The present subject matter provides a layered article for sealing an opening in a package for a high alcohol content product. The layered article has a facestock, a reclosure adhesive, a machine direction oriented film, and a sealing adhesive. The sealing adhesive provides a good long-term seal for the package that is resistant to degradation from alcohol. The machine direction oriented film provides an alcohol barrier between the product and the reclosure adhesive. Upon opening, the film tears clean and straight in the machine direction to allow a portion of the film to stay in contact with the package and another portion of the film to be pulled from the package to expose the opening. The reclosure adhesive provides resealing capabilities for the layered article after the initial opening of the package. The clean straight tear also provides a tamper evident feature for the package.
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1. A layered article to seal an opening in a package for a high alcohol content product comprising:
a facestock,
a reclosure adhesive disposed on the facestock,
a machine direction oriented film disposed on the reclosure adhesive, with at least one cut-out at a periphery of the film that is in line with a machine direction of the film,
a sealing adhesive disposed on the film and having an adhesive strength that is not significantly diminished by the product, for adhering the layered article to the package;
wherein an initial peeling of the layered article from the package causes the film to tear from said at least one cut-out, in the machine direction of the film, forming a peeled portion of the layered article that is peeled from the package and exposes the opening, and forming a remaining portion of the layered article that is retained on the package, and
wherein the machine direction oriented film has a reclosure surface, in the remaining portion of the layered article, to which the reclosure adhesive is adapted to bond to reseal the opening.
21. A container for a high alcohol content product comprising:
a package, having an opening;
a layered article sealing the opening comprising
a facestock,
a reclosure adhesive disposed on the facestock,
a machine direction oriented film disposed on the reclosure adhesive, with at least one cut-out at a periphery of the film that is in line with a machine direction of the film,
a sealing adhesive disposed on the film, having an adhesive strength that is not significantly diminished by the product, for adhering the layered article to the package; and
wherein initially peeling the layered article from the package causes the film to tear from said at least one cut-out, in the machine direction of the film, forming
a peeled portion of the layered article that is peeled from the package and exposes the opening, the peeled portion of the layered article comprising the facestock, the reclosure adhesive, a peeled portion of the film, and a peeled portion of the sealing adhesive, and
a remaining portion of the layered article that is retained on the package, the remaining portion of the layered article comprising a remaining portion of the film and a remaining portion of the sealing adhesive and
wherein the machine direction oriented film has a reclosure surface, in the remaining portion of the layered article, to which the reclosure adhesive is adapted to bond to release the opening.
41. A container for a high alcohol content product comprising:
a package, having an opening cover defined by one or more weakened regions,
a layered article, adhered to the package over the opening cover, comprising
a facestock,
a reclosure adhesive disposed on the facestock,
a machine direction oriented film disposed on the reclosure adhesive, with at least one cut-out at a periphery of the film that is in line with a machine direction of the film,
a sealing adhesive disposed on the film, having an adhesive strength that is not significantly diminished by the product, for adhering the layered article to the package; and
wherein initially peeling the layered article from the package causes the film to tear from said at least one cut-out, in the machine direction of the film, forming
a peeled portion of the layered article that is peeled from the package, the peeled portion of the layered article comprising the facestock, the reclosure adhesive, a peeled portion of the film, and a peeled portion of the sealing adhesive, the peeled portion of the sealing adhesive at least partially separates the opening cover from the package to thereby form an opening in the package, and
a remaining portion of the layered article that is retained on the package, the remaining portion of the layered article comprising a remaining portion of the film and a remaining portion of the sealing adhesive and
wherein the machine direction oriented film has a reclosure surface, in the remaining portion of the layered article, to which the reclosure adhesive is adapted to bond to reseal the opening.
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The present application claims priority to International Application No. PCT/CN2012/080154 filed Aug. 15, 2012, which is incorporated herein by reference in its entirety.
The present subject matter relates to a layered adhesive article used as a reclosure sealing label. The layered article is advantageously used for sealing packages that contain wet product that have high alcohol content. The layered article is also used as a tamper-evident sealing label. The present subject matter also relates to packages that incorporate the layered article.
Reclosure adhesive layered articles, also known as sealing labels, are one typical adhesive functional application which requires performance characteristics that enable the sealing label to be removed and resealed to the packaging, for example, from 1 to 150 times. Typically, the number of items contained in a package correlates to the number of times reclosure is required. If a single use/serving product is provided in a package, then the resealing capabilities of a layered article may only need to provide 1 to 3 reclosures. This situation is illustrative of resealable containers for dry pasta, bread, candy, or the like. Other situations may require a greater number of reclosures, i.e. 10 to 20 reclosures or even 50 to 150 reclosures. Examples of these are travel tissue containers, frozen vegetable containers, sliced meat containers, and the like.
The adhesive used to reseal a layered article to a container must have a certain level of resistance to degradation from the product in the container. This level of resistance to the package contents must increase as the number of required reclosures increases because the adhesive is presumably in proximity to the contents for a longer period of time. This increase in product resistance of the adhesive ensures proper reclosures of the container and prevents loss of adhesion. Loss of adhesion could cause product contamination, product degradation, or exposure to environmental elements.
Of particular importance is the resealing capability of layered articles that seal containers for “wet” products. By “wet” it is meant a product that contains an amount of moisture (being water, alcohol, or other liquid medium) that may decrease the adhesion of the layered article to the container, such as wet tissue or wet wipes. Wet products are one of the most challenging applications in the reclosure market because they can reduce the bond strength of an adhesive. Good content resistance is necessary for wet sealing layered articles because normally, about 50 to about 150 reclosures are required.
Typical wet sealing labels comprise a film facestock, a reclosure adhesive, and a release liner for production and handling purposes. The above structure has adequate performance for wet products that are free of alcohol content. But for wet product with high concentrations of alcohol, this type of reclosure adhesive has poor alcohol resistance and therefore has poor resealing capabilities. The bonding strength of the typical sealing label will decrease due to alcohol corrosion to the adhesive. Furthermore, as a result of alcohol evaporation, the functional component in the content formulation of the adhesive could migrate away from the layered article and package interface.
Problems associated with typical sealing labels, as applied to high alcohol content wet product, can lead to an improper seal that fails to maintain the integrity of the packaging. Over time, an improper seal can cause degradation of the high alcohol content wet product. Degradation can include evaporation of the liquid component of the product which produces a dry item not suitable for its intended purpose.
Therefore, a need exists to have a layered article that provides proper adhesion for high alcohol content wet products.
The difficulties and drawbacks associated with previously known reclosure sealing labels and strategies are overcome in the present layered article and container.
The present subject matter relates to a layered article used for sealing and re-closing packages that contain product that has high alcohol content. The layered article provides a tamper-evident feature for visual indication that the package has been initially opened. The present subject matter also relates to containers that incorporate the layered article.
In one aspect, the present subject matter provides a layered article to seal an opening in a package for a high alcohol content product. The layered article comprises a facestock, a reclosure adhesive, a machine direction oriented (hereinafter “MDO”) film, and a sealing adhesive for adhering the layered article to the package and having an adhesive strength that is not significantly diminished by the product. When the layered article is initially peeled back from the package, the MDO film tears in the machine direction of the MDO film, thus forming a peeled portion of the layered article and a remaining portion of the layered article. The peeled portion of the layered article is peeled from the package and exposes the opening. The remaining portion of the layered article is retained on the package.
In another aspect, the present subject matter provides a container for a high alcohol content product. The container comprises a package having an opening, a layered article sealing the opening including a facestock, a reclosure adhesive, an MDO film, and a sealing adhesive for adhering the layered article to the package and having an adhesive strength that is not significantly diminished by the product. When the layered article is initially peeled back from the package, the MDO film tears in the machine direction of the MDO film, thus forming a peeled portion of the layered article and a remaining portion of the layered article. The peeled portion of the layered article is peeled from the package and exposes the opening and comprises the facestock, the reclosure adhesive, a peeled portion of the film, and a peeled portion of the sealing adhesive. The remaining portion of the layered article is retained on the package and comprises a remaining portion of the film and a remaining portion of the sealing adhesive.
The preferred layered article provides a good seal over an opening in a package for a high alcohol content product. The layered article has good resistance to alcohol, provides reclosure capabilities of about 50 to about 150 times, and provides strong sealing adhesion that reduces the risk of packaging blast failure during high-temperature and/or long-term transportation or storage.
As will be realized, the subject matter described herein is capable of other and different embodiments and its several details are capable of modifications in various respects, all without departing from the claimed subject matter. Accordingly, the drawings and description are to be regarded as illustrative and not restrictive.
These, as well as other features, aspects, and advantages of the present subject matter, will be more completely understood and appreciated by referring to the following more detailed description of the exemplary embodiments of the present subject matter in conjunction with the accompanying drawings.
The subject matter described herein provides a layered article to seal an opening in a package for a high alcohol content product. The layered article has the capability of reclosing the package more than about 50 times and as many as about 150 times. The layered article also provides a tamper-evident feature. A related container for a high alcohol content product, incorporating the sealing layered article, is also provided.
By “alcohol” it is meant an organic compound in which the hydroxyl functional group (—OH) is bound to a carbon atom. In particular, this carbon atom should be saturated, having single bonds to three other atoms. These compounds include monohydric alcohols such as isopropyl alcohol, methanol, ethanol, propanol, butanol, and the like; polydydric alcohols such as ethylene glycol, glycerin, erythritol, zylitol, sorbitol, mannitol and the like; unsaturated aliphatic alcohols such as allyl alcohol, geraniol, propargyl alcohol and the like; and alicyclic alcohols such as inositol, menthol and the like.
By “high alcohol content product” it is meant a product containing about 5% by weight of alcohol and up to about 70% by weight of alcohol. For example, alcohol based wet tissue/wet wipes are in this category.
A preferred embodiment of the present subject matter is a layered article to seal an opening in a package for a high alcohol content wet product. The layered article comprises a facestock; a reclosure adhesive disposed on the facestock; a machine direction oriented film disposed on the reclosure adhesive, with at least one cut-out at a periphery of the film that is in line with a machine direction of the film; and a sealing adhesive disposed on the film having an adhesive strength that is not significantly diminished by the product, for adhering the layered article to the package. The layered article is such that peeling the layered article from the package causes the film to tear, beginning from the cut-outs and continuing in the machine direction of the film, thereby forming a peeled portion of the layered article and a remaining portion of the layered article. The peeled portion of the layered article is peeled from the package and exposes the opening. The remaining portion of the layered article is retained on the package. The layered article can many times re-seal the opening by releasably adhereing the peeled portion of the layered article to the remaining portion of the layered article as discussed in more detail herein.
Another preferred embodiment of the present subject matter is a container for a high alcohol content wet product. The container comprises a package, having an opening; a layered article for covering the opening, including a facestock, a reclosure adhesive disposed on the facestock, a machine direction oriented film disposed on the reclosure adhesive, with at least one cut-out at a periphery of the film that is in line with a machine direction of the film, a sealing adhesive disposed on the film having an adhesive strength that is not significantly diminished by the product, for adhering the layered article to the package. The layered article is such that peeling the layered article from the package causes the film to tear, beginning from the cut-outs and continuing in the machine direction of the film, thereby forming a peeled portion of the layered article and a remaining portion of the layered article. The peeled portion of the layered article is peeled from the package and exposes the opening and comprises the facestock, the reclosure adhesive, a peeled portion of the film, and a peeled portion of the sealing adhesive. The remaining portion of the layered article is retained on the package and comprises a remaining portion of the film and a remaining portion of the sealing adhesive. The layered article can many times re-seal the opening by releasably adhering the reclosure adhesive to the remaining portion of the film as discussed in more detail herein
The layered article of present subject matter displays good resistance to alcohol and provides a strong bond to the package. The present subject matter includes a sealing adhesive and MDO film that provide a barrier to alcohol in the product. The sealing adhesive is such that its bond strength is not significantly reduced by the alcohol present in the product. The strong bond between the layered article and the package is sustained over time to maintain the integrity of the package. The maintained integrity of the package preserves the product, extends the shelf-life of the product, and minimizes the risk of packaging blast failure during high-temperature and/or long term transportation and storage. The reclosure adhesives of typical wet sealing labels degrade when exposed to alcohol and package blast failure is a normal occurrence for packages housing high alcohol content product.
The present subject matter also utilizes the MDO film to physically separate the reclosure adhesive from the high alcohol content wet product. The reclosure adhesive is thereby protected from alcohol degradation and its reclosure capabilities and bond strength is maintained.
After the initial opening of a container, the layered article will provide a good seal upon reclosure and provide reclosure capabilities of about 50 to about 150 times or more. The reclosure adhesive maintains a releasable and resealable bond because it is not subject to significant degradation by the alcohol. Alcohol evaporation from the product is thus minimized and the product remains wet and suited for its intended use. In the case of high alcohol content wet tissue, the yet unused wet tissue remaining in the container retains its alcohol content over the life-span of the product.
These and other aspects are described in greater detail herein as follows.
The layered articles in accordance with the present subject matter can be used to seal openings in flexible containers such as pouches, and in rigid containers such as trays. The layered articles themselves can be flexible, rigid, or semi-rigid material or combinations thereof. Preferably, the layered articles have no scoring, perforations, or the like within their construction that would allow degradation of the product.
In reference to the Figures, identically numbered features indicate similar characteristics present in each embodiment. Now looking to
Now looking to
In a preferred embodiment, the layered article of the present subject matter comprises a sealing label. The sealing label is printable or has printing, images, or other indicia on or visible from the exposed side.
Facestock
In accordance with the present subject matter, the layered article comprises a facestock. The facestock of the layered article can comprise a single or multi-layered film, foil, fabric, paper, sheet, or combinations or laminations thereof, all of which are substantially two-dimensional objects having a first and second side. By substantially two-dimensional, it is meant an object having a significantly large size measurement in two dimensions compared to a significantly small size measurement in the third dimension. Alternatively, the facestock can comprise a three-dimensional object. The composition of the facestock, whether two-dimensional or three-dimensional, is not particularly limited and can comprise metal, paper, polymers, textiles, glass, ceramic, wood, or combinations thereof. Non-limiting examples of preferred facestock components are polypropylene, polyethylene, polyethylene terephthalate or combinations or blends thereof. The polymeric components of the facestock can be machine direction oriented, transverse direction oriented, or biaxially oriented.
The facestock of the present subject matter is preferably comprised of a thin polymeric elastic or flexible film formed from a pliable elastomer material. A preferred facestock comprises at least one layer that is biaxially oriented and more preferably comprises a layer of biaxially oriented polypropylene. The biaxially oriented film of the preferred facestock will be more resistant to tearing, ripping, or otherwise being damaged during peeling of the layered article from the package than a non-oriented film.
The film is continuous in that it has no perforations or pores which extend through the thickness of the film. The facestock preferably has a thickness from about 10 microns to about 100 microns, and more preferably has a thickness of about 50 microns.
The facestock can optionally include other layers or coatings for specific intended uses including printing receptive layers or coatings, hydrophobic layers or coatings, additional facestock layers, or the like. The facestock may optionally be coated on either surface.
In one aspect of the present subject matter, the facestock is at least partially transparent or translucent. That is, the facestock is not completely opaque, thus allowing underlying layers of the layered article to be observed or visible through the facestock. As will be discussed in further detail herein, when the facestock is not completely opaque, the MDO film will be observable through the facestock.
In a preferred embodiment a portion of the facestock comprises the exposed side of the layered article and can be printable or contain printing, images, or other indicia. The other side of the facestock preferably has the reclosure adhesive disposed thereon. Upon peeling the layered article from the package, the facestock preferably remains essentially intact and does not rip, tear, or otherwise become damaged.
Reclosure Adhesive
In accordance with the present subject matter, the layered article comprises a reclosure adhesive. The reclosure adhesive of the present subject matter preferably comprises a removable and resealable adhesive for resealing the layered article to the package. In one preferred aspect the reclosure layer comprises a pressure-sensitive adhesive (hereinafter “PSA”). The reclosure adhesive is preferably not completely opaque. That is, the reclosure adhesive is at least partially transparent or translucent, thus allowing underlying layers to be observable through the reclosure adhesive. As will be discussed in further detail herein, when the reclosure adhesive is not completely opaque, the MDO film will be observable through the reclosure adhesive.
Pressure-sensitive adhesives are adhesives that bond to a substrate with the application of pressure. Solvents, water, chemical reaction, or heat are not required to activate the adhesive. The degree of bonding strength is influenced by the amount of pressure which is used to apply the adhesive to the surface. Bonding strength is also affected by substrate characteristics such as smoothness, surface energy, presence of contaminants, and the like. Pressure-sensitive adhesives are usually designed for use at room temperature. They normally display a total or partial loss of bonding strength at low temperatures and shear holding ability at high temperatures.
Pressure-sensitive adhesives exhibit viscoelastic properties, which are tailored to ensure proper adhesion. Pressure-sensitive adhesives are designed to balance their tendency to flow (adhesive forces) and their resistance to flow (cohesive forces). Pressure-sensitive adhesives form a bond to a surface because their adhesive forces are such that they flow, or wet the substrate. The bond maintains strength because the cohesive forces of the pressure-sensitive adhesive are such that they resist flow when stress is applied to the bond.
Once the substrate and the pressure-sensitive adhesive are in proximity, there are also molecular interactions, such as van der Waals forces involved in the bond, which contribute significantly to the bond strength.
Pressure-sensitive adhesives are usually composed of elastomeric polymers with or without tackifiers. A variety of polymers have been used to manufacture pressure-sensitive adhesives; for example, acrylic and methacrylic ester homo- or copolymers, butyl rubber-based systems, silicones, nitriles, styrene block copolymers, ethylene-vinyl acetate, urethanes, vinyl esters and amides, olefin copolymer materials, natural or synthetic rubbers, and the like.
Pressure-sensitive adhesives are typically classified in one of two categories, permanent and removable. Permanent pressure-sensitive adhesives are adhesives which do not allow for the removal of an adhesive article from a substrate without considerable damage to the adhesive article, adhesive failure at the article surface, cohesive failure in the body of the adhesive, or residual transfer of the adhesive to the substrate.
The adhesion of removable pressure-sensitive adhesives is considerably lower, allowing removal of the adhesive article from the substrate even after a protracted period of contact. Removal is accomplished without significant damage to the adhesive article or substrate. Removable pressure-sensitive adhesives form a temporary bond and can be removed without leaving any residue on the substrate. Removable PSAs can often be removed from and resealed to a substrate multiple times without significant loss of adhesion between each resealing and removal.
A preferred embodiment for the reclosure adhesive of the present subject matter comprises a removable and resealable, acrylic based solvent pressure-sensitive adhesive that provides resealing capabilities from about 50 to about 150 times or more. An example of a preferred reclosure adhesive is SR101 provided by Avery Dennison Corporation, 150 North Orange Grove Boulevard, Pasadena, Calif. 91103-3596, USA. The SR101 adhesive is a removable acrylic based solvent pressure-sensitive adhesive featuring excellent die cutting, strip performance and UV resistance suitable for use on packages with low moisture content. Another example of a preferred reclosure adhesive is SR106 also provided by Avery Dennison Corporation. The SR106 adhesive is a removable acrylic based solvent pressure-sensitive adhesive with excellent die cutting, strip performance, and UV resistance suitable for use on packages with high moisture content. Regardless of the type of adhesive used for the reclosure adhesive, it is preferably protected from significant degradation from the alcohol in the product by the MDO film and sealing adhesive. Therefore, the reclosure adhesive does not necessarily have to be resistant to alcohol, but can be.
Other adhesives can be used; such as a polyurethane adhesive, a rubber adhesive, or the like. The adhesive layer should have a glass transition temperature less than about 10° C. below use temperature, typically less than about 30° C. below use temperature. As used herein, the phrase “use temperature” is the temperature at which the adhesive is normally bonded to a substrate. Use temperature is normally ambient (25°) but may be 0° C. or less for low temperature applications and higher than 25° C. for high temperature applications. The copolymers for the adhesive of the instant subject matter can be stabilized against UV and oxidative degradation by using UV stabilizers and antioxidants. Fillers, colorants, tackifiers, plasticizers, oils, and the like, may also be added.
Upon peeling the layered article from the package, the reclosure adhesive preferably remains essentially as a cohesive layer disposed on the facestock and does not separate, rip, tear, or otherwise become significantly damaged. The reclosure adhesive will provide a substantial portion of the resealing function for the layered article. The reclosure adhesive will remain affixed to the facestock of the layered article during each removal and resealing and separate from a portion of the MDO film as is discussed in greater detail herein.
The reclosure adhesive preferably has a thickness from about 5 microns to about 50 microns, and more preferably has a thickness from about 15 microns to about 25 microns.
The PSA layer can be disposed on one side of the facestock in a fashion suitable for a particular application. For example, the PSA can be disposed over portions of one side of the facestock or over the entire one side of the facestock. The coating of PSA disposed on the facestock can be patterned, continuous, or applied as discrete islands of adhesive. The PSA layer can have relative uniform thickness or can vary in thickness. In a preferred embodiment, the PSA is disposed in a continuous layer with relative uniform thickness on one entire side of a substantially two-dimensional facestock. In an alternative embodiment, the PSA is disposed on a portion of one side of a substantially two-dimensional facestock.
Machine Direction Oriented Film
The MDO film is preferably a substantially two-dimensional polymer film that is oriented in a machine direction having a first and second side. The MDO film is disposed on a side of the reclosure adhesive opposite the facestock.
Polymer films are typically produced using either a cast or blowing process, which produce optically cloudy films that are very flexible and conformable. After a plastic film has been formed, it can be stretched using basically two different methods—machine-direction orientation or transverse-direction orientation. By combining the above mentioned orientation processes it is also possible to produce bi-axially oriented films. Through the machine direction orientation process, the film is uni-axially oriented in the machine direction of the web. Stretching in the machine direction is normally accomplished via heated rolls that pull the film with gradually increasing speed. The film is brought to a sufficient temperature and is stretched in the machine direction. The film is then rapidly cooled to set the orientation of the film.
It is well known that orientation of plastic films enhances their properties, particularly mechanical, barrier and optical properties. The orientation process generally increases mechanical properties of the films, such as stiffness as measured by Young's modulus and tensile strength; but also improves optical properties such as clarity, haze and gloss. MDO films have good conformability due to the fact that orientation is only carried out in the machine direction. Good conformability in plastic films for label products allows labeling without wrinkles to the surface of packages, which is often significantly curved in two directions.
The orientation process may also produce a reduction of the tear resistance along the machine direction. This decrease in tear resistance along the machine direction is advantageously utilized in the present subject matter by incorporating the MDO film in the layered article such that the machine direction is in line with the direction of the peel for the layered article. Thus the peeling of the layered article from a package produces a tear along the machine direction of the MDO film. A straight clean tear is produced in the MDO film without the need for scoring, perforation, or the like. Therefore, the MDO film has no apertures, holes, or pores which extend through the thickness of the film prior to the initial opening. A continuous barrier between the high alcohol content wet product and the reclosure adhesive is provided before the initial opening of the container. The continuous barrier MDO film thereby prevents alcohol degradation of the reclosure adhesive. The MDO film preferably has a sealing adhesive disposed on a side opposite the reclosure adhesive, for bonding the layered article to the package.
The MDO film can be opaque or transparent or translucent. In one aspect, the MDO film preferably includes printing, images, or other indicia. When the facestock and reclosure adhesive are not completely opaque, the printing, images, and other indicia on the MDO film can be seen through the facestock and reclosure adhesive. When the facestock and reclosure adhesive are not totally opaque, the clean tear in the MDO film that is produced upon peeling the layered article from the package, will be seen through the facestock and reclosure adhesive. The clean tear in the MDO film being observable through the facestock and reclosure adhesive, provides visual indication that the layered article has been initially peeled from the package. Any misalignment of the printing on the MDO film will also be seen upon re-adhering the layered article to the package.
Referring now to
The MDO film 6 has a tab part 21 that is preferably free from the sealing adhesive and at least partially comprises the tab of the layered article. The tab part 21 is preferably on the same end/side of the MDO film 6 as are the cuts-outs 20. The tab part 21 (indicated by cross-hatching lines) is free from the sealing adhesive so that the tab of the layered article does not adhere to the package. This allows the tab of the layered article to be easily grasped and pulled by a user to peel the layered article from the package to open the package. The tab part 21 is preferably in line with the machine direction 8 of the MDO film 6. The tab part 21 can be recessed (as in
When peeled from a package by the tab part 21, the MDO film 6 tears, beginning at the one or more cut-outs 20, and extending in the machine direction 8 along tear lines 24. In conjunction with the cut-outs 20, the tab part 21 at least partially determines the location and direction of the clean tear in the MDO film 6.
The location of the clean tear in the MDO film is at least partially controlled by incorporating one or more cut-outs 20 in the MDO film. The cut-outs can be slits, voids, notches, perforations, or the like, preferably at a periphery of the MDO film and in the machine direction. Alternatively, the cut-outs 20 can begin inside the periphery of the MDO film 6. The shape of the cut-outs are not particularly limited and non-limiting examples are depicted in
When peeled from the package, the MDO film tears along tear lines 24. The peeled portion 25 of the MDO film 6 between the tear lines 24 is pulled from the package with the facestock and the reclosure adhesive. When the peeled portion 25 is pulled away from the package, the sealing adhesive that bonds the peeled portion 25 to the package is also pulled away to expose the opening 22. The remaining portion 26 of the MDO film 6 on either side of tear lines 24, remains bonded to the package with the sealing adhesive, thus forming a reclosure surface to be discussed in more detail herein.
Preferably, the tear lines 24 are formed in the MDO film 6 at a position beyond the opening edge 23 of the opening 22 as shown in
The clean straight tear of the MDO film also provides a tamper-evident function for the layered article. When torn, the MDO film creates a visible indication that the layered article has been initially peeled from the package. When the facestock and the reclosure adhesive are not completely opaque, the clean tear is visually observed through the facestock and reclosure adhesive. It is also contemplated that the clean tear in the MDO film will be noticeable underneath the facestock and reclosure adhesive even if the facestock and reclosure adhesive are totally opaque. When the layered article is re-adhered to the package, the clean tear in the MDO film will produce a bulge, a crease, a deformation, or the like in the layered article that is visually observed even though not seen through the totally opaque facestock and reclosure adhesive.
The MDO film can also preferably includes means to prevent a complete detachment of the peeled portion of the film from the remaining portion of the film. The means are preferably at or near an end of the MDO film distal to the cut-outs and tab part. The means can be a heat seal between the MDO film and the facestock. When the facestock is biaxially oriented, the facestock will provide resistance to tearing past the heat seal. Also possible is a cut-through in the MDO film. The cut-through can be a hook design, a portion of which is substantially perpendicular to the clean tear in the MDO film, in the plane of the substantially two-dimensional MDO film. The cut-through will provide an end point for the clean tear. Also possible is a permanent adhesive to bind the MDO film to the facestock. Like the heat seal, the permanent adhesive will provide resistance to tearing in the MDO film. Other means, well known in the art can be used and these examples are not meant to be limiting to the present subject matter. When the MDO film is prevented from completely separating into two or more pieces, so too is the layered article. Thus the layered article will not separate into two or more pieces when peeled from a package to expose the opening.
Discussed herein is the use of a film, oriented in the machine direction. Also contemplated by the present subject matter is the use of transverse direction oriented film. The same objectives are accomplished by placing the tab part 21 and the one or more cut-outs 20 in line with the transverse direction of the film and incorporating a means to prevent the MDO film from separating into two or more pieces near an edge distal to the cut-outs and tab part.
Sealing Adhesive
The layered article of the present subject matter preferably includes a sealing adhesive. The sealing adhesive provides the means for bonding the layered article to the package and comprises the package contacting layer of the layered article. The sealing adhesive provides a long-term seal for a container to protect against package blast failure, reclosure adhesive degradation, reclosure adhesive migration, and the like. Thus, the alcohol content of the product and the reclosure capabilities of the reclosure adhesive are maintained. The sealing adhesive preferably is resistant to corrosion from alcohol.
The sealing adhesive is preferably a pressure-sensitive adhesive as discussed herein and more preferably, a pure acrylic based removable pressure-sensitive adhesive having a bond strength that is not significantly diminished by the high alcohol content product. By “not significantly diminished” it is meant an adhesive that, when exposed to a high alcohol content product, is able to provide a sufficient seal with the package so that the product within the container does not dry out or otherwise degrade during the life span of the product, thus keeping the product in a state suitable for its intended use.
The composition of a preferred sealing adhesive is not particularly limited except that the sealing adhesive is resistant to alcohol, i.e. has a bond strength that is not significantly diminished by alcohol from the product. In a preferred embodiment, the sealing adhesive provides a strong bond to the package that is minimally degraded by the alcohol from the wet product.
The sealing adhesive is preferably releasable and resealable. A preferred embodiment sealing adhesive maintains at least a portion of its initial bond strength after the initial opening of the package. The sealing adhesive should maintain good adhesion when resealed to the package after initial opening to avoid drying of the product.
Also contemplated by the present subject matter is an adhesive that loses a substantial portion of its bond strength after the initial opening. In this aspect, the reclosure adhesive provides the adhesion to reseal the layered article to cover the opening and prevent the product from drying.
The sealing adhesive preferably completely covers the opening. That is, the sealing adhesive extends beyond the edge of the opening when the layered article is adhered to the package.
In one embodiment, the sealing adhesive has a greater adhesive strength than the reclosure adhesive. When the reclosure adhesive provides the majority of adhesion to reseal the layered article to the package, subsequent peeling of the layered article from the package requires less force than the initial peeling of the layered article.
The sealing adhesive preferably has a thickness from about 5 microns to about 50 microns, and more preferably has a thickness from about 15 microns to about 25 microns.
As previously discussed herein, the sealing adhesive is disposed on the MDO film layer to bond the layered article to the package. Referring to previously described
Release Liner
In a preferred embodiment of the present subject matter, the layered article has a release liner. The release liner is removed prior to applying the layered article to the package. The release liner provides protection for the sealing adhesive and prevents premature exposure of the sealing adhesive to a package, and prevents contamination by dirt, liquids, or other elemental exposure. Inadvertent contact or exposure to environmental elements can decrease the tackiness of the sealing adhesive and prevent the desired adhesion. The release liner maintains the adhesive tackiness of the sealing adhesive.
The release liner also allows for handling of the layered article prior to application to a package, i.e. during lamination, converting, packaging, printing, handling, shipping, and other manufacturing processes. The release liner may also provide stiffness to the layered article to facilitate these steps. The release liner may cover all or a portion of the sealing adhesive.
Typical materials used for the release liner in accordance with the present subject matter are super calandered kraft paper, glassine, clay coated kraft paper, machine finished kraft paper, machine glazed paper, biaxially oriented polyethylene terephthalate film, polypropylene film, polyethylene film, biaxially oriented polypropylene film, polyester, acrylic, nylon, cellulosic derivative, butylene; isobutylene; high, medium, low, and linear low density polyethylene; ethylene vinyl acetate; ethylene acrylic add; ethylene methyl (meth)acrylate; ethylene butyl acrylate; polypropylene; ethylene/propylene copolymers; and impact resistant ethylene/propylene copolymers and combinations thereof.
In a preferred embodiment, the release liner comprises polyethylene terephthalate or a glassine release liner. The thickness of the release liner is not particularly limited and can range from about 5 microns to about 200 microns.
The present subject matter also includes containers for high alcohol content wet product. The containers of the present subject matter include a package and incorporate the layered article as previously described; such description being incorporated herein.
In one aspect of the present subject matter, a container for a high alcohol content product is provided. The preferred container of the present subject matter comprises a package having an opening and a layered article for sealing the opening. The layered article includes a facestock; a reclosure adhesive disposed on the facestock; a machine direction oriented film disposed on the reclosure adhesive, with at least one cut-out at a periphery of the film that is in line with the machine direction of the film; a sealing adhesive disposed on the film having an adhesive strength that is not significantly diminished by the product, for adhering the layered article to the package; and wherein initially peeling the layered article from the package causes the film to tear from said at least one cut-out, in the machine direction of the film. The tear in the MDO film forms a peeled portion of the layered article that is peeled from the package and exposes the opening, and forms a remaining portion of the layered article that is retained on the package. The peeled portion of the layered article comprises the facestock, the reclosure adhesive, a peeled portion of the film, and a peeled portion of the sealing adhesive. The remaining portion of the layered article comprises a remaining portion of the film and a remaining portion of the sealing adhesive.
The package of the preferred embodiment container is not particularly limited and can be rigid, semi-rigid, flexible, or a combination thereof. The composition of the package can comprise polymeric material, metal, paper, fabric, or combinations thereof that are either coated to enhance alcohol resistance and provide alcohol barrier properties or free of such coatings. Non-limiting examples for the composition of the preferred package are polypropylene, polyethylene (including low density, linear low density, medium density, and high density polyethylene), polyethylene terephthalate, polyester, nylon, or combinations, blends, and laminates thereof. The polymeric components of the package can be machine direction oriented, transverse direction oriented, or biaxially oriented, and can be metalized and have sealant additive and coatings. The package can be printable or comprise printing, images, or other indicia on an exposed surface.
Regardless of the form or composition chosen for the package, the preferred embodiment container ensures that the high alcohol content product housed within is properly contained prior to the initial opening, i.e. that the alcohol does not significantly escape from the container allowing the product to dry out. Proper containment of the product is provided when a suitable seal is made between the package and the layered article and when the container itself is properly sealed.
In one aspect of the present subject matter, the package is a flexible polymeric film pouch. Examples of this type of package are the flexible containers used to hold wet tissue/wet wipes usually formed from a sheet of polymeric film that has been bonded to itself with a longitudinal fin seal and two transverse end seals. Other sealing arrangements are contemplated and well known in the art.
The package of the present subject matter has an opening that is sealed by the layered article. The opening in the package can be pre-formed or created when the layered article is peeled from the package by pulling away an opening cover portion of the package. The opening cover can be formed from the package material itself and can be defined by perforations, a score line, a cut-though, bending, stamping, a three dimensional impression, or similar weakened region of the package. Alternatively, the opening cover can be distinct from the package.
When the layered article 1 is peeled from the package 32 by use of the tab 9, the MDO film 6 tears. The tear begins at two cut-outs 20 on either side of the tab part 21, and continues in the machine direction 8 of the MDO film 6. The tear forms a peeled portion 42 of the layered article 1 and a remaining portion 43 of the layered article 1. The peeled portion 42 is peeled from the package 32 and exposes the opening 22. The remaining portion 43 is retained on the package.
The peeled portion 42 of the layered article 1 comprises the facestock 4, the reclosure adhesive 5, a peeled portion 25 of the MDO film 6, and a peeled portion 40 of the sealing adhesive 7. The peeled portion 40 of the sealing adhesive 7 is shown partially revealing the opening 22 in the package 32 that is defined by an opening edge 23. The peeled portion 40 of the sealing adhesive 7 and the peeled portion 26 of the MDO film 6 cover opening 22 and extend beyond the opening edge 23 of the opening 22. The opening 22 is shown to be formed in the package 32 as the peeled portion 40 of the sealing adhesive 7 pulls away an opening cover 30 from the package 32. The opening cover 30 is shown to be formed from the package 32 material.
The remaining portion 43 of the layered article 1 remains bonded to the package and comprises a remaining portion 26 of the MDO film 6 and a remaining portion 41 of the sealing adhesive 7. The remaining portion 26 of the MDO film has a reclosure surface 31 to which the reclosure adhesive 5 can bond to reseal the opening 22 in the container 33. In a preferred embodiment, the reclosure adhesive 5, along with the peeled portion 40 of the sealing adhesive 7 combine to provide adhesion to reseal the opening 22 in the container 33.
The peeled portion 42 of the layered article 1 is prevented from completely detaching or separating from the remaining portion 43 of the layered article 1 by means of heat seals 44 fashioned in a hook design, that are in line with the tear in the MDO film 6.
As discussed previously herein, the clean straight tear of the MDO film 6 also provides a tamper-evident function for the layered article 1. When the facestock 4 and reclosure adhesive 5 are not totally opaque, the tear in the MDO film is visible through the facestock 6 and reclosure adhesive 5. Other tamper-evident features can optionally be incorporated into the layered article 1, package 32, or container 33.
The container and layered article of the present subject matter provide a good initial seal for high alcohol content wet product that is resistant to alcohol degradation and reduces the likelihood of package blast failure. The container and layered article also provide good resealing capabilities and reduce the likelihood of the product drying out during the lifespan of the product.
Many other benefits will no doubt become apparent from future application and development of this technology.
As described hereinabove, the present subject matter solves many problems associated with previous strategies, systems and/or devices. However, it will be appreciated that various changes in the details, materials and arrangements of components, which have been herein described and illustrated in order to explain the nature of the present subject matter, may be made by those skilled in the art without departing from the principle and scopes of the claimed subject matter, as expressed in the appended claims.
| Patent | Priority | Assignee | Title |
| Patent | Priority | Assignee | Title |
| 3113986, | |||
| 3207735, | |||
| 3207736, | |||
| 3207737, | |||
| 3207738, | |||
| 3207739, | |||
| 3251905, | |||
| 3268627, | |||
| 3390207, | |||
| 3598887, | |||
| 3639521, | |||
| 3853595, | |||
| 3887745, | |||
| 3894904, | |||
| 3963851, | Aug 06 1971 | Kabushiki Kaisha Oji Yuka Goseishi Kenkyujo | Paper for adhesive stickers and the like |
| 4016118, | Aug 16 1974 | MILLIKEN RESEARCH CORP0RATION A CORP OF SC | Polyolefin plastic compositions |
| 4020141, | Sep 14 1973 | E. I. du Pont de Nemours and Company | Method of making heat-sealable, heat-shrinkable, biaxially oriented polyester film |
| 4059667, | Oct 20 1975 | E. I. du Pont de Nemours and Company | Biaxially oriented polyethylene terephthalate film and method of making such film |
| 4124677, | Dec 09 1975 | Toshiba Kikai Kabushiki Kaisha | Method of manufacturing polyvinyl alcohol films oriented in two orthogonal directions |
| 4188350, | Jan 17 1978 | VISKASE CORPORATION, A CORP OF PA | Olefin polymer blends and films therefrom |
| 4205021, | Jan 27 1977 | Mitsui Petrochemical Industries, Ltd. | Ethylene copolymers |
| 4207363, | Mar 29 1978 | VISKASE CORPORATION, A CORP OF PA | Flexible heat-shrinkable multilayer film for packaging primal meat |
| 4208356, | Sep 17 1974 | Asahi Kasei Kogyo Kabushiki Kaisha | Process for producing mixture of block copolymers |
| 4219627, | Mar 09 1977 | BRIDGESTONE FIRESTONE, INC | Process for the preparation of block copolymers |
| 4226952, | Aug 20 1979 | BRIDGESTONE FIRESTONE, INC | Thermoplastic elastomer blends of alpha-olefin polymers and hydrogenated medium and high vinyl butadiene polymers |
| 4314039, | Aug 21 1979 | Mitsui Chemicals, Inc | Polypropylene composition containing a 1.3,2.4-di(alkylbenzylidene) sorbitol |
| 4340640, | Oct 05 1979 | Mobil Oil Corporation | Heat sealable packaging film comprising propylene polymer substrate and a surface layer blend of ethylene copolymer and propylene copolymer |
| 4371645, | Apr 24 1980 | Milliken Research Corporation | Polyolefin plastic compositions comprising meta- or papa-derivatives (choro- or bromo-) of di-benzyuidene sorbitol |
| 4399180, | Sep 15 1978 | Tyco Plastics Services AG | Coextruded thermoplastic stretch-wrap |
| 4399181, | Dec 18 1978 | Asahi Kasei Kogyo Kabushiki Kaisha | Cold drawn high-orientation multilayered film and process for manufacture of said film |
| 4405667, | Aug 06 1982 | American National Can Company | Retortable packaging structure |
| 4407873, | Aug 06 1982 | PECHINEY PLASTIC PACKAGINC, INC | Retortable packaging structure |
| 4407874, | Aug 06 1982 | PECHINEY PLASTIC PACKAGINC, INC | Sterilizable flexible packaging structure |
| 4430377, | Dec 18 1978 | Asahi Kasei Kogyo Kabushiki Kaisha | Cold drawn high-orientation multilayered film and process for manufacture of said film |
| 4434264, | Mar 22 1983 | Huntsman Polymers Corporation | High clarity propylene polymer compositions of improved impact strength |
| 4447485, | Aug 04 1981 | Mitsubishi Plastics Industries Limited | Adhesive tape and process for its production |
| 4451533, | Feb 09 1983 | Minnesota Mining and Manufacturing Company | Dispensable polypropylene adhesive-coated tape |
| 4463113, | Jun 25 1981 | ADEKA ARGUS CHEMICAL CO , LTD URAWA, JAPAN A CORP OF | Bis-phenol phosphates as clarifiers for polyolefin resins |
| 4508872, | Feb 22 1984 | Union Carbide Chemicals & Plastics Technology Corporation | High toughness propylene polymer compositions |
| 4514534, | Apr 13 1984 | SUNOCO, INC R&M | Modified polypropylene for film |
| 4522887, | Apr 18 1983 | Toray Industries, Inc. | Laminated film of biaxially oriented polypropylene and an olefin polymer film |
| 4525416, | May 04 1982 | Hoechst Aktiengesellschaft | Adhesive tape |
| 4532280, | Jun 11 1984 | New Japan Chemical Co., Ltd. | Crystalline polyolefin-type resin compositions |
| 4535125, | Oct 13 1983 | Union Carbide Chemicals & Plastics Technology Corporation | High flow propylene polymer compositions |
| 4551380, | May 10 1984 | CRYOVAC, INC | Oriented heat-sealable multilayer packaging film |
| 4564559, | Dec 28 1984 | Mobil Oil Corporation | Oriented multi-layer heat sealable film |
| 4565738, | Jun 01 1983 | Imperial Chemical Industries, PLC | Multiple-layer polyolefin films |
| 4578316, | Dec 19 1984 | Mobil Oil Corporation | Multi-layer oriented polypropylene films with low COF skin(s) |
| 4578429, | Aug 31 1984 | SHELL ELASTOMERS LLC | Selectively hydrogenated block copolymers modified with acid compounds or derivatives |
| 4581262, | Jan 14 1985 | OWENS-ILLINOIS PLASTIC PRODUCTS INC , A CORP OF DE | Coextruded multilayer sheet and sleeve label made therefrom |
| 4585679, | Jan 14 1985 | FUJI SEAL INTERNATIONAL, INC | Coextruded multilayer sheet and tough sleeve label made therefrom |
| 4588775, | Jun 22 1984 | Union Carbide Chemicals & Plastics Technology Corporation | High toughness propylene polymer compositions |
| 4604324, | Sep 28 1984 | Mobil Oil Corporation | Multi-layer polypropylene film structure and method of forming the same |
| 4605576, | Oct 22 1984 | OWENS-BROCKWAY PLASTIC PRODUCTS INC | Multilayer plastic articles |
| 4613547, | Dec 19 1984 | Mobil Oil Corporation | Multi-layer oriented polypropylene films |
| 4613643, | Feb 09 1984 | Tokuyama Soda Kabushiki Kaisha | Porous sheet |
| 4616470, | Dec 03 1979 | KENNAK U S A INC , A CORP OF NY | Method of forming re-sealable dispenser-container |
| 4621119, | Dec 27 1984 | Mobil Oil Corporation | Polypropylene-polyethylene-(ethylene-propylene rubber) compositions and films thereof with improved tear strength |
| 4626574, | Jul 21 1982 | CLOPAY PLASTIC PRODUCTS COMPANY, INC | Linear low density polyethylene film and method of making |
| 4634735, | Nov 13 1980 | BP Chemicals Limited | Polypropylene compositions with high impact strength |
| 4643945, | Sep 03 1985 | USI CHEMICAL CO , INC | Heat sealable blend of polypropylene terpolymers and linear low density polyethylene |
| 4657970, | Aug 13 1981 | Asahi Kasei Kogyo Kabushiki Kaisha | Modified block copolymer composition |
| 4659612, | Feb 13 1986 | Mobil Oil Corporation | Polymer film laminate and method for its preparation |
| 4663216, | Jun 18 1984 | OJI-YUKA SYNTHETIC PAPER CO , LTD | Synthetic paper printable in high gloss |
| 4684578, | Oct 12 1979 | Toa Nenryo Kogyo Kabushiki Kaisha | Modified elastomer and laminate thereof |
| 4692489, | Aug 06 1985 | Huntsman Polymers Corporation | Polypropylene compositions of improved clarity |
| 4695503, | Mar 07 1986 | Mobil Oil Corporation | Coated, oriented, polymer film laminate |
| 4704421, | Aug 06 1985 | Huntsman Polymers Corporation | Nucleation of propylene polymers |
| 4713273, | Feb 05 1985 | Avery Dennison Corporation | Composite facestocks and liners |
| 4716068, | Jan 19 1985 | Hoechst Aktiengesellschaft | Polypropylene adhesive tape |
| 4720427, | Oct 28 1985 | Mobil Oil Corporation | Oriented multi-layer heat sealable film |
| 4724185, | Sep 17 1985 | CRYOVAC, INC | Oxygen barrier oriented film |
| 4728377, | Nov 08 1982 | AMERICAN BANK NOTE HOLOGRAPHICS, INC , 500 EXECUTIVE BLVD , ELMSFORD, NY 10523 A CORP OF DE | Process for providing holograms on documents or the like |
| 4735335, | May 06 1987 | Etude et Realisation de Chaines Automatiques-E.R.C.A. | Composite band for lids for thermoplastic containers |
| 4748206, | Nov 11 1985 | Nippon Petrochemicals Company, Limited | Polyolefin composition and the same used for vehicle exterior members |
| 4752597, | Dec 12 1985 | Exxon Chemical Patents Inc. | New polymerization catalyst |
| 4769284, | Apr 26 1985 | Sumitomo Chemical Company, Limited | Polypropylene multi-layer film |
| 4778697, | Nov 29 1985 | PECHINEY PLASTIC PACKAGINC, INC | Polymeric films |
| 4790436, | Jun 23 1986 | KENNAK U S A INC , A CORP OF NY | Resealable dispenser-container |
| 4795782, | Sep 25 1986 | Shell Oil Company | Impact resistant blends of thermoplastic polyamides, functionalized polyolefins and functionalized elastomers |
| 4797235, | Apr 16 1987 | W R GRACE & CO -CONN, A CORP OF CT | Process for enhanced orientation of polymeric films |
| 4798081, | Nov 27 1985 | The Dow Chemical Company | High temperature continuous viscometry coupled with analytic temperature rising elution fractionation for evaluating crystalline and semi-crystalline polymers |
| 4808561, | Jun 21 1985 | Exxon Chemical Patents Inc. | Supported polymerization catalyst |
| 4833024, | Apr 03 1987 | CRYOVAC, INC | Low shrink energy films |
| 4843129, | Jun 15 1983 | ADVANCED ELASTOMER SYSTEMS, L P AES | Elastomer-plastic blends |
| 4855187, | May 06 1988 | Mobil Oil Corporation | Low coefficient of friction biaxially oriented film |
| 4865908, | Mar 07 1986 | Mobil Oil Corporation | Coated, oriented polymer film laminate |
| 4880422, | Jul 05 1988 | TREDEGAR FILM PRODUCTS CORPORATION A VIRGINIA CORPORATION | Refastenable diaper sheet |
| 4906315, | Jun 20 1983 | Surface relief holograms and holographic hot-stamping foils, and method of fabricating same | |
| 4913858, | Jun 19 1987 | VACUMET CORPORATION | Method of embossing a coated sheet with a diffraction or holographic pattern |
| 4933120, | Apr 18 1988 | AMERICAN BANK NOTE HOLOGRAPHICS, INC , ELMSFORD, NY , A CORP OF DE | Combined process of printing and forming a hologram |
| 4937299, | Jun 06 1983 | Exxon Research & Engineering Company | Process and catalyst for producing reactor blend polyolefins |
| 4956232, | Dec 27 1988 | MOBIL OIL CORPORATION, A CORP OF NY | Multi-layer heat-sealable polypropylene films |
| 4957790, | Dec 21 1987 | CRYOVAC, INC | Oriented polymeric films |
| 4966795, | Nov 29 1985 | PECHINEY PLASTIC PACKAGINC, INC | Multiple layer sheet structures and package |
| 4988465, | May 28 1987 | CURWOOD, INC | Manufacture of multilayer film containing very low density polyethylene |
| 5003915, | Apr 18 1988 | American Bank Note Holographics, Inc. | Apparatus for printing and for forming a hologram on sheet material |
| 5026592, | Dec 23 1987 | Hoechst Aktiengesellschaft | Opaque multilayered film having an inherent resistance to delamination |
| 5026778, | May 26 1988 | IDEMITSU KOSAN CO ,LTD | Polypropylene-based resin composition and process for preparation of sheets comprising the resin composition |
| 5028480, | Oct 05 1987 | AKZO NOBEL FILMS HOLDINGS LIMITED | Polymeric films |
| 5049436, | Jun 11 1990 | Mobil Oil Corporation | Broad sealing multi-layered opp films which yield hermetic seals |
| 5049605, | Sep 20 1989 | Milliken Research Corporation | Bis(3,4-dialkylbenzylidene) sorbitol acetals and compositions containing same |
| 5068155, | Aug 29 1989 | Chisso Corporation | Opaque, laminated and stretched products, and method for making them |
| 5077129, | Mar 01 1990 | Wolff Walsrode AG | Stretched polypropylene films having good surface slip |
| 5083850, | Aug 29 1989 | AMERICAN BANK NOTE HOLOGRAPHICS, INC , ELMSFORD, NEW YORK, A CORP OF DE | Technique of forming a separate information bearing printed pattern on replicas of a hologram or other surface relief diffraction pattern |
| 5084558, | Nov 10 1986 | OPK BIOTECH LLC | Extra pure semi-synthetic blood substitute |
| 5085816, | May 15 1989 | E. I. du Pont de Nemours and Company | Process for preparing laminar articles from a mixture of a polyolefin and ethylene/vinyl alcohol copolymers |
| 5089352, | Apr 16 1987 | CRYOVAC, INC | Cross-linked multilayer heat-shrinkable oriented polymeric film |
| 5100728, | Jul 01 1987 | Avery Dennison Corporation | High performance pressure sensitive adhesive tapes and process for making the same |
| 5110671, | Aug 04 1989 | Mobil Oil Corporation | One side heat sealable polypropylene film |
| 5116548, | Aug 29 1989 | JDS Uniphase Corporation | Replicaton of microstructures by casting in controlled areas of a substrate |
| 5125529, | Jun 28 1989 | ERCA Holding | Thermoplastic container opened by partially peeling back a multi-layered top which has been heat-sealed to its edge, and film for multi-layer tops |
| 5145212, | Feb 12 1988 | JDS Uniphase Corporation | Non-continuous holograms, methods of making them and articles incorporating them |
| 5151309, | Jul 05 1989 | The Dow Chemical Company | Die-cuttable and dispensable deformable labels |
| 5164227, | Jun 19 1987 | VACUMET CORPORATION | Method for embossing a coated sheet with a diffraction or holographic pattern |
| 5164444, | Aug 14 1989 | Avery Dennison Corporation | Emulsion pressure-sensitive adhesive polymers exhibiting excellent room- and low-temperature performance |
| 5175054, | Nov 08 1991 | Mobil Oil Corporation | Metallized film structure and method |
| 5186782, | Oct 17 1990 | Avery Dennison Corporation; AVERY INTERNATIONAL CORPORATION, A DE CORP | Method for high speed labelling of deformable substrates |
| 5190609, | Apr 02 1991 | Avery Dennison Corporation | Stable pressure sensitive shrink label technique |
| 5194324, | Dec 16 1991 | Mobil Oil Corporation | High gloss label face stock |
| 5206075, | Dec 19 1991 | Exxon Chemical Patents Inc. | Sealable polyolefin films containing very low density ethylene copolymers |
| 5212246, | Sep 28 1990 | Himont Incorporated | Olefin polymer films |
| 5213744, | Apr 20 1988 | Exxon Chemical Patents Inc. | Process for making polyolefin films |
| 5217812, | Jun 25 1990 | E. I. du Pont de Nemours and Company | Extrudable and primerless adhesives and products therefrom |
| 5242650, | Sep 09 1991 | Avery Dennison Corporation | In-mold labelling a coextruded, stretched and annealed label |
| 5250631, | Jun 13 1990 | Union Carbide Chemicals & Plastics Technology Corporation | Polymer compositions |
| 5252384, | Nov 07 1990 | Basell Polyolefine GmbH | Heat-sealable packaging film |
| 5254393, | Oct 26 1990 | Hoechst Aktiengesellschaft | Biaxially oriented multi-layer polyolefin film |
| 5254394, | Nov 07 1990 | Basell Polyolefine GmbH | Heat-sealable packaging film |
| 5272236, | Oct 15 1991 | DOW CHEMICAL COMPANY, THE | Elastic substantially linear olefin polymers |
| 5275886, | Oct 08 1992 | Mobil Oil Corporation | Polypropylene film |
| 5278272, | Oct 15 1991 | DOW CHEMICAL COMPANY, THE | Elastic substantialy linear olefin polymers |
| 5286552, | Feb 28 1990 | Himont Incorporated | Process for the production of propylene polymer films and laminates and products thus obtained |
| 5286564, | Aug 01 1990 | Himont Incorporated | Elastoplastic polyolefin compositions |
| 5288548, | Jul 31 1992 | Mobil Oil Corporation | Label face stock |
| 5292561, | Sep 26 1990 | Hoechst Aktiengesellschaft | Transparent shrink film made from biaxially oriented polypropylene |
| 5298561, | Dec 14 1988 | Himont Incorporated | Propylene polymer composition having good transparency and improved impact resistance |
| 5300365, | Sep 28 1990 | Himont Incorporated | Olefin polymer films |
| 5316777, | Apr 19 1991 | OJI-YUKA SYNTHETIC PAPER CO , LTD | Lid of container and container for instant foods using the same |
| 5326639, | Aug 23 1989 | Himont Incorporated | Thermoplastic olefin polymer and method of preparing same |
| 5331047, | Feb 17 1993 | Himont Incorporated | Olefin polymer films |
| 5332542, | Jul 03 1991 | OJI-YUKA SYNTHETIC PAPER CO , LTD | Process for producing labeled hollow container |
| 5342868, | Mar 04 1993 | Adeka Corporation | Crystalline synthetic resin composition |
| 5358792, | Feb 22 1991 | Exxon Chemical Patents Inc. | Heat sealable blend of very low density polyethylene or plastomer with polypropylene based polymers and heat sealable film and articles made thereof |
| 5360868, | Aug 30 1993 | Himont Incorporated | Polyolefin compositions having a high balance of stiffness and impact strength |
| 5362782, | May 14 1990 | Union Carbide Chemicals & Plastics Technology Corporation | Polymer compositions |
| 5376417, | Aug 08 1991 | Lintec Corporation | Label for a squeezable container and squeezable container bearing same |
| 5380572, | Aug 26 1992 | Lintec Corporation | Pressure sensitive adhesive label sheet |
| 5380810, | Oct 15 1991 | The Dow Chemical Company | Elastic substantially linear olefin polymers |
| 5382631, | Sep 30 1988 | Exxon Chemical Patents INC | Linear ethylene interpolymer blends of interpolymers having narrow molecular weight and composition distributions |
| 5395471, | Oct 15 1991 | DOW CHEMICAL COMPANY, THE | High drawdown extrusion process with greater resistance to draw resonance |
| 5407732, | Oct 29 1993 | Tyco Plastics Services AG | Multi-layer coextruded polyolefin stretch wrap films |
| 5409992, | Feb 28 1994 | Himont Incorporated | Calenderable blends containing broad molecular weight distribution propylene polymer material |
| 5414040, | Sep 15 1992 | DOW CHEMICAL COMPANY, THE | Formulated ethylene/α-olefin elastomeric compounds |
| 5424362, | Apr 28 1993 | DOW CHEMICAL COMPANY, THE | Paintable olefinic interpolymer compositions |
| 5425990, | Mar 27 1992 | Wolff Walsrode AG | Matt-effect, biaxially stretched polypropylene film and a process for its production |
| 5427807, | Oct 15 1991 | DOW CHEMICAL COMPANY, THE | Method of packaging food products |
| 5435963, | Sep 09 1991 | Avery Dennison Corporation | In-mold labelling a coextruded, stretched and annealed label |
| 5451283, | Jul 16 1993 | Avery Dennison Corporation | Method of making a uniaxially oriented label film with compatibilizer |
| 5451455, | Oct 02 1990 | Hoechst Aktiengesellschaft | Biaxially oriented polypropylene film suitable for twist wrapping |
| 5453466, | Aug 30 1993 | Montell North America Inc. | Polyolefin compositions having high balance of stiffness and impact strength |
| 5462809, | Jun 16 1992 | The Regents of the University of California | Giant magnetoresistant single film alloys |
| 5464690, | Apr 04 1994 | National City Bank | Holographic document and method for forming |
| 5468440, | May 06 1994 | Exxon Chemical Patents Inc.; Exxon Chemical Patents INC | Process of making oriented film or structure |
| 5468535, | Aug 08 1991 | Lintec Corporation | Label for a squeezable container and squeezable container bearing same |
| 5474820, | Apr 02 1992 | Hoechst Aktiengesellschaft | Biaxially-oriented multilayer polyolefin film with a silk-matt finish, process for its preparation and use thereof |
| 5475075, | Dec 13 1991 | Exxon Chemical Patents Inc. | Ethylene/longer α-olefin copolymers |
| 5476914, | Jul 15 1988 | Fina Technology, Inc. | Syndiotactic polypropylene |
| 5482766, | Jun 21 1993 | Benecke-Kaliko AG | Deep-drawable film |
| 5482780, | Apr 07 1994 | DDJ CAPITAL MANAGEMENT, LLC | Polypropylene film with cold seal release and cold seal receptive surfaces |
| 5491019, | Mar 28 1994 | CRYOVAC, INC | Oxygen-permeable multilayer film |
| 5492757, | Apr 10 1993 | Hoechst Aktiengesellschaft | Opaque, matte, multilayer polypropylene film, process for the production thereof, and the use thereof |
| 5496600, | Apr 27 1993 | Hoechst Aktiengesellschaft | Matte biaxially oriented, multilayer polypropylene film and the use thereof |
| 5501905, | Mar 24 1993 | Wolff Walsrode Aktiengesellschaft | Matt biaxially stretched polypropylene film and a process for producing the same |
| 5503923, | Apr 27 1993 | Toyoda Gosei Co., Ltd. | Molded sandwich article |
| 5508090, | Apr 01 1993 | Hoechst Aktiengesellschaft | Heat-sealable, oriented, multilayer polyolefin film, process for the production thereof, and the use thereof |
| 5516563, | Apr 07 1993 | Hoechst Aktiengesellschaft | Opaque, matte, biaxially oriented, multilayer polypopylene film, process for the production thereof, and the use thereof |
| 5525695, | Oct 15 1991 | The Dow Chemical Company | Elastic linear interpolymers |
| 5527601, | Feb 06 1993 | AKZO NOBEL FILMS HOLDINGS LIMITED | Biaxially oriented polypropylene film |
| 5529843, | Aug 29 1992 | Basell Polyolefine GmbH | Sealable composite polypropylene film |
| 5530054, | Sep 13 1989 | Exxon Chemical Patents Inc. | Elastomeric ethylene copolymers for hot melt adhesives |
| 5530055, | Dec 09 1994 | Nucleated polyolefin-based composition for rotational molding | |
| 5552482, | Sep 08 1995 | Montell North America Inc. | Thermoplastic elastomers with improved extrusion performance |
| 5560563, | Jun 02 1995 | Eastman Kodak Company | Light shield for closing the film slot of a film cartridge |
| 5560885, | Apr 02 1992 | Hoechst Aktiengesellschaft | Process for the production of biaxially-oriented multilayer polyolefin film with a silk-matt finish |
| 5560997, | Jul 01 1992 | Lintec Corporation | Film for label |
| 5562958, | Oct 15 1991 | DOW CHEMICAL COMPANY, THE | Packaging and wrapping film |
| 5573723, | Oct 02 1990 | Hoechst Aktiengesellschaft | Process for preparing biaxially oriented polypropylene film suitable for twist wrapping |
| 5582889, | May 30 1995 | BARILLA G E R F LLI-SOCIETA PER AZIONI | Self-adhesive label for reclosing packets |
| 5582923, | Oct 15 1991 | DOW CHEMICAL COMPANY, THE | Extrusion compositions having high drawdown and substantially reduced neck-in |
| 5585193, | Jul 16 1993 | Avery Dennison Corporation | Machine-direction oriented label films and die-cut labels prepared therefrom |
| 5591390, | Oct 14 1992 | The Dow Chemical Company | Method of manufacturing packaging and wrapping film |
| 5594070, | Dec 21 1990 | RKW AG RHEINISCHE KUNSTSTOFFWERKE | Oriented polymeric microporous films |
| 5595705, | Oct 14 1992 | The Dow Chemical Company | Method of manufacturing packaging and wrapping film |
| 5611980, | Jun 08 1994 | Toto Ltd. | Apparatus and method for slip casting |
| 5611982, | Jun 21 1993 | Benecke-Kaliko AG | Product for the production of a deep-drawable film |
| 5639811, | Sep 14 1989 | Avery Dennison Corporation | Tackified dual cure pressure-sensitive adhesive |
| 5641848, | Jul 24 1995 | Montell North America Inc. | Polypropylene blown film |
| 5643678, | Apr 04 1994 | National City Bank | Holographic film and method for forming |
| 5662985, | May 21 1996 | Jindal Films Americas LLC | Two-side coated label facestock |
| 5665800, | Oct 15 1991 | The Dow Chemical Company | Elastic substantially linear olefin polymers |
| 5670003, | Apr 04 1994 | National City Bank | Holographic document and method for forming |
| 5672224, | Oct 15 1992 | BECKETT COMPANY L P | Peel-back re-sealable multi-ply label |
| 5674342, | Oct 15 1991 | DOW CHEMICAL COMPANY, THE | High drawdown extrusion composition and process |
| 5674580, | Apr 04 1994 | National City Bank | Plastic foil for hot leaf stamping and method for forming |
| 5674630, | May 08 1995 | W R GRACE & CO CONN ; W R GRACE & CO - CONN | Polymer compositions and cast films |
| 5677383, | Oct 15 1991 | The Dow Chemical Company | Fabricated articles made from ethylene polymer blends |
| 5685128, | Oct 15 1991 | The Dow Chemical Company | Method of packaging food products |
| 5691043, | Jul 15 1994 | Jindal Films Americas LLC | Uniaxially shrinkable biaxially oriented polypropylene film and its method of preparation |
| 5709937, | Jan 13 1995 | Avery Dennison Corporation | Clear conformable oriented films and labels |
| 5711839, | Sep 13 1995 | Multi-Color Corporation | Process for the production of in-line gravure-printed in-mold labeled blow molded containers |
| 5712031, | Mar 06 1996 | DOW CHEMICAL COMPANY, THE | Plastic adhesive labels for glass substrates |
| 5716669, | Mar 26 1997 | Avery Dennison Corporation | Process for producing polymer films from aqueous polymer compositions |
| 5747192, | Jun 07 1995 | CCL LABEL, INC | Single ply PSA labels for battery applications |
| 5747594, | Oct 21 1994 | The Dow Chemical Company | Polyolefin compositions exhibiting heat resistivity, low hexane-extractives and controlled modulus |
| 5753349, | Apr 04 1994 | National City Bank | Document having security image and composite sheet and method for forming |
| 5756169, | Oct 27 1993 | Hoechst AG | Biaxially oriented polyolefin film, process for its preparation and its use |
| 5759648, | Jul 05 1996 | CURWOOD, INC | Multilayer plastic film, useful for packaging a cook-in foodstuff |
| 5759683, | Apr 04 1994 | National City Bank | Holographic document with holographic image or diffraction pattern directly embossed thereon |
| 5773155, | Oct 15 1991 | The Dow Chemical Company | Extrusion compositions having high drawdown and substantially reduced neck-in |
| 5783017, | Apr 04 1994 | National City Bank | Plastic foil for hot leaf stamping and method for forming |
| 5783638, | Oct 15 1991 | The Dow Chemical Company | Elastic substantially linear ethylene polymers |
| 5792549, | May 30 1996 | DDJ CAPITAL MANAGEMENT, LLC | Biaxially oriented polypropylene cold seal release films |
| 5810957, | Apr 04 1994 | National City Bank | Method for forming holographic foil |
| 5844045, | Jan 29 1993 | The Dow Chemical Company | Ethylene interpolymerizations |
| 5847053, | Oct 15 1991 | The Dow Chemical Company | Ethylene polymer film made from ethylene polymer blends |
| 5849419, | Jul 16 1993 | Avery Dennison Corporation | Uniaxially oriented label film with compatibilizer |
| 5852152, | Oct 15 1991 | The Dow Chemical Company | Packaging and wrapping film |
| 5863665, | Oct 15 1991 | The Dow Chemical Company | Extrusion compositions having high drawdown and substantially reduced neck-in |
| 5863834, | Mar 06 1996 | Matsushita Electric Industrial Co., Ltd. | Semiconductor device and method of manufacturing the same |
| 5869575, | Aug 02 1995 | The Dow Chemical Company | Ethylene interpolymerizations |
| 5874139, | Oct 21 1994 | DOW CHEMICAL COMPANY, THE | Multilayer polyolefin with balanced sealant properties |
| 5882749, | Jun 08 1995 | Exopack, LLC | Easy-opening reclosable package |
| 5885699, | Aug 27 1992 | CRYOVAC, INC | Multilayer thermoplastic packaging film |
| 5885707, | Sep 25 1995 | Wolff Walsrode AG | Sealable laminated film containing copolymers produced with metallocene catalysts |
| 5885721, | Oct 03 1996 | Mobil Oil Corporation; MOBIL CHEMICAL CORPORATION | Multilaminar high density polyethylene film with high biaxial orientation |
| 5897941, | Apr 12 1996 | CRYOVAC, INC | High modulus film |
| 5900294, | Feb 13 1993 | Hoechst Aktiengesellschaft | Biaxially oriented multilayer polyolefin film which can be heat-sealed at low temperatures, process for the production thereof, and the uses thereof |
| 5900310, | Mar 19 1993 | Hoechst Aktiengesellschaft | Heat-sealable, oriented, multilayer polyolefin film |
| 5907942, | May 21 1997 | Berry Plastics Corporation | Stretch wrap films |
| 5922800, | |||
| 5932157, | Aug 29 1992 | Basell Polyolefine GmbH | Sealable composite polypropylene film and processes for producing and using it |
| 5948199, | Jun 20 1983 | Surface relief holograms and holographic hot-stamping foils, and method of fabricating same | |
| 5948839, | May 08 1995 | W R GRACE & CO CONN ; W R GRACE & CO - CONN | Polymer compositions and cast films |
| 5955205, | Dec 08 1993 | The Dow Chemical Company | Stretch cling film and fabrication method |
| 5961766, | Apr 17 1998 | Avery Dennison Corporation | Method for selecting a substrate intended for use in a cutting operation |
| 5962092, | Mar 28 1994 | CRYOVAC, INC | Oxygen-permeable multilayer film containing antifog agent and package made therefrom |
| 5972443, | Feb 08 1994 | LIQUI-BOX CANADA INC | Multilayer ethylene copolymer film |
| 5972444, | Oct 15 1991 | DOW CHEMICAL COMPANY, THE | Polyolefin compositions with balanced shrink properties |
| 5986009, | Dec 03 1997 | DOW CHEMICAL COMPANY, THE | Blends of polypropylenes |
| 5986028, | Sep 02 1992 | The Dow Chemical Company | Elastic substantially linear ethlene polymers |
| 5998017, | Mar 12 1996 | COVALENCE SPECIALTY MATERIALS CORP | Stretch wrap films |
| 6007665, | May 23 1997 | Eastman Kodak Company | Photographic element with indicia on oriented polymer back sheet |
| 6017615, | Aug 25 1997 | JPMORGAN CHASE BANK, N A , AS COLLATERAL AGENT | Film product comprising novel polyolefins |
| 6020046, | Oct 23 1998 | Montell North America Inc. | Embossed sheets of polyolefin compositions with improved grain retention |
| 6026953, | Dec 10 1998 | Resealable dispenser-container | |
| 6033514, | Sep 02 1993 | DDJ CAPITAL MANAGEMENT, LLC | Biaxially-oriented polypropylene films |
| 6042930, | Dec 24 1997 | DOW CHEMICAL COMPANY, THE | Plastic heat-activated adhesive labels |
| 6051305, | Jan 22 1997 | CRYOVAC, INC | Printed polymeric film and process for making same |
| 6060567, | Oct 15 1991 | The Dow Chemical Company | Interpolymers formed by continuous processes |
| 6072005, | Oct 31 1997 | Kimberly-Clark Worldwide, Inc | Breathable films and process for producing them |
| 6074762, | Feb 19 1998 | Jindal Films Americas LLC | Block resistant film |
| 6083611, | Nov 12 1997 | Berry Plastics Corporation | Roll wrap film |
| 6093464, | May 24 1996 | Nitto Denko Corporation | Pressure-sensitive adhesive composition and pressure-sensitive adhesive sheets |
| 6093480, | May 21 1997 | Berry Plastics Corporation | Stretch wrap films |
| 6094889, | Feb 25 1997 | Exxon Chemical Patents, Inc. | Method of form and seal packaging |
| 6096014, | Dec 27 1996 | Kimberly-Clark Worldwide, Inc | Stable and breathable films of improved toughness and method of making the same |
| 6111023, | Oct 15 1991 | The Dow Chemical Company | Fabricated articles made from ethylene polymer blends |
| 6111102, | Mar 07 1992 | Hoechst Schering AgrEvo GmbH | Processes for preparing sulfonylureas |
| 6113271, | Mar 11 1999 | Prime Label & Screen, Inc. | Resealable label flap including label stop |
| 6127043, | Mar 21 1996 | Sengewald Verpackungen GmbH | Multilayered sheet, process for the production thereof and use thereof |
| 6136439, | Oct 23 1996 | Monolayer polymeric film and method of fabrication | |
| 6136937, | Oct 15 1991 | The Dow Chemical Company | Elastic substantially linear ethylene polymers |
| 6140442, | Oct 15 1991 | The Dow Chemical Company | Elastic fibers, fabrics and articles fabricated therefrom |
| 6165599, | Sep 15 1997 | TAGHLEEF INDUSTRIES INC | Biaxially oriented film prepared from metallocene catalyzed polypropylene |
| 6165609, | Oct 30 1998 | Avery Dennison Corporation | Security coatings for label materials |
| 6180720, | May 29 1997 | Montell North America Inc. | Polyolefin mixture containing poly(1-butene) |
| 6183856, | Jul 25 1996 | Mobil Oil Corporation | Opaque polymeric films and processes for making same |
| 6194532, | Oct 15 1991 | The Dow Chemical Company | Elastic fibers |
| 6197886, | Oct 24 1997 | Union Carbide Chemicals & Plastics Technology Corporation | Compositions containing impact copolymers made from a blend of a homopolymer phase and a rubber phase having a high ethylene content |
| 6204330, | Nov 15 1996 | Montell North Americia Inc. | Polymer mixture for slush molding |
| 6204335, | Sep 12 1997 | Westlake Longview Corporation | Compositions of linear ultra low density polyethylene and propylene polymers and films therefrom |
| 6214443, | Jun 15 1998 | OPSEC SECURITY GROUP, INC | Tamper evident holographic devices and methods of manufacture |
| 6214447, | Apr 07 1997 | Mitsui Chemicals, Inc. | Laminating propylene/1-butene random copolymer composition and composite film using the same |
| 6214935, | Jul 15 1998 | Avery Dennison Corporation | Intermediate softening point resin-based hot melt PSAs |
| 6231936, | Aug 29 1995 | Exxon Chemical Patents, Inc. | Radiation tolerant polypropylene and its useful articles |
| 6231975, | Jan 24 1997 | Mobil Oil Corporation | Sealable film |
| 6235818, | Jan 30 1997 | Mitsui Chemicals | Hot melt adhesive composition containing α-olefin/aromatic vinyl compound random copolymer |
| 6245857, | Feb 22 1999 | Fina Technology, Inc. | Compositions useful for tough, high crystallinity films |
| 6248851, | Oct 15 1991 | The Dow Chemical Company | Fabrics fabricated from elastic fibers |
| 6268062, | Apr 06 1998 | TAGHLEEF INDUSTRIES INC | Polypropylene blends and films prepared therewith |
| 6287684, | Sep 22 1998 | Yupo Corporation | Transparent label |
| 6288168, | Dec 25 1998 | Sumitomo Chemical Company, Limited | Propylene based resin composition |
| 6290261, | Jul 17 1998 | TAYLOR COMMUNICATIONS, INC | Shipment form including reusable adhesive |
| 6299984, | Sep 07 1999 | CRYOVAC, INC | Heat-shrinkable multilayer thermoplastic film |
| 6300415, | Nov 24 1995 | JNC Corporation | Propylene composition, process for preparing the same, polypropylene composition, and molded articles |
| 6300419, | Dec 08 1999 | DOW CHEMICAL COMPANY, THE | Propylene polymer composition |
| 6303233, | Apr 06 1998 | Mobil Oil Corporation | Uniaxially shrinkable biaxially oriented polypropylene film |
| 6306518, | May 19 1999 | Basell Technology Company BV | High surface gloss, co-extruded sheets from propylene polymer materials |
| 6316549, | Oct 15 1991 | The Dow Chemical Company | Ethylene polymer fiber made from ethylene polymer blends |
| 6319975, | Jul 23 1999 | HYUNDAI ENGINEERING PLASTICS CO , LTD | Composition for air permeable film of high processability and permeability and production of air permeable film |
| 6322883, | Jul 15 1994 | ExxonMobil Oil Corporation | Uniaxially shrinkable biaxially oriented polypropylene film with HDPE skin |
| 6329454, | Dec 08 1999 | DOW CHEMICAL COMPANY, THE | Filled propylene polymer composition |
| 6333096, | Dec 21 1999 | Montell Technology Company BV | Co-extruded, multilayer packaging film made from propylene polymer material |
| 6340532, | Jan 31 2001 | Nova Chemicals (International) S.A. | Shrink films |
| 6342564, | Jun 24 1997 | Borealis Technology Oy | Heterophasic propylene copolymer and process for its preparation |
| 6342566, | Feb 08 2000 | ExxonMobil Chemical Patents Inc. | Propylene impact copolymers |
| 6344250, | Jun 10 1998 | INTERTAPE POLYMER CORP | Multilayered polyolefin high shrinkage, low shrink force shrink film |
| 6348555, | Oct 15 1991 | The Dow Chemical Company | Elastic substantially linear olefin polymers |
| 6362270, | Aug 12 1999 | DOW CHEMICAL COMPANY, THE | Thermoplastic compositions for durable goods applications |
| 6364988, | Sep 13 1999 | NAN YA PLASTICS CORPORATION | Process for producing a 3-layer co-extruded biaxially oriented polypropylene synthetic paper of thickness 25-250 μm |
| 6365682, | Jun 24 1997 | Borealis Technology Oy | Process for the production of propylene terpolymers |
| 6368545, | May 13 1999 | ExxonMobil Chemical Patents INC | High clarity polyolefin multilayer blown coextruded film |
| 6376058, | Dec 21 1999 | Avery Dennison Corporation | Polypropylene based compositions and films and labels formed therefrom |
| 6379605, | Oct 22 1999 | NAN YA PLASTICS CORPORATION | Process for producing a 3-layer co-extruded biaxial-oriented polypropylene synthetic paper and transparent film for in-mold label |
| 6384123, | Jul 14 2000 | HC PROFUSION LLC | Thermoplastic elastomer film composition |
| 6384138, | Sep 04 1998 | ExxonMobil Chemical Patents INC | Hot melt pressure sensitive adhesive composition |
| 6384142, | Feb 08 2000 | ExxonMobil Chemical Patents INC | Propylene impact copolymers |
| 6387529, | Dec 24 1997 | Mobil Oil Corporation | Biaxially oriented HDPE multilayer film |
| 6391425, | Mar 30 1999 | Mobil Oil Corporation | Polyolefin film with embossed surface |
| 6410648, | Dec 17 1997 | Japan Polychem Corporation | Tacky films |
| 6423420, | Aug 11 1997 | Jindal Films Americas LLC | Oriented coextruded films |
| 6436496, | Nov 06 1998 | Avery Dennison Corporation | Halogen-free, printable, multilayered shrink films and articles encapsulated therein |
| 6436531, | Jul 20 1998 | 3M Innovative Properties Company | Polymer blends and tapes therefrom |
| 6436534, | Oct 15 1991 | The Dow Chemical Company | Elastic fibers, fabrics and articles fabricated therefrom |
| 6440533, | Sep 22 2000 | TREDEGAR FILM PRODUCTS CORPORATION A VIRGINIA CORPORATION | PVC replacement film |
| 6441094, | Sep 14 1999 | Baselltech USA Inc. | Impact resistant polyolefin compositions |
| 6444301, | Mar 18 1997 | Hoechst Trespaphan GmbH | Labels |
| 6448355, | Oct 15 1991 | The Dow Chemical Company | Elastic fibers, fabrics and articles fabricated therefrom |
| 6451426, | Jan 24 1997 | ExxonMobil Oil Corporation | Sealable film |
| 6455150, | Dec 09 1993 | ExxonMobil Oil Corporation | Multi-layer oriented heat sealable film structure of improved machinability |
| 6455171, | Feb 03 2000 | LYONDELLBASELL ADVANCED POLYMERS INC | Multilayer structure with acrylic cap layer, polyolefin core layer, and intermediate tie layer |
| 6455643, | Jun 24 1997 | Borealis Technology Oy | Process for preparing propylene homopolymers and copolymers |
| 6461555, | Feb 05 1985 | Avery Dennison Corporation | Method of preparing facestock for labels |
| 6461706, | Apr 17 1998 | Avery Dennison Corporation | Multilayer films and labels |
| 6469110, | Jun 24 1997 | Borealis Technology Oy | Process for preparing polypropylene alloys |
| 6472077, | Dec 20 1999 | Jindal Films Americas LLC | Block-resistant film |
| 6472474, | Feb 08 2000 | ExxonMobil Chemical Patents Inc. | Propylene impact copolymers |
| 6486284, | Aug 15 1997 | Dow Global Technologies LLC | Films produced from substantially linear homogeneous olefin polymer compositions |
| 6489019, | May 19 1999 | BASELL POLIOLEFINE ITALIA S P A | High surface gloss, co-extruded sheets from olefin polymer materials |
| 6495266, | Nov 12 1999 | Jindal Films Americas LLC | Films with improved blocking resistance and surface properties |
| 6500563, | May 13 1999 | EXXONMOBIL CHEMCIAL PATENTS INC | Elastic films including crystalline polymer and crystallizable polymers of propylene |
| 6500901, | Sep 12 1997 | Westlake Longview Corporation | Compositions of linear ultra low density polyethylene and propylene polymers and films therefrom |
| 6503619, | Aug 07 1998 | The Procter & Gamble Company | Soft touch labels |
| 6503635, | Nov 08 1999 | ExxonMobil Oil Corporation | Metallized multi-layer film |
| 6503637, | Feb 25 1997 | ExxonMobil Chemical Patents INC | Heat sealable films |
| 6506867, | Oct 15 1991 | Dow Global Technologies Inc | Elastic substantially linear ethylene polymers |
| 6511755, | Aug 21 1998 | JNC Corporation | Polypropylene film and multilayered polypropylene film |
| 6515093, | Sep 12 1997 | Westlake Longview Corporation | Polymers, and novel compositions and films therefrom |
| 6518377, | Apr 09 1997 | Fina Technology, Inc. | Metallocene catalyst and catalyst system for producing polypropylene blend of iso- and syndio-tactic polypropylene |
| 6534612, | Oct 15 1991 | Dow Global Technologies Inc | Elastic substantially linear ethylene polymers |
| 6548611, | Oct 15 1991 | Dow Global Technologies Inc | Elastic substantially linear olefin polymers |
| 6552149, | Jun 24 1997 | Borealis Technology Oy | Propylene terpolymers |
| 6566446, | Dec 30 1991 | Dow Global Technologies LLC | Ethylene interpolymer polymerizations |
| 6566450, | Sep 25 1998 | Fina Research, S.A. | Production of multimodal polyethylene |
| 6576306, | Sep 04 1996 | ExxonMobil Chemical Patents INC | Propylene polymers for films |
| 6576329, | Jun 12 2001 | ExxonMobil Oil Corporation | Multilayer thermoplastic film |
| 6583209, | Sep 06 2001 | Equistar Chemicals, LP | Propylene polymer composites having improved melt strength |
| 6583227, | Sep 04 1996 | ExxonMobil Chemical Patents INC | Propylene polymers for films |
| 6610792, | Jul 26 2001 | Fina Technology, Inc. | Polypropylene copolymers and method of preparing polyproylene copolymers |
| 6623866, | Apr 04 2001 | Jindal Films Americas LLC | Multilayer films including anti-block |
| 6638637, | Feb 16 2000 | 3M Innovative Properties Company | Oriented multilayer polyolefin films |
| 6642290, | Apr 12 2002 | Milliken & Company | Highly nucleated syndiotactic polypropylene |
| 6663947, | Apr 17 1998 | Avery Dennison Corporation | Multilayer films and labels |
| 6703134, | Jul 31 2000 | ExxonMobil Oil Corporation | Multi-layer film with grafted syndiotactic polypropylene adhesion promoting layer |
| 6703447, | Nov 24 1997 | High bi-directional strength monolayer polymeric film and method of fabrication | |
| 6706342, | Feb 21 2001 | ExxonMobil Oil Corporation | Polymeric labels |
| 6716501, | Jul 18 2002 | Avery Dennison Corporation | Multilayered film |
| 6723829, | Nov 12 1999 | Borealis Technology Oy | Heterophasic copolymers |
| 6734256, | Dec 29 1998 | 3M Innovative Properties Company | Block copolymer hot-melt processable adhesives, methods of their preparation, and articles therefrom |
| 6765068, | Jul 26 2001 | Fina Technology, Inc. | Polypropylene copolymers and method of preparing polypropylene copolymers |
| 6780936, | Feb 11 2003 | ExxonMobil Chemical Patents Inc. | Diene-modified propylene polymer nucleating agents |
| 6787217, | Oct 29 2002 | ExxonMobil Oil Corporation | Thermoplastic film label composite with a printable, untreated, cavitated surface |
| 6790516, | Sep 27 2001 | Nordenia Deutschland Gronau GmbH | Multi-layer label film |
| 6803421, | Nov 12 2002 | Equister Chemicals, LP; Equistar Chemicals, LP | High flow filled propylene polymer compositions having improved impact and dimensional properties |
| 6808822, | Oct 17 2001 | Medical Research Council | Multilayered shrink films and labels made therefrom |
| 6821592, | Jul 31 2001 | AVERY DENNISON CORPORAITON | Conformable holographic labels |
| 6828019, | May 01 2002 | ExxonMobil Oil Corporation | Thermoplastic film |
| 6835462, | Mar 20 2000 | Avery Dennison Corporation | Conformable and die-cuttable biaxially oriented films and labelstocks |
| 6844079, | Jun 02 2001 | Trespaphan GmbH | Film having an improved sealability and adherence |
| 6872462, | Aug 05 2002 | CRYOVAC, INC | High free shrink, high modulus, low shrink tension film with elastic recovery |
| 6881793, | Jul 16 2002 | Fina Technology, Inc. | Polyproplylene materials and method of preparing polypropylene materials |
| 6887582, | Oct 12 2001 | TORAY PLASTICS AMERICA , INC | Polyolefin film for use in cold seal cohesive applications |
| 6908687, | Dec 30 2002 | Jindal Innovation Center SRL | Heat-shrinkable polymeric films |
| 6919113, | Jul 18 2001 | Avery Dennison Corporation | Multilayered film |
| 6919407, | Nov 06 2001 | Dow Global Technologies Inc. | Blends and sealant compositions comprising isotactic propylene copolymers |
| 6939602, | Dec 31 2002 | Jindal Innovation Center SRL | Coating for the adhesive-receiving surface of polymeric labels |
| 6946535, | Nov 06 2001 | Dow Global Technologies Inc. | Films comprising isotactic propylene copolymers |
| 6982311, | Aug 15 1997 | Dow Global Technologies, Inc. | Films produced from substantially linear homogeneous olefin polymer compositions |
| 6991261, | Jun 22 2001 | Multi-Color Corporation | Labels with removable section for in-mold production of in-mold labeled molded containers |
| 6994915, | Dec 22 2000 | BASELL POLIOLEFINE ITALIA S P A | Biaxially oriented polypropylene films |
| 6995213, | Sep 29 2003 | Fina Technology, Inc. | Oriented films prepared using impact copolymer polypropylene |
| 7041765, | Nov 06 2001 | Dow Global Technologies LLC | Films comprising isotactic propylene copolymers |
| 7165888, | Jul 25 2001 | Avery Dennison Corporation | Resealable closures for packages and packages containing the same |
| 7186366, | Dec 23 1998 | NORDENIA U S A , INC | Recyclable label foil |
| 7217463, | Jun 26 2002 | Avery Dennison Corporation | Machine direction oriented polymeric films and methods of making the same |
| 7217767, | Jul 06 2004 | Fina Technology, Inc. | Blends of polypropylene impact copolymer with other polymers |
| 7309742, | Nov 14 2003 | Fina Technology, Inc | Impact copolymer with optimized melt flow, stiffness, and low-temperature impact resistance |
| 7410706, | Sep 10 2004 | Avery Dennison Corporation | Machine direction only oriented films |
| 7449522, | Jul 06 2004 | Fina Technology, Inc. | Blends of polypropylene impact copolymer with other polymers |
| 7655317, | Jan 19 2005 | ExxonMobil Chemical Patents Inc.; ExxonMobil Chemical Patents INC | Stretch-cling films |
| 7700189, | Sep 09 2005 | Avery Dennison Corporation | Heat shrinkable film with (meth)acrylate resin curable adhesive |
| 7722960, | Jul 17 2003 | INNOVIA FILMS LIMITED | Polymeric films |
| 7754814, | May 16 2005 | Fina Technology, Inc. | Polypropylene materials and method of preparing polypropylene materials |
| 7794848, | Jan 25 2007 | EQUISTAR CHEMICALS, INC | MDO multilayer polyethylene film |
| 7842365, | Oct 18 2005 | PPC RECLOSABLE PACKAGING, LLC | Resealable label flap and base material |
| 7927712, | Jul 19 2002 | INNOVIA FILMS, LTD | Polymeric film |
| 7951462, | Nov 22 2005 | Shaw Industries Group, Inc. | Monoxially-oriented and annealed films with high cross machine toughness and related process |
| 7963413, | May 23 2006 | Intercontinental Great Brands LLC | Tamper evident resealable closure |
| 8012558, | Aug 13 2007 | tesa SE | Release agent based on ethylene multi-block copolymer |
| 8105686, | Jul 17 2006 | Avery Dennison Corporation | Asymmetric multilayered polymeric film and label stock and label thereof |
| 8181783, | Nov 02 2007 | Uni-Charm Corporation | Wet sheet flexible package and label for the wet sheet flexible package |
| 8182891, | Dec 18 2008 | Prime Label & Screen, Inc. | Rigid resealable label flap having a hinge |
| 8709610, | Oct 17 2008 | Dow Global Technologies LLC | Biaxially oriented film which could be thermally laminated with paper and other substrates |
| 20010018125, | |||
| 20010029232, | |||
| 20010039314, | |||
| 20010041776, | |||
| 20010044506, | |||
| 20010051265, | |||
| 20010055692, | |||
| 20020006498, | |||
| 20020006520, | |||
| 20020028340, | |||
| 20020037969, | |||
| 20020050319, | |||
| 20020064646, | |||
| 20020065384, | |||
| 20020098303, | |||
| 20020146520, | |||
| 20020155283, | |||
| 20020160170, | |||
| 20020182390, | |||
| 20020192466, | |||
| 20030008082, | |||
| 20030021930, | |||
| 20030049436, | |||
| 20030049476, | |||
| 20030072957, | |||
| 20030078357, | |||
| 20030087114, | |||
| 20030099792, | |||
| 20030113535, | |||
| 20030114579, | |||
| 20030134062, | |||
| 20030143357, | |||
| 20030148132, | |||
| 20030157313, | |||
| 20030176603, | |||
| 20030180490, | |||
| 20030203230, | |||
| 20030207137, | |||
| 20030207138, | |||
| 20030211298, | |||
| 20040013870, | |||
| 20040023052, | |||
| 20040033349, | |||
| 20040050479, | |||
| 20040072004, | |||
| 20040081776, | |||
| 20040110019, | |||
| 20040126518, | |||
| 20040127614, | |||
| 20040197572, | |||
| 20040224175, | |||
| 20050031824, | |||
| 20050037191, | |||
| 20050048303, | |||
| 20050069723, | |||
| 20050113524, | |||
| 20050129811, | |||
| 20050167026, | |||
| 20050214558, | |||
| 20050234172, | |||
| 20050276525, | |||
| 20050287359, | |||
| 20060008666, | |||
| 20060009586, | |||
| 20060024518, | |||
| 20060024520, | |||
| 20060040100, | |||
| 20060057410, | |||
| 20060147663, | |||
| 20060251342, | |||
| 20060258811, | |||
| 20060293424, | |||
| 20070059545, | |||
| 20070142801, | |||
| 20080020191, | |||
| 20080134642, | |||
| 20080199647, | |||
| 20090068486, | |||
| 20090110944, | |||
| 20090130360, | |||
| 20090155614, | |||
| 20090220757, | |||
| 20100002963, | |||
| 20100055429, | |||
| 20100300616, | |||
| 20100323134, | |||
| 20110039151, | |||
| 20110123743, | |||
| 20110163100, | |||
| 20110177326, | |||
| 20120040197, | |||
| 20120060997, | |||
| 20120189830, | |||
| 20120196102, | |||
| 20130320019, | |||
| 20140205847, | |||
| 20140248480, | |||
| 20150151885, | |||
| 20150190988, | |||
| CN101239666, | |||
| CN101239668, | |||
| CN101489786, | |||
| CN102083619, | |||
| CN102137797, | |||
| CN102596567, | |||
| CN1086488, | |||
| CN1533342, | |||
| CN1659030, | |||
| CN1720170, | |||
| DE10147538, | |||
| DE3710670, | |||
| EP29368, | |||
| EP119314, | |||
| EP122495, | |||
| EP185454, | |||
| EP341091, | |||
| EP373660, | |||
| EP377289, | |||
| EP416379, | |||
| EP416815, | |||
| EP444671, | |||
| EP457082, | |||
| EP472946, | |||
| EP477662, | |||
| EP569621, | |||
| EP575465, | |||
| EP589213, | |||
| EP608369, | |||
| EP619827, | |||
| EP640649, | |||
| EP677832, | |||
| EP681592, | |||
| EP688007, | |||
| EP696300, | |||
| EP706448, | |||
| EP782589, | |||
| EP783006, | |||
| EP787167, | |||
| EP830248, | |||
| EP831994, | |||
| EP863183, | |||
| EP887380, | |||
| EP887381, | |||
| EP899278, | |||
| EP899279, | |||
| EP950511, | |||
| EP956947, | |||
| EP991679, | |||
| EP991684, | |||
| EP991719, | |||
| EP1044995, | |||
| EP1116745, | |||
| EP1244743, | |||
| EP1283242, | |||
| EP1376516, | |||
| EP1409360, | |||
| EP1719712, | |||
| EP1775122, | |||
| EP1813423, | |||
| EP1886934, | |||
| EP2323921, | |||
| GB1171219, | |||
| JP11198310, | |||
| JP2002037311, | |||
| JP2002370328, | |||
| JP2003137314, | |||
| JP2004114610, | |||
| JP2004182310, | |||
| JP2005281599, | |||
| JP2006326890, | |||
| JP2008063004, | |||
| JP2011526867, | |||
| JP52109580, | |||
| JP52126487, | |||
| JP54130295, | |||
| JP60178132, | |||
| JP62056117, | |||
| JP62121709, | |||
| JP8099353, | |||
| WO13888, | |||
| WO58090, | |||
| WO103922, | |||
| WO117775, | |||
| WO146314, | |||
| WO170484, | |||
| WO2084343, | |||
| WO211983, | |||
| WO3011584, | |||
| WO3014219, | |||
| WO3018312, | |||
| WO3033262, | |||
| WO3093003, | |||
| WO3093004, | |||
| WO3106514, | |||
| WO2004003874, | |||
| WO2004009348, | |||
| WO2004055101, | |||
| WO2004094129, | |||
| WO2005040270, | |||
| WO2005097492, | |||
| WO2006022973, | |||
| WO2006031435, | |||
| WO2006043919, | |||
| WO2006062504, | |||
| WO2007085283, | |||
| WO2007146986, | |||
| WO2007149900, | |||
| WO2008011402, | |||
| WO2010002834, | |||
| WO2010067111, | |||
| WO2011100029, | |||
| WO2011113008, | |||
| WO2011128669, | |||
| WO2012106025, | |||
| WO9000788, | |||
| WO9003414, | |||
| WO9206836, | |||
| WO9303093, | |||
| WO9303695, | |||
| WO9310007, | |||
| WO9313143, | |||
| WO9409060, | |||
| WO9501397, | |||
| WO9526268, | |||
| WO9532242, | |||
| WO9621557, | |||
| WO9701440, | |||
| WO9708235, | |||
| WO9801285, | |||
| WO9859002, |
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