An integrated circuit (IC) sensor is described. The IC sensor includes a pixel array and IC components. The pixel array has a plurality of pixels, wherein each pixel includes an emr absorption region including a detector material having a plurality of nanoparticles embedded in a matrix material and exhibiting a nano-plasmonic property. The IC components are arranged to provide amplification of a voltage signal from the emr absorption region, and to select the voltage signal from the emr absorption region.
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1. An integrated circuit (IC) sensor, comprising:
a pixel array comprising a plurality of pixels, wherein each pixel comprises an emr absorption region comprising a detector material having a plurality of nanoparticles embedded in a matrix material and exhibiting a nano-plasmonic property;
IC components arranged to provide amplification of a voltage signal from the emr absorption region, and to select the voltage signal from the emr absorption region,
wherein the matrix material comprises a first matrix material and a second matrix material,
wherein the first matrix material comprises a doped silicon well region contacting the nano-particles; and
a doped contact on the well region.
3. The IC sensor of
4. The IC sensor of
5. The IC sensor of
6. The IC sensor of
7. The IC sensor of
8. The IC sensor of
9. The IC sensor of
wherein the second matrix material comprises an amorphous silicon layer contacting the nano-particles and the first matrix material.
11. The IC sensor of
12. The IC sensor of
13. The IC sensor of
14. The IC sensor of
15. The IC sensor of
16. The IC sensor
17. The IC sensor of
row access drivers configured to access rows of the pixel array.
18. The IC sensor of
a column amplifier configured to amplify a signal from pixels in columns of the pixel array.
19. The IC sensor of
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This application is a continuation-in-part application of U.S. application Ser. No. 13/690,276, filed Nov. 30, 2012, entitled VIS-NIR PLASMONIC APD DETECTORS, which is a continuation-in-part application of U.S. application Ser. No. 13/360,570, filed Jan. 27, 2012, entitled APDs USING NANO-PLASMONIC METAMATERIALS, which is a continuation-in-part application of U.S. application Ser. No. 13/243,342, filed Sep. 23, 2011, entitled NANO-STRUCTURE ARRAYS FOR EMR IMAGING, the entire contents of which are incorporated by reference.
The present disclosure relates to an image sensor incorporating a nano-plasmonic structure in an integrated circuit, such as a CMOS (complimentary metal-oxide-semiconductor) integrated circuit, or a CCD (charge coupled device) integrated circuit.
Image sensors using CMOS architecture, or CCD architecture, are known. For example, a CMOS active-pixel sensor (APS) typically includes an array of pixel sensors, where each pixel has a photodetector and an active amplifier. Such a CMOS image sensor is produced by a CMOS process. Electromagnetic radiation (EMR), such as visible light, impinging upon a pixel, is converted to electrons and sensed by the pixel. Circuitry next to each photodetector of a pixel converts the light energy to a voltage.
Image sensors are limited to sensing EMR within a wavelength band or bands, to which the pixel material is sensitive. For example, typical pixel sensors are made of silicon, and are sensitive to EMR wavelengths to which silicon is responsive. Sensing other wavelengths such as short-wave infrared (SWIR), mid-wave infrared (MWIR) or long-wave infrared (LWIR), is generally not possible with a silicon based CMOS image sensing array.
According to one embodiment, there is provided an integrated circuit (IC) sensor, comprising: a pixel array comprising a plurality of pixels, wherein each pixel comprises an EMR absorption region comprising a detector material having a plurality of nanoparticles embedded in a matrix material and exhibiting a nano-plasmonic property; and IC components arranged to provide amplification of a voltage signal from the EMR absorption region, and to select the voltage signal from the EMR absorption region.
According to one aspect of the embodiment, the pixel array comprises a semiconductor substrate.
According to another aspect of the embodiment, the semiconductor substrate comprises at least one of a IV semiconductor, a IV-VI semiconductor, a II-VI semiconductor, or a III-V semiconductor.
According to another aspect of the embodiment, the IC sensor is a charge coupled device (CCD) sensor.
According to another aspect of the embodiment, the IC sensor is a complimentary metal-oxide-semiconductor (CMOS) sensor, and the IC components are CMOS components.
According to another aspect of the embodiment, the CMOS components are arranged in a five transistor arrangement.
According to another aspect of the embodiment, the CMOS components include a source follower transistor arranged to provide amplification of the voltage signal from the EMR absorption region.
According to another aspect of the embodiment, the CMOS components include a select transistor arranged to select the voltage signal from the EMR absorption region.
According to another aspect of the embodiment, the matrix material comprises a first matrix material and a second matrix material.
According to another aspect of the embodiment, the first matrix material comprises a doped silicon well region contacting the nano-particles.
According to another aspect of the embodiment, the doped silicon well region comprises a n-well contacting the nano-particles.
According to another aspect of the embodiment, the doped silicon well region comprises a n-well and a p-well on the n-well, the p-well contacting the nano-particles.
According to another aspect of the embodiment, the second matrix material comprises an amorphous silicon layer contacting the nano-particles and the first matrix material.
According to another aspect of the embodiment, the IC sensor further comprises a doped contact on the well region.
According to another aspect of the embodiment, the IC sensor further comprises a doped contact on the amorphous silicon layer.
According to another aspect of the embodiment, the IC sensor further comprises a metal interconnect contacting the doped contact.
According to another aspect of the embodiment, the IC sensor further comprises a p+ doped contact on the p-well, and a n+ doped contact on the n-well.
According to another aspect of the embodiment, the nano-particles are formed of gold, silver, aluminum, oxides, or nitrides.
According to another aspect of the embodiment, the shape of the nano-particles is one of cylindrical, spherical, cubic, rectangular-cubic, ellipsoidal, planar, chevrons, slots, near-planar or spiral-twisted.
According to another aspect of the embodiment, the IC sensor further comprises row access drivers configured to access rows of the pixel array.
According to another aspect of the embodiment, the IC sensor further comprises a column amplifier configured to amplify a signal from pixels in columns of the pixel array.
According to another aspect of the embodiment, the nano-particles are arranged in a substantially regular array.
According to another embodiment, there is provided a method of forming an integrated circuit (IC) sensor, comprising: forming an IC region comprising an IC component on a substrate; and forming a plasmonic pixel region on the substrate, comprising: forming a first matrix material in the substrate; forming a plurality of nano-particles contacting the first matrix material; and forming a second matrix material contacting the first matrix material and the plurality of nano-particles, wherein the first matrix material and the second matrix material together form a matrix material which embeds the nano-particles, such that matrix material together with the nano-particles exhibit a nano-plasmonic property.
According to an aspect of the one embodiment, the substrate comprises a semiconductor substrate.
According to another aspect of the one embodiment, the semiconductor substrate comprises at least one of a IV semiconductor, a IV-VI semiconductor, a II-VI semiconductor, or a III-V semiconductor.
According to another aspect of the one embodiment, the IC sensor is a charge coupled device (CCD) sensor.
According to another aspect of the one embodiment, the IC sensor is a complimentary metal-oxide-semiconductor (CMOS) sensor, and the IC component is a CMOS component.
According to another aspect of the embodiment, the method further comprises: forming a dielectric passivation layer on the first matrix material; and forming a window in the dielectric passivation layer to expose the first matrix material.
According to another aspect of the embodiment, the forming the first matrix material comprises implanting the substrate to form a doped silicon well region.
According to another aspect of the embodiment, the method further comprises implanting to form a doped contact on the doped silicon well region.
According to another aspect of the embodiment, the implanting comprises implanting to form a n-well.
According to another aspect of the embodiment, the implanting further comprises implanting to form a p-well on the n-well.
According to another aspect of the embodiment, the method further comprises: implanting to form a p+ doped contact on the p-well; and implanting to form a n+ doped contact on the n-well.
According to another aspect of the embodiment, the forming the second matrix material comprises forming a doped amorphous silicon layer.
According to another aspect of the embodiment, the method further comprises: implanting to form a doped contact on the amorphous silicon layer.
According to another aspect of the embodiment, the forming the plurality of nano-particles comprises: depositing a nano-particle material on the first matrix material; and patterning the nano-particle material to form the plurality of nano-particles.
According to another aspect of the one embodiment, the patterning the nano-particle material comprises performing electron beam lithography on the nano-particle material.
According to another aspect of the one embodiment, the nano-particles are formed of gold, silver, aluminum, oxides, or nitrides.
According to another aspect of the one embodiment, the shape of the nano-particles is one of cylindrical, spherical, cubic, rectangular-cubic, ellipsoidal, planar, chevrons, slots, near-planar or spiral-twisted.
According to another aspect of the one embodiment, the nano-particles are arranged in a substantially regular array.
The sensors described herein incorporate integrated circuit processing, such as a CMOS process with the formation of nano-plasmonic structures for detection of EMR in a desired wavelength range, which allows for detection of wavelengths over several regions of the EMR spectrum according to one embodiment. The use of appropriately chosen nano-plasmonic structures allow EMR detection in the UV, visible, SWIR, MWIR and LWIR regions according to one embodiment. The electrons generated by EMR absorption by the nano-plasmonic structures provide a detectable signal that can be sensed electronically with appropriate amplification, discrimination and signal processing according to one embodiment. By incorporating nano-plasmonic structures with circuits on a CMOS integrated circuit, it is possible to create a monolithic, uncooled semiconductor device that is responsive to a complete range of UV, visible, and IR wavelengths according to one embodiment.
In an embodiment of the present invention, the pixel sensor material for sensing EMR includes nanostructure, such as nano-particles having an appropriate geometry (size, shape, orientation and spacing), embedded in a matrix material, so that the sensor material is sensitive to EMR in a desired wavelength range. The present inventors have found that by appropriately selecting the geometry and materials for a detector material comprising a substantially regular array of nanoparticles embedded in a matrix material, and by applying an appropriate bias voltage to the matrix material, a direct electrical current may be generated based on a cooperative plasmon effect in the detector material when EMR in a desired wavelength range is incident upon the detector material, and where the dominant mechanism for decay in the cooperative plasmon effect is nonradiative according to one embodiment. Thus the detector material, comprising the substantially regular array of nanoparticles embedded in the matrix material, has a nano-plasmonic property, where the nano-plasmonic property means that when an appropriate bias voltage is applied to the matrix material, a direct electrical current may be generated based on a cooperative plasmon effect in the detector material when EMR in a desired wavelength range is incident upon the detector material, and where the dominant mechanism for decay in the cooperative plasmon effect is nonradiative. The detector material may be arranged in an EMR absorption region of the detection device.
An important concept in certain embodiments of the nano-plasmonics detector designs disclosed here is the replacement of the currently ubiquitous semiconductor EMR absorption region, by a lattice structured nano-plasmonic meta-material absorber. The concept of a lattice structured nano-plasmonic meta-material absorber is described in detail in U.S. Application No. 13,243,342, filed Sep. 23, 2011, entitled NANO-STRUCTURE ARRAYS FOR EMR IMAGING, incorporated by reference herein in its entirety. The concept of a nano-plasmonic detector using gold nanoparticles is described in U.S. application Ser. No. 13,360,570, filed Jan. 27, 2012, entitled APDs USING NANO-PLASMONIC METAMATERIALS, incorporated by reference herein in its entirety. The concept of a nano-plasmonic detector using silver or aluminum nano-particles is described in U.S. Application No. 13,690,276, filed Nov. 30, 2012, entitled VIS-NIR PLASMONIC APD DETECTORS, incorporated by reference herein in its entirety. The nano-plasmonic designs disclosed here allow for EMR absorption in the nano-particles under conditions sufficient to release electrons through a modified Schottky barrier unipolar transport process. An important aspect of the structure is its characteristic long decay-time of the collective interactions, which enable the electrons to interact with the Schottky barrier.
The geometry of
FIGS. 3 and 4A-4F are cross-sectional views illustrating an IC region 300, and a plasmonic pixel region 400, respectively, during the manufacturing of the sensor.
The N-FET 340 includes a gate dielectric 346 and gate 348 formed, for example, by formation of a dielectric and gate material, followed by patterning. The gate material may include polysilicon, for example. Source/drain regions 344 are formed in the p-doped substrate 390, for example, by a n+ dopant to implant n+ regions using the gate 348 as an implant mask.
In operation, substrate 390 is typically connected to ground (VSS). The n-well 312 is typically connected to the highest positive voltage in the system, so the source/drain 314 and n-well regions 312 are reverse biased and therefore electrically isolated. Source/drain connections and gate connections are typically made by metal interconnects through ohmic n+/p+ contacts.
A p+ contact 416 is made in the p-well 410 by implanting p dopant, for example. Likewise a n+ contact 418 is made in the n-well 412 by implanting n dopant, for example. The p dopant implant may be the same implant process step used to form the PFET source/drain regions 314 in
Metal interconnects 420 and 424 are formed to contact the n+ contact 418 and the p+ contact 416, respectively. The metal interconnects 420 and 424 may be formed of Al or Cu for example, and may include vertically aligned plugs of tungsten, for example. An interlevel dielectric 428 is provided to insulate the metal interconnects from each other. The metal interconnects 420 and 424 connect to CMOS logic of the sensor.
Dielectric passivation layer 430 is formed covering the p well 412. The dielectric passivation layer 430 may be a thermal oxide, for example.
While
Referring to
Referring to
The nano-particles 436, for example, may comprise gold, aluminum, silver or oxides, for example, depending upon the desired EMR wavelength to be detected. The nano-particles 436 may be formed using a variety of nanolithographic techniques, and may have a variety of shapes such as cylindrical, spherical, cubic, rectangular-cubic, ellipsoidal, planar, chevrons, slots, near-planar or spiral-twisted. As one example, the nano-particles 436 may be gold particles which are 20 nm thick, 20-50 nm wide, and 400 to 1000 nm long. The nano-particles 436 may formed by depositing the material for the nano-particles followed by patterning the nano-particles by electron beam lithography to form an array of nanostructures. Certain nanoscale materials and fabrication processes, such as gold deposited on silicon, may be sensitive to high processing temperatures. In this case, all high temperature semiconductor processing should be completed before any nanoscale fabrication occurs.
The nano-particles 436 should have a good contact to the first matrix material layer 414 to ensure an appropriate nano-plasmonic effect. Therefore any dielectric, such as thermal or native oxide, should be removed prior to forming the nano-particles 436 on the first matrix material layer 414. Further, certain typical seed metals such as titanium that inhibit plasmonic behavior may need to be avoided.
Referring to
Referring to
Referring to
Referring to
The notional pixel 500 of
In operation to bias a pixel, a voltage may be driven externally by a control circuit onto the shared COL during the pixel reset time, the bias1 transistor MB1 is driven on by a voltage applied on the RST, and the bias2 transistor MB2 is driven by ROW going high. In the case of the pixel material including amorphous silicon as the matrix material, this operation causes the voltage on COL to be driven onto the amorphous silicon that surrounds the nano-particles. In general, to access the pixels of a column of the array, a voltage is driven to COL, and then rows are sequentially driven by sequentially driving ROW.
In order to provide an appropriate voltage to bias the individual pixels of an M column and N row array, an M×N table may be used, where the table contains the respective values of the voltages driven onto each pixel. That is, the pixel in row i, column j, is driven by the voltage having the value in the ith, jth element of the M×N table. A mechanism of driving the voltages on the pixels may be implemented such that at each frame time the voltage driven on the pixels are refreshed at a full frame rate.
While
The sensors described herein incorporate the CMOS process with the formation of nano-plasmonic structures for detection of EMR in a desired wavelength range, which allows for detection of wavelengths over several regions of the EMR spectrum in a CMOS process.
The embodiments of the invention have been described in detail with particular reference to preferred embodiments thereof, but it will be understood by those skilled in the art that variations and modifications can be effected within the spirit and scope of the invention.
Koenck, Steven E., Jensen, David W., Brown, Robert G.
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