, the brine tank includes: an outer shell for storing salt and water; and an un-dissolved salt indicator capable of indicating a level of un-dissolved salt.
In preferred embodiments, the chlorine-generating cell includes: an anode electrode chamber containing softened water; and a cathode electrode chamber containing softened household water, the anode electrode chamber being separated from the cathode electrode chamber by an ion selective membrane, the ion selective membrane keeping chlorine and oxygen gases produced in the anode electrode chamber separate from sodium and hydrogen gas produced in the cathode electrode chamber. In a further preferred embodiment, gases in each electrode chamber pump liquid from each electrode chamber in a percolating fashion, thereby urging liquid and gas products produced in each chamber to be delivered to a desired location.
In another preferred embodiment, the chlorine-generating cell includes electrical leads that are connected to electrodes in the anode and cathode chambers, the electrical leads being enclosed in PVC pipes that are injected with a sealing agent that seals the pipes so as to prevent condensation in the pipe, thereby preventing corrosion of electrical connections of the electrical leads.
In still another preferred embodiment, the brine tank includes: a sealed de-watering device attached directly to the intake of the anode electrode chamber, the sealed de-watering device being capable of separating chlorine gas from the brine water after the brine water has been pumped from the anode electrode chamber, the sealed de-watering device also being capable of directing the chlorine gas to a mixing chamber, while the unused brine water is returned to the intake of the anode electrode chamber, thereby minimizing the amount of chlorine fumes escaping the brine tank, while also increasing the efficiency of chlorine production by returning discharge from the sealed de-watering device to the intake of the anode side of the chlorine-generating cell.
In yet another preferred embodiment, the apparatus further includes: a reverse osmosis system, connected to the brine tank, the reverse osmosis system including: a reverse osmosis housing connected to the brine tank, a pre-sediment filter connected to the reverse osmosis housing, a reverse osmosis cartridge disposed within the reverse osmosis housing, and an inline restrictor connected to the reverse osmosis housing, wherein household water enters the pre-sediment filter, and then flows into the reverse osmosis housing where the reverse osmosis cartridge serves to separate the water so that a more mineral-free water enters the precipitation tank, and so that the mineral laden water exits the reverse osmosis cartridge through the inline restrictor and into the mixing chamber.
In another preferred embodiment, the brine tank further includes: a sealed mixing chamber, wherein a by-pass stream exiting the reverse osmosis system enters a restrictor and is then directed to the top of the sealed mixing chamber where the by-pass stream efficiently combines with chlorine gas and forms a chlorinated liquid that is then directed to the water being treated. In a further preferred embodiment, the sealed mixing chamber is mounted inside the brine tank above a highest water level within the brine tank, thereby eliminating leaks.
In another further preferred embodiment, the apparatus includes: a precipitation tank, connected to the inside of the brine tank, wherein a more mineral-free water that has exited the reverse osmosis cartridge is mixed with a high pH liquid that is pumped from the cathode electrode chamber of the chlorine-generating cell, thereby causing additional minerals in the more mineral-free water to precipitate to the bottom of the precipitation tank, resulting in a much softer water that then flows into the brine tank. In a still further preferred embodiment, the precipitation tank includes a pH valve that can be opened so as to allow some high pH water to be directed to waste, thereby lowering the pH of the chlorinated liquid exiting the unit.
In another further preferred embodiment, the cathode electrode compartment of the chlorine-generating cell produces a high pH solution, which is pumped from the cathode electrode chamber to the precipitation tank, and is then mixed with the reduced-mineral water exiting the reverse osmosis cartridge, thereby causing dissolved minerals to precipitate to the bottom of the precipitation tank, thereby substantially reducing the amount of dissolved minerals entering the brine tank.
In a preferred embodiment, the chlorine-generating cell includes: a chlorine-generating cell container that: separates the un-dissolved salt in the bottom of the brine tank from the brine water, while allowing the brine water to enter an intake of the anode electrode chamber of the chlorine generating cell, the intake being located in the bottom portion of the cell container, thereby preventing un-dissolved salt from entering the intake of the anode electrode chamber of the chlorine-generating cell; and allows softened mild salt water at the top of the chlorine-generating cell container to be directed to the intake of the cathode electrode chamber of the chlorine-generating cell. In a further preferred embodiment, the chlorine-generating cell container has a series of small holes in its side wall, and is sealed at the bottom so as to form a pocket that discourages chlorinated brine water returning from the dewatering device from migrating throughout the bottom of the brine tank, thereby improving efficiency of production of chlorine gas delivered to the dewatering device, and thereby minimizing the amount of chlorine fumes escaping from the brine tank.
In a preferred embodiment, the apparatus further includes a cell-cleaning reservoir, connected to the a chlorine-generating cell, the cell cleaning reservoir storing an acidic solution that is sent to: the chlorine-generating cell, the mixing chamber, and plumbing going to a body of water to be treated.
In another preferred embodiment, the apparatus further includes a cell-cleaning reservoir, connected to the chlorine-generating cell, the cell cleaning reservoir having an air injection fitting that can be used to attach a compressed air source that can be used to empty the cell-cleaning reservoir of solution by injecting compressed air.
In a further preferred embodiment, the cell-cleaning reservoir includes: an electrical circuit that can be programmed to periodically activate the release of household water into the cell-cleaning reservoir which in turn forces a portion of the acidic solution from the cell-cleaning reservoir so as to clean: the chlorine-generating cell, the mixing chamber, and the plumbing going to the body of water to be treated. In a further preferred embodiment, the apparatus includes a solid state power supply with thermal protection that incorporates full voltage regulation, such that when the acidic solution is injected into the chlorine-generating cell, the acid will not cause an electrical overload.
In a further preferred embodiment, the apparatus includes: a solid state power supply that can react to information delivered by a controlling unit capable of sensing at least one of the readings of the water being treated, including: pH, chlorine, and copper/silver ions.
In another further preferred embodiment, the apparatus includes: a solid state power supply that has an optional circuit having a 24-hour programmable timer; and a pulsating circuit controlling device adapted to power an ionizing copper/silver cell installed in a circulating system of the body of water being treated.
In a preferred embodiment, the apparatus further includes: a check valve, installed in a chlorine exit line connected to the chlorine-generating cell, the check valve preventing back-up water from back-flowing into the unit when the same line for delivering make up water is used for adding chlorine from the unit.
The present invention may best be understood by reference to the following description taken in connection with the accompanying figures, wherein:
Water exits one side of the incoming water tee fitting 41 enters water “in” fitting 101 of the cleaning solenoid valve, flows through cleaning solenoid valve 102 and exits through fitting 103. Water then enters the top of the brine tank 13 through cleaning water tube hole 105, goes Out through tube 106 and connects to Teflon tee 107 which connects to “in” PVC fitting 139 (see
The other side of tee 41 connects to water “in” fitting 43. Water enters the water solenoid valve 44 through fitting 43. The water exits the water solenoid valve 44 through tubing connected to water exit fitting 45. The tubing then goes through top hole 46 in top of brine tank 13. The water then enters the heat exchanger 47 (see
1. The by-pass water exits the reverse osmosis unit 58 through by-pass exit fitting 70 through black exit tube 71 to inline flow restrictor 72. By-pass water then enters the inline flow restrictor 72, and then flows through Teflon fitting 73. The water then enters water p-trap fitting 75. The water then goes through the brine tank 13, through by-pass “in” fitting 76 and enters the mixer 210 (see
2. The softened water exits the reverse osmosis unit 58 through 90° water fitting 59 and flows through softened water tube 60, which is connected to 90° fitting 61, which goes through the wall of the brine tank 13. The softened water then continues through softened water tube 60 and discharges into the precipitation tank 128 (
The by-pass water is mixed with chlorine gas in the mixer 210; (see
Extending upwards from the chlorine exit tee 14 is a vent pipe 25. At the top of the vent pipe 25, there is a vent pipe 180° bend 26 and the vent pipe continues down ending near the bottom of the outside of the brine tank 13.
The aluminum power supply cabinet 160 is mounted on top of the brine tank 13 cabinet (see
Internally, there are two perforated disks 215 that allow liquid to flow through them but retain the medium 214 in their proper place. Overflow water from the brine tank 13 enters the bottom of the mixer at 216. The liquid and manufactured chemicals gravity feed out of the lower threaded nipple 218 through the wall of the brine tank 13 on their way to the pool.
During the construction of the pool, a separate chlorine pipe 180 is installed that exits the side of the pool through a wall fitting 179. Usually the line is a 1½ to 2 inch. PVC pipe that runs from the pool to the equipment pad providing that the pad is level with, or higher than, the water in the pool. Where the pipe protrudes out of the equipment pad, two PVC tees are installed. One tee, the chlorine reducing tee 181, is installed leading to a Teflon ¼″ fitting 183 for the chlorinated liquid to enter the chlorine pipe 180 at the equipment pad. The other is the filtered water PVC tee 188, which is installed on the chlorine pipe 180 at the equipment pad. A PVC pipe 190 is connected between filtered water tee 191 and tee 188 that provides a small adjustable stream of filtered water. A check valve 189 is installed in pipe 190 to prevent air from entering the pool's filter and pumping system when the filter pump is in the “off” position. A flow control valve 193 is installed in line 190. A separate chlorine line 180 is extended up approximately 18 inches and a PVC cap 186 is installed. The cap has a small vent hole 184 in it.
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Feb 02 2021 | TUCKER, DANIEL MORONI | ULTIMATE WATER, INC | ASSIGNMENT OF ASSIGNORS INTEREST SEE DOCUMENT FOR DETAILS | 055114 | /0394 | |
Aug 07 2024 | ULTIMATE WATER, INC | HASA, INC | ASSIGNMENT OF ASSIGNORS INTEREST SEE DOCUMENT FOR DETAILS | 068221 | /0376 | |
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