Multi-channel body

Abstract

A multi-channel body having excellent heat exchanging effectiveness, gas separating effectiveness and high thermal shock resistance is characterized in that a large number of channels are formed independently by being surrounded with partition walls, said partition walls are connected with partition walls surrounding other independent channels, continuous channels are formed with the partition walls, outer wall and the connecting walls around each channel, and a part of said continuous passages open outward the outer wall and a side face of said continuous passage is integrally and air-tightly sealed with the outer wall at at least one end face where the channels open.

Description

longitudinal channels 10 penetrate through from an end face X of the multi-channel body toward another end face X' and the portion 11 other than the longitudinal channels 10 in the end faces X and X' is integrally and air-tightly connected and sealed with an outer wall 12. On a face Y different from the end faces X and X', there is an opening 13 which opens outward the outer wall 12 and on a face Z there are openings 13', on a face Y' there are openings 14' and on a face Z' there are openings 14.

For example, when the multi-channel body shown in FIGS. 4 and 5 is used as a heat exchanger, a hot fluid is flowed into the openings of the longitudinal channels 10 provided in a large number on the end face X as shown by an arrow A and is flowed out toward an arrow B. On the other hand, a cool fluid, which is intended to be heat-exchanged, is flowed from the openings 13 on the face Y to the openings 13' on the face Z, similarly from the openings 14 on the face Z' to the openings 14' on the face Y' as shown by the arrows C, D, E and F to effect the heat exchange with the hot fluid. A cross-section along line M--M' of the multi-channel shown in FIG. 4 is shown in FIG. 6.

As shown in FIG. 6, a large number of longitudinal channels 10, which open in the end face X of FIG. 4, are independent longitudinal channels surrounded by longitudinal partition walls, respectively, with the longitudinal partition walls 15 defining the independent longitudinal channels 10 being connected to the longitudinal partition walls of other adjacent independent longitudinal channels 10 with longitudinal connecting walls 16 and similarly the longitudinal partition walls 15 being connected to the outer wall 12 with the longitudinal connecting walls 16. As the results, the circumference of each longitudinal channel 10 defines and forms a continuous passage 17 with the longitudinal partition walls 15, the out wall 12 and the longitudinal connecting walls 16, and the passages 17 are connected to the openings 13, 13', 14 and 14' and open outward the outer wall 12.

Thus, as shown in FIG. 7, in the multi-channel body of the present invention, all four sides a, b, c and d of the longitudinal partition wall 15 surrounding the independent longitudinal channel 10 are contacted with the passages 17. When the multi-channel body is used as a heat exchanger, the heat transfer area or contacting area is twice as large as the heat transfer area in the prior multi-channel body shown in FIG. 2. Therefore, the heat exchanging effectiveness and gas separating effectiveness are noticeably improved.

In the multi-channel body of the present invention, the longitudinal channels 10 are independent respectively and the longitudinal partition walls 15 defining and forming each longitudinal channel 10 are independent from adajcent longitudinal channels 10 because adjacent longitudinal channels 10 do not have any common longitudinal partition wall 15 between them and the independent longitudinal partition walls 15 are connected to the longitudinal connecting walls 16.

Thus, any deformation due to the heat stress can be suppressed and a thermally flexible structure can be obtained.

In the multi-channel body shown in FIG. 4, the longitudinal walls connecting the longitudinal partition wall 15 with the longitudinal partition wall 15 are arranged symmetrically with respect to the longitudinal channels 10, as shown in FIGS. 6-7, but such an arrangement is not always necessary. In FIGS. 4 and 5, the openings of the continuous passages 17 around each longitudinal channel 10 are provided at four portions 13, 13', 14 and 14' but the openings of the passages 17 may be only the openings 13 and 14.

In the multi-channel body shown in FIGS. 4-7, longitudinal communicating portions 18, as shown in FIG. 8, may be provided on a part of the longitudinal wall 16 connecting to the outer wall 12 to communicate the passages 17. For example, if the longitudinal communicating portions 18 are provided at several portions in the outer circumference as shown in FIG. 9, the number of openings, 13 and 13' shown in FIG. 4, may be reduced to the openings 19 and 19'. A plurality of openings 13 and 13' in FIG. 4 or 5 are provided but this plurality of openings may be reduced to one opening (not shown). Even in the same cross-sectional shape, the flow way of the passages 17 may be freely selected according to the means for connecting the longitudinal channels and the manner for arranging the communicating portions of the longitudinal connecting walls.

In the multi-channel body of the present invention, by integrally connecting and air-tightly sealing either one of the end portions of the longitudinal channel 10 with the outer wall 12, a component flowed from the opened end portion of the longitudinal channel 10 may be filtered and the filtered fluid is obtained from the opening connected to the continuous passage 17 around the longitudinal channel. Alternatively, the fluid filtered through the longitudinal partition walls may be obtained from a side face of the passage 17 without air-tight sealing of the side face of the continuous passage 17 positioning the end face of the multi-channel body at which one end of the longitudinal channel 10 is sealed. The multi-channel body may be of various structures according to the cross-sectional shape of the longitudinal channel 10 and the manner how the opening of the continuous passage 17 around the longitudinal channels 10 is provided on the outer wall 12.

If the various embodiments of the multi-channel bodies of the present invention are shown by the cross-sectional view corresponding to FIG. 6, they may be shown by FIGS. 10-17.

In FIG. 15, the longitudinal connecting wall 16 is present as an intersecting point of the longitudinal partition walls 15 of the independent longitudinal channel 10.

In FIG. 17, different longitudinal partition walls 20 and 21 are provided in the continuous passage 17 to form a passage 22 held between the passages 17. In this manner, the multi-channel body of the present invention may be constructed by dividing the flow way of the passage 17 by means of the longitudinal partition walls 20 and 21.

The multi-channel bodies may be used in a combination of two or more in series or parallel.

As a material forming the multi-channel bodies of the present invention, a dense material, a vapor permeable material or a water permeable material may be selected according to the use but practically, metallic, ceramic, glass, plastic material or the like or a combination thereof is preferable.

Among them, inorganic materials, such as cement, refractory material, ceramics, glass or a carbonaceous material or a metallic material is preferable and the inorganic materials include carbon, mullite, cordierite, silica, zircon, silica-alumina, silimanite, zirconia, zircon mullite, spinel, zirconia-spinel, titania, alumina, clay, beryllia, alumina-titanate, mullite-aluminatitanate, magnesia-aluminatitanate, zeolite, Vicor glass, silicon carbide, silicon nitride, LaCoO₃, La-Sr-CoO₃, Sr-Ce-Y-O, Sr-Ce-Zn-O, BaTiO₃, GaAs, ZrO₂ -CaO, ZnO, SnO₂, Fe₂ O₃, LiNbO₃, SrTiO₃, PbO-ZrO₂ -TiO₂, LiTaO₃, LaCrO₃, GaP, CBN, ZrC, ZrO₂ -Y₂ O₃, TiC, TaC, GaAsP, LaB₆, etc., and combinations thereof. Metallic materials include aluminum, copper, iron and the like. These materials are relatively easily extrusion-shaped to produce the monolithical multi-channel bodies of the present invention.

The cross-sectional shape of the longitudinal channels of the multi-channel bodies of the present invention may be any shape but particularly circular, ovular, triangular, tetragonal, pentagonal and hexagonal are preferred.

The connecting portion of the longitudinal partition walls surrounding each longitudinal channel with the longitudinal connecting wall may be freely selected but it is preferable to provide said portion at a position of point or line symmetry with respect to the longitudinal channel in view of the strength, the easiness of designing of the continuous passage, and other similar considerations. In addition, it is preferable that the wall thickness of the longitudinal partition walls surrounding each channel is uniform, but it is acceptable for the wall thickness of the outer wall to be larger. Furthermore, it is preferable that the axial line of each of the large number of independent longitudinal channels is parallel, because the thickness of the longitudinal partition walls forming the channels is uniform, so that the pressure loss, filtration area, heat conducting area and the like are uniform in each longitudinal channel. The term "parallel" used herein means that the axial lines of the longitudinal channels are parallel in the three dimensional Euclid space, that is when the channels are in zigzag line, parallel includes a case where the curved channels are parallel.

As materials to be used for the air-tightly sealed portion, a ceramic paste, ceramic cement, ceramic sheet, metal, glass, silicone rubber, plastics and the like are preferable.

The following examples are given for the purpose of illustration of this invention and are not intended as limitations thereof.

EXAMPLE 1

Cordierite raw material was added with water and a shaping aid, such as methyl cellulose, etc., a surfactant and the like to prepare a mixture. The mixture was kneaded with a kneader to obtain a shaping raw batch material composition.

This composition was extruded through an extrusion die to obtain a multi-channel body in which the cross-sectional shape of openings of the channels is as shown in FIG. 6. The thickness of the partition walls was 0.4 mm, the diameter corresponding to the channels was 3 mm and the distance of the continuous connecting passage surrounding the channels was 1 mm.

Then, a cordierite paste was injected only to an end face corresponding to a side face of passages excluding the channels among the end face where the channels of the shaped body open, to a depth of 1 mm to air-tightly seal the side face of the continuous passage. Openings 13, 13', 14 and 14' communicating with the continuous passages surrounding the channels were provided at side faces Y, Y', Z and Z' as shown in FIGS. 4 and 5.

The thus formed shaped body was fired in an electric furnace at 1,400°C for 5 hours to obtain a multi-channel body of the present invention.

A heat exchange was effected by using this multi-channel body as a heat exchanger and feeding a fired gas at 800°C as a hot fluid and air at 150°C as a cool fluid and the heat exchanging effectiveness was determined.

For comparison, with respect to a heat exchanger having the prior structure described in Japanese Patent Laid Open Application No. 103,058/1977 as shown in FIG. 2, the heat exchanging effectiveness was determined and as the results, the multi-channel body of the present invention had a heat exchanging effectiveness of 2.3 times the prior art article.

EXAMPLE 2

A multi-channel body of the present invention having the cross-sectional shape shown in FIG. 13 was prepared in the same manner as described in Example 1 by using an alumina raw material. An alumina paste was used for air-tightly sealing the proper portion and the diameter corresponding to the channel was 5 mm, the wall thickness was 1 mm, the width of the continuous passage was 2 mm, the size of the end face was 15×15 cm and the length was 50 cm.

With respect to a multi-channel body as shown in FIG. 2 produced from a prior honeycomb structure having a diameter corresponding to the channel of 5 mm and a wall thickness of 1 mm, a gas separating effectiveness of a starting gas of CO30%-H₂ 70% was determined under the conditions of an inlet temperature of 200°C, an inlet pressure of 20 kg/cm² and a pressure difference of 5 kg/cm² for comparison.

As the results, in the prior multi-channel body, a purified gas of CO13%-H₂ 87% was obtained in 110 Nm³ /hr, while in the multi-channel of the present invention, 320 Nm³ /hr was obtained and the separating effectiveness of the present invention was 2.8 times greater than the prior art article.

EXAMPLE 3

A multi-channel body of the present invention having the same shape and size as in Example 1 and a multi-channel body of a prior honeycomb structure shown by FIG. 2 were prepared by using mullite raw material and a thermal shock test was carried out.

These multi-channel bodies were rapidly heated from room temperature to 1,100°C in 5 minutes by means of a propane burner and kept at 1,100°C for 20 minutes and then quenched to room temperature in 5 minutes. This spalling test was repeated five times and the formation of cracks was observed. The multi-channel body of the prior structure was broken and the original shape was not maintained, while the multi-channel body of the present invention was not cracked at all and the thermal shock resistance was noticeably improved.

As mentioned above, in the multi-channel body of the present invention, the partition walls of a large number of independent channels are connected with the partition walls of the other independent adjacent channels by the connecting walls and the continuous channels are formed at the entire circumference of the channels, so that all the partition walls surrounding the channels are effectively utilized and therefore the contacting area between the passages wherein the different fluids flow, is considerably increased.

Accordingly, the multi-channel bodies of the present invention are particularly excellent in the heat exchanging effectiveness and the gas separating effectiveness and are high in the thermal shock resistance.

Thus, the multi-channel bodies of the present invention can be advantageously used, for example, for heat exchanger, gas separating membrane, filtrating device, cooler, permeating device, filter, various packages, and for reactors in which gas-solid reactions occur, liquid-solid reaction and the like, which are carried out in the channels in the multi-channel body, and are controlled by flowing a hot fluid in the continuous passage surrounding the channels whereby the temperature of the catalyst supported on an inner surface of the channels of the multi-channel body is controlled.

Moreover, the multi-channel bodies of the present invention can be used for gas-liquid reaction system, for example, by flowing a liquid in one passage to permeate out the liquid on the partition wall and flowing a gas in another passage, whereby said gas is reacted with the permeated liquid, gas-gas reaction system, liquid-liquid reaction system or gas-liquid-solid reaction system. Furthermore, if a heating element, such as PTCR honeycomb heater has the structure of the multi-channel of the present invention, the heater capable of controlling the temperature at a high precision can be obtained by adjusting the fluid in the continuous passage surrounding the channels and the multi-channel bodies of the present invention are very commercially useful.

Claims

1. A multi-channel body comprising:

an outer wall;

a plurality of parallelly situated independent longitudinal channels located inside of said outer wall, each of said independent longitudinal channels being defined by longitudinal partition walls having an inner surface and an outer surface and each parallelly situated independent longtudinal channel does not share any portion of any longitudinal partition wall with any other parallelly situated independent longitudinal channel, whereby a first fluid passes through said parallelly situated independent longitudinal channels in contact with inner surfaces of said longitudinal partition walls;

a plurality of longitudinal connecting walls for formed integrally with said longitudinal channels, each of said longitudinal connecting walls having a plane which does not transversely intersect the plane of said longitudinal partitions walls, and each of said connecting walls connecting two of said parallelly situated independent longitudinal channels, and at least one longitudinal connecting wall communicates with one longitudinal partition wall of each independent longitudinal channel, whereby a plurality of continuous longitudinal passages are formed throughout said multi-channel body around said plurality of parallelly situated independent longitudinal channels, said continuous longitudinal passages being defined by outer surfaces of said longitudinal partition walls, said connecting walls and said outer wall of the multi-channel multi-longitudinal channel body, such that a major portion of said continuous longitudinal passages are made up of said outer surface of said longitudinal partition walls and a minor portion of said continuous longitudinal passages are made up of said longitudinal connecting walls, thereby permitting a second fluid to pass through said plurality of continuous longitudinal passages in contact with outer surfaces of said longitudinal partition walls;

at least one inlet in said outer wall of the multi-channel body communicating with said continuous longitudinal passages to permit said second fluid to enter said continuous longitudinal passages; and

at least one outlet in said outer wall of the multi-channel body communicating with said continuous longitudinal passages to permit said second fluid to exit said continuous longitudinal passages.

2. The multi-channel body as claimed in claim 1, wherein one side of openings in said parallelly situated independent longitudinal channels are integrally and air-tightly sealed with the outer wall.

3. The multi-channel body as claimed in claim 1, wherein the longitudinal connecting walls are connected symmetrically with respect to each other and with respect to the parallelly situated independent longitudinal channels.

4. The multi-channel body as claimed in claim 1, wherein entrances and exits for the parallelly situated independent longitudinal channels and the continuous longitudinal passages are located on mutually exclusive surfaces of the outer wall.

5. The multi-channel body as claimed in claim 1, wherein the longitudinal partition walls, longitudinal connecting walls and outer wall forming the multi-channel body are formed in a monolithic structure consisting essentially of a material selected from the group of materials consisting of an inorganic material and a metallic material.

6. The multi-channel body as claimed in claim 1, wherein a cross-sectional shape of the longitudinal channels is selected from the group of cross-sectional shapes consisting of circular, ovular, triangular, tetragonal, pentagonal and hexagonal.

7. The multi-channel body as claimed in claim 1, wherein said first and said second fluids are not permitted to mix because of air-tightly sealing said plurality of parallelly situated independent longitudinal channels from said plurality of continuous longitudinal passages.