A method of controlling a reactive sputter deposition process includes selecting a control process parameter for a target material and a reactive gas, the target material included in a target acting as a cathode, the reactive sputter deposition process involving forming a compound from a reaction between the target material and reactive gas species associated with the reactive gas in a vacuum chamber; establishing an operation regime for the reactive sputter deposition process for a given target power; and performing, based on the selected control process parameter and the established operation regime, the reactive sputter deposition process in a transition region between a metallic mode and a covered mode through a controlled pulsed reactive gas flow rate into the vacuum chamber, such that a stabilized reactive deposition of the compound on a substrate is achieved, the deposited compound on the substrate comprising a dielectric stoichiometric film.
|
1. A method of controlling a reactive sputter deposition process, comprising:
selecting a control process parameter for a target material and a reactive gas, the target material included in a target acting as a cathode, the reactive sputter deposition process involving forming a compound from a reaction between the target material and reactive gas species associated with the reactive gas in a vacuum chamber;
establishing an operation regime for the reactive sputter deposition process for a given target power; and
performing, based on the selected control process parameter and the established operation regime, the reactive sputter deposition process in a transition region between a metallic mode and a covered mode through a controlled pulsed reactive gas flow rate into the vacuum chamber, such that a stabilized reactive deposition of the compound on a substrate is achieved, the deposited compound on the substrate comprising a dielectric stoichiometric film.
12. A reactive sputter deposition apparatus, comprising:
a vacuum chamber;
an anode;
a reactive gas source providing a reactive gas into the vacuum chamber;
a target including a target material and acting as a cathode in the vacuum chamber;
a power supply electrically coupled to the target such that the target is selectively powered by the power supply to generate a discharge plasma in the vacuum chamber with reactive gas species associated with the reactive gas that combine with the target material to form a compound; and
a control device configured to sense time-dependent values of a control process parameter and provide a signal to at least one mass flow controller to adjust a pulsed reactive gas flow rate into the vacuum chamber at a constant value of a non-reactive gas partial pressure to perform a stabilized reactive deposition of the compound on a substrate and with a minimized arcing in a transition region between a metallic mode and covered mode, the deposited compound on the substrate comprising a dielectric stoichiometric film.
2. The method of
3. The method of
4. The method of
5. The method of
wherein the particular sputtering current comprises one of:
a target current in case of continuous direct-current (DC) sputtering and
an average target current in a period of a pulsed power supply in case of pulsed sputtering.
6. The method of
7. The method of
selecting one of the particular sputtering current and the reactive gas partial pressure with a higher of the first and second sensitivities as the control process parameter.
8. The method of
9. The method of
10. The method of
a constant target voltage using a DC power supply and a constant target voltage during discharge pulses using a pulsed power supply.
11. The method of
13. The reactive sputter deposition apparatus of
maintain the pulsed reactive gas flow rate by at least one of the mass flow controller or the non-reactive gas partial pressure in the vacuum chamber, and
determine the pulsed reactive gas flow rate from a total gas pressure in the vacuum chamber measured at a fixed preset value of the non-reactive gas partial pressure.
14. The reactive sputter deposition apparatus of
15. The reactive sputter deposition apparatus of
simultaneously monitor in time both the reactive gas partial pressure in the vacuum chamber and a particular sputtering current to determine a first sensitivity of the reactive gas partial pressure and a second sensitivity of the particular sputtering current to constant flow rate pulses of the reactive gas into the vacuum chamber at a constant target voltage under same discharge conditions, respectively, and
select, for a given target material and reactive gas, one of the reactive gas partial pressure and the particular sputtering current with a higher sensitivity of the first and second sensitivities as the control process parameter.
16. The reactive sputter deposition apparatus of
a target current in case of continuous DC sputtering and
an average target current in a period of a pulsed power supply in case of pulsed sputtering.
17. The reactive sputter deposition apparatus of
18. The reactive sputter deposition apparatus of
19. The reactive sputter deposition apparatus of
wherein the pulsed power supplies processing an internal or external computer control allowing to evaluate a time-dependent average target current in a period of the pulsed power supply during the reactive gas flow rate pulsing.
20. The reactive sputter deposition apparatus of
|
This application is a continuation of and claims priority under 35 U.S.C. §120 to PCT Application No. PCT/EP2014/051233 filed on Jan. 22, 2014, which claimed priority to European Application No. EP 13 155 936.1, filed on Feb. 20, 2013. The contents of both of these priority applications are hereby incorporated by reference in their entirety.
This disclosure relates to methods, systems, and apparatus for reactive sputtering, particularly for establishing high-rate depositions of dielectric stoichiometric films with minimized arcing.
Dielectric films (particularly oxides and nitrides) are widely used in a broad range of applications such as semiconductor chips, magnetic and optical recording, flat panel displays, ink jet printer heads, solar cells, integrated optics, optical films, and hard protective films. Reactive magnetron sputtering which involves sputtering a metal target in argon-oxygen or argon-nitrogen gas mixtures is a commonly used deposition method to produce these films. However, control of such a reactive sputtering process to both maximize the rate of deposition or film formation and to achieve a proper film stoichiometry has been difficult to accomplish.
Reactive sputtering is a very versatile coating technique that allows the preparation of a wide variety of compound materials. However, it has traditionally had one major drawback. When the partial pressure of the reactive gas (e.g., oxygen or nitrogen) reaches the right level to form a stoichiometric film of the metal compound (e.g., oxide or nitride) on the surface of a substrate, it also forms the same metal compound on the surface of the metal target. This, in turn, results in a substantially reduced deposition rate of the films due to low sputtering yield of the metal atoms from the compound part of the metal target. In addition, considerable arcing, leading to a low quality of the deposited films, can be observed on the target under these conditions at high target power densities applied (e.g., during high power impulse magnetron sputtering). Arcing indicates the generation of short circuits between the target (cathode) and an anode or electric ground of vacuum system, caused by the build-up of insulating films on the target. There are two “modes” of operation for reactive sputtering of a metal target to deposit a compound film. For a low flow rate of the reactive gas into the vacuum chamber, the target remains metallic. For a high flow rate of the reactive gas, the target is covered by the compound. Much higher (usually 5 to 10 times) deposition rates are achieved in the “metallic mode” than in the “covered (poisoned) mode”.
A recent development of the well-established magnetron sputtering technique is the high power impulse magnetron sputtering (HiPIMS) which is characterized by target power densities applied during short voltage pulses. The high target power density leads to the generation of very dense discharge plasmas with high degrees of ionization of sputtered atoms. Consequently, film deposition can be carried out at highly ionized fluxes of the target material atoms. This is of significant interest for directional deposition into high aspect ratio trench and via structures, for substrate-coating interface engineering and ion-assisted growth of films. In spite of several successful applications of these systems to reactive sputter depositions of dielectric films, there are still substantial problems with arcing during the deposition processes at high target power densities and with low deposition rates achieved.
Accordingly, there is a need in the art of HiPIMS for a method and apparatus providing effective and reliable control of the reactive sputtering process to achieve high-rate deposition of dielectric stoichiometric films with minimized arcing.
The present invention overcomes the above mentioned problems, even when high power impulse magnetron sputtering a metal target is used, by providing a reactive sputtering processing system and method that controls a pulsed reactive gas flow rate into a vacuum chamber at a constant target voltage, kept by a power supply, to promote a high-rate deposition of dielectric stoichiometric films in a transition region between a metallic mode and a covered (poisoned) mode.
As the reactive gas flow rate is varied, there is a transition between the metallic mode and the covered mode exhibiting hysteresis; i.e., the difference in the deposition rate (and the target voltage) depending on whether a specific sputtering state is entered from the metallic mode or from the covered mode under otherwise identical process conditions. To form high-quality dielectric stoichiometric films at a high rate, reactive sputtering can be operated in the transition region between the metallic mode and the covered mode.
One aspect of the invention features a method of controlling a reactive sputter deposition process. The method includes selecting a control process parameter for a target material and a reactive gas, the target material included in a target acting as a cathode, the reactive sputter deposition process involving forming a compound from a reaction between the target material and reactive gas species associated with the reactive gas in a vacuum chamber; establishing an operation regime for the reactive sputter deposition process for a given target power; and performing, based on the selected control process parameter and the established operation regime, the reactive sputter deposition process in a transition region between a metallic mode and a covered mode through a controlled pulsed reactive gas flow rate into the vacuum chamber, such that a stabilized reactive deposition of the compound on a substrate is achieved, the deposited compound on the substrate comprising a dielectric stoichiometric film.
The method makes it possible to utilize benefits of the HiPIMS discharges with target power densities of up to several kWcm-2 during short target voltage pulses (typically 40 μs to 200 μs) in high-rate depositions of dielectric stoichiometric films.
The transition region between a metallic mode and a covered mode may be determined based on a range of the reactive gas partial pressure in the vacuum chamber defined using a critical value of the control process parameter. In some implementations, for a given target material and reactive process gas, one of the two process parameters (namely, the target current, alternatively the average target current in a period of a pulsed power supply, or the reactive gas partial pressure in the vacuum chamber), which are simultaneously monitored in time by a process controller, is selected as a control process parameter. For a given nominal target power, and the target material and the reactive process gas, an optimized constant target voltage, non-reactive gas (argon) partial pressure, total reactive gas flow rate into the vacuum chamber and configuration of the reactive gas conduit system, together with a critical value of the control process parameter selected, are determined empirically using the apparatus controlling the reactive sputtering process on the basis of the sensed time-dependent values of the control parameter. This determination is based on measurements of the deposition rates and characterization of the films deposited. The critical value of the control parameter defines a range of the reactive gas partial pressure in the chamber through the controlled pulsed reactive gas flow rate into the chamber allowing to perform a stabilized high-rate reactive magnetron deposition of dielectric stoichiometric films in a transition region between a metallic mode and a covered (poisoned) mode.
The target may be a metal and a compound formed from the reaction may be a dielectric stoichiometric material. The sputter deposition of a compound onto a substrate may be performed at a rate at least about 40% of a rate of deposition of the target material in a metallic mode corresponding to operating without the presence of said reactive gas at substantially the same power conditions.
The compound may be selected from the group comprising oxides, nitrides, oxynitrides, carbides, sulfides, fluorides, chlorides, borides, and mixtures thereof. The control process parameter may be the target current in case of continuous DC sputtering, or the average target current in a period of a pulsed power supply in case of pulsed sputtering, or the reactive gas partial pressure in a vacuum chamber.
The sensitivity of the target current in case of continuous DC sputtering, or of the average target current in a period of a pulsed power supply in case of pulsed sputtering, and of the reactive gas partial pressure in a vacuum chamber to constant flow rate pulses of the reactive gas into the vacuum chamber at a constant target voltage under the same discharge conditions is determined. In other words, process characterization is carried out and it is determined how the parameters mentioned above respond to constant flow rate pulses of the reactive gas into the vacuum chamber at a constant target voltage under the same discharge conditions. The parameter showing the highest sensitivity to constant flow rate pulses of the reactive gas into the vacuum chamber at a constant target voltage under the same discharge conditions may be selected as control process parameter.
The operation regime may be established based on determining an (optimized) constant target voltage, non-reactive gas (e.g., argon), partial pressure, total reactive gas flow rate into the vacuum chamber and configuration of the reactive gas conduit system, together with a critical value of the control process parameter selected, such that a given deposition rate and desired physical properties of films formed are achieved at arcing below a given level.
This results in high deposition rates and desired elemental compositions and physical properties of films formed at a minimized arcing. The determination of the above quantities is based on fundamental knowledge in the art of reactive magnetron sputtering, on measurements of the deposition rates, on characterization of the films deposited and on detection of discharge instabilities (arcs).
The critical value of the control process parameter may be used to define the times of terminations and successive initiations of preset constant reactive gas flow rate pulses into the vacuum chamber. The target power may be supplied at a constant target voltage using a DC power supply or at a constant target voltage during discharge pulses using a pulsed power supply, including a high power pulsed DC power supply with target power densities of up to several kWcm−2 in short target voltage pulses.
Another aspect of the invention features a reactive sputter deposition apparatus, comprising: a vacuum chamber; an anode; a reactive gas source that provides a reactive gas into the vacuum chamber, the reactive gas characterized by a given pulsed flow rate into the chamber, maintained by mass flow controllers, or by a given partial pressure in the chamber, determined from a total gas pressure in the chamber measured at a fixed preset value of the non-reactive gas partial pressure; a target as a cathode in the vacuum chamber and including a material to be combined with reactive gas species to form a compound; a power supply electrically coupled to said target such that said target may be selectively powered by the power supply to generate a discharge plasma in the chamber with the reactive gas species that combine with the material of the target to form the compound; a control device that senses time-dependent values of said control process parameter and provides a signal to said mass flow controllers to adjust a pulsed reactive gas flow rate into the vacuum chamber at a constant value of the non-reactive gas partial pressure to perform a stabilized reactive deposition of dielectric stoichiometric films at high rates and a minimized arcing in a transition region between a metallic mode and covered mode.
The target may be a metal and the compound may be a dielectric stoichiometric material. The control device may be configured to allow simultaneously monitoring in time both the reactive gas partial pressure in said vacuum chamber, and either the target current in case of continuous DC sputtering or the average target current in a period of a pulsed power supply in case of pulsed sputtering to select one of them as said control process parameter for a given target material and reactive process gas on the basis of a higher sensitivity of one of these quantities to constant flow rate pulses of said reactive gas into said vacuum chamber at a constant target voltage under the same discharge conditions.
The power supply may be a DC power supply operating at a constant target voltage or a pulsed power supply operating at a constant target voltage during discharge pulses, including a high power pulsed DC power supply with target power densities of up to several kWcm−2 in short target voltage pulses, the pulsed power supplies possessing an internal or external computer control allowing to evaluate a time-dependent average target current in a period of the pulsed power supply during the reactive gas flow rate pulsing.
The invention may take physical form in certain parts and arrangement of parts, embodiments of which will be described in detail in this specification and illustrated in the accompanying drawings which form a part hereof.
The method and associated apparatus of the present invention are designed to control and preferably optimize the conditions for interaction between target material atoms and reactive gas atoms and molecules on the target surface, on the surface of growing films and in the discharge plasma during reactive high power magnetron sputtering (particularly HiPIMS) a metal target such that high quality dielectric stoichiometric films may be deposited at high deposition rates.
Referring to
A non-reactive gas (e.g., inert gas like argon) is admitted to chamber 10 from a source 20 via a mass flow controller 22, shut-off valve 24, and conduit. A reactive gas (e.g., oxygen, nitrogen, methane, acetylene, etc.) is provided from a source 26 through mass flow controllers 28 and 30, shut-off valves 32 and 34, and via conduits 36 and 38 located generally at two different positions in front of the sputtered target to reduce the target coverage by a compound particularly during a high power magnetron sputtering process, when the degree of dissociation of the reactive gas molecules is significantly increased not only in the flux onto the substrate but also in the flux onto the target. In an alternative embodiment, the reactive gas source 26 may be replaced by two sources of different reactive gases (e.g., oxygen and nitrogen) to reactively sputter deposit ternary compounds (e.g., oxynitrides or mixtures of oxide and nitride material phases). A pressure sensor 40 measures the total pressure in the vacuum chamber at a fixed preset value of the argon partial pressure, kept by mass flow controller 22. A process controller 42 (preferably a programmable logical controller) provides a control signal to the mass flow controllers 28 and 30 on the basis of sensed time-dependent values of either the target current (alternatively, the average target current in a period, which may be evaluated by a computer controlling the operation of a pulsed power supply 44 used), e.g., for sputter deposition of ZrO2 films, or the total pressure in vacuum chamber determined by the pressure sensor 40 (e.g., for sputter deposition of Ta2O5 films), as will be further explained below.
The power supply 44 provides power to target 18 (e.g., by an electrically conductive connection of a cathode terminal conductor to the target, the target thus acting as part of the cathode when so connected). In a preferred embodiment of the present invention, a high power pulsed DC power supply 44 with arc handling capabilities (a fast arc detection and suppression technique) provides short (typically 40 μs to 200 μs) negative constant-voltage pulses at the target with target power densities on the order of kWcm−2 and a typical duty cycle (ratio of the voltage pulse duration to the period duration) in the range from 2% to 10%. Alternative implementations of the present invention may employ various continuous DC, pulsed or RF power supplies as the power supply 44, such target power supply techniques being generally known in the art.
Accordingly, in a reactive sputtering process, reactive and non-reactive gases flow into the chamber, and power supplied to the cathode provides an electric potential between the cathode and the anode, thus generating a discharge plasma in the chamber. The plasma includes non-reactive gas atoms and ions, reactive gas atoms, molecules and ions, and sputtered target material atoms and ions, particularly at high target power densities. A source of metal atoms for deposition on substrate is their sputtering from the target due to its ion bombarding. The main source of reactive gas for deposition on the substrate is its flow into the vacuum chamber, which is related to the reactive gas partial pressure. In addition, reactive gas species can react with the target material at the target surface to form a compound on the target (e.g., oxidize the target). Such compound formation on the target is well recognized as a primary problem in reactive sputtering, and is particularly a problem in reactive sputtering of metal targets to produce dielectric stoichiometric films at high deposition rates.
In accordance with the present invention, process controller 42 provides a control signal to the mass flow controllers 28 and 30 to adjust the pulsed reactive gas flow rate into the chamber (by a duration of preset constant gas flow rate pulses) such that the reactive gas flow rate, which is related to the reactive gas partial pressure in the chamber, is maintained within a certain specified range. This range of the reactive gas flow rate into the chamber (and the reactive gas partial pressure in the chamber) is determined based on a process development procedure as follows.
First, for a given target material and reactive process gas (or gases), one of the two process parameters (namely, the target current, alternatively the average target current in a period of a pulsed power supply, or the total pressure in the chamber at a fixed preset value of the argon partial pressure, i.e., the reactive gas partial pressure in the chamber), which are simultaneously monitored in time by process controller 42, is selected as a control process parameter on the basis of a higher sensitivity of one of these quantities to constant flow rate pulses of the reactive gas into the vacuum chamber at a constant target voltage (alternatively, a constant target voltage during discharge pulses) under the same discharge conditions. A different behavior of various target materials is mainly caused by their different affinities for chemical reactions with reactive gases on target surfaces and by different, or even opposite, dependences of the secondary electron emission coefficients for partly covered targets (e.g., by oxides or nitrides) on the target coverage.
Second, for a given nominal target power, and the target material and the reactive process gas, an optimized constant target voltage, non-reactive gas (argon) partial pressure, total reactive gas flow rate in both conduits 36 and 38 and its dividing into them, as well as the locations of the conduits in front of the target and directions of the reactive gas flow from them (e.g., towards the target or substrate), together with a critical value of the control process parameter selected (the average target current in a period for sputter deposition of ZrO2 films and the oxygen partial pressure for sputter deposition of Ta2O5 films in
In addition to various alternative implementations of the present invention with the use of standard “low power” continuous DC, pulsed or RF power supplies with a usual target power density less than 20 Wcm−2 as the power supply 44, it is particularly useful for high-rate deposition of dielectric stoichiometric compounds using high power magnetron sputtering a metal target, including high power impulse magnetron sputtering (HiPIMS) with target power densities of up to several kWcm−2 in short target voltage pulses (typically 40 μs to 200 μs). Application of the pulsed reactive gas flow control according to the present invention with the use of a commercially available high power pulsed DC power supply possessing the following features, (i) production of negative voltage pulses at an essentially constant value (the so-called constant-voltage mode of operation), (ii) effective arc handling capabilities (a fast arc detection and suppression technique), and (iii) a computer control able to evaluate the time-dependent average target current in a period of the pulsed power supply during the reactive gas flow rate pulsing (as shown in
Process controller 42 may be implemented in various ways. In some examples, process controller 42 includes a programmable logical controller or a programmed digital computer (e.g., personal computer or workstation) with data acquisition and control interfaces. It may be understood to incorporate the process controller 42 into the power supply 44 itself.
The following example of experimental results obtained in developing and implementing reactive sputter deposition processes for ZrO2 and Ta2O5 films in accordance with the hereinabove described embodiments is merely provided by way of example to illustrate features and characteristics of the present invention, which is not to be construed as being limited thereby.
The experiments were performed using a strongly unbalanced magnetron source with a directly water-cooled planar zirconium or tantalum target (99.9% Zr and Ta purity, diameter of 100 mm and thickness of 6 mm) in a standard stainless-steel vacuum chamber (a diameter of 507 mm and a length of 520 mm), which was evacuated by a diffusion pump (2 m3 s−1) backed up with a rotary pump (30 m3 h−1). The base pressure before deposition was 10−3 Pa. The total pressure of the argon-oxygen gas mixture was around 2 Pa.
The magnetron was driven by a high power pulsed DC power supply (HMP 2/1, Hüttinger Elektronik). The repetition frequency was 500 Hz and the voltage pulse duration ranged from 50 μs to 200 μs with the corresponding duty cycle from 2.5% to 10%. The ZrO2 and Ta2O5 films were deposited on silicon substrates at a floating potential. The target-to-substrate distance was 100 mm. The film thickness (typically between 800 nm and 1200 nm) was measured by profilometry (Dektak 8 Stylus Profiler, Veeco). The substrate temperatures were less than 300° C. during depositions. The elemental composition of the films was measured by a PANalytical wavelength-dispersive X-ray fluorescence spectrometer MagiX PRO with a calibration performed by Rutherford backscattering spectrometry. Structure of the films was investigated using a PANalytical X'Pert PRO diffractometer. The refractive index and extinction coefficient were determined by variable angle spectroscopic ellipsometry using the J. A. Woollam Co. Inc. instrument. Film hardness was determined using a computer-controlled microhardness tester (Fischerscope H-100B) with a preset maximum load of 20 mN.
Although the above description provides many specificities, these enabling details should not be construed as limiting the scope of the invention, and it will be readily understood by those persons skilled in the art that the present invention is susceptible to many modifications and equivalent implementations without departing from this scope and without diminishing its advantages. It is therefore intended that the present invention is not limited to the disclosed embodiments but should be defined in accordance with the claims which follow.
A number of embodiments of the invention have been described. Nevertheless, it will be understood that various modifications may be made without departing from the spirit and scope of the invention. Accordingly, other embodiments are within the scope of the following claims.
Bugyi, Rafal, Vlcek, Jaroslav, Rezek, Jiri, Lazar, Jan
Patent | Priority | Assignee | Title |
10260145, | Mar 17 2016 | SHIBAURA MECHATRONICS CORPORATION | Film formation apparatus and film formation method |
11284500, | May 10 2018 | Applied Materials, Inc. | Method of controlling ion energy distribution using a pulse generator |
11462388, | Jul 31 2020 | Applied Materials, Inc | Plasma processing assembly using pulsed-voltage and radio-frequency power |
11462389, | Jul 31 2020 | Applied Materials, Inc | Pulsed-voltage hardware assembly for use in a plasma processing system |
11476090, | Aug 24 2021 | Applied Materials, Inc | Voltage pulse time-domain multiplexing |
11476145, | Nov 20 2018 | Applied Materials, Inc | Automatic ESC bias compensation when using pulsed DC bias |
11486927, | Apr 02 2020 | Applied Materials, Inc | Bode fingerprinting for characterizations and failure detections in processing chamber |
11495470, | Apr 16 2021 | Applied Materials, Inc | Method of enhancing etching selectivity using a pulsed plasma |
11508554, | Jan 24 2019 | Applied Materials, Inc | High voltage filter assembly |
11569066, | Jun 23 2021 | Applied Materials, Inc | Pulsed voltage source for plasma processing applications |
11693053, | Apr 02 2020 | Applied Materials, Inc. | Bode fingerprinting for characterizations and failure detections in processing chamber |
11694876, | Dec 08 2021 | Applied Materials, Inc. | Apparatus and method for delivering a plurality of waveform signals during plasma processing |
11699572, | Jan 22 2019 | Applied Materials, Inc | Feedback loop for controlling a pulsed voltage waveform |
11776788, | Jun 28 2021 | Applied Materials, Inc | Pulsed voltage boost for substrate processing |
11776789, | Jul 31 2020 | Applied Materials, Inc. | Plasma processing assembly using pulsed-voltage and radio-frequency power |
11791138, | May 12 2021 | Applied Materials, Inc | Automatic electrostatic chuck bias compensation during plasma processing |
11798790, | Nov 16 2020 | Applied Materials, Inc | Apparatus and methods for controlling ion energy distribution |
11810760, | Jun 16 2021 | Applied Materials, Inc | Apparatus and method of ion current compensation |
11848176, | Jul 31 2020 | Applied Materials, Inc | Plasma processing using pulsed-voltage and radio-frequency power |
11887813, | Jun 23 2021 | Applied Materials, Inc. | Pulsed voltage source for plasma processing |
11901157, | Nov 16 2020 | Applied Materials, Inc | Apparatus and methods for controlling ion energy distribution |
11948780, | May 12 2021 | Applied Materials, Inc | Automatic electrostatic chuck bias compensation during plasma processing |
11967483, | Jun 02 2021 | Applied Materials, Inc | Plasma excitation with ion energy control |
11972924, | Jun 08 2022 | Applied Materials, Inc | Pulsed voltage source for plasma processing applications |
Patent | Priority | Assignee | Title |
5292417, | Apr 12 1991 | OERLIKON TRADING AG, TRUBBACH FORMERLY KNOWN AS UNAXIS TRADING AG, FORMERLY KNOWN AS BALZERS HOCHVAKUUM AG | Method for reactive sputter coating at least one article |
20090173622, | |||
20120031749, | |||
EP1553206, | |||
WO2007147582, | |||
WO2009071667, | |||
WO2010125002, |
Executed on | Assignor | Assignee | Conveyance | Frame | Reel | Doc |
Aug 20 2015 | University of West Bohemia in Pilsen | (assignment on the face of the patent) | / | |||
Aug 20 2015 | TRUMPF Huettinger Sp. z o. o. | (assignment on the face of the patent) | / | |||
Oct 07 2015 | BUGYI, RAFAL | University of West Bohemia in Pilsen | ASSIGNMENT OF ASSIGNORS INTEREST SEE DOCUMENT FOR DETAILS | 037293 | /0119 | |
Oct 07 2015 | BUGYI, RAFAL | TRUMPF HUETTINGER SP Z O O | ASSIGNMENT OF ASSIGNORS INTEREST SEE DOCUMENT FOR DETAILS | 037293 | /0119 | |
Oct 26 2015 | REZEK, JIRI | TRUMPF HUETTINGER SP Z O O | ASSIGNMENT OF ASSIGNORS INTEREST SEE DOCUMENT FOR DETAILS | 037293 | /0119 | |
Oct 26 2015 | VLCEK, JAROSLAV | TRUMPF HUETTINGER SP Z O O | ASSIGNMENT OF ASSIGNORS INTEREST SEE DOCUMENT FOR DETAILS | 037293 | /0119 | |
Oct 26 2015 | LAZAR, JAN | University of West Bohemia in Pilsen | ASSIGNMENT OF ASSIGNORS INTEREST SEE DOCUMENT FOR DETAILS | 037293 | /0119 | |
Oct 26 2015 | REZEK, JIRI | University of West Bohemia in Pilsen | ASSIGNMENT OF ASSIGNORS INTEREST SEE DOCUMENT FOR DETAILS | 037293 | /0119 | |
Oct 26 2015 | VLCEK, JAROSLAV | University of West Bohemia in Pilsen | ASSIGNMENT OF ASSIGNORS INTEREST SEE DOCUMENT FOR DETAILS | 037293 | /0119 | |
Oct 26 2015 | LAZAR, JAN | TRUMPF HUETTINGER SP Z O O | ASSIGNMENT OF ASSIGNORS INTEREST SEE DOCUMENT FOR DETAILS | 037293 | /0119 |
Date | Maintenance Fee Events |
May 22 2017 | ASPN: Payor Number Assigned. |
Oct 26 2020 | M1551: Payment of Maintenance Fee, 4th Year, Large Entity. |
Date | Maintenance Schedule |
May 02 2020 | 4 years fee payment window open |
Nov 02 2020 | 6 months grace period start (w surcharge) |
May 02 2021 | patent expiry (for year 4) |
May 02 2023 | 2 years to revive unintentionally abandoned end. (for year 4) |
May 02 2024 | 8 years fee payment window open |
Nov 02 2024 | 6 months grace period start (w surcharge) |
May 02 2025 | patent expiry (for year 8) |
May 02 2027 | 2 years to revive unintentionally abandoned end. (for year 8) |
May 02 2028 | 12 years fee payment window open |
Nov 02 2028 | 6 months grace period start (w surcharge) |
May 02 2029 | patent expiry (for year 12) |
May 02 2031 | 2 years to revive unintentionally abandoned end. (for year 12) |