A new and distinct variety of hop, Humulus lupulus L., named Columbus, has a superior yield of cones and a superior content of alpha acids in its resin. The new variety was cultivated as a result of a cross at a nursery near Prosser, Wash., United States, and has been asexually reproduced in and about Yakima, Wash., United States.
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This application is a continuation of U.S. patent application Ser. No. 08/159,859, filed Nov. 30, 1993, now abandoned.
The field of the present invention is hops.
Of conventional hop varieties, there are at least twenty named commercially grown hop varieties in the United States today, and some seventy-five to eighty varieties that are grown around the world. The varieties differ as to assorted physical features such as vine color and structure, as well as cone number, location, size and shape.
Commercial varieties of hop are female hops that exist as a perennial rootstock that produces an annual flush of above-ground, or aerial, vegetation. The perennial rootstock is comprised of a woody crown with a number of main roots and sub-roots that are used for water uptake, nutrient uptake, and winter starch storage. Over the winter, the woody crown supports many buds that develop into main vines (shoots) in the spring, emerge from the ground, and extend to produce the annual above-ground vegetation. In nature, with the onset of frosts in the fall, the above-ground portion of the plant "dies-back" to ground level, and only the perennial rootstock survives into the following year.
A main vine consists of a single flexible cylinder that produces pairs of leaves at nodes separated by variable distances along the length of the vine. The length of main vine between a pair of nodes is known as an internode. A bud is produced in the junction between leaf and vine, which junction is also known by the botanical term axil. Such a botanical term, as well as other botanical terms herein, are generally known to those of skill in the art, and can also be found in standard botanical texts such as Simon, E.W., et al., Lawson's Textbook of Botany--Revised, University Tutorial Press Ltd., London, England, 14th Ed. 1966. The bud grows and develops into a lateral, also known as a side-shoot or side-arm, with the same basic vegetative structure as the main vine. The buds on the laterals develop into groups of flowers that later mature into cones (strobiles). Because the laterals produce and support the cones of the hop, the structure of the laterals strongly influences the number of cones produced and hence the ultimate commercial yield of a variety.
The cones are the useful brewing commodity, and are referred to as "hops" in the commercial industry. Each cone is a group of flowers (inflorescence) consisting of sepals and petals (bracts and bracteoles) mounted on a central strig (or rachis). The resultant structure resembles a small pine cone or fir cone but is non-woody and green in color. In nature, the bracteoles support the seed of the plant.
Complete descriptions of the botanical structure of the hop plant are given in Burgess, "Hops--Botany, Cultivation and Utilization," Weed Crop Series, Interscience Publishers, Inc., New York, 1964 and Neve, "Hops," von Nostrand Reinhold, New York, 1991.
A trellis of poles and wire, commonly 18 feet in height and known as a "high trellis," supports strings that the main vines climb. The main vines grow to the top of the trellis, where they produce the laterals that support the groups of flowers that develop into the cones. Typically, the laterals bear cones only in the upper parts of the plant (i.e., closer to the main vine); the distance from the main vine varies from one variety to another. Under an alternative growing system, the "HopUnion Low Trellis Hop Growing System," the vines are grown on a trellis of single rows of 10 feet in height, like wine grapes (the 10 foot trellis is referred to herein as a "low trellis"). (Lewis, "The HopUnion U.S.A., Inc.--Low Trellis Hop Production System," Proc. Tech. Comm. of the IHGC of the XXXVIIIth International Hop Congress, Hereford, U.K. Published Rijksstation voor Landbouwtechniek, Merelbeke/Gent, Belgium, 17-37, 1990.) Under either system, when the cones are physiologically mature (ripe), the cones are harvested, then dried and compressed into bales for market, where the cones are typically used for the productuion of beverages such as beers, ales and related alcohol-containing liquids.
Different varieties of hops have differences in the chemical constituents of the lupulin of their cones. Accordingly, chemical analysis of such differences can be useful in distinguishing one hop variety from another. Such analysis is generally performed by high pressure liquid chromatography ("HPLC") of the soft resins along with gas liquid chromatography ("GLC") of the essential oils. Recently, Kenny developed a key for differentiation of hop varieties based on chemical analysis of the soft resins. (Kenny, "Identification of U.S. Grown Hop Cultivars by Hop Acid and Essential Oil Analyses," J. Amer. Soc. Brewing Chemists 48(1):3-8, 1990.) Further, Peacock and McCarty, as well as Kenny, have developed keys for the differentiation of hop varieties based on chemical analysis of the essential oils. (Peacock and McCarty, "Varietal Identification of Hops and Hop Pellets," Master Brewer Assoc. of the Americas Technical Quarterly 27:81-85, 1992; Kenny, supra.) These keys are based on gross differences in the amounts of, and ratios between, major constituents, which differences are large enough to overcome variation inherent in the analytical analysis of biological material.
The present invention provides a new variety of hop (Humulus lupulus L.), which has been named `Columbus`. The new variety comprises a superior yield of cones and, as discussed below, a superior content of alpha acids in its soft resins. Columbus is particularly suited for the production of beverages such as beers, ales and related alcohol-containing liquids.
FIG. 1 depicts a section of Columbus vine near harvest.
FIG. 2 depicts a low trellis planting of Columbus.
FIG. 3 depicts early season growth of Columbus with an internode length of about 3 inches.
FIG. 4 depicts Columbus on a low trellis and shows the density of the cones in the canopy (cones per lateral node).
FIG. 5 depicts the physical appearance of Columbus cones.
The present invention provides a new variety of hop (Humulus lupulus L.), named `Columbus,` that has a superior yield of cones and a superior content of alpha acids in its soft resins. Columbus may be classed as a bitter hop (i.e., high in alpha acids content). Columbus was bred as the result of an open-pollination cross that was carried out in 1982 at a small hop nursery near Prosser, Wash. U.S.A, and was known by the identification number 9/17. Pursuant to growth, analysis, and testing, Columbus was identified and selected from numerous candidates arising from the cross. The exact parentage of Columbus is unknown. The breeding nursery that produced Columbus contained 20-30 female plants from which seed was collected en masse, and an approximately identical number of male plants were growing and flowering at the time that pollination occurred. Columbus is a diploid hop.
Set forth below are various characteristics that distinguish Columbus from conventional hop varieties. Columbus is initially distinguishable on the basis of its physical characteristics, including the location of its cones, the internode distance, number of cones per node, the yield of its cones, and the physical characteristics of the cones. Columbus is also distinguishable on the basis of its chemical characteristics, which are determined by chemical analyses of the soft resins and essential oils. Additionally, methods for asexual reproduction of Columbus are discussed.
PAC A. Location of ConesColumbus bears a high number of cones on its laterals down to a height of about 4 feet from the ground, when grown on a high trellis. A close-up Figure depicting in detail the vine structure of Columbus is presented as FIG. 1. Conversely, most conventional hop varieties on a high trellis do not bear significant numbers of cones below about 8 feet from the ground.
On a low trellis, Columbus produces significant numbers of cones down to ground level, and cones can even be found on untrained side-shoots running along the ground. (FIG. 2.) Conversely, most conventional hop varieties on a low trellis produce cones down to about 4 to 8 feet from the ground.
The internode distance on a main vine of any hop variety is important to the yield of cones because the shorter the internode length, the greater the number of yielding laterals for a given length of main vine. Columbus has a shorter than average mature internode length, about 8" to 12", with an early season internode distance of about 3". (FIG. 3.) Conversely, in conventional hop varieties such as Nugget, the mature internode length varies from 10" to 16", with an early season internode distance of about 8". There are also "dwarf hops" in which the mature internode length varies between 5" to 8".
Although the early season growth rate and length of time for hop vines to reach the top wire of a trellis vary widely due to factors such as climatic conditions and growth and harvest management, the early season growth of Columbus is generally faster than the most aroma hops (such as Tettnang, Perle, Centennial, Saaz, Spalt, Mt. Hood, Liberty, Hallertau, Hersbruck, and Fuggle), and also faster than the quicker-growing aroma hops such as Cascade and Willamette. Such aroma hops are generally first trained between May 7 and May 10, and reach the top wire between June 20 and June 30. The aroma hop Cluster and the bitter hops Galena and Chinook are typically trained about May 15 and reach the top wire from about June 20 to about June 30. The bitter hops Nugget, Olympic, Eroica, and Columbus are typically trained about May 25 and reach the top wire about June 27 to about July 7. Among this latter group, Columbus typically grows slower than the other hop varieties at first, but then accelerates its growth and can grow to the top faster than Nugget on occasion. In other words, Columbus is a late maturing hop, and has an early growth rate that is typical for bitter hops and for Cluster, but it is a slow starter.
In common with most other hop varieties, the main vines of Columbus are originally green in color but turn to dark red to purple as the season progresses. The main vines are ridged, and along the ridges are hooked hairs that adhere to the supporting trellis. A characteristic feature of Columbus vines, as discussed above, is the short internodes.
Although the lateral length of a hop variety can vary greatly due to factors such as climate and management practices, the laterals of Columbus are typically longer than those of aroma varieties, are typically similar in length to those of Galena and Nugget, and are typically shorter than Cluster, Chinook, Olympic and Eroica. A generalization of comparative lateral lengths is as follows:
| TABLE 1 |
| ______________________________________ |
| Hop Variety Length of Lateral |
| ______________________________________ |
| Mt. Hood, Liberty, Saaz, Spalt, Perle, |
| 1'-2' |
| Hallertau, Tettnang, Hersbruck, Fuggle, |
| Centennial |
| Cascade, Willamette 1.5'-2.5' |
| Columbus, Galena, Nugget |
| 2.0'-3.0' |
| Cluster, Chinook, Olympic, Eroica |
| 2.5'-3.5' |
| ______________________________________ |
Although most commercial hops have longer laterals in the head and much shorter laterals in the lower reaches of the vine. Columbus tends to have approximately even length laterals along the length of the vine. The sub-branches of the laterals develop as bunches of cones, and as set forth below, Columbus has an unusually high number of cones in each lateral bunch, typically greater than any other commercial variety.
The head of the vine is also subject to variation depending on such factors as climatic conditions and management practices, but Columbus can be generally grouped with Cascade. Willamette, Nugget and Galena as having a moderate head, although the head of Columbus is slightly smaller and neater than typical. The head of Columbus also appears more dense than most other varieties, apparently because more laterals are developed from an equivalent vine length due to the short internode distance discussed above.
In terms of overall vine morphology, Columbus tends to be stronger than the aroma varieties but slighter than the other bitter hops and Cluster. As noted above, the overall vine morphology also gives the appearance of being more dense than other commercial hop varieties.
The leaf morphology of Columbus is typical for most commercial hop varieties, and may be summarized as set forth in the table below.
| TABLE 2 |
| ______________________________________ |
| Early Main Vine |
| Late Main Vine |
| Lateral |
| Character |
| Leaves Leaves Leaves |
| ______________________________________ |
| Number 2/node 2/node 2/node |
| Lobes cordate - 3 35 cordate - 3 |
| Width 3-5" 4-7" 1-2" |
| Length 3-5" 4-7" 1-2" |
| Upper Surface |
| smooth smooth smooth |
| Texture |
| Lower Surface |
| fairly rough |
| rough slightly rough |
| Texture |
| Color med-dark green |
| dark green med-dark green |
| Margins lightly serrated |
| moderately serrated |
| lightly serrated |
| ______________________________________ |
The leaf color of Columbus is also similar to other commercial hop varieties, although in the early part of the growing season when Columbus is slower growing than other bitter hops and Cluster, Columbus has a darker leaf, while later in the season when Columbus is faster growing, the leaf of Columbus is similar to other hops in its class. The leaf of Columbus is typically not as dark as most of the slower growing aroma hops.
Typically, cones are found in high number clusters borne at nodes on a lateral that are close to the main vine ("basal lateral nodes"). Progressively fewer cones are found in the clusters located at nodes progressively farther away from the main vine. Ultimately, the lateral terminates in a tip bearing a single cone. Columbus yields a high number of cones at the basal lateral nodes as well as at nodes located farther away from the main vine. (FIG. 4.) The basal lateral nodes of Columbus have produced up to 42 cones. Conversely, conventional low yielding hop varieties typically bear clusters of about 8-16 cones at basal lateral nodes, while conventional high yielding varieties typically bear clusters of about 16-28 cones at basal lateral nodes.
Due to the above discussed characteristics, Columbus provides an outstanding hop variety comprising the following: a plant bearing cones much lower down the main vine; a reduced internode length on the main vine, which results in a greater number of yielding laterals per given length of main vine; and, greater numbers of cones at each node, which results in greater numbers of cones on each of the yielding laterals. Accordingly, Columbus produces an outstanding yield of cones, whether grown on a high trellis or a low trellis.
Yield data for many hop varieties are compared with yield data for Columbus in Table 3. All hops were grown on a high trellis.
| TABLE 3 |
| ______________________________________ |
| Washington State |
| HopUnion |
| Five-Year Average |
| 1992 Average |
| Variety Yield (lb/acre) |
| Yield (lb/acre) |
| ______________________________________ |
| Low yielding varieties |
| Perle 1172 1366 |
| Tettnang 970 1140 |
| High yielding varieties |
| Cluster 2018 2407 |
| Chinook 1938 2216 |
| Nugget 1950 |
| 2829 |
| Galena 1926 |
| 2502 |
| Columbus -- 3290 |
| ______________________________________ |
(Hop Growers of America, Inc., 1991-1992 Annual Statistical Report, 37th Annual HGA Convention, Portland, Oreg., 1993.)
Below in Table 4, yield data from low trellis hops grown at HopUnion farms for 1990 and 1992 are compared with experimental yield data for Columbus from 1991 and 1992.
| TABLE 4 |
| ______________________________________ |
| Yield Data for Low Trellis Hops |
| 1990 Average |
| 1992 Average |
| Variety Yield (lb/acre) |
| Yield (lb/acre) |
| ______________________________________ |
| Perle 1557 1010 |
| Tettnang 1062 800 |
| Cascade 1415 |
| 1570 |
| Chinook 1234 |
| 1017 |
| Nugget 1712 |
| 1175 |
| Galena 1800 |
| 1500 |
| (Year: 1991) |
| Columbus 2832 3408 |
| ______________________________________ |
First year plantings of hops typically yield significantly less than mature plantings of the same varieties. However, a 1992 first year planting of Columbus on a low trellis yielded, over an area of about 4.5 acres, an average of 2547 lb/acre. Columbus produces such yields with a growth habit that presents no problems for ease of harvesting.
Cones are typically described by size (large, medium, or small) and by degree of compactness (loose, medium, or tight). Size and compactness are indicative of the degree of compression (internode length) between the nodes of the central strig that subtends (supports) the bracts and bracteoles. Also, cones are often described in terms of weight, most often expressed in milligrams (mg). Light cones are usually between 120 and 160 mg in weight, heavy cones usually between 160-220 mg (kiln dry basis). Often the description includes a brief comment on general shape of the cone, such as round, ovoid, plump, etc.
Columbus cones are normally medium in length, typically about 1.25", medium to tight in compactness, and typically about 1" in diameter. Further, Columbus cones are typically quite rounded and plump, and weigh about 180-250 mg (kiln dry basis) at maturity. (FIG. 5.) Conversely, Chinook cones typically have bracts with the tips turned backwards (reflexed). Fuggle cones are typically square in cross-section. Nugget cones are typically compact, tight, and firm. Columbus cones are typically more dense than other commercial hop varieties, and hence typically heavier on a per cone basis. Columbus cones have little or no propensity to shatter when fresh or when properly dried.
The susceptibility of Columbus to downy mildew (Pseudoperunospora humuli) is similar to Galena and Cluster, which are less resistant than most other commercial hop varieties. Columbus is apparently resistant to Verticillium wilt (Verticillium dahliae). Tests have indicated that Columbus can become infected with Prunus necrotic ringspot virus, hop latent virus and American hop latent virus, although it is also possible to free Columbus of these viruses by standard meristem culture techniques. Columbus has not shown any symptoms of infection when carrying these viruses, as is usual for most commercial hop varieties. Columbus shows no unusual tolerance or sensitivity to damson hop aphid (Phorodon humuli) and two spotted mite (Tetranychus urticae).
Based upon sensory analyses of dried/baled leaf hop samples, Columbus has a quality profile that is similar to most other commercial hop varieties. Columbus has a mild, gentle aroma with no particular, peculiar character. However, Columbus is distinguishable from the commercial aroma varieties and Cluster by virtue of its higher resin content, which is indicated by visual inspection of the open cone and the much greater number of lupulin glands present in Columbus.
PAC A. Chemical Analyses in GeneralChemical analysis of hops typically consists of analysis of the lupulin of the cones. The lupulin consists of the following chemical components and sub-components:
| ______________________________________ |
| Soft resins alpha acids (humulones) |
| beta acids (lupulones) |
| Hard resins |
| Uncharacterized resins |
| Waxes |
| Tannins |
| Essential oils hydrocarbons |
| oxygenated compounds |
| sulfur compounds |
| ______________________________________ |
Of the above components, the soft resins and essential oils are of particular relevance to the differentiation of hop varieties. In regard to the soft resins, there are three analogues of the alpha acids, i.e., humulone, ad-humulone, and cohumulone, and there are also three analogues of the beta acids, i.e., lupulone, ad-lupulone, and colupulone.
Due to their chemical characteristics, some hop varieties are referred to as aromatic, or low alpha, hops and are known to contribute good hop flavor and aroma. Other hop varieties are high in bittering potential (i.e., high in alpha acids) and are referred to as bitter or high alpha hops. Columbus may be referred to as such a bitter or high alpha hop. Hop varieties in an intermediate varietal classification have medium levels of alpha acids and are referred to as dual-purpose hops.
Table 5 lists the total amount of alpha and beta acids, the ratio of alpha acids to beta acids, and estimates of the relative proportions of cohumulone and colupulone for several high alpha hops. This data was determined by HPLC analysis according to standard methods well known to those having skill in the art. (See, e.g., American Society of Brewing Chemists, "Hops Method 12: Analysis of Hops, Hop Powders and Hop Pellets by High Pressure Liquid Chromatography," in "Methods of Analysis," The Society, St. Paul, Mn., 8th ed. 1991.) Table 5 also gives data on storage losses, which indicate the loss of alpha acids by oxidation. The data are expressed as ranges to account for inherent biological variation from sample to sample.
| TABLE 5 |
| ______________________________________ |
| Parameter Chinook Nugget Galena |
| ______________________________________ |
| Alpha acids (% w/w) |
| 12.0-14.0 12.0-14.0 |
| 11.0-13.0 |
| cohumulone (%) |
| 30-35 |
| 24-30 |
| 36-42 |
| Beta acids (% w/w) |
| 3.4-4.0 |
| 4.0-5.5 |
| 7.0-9.0 |
| colupulone (%) |
| 55-66 |
| 50-55 |
| 60-65 |
| Alpha/beta ratio |
| 3.5-4.0 |
| 2.5-3.0 |
| 1.5-2.0 |
| Oil content (mls/100 g) |
| 1.5-2.3 |
| 1.2-2.0 |
| 0.7-1.2 |
| Loss of alpha acids (%) |
| 35-45 |
| 20-35 |
| 20-30 |
| 6 months storage |
| room temperature |
| ______________________________________ |
| Parameter Olympic Eroica Columbus |
| ______________________________________ |
| Alpha acids (% w/w) |
| 11.5-13.5 11.0-13.0 |
| 14.0-16.0 |
| cohumulone (%) |
| 38-43 |
| 30-35 |
| Beta acids (% w/w) |
| 4.0-6.0 |
| 4.0-5.5 |
| 4.5-5.5 |
| colupulone (%) |
| 57-62 |
| 67-70 |
| 55-60 |
| Alpha/beta ratio |
| 2.0-2.7 |
| 2.2-2.8 |
| 2.7-3.3 |
| Oil content (mls/100 g) |
| 1.4-2.0 |
| 0.5-1.3 |
| 1.5-2.2 |
| Loss of alpha acids (%) |
| 40-55 |
| 35-50 |
| 60-80 |
| 6 months storage |
| room temperature |
| ______________________________________ |
Table 5 indicates the following: (a) Columbus has a higher content of alpha acids than the other high alpha hops; (b) Columbus' cohumulone and colupulone contents are higher than Nugget, lower than Eroica and Galena, and similar to Chinook; (c) Columbus' beta acid content is higher than Chinook and lower than Galena; (d) Columbus' alpha/beta ratio is higher than Galena or Olympic but lower than Chinook; and (e) Columbus more rapidly loses its alpha acids in ambient storage than the other varieties.
Table 5 shows that Columbus has an alpha acids content well in excess of 10% w/w. This distinguishes Columbus from the aromatic hops. Examples of such aromatic hops are listed in Table 6.
| TABLE 6 |
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| Alpha acids content |
| Variety (% w/w of cone) |
| ______________________________________ |
| Cascade 4.5-7.0 |
| Cluster 5.5-8.5 |
| Fuggle 4.0-5.5 |
| Hallertau 3.5-5.5 |
| Hersbruck 3.5-5.5 |
| Liberty 3.0-5.0 |
| Mount Hood 5.0-7.5 |
| Perle 7.0-9.5 |
| Saaz 3.0-4.5 |
| Spalt 3.0-5.5 |
| Tettnang 4.0-5.0 |
| Willamette 4.0-6.0 |
| ______________________________________ |
As discussed above, Kenny developed a key for identification of hop varieties based on the soft resin components. The application of the key of Kenny to Columbus is depicted in Table 7. At each decision point, certain varieties are eliminated according to a yes/no decision. The path to Columbus is shown by the double arrow. In the key depicted in Table 5, as well as in the other keys discussed herein, steps from the published key that did not eliminate any varieties in the present analysis have been deleted.
| TABLE 7 |
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| Major U.S. Variety Eliminations |
| ______________________________________ |
| 1. Fresh alpha + beta > 15% |
| → |
| NO Cascade, Cluster, |
| and Fresh Alpha > 10% Fuggle, Hallertau, |
| Hersbruck, Liberty, |
| ⇓ |
| YES Mt. Hood, Perle, Saaz, |
| (High alpha hops) |
| Spalt, Tettnang, |
| Willamette |
| 2. Cohumulone > 40% |
| → |
| YES Eroica |
| ⇓ |
| NO |
| 3. Colupulone > 60% |
| → |
| YES Galena |
| ⇓ |
| NO |
| 4. Cohumulone < 30% |
| → |
| YES Nugget |
| ⇓ |
| NO |
| 5. Alpha/beta ratio > 3.0 |
| → |
| YES Chinook (3.5-4.0) |
| ⇓ → |
| NO Olympic (2.0-2.7) |
| Columbus(2.7-3.3) |
| ______________________________________ |
Table 7 relates to hops with a hop storage index, or HSI, well below 0.300, which indicates that the alpha and beta acids of the hops are fresh when analyzed. In Table 7, step 1 eliminates all the aromatic hops on the basis of their low content of alpha acids and low alpha plus beta acids. Step 2 eliminates Eroica on the basis of high cohumulone content. Step 3 eliminates Galena on the basis of high colupulone content. (Eroica is again eliminated at this step.) Step 4 eliminates Nugget on the basis of low cohumulone content. Step 5 eliminates Chinook on the basis of a high alpha/beta ratio, while Olympic is eliminated on the basis of a low alpha/beta ratio. Note, Chinook is also eliminated on the basis of its higher beta acid content.
Accordingly, Columbus is differentiated from all major U.S. varieties based on its soft resins content. Similarly, Columbus is distinguished from the minor U.S. hop varieties, except Aquila, Banner, and Centennial, based on soft resins content. However, Columbus is distinguished from Aquila, Banner, and Centennial by its essential oils content, as discussed below.
Detailed analysis of the essential oils allows a further differentiation of Columbus from other hops. Table 8 further distinguishes some of the varieties discussed above in Table 7, while Table 9 distinguishes varieties not distinguished above.
Extraction and analysis of essential oils are performed according to methods well known to those having skill in the art. Preferably, the essential oils are extracted by steam distilling previously dried hops for about four hours (with the steam of the distillation condensed using a cold-finger condenser). The resultant essential oils are then examined by GLC analysis.
GLC analysis for various hops are presented as Appendices 1 and 2 hereto as follows:
Appendix 1: Detailed essential oil analysis results of many of the world's hop varieties including all U.S. grown varieties except Mount Hood. Columbus is the final entry.
Appendix 2: Detailed GLC traces and listings of constituent peaks from essential oils analysis. Columbus is compared with the other U.S. high alpha hops, Galena, Chinook, and Nugget.
As with the soft resins, keys can be used to differentiate by essential oils content. Only United States varietal differentiations are depicted below in Tables 8 and 9, but non-United States varietal eliminations are listed in Peacock and McCarty, supra, and can be readily utilized by those having skill in the art to distinguish between those varieties and Columbus.
| TABLE 8 |
| ______________________________________ |
| Key of Kenny |
| Major U.S. variety eliminations |
| ______________________________________ |
| 1. β-Farnesene content > 1% |
| → |
| YES Cascade, Fuggle, |
| ⇓ |
| NO Saaz, Spalt |
| Tettnang, Willamette |
| 2. Humulene/ → |
| NO Eroica, Olympic |
| β-Caryophyllene ratio > 1.5 |
| ⇓ |
| YES |
| 3. Presence of 2-Tridecanone/ |
| → |
| NO Galena |
| presence of a peak @ (*see note in text) |
| 34.38 > 1.0% |
| ⇓ |
| NO |
| 4. β-Caryophyllene/ |
| → |
| YES Cluster, Nugget |
| ∝-copaene > 20 |
| ⇓ |
| NO |
| Chinook Columbus |
| (12.1) (13.4) |
| ______________________________________ |
Table 8 was prepared using the data provided in Appendix 1. As shown in Table 8, step 1 eliminates the high β-farnesene hops, i.e., Cascade, Fuggle, Saaz, Spalt, Tettnang, and Willamette. Step 2 eliminates the low humulene varieties, i.e., Eroica and Olympic. Step 3 eliminates Galena because Columbus is unique for having no 2-tridecanone, and Columbus lacks a large peak found in Galena at 34.38 minutes (the peak is greater than 1% of the measured components of Galena). Step 4 eliminates both Cluster and Nugget. The remaining varieties are Columbus and Chinook. As shown in Table 7, Columbus is differentiated from Chinook by Columbus' lower alpha/beta ratio. In regard to some other varieties, Perle is eliminated by virtue of its low alpha acids content, while Columbus is distinguishable from Hersbruck, Hallertau, Liberty, and Mount Hood because Columbus has a much higher alpha acids content.
| TABLE 9 |
| ______________________________________ |
| Key of Peacock and McCarty (1992) |
| Major U.S. variety eliminations |
| ______________________________________ |
| Columbus |
| ⇓ |
| 1. Humulene present |
| → |
| YES Aquila, Eroica |
| ⇓ |
| YES |
| 2. β-Farnesene > |
| → |
| YES Cascade, Fuggle |
| 5% Humulene Saaz, Spalt, |
| Tettnang, Willamette |
| ⇓ |
| NO |
| 3. Humulene/Selinene > 20 |
| → |
| YES Banner, Hallertau, |
| Liberty, Mt. Hood, |
| Perle |
| ⇓ |
| NO |
| 4. Contains Eudesmol |
| → |
| YES Chinook, Hersbruck |
| ⇓ |
| NO |
| 5. Cohumulone < 38% |
| → |
| NO Cluster, Galena |
| ⇓ |
| YES |
| Columbus, Nugget, |
| Olympic |
| ______________________________________ |
Table 9 depicts the key of Peacock and McCarty, which differentiates Aquila, Banner, and Centennial. The data from Appendix 1 is used for all steps except step 4, for which the data in Appendix 2 (which quantifies eusdesmol) is necessary. In Table 9, Step 1 eliminates Aquila and Eroica. Step 2 eliminates the six high β-farnesene hops. Step 3 eliminates Perle, Banner, Hallertau, Liberty, and Mount Hood. Step 4 eliminates Hersbruck and Chinook. Step 5 eliminates Cluster and Galena. Table 7 does not distinguish Columbus from Nugget and Olympic. However, as discussed above, Nugget and Olympic are distinguished from Columbus by each of Table 7 and Table 8.
Finally, the variety Centennial has not yet been distinguished. The data in Appendix 1 show that Centennial has a β-caryophyllene level of 2.649, while Columbus has a β-caryophyllene level of 10.236. Therefore, the varieties are distinguished because they are at virtually opposite ends of the scale for β-caryophyllene.
Columbus is asexually reproduced according to methods well known to those having skill in the art. Such methods generally comprise one of three procedures: (a) taking rootstock cuttings known as "roots" or "strap cuts;" (b) converting vine material into woody root-like material in the field and dividing this material into "layered cuttings;" or (c) the use of softwood cuttings, which are also known as "mist cuttings," of green vegetative or shoot material, usually under greenhouse conditions. Further, traditional methods can be applied to make a cell tissue culture from Columbus. Such a cell tissue culture can be stored for extended periods, and gives rise to clones (i.e., asexual progeny) of Columbus. Columbus has been asexually reproduced on ranches associated with HopUnion USA, Inc., located in and about Yakima, Wash. U.S.A.
In the field, when main vines die back in the fall, their bases turn woody and swell with the deposition of starch reserves. These bases produce buds at the sites where the main vine nodes were previously located. The bases, usually 4"-8" long and between one-half and two inches thick, are removed by cutting with a sharp knife; other buds on the rootstock produce re-growth in the spring. The detached vine bases are then planted singly or in multiples, in pots or in the field.
Such a procedure typically provides up to a 15-fold increase over the starting number of plants. The increase may be lower where multiple rootstocks (up to 6-8) are to be planted at a single site, to form a single new composite plant.
In the field, main vines are grown up a string, typically to a pre-determined height of about 10 feet. The string is then lowered and the newly grown main vines laid along the ground (for example, for about 8 feet). The string is then re-hung so that a portion of the main vines can renew vertical growth, but in a new location. Some main vines are left laying along the ground and are buried with soil, where the absence of light on the buried, green main vine stimulates it to turn woody, form buds at the nodes and swell with starch deposits. When the unburied portion of the vine has died back, the buried, now woody, portion is dug up and cut up into numerous layered cuttings, which are then replanted to give new plants. Such a procedure provides up to about a 50-fold increase over the starting number of plants.
In an alternative embodiment, new plants are placed at the bottom of deep, open trenches, preferably in a nursery. As the plants grow, soil is periodically pushed into the trench around the vines, thereby yielding layered cuttings in a vertical plane.
Actively growing main vines of a plant are cut into sections comprising a half-node, a single node, or two nodes. Main vines for this purpose are preferably grown in a greenhouse, where growing conditions can be maximized. The cuttings are planted and stuck in a suitable medium, preferably with bottom heat and an intermittent water mist, further preferably under glass. The cuttings produce a rooted plant with new main vine growth about two to three weeks after removal from the original plant. These rooted softwood cuttings can be further grown in pots, in a nursery, or even in the final new plantation. Using such a procedure, it is possible to achieve up to about a 100-fold increase over the starting number of plants.
| APPENDIX 1 |
| ______________________________________ |
| Detailed GLC analysis of assorted hop varieties. |
| Analytical Conditions: see Kenny (1990), supra. |
| OIL AREA PERCENTS OF COMMERCIAL HOPS |
| ______________________________________ |
| GC/ TENTATIVE IDENTI- |
| FID CMPD. FICATION BY GC./ 21223 21053 |
| RT. # MASS SPECTROSCOPY |
| AQUILA AURORA |
| ______________________________________ |
| 6.42 9 A-PINENE 0.105 0.112 |
| 7.46 14 ISOBUTYL ISOBUTYRATE |
| 0.000 0.326 |
| 8.10 16 8-PINENE 0.898 0.817 |
| 9.11 18 MYRCENE 62.462 58.731 |
| 9.77 22 2-METHYL-BUTYL 0.171 0.159 |
| PROPANOATE |
| 9.90 23 ISOAMYL ISOBUTYRATE |
| 0.000 0.076 |
| 9.96 24 2-METHYL-BUTYL 0.370 0.754 |
| ISOBUTARATE |
| 10.28 |
| 26 L-LIMONENE 0.243 0.228 |
| 10.62 |
| 27 B-PHELLANDRENE? 0.262 0.234 |
| C10H15 |
| 11.59 |
| 32 trans-OCIMENE 1.542 0.207 |
| 12.45 |
| 35 2-METHYL-BUTYL 0.000 0.000 |
| 2-METHYL-BUTYRATE |
| 12.68 |
| 36 METHYL HEPTANOATE |
| 0.445 0.656 |
| 12.91 |
| 40 ISOAMYL ISOVALERATE |
| 0.000 0.000 |
| 14.31 |
| 43 METHYL 4-METHYL- 0.069 0.160 |
| HEXA-2-ENOATE |
| 14.39 |
| 45 METHYL 6-METHYL- 0.230 0.264 |
| HEPTANOATE |
| 15.98 |
| 51 METHYL OCTANOATE 0.317 0.506 |
| 16.26 |
| 55 NONANAL 0.048 0.083 |
| 19.41 |
| 73 METHYL NONANOATE 0.172 0.343 |
| 19.56 |
| 75 2-DECANONE, 0.139 0.379 |
| A-YLANGENE |
| 19.93 |
| 77 A-COPAENE 0.121 0.161 |
| 21.00 |
| 83 LINALOOL 0.368 0.997 |
| 21.31 |
| 88 A-GURJUNENE 0.000 0.000 |
| 21.42 |
| 89 7-METHYL-2-DECANONE |
| 0.062 0.218 |
| 22.56 |
| 93 C15H24 CALARENE? 0.000 0.000 |
| 22.72 |
| 95 A-BERGAMOTENE, 0.239 0.408 |
| METHYL DECANOATE |
| 23.01 |
| 96 2-UNDECANONE 0.448 1.402 |
| 23.10 |
| 97 2-DECANOL 0.000 0.160 |
| 23.44 |
| 99 8-CARYOPHYLLENE 4.104 4.403 |
| 23.84 |
| 102 METHYL DEC-4-ENOATE |
| 1.608 1.286 |
| 24.03 |
| 103 MW168 2-OL? 0.000 0.181 |
| ME 43,81,110,108 |
| 25.18 |
| 114 B-FARNESENE 0.000 4.371 |
| 26.10 |
| 122 HUMULENE 1.193 14.141 |
| 26.16 |
| 123 METHYL DEC-4,8- 1.462 0.310 |
| DIENOATE |
| 26.46 |
| 129 WILEY# 123998 MW 204 |
| 0.341 0.635 |
| C15H24 |
| 26.59 |
| 131 2-DODECANONE 0.311 0.000 |
| 27.32 |
| 138 A-FARNESENE OR 0.270 0.132 |
| ZINGIBERENE |
| 27.53 |
| 139 CAS# 030021-74-0 0.000 0.000 |
| 27.75 |
| 143 A-MUUROLENE 0.114 0.182 |
| 27.90 |
| 144 B-SELINENE 2.421 0.109 |
| 28.04 |
| 145 A-SELINENE 2.745 0.130 |
| 28.34 |
| 147 METHYL 0.266 0.308 |
| ?-UNDECENOATE |
| 29.16 |
| 154 D-CADINENE 0.531 0.696 |
| 29.39 |
| 155 G-CADINENE 0.191 0.381 |
| 30.34 |
| 164 CAS# 016728-99-7 OR |
| 3.659 0.184 |
| G-SELINENE |
| 30.73 |
| 166 A-MUUROLINE 0.000 0.000 |
| 31.15 |
| 170 2-TRIDECANONE 1.620 1.080 |
| 31.36 |
| 171 GERANYL PROPANOATE |
| 0.275 0.000 |
| 31.46 |
| 172 MW 212 METHYL 0.000 0.000 |
| ?-DODECENOATE |
| 32.28 |
| 177 trans-GERANIOL 0.264 0.000 |
| 32.54 |
| 179 CAS# 000483-77-2 1.173 0.000 |
| (CALAMENENE ?) |
| 34.38 |
| 187 METHYL 3,6- 0.109 0.000 |
| DODECDIENOATE ME 79 |
| 36.42 |
| 196 MW 210 ME 43,54,82 |
| 0.122 0.282 |
| 39.11 |
| 211 CARYOPHYLLENE OXIDE |
| 0.121 0.083 |
| 40.23 |
| 221 HUMULENE 0.000 0.530 |
| MONO-EPOXIDE I |
| 40.28 |
| 223 MW222 ME 43,82 0.177 0.000 |
| 41.07 |
| 225 HUMULENE 0.000 0.199 |
| MONO-EPOXIDE II |
| 41.55 |
| 228 HUMULENE 0.000 0.000 |
| MONO-EPOXIDE III |
| 41.88 |
| 231 MW 222 ME 43,79,80 |
| 0.598 0.950 |
| 43.88 |
| 242 MW 220 ME 43,79,91 |
| 0.170 0.262 |
| 44.73 |
| 246 T-CADINOL 0.214 0.000 |
| 46.08 |
| 255 T-MUUROLOL 0.000 0.000 |
| ME 95,121,204 |
| 47.50 |
| 262 MW 220 ME 41,67,109 |
| 0.000 0.000 |
| DIEPOXIDE? |
| 48.69 |
| 268 FARNESOL 0.407 0.000 |
| ______________________________________ |
| GC/ TENTATIVE IDENTI- |
| FID CMPD. FICATION BY GC./ 21080 21287 |
| RT. # MASS SPECTROSCOPY |
| BACKA BANNER |
| ______________________________________ |
| 6.42 9 A-PINENE 0.000 0.110 |
| 7.46 14 ISOBUTYL ISOBUTYRATE |
| 0.000 0.129 |
| 8.10 16 8-PINENE 0.275 0.842 |
| 9.11 18 MYRCENE 15.376 65.305 |
| 9.77 22 2-METHYL-BUTYL 0.075 0.391 |
| PROPANOATE |
| 9.90 23 ISOAMYL ISOBUTYRATE |
| 0.000 0.173 |
| 9.96 24 2-METHYL-BUTYL 0.000 0.988 |
| ISOBUTARATE |
| 10.28 |
| 26 L-LIMONENE 0.108 0.243 |
| 10.62 |
| 27 B-PHELLANDRENE? 0.000 0.273 |
| C10H15 |
| 11.59 |
| 32 trans-OCIMENE 0.000 0.681 |
| 12.45 |
| 35 2-METHYL-BUTYL 0.000 0.068 |
| 2-METHYL-BUTYRATE |
| 12.68 |
| 36 METHYL HEPTANOATE |
| 0.281 0.381 |
| 12.91 |
| 40 ISOAMYL ISOVALERATE |
| 0.000 0.000 |
| 14.31 |
| 43 METHYL 4-METHYL- 0.298 0.093 |
| HEXA-2-ENOATE |
| 14.39 |
| 45 METHYL 6-METHYL- 0.000 0.413 |
| HEPTANOATE |
| 15.98 |
| 51 METHYL OCTANOATE 0.090 0.269 |
| 16.26 |
| 55 NONANAL 0.939 0.037 |
| 19.41 |
| 73 METHYL NONANOATE 0.075 0.188 |
| 19.56 |
| 75 2-DECANONE, 0.497 0.051 |
| A-YLANGENE |
| 19.93 |
| 77 A-COPAENE 0.420 0.173 |
| 21.00 |
| 83 LINALOOL 0.461 0.583 |
| 21.31 |
| 88 A-GURJUNENE 0.164 0.166 |
| 21.42 |
| 89 7-METHYL-2-DECANONE |
| 0.384 0.000 |
| 22.56 |
| 93 C15H24 CALARENE? 0.382 0.069 |
| 22.72 |
| 95 A-BERGAMOTENE, 0.000 0.243 |
| METHYL DECANOATE |
| 23.01 |
| 96 2-UNDECANONE 1.442 0.046 |
| 23.10 |
| 97 2-DECANOL 0.685 0.173 |
| 23.44 |
| 99 8-CARYOPHYLLENE 10.792 5.478 |
| 23.84 |
| 102 METHYL DEC-4-ENOATE |
| 0.588 0.910 |
| 24.03 |
| 103 MW168 2-OL? 0.394 0.000 |
| ME 43,81,110,108 |
| 25.18 |
| 114 B-FARNESENE 0.439 0.000 |
| 26.10 |
| 122 HUMULENE 37.338 13.256 |
| 26.16 |
| 123 METHYL DEC-4,8- 0.000 0.157 |
| DIENOATE |
| 26.46 |
| 129 WILEY# 123998 MW 204 |
| 1.342 0.475 |
| C15H24 |
| 26.59 |
| 131 2-DODECANONE 0.000 0.000 |
| 27.32 |
| 138 A-FARNESENE OR 0.114 0.134 |
| ZINGIBERENE |
| 27.53 |
| 139 CAS# 030021-74-0 0.182 0.094 |
| 27.75 |
| 143 A-MUUROLENE 0.314 0.173 |
| 27.90 |
| 144 B-SELINENE 0.391 0.126 |
| 28.04 |
| 145 A-SELINENE 0.429 0.140 |
| 28.34 |
| 147 METHYL 0.000 0.000 |
| ?-UNDECENOATE |
| 29.16 |
| 154 D-CADINENE 1.688 0.873 |
| 29.39 |
| 155 G-CADINENE 1.075 0.478 |
| 30.34 |
| 164 CAS# 016728-99-7 OR |
| 0.263 0.126 |
| G-SELINENE |
| 30.73 |
| 166 A-MUUROLINE 0.201 0.100 |
| 31.15 |
| 170 2-TRIDECANONE 0.871 1.945 |
| 31.36 |
| 171 GERANYL PROPANOATE |
| 0.000 0.269 |
| 31.46 |
| 172 MW 212 METHYL 0.000 0.081 |
| ?-DODECENOATE |
| 32.28 |
| 177 trans-GERANIOL 0.000 0.000 |
| 32.54 |
| 179 CAS# 000483-77-2 0.359 0.082 |
| (CALAMENENE ?) |
| 34.38 |
| 187 METHYL 3,6- 0.000 0.484 |
| DODECDIENOATE ME 79 |
| 36.42 |
| 196 MW 210 ME 43,54,82 |
| 0.236 0.137 |
| 39.11 |
| 211 CARYOPHYLLENE OXIDE |
| 2.753 0.097 |
| 40.23 |
| 221 HUMULENE 0.173 0.048 |
| MONO-EPOXIDE I |
| 40.28 |
| 223 MW222 ME 43,82 1.201 0.113 |
| 41.07 |
| 225 HUMULENE 9.016 0.176 |
| MONO-EPOXIDE II |
| 41.55 |
| 228 HUMULENE 0.124 0.000 |
| MONO-EPOXIDE III |
| 41.88 |
| 231 MW 222 ME 43,79,80 |
| 1.910 0.213 |
| 43.88 |
| 242 MW 220 ME 43,79,91 |
| 0.500 0.113 |
| 44.73 |
| 246 T-CADINOL 0.403 0.070 |
| 46.08 |
| 255 T-MUUROLOL 0.209 0.040 |
| ME 95,121,204 |
| 47.50 |
| 262 MW 220 ME 41,67,109 |
| 0.333 0.000 |
| DIEPOXIDE? |
| 48.69 |
| 268 FARNESOL 0.000 0.084 |
| ______________________________________ |
| GC/ TENTATIVE IDENTI- |
| 21116 |
| FID CMPD. FICATION BY GC./ BREWERS 64100 |
| RT. # MASS SPECTROSCOPY |
| GOLD BULLION |
| ______________________________________ |
| 6.42 9 A-PINENE 0.117 0.110 |
| 7.46 14 ISOBUTYL ISOBUTYRATE |
| 0.169 0.251 |
| 8.10 16 8-PINENE 0.988 0.934 |
| 9.11 18 MYRCENE 69.050 67.113 |
| 9.77 22 2-METHYL-BUTYL 0.344 0.469 |
| PROPANOATE |
| 9.90 23 ISOAMYL ISOBUTYRATE |
| 0.068 0.153 |
| 9.96 24 2-METHYL-BUTYL 1.267 1.053 |
| ISOBUTARATE |
| 10.28 |
| 26 L-LIMONENE 0.260 0.254 |
| 10.62 |
| 27 B-PHELLANDRENE? 0.328 0.324 |
| C10H15 |
| 11.59 |
| 32 trans-OCIMENE 0.549 0.441 |
| 12.45 |
| 35 2-METHYL-BUTYL 0.096 0.045 |
| 2-METHYL-BUTYRATE |
| 12.68 |
| 36 METHYL HEPTANOATE |
| 0.298 0.543 |
| 12.91 |
| 40 ISOAMYL ISOVALERATE |
| 0.000 0.038 |
| 14.31 |
| 43 METHYL 4-METHYL- 0.000 0.089 |
| HEXA-2-ENOATE |
| 14.39 |
| 45 METHYL 6-METHYL- 0.105 0.205 |
| HEPTANOATE |
| 15.98 |
| 51 METHYL OCTANOATE 0.206 0.174 |
| 16.26 |
| 55 NONANAL 0.049 0.040 |
| 19.41 |
| 73 METHYL NONANOATE 0.105 0.208 |
| 19.56 |
| 75 2-DECANONE, 0.040 0.070 |
| A-YLANGENE |
| 19.93 |
| 77 A-COPAENE 0.166 0.149 |
| 21.00 |
| 83 LINALOOL 0.461 0.441 |
| 21.31 |
| 88 A-GURJUNENE 0.039 0.070 |
| 21.42 |
| 89 7-METHYL-2-DECANONE |
| 0.000 0.000 |
| 22.56 |
| 93 C15H24 CALARENE? 0.085 0.064 |
| 22.72 |
| 95 A-BERGAMOTENE, 0.105 0.154 |
| METHYL DECANOATE |
| 23.01 |
| 96 2-UNDECANONE 0.000 0.119 |
| 23.10 |
| 97 2-DECANOL 0.179 0.156 |
| 23.44 |
| 99 8-CARYOPHYLLENE 6.305 6.054 |
| 23.84 |
| 102 METHYL DEC-4-ENOATE |
| 0.566 0.837 |
| 24.03 |
| 103 MW168 2-OL? 0.000 0.044 |
| ME 43,81,110,108 |
| 25.18 |
| 114 B-FARNESENE 0.000 0.000 |
| 26.10 |
| 122 HUMULENE 10.326 10.525 |
| 26.16 |
| 123 METHYL DEC-4,8- 1.153 0.252 |
| DIENOATE |
| 26.46 |
| 129 WILEY# 123998 MW 204 |
| 0.433 0.396 |
| C15H24 |
| 26.59 |
| 131 2-DODECANONE 0.000 0.047 |
| 27.32 |
| 138 A-FARNESENE OR 0.177 0.169 |
| ZINGIBERENE |
| 27.53 |
| 139 CAS# 030021-74-0 0.104 0.084 |
| 27.75 |
| 143 A-MUUROLENE 0.172 0.135 |
| 27.90 |
| 144 B-SELINENE 0.378 0.433 |
| 28.04 |
| 145 A-SELINENE 0.410 0.495 |
| 28.34 |
| 147 METHYL 0.000 0.000 |
| ?-UNDECENOATE |
| 29.16 |
| 154 D-CADINENE 0.864 0.790 |
| 29.39 |
| 155 G-CADINENE 0.443 0.387 |
| 30.34 |
| 164 CAS# 016728-99-7 OR |
| 0.080 0.084 |
| G-SELINENE |
| 30.73 |
| 166 A-MUUROLINE 0.091 0.083 |
| 31.15 |
| 170 2-TRIDECANONE 0.348 0.802 |
| 31.36 |
| 171 GERANYL PROPANOATE |
| 0.257 0.493 |
| 31.46 |
| 172 MW 212 METHYL 0.000 0.000 |
| ?-DODECENOATE |
| 32.28 |
| 177 trans-GERANIOL 1.003 0.060 |
| 32.54 |
| 179 CAS# 000483-77-2 0.000 0.051 |
| (CALAMENENE ?) |
| 34.38 |
| 187 METHYL 3,6- 0.000 0.126 |
| DODECDIENOATE ME 79 |
| 36.42 |
| 196 MW 210 ME 43,54,82 |
| 0.000 0.267 |
| 39.11 |
| 211 CARYOPHYLLENE OXIDE |
| 0.082 0.084 |
| 40.23 |
| 221 HUMULENE 0.097 0.227 |
| MONO-EPOXIDE I |
| 40.28 |
| 223 MW222 ME 43,82 0.047 0.107 |
| 41.07 |
| 225 HUMULENE 0.115 0.131 |
| MONO-EPOXIDE II |
| 41.55 |
| 228 HUMULENE 0.057 0.000 |
| MONO-EPOXIDE III |
| 41.88 |
| 231 MW 222 ME 43,79,80 |
| 0.073 0.469 |
| 43.88 |
| 242 MW 220 ME 43,79,91 |
| 0.000 0.265 |
| 44.73 |
| 246 T-CADINOL 0.078 0.073 |
| 46.08 |
| 255 T-MUUROLOL 0.046 0.044 |
| ME 95,121,204 |
| 47.50 |
| 262 MW 220 ME 41,67,109 |
| 0.000 0.000 |
| DIEPOXIDE? |
| 48.69 |
| 268 FARNESOL 0.586 0.472 |
| ______________________________________ |
| GC/ TENTATIVE IDENTI- 21507 |
| FID CMPD. FICATION BY GC./ 56013 CENTE- |
| RT. # MASS SPECTROSCOPY |
| CASCADE NNIAL |
| ______________________________________ |
| 6.42 9 A-PINENE 0.098 0.155 |
| 7.46 14 ISOBUTYL ISOBUTYRATE |
| 0.110 0.127 |
| 8.10 16 8-PINENE 0.933 1.125 |
| 9.11 18 MYRCENE 68.051 77.911 |
| 9.77 22 2-METHYL-BUTYL 0.260 0.372 |
| PROPANOATE |
| 9.90 23 ISOAMYL ISOBUTYRATE |
| 0.096 0.234 |
| 9.96 24 2-METHYL-BUTYL 0.527 0.911 |
| ISOBUTARATE |
| 10.28 |
| 26 L-LIMONENE 0.233 0.324 |
| 10.62 |
| 27 B-PHELLANDRENE? 0.337 0.358 |
| C10H15 |
| 11.59 |
| 32 trans-OCIMENE 0.132 0.080 |
| 12.45 |
| 35 2-METHYL-BUTYL 0.000 0.094 |
| 2-METHYL-BUTYRATE |
| 12.68 |
| 36 METHYL HEPTANOATE |
| 0.210 0.333 |
| 12.91 |
| 40 ISOAMYL ISOVALERATE |
| 0.043 0.126 |
| 14.31 |
| 43 METHYL 4-METHYL- 0.055 0.114 |
| HEXA-2-ENOATE |
| 14.39 |
| 45 METHYL 6-METHYL- 0.091 0.168 |
| HEPTANOATE |
| 15.98 |
| 51 METHYL OCTANOATE 0.093 0.193 |
| 16.26 |
| 55 NONANAL 0.051 0.000 |
| 19.41 |
| 73 METHYL NONANOATE 0.072 0.101 |
| 19.56 |
| 75 2-DECANONE, 0.044 0.000 |
| A-YLANGENE |
| 19.93 |
| 77 A-COPAENE 0.118 0.088 |
| 21.00 |
| 83 LINALOOL 0.312 0.470 |
| 21.31 |
| 88 A-GURJUNENE 0.000 0.054 |
| 21.42 |
| 89 7-METHYL-2-DECANONE |
| 0.000 0.000 |
| 22.56 |
| 93 C15H24 CALARENE? 0.070 0.000 |
| 22.72 |
| 95 A-BERGAMOTENE, 0.275 0.050 |
| METHYL DECANOATE |
| 23.01 |
| 96 2-UNDECANONE 0.110 0.000 |
| 23.10 |
| 97 2-DECANOL 0.175 0.009 |
| 23.44 |
| 99 8-CARYOPHYLLENE 4.059 4.649 |
| 23.84 |
| 102 METHYL DEC-4-ENOATE |
| 0.333 0.809 |
| 24.03 |
| 103 MW168 2-OL? 0.000 0.000 |
| ME 43,81,110,108 |
| 25.18 |
| 114 B-FARNESENE 5.285 0.000 |
| 26.10 |
| 122 HUMULENE 10.063 5.699 |
| 26.16 |
| 123 METHYL DEC-4,8- 0.219 2.229 |
| DIENOATE |
| 26.46 |
| 129 WILEY# 123998 MW 204 |
| 0.325 0.239 |
| C15H24 |
| 26.59 |
| 131 2-DODECANONE 0.000 0.000 |
| 27.32 |
| 138 A-FARNESENE OR 0.311 0.110 |
| ZINGIBERENE |
| 27.53 |
| 139 CAS# 030021-74-0 0.087 0.000 |
| 27.75 |
| 143 A-MUUROLENE 0.107 0.170 |
| 27.90 |
| 144 B-SELINENE 0.508 0.000 |
| 28.04 |
| 145 A-SELINENE 0.533 0.050 |
| 28.34 |
| 147 METHYL 0.195 0.000 |
| ?-UNDECENOATE |
| 29.16 |
| 154 D-CADINENE 0.624 0.420 |
| 29.39 |
| 155 G-CADINENE 0.306 0.246 |
| 30.34 |
| 164 CAS# 016728-99-7 OR |
| 0.071 0.000 |
| G-SELINENE |
| 30.73 |
| 166 A-MUUROLINE 0.066 0.000 |
| 31.15 |
| 170 2-TRIDECANONE 0.836 0.565 |
| 31.36 |
| 171 GERANYL PROPANOATE |
| 0.402 0.218 |
| 31.46 |
| 172 MW 212 METHYL 0.109 0.069 |
| ?-DODECENOATE |
| 32.28 |
| 177 trans-GERANIOL 0.092 0.762 |
| 32.54 |
| 179 CAS# 000483-77-2 0.000 0.000 |
| (CALAMENENE ?) |
| 34.38 |
| 187 METHYL 3,6- 0.047 0.098 |
| DODECDIENOATE ME 79 |
| 36.42 |
| 196 MW 210 ME 43,54,82 |
| 0.148 0.000 |
| 39.11 |
| 211 CARYOPHYLLENE OXIDE |
| 0.075 0.072 |
| 40.23 |
| 221 HUMULENE 0.000 0.000 |
| MONO-EPOXIDE I |
| 40.28 |
| 223 MW222 ME 43,82 0.064 0.000 |
| 41.07 |
| 225 HUMULENE 0.157 0.114 |
| MONO-EPOXIDE II |
| 41.55 |
| 228 HUMULENE 0.000 0.000 |
| MONO-EPOXIDE III |
| 41.88 |
| 231 MW 222 ME 43,79,80 |
| 0.490 0.164 |
| 43.88 |
| 242 MW 220 ME 43,79,91 |
| 0.382 0.000 |
| 44.73 |
| 246 T-CADINOL 0.069 0.000 |
| 46.08 |
| 255 T-MUUROLOL 0.000 0.000 |
| ME 95,121,204 |
| 47.50 |
| 262 MW 220 ME 41,67,109 |
| 0.000 0.000 |
| DIEPOXIDE? |
| 48.69 |
| 268 FARNESOL 0.093 0.000 |
| ______________________________________ |
| GC/ TENTATIVE IDENTI- |
| 21043 |
| FID CMPD. FICATION BY GC./ CHALL- 21226 |
| RT. # MASS SPECTROSCOPY |
| ANGER CHINOCK |
| ______________________________________ |
| 6.42 9 A-PINENE 0.078 0.102 |
| 7.46 14 ISOBUTYL ISOBUTYRATE |
| 0.192 0.270 |
| 8.10 16 8-PINENE 0.765 0.768 |
| 9.11 18 MYRCENE 55.224 48.105 |
| 9.77 22 2-METHYL-BUTYL 0.254 0.477 |
| PROPANOATE |
| 9.90 23 ISOAMYL ISOBUTYRATE |
| 0.082 0.447 |
| 9.96 24 2-METHYL-BUTYL 1.164 2.385 |
| ISOBUTARATE |
| 10.28 |
| 26 L-LIMONENE 0.204 0.210 |
| 10.62 |
| 27 B-PHELLANDRENE? 0.260 0.228 |
| C10H15 |
| 11.59 |
| 32 trans-OCIMENE 0.259 0.067 |
| 12.45 |
| 35 2-METHYL-BUTYL 0.067 0.185 |
| 2-METHYL-BUTYRATE |
| 12.68 |
| 36 METHYL HEPTANOATE |
| 0.631 0.200 |
| 12.91 |
| 40 ISOAMYL ISOVALERATE |
| 0.000 0.398 |
| 14.31 |
| 43 METHYL 4-METHYL- 0.337 0.099 |
| HEXA-2-ENOATE |
| 14.39 |
| 45 METHYL 6-METHYL- 0.241 1.211 |
| HEPTANOATE |
| 15.98 |
| 51 METHYL OCTANOATE 0.323 0.199 |
| 16.26 |
| 55 NONANAL 0.076 0.043 |
| 19.41 |
| 73 METHYL NONANOATE 0.000 0.162 |
| 19.56 |
| 75 2-DECANONE, 0.189 0.158 |
| A-YLANGENE |
| 19.93 |
| 77 A-COPAENE 0.164 0.530 |
| 21.00 |
| 83 LINALOOL 0.714 0.400 |
| 21.31 |
| 88 A-GURJUNENE 0.000 0.696 |
| 21.42 |
| 89 7-METHYL-2-DECANONE |
| 0.076 0.079 |
| 22.56 |
| 93 C15H24 CALARENE? 0.109 0.186 |
| 22.72 |
| 95 A-BERGAMOTENE, 0.094 0.156 |
| METHYL DECANOATE |
| 23.01 |
| 96 2-UNDECANONE 0.793 0.127 |
| 23.10 |
| 97 2-DECANOL 0.227 0.453 |
| 23.44 |
| 99 8-CARYOPHYLLENE 5.394 6.439 |
| 23.84 |
| 102 METHYL DEC-4-ENOATE |
| 0.760 1.180 |
| 24.03 |
| 103 MW168 2-OL? 0.105 0.044 |
| ME 43,81,110,108 |
| 25.18 |
| 114 B-FARNESENE 1.041 0.000 |
| 26.10 |
| 122 HUMULENE 17.304 14.547 |
| 26.16 |
| 123 METHYL DEC-4,8- 0.000 0.583 |
| DIENOATE |
| 26.46 |
| 129 WILEY# 123998 MW 204 |
| 0.232 1.511 |
| C15H24 |
| 26.59 |
| 131 2-DODECANONE 0.403 0.000 |
| 27.32 |
| 138 A-FARNESENE OR 0.319 0.362 |
| ZINGIBERENE |
| 27.53 |
| 139 CAS# 030021-74-0 0.099 0.331 |
| 27.75 |
| 143 A-MUUROLENE 0.148 0.510 |
| 27.90 |
| 144 B-SELINENE 2.769 0.886 |
| 28.04 |
| 145 A-SELINENE 3.204 0.971 |
| 28.34 |
| 147 METHYL 0.241 0.000 |
| ?-UNDECENOATE |
| 29.16 |
| 154 D-CADINENE 0.810 2.685 |
| 29.39 |
| 155 G-CADINENE 0.409 1.493 |
| 30.34 |
| 164 CAS# 016728-99-7 OR |
| 0.105 1.965 |
| G-SELINENE |
| 30.73 |
| 166 A-MUUROLINE 0.000 0.288 |
| 31.15 |
| 170 2-TRIDECANONE 0.397 0.512 |
| 31.36 |
| 171 GERANYL PROPANOATE |
| 0.000 0.088 |
| 31.46 |
| 172 MW 212 METHYL 0.000 0.074 |
| ?-DODECENOATE |
| 32.28 |
| 177 trans-GERANIOL 0.000 0.979 |
| 32.54 |
| 179 CAS# 000483-77-2 0.061 0.346 |
| (CALAMENENE ?) |
| 34.38 |
| 187 METHYL 3,6- 0.000 0.446 |
| DODECDIENOATE ME 79 |
| 36.42 |
| 196 MW 210 ME 43,54,82 |
| 0.135 0.089 |
| 39.11 |
| 211 CARYOPHYLLENE OXIDE |
| 0.106 0.066 |
| 40.23 |
| 221 HUMULENE 0.048 0.131 |
| MONO-EPOXIDE I |
| 40.28 |
| 223 MW222 ME 43,82 0.232 0.122 |
| 41.07 |
| 225 HUMULENE 0.250 0.153 |
| MONO-EPOXIDE II |
| 41.55 |
| 228 HUMULENE 0.063 0.136 |
| MONO-EPOXIDE III |
| 41.88 |
| 231 MW 222 ME 43,79,80 |
| 0.356 0.268 |
| 43.88 |
| 242 MW 220 ME 43,79,91 |
| 0.163 0.000 |
| 44.73 |
| 246 T-CADINOL 0.077 0.248 |
| 46.08 |
| 255 T-MUUROLOL 0.057 0.119 |
| ME 95,121,204 |
| 47.50 |
| 262 MW 220 ME 41,67,109 |
| 0.000 0.000 |
| DIEPOXIDE? |
| 48.69 |
| 268 FARNESOL 0.076 0.524 |
| ______________________________________ |
| GC/ TENTATIVE IDENTI- |
| 65103 65103 |
| FID CMPD. FICATION BY GC./ CLUS- CLUS- |
| RT. # MASS SPECTROSCOPY |
| TER L-1 TER L-2 |
| ______________________________________ |
| 6.42 9 A-PINENE 0.103 0.153 |
| 7.46 14 ISOBUTYL ISOBUTYRATE |
| 0.280 0.153 |
| 8.10 16 8-PINENE 0.866 0.655 |
| 9.11 18 MYRCENE 60.712 45.653 |
| 9.77 22 2-METHYL-BUTYL 0.536 0.335 |
| PROPANOATE |
| 9.90 23 ISOAMYL ISOBUTYRATE |
| 0.483 0.525 |
| 9.96 24 2-METHYL-BUTYL 1.641 1.178 |
| ISOBUTARATE |
| 10.28 |
| 26 L-LIMONENE 0.268 0.235 |
| 10.62 |
| 27 B-PHELLANDRENE? 0.295 0.210 |
| C10H15 |
| 11.59 |
| 32 trans-OCIMENE 0.370 0.229 |
| 12.45 |
| 35 2-METHYL-BUTYL 0.075 0.070 |
| 2-METHYL-BUTYRATE |
| 12.68 |
| 36 METHYL HEPTANOATE |
| 0.244 0.220 |
| 12.91 |
| 40 ISOAMYL ISOVALERATE |
| 0.187 0.271 |
| 14.31 |
| 43 METHYL 4-METHYL- 0.342 0.310 |
| HEXA-2-ENOATE |
| 14.39 |
| 45 METHYL 6-METHYL- 0.447 0.399 |
| HEPTANOATE |
| 15.98 |
| 51 METHYL OCTANOATE 0.721 0.555 |
| 16.26 |
| 55 NONANAL 0.250 0.467 |
| 19.41 |
| 73 METHYL NONANOATE 0.165 0.158 |
| 19.56 |
| 75 2-DECANONE, 0.060 0.100 |
| A-YLANGENE |
| 19.93 |
| 77 A-COPAENE 0.126 0.242 |
| 21.00 |
| 83 LINALOOL 0.347 0.259 |
| 21.31 |
| 88 A-GURJUNENE 0.372 0.374 |
| 21.42 |
| 89 7-METHYL-2-DECANONE |
| 0.071 0.075 |
| 22.56 |
| 93 C15H24 CALARENE? 0.082 0.158 |
| 22.72 |
| 95 A-BERGAMOTENE, 0.953 0.855 |
| METHYL DECANOATE |
| 23.01 |
| 96 2-UNDECANONE 0.533 0.648 |
| 23.10 |
| 97 2-DECANOL 0.180 0.352 |
| 23.44 |
| 99 8-CARYOPHYLLENE 4.725 8.080 |
| 23.84 |
| 102 METHYL DEC-4-ENOATE |
| 1.801 1.927 |
| 24.03 |
| 103 MW168 2-OL? 0.073 0.108 |
| ME 43,81,110,108 |
| 25.18 |
| 114 B-FARNESENE 0.000 0.000 |
| 26.10 |
| 122 HUMULENE 13.195 20.805 |
| 26.16 |
| 123 METHYL DEC-4,8- 0.154 0.132 |
| DIENOATE |
| 26.46 |
| 129 WILEY# 123998 MW 204 |
| 0.306 0.538 |
| C15H24 |
| 26.59 |
| 131 2-DODECANONE 0.064 0.078 |
| 27.32 |
| 138 A-FARNESENE OR 0.135 0.197 |
| ZINGIBERENE |
| 27.53 |
| 139 CAS# 030021-74-0 0.084 0.137 |
| 27.75 |
| 143 A-MUUROLENE 0.127 0.216 |
| 27.90 |
| 144 B-SELINENE 0.319 0.558 |
| 28.04 |
| 145 A-SELINENE 0.356 0.612 |
| 28.34 |
| 147 METHYL 0.000 0.000 |
| ?-UNDECENOATE |
| 29.16 |
| 154 D-CADINENE 0.655 1.137 |
| 29.39 |
| 155 G-CADINENE 0.330 0.604 |
| 30.34 |
| 164 CAS# 016728-99-7 OR |
| 0.081 0.141 |
| G-SELINENE |
| 30.73 |
| 166 A-MUUROLINE 0.059 0.110 |
| 31.15 |
| 170 2-TRIDECANONE 0.843 1.060 |
| 31.36 |
| 171 GERANYL PROPANOATE |
| 0.000 0.000 |
| 31.46 |
| 172 MW 212 METHYL 0.741 0.925 |
| ?-DODECENOATE |
| 32.28 |
| 177 trans-GERANIOL 0.703 0.446 |
| 32.54 |
| 179 CAS# 000483-77-2 0.000 0.108 |
| (CALAMENENE ?) |
| 34.38 |
| 187 METHYL 3,6- 0.228 0.221 |
| DODECDIENOATE ME 79 |
| 36.42 |
| 196 MW 210 ME 43,54,82 |
| 0.062 0.082 |
| 39.11 |
| 211 CARYOPHYLLENE OXIDE |
| 0.094 0.251 |
| 40.23 |
| 221 HUMULENE 0.000 0.147 |
| MONO-EPOXIDE I |
| 40.28 |
| 223 MW222 ME 43,82 0.151 0.201 |
| 41.07 |
| 225 HUMULENE 0.237 0.653 |
| MONO-EPOXIDE II |
| 41.55 |
| 228 HUMULENE 0.000 0.137 |
| MONO-EPOXIDE III |
| 41.88 |
| 231 MW 222 ME 43,79,80 |
| 0.666 1.036 |
| 43.88 |
| 242 MW 220 ME 43,79,91 |
| 0.429 0.609 |
| 44.73 |
| 246 T-CADINOL 0.088 0.170 |
| 46.08 |
| 255 T-MUUROLOL 0.000 0.090 |
| ME 95,121,204 |
| 47.50 |
| 262 MW 220 ME 41,67,109 |
| 0.000 0.077 |
| DIEPOXIDE? |
| 48.69 |
| 268 FARNESOL 0.066 0.084 |
| ______________________________________ |
| GC/ TENTATIVE IDENTI- |
| FID CMPD. FICATION BY GC./ 21220 21016 |
| RT. # MASS SPECTROSCOPY |
| EROICA FUGGLE |
| ______________________________________ |
| 6.42 9 A-PINENE 0.155 0.075 |
| 7.46 14 ISOBUTYL ISOBUTYRATE |
| 0.000 0.221 |
| 8.10 16 8-PINENE 0.884 0.712 |
| 9.11 18 MYRCENE 61.773 54.039 |
| 9.77 22 2-METHYL-BUTYL 0.237 0.157 |
| PROPANOATE |
| 9.90 23 ISOAMYL ISOBUTYRATE |
| 0.124 0.000 |
| 9.96 24 2-METHYL-BUTYL 0.549 0.443 |
| ISOBUTARATE |
| 10.28 |
| 26 L-LIMONENE 0.233 0.186 |
| 10.62 |
| 27 B-PHELLANDRENE? 0.264 0.242 |
| C10H15 |
| 11.59 |
| 32 trans-OCIMENE 1.577 0.105 |
| 12.45 |
| 35 2-METHYL-BUTYL 0.000 0.000 |
| 2-METHYL-BUTYRATE |
| 12.68 |
| 36 METHYL HEPTANOATE |
| 0.292 0.426 |
| 12.91 |
| 40 ISOAMYL ISOVALERATE |
| 0.000 0.000 |
| 14.31 |
| 43 METHYL 4-METHYL- 0.000 0.170 |
| HEXA-2-ENOATE |
| 14.39 |
| 45 METHYL 6-METHYL- 0.271 0.114 |
| HEPTANOATE |
| 15.98 |
| 51 METHYL OCTANOATE 0.257 0.088 |
| 16.26 |
| 55 NONANAL 0.070 0.098 |
| 19.41 |
| 73 METHYL NONANOATE 0.204 0.097 |
| 19.56 |
| 75 2-DECANONE, 0.161 0.212 |
| A-YLANGENE |
| 19.93 |
| 77 A-COPAENE 0.053 0.225 |
| 21.00 |
| 83 LINALOOL 0.508 0.651 |
| 21.31 |
| 88 A-GURJUNENE 0.155 0.000 |
| 21.42 |
| 89 7-METHYL-2-DECANONE |
| 0.214 0.083 |
| 22.56 |
| 93 C15H24 CALARENE? 0.000 0.157 |
| 22.72 |
| 95 A-BERGAMOTENE, 0.325 0.272 |
| METHYL DECANOATE |
| 23.01 |
| 96 2-UNDECANONE 0.820 0.406 |
| 23.10 |
| 97 2-DECANOL 0.000 0.348 |
| 23.44 |
| 99 8-CARYOPHYLLENE 12.756 7.628 |
| 23.84 |
| 102 METHYL DEC-4-ENOATE |
| 0.875 0.409 |
| 24.03 |
| 103 MW168 2-OL? 0.167 0.122 |
| ME 43,81,110,108 |
| 25.18 |
| 114 B-FARNESENE 0.000 4.870 |
| 26.10 |
| 122 HUMULENE 0.355 20.059 |
| 26.16 |
| 123 METHYL DEC-4,8- 0.419 0.147 |
| DIENOATE |
| 26.46 |
| 129 WILEY# 123998 MW 204 |
| 0.104 0.528 |
| C15H24 |
| 26.59 |
| 131 2-DODECANONE 0.344 0.073 |
| 27.32 |
| 138 A-FARNESENE OR 0.000 0.543 |
| ZINGIBERENE |
| 27.53 |
| 139 CAS# 030021-74-0 0.000 0.090 |
| 27.75 |
| 143 A-MUUROLENE 0.060 0.173 |
| 27.90 |
| 144 B-SELINENE 2.268 0.177 |
| 28.04 |
| 145 A-SELINENE 2.562 0.186 |
| 28.34 |
| 147 METHYL 0.000 0.424 |
| ?-UNDECENOATE |
| 29.16 |
| 154 D-CADINENE 0.293 1.092 |
| 29.39 |
| 155 G-CADINENE 0.167 0.573 |
| 30.34 |
| 164 CAS# 016728-99-7 OR |
| 0.000 0.147 |
| G-SELINENE |
| 30.73 |
| 166 A-MUUROLINE 0.000 0.117 |
| 31.15 |
| 170 2-TRIDECANONE 0.606 0.397 |
| 31.36 |
| 171 GERANYL PROPANOATE |
| 0.091 0.000 |
| 31.46 |
| 172 MW 212 METHYL 0.000 0.000 |
| ?-DODECENOATE |
| 32.28 |
| 177 trans-GERANIOL 0.949 0.000 |
| 32.54 |
| 179 CAS# 000483-77-2 0.077 0.080 |
| (CALAMENENE ?) |
| 34.38 |
| 187 METHYL 3,6- 0.228 0.064 |
| DODECDIENOATE ME 79 |
| 36.42 |
| 196 MW 210 ME 43,54,82 |
| 0.437 0.080 |
| 39.11 |
| 211 CARYOPHYLLENE OXIDE |
| 0.156 0.126 |
| 40.23 |
| 221 HUMULENE 0.164 0.000 |
| MONO-EPOXIDE I |
| 40.28 |
| 223 MW222 ME 43,82 0.878 0.087 |
| 41.07 |
| 225 HUMULENE 0.000 0.279 |
| MONO-EPOXIDE II |
| 41.55 |
| 228 HUMULENE 0.000 0.088 |
| MONO-EPOXIDE III |
| 41.88 |
| 231 MW 222 ME 43,79,80 |
| 1.761 0.435 |
| 43.88 |
| 242 MW 220 ME 43,79,91 |
| 0.461 0.235 |
| 44.73 |
| 246 T-CADINOL 0.055 0.125 |
| 46.08 |
| 255 T-MUUROLOL 0.000 0.070 |
| ME 95,121,204 |
| 47.50 |
| 262 MW 220 ME 41,67,109 |
| 0.000 0.000 |
| DIEPOXIDE? |
| 48.69 |
| 268 FARNESOL 0.326 0.134 |
| ______________________________________ |
| GC/ TENTATIVE IDENTI- 21014 |
| FID CMPD. FICATION BY GC./ 21102 HALL- |
| RT. # MASS SPECTROSCOPY |
| GALENA ERTAU |
| ______________________________________ |
| 6.42 9 A-PINENE 0.109 0.064 |
| 7.46 14 ISOBUTYL ISOBUTYRATE |
| 0.479 0.151 |
| 8.10 16 8-PINENE 0.027 0.653 |
| 9.11 18 MYRCENE 55.179 53.508 |
| 9.77 22 2-METHYL-BUTYL 1.009 0.184 |
| PROPANOATE |
| 9.90 23 ISOAMYL ISOBUTYRATE |
| 0.554 0.000 |
| 9.96 24 2-METHYL-BUTYL 5.004 0.278 |
| ISOBUTARATE |
| 10.28 |
| 26 L-LIMONENE 0.218 0.158 |
| 10.62 |
| 27 B-PHELLANDRENE? 0.239 0.204 |
| C10H15 |
| 11.59 |
| 32 trans-OCIMENE 2.260 0.144 |
| 12.45 |
| 35 2-METHYL-BUTYL 0.151 0.000 |
| 2-METHYL-BUTYRATE |
| 12.68 |
| 36 METHYL HEPTANOATE |
| 0.427 0.647 |
| 12.91 |
| 40 ISOAMYL ISOVALERATE |
| 0.169 0.000 |
| 14.31 |
| 43 METHYL 4-METHYL- 0.152 0.264 |
| HEXA-2-ENOATE |
| 14.39 |
| 45 METHYL 6-METHYL- 0.930 0.150 |
| HEPTANOATE |
| 15.98 |
| 51 METHYL OCTANOATE 0.878 0.203 |
| 16.26 |
| 55 NONANAL 0.079 0.095 |
| 19.41 |
| 73 METHYL NONANOATE 0.436 0.138 |
| 19.56 |
| 75 2-DECANONE, 0.071 0.258 |
| A-YLANGENE |
| 19.93 |
| 77 A-COPAENE 0.111 0.214 |
| 21.00 |
| 83 LINALOOL 0.206 0.939 |
| 21.31 |
| 88 A-GURJUNENE 0.577 0.044 |
| 21.42 |
| 89 7-METHYL-2-DECANONE |
| 0.009 0.086 |
| 22.56 |
| 93 C15H24 CALARENE? 0.053 0.120 |
| 22.72 |
| 95 A-BERGAMOTENE, 1.317 0.000 |
| METHYL DECANOATE |
| 23.01 |
| 96 2-UNDECANONE 0.386 0.696 |
| 23.10 |
| 97 2-DECANOL 0.131 0.337 |
| 23.44 |
| 99 8-CARYOPHYLLENE 4.602 7.238 |
| 23.84 |
| 102 METHYL DEC-4-ENOATE |
| 2.237 0.660 |
| 24.03 |
| 103 MW168 2-OL? 0.042 0.157 |
| ME 43,81,110,108 |
| 25.18 |
| 114 B-FARNESENE 0.000 0.000 |
| 26.10 |
| 122 HUMULENE 10.599 24.799 |
| 26.16 |
| 123 METHYL DEC-4,8- 0.180 0.000 |
| DIENOATE |
| 26.46 |
| 129 WILEY# 123998 MW 204 |
| 0.281 0.670 |
| C15H24 |
| 26.59 |
| 131 2-DODECANONE 0.076 0.132 |
| 27.32 |
| 138 A-FARNESENE OR 0.000 0.227 |
| ZINGIBERENE |
| 27.53 |
| 139 CAS# 030021-74-0 0.054 0.113 |
| 27.75 |
| 143 A-MUUROLENE 0.101 0.214 |
| 27.90 |
| 144 B-SELINENE 0.465 0.190 |
| 28.04 |
| 145 A-SELINENE 0.544 0.207 |
| 28.34 |
| 147 METHYL 0.000 0.069 |
| ?-UNDECENOATE |
| 29.16 |
| 154 D-CADINENE 0.586 1.250 |
| 29.39 |
| 155 G-CADINENE 0.300 0.653 |
| 30.34 |
| 164 CAS# 016728-99-7 OR |
| 0.142 0.151 |
| G-SELINENE |
| 30.73 |
| 166 A-MUUROLINE 0.064 0.136 |
| 31.15 |
| 170 2-TRIDECANONE 1.561 0.421 |
| 31.36 |
| 171 GERANYL PROPANOATE |
| 0.119 0.000 |
| 31.46 |
| 172 MW 212 METHYL 0.219 0.000 |
| ?-DODECENOATE |
| 32.28 |
| 177 trans-GERANIOL 0.000 0.000 |
| 32.54 |
| 179 CAS# 000483-77-2 0.000 0.102 |
| (CALAMENENE ?) |
| 34.38 |
| 187 METHYL 3,6- 1.725 0.071 |
| DODECDIENOATE ME 79 |
| 36.42 |
| 196 MW 210 ME 43,54,82 |
| 0.186 0.125 |
| 39.11 |
| 211 CARYOPHYLLENE OXIDE |
| 0.064 0.111 |
| 40.23 |
| 221 HUMULENE 0.000 0.099 |
| MONO-EPOXIDE I |
| 40.28 |
| 223 MW222 ME 43,82 0.237 0.239 |
| 41.07 |
| 225 HUMULENE 0.134 0.357 |
| MONO-EPOXIDE II |
| 41.55 |
| 228 HUMULENE 0.000 0.100 |
| MONO-EPOXIDE III |
| 41.88 |
| 231 MW 222 ME 43,79,80 |
| 0.579 0.638 |
| 43.88 |
| 242 MW 220 ME 43,79,91 |
| 0.263 0.263 |
| 44.73 |
| 246 T-CADINOL 0.059 0.125 |
| 46.08 |
| 255 T-MUUROLOL 0.000 0.075 |
| ME 95,121,204 |
| 47.50 |
| 262 MW 220 ME 41,67,109 |
| 0.000 0.000 |
| DIEPOXIDE? |
| 48.69 |
| 268 FARNESOL 0.000 0.064 |
| ______________________________________ |
| GC/ TENTATIVE IDENTI- |
| 21135 21097 |
| FID CMPD. FICATION BY GC./ HERS- HULLERER |
| RT. # MASS SPECTROSCOPY |
| BRUCK BITTERER |
| ______________________________________ |
| 6.42 9 A-PINENE 0.000 0.087 |
| 7.46 14 ISOBUTYL ISOBUTYRATE |
| 0.000 0.088 |
| 8.10 16 8-PINENE 0.527 0.737 |
| 9.11 18 MYRCENE 44.828 52.818 |
| 9.77 22 2-METHYL-BUTYL 0.000 0.415 |
| PROPANOATE |
| 9.90 23 ISOAMYL ISOBUTYRATE |
| 0.000 0.168 |
| 9.96 24 2-METHYL-BUTYL 0.066 0.844 |
| ISOBUTARATE |
| 10.28 |
| 26 L-LIMONENE 0.147 0.207 |
| 10.62 |
| 27 B-PHELLANDRENE? 0.145 0.212 |
| C10H15 |
| 11.59 |
| 32 trans-OCIMENE 0.000 0.092 |
| 12.45 |
| 35 2-METHYL-BUTYL 0.000 0.079 |
| 2-METHYL-BUTYRATE |
| 12.68 |
| 36 METHYL HEPTANOATE |
| 0.418 0.231 |
| 12.91 |
| 40 ISOAMYL ISOVALERATE |
| 0.000 0.075 |
| 14.31 |
| 43 METHYL 4-METHYL- 0.289 0.000 |
| HEXA-2-ENOATE |
| 14.39 |
| 45 METHYL 6-METHYL- 0.171 0.408 |
| HEPTANOATE |
| 15.98 |
| 51 METHYL OCTANOATE 0.134 0.110 |
| 16.26 |
| 55 NONANAL 0.226 0.084 |
| 19.41 |
| 73 METHYL NONANOATE 0.090 0.088 |
| 19.56 |
| 75 2-DECANONE, 0.334 0.251 |
| A-YLANGENE |
| 19.93 |
| 77 A-COPAENE 0.259 0.617 |
| 21.00 |
| 83 LINALOOL 0.805 0.503 |
| 21.31 |
| 88 A-GURJUNENE 0.077 0.169 |
| 21.42 |
| 89 7-METHYL-2-DECANONE |
| 0.214 0.121 |
| 22.56 |
| 93 C15H24 CALARENE? 0.190 0.300 |
| 22.72 |
| 95 A-BERGAMOTENE, 0.000 0.000 |
| METHYL DECANOATE |
| 23.01 |
| 96 2-UNDECANONE 0.921 0.387 |
| 23.10 |
| 97 2-DECANOL 0.531 0.602 |
| 23.44 |
| 99 8-CARYOPHYLLENE 5.573 4.386 |
| 23.84 |
| 102 METHYL DEC-4-ENOATE |
| 0.551 0.772 |
| 24.03 |
| 103 MW168 2-OL? 0.210 0.122 |
| ME 43,81,110,108 |
| 25.18 |
| 114 B-FARNESENE 0.324 0.093 |
| 26.10 |
| 122 HUMULENE 29.352 8.090 |
| 26.16 |
| 123 METHYL DEC-4,8- 0.132 0.352 |
| DIENOATE |
| 26.46 |
| 129 WILEY# 123998 MW 204 |
| 0.735 1.994 |
| C15H24 |
| 26.59 |
| 131 2-DODECANONE 0.203 0.000 |
| 27.32 |
| 138 A-FARNESENE OR 0.326 0.273 |
| ZINGIBERENE |
| 27.53 |
| 139 CAS# 030021-74-0 0.103 0.352 |
| 27.75 |
| 143 A-MUUROLENE 0.248 0.574 |
| 27.90 |
| 144 B-SELINENE 0.306 2.221 |
| 28.04 |
| 145 A-SELINENE 0.335 2.426 |
| 28.34 |
| 147 METHYL 0.191 0.399 |
| ?-UNDECENOATE |
| 29.16 |
| 154 D-CADINENE 1.330 2.714 |
| 29.39 |
| 155 G-CADINENE 0.746 1.516 |
| 30.34 |
| 164 CAS# 016728-99-7 OR |
| 0.141 3.993 |
| G-SELINENE |
| 30.73 |
| 166 A-MUUROLINE 0.146 0.364 |
| 31.15 |
| 170 2-TRIDECANONE 0.580 0.241 |
| 31.36 |
| 171 GERANYL PROPANOATE |
| 0.000 0.000 |
| 31.46 |
| 172 MW 212 METHYL 0.000 0.000 |
| ?-DODECENOATE |
| 32.28 |
| 177 trans-GERANIOL 0.000 0.134 |
| 32.54 |
| 179 CAS# 000483-77-2 0.229 0.205 |
| (CALAMENENE ?) |
| 34.38 |
| 187 METHYL 3,6- 0.000 0.340 |
| DODECDIENOATE ME 79 |
| 36.42 |
| 196 MW 210 ME 43,54,82 |
| 0.147 0.179 |
| 39.11 |
| 211 CARYOPHYLLENE OXIDE |
| 0.331 0.082 |
| 40.23 |
| 221 HUMULENE 0.145 0.137 |
| MONO-EPOXIDE I |
| 40.28 |
| 223 MW222 ME 43,82 0.260 0.000 |
| 41.07 |
| 225 HUMULENE 0.962 0.194 |
| MONO-EPOXIDE II |
| 41.55 |
| 228 HUMULENE 0.159 0.074 |
| MONO-EPOXIDE III |
| 41.88 |
| 231 MW 222 ME 43,79,80 |
| 0.752 0.531 |
| 43.88 |
| 242 MW 220 ME 43,79,91 |
| 0.489 0.195 |
| 44.73 |
| 246 T-CADINOL 0.177 0.336 |
| 46.08 |
| 255 T-MUUROLOL 0.114 0.132 |
| ME 95,121,204 |
| 47.50 |
| 262 MW 220 ME 41,67,109 |
| 0.000 0.000 |
| DIEPOXIDE? |
| 48.69 |
| 268 FARNESOL 0.161 0.166 |
| ______________________________________ |
| GC/ TENTATIVE IDENTI- 21113 |
| FID CMPD. FICATION BY GC./ 21457 LUB- |
| RT. # MASS SPECTROSCOPY |
| LIBERTY ELSKA |
| ______________________________________ |
| 6.42 9 A-PINENE 0.043 0.047 |
| 7.46 14 ISOBUTYL ISOBUTYRATE |
| 0.068 0.000 |
| 8.10 16 8-PINENE 0.504 0.421 |
| 9.11 18 MYRCENE 41.506 29.558 |
| 9.77 22 2-METHYL-BUTYL 0.117 0.000 |
| PROPANOATE |
| 9.90 23 ISOAMYL ISOBUTYRATE |
| 0.000 0.000 |
| 9.96 24 2-METHYL-BUTYL 0.197 0.176 |
| ISOBUTARATE |
| 10.28 |
| 26 L-LIMONENE 0.124 0.145 |
| 10.62 |
| 27 B-PHELLANDRENE? 0.149 0.099 |
| C10H15 |
| 11.59 |
| 32 trans-OCIMENE 0.066 0.000 |
| 12.45 |
| 35 2-METHYL-BUTYL 0.000 0.000 |
| 2-METHYL-BUTYRATE |
| 12.68 |
| 36 METHYL HEPTANOATE |
| 0.293 0.259 |
| 12.91 |
| 40 ISOAMYL ISOVALERATE |
| 0.000 0.000 |
| 14.31 |
| 43 METHYL 4-METHYL- 0.128 0.081 |
| HEXA-2-ENOATE |
| 14.39 |
| 45 METHYL 6-METHYL- 0.083 0.148 |
| HEPTANOATE |
| 15.98 |
| 51 METHYL OCTANOATE 0.189 0.100 |
| 16.26 |
| 55 NONANAL 0.091 0.193 |
| 19.41 |
| 73 METHYL NONANOATE 0.092 0.183 |
| 19.56 |
| 75 2-DECANONE, 0.240 0.268 |
| A-YLANGENE |
| 19.93 |
| 77 A-COPAENE 0.304 0.268 |
| 21.00 |
| 83 LINALOOL 0.814 0.254 |
| 21.31 |
| 88 A-GURJUNENE 0.043 0.106 |
| 21.42 |
| 89 7-METHYL-2-DECANONE |
| 0.098 0.198 |
| 22.56 |
| 93 C15H24 CALARENE? 0.172 0.179 |
| 22.72 |
| 95 A-BERGAMOTENE, 0.000 0.947 |
| METHYL DECANOATE |
| 23.01 |
| 96 2-UNDECANONE 0.737 0.690 |
| 23.10 |
| 97 2-DECANOL 0.442 0.443 |
| 23.44 |
| 99 8-CARYOPHYLLENE 9.651 6.953 |
| 23.84 |
| 102 METHYL DEC-4-ENOATE |
| 0.663 1.089 |
| 24.03 |
| 103 MW168 2-OL? 0.140 0.207 |
| ME 43,81,110,108 |
| 25.18 |
| 114 B-FARNESENE 0.080 17.712 |
| 26.10 |
| 122 HUMULENE 32.402 21.404 |
| 26.16 |
| 123 METHYL DEC-4,8- 0.075 0.451 |
| DIENOATE |
| 26.46 |
| 129 WILEY# 123998 MW 204 |
| 0.387 0.796 |
| C15H24 |
| 26.59 |
| 131 2-DODECANONE 0.105 0.167 |
| 27.32 |
| 138 A-FARNESENE OR 0.509 0.316 |
| ZINGIBERENE |
| 27.53 |
| 139 CAS# 030021-74-0 0.181 0.157 |
| 27.75 |
| 143 A-MUUROLENE 0.289 0.282 |
| 27.90 |
| 144 B-SELINENE 0.325 1.492 |
| 28.04 |
| 145 A-SELINENE 0.358 1.546 |
| 28.34 |
| 147 METHYL 0.310 0.242 |
| ?-UNDECENOATE |
| 29.16 |
| 154 D-CADINENE 1.508 1.438 |
| 29.39 |
| 155 G-CADINENE 0.887 0.811 |
| 30.34 |
| 164 CAS# 016728-99-7 OR |
| 0.213 0.237 |
| G-SELINENE |
| 30.73 |
| 166 A-MUUROLINE 0.103 0.159 |
| 31.15 |
| 170 2-TRIDECANONE 0.458 0.738 |
| 31.36 |
| 171 GERANYL PROPANOATE |
| 0.000 0.000 |
| 31.46 |
| 172 MW 212 METHYL 0.000 0.070 |
| ?-DODECENOATE |
| 32.28 |
| 177 trans-GERANIOL 0.099 0.257 |
| 32.54 |
| 179 CAS# 000483-77-2 0.193 0.196 |
| (CALAMENENE ?) |
| 34.38 |
| 187 METHYL 3,6- 0.057 0.203 |
| DODECDIENOATE ME 79 |
| 36.42 |
| 196 MW 210 ME 43,54,82 |
| 0.115 0.199 |
| 39.11 |
| 211 CARYOPHYLLENE OXIDE |
| 0.205 0.550 |
| 40.23 |
| 221 HUMULENE 0.103 0.298 |
| MONO-EPOXIDE I |
| 40.28 |
| 223 MW222 ME 43,82 0.308 0.261 |
| 41.07 |
| 225 HUMULENE 0.599 1.612 |
| MONO-EPOXIDE II |
| 41.55 |
| 228 HUMULENE 0.144 0.000 |
| MONO-EPOXIDE III |
| 41.88 |
| 231 MW 222 ME 43,79,80 |
| 0.568 1.358 |
| 43.88 |
| 242 MW 220 ME 43,79,91 |
| 0.342 0.439 |
| 44.73 |
| 246 T-CADINOL 0.179 0.247 |
| 46.08 |
| 255 T-MUUROLOL 0.128 0.131 |
| ME 95,121,204 |
| 47.50 |
| 262 MW 220 ME 41,67,109 |
| 0.000 0.094 |
| DIEPOXIDE? |
| 48.69 |
| 268 FARNESOL 0.340 0.339 |
| ______________________________________ |
| 21073 |
| GC/ TENTATIVE IDENTI- |
| 21114 NORTH- |
| FID CMPD. FICATION BY GC./ NADWIS- ERN |
| RT. # MASS SPECTROSCOPY |
| LANSKA BREWER |
| ______________________________________ |
| 6.42 9 A-PINENE 0.066 0.125 |
| 7.46 14 ISOBUTYL ISOBUTYRATE |
| 0.000 0.174 |
| 8.10 16 8-PINENE 0.649 0.862 |
| 9.11 18 MYRCENE 44.179 55.587 |
| 9.77 22 2-METHYL-BUTYL 0.000 0.183 |
| PROPANOATE |
| 9.90 23 ISOAMYL ISOBUTYRATE |
| 0.000 0.108 |
| 9.96 24 2-METHYL-BUTYL 0.000 0.428 |
| ISOBUTARATE |
| 10.28 |
| 26 L-LIMONENE 0.169 0.248 |
| 10.62 |
| 27 B-PHELLANDRENE? 0.149 0.265 |
| C10H15 |
| 11.59 |
| 32 trans-OCIMENE 0.000 0.488 |
| 12.45 |
| 35 2-METHYL-BUTYL 0.000 0.000 |
| 2-METHYL-BUTYRATE |
| 12.68 |
| 36 METHYL HEPTANOATE |
| 0.391 0.706 |
| 12.91 |
| 40 ISOAMYL ISOVALERATE |
| 0.000 0.000 |
| 14.31 |
| 43 METHYL 4-METHYL- 0.206 0.251 |
| HEXA-2-ENOATE |
| 14.39 |
| 45 METHYL 6-METHYL- 0.178 0.150 |
| HEPTANOATE |
| 15.98 |
| 51 METHYL OCTANOATE 0.113 0.199 |
| 16.26 |
| 55 NONANAL 0.141 0.077 |
| 19.41 |
| 73 METHYL NONANOATE 0.155 0.166 |
| 19.56 |
| 75 2-DECANONE, 0.260 0.177 |
| A-YLANGENE |
| 19.93 |
| 77 A-COPAENE 0.160 0.284 |
| 21.00 |
| 83 LINALOOL 0.390 0.344 |
| 21.31 |
| 88 A-GURJUNENE 0.073 0.000 |
| 21.42 |
| 89 7-METHYL-2-DECANONE |
| 0.116 0.049 |
| 22.56 |
| 93 C15H24 CALARENE? 0.113 0.154 |
| 22.72 |
| 95 A-BERGAMOTENE, 0.854 0.000 |
| METHYL DECANOATE |
| 23.01 |
| 96 2-UNDECANONE 0.592 0.292 |
| 23.10 |
| 97 2-DECANOL 0.284 0.307 |
| 23.44 |
| 99 8-CARYOPHYLLENE 5.415 9.217 |
| 23.84 |
| 102 METHYL DEC-4-ENOATE |
| 0.939 0.565 |
| 24.03 |
| 103 MW168 2-OL? 0.211 0.077 |
| ME 43,81,110,108 |
| 25.18 |
| 114 B-FARNESENE 17.417 0.000 |
| 26.10 |
| 122 HUMULENE 18.740 21.642 |
| 26.16 |
| 123 METHYL DEC-4,8- 0.368 0.389 |
| DIENOATE |
| 26.46 |
| 129 WILEY# 123998 MW 204 |
| 0.461 0.619 |
| C15H24 |
| 26.59 |
| 131 2-DODECANONE 0.127 0.084 |
| 27.32 |
| 138 A-FARNESENE OR 0.264 0.179 |
| ZINGIBERENE |
| 27.53 |
| 139 CAS# 030021-74-0 0.053 0.112 |
| 27.75 |
| 143 A-MUUROLENE 0.143 0.217 |
| 27.90 |
| 144 B-SELINENE 0.217 0.182 |
| 28.04 |
| 145 A-SELINENE 0.161 0.210 |
| 28.34 |
| 147 METHYL 0.206 0.000 |
| ?-UNDECENOATE |
| 29.16 |
| 154 D-CADINENE 0.766 1.301 |
| 29.39 |
| 155 G-CADINENE 0.431 0.650 |
| 30.34 |
| 164 CAS# 016728-99-7 OR |
| 0.121 0.129 |
| G-SELINENE |
| 30.73 |
| 166 A-MUUROLINE 0.085 0.124 |
| 31.15 |
| 170 2-TRIDECANONE 0.417 0.337 |
| 31.36 |
| 171 GERANYL PROPANOATE |
| 0.000 0.000 |
| 31.46 |
| 172 MW 212 METHYL 0.000 0.000 |
| ?-DODECENOATE |
| 32.28 |
| 177 trans-GERANIOL 0.200 0.000 |
| 32.54 |
| 179 CAS# 000483-77-2 0.131 0.110 |
| (CALAMENENE ?) |
| 34.38 |
| 187 METHYL 3,6- 0.146 0.068 |
| DODECDIENOATE ME 79 |
| 36.42 |
| 196 MW 210 ME 43,54,82 |
| 0.127 0.082 |
| 39.11 |
| 211 CARYOPHYLLENE OXIDE |
| 0.284 0.122 |
| 40.23 |
| 221 HUMULENE 0.156 0.065 |
| MONO-EPOXIDE I |
| 40.28 |
| 223 MW222 ME 43,82 0.127 0.109 |
| 41.07 |
| 225 HUMULENE 0.855 0.250 |
| MONO-EPOXIDE II |
| 41.55 |
| 228 HUMULENE 0.112 0.090 |
| MONO-EPOXIDE III |
| 41.88 |
| 231 MW 222 ME 43,79,80 |
| 0.755 0.295 |
| 43.88 |
| 242 MW 220 ME 43,79,91 |
| 0.210 0.169 |
| 44.73 |
| 246 T-CADINOL 0.113 0.119 |
| 46.08 |
| 255 T-MUUROLOL 0.045 0.057 |
| ME 95,121,204 |
| 47.50 |
| 262 MW 220 ME 41,67,109 |
| 0.000 0.000 |
| DIEPOXIDE? |
| 48.69 |
| 268 FARNESOL 0.187 0.230 |
| ______________________________________ |
| GC/ TENTATIVE IDENTI- |
| 21044 |
| FID CMPD. FICATION BY GC./ NORTH- 21197 |
| RT. # MASS SPECTROSCOPY |
| DOWN NUGGET |
| ______________________________________ |
| 6.42 9 A-PINENE 0.066 0.095 |
| 7.46 14 ISOBUTYL ISOBUTYRATE |
| 0.000 0.244 |
| 8.10 16 8-PINENE 0.639 0.671 |
| 9.11 18 MYRCENE 42.280 60.676 |
| 9.77 22 2-METHYL-BUTYL 0.106 0.559 |
| PROPANOATE |
| 9.90 23 ISOAMYL ISOBUTYRATE |
| 0.000 0.550 |
| 9.96 24 2-METHYL-BUTYL 0.173 1.307 |
| ISOBUTARATE |
| 10.28 |
| 26 L-LIMONENE 0.173 0.203 |
| 10.62 |
| 27 B-PHELLANDRENE? 0.199 0.244 |
| C10H15 |
| 11.59 |
| 32 trans-OCIMENE 0.104 0.571 |
| 12.45 |
| 35 2-METHYL-BUTYL 0.000 0.063 |
| 2-METHYL-BUTYRATE |
| 12.68 |
| 36 METHYL HEPTANOATE |
| 0.337 0.615 |
| 12.91 |
| 40 ISOAMYL ISOVALERATE |
| 0.000 0.124 |
| 14.31 |
| 43 METHYL 4-METHYL- 0.127 0.201 |
| HEXA-2-ENOATE |
| 14.39 |
| 45 METHYL 6-METHYL- 0.098 0.257 |
| HEPTANOATE |
| 15.98 |
| 51 METHYL OCTANOATE 0.165 0.470 |
| 16.26 |
| 55 NONANAL 0.000 0.052 |
| 19.41 |
| 73 METHYL NONANOATE 0.122 0.326 |
| 19.56 |
| 75 2-DECANONE, 0.000 0.052 |
| A-YLANGENE |
| 19.93 |
| 77 A-COPAENE 0.321 0.167 |
| 21.00 |
| 83 LINALOOL 0.559 0.904 |
| 21.31 |
| 88 A-GURJUNENE 0.000 0.113 |
| 21.42 |
| 89 7-METHYL-2-DECANONE |
| 0.000 0.000 |
| 22.56 |
| 93 C15H24 CALARENE? 0.228 0.069 |
| 22.72 |
| 95 A-BERGAMOTENE, 0.000 0.298 |
| METHYL DECANOATE |
| 23.01 |
| 96 2-UNDECANONE 0.181 0.363 |
| 23.10 |
| 97 2-DECANOL 0.474 0.230 |
| 23.44 |
| 99 8-CARYOPHYLLENE 12.260 6.289 |
| 23.84 |
| 102 METHYL DEC-4-ENOATE |
| 0.798 1.366 |
| 24.03 |
| 103 MW168 2-OL? 0.000 0.054 |
| ME 43,81,110,108 |
| 25.18 |
| 114 B-FARNESENE 0.746 0.000 |
| 26.10 |
| 122 HUMULENE 31.313 15.386 |
| 26.16 |
| 123 METHYL DEC-4,8- 0.000 0.128 |
| DIENOATE |
| 26.46 |
| 129 WILEY# 123998 MW 204 |
| 0.198 0.359 |
| C15H24 |
| 26.59 |
| 131 2-DODECANONE 0.800 0.077 |
| 27.32 |
| 138 A-FARNESENE OR 0.210 0.321 |
| ZINGIBERENE |
| 27.53 |
| 139 CAS# 030021-74-0 0.153 0.086 |
| 27.75 |
| 143 A-MUUROLENE 0.300 0.237 |
| 27.90 |
| 144 B-SELINENE 0.291 0.560 |
| 28.04 |
| 145 A-SELINENE 0.324 0.647 |
| 28.34 |
| 147 METHYL 0.000 0.164 |
| ?-UNDECENOATE |
| 29.16 |
| 154 D-CADINENE 1.517 0.760 |
| 29.39 |
| 155 G-CADINENE 0.815 0.399 |
| 30.34 |
| 164 CAS# 016728-99-7 OR |
| 0.146 0.102 |
| G-SELINENE |
| 30.73 |
| 166 A-MUUROLINE 0.163 0.075 |
| 31.15 |
| 170 2-TRIDECANONE 0.149 0.500 |
| 31.36 |
| 171 GERANYL PROPANOATE |
| 0.000 0.000 |
| 31.46 |
| 172 MW 212 METHYL 0.000 0.077 |
| ?-DODECENOATE |
| 32.28 |
| 177 trans-GERANIOL 0.000 0.000 |
| 32.54 |
| 179 CAS# 000483-77-2 0.199 0.000 |
| (CALAMENENE ?) |
| 34.38 |
| 187 METHYL 3,6- 0.000 0.119 |
| DODECDIENOATE ME 79 |
| 36.42 |
| 196 MW 210 ME 43,54,82 |
| 0.000 0.112 |
| 39.11 |
| 211 CARYOPHYLLENE OXIDE |
| 0.410 0.051 |
| 40.23 |
| 221 HUMULENE 0.089 0.000 |
| MONO-EPOXIDE I |
| 40.28 |
| 223 MW222 ME 43,82 0.067 0.328 |
| 41.07 |
| 225 HUMULENE 0.801 0.113 |
| MONO-EPOXIDE II |
| 41.55 |
| 228 HUMULENE 0.153 0.000 |
| MONO-EPOXIDE III |
| 41.88 |
| 231 MW 222 ME 43,79,80 |
| 0.168 0.643 |
| 43.88 |
| 242 MW 220 ME 43,79,91 |
| 0.101 0.206 |
| 44.73 |
| 246 T-CADINOL 0.138 0.062 |
| 46.08 |
| 255 T-MUUROLOL 0.086 0.000 |
| ME 95,121,204 |
| 47.50 |
| 262 MW 220 ME 41,67,109 |
| 0.000 0.000 |
| DIEPOXIDE? |
| 48.69 |
| 268 FARNESOL 0.154 0.071 |
| ______________________________________ |
| GC/ TENTATIVE IDENTI- |
| FID CMPD. FICATION BY GC./ 21223 21227 |
| RT. # MASS SPECTROSCOPY |
| OLYMPIC PERLE |
| ______________________________________ |
| 6.42 9 A-PINENE 0.127 0.077 |
| 7.46 14 ISOBUTYL ISOBUTYRATE |
| 0.116 0.193 |
| 8.10 16 8-PINENE 1.037 0.618 |
| 9.11 18 MYRCENE 61.466 41.489 |
| 9.77 22 2-METHYL-BUTYL 0.470 0.120 |
| PROPANOATE |
| 9.90 23 ISOAMYL ISOBUTYRATE |
| 0.121 0.000 |
| 9.96 24 2-METHYL-BUTYL 1.424 0.308 |
| ISOBUTARATE |
| 10.28 |
| 26 L-LIMONENE 0.247 0.177 |
| 10.62 |
| 27 B-PHELLANDRENE? 0.269 0.199 |
| C10H15 |
| 11.59 |
| 32 trans-OCIMENE 0.040 0.591 |
| 12.45 |
| 35 2-METHYL-BUTYL 0.549 0.000 |
| 2-METHYL-BUTYRATE |
| 12.68 |
| 36 METHYL HEPTANOATE |
| 0.136 0.425 |
| 12.91 |
| 40 ISOAMYL ISOVALERATE |
| 0.476 0.000 |
| 14.31 |
| 43 METHYL 4-METHYL- 0.051 0.111 |
| HEXA-2-ENOATE |
| 14.39 |
| 45 METHYL 6-METHYL- 0.216 0.061 |
| HEPTANOATE |
| 15.98 |
| 51 METHYL OCTANOATE 0.066 0.053 |
| 16.26 |
| 55 NONANAL 0.053 0.096 |
| 19.41 |
| 73 METHYL NONANOATE 0.040 0.047 |
| 19.56 |
| 75 2-DECANONE, 0.056 0.256 |
| A-YLANGENE |
| 19.93 |
| 77 A-COPAENE 0.201 0.350 |
| 21.00 |
| 83 LINALOOL 0.316 0.242 |
| 21.31 |
| 88 A-GURJUNENE 0.096 0.000 |
| 21.42 |
| 89 7-METHYL-2-DECANONE |
| 0.000 0.047 |
| 22.56 |
| 93 C15H24 CALARENE? 0.093 0.224 |
| 22.72 |
| 95 A-BERGAMOTENE, 0.055 0.000 |
| METHYL DECANOATE |
| 23.01 |
| 96 2-UNDECANONE 0.000 0.319 |
| 23.10 |
| 97 2-DECANOL 0.238 0.487 |
| 23.44 |
| 99 8-CARYOPHYLLENE 8.722 12.480 |
| 23.84 |
| 102 METHYL DEC-4-ENOATE |
| 0.743 0.150 |
| 24.03 |
| 103 MW168 2-OL? 0.000 0.096 |
| ME 43,81,110,108 |
| 25.18 |
| 114 B-FARNESENE 0.000 0.162 |
| 26.10 |
| 122 HUMULENE 13.614 31.397 |
| 26.16 |
| 123 METHYL DEC-4,8- 0.408 0.175 |
| DIENOATE |
| 26.46 |
| 129 WILEY# 123998 MW 204 |
| 0.518 0.845 |
| C15H24 |
| 26.59 |
| 131 2-DODECANONE 0.000 0.110 |
| 27.32 |
| 138 A-FARNESENE OR 0.177 0.296 |
| ZINGIBERENE |
| 27.53 |
| 139 CAS# 030021-74-0 0.116 0.183 |
| 27.75 |
| 143 A-MUUROLENE 0.248 0.315 |
| 27.90 |
| 144 B-SELINENE 0.738 0.276 |
| 28.04 |
| 145 A-SELINENE 0.764 0.320 |
| 28.34 |
| 147 METHYL 0.000 0.000 |
| ?-UNDECENOATE |
| 29.16 |
| 154 D-CADINENE 0.979 1.770 |
| 29.39 |
| 155 G-CADINENE 0.547 0.862 |
| 30.34 |
| 164 CAS# 016728-99-7 OR |
| 0.116 0.190 |
| G-SELINENE |
| 30.73 |
| 166 A-MUUROLINE 0.107 0.177 |
| 31.15 |
| 170 2-TRIDECANONE 0.300 0.273 |
| 31.36 |
| 171 GERANYL PROPANOATE |
| 0.105 0.000 |
| 31.46 |
| 172 MW 212 METHYL 0.065 0.000 |
| ?-DODECENOATE |
| 32.28 |
| 177 trans-GERANIOL 1.055 0.000 |
| 32.54 |
| 179 CAS# 000483-77-2 0.084 0.123 |
| (CALAMENENE ?) |
| 34.38 |
| 187 METHYL 3,6- 0.063 0.000 |
| DODECDIENOATE ME 79 |
| 36.42 |
| 196 MW 210 ME 43,54,82 |
| 0.000 0.077 |
| 39.11 |
| 211 CARYOPHYLLENE OXIDE |
| 0.166 0.152 |
| 40.23 |
| 221 HUMULENE 0.059 0.072 |
| MONO-EPOXIDE I |
| 40.28 |
| 223 MW222 ME 43,82 0.113 0.100 |
| 41.07 |
| 225 HUMULENE 0.224 0.366 |
| MONO-EPOXIDE II |
| 41.55 |
| 228 HUMULENE 0.076 0.136 |
| MONO-EPOXIDE III |
| 41.88 |
| 231 MW 222 ME 43,79,80 |
| 0.253 0.389 |
| 43.88 |
| 242 MW 220 ME 43,79,91 |
| 0.139 0.276 |
| 44.73 |
| 246 T-CADINOL 0.097 0.186 |
| 46.08 |
| 255 T-MUUROLOL 0.057 0.115 |
| ME 95,121,204 |
| 47.50 |
| 262 MW 220 ME 41,67,109 |
| 0.000 0.000 |
| DIEPOXIDE? |
| 48.69 |
| 268 FARNESOL 0.127 0.192 |
| ______________________________________ |
| GC/ TENTATIVE IDENTI- |
| 60052 |
| FID CMPD. FICATION BY GC./ PRIDE OF 21077 |
| RT. # MASS SPECTROSCOPY |
| RINGWOOD SAAZ |
| ______________________________________ |
| 6.42 9 A-PINENE 0.089 0.049 |
| 7.46 14 ISOBUTYL ISOBUTYRATE |
| 0.043 0.000 |
| 8.10 16 8-PINENE 0.690 0.486 |
| 9.11 18 MYRCENE 46.727 34.050 |
| 9.77 22 2-METHYL-BUTYL 0.121 0.000 |
| PROPANOATE |
| 9.90 23 ISOAMYL ISOBUTYRATE |
| 0.000 0.000 |
| 9.96 24 2-METHYL-BUTYL 0.220 0.000 |
| ISOBUTARATE |
| 10.28 |
| 26 L-LIMONENE 0.197 0.166 |
| 10.62 |
| 27 B-PHELLANDRENE? 0.156 0.081 |
| C10H15 |
| 11.59 |
| 32 trans-OCIMENE 0.000 0.000 |
| 12.45 |
| 35 2-METHYL-BUTYL 0.000 0.000 |
| 2-METHYL-BUTYRATE |
| 12.68 |
| 36 METHYL HEPTANOATE |
| 0.334 0.626 |
| 12.91 |
| 40 ISOAMYL ISOVALERATE |
| 0.000 0.000 |
| 14.31 |
| 43 METHYL 4-METHYL- 0.180 0.258 |
| HEXA-2-ENOATE |
| 14.39 |
| 45 METHYL 6-METHYL- 0.319 0.340 |
| HEPTANOATE |
| 15.98 |
| 51 METHYL OCTANOATE 0.473 0.225 |
| 16.26 |
| 55 NONANAL 0.116 0.308 |
| 19.41 |
| 73 METHYL NONANOATE 0.250 0.380 |
| 19.56 |
| 75 2-DECANONE, 0.147 0.501 |
| A-YLANGENE |
| 19.93 |
| 77 A-COPAENE 0.241 0.191 |
| 21.00 |
| 83 LINALOOL 0.317 0.337 |
| 21.31 |
| 88 A-GURJUNENE 0.230 0.173 |
| 21.42 |
| 89 7-METHYL-2-DECANONE |
| 0.125 0.222 |
| 22.56 |
| 93 C15H24 CALARENE? 0.133 0.113 |
| 22.72 |
| 95 A-BERGAMOTENE, 0.326 1.043 |
| METHYL DECANOATE |
| 23.01 |
| 96 2-UNDECANONE 0.690 1.394 |
| 23.10 |
| 97 2-DECANOL 0.226 0.299 |
| 23.44 |
| 99 8-CARYOPHYLLENE 8.708 5.010 |
| 23.84 |
| 102 METHYL DEC-4-ENOATE |
| 1.808 1.769 |
| 24.03 |
| 103 MW168 2-OL? 0.230 0.417 |
| ME 43,81,110,108 |
| 25.18 |
| 114 B-FARNESENE 0.000 18.900 |
| 26.10 |
| 122 HUMULENE 1.946 18.111 |
| 26.16 |
| 123 METHYL DEC-4,8- 0.571 0.259 |
| DIENOATE |
| 26.46 |
| 129 WILEY# 123998 MW 204 |
| 0.680 0.531 |
| C15H24 |
| 26.59 |
| 131 2-DODECANONE 0.053 0.264 |
| 27.32 |
| 138 A-FARNESENE OR 1.932 0.255 |
| ZINGIBERENE |
| 27.53 |
| 139 CAS# 030021-74-0 0.000 0.134 |
| 27.75 |
| 143 A-MUUROLENE 0.000 0.189 |
| 27.90 |
| 144 B-SELINENE 9.372 0.255 |
| 28.04 |
| 145 A-SELINENE 10.128 0.178 |
| 28.34 |
| 147 METHYL 1.329 0.104 |
| ?-UNDECENOATE |
| 29.16 |
| 154 D-CADINENE 1.124 0.829 |
| 29.39 |
| 155 G-CADINENE 0.650 0.519 |
| 30.34 |
| 164 CAS# 016728-99-7 OR |
| 0.137 0.181 |
| G-SELINENE |
| 30.73 |
| 166 A-MUUROLINE 0.133 0.099 |
| 31.15 |
| 170 2-TRIDECANONE 0.551 0.957 |
| 31.36 |
| 171 GERANYL PROPANOATE |
| 0.000 0.000 |
| 31.46 |
| 172 MW 212 METHYL 0.104 0.081 |
| ?-DODECENOATE |
| 32.28 |
| 177 trans-GERANIOL 0.217 0.080 |
| 32.54 |
| 179 CAS# 000483-77-2 0.146 0.167 |
| (CALAMENENE ?) |
| 34.38 |
| 187 METHYL 3,6- 0.182 0.424 |
| DODECDIENOATE ME 79 |
| 36.42 |
| 196 MW 210 ME 43,54,82 |
| 0.079 0.272 |
| 39.11 |
| 211 CARYOPHYLLENE OXIDE |
| 0.337 0.476 |
| 40.23 |
| 221 HUMULENE 0.076 0.329 |
| MONO-EPOXIDE I |
| 40.28 |
| 223 MW222 ME 43,82 0.175 0.294 |
| 41.07 |
| 225 HUMULENE 0.106 1.530 |
| MONO-EPOXIDE II |
| 41.55 |
| 228 HUMULENE 0.082 0.155 |
| MONO-EPOXIDE III |
| 41.88 |
| 231 MW 222 ME 43,79,80 |
| 0.852 1.789 |
| 43.88 |
| 242 MW 220 ME 43,79,91 |
| 0.231 0.487 |
| 44.73 |
| 246 T-CADINOL 0.140 0.174 |
| 46.08 |
| 255 T-MUUROLOL 0.067 0.099 |
| ME 95,121,204 |
| 47.50 |
| 262 MW 220 ME 41,67,109 |
| 0.000 0.083 |
| DIEPOXIDE? |
| 48.69 |
| 268 FARNESOL 0.169 0.160 |
| ______________________________________ |
| GC/ TENTATIVE IDENTI- 21173 |
| FID CMPD. FICATION BY GC./ 21186 STRISS- |
| RT. # MASS SPECTROSCOPY |
| SPALTER LESPALT |
| ______________________________________ |
| 6.42 9 A-PINENE 0.091 0.062 |
| 7.46 14 ISOBUTYL ISOBUTYRATE |
| 0.000 0.202 |
| 8.10 16 8-PINENE 0.861 0.634 |
| 9.11 18 MYRCENE 60.356 43.977 |
| 9.77 22 2-METHYL-BUTYL 0.000 0.257 |
| PROPANOATE |
| 9.90 23 ISOAMYL ISOBUTYRATE |
| 0.000 0.112 |
| 9.96 24 2-METHYL-BUTYL 0.000 0.736 |
| ISOBUTARATE |
| 10.28 |
| 26 L-LIMONENE 0.225 0.175 |
| 10.62 |
| 27 B-PHELLANDRENE? 0.234 0.139 |
| C10H15 |
| 11.59 |
| 32 trans-OCIMENE 0.055 0.082 |
| 12.45 |
| 35 2-METHYL-BUTYL 0.000 0.000 |
| 2-METHYL-BUTYRATE |
| 12.68 |
| 36 METHYL HEPTANOATE |
| 0.658 0.326 |
| 12.91 |
| 40 ISOAMYL ISOVALERATE |
| 0.000 0.000 |
| 14.31 |
| 43 METHYL 4-METHYL- 0.238 0.323 |
| HEXA-2-ENOATE |
| 14.39 |
| 45 METHYL 6-METHYL- 0.230 0.000 |
| HEPTANOATE |
| 15.98 |
| 51 METHYL OCTANOATE 0.168 0.103 |
| 16.26 |
| 55 NONANAL 0.166 0.255 |
| 19.41 |
| 73 METHYL NONANOATE 0.341 0.119 |
| 19.56 |
| 75 2-DECANONE, 0.313 0.216 |
| A-YLANGENE |
| 19.93 |
| 77 A-COPAENE 0.090 0.293 |
| 21.00 |
| 83 LINALOOL 0.557 0.649 |
| 21.31 |
| 88 A-GURJUNENE 0.127 0.000 |
| 21.42 |
| 89 7-METHYL-2-DECANONE |
| 0.144 0.133 |
| 22.56 |
| 93 C15H24 CALARENE? 0.055 0.243 |
| 22.72 |
| 95 A-BERGAMOTENE, 0.691 0.000 |
| METHYL DECANOATE |
| 23.01 |
| 96 2-UNDECANONE 0.612 0.385 |
| 23.10 |
| 97 2-DECANOL 0.179 0.509 |
| 23.44 |
| 99 8-CARYOPHYLLENE 2.481 10.500 |
| 23.84 |
| 102 METHYL DEC-4-ENOATE |
| 1.180 0.570 |
| 24.03 |
| 103 MW168 2-OL? 0.211 0.091 |
| ME 43,81,110,108 |
| 25.18 |
| 114 B-FARNESENE 14.019 0.000 |
| 26.10 |
| 122 HUMULENE 9.083 29.252 |
| 26.16 |
| 123 METHYL DEC-4,8- 0.313 0.147 |
| DIENOATE |
| 26.46 |
| 129 WILEY# 123998 MW 204 |
| 0.243 0.872 |
| C15H24 |
| 26.59 |
| 131 2-DODECANONE 0.174 0.000 |
| 27.32 |
| 138 A-FARNESENE OR 0.179 0.131 |
| ZINGIBERENE |
| 27.53 |
| 139 CAS# 030021-74-0 0.000 0.088 |
| 27.75 |
| 143 A-MUUROLENE 0.137 0.233 |
| 27.90 |
| 144 B-SELINENE 0.130 0.237 |
| 28.04 |
| 145 A-SELINENE 0.069 0.281 |
| 28.34 |
| 147 METHYL 0.118 0.082 |
| ?-UNDECENOATE |
| 29.16 |
| 154 D-CADINENE 0.398 1.364 |
| 29.39 |
| 155 G-CADINENE 0.226 0.824 |
| 30.34 |
| 164 CAS# 016728-99-7 OR |
| 0.119 0.210 |
| G-SELINENE |
| 30.73 |
| 166 A-MUUROLINE 0.000 0.196 |
| 31.15 |
| 170 2-TRIDECANONE 0.479 0.255 |
| 31.36 |
| 171 GERANYL PROPANOATE |
| 0.000 0.000 |
| 31.46 |
| 172 MW 212 METHYL 0.063 0.000 |
| ?-DODECENOATE |
| 32.28 |
| 177 trans-GERANIOL 0.193 0.000 |
| 32.54 |
| 179 CAS# 000483-77-2 0.073 0.205 |
| (CALAMENENE ?) |
| 34.38 |
| 187 METHYL 3,6- 0.233 0.000 |
| DODECDIENOATE ME 79 |
| 36.42 |
| 196 MW 210 ME 43,54,82 |
| 0.155 0.172 |
| 39.11 |
| 211 CARYOPHYLLENE OXIDE |
| 0.139 0.540 |
| 40.23 |
| 221 HUMULENE 0.106 0.152 |
| MONO-EPOXIDE I |
| 40.28 |
| 223 MW222 ME 43,82 0.137 0.150 |
| 41.07 |
| 225 HUMULENE 0.425 1.140 |
| MONO-EPOXIDE II |
| 41.55 |
| 228 HUMULENE 0.000 0.000 |
| MONO-EPOXIDE III |
| 41.88 |
| 231 MW 222 ME 43,79,80 |
| 0.854 0.609 |
| 43.88 |
| 242 MW 220 ME 43,79,91 |
| 0.186 0.141 |
| 44.73 |
| 246 T-CADINOL 0.064 0.144 |
| 46.08 |
| 255 T-MUUROLOL 0.000 0.092 |
| ME 95,121,204 |
| 47.50 |
| 262 MW 220 ME 41,67,109 |
| 0.000 0.000 |
| DIEPOXIDE? |
| 48.69 |
| 268 FARNESOL 0.093 0.191 |
| ______________________________________ |
| GC/ TENTATIVE IDENTI- |
| FID CMPD. FICATION BY GC./ 21049 21112 |
| RT. # MASS SPECTROSCOPY |
| STYRIAN TARGET |
| ______________________________________ |
| 6.42 9 A-PINENE 0.089 0.119 |
| 7.46 14 ISOBUTYL ISOBUTYRATE |
| 0.328 0.406 |
| 8.10 16 8-PINENE 0.795 0.865 |
| 9.11 18 MYRCENE 56.296 58.164 |
| 9.77 22 2-METHYL-BUTYL 0.171 0.482 |
| PROPANOATE |
| 9.90 23 ISOAMYL ISOBUTYRATE |
| 0.000 0.461 |
| 9.96 24 2-METHYL-BUTYL 0.753 1.408 |
| ISOBUTARATE |
| 10.28 |
| 26 L-LIMONENE 0.207 0.228 |
| 10.62 |
| 27 B-PHELLANDRENE? 0.229 0.226 |
| C10H15 |
| 11.59 |
| 32 trans-OCIMENE 0.057 0.366 |
| 12.45 |
| 35 2-METHYL-BUTYL 0.000 0.054 |
| 2-METHYL-BUTYRATE |
| 12.68 |
| 36 METHYL HEPTANOATE |
| 0.270 0.602 |
| 12.91 |
| 40 ISOAMYL ISOVALERATE |
| 0.000 0.118 |
| 14.31 |
| 43 METHYL 4-METHYL- 0.305 0.427 |
| HEXA-2-ENOATE |
| 14.39 |
| 45 METHYL 6-METHYL- 0.000 0.589 |
| HEPTANOATE |
| 15.98 |
| 51 METHYL OCTANOATE 0.000 0.446 |
| 16.26 |
| 55 NONANAL 0.141 0.107 |
| 19.41 |
| 73 METHYL NONANOATE 0.070 0.689 |
| 19.56 |
| 75 2-DECANONE, 0.216 0.821 |
| A-YLANGENE |
| 19.93 |
| 77 A-COPAENE 0.198 0.336 |
| 21.00 |
| 83 LINALOOL 0.751 0.891 |
| 21.31 |
| 88 A-GURJUNENE 0.000 0.000 |
| 21.42 |
| 89 7-METHYL-2-DECANONE |
| 0.094 0.401 |
| 22.56 |
| 93 C15H24 CALARENE? 0.166 0.000 |
| 22.72 |
| 95 A-BERGAMOTENE, 0.266 0.519 |
| METHYL DECANOATE |
| 23.01 |
| 96 2-UNDECANONE 0.301 1.502 |
| 23.10 |
| 97 2-DECANOL 0.366 0.282 |
| 23.44 |
| 99 8-CARYOPHYLLENE 7.269 4.952 |
| 23.84 |
| 102 METHYL DEC-4-ENOATE |
| 0.196 1.912 |
| 24.03 |
| 103 MW168 2-OL? 0.096 0.214 |
| ME 43,81,110,108 |
| 25.18 |
| 114 B-FARNESENE 4.187 0.000 |
| 26.10 |
| 122 HUMULENE 20.607 10.291 |
| 26.16 |
| 123 METHYL DEC-4,8- 0.106 0.221 |
| DIENOATE |
| 26.46 |
| 129 WILEY# 123998 MW 204 |
| 0.527 1.123 |
| C15H24 |
| 26.59 |
| 131 2-DODECANONE 0.000 0.000 |
| 27.32 |
| 138 A-FARNESENE OR 0.000 0.233 |
| ZINGIBERENE |
| 27.53 |
| 139 CAS# 030021-74-0 0.000 0.165 |
| 27.75 |
| 143 A-MUUROLENE 0.211 0.215 |
| 27.90 |
| 144 B-SELINENE 0.152 0.329 |
| 28.04 |
| 145 A-SELINENE 0.184 0.404 |
| 28.34 |
| 147 METHYL 0.269 0.000 |
| ?-UNDECENOATE |
| 29.16 |
| 154 D-CADINENE 0.013 1.215 |
| 29.39 |
| 155 G-CADINENE 0.536 0.653 |
| 30.34 |
| 164 CAS# 016728-99-7 OR |
| 0.000 0.798 |
| G-SELINENE |
| 30.73 |
| 166 A-MUUROLINE 0.167 0.198 |
| 31.15 |
| 170 2-TRIDECANONE 0.228 0.974 |
| 31.36 |
| 171 GERANYL PROPANOATE |
| 0.000 0.000 |
| 31.46 |
| 172 MW 212 METHYL 0.000 0.114 |
| ?-DODECENOATE |
| 32.28 |
| 177 trans-GERANIOL 0.000 0.000 |
| 32.54 |
| 179 CAS# 000483-77-2 0.112 0.118 |
| (CALAMENENE ?) |
| 34.38 |
| 187 METHYL 3,6- 0.000 0.388 |
| DODECDIENOATE ME 79 |
| 36.42 |
| 196 MW 210 ME 43,54,82 |
| 0.000 0.460 |
| 39.11 |
| 211 CARYOPHYLLENE OXIDE |
| 0.265 0.095 |
| 40.23 |
| 221 HUMULENE 0.000 0.536 |
| MONO-EPOXIDE I |
| 40.28 |
| 223 MW222 ME 43,82 0.000 0.000 |
| 41.07 |
| 225 HUMULENE 0.569 0.210 |
| MONO-EPOXIDE II |
| 41.55 |
| 228 HUMULENE 0.000 0.000 |
| MONO-EPOXIDE III |
| 41.88 |
| 231 MW 222 ME 43,79,80 |
| 0.394 1.253 |
| 43.88 |
| 242 MW 220 ME 43,79,91 |
| 0.119 0.266 |
| 44.73 |
| 246 T-CADINOL 0.119 0.114 |
| 46.08 |
| 255 T-MUUROLOL 0.000 0.000 |
| ME 95,121,204 |
| 47.50 |
| 262 MW 220 ME 41,67,109 |
| 0.000 0.000 |
| DIEPOXIDE? |
| 48.69 |
| 268 FARNESOL 0.000 0.000 |
| ______________________________________ |
| GC/ TENTATIVE IDENTI- |
| 21015 21041 |
| FID CMPD. FICATION BY GC./ TETT- WTILAM- |
| RT. # MASS SPECTROSCOPY |
| NANG EITF |
| ______________________________________ |
| 6.42 9 A-PINENE 0.080 0.078 |
| 7.46 14 ISOBUTYL ISOBUTYRATE |
| 0.000 0.217 |
| 8.10 16 8-PINENE 0.753 0.741 |
| 9.11 18 MYRCENE 50.137 55.492 |
| 9.77 22 2-METHYL-BUTYL 0.000 0.234 |
| PROPANOATE |
| 9.90 23 ISOAMYL ISOBUTYRATE |
| 0.000 0.000 |
| 9.96 24 2-METHYL-BUTYL 0.000 0.507 |
| ISOBUTARATE |
| 10.28 |
| 26 L-LIMONENE 0.205 0.191 |
| 10.62 |
| 27 B-PHELLANDRENE? 0.147 0.251 |
| C10H15 |
| 11.59 |
| 32 trans-OCIMENE 0.000 0.114 |
| 12.45 |
| 35 2-METHYL-BUTYL 0.000 0.000 |
| 2-METHYL-BUTYRATE |
| 12.68 |
| 36 METHYL HEPTANOATE |
| 0.509 0.532 |
| 12.91 |
| 40 ISOAMYL ISOVALERATE |
| 0.000 0.000 |
| 14.31 |
| 43 METHYL 4-METHYL- 0.230 0.224 |
| HEXA-2-ENOATE |
| 14.39 |
| 45 METHYL 6-METHYL- 0.260 0.120 |
| HEPTANOATE |
| 15.98 |
| 51 METHYL OCTANOATE 0.172 0.087 |
| 16.26 |
| 55 NONANAL 0.233 0.073 |
| 19.41 |
| 73 METHYL NONANOATE 0.228 0.078 |
| 19.56 |
| 75 2-DECANONE, 0.290 0.097 |
| A-YLANGENE |
| 19.93 |
| 77 A-COPAENE 0.129 0.190 |
| 21.00 |
| 83 LINALOOL 0.441 0.661 |
| 21.31 |
| 88 A-GURJUNENE 0.125 0.000 |
| 21.42 |
| 89 7-METHYL-2-DECANONE |
| 0.199 0.000 |
| 22.56 |
| 93 C15H24 CALARENE? 0.085 0.141 |
| 22.72 |
| 95 A-BERGAMOTENE, 0.873 0.380 |
| METHYL DECANOATE |
| 23.01 |
| 96 2-UNDECANONE 0.759 0.131 |
| 23.10 |
| 97 2-DECANOL 0.257 0.313 |
| 23.44 |
| 99 8-CARYOPHYLLENE 3.697 6.934 |
| 23.84 |
| 102 METHYL DEC-4-ENOATE |
| 1.220 0.288 |
| 24.03 |
| 103 MW168 2-OL? 0.255 0.041 |
| ME 43,81,110,108 |
| 25.18 |
| 114 B-FARNESENE 16.938 7.097 |
| 26.10 |
| 122 HUMULENE 13.277 18.815 |
| 26.16 |
| 123 METHYL DEC-4,8- 0.338 0.196 |
| DIENOATE |
| 26.46 |
| 129 WILEY# 123998 MW 204 |
| 0.321 0.472 |
| C15H24 |
| 26.59 |
| 131 2-DODECANONE 0.169 0.000 |
| 27.32 |
| 138 A-FARNESENE OR 0.194 0.599 |
| ZINGIBERENE |
| 27.53 |
| 139 CAS# 030021-74-0 0.000 0.106 |
| 27.75 |
| 143 A-MUUROLENE 0.121 0.170 |
| 27.90 |
| 144 B-SELINENE 0.166 0.245 |
| 28.04 |
| 145 A-SELINENE 0.099 0.238 |
| 28.34 |
| 147 METHYL 0.177 0.407 |
| ?-UNDECENOATE |
| 29.16 |
| 154 D-CADINENE 0.532 0.970 |
| 29.39 |
| 155 G-CADINENE 0.317 0.493 |
| 30.34 |
| 164 CAS# 016728-99-7 OR |
| 0.114 0.107 |
| G-SELINENE |
| 30.73 |
| 166 A-MUUROLINE 0.059 0.099 |
| 31.15 |
| 170 2-TRIDECANONE 0.574 0.142 |
| 31.36 |
| 171 GERANYL PROPANOATE |
| 0.000 0.000 |
| 31.46 |
| 172 MW 212 METHYL 0.000 0.000 |
| ?-DODECENOATE |
| 32.28 |
| 177 trans-GERANIOL 0.157 0.050 |
| 32.54 |
| 179 CAS# 000483-77-2 0.131 0.071 |
| (CALAMENENE ?) |
| 34.38 |
| 187 METHYL 3,6- 0.192 0.000 |
| DODECDIENOATE ME 79 |
| 36.42 |
| 196 MW 210 ME 43,54,82 |
| 0.163 0.000 |
| 39.11 |
| 211 CARYOPHYLLENE OXIDE |
| 0.282 0.097 |
| 40.23 |
| 221 HUMULENE 0.180 0.000 |
| MONO-EPOXIDE I |
| 40.28 |
| 223 MW222 ME 43,82 0.161 0.000 |
| 41.07 |
| 225 HUMULENE 0.901 0.200 |
| MONO-EPOXIDE II |
| 41.55 |
| 228 HUMULENE 0.089 0.071 |
| MONO-EPOXIDE III |
| 41.88 |
| 231 MW 222 ME 43,79,80 |
| 1.033 0.118 |
| 43.88 |
| 242 MW 220 ME 43,79,91 |
| 0.235 0.000 |
| 44.73 |
| 246 T-CADINOL 0.098 0.104 |
| 46.08 |
| 255 T-MUUROLOL 0.000 0.061 |
| ME 95,121,204 |
| 47.50 |
| 262 MW 220 ME 41,67,109 |
| 0.000 0.000 |
| DIEPOXIDE? |
| 48.69 |
| 268 FARNESOL 0.131 0.457 |
| ______________________________________ |
| GC/ TENTATIVE IDENTI- 9/17 |
| FID CMPD. FICATION BY GC./ 21498 COLUM- |
| RT. # MASS SPECTROSCOPY |
| YEOMAN BUS |
| ______________________________________ |
| 6.42 9 A-PINENE 0.121 0.125 |
| 7.46 14 ISOBUTYL ISOBUTYRATE |
| 0.455 0.066 |
| 8.10 16 8-PINENE 0.829 0.745 |
| 9.11 18 MYRCENE 51.427 42.267 |
| 9.77 22 2-METHYL-BUTYL 0.659 0.370 |
| PROPANOATE |
| 9.90 23 ISOAMYL ISOBUTYRATE |
| 0.522 0.184 |
| 9.96 24 2-METHYL-BUTYL 1.946 0.800 |
| ISOBUTARATE |
| 10.28 |
| 26 L-LIMONENE 0.237 0.236 |
| 10.62 |
| 27 B-PHELLANDRENE? 0.260 0.177 |
| C10H15 |
| 11.59 |
| 32 trans-OCIMENE 0.159 0.168 |
| 12.45 |
| 35 2-METHYL-BUTYL 0.180 0.090 |
| 2-METHYL-BUTYRATE |
| 12.68 |
| 36 METHYL HEPTANOATE |
| 0.349 0.000 |
| 12.91 |
| 40 ISOAMYL ISOVALERATE |
| 0.274 0.106 |
| 14.31 |
| 43 METHYL 4-METHYL- 0.139 0.000 |
| HEXA-2-ENOATE |
| 14.39 |
| 45 METHYL 6-METHYL- 0.119 0.153 |
| HEPTANOATE |
| 15.98 |
| 51 METHYL OCTANOATE 0.209 0.000 |
| 16.26 |
| 55 NONANAL 0.059 0.000 |
| 19.41 |
| 73 METHYL NONANOATE 0.070 0.000 |
| 19.56 |
| 75 2-DECANONE, 0.133 |
| A-YLANGENE |
| 19.93 |
| 77 A-COPAENE 0.252 0.764 |
| 21.00 |
| 83 LINALOOL 0.379 0.417 |
| 21.31 |
| 88 A-GURJUNENE 0.000 |
| 21.42 |
| 89 7-METHYL-2-DECANONE |
| 0.000 0.000 |
| 22.56 |
| 93 C15H24 CALARENE? 0.123 0.252 |
| 22.72 |
| 95 A-BERGAMOTENE, 0.000 0.000 |
| METHYL DECANOATE |
| 23.01 |
| 96 2-UNDECANONE 0.361 0.068 |
| 23.10 |
| 97 2-DECANOL 0.268 |
| 23.44 |
| 99 8-CARYOPHYLLENE 6.954 10.236 |
| 23.84 |
| 102 METHYL DEC-4-ENOATE |
| 0.692 0.457 |
| 24.03 |
| 103 MW168 2-OL? 0.115 0.000 |
| ME 43,81,110,108 |
| 25.18 |
| 114 B-FARNESENE 0.000 0.000 |
| 26.10 |
| 122 HUMULENE 10.146 17.370 |
| 26.16 |
| 123 METHYL DEC-4,8- 0.553 |
| DIENOATE |
| 26.46 |
| 129 WILEY# 123998 MW 204 |
| 0.439 1.992 |
| C15H24 |
| 26.59 |
| 131 2-DODECANONE 0.045 0.000 |
| 27.32 |
| 138 A-FARNESENE OR 0.223 0.508 |
| ZINGIBERENE |
| 27.53 |
| 139 CAS# 030021-74-0 0.117 0.464 |
| 27.75 |
| 143 A-MUUROLENE 0.209 0.733 |
| 27.90 |
| 144 B-SELINENE 2.829 1.230 |
| 28.04 |
| 145 A-SELINENE 3.352 1.291 |
| 28.34 |
| 147 METHYL 0.075 0.000 |
| ?-UNDECENOATE |
| 29.16 |
| 154 D-CADINENE 1.028 3.412 |
| 29.39 |
| 155 G-CADINENE 0.484 2.048 |
| 30.34 |
| 164 CAS# 016728-99-7 OR |
| 0.134 2.809 |
| G-SELINENE |
| 30.73 |
| 166 A-MUUROLINE 0.095 0.366 |
| 31.15 |
| 170 2-TRIDECANONE 0.313 0.000 |
| 31.36 |
| 171 GERANYL PROPANOATE |
| 0.000 0.753 |
| 31.46 |
| 172 MW 212 METHYL 0.000 0.000 |
| ?-DODECENOATE |
| 32.28 |
| 177 trans-GERANIOL 0.363 0.180 |
| 32.54 |
| 179 CAS# 000483-77-2 0.069 0.381 |
| (CALAMENENE ?) |
| 34.38 |
| 187 METHYL 3,6- 0.061 0.000 |
| DODECDIENOATE ME 79 |
| 36.42 |
| 196 MW 210 ME 43,54,82 |
| 0.048 0.135 |
| 39.11 |
| 211 CARYOPHYLLENE OXIDE |
| 0.061 0.235 |
| 40.23 |
| 221 HUMULENE 0.059 0.109 |
| MONO-EPOXIDE I |
| 40.28 |
| 223 MW222 ME 43,82 0.078 |
| 41.07 |
| 225 HUMULENE 0.161 0.358 |
| MONO-EPOXIDE II |
| 41.55 |
| 228 HUMULENE 0.073 0.167 |
| MONO-EPOXIDE III |
| 41.88 |
| 231 MW 222 ME 43,79,80 |
| 0.365 0.847 |
| 43.88 |
| 242 MW 220 ME 43,79,91 |
| 0.000 0.455 |
| 44.73 |
| 246 T-CADINOL 0.101 0.232 |
| 46.08 |
| 255 T-MUUROLOL 0.062 0.111 |
| ME 95,121,204 |
| 47.50 |
| 262 MW 220 ME 41,67,109 |
| 0.000 0.112 |
| DIEPOXIDE? |
| 48.69 |
| 268 FARNESOL 0.148 |
| ______________________________________ |
| APPENDIX 2 |
| ______________________________________ |
| Detailed GLC analyses of Columbus and other U.S. high alpha |
| ______________________________________ |
| hops. |
| Area % |
| COLUMBUS GALENA |
| Identification |
| Group 92-12-8-2 92-12-8-3 |
| ______________________________________ |
| Apha-Pinene 0.125 0.184 |
| Beta-Pinene 1 0.943 0.883 |
| Myrcene 1 51.571 66.560 |
| Methyl butyl Isobutyrate |
| 0.838 3.575 |
| Limonene 4 0.288 0.350 |
| Linalool 3 0.470 0.294 |
| Caryophyllene 1 6.297 3.097 |
| Farnesene? 1 0.275 0.112 |
| Humulene 1 11.049 5.764 |
| Muurolene 4 0.768 0.309 |
| Selinene 4 1.472 0.341 |
| Geranyl Acetate |
| 3 0.016 0.048 |
| delta Cadinene |
| 4 1.834 0.292 |
| Gamma Cadinene |
| 4 1.095 0.143 |
| Geranyl Isobutyrate |
| 3 1.716 0.296 |
| Undecanone-2 1.348 0.059 |
| Geraniol 3 0.048 0.060 |
| Limonen-10-ol 0.155 0.021 |
| Caryophyllene oxide |
| 2 0.259 0.014 |
| Humulene epoxide I |
| 2 0.430 0.033 |
| Humulene epoxide II |
| 2 1.450 0.068 |
| Caryolan-i-ol 2 0.120 0.006 |
| Humulene epoxide III |
| 2 0.025 0.013 |
| Humulol 2 0.185 0.011 |
| beta Eudesmol? |
| alpha Eudesmol? |
| Humulenol II 2 0.103 |
| Humulene diepoxide? |
| 2 |
| Major Hydrocarbons (1) 70.135 76.216 |
| Oxidation Products (2) 2.572 0.145 |
| Floral-Estery (3) 2.250 0.698 |
| Citrus Piney (4) 5.457 1.435 |
| Total Accounted For 80.414 78.494 |
| Humulene/Caryophyllene 1.753 1.861 |
| ______________________________________ |
| CHINOOK NUGGET |
| Identification |
| Group 92-12-9-1 92-12-9-2 |
| ______________________________________ |
| Apha-Pinene 0.047 0.081 |
| Beta-Pinene 1 0.435 0.667 |
| Myrcene 1 28.469 51.972 |
| Methyl butyl Isobutyrate |
| 1.410 1.274 |
| Limonene 4 0.136 0.183 |
| Linalool 3 0.369 1.022 |
| Caryophyllene 1 9.516 8.597 |
| Farnesene? 1 0.353 0.162 |
| Humulene 1 21.157 19.029 |
| Muurolene 4 1.517 0.921 |
| Selinene 4 1.385 0.818 |
| Geranyl Acetate |
| 3 0.210 0.044 |
| delta Cadinene |
| 4 4.215 0.926 |
| Gamma Cadinene |
| 4 2.686 0.445 |
| Geranyl Isobutyrate |
| 3 3.323 0.076 |
| Undecanone-2 0.675 0.453 |
| Geraniol 3 0.155 0.079 |
| Limonen-10-ol 0.049 0.037 |
| Caryophyllene oxide |
| 2 0.076 0.032 |
| Humulene epoxide I |
| 2 0.326 0.220 |
| Humulene epoxide II |
| 2 0.663 0.328 |
| Caryolan-i-ol 2 0.088 0.015 |
| Humulene epoxide III |
| 2 0.033 |
| Humulol 2 0.379 0.040 |
| beta Eudesmol? 0.248 |
| alpha Eudesmol? 0.205 |
| Humulenol II 2 0.112 0.022 |
| Humulene diepoxide? |
| 2 0.316 |
| Major Hydrocarbons (1) 59.924 80.427 |
| Oxidation Products (2) 1.993 0.657 |
| Floral-Estery (3) 4.057 1.221 |
| Citrus Piney (4) 9.939 3.293 |
| Total Accounted For 75.913 85.598 |
| Humulene/Caryophyllene 2.223 2.213 |
| ______________________________________ |
| Area Percent Report |
| Sample Name: 92-12-8-2 |
| Pk # Ret Time Area Area % |
| Identification |
| ______________________________________ |
| 1 7.030 3884 0.031 |
| 2 7.854 1456 0.011 |
| 3 8.010 1580 0.012 |
| 4 9.053 8364 0.066 |
| 5 9.260 10821 0.086 |
| 6 9.358 15718 0.125 Alpha-Pinene |
| 7 9.800 4213 0.033 |
| 8 10.297 2957 0.023 |
| 9 10.543 9679 0.077 |
| 10 11.097 967 0.007 |
| 11 11.242 118386 0.943 Beta-Pinene |
| 12 11.904 1183 0.009 |
| 13 12.476 6468547 51.571 |
| Myrcene |
| 14 12.685 4762 0.038 |
| 15 12.746 3884 0.031 |
| 16 13.064 52106 0.415 |
| 17 13.204 48568 0.387 |
| 18 13.274 105192 0.838 Methyl butyl Isobutyrate |
| 19 13.586 36238 0.288 Limonene |
| 20 13.797 3396 0.027 |
| 21 13.938 26704 0.212 |
| 22 14.149 4588 0.036 |
| 23 14.333 8748 0.069 |
| 24 14.520 1416 0.011 |
| 25 14.602 16543 0.131 |
| 26 14.879 17328 0.138 |
| 27 15.087 7345 0.058 |
| 28 15.212 931 0.007 |
| 29 15.420 743 0.005 |
| 30 15.506 3693 0.029 |
| 31 15.722 3398 0.027 |
| 32 15.801 10636 0.084 |
| 33 16.009 5267 0.042 |
| 34 16.069 2526 0.020 |
| 35 16.244 25684 0.204 |
| 36 16.624 3088 0.024 |
| 37 16.793 10279 0.081 |
| 38 16.915 3626 0.028 |
| 39 17.427 1969 0.015 |
| 40 17.673 67587 0.538 |
| 41 18.248 2557 0.020 |
| 42 18.354 1000 0.008 |
| 43 18.423 691 0.005 |
| 44 18.953 7042 0.056 |
| 45 19.178 7410 0.059 |
| 46 19.291 6033 0.048 |
| 47 19.466 10779 0.085 |
| 48 19.777 7142 0.056 |
| 49 19.956 4956 0.039 |
| 50 20.134 23743 0.189 |
| 51 20.364 804 0.006 |
| 52 20.742 2092 0.016 |
| 53 20.877 5423 0.043 |
| 54 20.984 1676 0.013 |
| 55 21.043 923 0.007 |
| 56 21.229 29717 0.236 |
| 57 21.448 1539 0.012 |
| 58 21.532 7494 0.059 |
| 59 21.843 8179 0.065 |
| 60 22.211 1838 0.014 |
| 61 22.295 6856 0.054 |
| 62 22.441 19924 0.158 |
| 63 22.568 2933 0.023 |
| 64 22.750 66342 0.528 |
| 65 22.922 5479 0.043 |
| 66 23.076 2236 0.017 |
| 67 23.224 1919 0.015 |
| 68 23.360 6240 0.049 |
| 69 23.682 59058 0.470 Linalool |
| 70 23.938 25935 0.206 |
| 71 24.171 19672 0.156 |
| 72 24.285 1535 0.012 |
| 73 24.432 6320 0.050 |
| 74 24.542 1797 0.014 |
| 75 24.816 10688 0.085 |
| 76 25.028 9189 0.073 |
| 77 25.276 29524 0.235 |
| 78 25.457 3016 0.024 |
| 79 25.597 16721 0.133 |
| 80 25.737 4624 0.036 |
| 81 25.858 45802 0.365 |
| 82 26.177 789857 6.297 Caryophyllene |
| 83 26.267 147160 1.173 |
| 84 26.483 11876 0.094 |
| 85 26.654 2115 0.016 |
| 86 26.951 19239 0.153 |
| 87 27.128 7807 0.062 |
| 88 27.262 34560 0.275 Farnesene? |
| 89 27.452 5485 0.043 |
| 90 27.650 12130 0.096 |
| 91 27.741 32092 0.255 |
| 92 28.029 22059 0.175 |
| 93 28.286 1385879 11.049 |
| Humulene |
| 94 28.518 174316 1.389 |
| 95 28.816 1217 0.009 |
| 96 29.099 46594 0.371 |
| 97 29.289 65255 0.520 |
| 98 29.452 50235 0.400 |
| 99 29.663 101538 0.809 |
| 100 29.743 96334 0.768 Muurolene |
| 101 29.922 184741 1.472 Selinene |
| 102 30.066 2003 0.016 Geranyl Acetate |
| 103 30.168 16997 0.135 |
| 104 30.380 230089 1.834 delta Cadinene |
| 105 30.604 137367 1.095 Gamma Cadiene |
| 106 30.702 18692 0.149 |
| 107 30.952 9850 0.078 |
| 108 31.085 4796 0.038 |
| 109 31.312 215300 1.716 Geranyl Isobutyrate |
| 110 31.411 169139 1.348 Undecanone-2 |
| 111 31.517 26715 0.213 |
| 112 31.630 77466 0.617 |
| 113 31.737 5913 0.047 |
| 114 31.821 6115 0.048 Geraniol |
| 115 32.106 9621 0.076 |
| 116 32.224 20686 0.164 |
| 117 32.501 13220 0.105 |
| 118 32.620 30790 0.245 |
| 119 33.031 7712 0.061 |
| 120 33.254 2445 0.019 |
| 121 33.462 7790 0.062 |
| 122 33.722 28110 0.224 |
| 123 33.960 4270 0.034 |
| 124 34.081 2094 0.016 |
| 125 34.192 4256 0.033 |
| 126 34.312 4289 0.034 |
| 127 34.372 5764 0.046 |
| 128 34.483 5031 0.040 |
| 129 34.565 5092 0.040 |
| 131 34.901 34301 0.273 |
| 132 35.009 13488 0.107 |
| 133 35.126 5975 0.047 |
| 134 35.299 1614 0.012 |
| 135 35.487 11667 0.093 |
| 136 35.854 17035 0.135 Limonen-10-ol |
| 137 36.161 2233 0.017 |
| 138 36.312 32546 0.259 Caryophyllene oxide |
| 139 36.476 1067 0.008 |
| 140 36.577 2462 0.019 |
| 141 36.935 6949 0.055 |
| 142 37.071 1073 0.008 |
| 143 37.206 13125 0.104 |
| 144 37.370 2081 0.016 |
| 145 37.555 7101 0.056 |
| 146 37.672 54047 0.430 Humulene epoxide I |
| 147 38.006 8150 0.065 |
| 148 38.127 3162 0.025 |
| 149 38.444 2423 0.019 |
| 150 38.688 30971 0.246 |
| 151 38.915 181869 1.450 Humulene epoxide II |
| 152 39.075 15063 0.120 Caryolan-1-ol |
| 153 39.222 3225 0.025 Humulene epoxide III |
| 154 39.501 7444 0.059 |
| 155 39.809 1283 0.010 |
| 156 39.935 1171 0.009 |
| 157 40.158 5912 0.047 |
| 158 40.396 1243 0.009 |
| 159 40.677 52277 0.416 |
| 160 40.871 8343 0.066 |
| 161 41.254 6706 0.053 |
| 162 41.404 23253 0.185 Humulol |
| 163 41.759 4806 0.038 |
| 164 41.946 30832 0.245 |
| 165 42.077 2776 0.022 |
| 166 42.236 2521 0.020 |
| 167 42.537 2687 0.021 |
| 168 42.964 11140 0.088 |
| 169 43.065 7509 0.059 |
| 170 43.258 23800 0.189 |
| 171 43.848 4438 0.035 |
| 172 44.637 12985 0.103 Humulenol II |
| 173 45.039 5691 0.045 |
| 174 45.892 3866 0.030 |
| 175 46.597 1815 0.014 |
| 176 47.014 2417 0.019 |
| 177 50.412 1109 0.008 |
| = 1.25428E + 007 |
| ______________________________________ |
| Area Percent Report |
| Sample Name: 92-12-8-3 |
| Pk # Ret Time Area Area % |
| Identification |
| ______________________________________ |
| 1 7.034 2371 0.022 |
| 2 7.855 753 0.007 |
| 3 7.988 864 0.008 |
| 4 8.623 706 0.066 |
| 5 9.056 1684 0.016 |
| 6 9.262 2429 0.023 |
| 7 9.359 19367 0.184 alpha Pinene |
| 8 9.801 6546 0.062 |
| 9 10.096 924 0.008 |
| 10 10.318 10977 0.104 |
| 11 10.547 49458 0.469 |
| 12 10.920 660 0.006 |
| 13 11.098 1561 0.014 |
| 14 11.242 93039 0.883 beta Pinene |
| 15 11.733 1061 0.010 |
| 16 11.901 3162 0.030 |
| 17 12.090 1322 0.012 |
| 18 12.484 6985773 66.360 |
| Myrcene |
| 19 12.692 7230 0.068 |
| 20 12.750 5559 0.052 |
| 21 13.073 155982 1.481 |
| 22 13.217 83592 0.794 |
| 23 13.301 376416 3.575 Methylbutyl Isobutyrate |
| 24 13.593 36853 0.350 Limoene |
| 25 13.810 1808 0.017 |
| 26 13.942 30257 0.287 |
| 27 14.151 2083 0.019 |
| 28 14.317 15305 0.145 |
| 29 14.529 2092 0.019 |
| 30 14.609 73712 0.700 |
| 31 14.896 239176 2.272 |
| 32 15.091 5970 0.056 |
| 33 15.333 699 0.006 |
| 34 15.508 2556 0.024 |
| 35 15.713 3795 0.036 |
| 36 15.804 17078 0.162 |
| 37 16.011 59153 0.561 |
| 38 16.246 26755 0.254 |
| 39 16.818 12944 0.123 |
| 40 17.427 1728 0.016 |
| 41 17.682 151069 1.435 |
| 42 18.253 1689 0.016 |
| 43 18.730 932 0.008 |
| 44 18.953 1326 0.012 |
| 45 19.192 122003 1.159 |
| 46 19.329 5927 0.056 |
| 47 19.481 11385 0.108 |
| 48 19.791 7946 0.075 |
| 49 19.952 1333 0.012 |
| 50 20.134 5804 0.055 |
| 51 20.727 9706 0.092 |
| 52 20.879 21447 0.203 |
| 53 21.054 2750 0.026 |
| 54 21.227 17557 0.166 |
| 55 21.769 2599 0.024 |
| 56 22.298 42843 0.407 |
| 57 22.437 4686 0.044 |
| 58 22.494 4842 0.046 |
| 59 22.739 15483 0.147 |
| 60 22.234 720 0.006 |
| 61 23.358 6212 0.059 |
| 62 23.681 30996 0.294 Linalool |
| 63 23.937 41114 0.390 |
| 64 24.168 9021 0.085 |
| 65 24.789 2293 0.021 |
| 66 25.025 2599 0.024 |
| 67 25.343 82950 0.788 |
| 68 25.449 1561 0.014 |
| 69 25.596 28078 0.266 |
| 70 25.830 3277 0.031 |
| 71 26.073 326058 3.097 Caryophyllene |
| 72 26.267 160273 1.522 |
| 73 26.482 8286 0.078 |
| 74 26.695 887 0.008 |
| 75 26.833 1478 0.014 |
| 76 26.923 20836 0.197 |
| 77 27.019 1307 0.012 |
| 78 27.112 1737 0.016 |
| 79 27.223 11802 0.112 Farnesene? |
| 80 27.440 2763 0.026 |
| 81 27.709 6688 0.063 |
| 82 28.023 24366 0.231 |
| 83 28.227 606830 5.764 Humulene |
| 84 28.353 4325 0.041 |
| 85 28.485 24982 0.237 |
| 86 28.582 4950 0.047 |
| 87 28.782 837 0.008 |
| 88 29.082 8038 0.076 |
| 89 29.251 9309 0.088 |
| 90 29.429 7845 0.074 |
| 91 29.642 32547 0.309 Muurolene |
| 92 29.716 35968 0.341 Selinene |
| 93 29.883 5145 0.048 Geranyl Acetate |
| 94 30.139 3103 0.029 |
| 95 30.328 30746 0.292 delta Cadinene |
| 96 30.562 15061 0.143 gamma Cadinene |
| 97 30.780 1170 0.011 |
| 98 31.068 2479 0.023 |
| 99 31.144 7554 0.071 |
| 100 31.383 31189 0.296 Geranyl Isobutyrate |
| 101 31.504 6271 0.059 Undecanone-2 |
| 102 31.610 3590 0.034 |
| 103 31.720 6384 0.060 Geraniol |
| 104 32.097 2303 0.021 |
| 105 32.222 1438 0.013 |
| 106 32.489 10866 0.103 |
| 107 32.608 3493 0.033 |
| 108 33.028 780 0.007 |
| 109 33.719 42378 0.402 |
| 110 33.949 697 0.006 |
| 111 34.181 786 0.007 |
| 112 34.478 1455 0.013 |
| 113 34.754 699 0.006 |
| 114 34.891 1927 0.018 |
| 115 35.004 1561 0.014 |
| 116 35.121 616 0.005 |
| 117 35.487 19190 0.182 |
| 118 35.892 2261 0.021 Limonen-10-ol |
| 119 36.302 1551 0.014 Caryophyllene oxide |
| 120 37.203 2536 0.024 |
| 121 37.660 3554 0.033 Humulene epoxide I |
| 122 38.680 5605 0.053 |
| 123 38.888 7257 0.068 Humulene epoxide II |
| 124 39.082 690 0.006 Caryolan-1-ol |
| 125 40.154 1386 0.013 Humulene epoxide III |
| 126 40.669 3261 0.031 |
| 127 40.872 1801 0.017 |
| 128 41.248 3412 0.032 |
| 129 41.399 1245 0.011 Humulol |
| 130 41.937 4179 0.039 |
| 131 43.258 1708 0.016 |
| Total area = 1.0527E + 007 |
| ______________________________________ |
| Area Percent Report |
| Sample Name: 92-12-9-1 |
| Pk # Ret Time Area Area % |
| Identification |
| ______________________________________ |
| 1 7.028 3603 0.029 |
| 2 7.848 1142 0.009 |
| 3 8.004 772 0.006 |
| 4 9.048 3120 0.025 |
| 5 9.253 7251 0.060 |
| 6 9.351 5689 0.047 alpha Pinene |
| 7 9.794 4017 0.033 |
| 8 10.302 1522 0.012 |
| 9 10.538 14530 0.120 |
| 10 11.090 761 0.006 |
| 11 11.231 52365 0.435 beta Pinene |
| 12 11.886 700 0.005 |
| 13 12.412 3424969 28.463 |
| Myrcene |
| 14 12.648 2525 0.021 |
| 15 12.725 2971 0.024 |
| 16 13.048 23622 0.196 |
| 17 13.193 43283 0.359 |
| 18 13.268 169688 1.410 Methylbutyl Isobutyrate |
| 19 13.576 16461 0.136 Limonene |
| 20 13.794 2031 0.016 |
| 21 13.929 18137 0.150 |
| 22 14.311 4573 0.038 |
| 23 14.595 10186 0.084 |
| 24 14.873 11403 0.094 |
| 25 15.080 12395 0.103 |
| 26 15.413 700 0.005 |
| 27 15.501 899 0.007 |
| 28 15.700 2332 0.019 |
| 29 15.796 15536 0.129 |
| 30 16.002 9137 0.075 |
| 31 16.243 38778 0.322 |
| 32 16.787 5760 0.047 |
| 33 16.906 1286 0.010 |
| 34 17.425 608 0.005 |
| 35 17.676 114830 0.954 |
| 36 18.247 625 0.005 |
| 37 18.947 1621 0.013 |
| 38 19.175 28172 0.234 |
| 39 19.294 3311 0.027 |
| 40 19.463 9984 0.083 |
| 41 19.771 2700 0.022 |
| 42 19.947 1731 0.014 |
| 43 20.130 4426 0.036 |
| 44 20.732 2604 0.021 |
| 45 20.874 10809 0.089 |
| 46 21.044 2047 0.017 |
| 47 21.230 61271 0.509 |
| 48 21.533 14424 0.119 |
| 49 21.780 1521 0.012 |
| 50 21.843 956 0.007 |
| 51 22.211 2063 0.017 |
| 52 22.293 15179 0.126 |
| 53 22.443 32264 0.268 |
| 54 22.570 3366 0.028 |
| 55 22.756 106737 0.887 |
| 56 23.080 5302 0.044 |
| 57 23.356 6309 0.052 |
| 58 23.680 44440 0.369 Linalool |
| 59 23.941 75567 0.628 |
| 60 24.170 15675 0.130 |
| 61 24.434 2150 0.017 |
| 62 24.524 1616 0.013 |
| 63 24.806 7293 0.060 |
| 64 25.028 2541 0.021 |
| 65 25.278 37278 0.309 |
| 66 25.346 31734 0.263 |
| 67 25.605 32557 0.270 |
| 68 25.881 90397 0.751 |
| 69 26.140 1145130 9.516 Caryophyllene |
| 70 26.269 176130 1.463 |
| 71 26.486 9543 0.079 |
| 72 26.835 1812 0.015 |
| 73 26.988 22481 0.186 |
| 74 27.140 17473 0.145 |
| 75 27.353 42477 0.353 Farnesene? |
| 76 27.473 5304 0.044 |
| 77 27.783 61915 0.514 |
| 78 28.035 24287 0.201 |
| 79 28.343 2545867 21.157 |
| Humulene |
| 80 28.547 315497 2.622 |
| 81 28.832 2334 0.019 |
| 82 28.945 5985 0.049 |
| 83 29.120 75042 0.623 |
| 84 29.300 116317 0.966 |
| 85 29.469 97160 0.807 |
| 86 29.682 182550 1.517 Muurolene |
| 87 29.764 166698 1.385 Selinene |
| 88 29.967 25357 0.210 Geranyl Acetate |
| 89 30.169 7062 0.058 |
| 90 30.417 507237 4.215 delta Cadiene |
| 91 30.630 323297 2.686 gamma Cadiene |
| 92 30.879 5404 0.044 |
| 93 31.069 10371 0.086 |
| 94 31.155 5319 0.044 |
| 95 31.332 399851 3.323 Geranyl Isoburyrate |
| 96 31.467 81272 0.675 Undecanone-2 |
| 97 31.617 7782 0.064 |
| 98 31.730 18703 0.155 Geraniol |
| 99 31.890 7540 0.062 |
| 100 32.109 8984 0.074 |
| 101 32.223 86628 0.719 |
| 102 32.436 9265 0.077 |
| 103 32.491 6647 0.055 |
| 104 32.620 30270 0.251 |
| 105 33.035 3306 0.027 |
| 106 33.230 743 0.006 |
| 107 33.464 4214 0.035 |
| 108 33.728 87090 0.723 |
| 109 33.951 2444 0.020 |
| 110 34.183 3253 0.027 |
| 111 34.370 4703 0.039 |
| 112 34.480 4897 0.040 |
| 113 34.758 3342 0.027 |
| 114 34.896 11595 0.096 |
| 115 35.007 14221 0.118 |
| 116 35.299 1278 0.010 |
| 117 35.489 39880 0.331 |
| 118 35.873 5944 0.049 Limonen-10-ol |
| 119 35.982 1196 0.009 |
| 120 36.163 3016 0.025 |
| 121 36.310 9199 0.076 Caryophyllene oxide |
| 122 36.564 1474 0.012 |
| 123 36.871 5580 0.046 |
| 124 37.205 13593 0.113 |
| 125 37.365 21562 0.179 |
| 126 37.551 3095 0.025 |
| 127 37.669 39322 0.326 Humulene epoxide I |
| 128 37.863 1467 0.012 |
| 129 38.004 7647 0.063 |
| 130 38.124 2074 0.017 |
| 131 38.438 1793 0.014 |
| 132 38.685 50800 0.422 |
| 133 38.900 79889 0.663 Humulene epoxide II |
| 134 39.082 10671 0.088 Caryolan-1-ol |
| 135 39.209 4042 0.033 Humulene epoxide III |
| 136 39.500 2852 0.023 |
| 137 39.716 694 0.005 |
| 138 39.789 600 0.005 |
| 139 40.149 3072 0.025 |
| 140 40.465 1310 0.010 |
| 141 40.672 16151 0.134 |
| 142 40.874 13029 0.108 |
| 143 41.250 10136 0.084 |
| 144 41.406 45643 0.379 Humulol |
| 145 41.758 11528 0.095 |
| 146 41.846 13183 0.109 |
| 147 41.945 25814 0.214 |
| 148 42.073 9818 0.081 |
| 149 42.534 5222 0.043 |
| 150 42.964 29878 0.248 beta Eudesmol? |
| 151 43.065 24765 0.205 alpha Eudesmol? |
| 152 43.255 33781 0.280 |
| 153 43.565 1828 0.015 |
| 154 43.846 10003 0.083 |
| 155 44.289 5485 0.045 |
| 156 44.370 3097 0.025 |
| 157 44.633 13527 0.112 Humulenol II |
| 158 45.042 12525 0.104 |
| 159 45.700 38097 0.316 Humulene diepoxide? |
| 160 45.885 3830 0.031 |
| 161 46.615 2140 0.017 |
| 162 47.030 2967 0.024 |
| 163 48.254 4136 0.034 |
| 164 48.524 1729 0.014 |
| 165 52.198 1275 0.010 |
| Total area = 1.20327E + 007 |
| ______________________________________ |
| Area Percent Report |
| Sample Name: 92-12-9-2 |
| Pk # Ret Time Area Area % |
| Identification |
| ______________________________________ |
| 1 7.034 1627 0.013 |
| 2 7.850 1222 0.010 |
| 3 9.051 1362 0.011 |
| 4 9.259 2214 0.018 |
| 5 9.355 9693 0.081 alpha Pinene |
| 6 9.796 3741 0.031 |
| 7 10.309 1970 0.016 |
| 8 10.542 19685 0.166 |
| 9 11.093 943 0.008 |
| 10 11.236 79174 0.667 beta Pinene |
| 11 11.895 2296 0.019 |
| 12 12.468 6160576 51.972 |
| Myrcene |
| 13 12.679 3749 0.031 |
| 14 12.741 4270 0.036 |
| 15 13.058 44822 0.378 |
| 16 13.201 59258 0.499 |
| 17 13.275 151104 1.274 Methylbutyl Isobutyrate |
| 18 13.582 21713 0.183 Limonene |
| 19 13.800 1814 0.015 |
| 20 13.934 28562 0.241 |
| 21 14.144 933 0.007 |
| 22 14.311 6730 0.056 |
| 23 14.519 2088 0.017 |
| 24 14.609 6243 0.052 |
| 25 14.875 55333 0.466 |
| 26 15.083 3970 0.033 |
| 27 15.326 1045 0.008 |
| 28 15.416 636 0.005 |
| 29 15.503 2028 0.017 |
| 30 15.702 2642 0.022 |
| 31 15.798 10210 0.086 |
| 32 16.005 54321 0.458 |
| 33 16.241 21435 0.180 |
| 34 16.809 7970 0.067 |
| 35 17.438 1939 0.016 |
| 36 17.655 61020 0.514 |
| 37 17.783 1252 0.010 |
| 38 18.248 665 0.005 |
| 39 18.948 1086 0.009 |
| 40 19.179 60530 0.510 |
| 41 19.314 1798 0.015 |
| 42 19.462 8464 0.071 |
| 43 19.546 4332 0.036 |
| 44 19.785 6451 0.054 |
| 45 19.949 1390 0.011 |
| 46 20.130 4840 0.040 |
| 47 20.722 11806 0.099 |
| 48 20.873 1283 0.010 |
| 49 20.945 2757 0.023 |
| 50 21.226 4405 0.037 |
| 51 21.524 2418 0.020 |
| 52 21.776 2520 0.021 |
| 53 22.199 1123 0.009 |
| 54 22.294 37518 0.316 |
| 55 22.438 12669 0.106 |
| 56 22.558 1478 0.012 |
| 57 22.743 43371 0.365 |
| 58 23.076 1222 0.010 |
| 59 23.236 1059 0.008 |
| 60 23.355 8797 0.074 |
| 61 23.681 121220 1.022 Linalool |
| 62 23.935 17913 0.151 |
| 63 24.167 9930 0.083 |
| 64 24.417 1477 0.012 |
| 65 24.798 946 0.008 |
| 66 24.923 911 0.007 |
| 67 25.023 2303 0.019 |
| 68 25.347 50189 0.423 |
| 69 25.462 730 0.006 |
| 70 25.605 63484 0.535 |
| 71 25.731 14566 0.122 |
| 72 25.863 19067 0.160 |
| 73 26.129 1019106 8.597 Caryophyllene |
| 74 26.267 172193 1.452 |
| 75 26.484 13509 0.114 |
| 76 26.649 3488 0.029 |
| 77 26.830 1518 0.012 |
| 78 26.973 2085 0.017 |
| 79 37.057 3159 0.026 |
| 80 27.127 4597 0.038 |
| 81 27.284 19285 0.162 Farnesene? |
| 82 27.452 4597 0.038 |
| 83 27.558 1014 0.008 |
| 84 27.766 17735 0.149 |
| 85 28.030 20185 0.170 |
| 86 28.324 2255638 19.029 |
| Humulene |
| 87 28.509 62699 0.529 |
| 88 28.575 78837 0.665 |
| 89 28.933 16176 0.136 |
| 90 29.101 26411 0.222 |
| 91 29.319 43633 0.368 |
| 92 29.442 23012 0.194 |
| 93 29.658 109275 0.921 Muurolene |
| 94 29.741 97039 0.818 Selinene |
| 95 29.881 5248 0.044 Geranyl Acetate |
| 96 30.142 4602 0.038 |
| 97 30.351 109776 0.926 delta Cadinene |
| 98 30.580 52832 0.445 gamma Cadinene |
| 99 30.771 1506 0.012 |
| 100 30.851 1737 0.014 |
| 101 31.082 5775 0.048 |
| 102 31.205 11532 0.097 |
| 103 31.330 9041 0.076 Geranyl isobutyrate |
| 104 31.511 53799 0.453 Undecanone-2 |
| 105 31.717 9415 0.079 Geraniol |
| 106 31.814 3048 0.025 |
| 107 32.085 5681 0.047 |
| 108 32.219 5853 0.049 |
| 109 32.492 1416 0.011 |
| 110 32.608 7265 0.061 |
| 111 33.033 906 0.007 |
| 112 33.253 722 0.006 |
| 113 33.712 10903 0.092 |
| 114 33.945 1308 0.011 |
| 115 34.071 2438 0.020 |
| 116 34.181 1069 0.009 |
| 117 34.368 5360 0.045 |
| 118 34.474 674 0.005 |
| 119 34.889 9616 0.081 |
| 120 35.001 4520 0.038 |
| 121 35.481 8543 0.072 |
| 122 35.853 4382 0.037 Limonen 10-ol |
| 123 35.976 1266 0.010 |
| 124 36.154 1163 0.009 |
| 125 36.296 3788 0.032 Caryophyllene oxide |
| 126 36.909 1692 0.014 |
| 127 37.183 9203 0.077 |
| 128 37.358 1754 0.014 |
| 129 37.660 26083 0.220 Humulene epoxide I |
| 130 37.996 2405 0.020 |
| 131 38.673 14395 0.121 |
| 132 38.889 38989 0.328 Humulene epoxide II |
| 133 39.079 1867 0.015 Caryolan-1 ol |
| 134 39.922 885 0.007 |
| 135 40.138 1296 0.010 |
| 136 40.666 11481 0.096 |
| 137 40.870 4099 0.034 |
| 138 41.245 7744 0.065 |
| 139 41.397 4776 0.040 Humulol |
| 140 41.934 9925 0.083 |
| 141 43.059 2394 0.020 |
| 142 43.254 5249 0.044 |
| 143 43.842 1927 0.016 |
| 144 44.637 2619 0.022 Humulenol II |
| = 1.18535E + 007 |
| ______________________________________ |
| Reference: |
| Code Variety |
| 92-12-8-2 |
| Columbus |
| 92-12-8-3 |
| Galena |
| 92-12-9-1 |
| Chinook |
| 92-12-9-2 |
| Nugget |
| Analytical Conditions: See, Nickerson and van Engel, "Hop Aroma Component |
| Profile and the Aroma Unit," Journal American Society of Brewing Chemists |
| 50(3), 7782(1992). |
Zimmermann, Charles E., Lewis, Gregory K., Hazenberg, Henry
| Patent | Priority | Assignee | Title |
| PP13128, | Sep 09 1999 | JOHN I HAAS, INC | Hop plant named `Millennium-48` |
| PP13129, | Sep 09 1999 | JOHN I HAAS, INC | Hop plant named `Millennium-MiddleLate` |
| PP13132, | Sep 09 1999 | JOHN I HAAS, INC | Hop plant named `Millennium-44` |
| PP13311, | Sep 09 1999 | JOHN I HAAS, INC | Hop plant named `Millennium-Late` |
| PP14127, | Feb 03 2000 | Hop plant named "VGXP01" | |
| PP24125, | May 20 2011 | Hop Breeding Company, LLC. | Hop plant named ‘HBC 369’ |
| Patent | Priority | Assignee | Title |
| PP8812, | Dec 17 1992 | John I. Haas, Inc. | Hop plant named H87311-3 |
| PP8823, | Dec 17 1992 | John I. Haas, Inc. | Hop plant named "H87207-2" |
| PP8824, | Dec 17 1992 | John I. Haas, Inc. | Hop plant named 37 H87203-1" |
| Executed on | Assignor | Assignee | Conveyance | Frame | Reel | Doc |
| Mar 22 1995 | Hopunion USA | (assignment on the face of the patent) | / | |||
| Mar 28 1997 | HAZENBERG, HENRY | Hopunion USA | ASSIGNMENT OF ASSIGNORS INTEREST SEE DOCUMENT FOR DETAILS | 008432 | /0889 | |
| Sep 18 1998 | HOPUNION U S A | HUSA-CEZ, L L C | ASSIGNMENT OF ASSIGNORS INTEREST SEE DOCUMENT FOR DETAILS | 009544 | /0609 | |
| Oct 12 1998 | YAKIMA CHIEF RANCHES, INC | HUSA-CEZ, L L C | ASSIGNMENT OF ASSIGNORS INTEREST SEE DOCUMENT FOR DETAILS | 009544 | /0712 | |
| Oct 13 1998 | ZIMMERMAN, CHARLES E | HUSA-CEZ, L L C | ASSIGNMENT OF ASSIGNORS INTEREST SEE DOCUMENT FOR DETAILS | 009544 | /0612 |
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