Method and apparatus for measuring ratio of mass flow rates and energy flow in a gas pipeline

Abstract

The present invention is a method and apparatus for monitoring in real time the mass and energy flow rate of a gas through a pipeline. The invention determines the mass flow ratio of a pipeline gas flowing through a pipeline compared to sample gas tapped from the pipeline line when the volumetric flow of pipeline gas through the pipeline is measured by a linear flow meter. Sample gas tapped from the pipeline is flowed to a chamber having a section with a fixed volume until the pressure in the chamber section is substantially equal to the pipeline gas pressure. The sample gas is maintained at substantially the same temperature as the gas in the pipeline while the sample gas is in the chamber section. A timer measures the time interval for the sample gas to flow from the chamber section at a selected rate for a calculated pressure drop the selected rate being controlled by a flow controller. The mass flow ratio is computed using the measured time interval and a signal from the linear flow meter. The energy flow rate of the pipeline gas is determined by measuring the energy flow rate of the sample gas and relating that value to the mass flow ratio of the pipeline gas compared to the sample gas.

Description

section 43 of the first chamber 20 43. The volume within the hollow coil 20' after the second solenoid 42 and before the flow controller 26 is a second section chamber 44 of the first chamber hollow coil 20'. The sample gas 18 flows from the second section chamber 44 continuously at a rate selected by the flow controller 26.

The hollow coil 20' is mounted in intimate contact with the pipeline 14 and serpentines back and forth across the outer surface of a portion of the pipeline 14. Insulation 45 should be placed around the hollow coil 20', the solenoid valve 22 and 42, and the pipeline 14. A heat transfer compound may also be used to facilitate temperature equalization. With this configuration, the temperature of the sample gas 18 within the first section chamber 43 of the first chamber 20 is maintained at substantially the same temperature as the temperature of the pipeline gas 12 flowing through the pipeline 14.

The second solenoid valve 42 is closed when sample gas 18 is filling the first section chamber 43 of the hollow coil 20' to pipeline pressure P_L. When the sample gas 18 pressure in the first section chamber 43 reaches P_L, the first solenoid valve 22 closes and the second solenoid valve 42 opens. The sample gas 18 pressure in the first section chamber 43' reduces quickly because the sample gas 18 pressure in the second volume chamber 44 is less than the sample gas 18 pressure in the first section 43 at that instant. The volume of the second second chamber 44 is such that the pressure in both chambers will stabilize at a pressure slightly higher than the starting pressure P₁. The pressure in both sections chambers 43 and 44 combined then decays to P₁ at which time the timer 34 begins and measures the time interval t_m for the pressure in both sections chambers 43 and 44 to decay from the starting pressure P₁ to the stopping pressure P₂.

In this embodiment, where the with first chamber has a first 43 and a second chamber 44 section, it is necessary for the sample gas pressure in the first section chamber 43 to reach P_L while being maintained at substantially the same temperature as the pipeline gas 12, but it is not necessary for the sample gas pressure in the second second chamber 44 to reach P_L. This configuration allows rapid containment of the sample gas 18 within the fixed volume of the first section chamber 43 of the hollow coil 20' at pipeline pressure P_L and alleviates the need to wait for the sample gas 18 pressure to slowly decay to the starting pressure P₁. Moreover, the second section chamber 44 of the hollow coil 20' has a much larger volume than the first section chamber 43 (i.e. about 12 fold) and thus the sample gas 18 pressure within the second section chamber 44 does not fluctuate substantially. The flow rate through the flow controller 26 is thus easier to maintain at the selected rate.

Still referring to FIG. 3, an arching sample gas feed 46 along with a valve 48 and a valve 50 are used to remove debris from the sample gas 18 before the sample gas 18 flows to the hollow coil 40. The low velocity in the rising section containing the valve 48 precludes particles from reaching the arch in the arching sample gas feed 46. Instead, the particles fall into a lower section of the pipe containing the valve 50. Periodically, the valve 50 can be opened to blow the collected debris from the lower section of the pipe through a blow hole 52. A filter 54 is also installed on the arching sample gas feed 46 to remove debris from the sample gas 18.

The following analysis is recited to emphasize the significance that ##EQU1## and to also explain additional features of the preferred embodiment of the invention that further improve the accuracy of the invention.

The total derivative of pressure with respect to time must account for density changes as well as molar flow and is given by: ##EQU2## is the total derivative of pressure with respect to time at constant temperature T, R is the real gas constant, V is the volume of the first fixed-volume chamber 20 (or the volume of the first section 43 of the hollow coil 20' if the embodiment in FIG. 3 is used), M_W is the molecular weight of the sample gas 18, ω_m is the mass flow rate of the sample gas 18, Z is the supercompressibility constant for the gas, and ##EQU3## is the partial derivative of Z at constant temperature T with respect to the density of the gas ρ.

The supercompressibility constant Z, which describes the dynamics of supercompressible gas, can be closely approximated by expanding the virial equation of state through the first three terms:

Z=1+bP+cP² =1+Bρ+Cρ² (2)

where ρ is gas density, P is the absolute gas pressure, B and C are the second and third density viral coefficients of the gas, and b and c are the second and third pressure virial coefficients of the gas. The virial coefficients depend on gas temperature and composition. The density virial coefficients are related to the pressure virial coefficients according to generally accepted mixing rules: ##EQU4## where R is the real gas constant and T is the absolute temperature of the gas.

It follows from Eqs. (1), (2) and (3) that the total derivative ##EQU5## for the sample gas is: ##EQU6## In the present invention, the derivative ##EQU7## is represented by: ##EQU8## where t_m is the time interval for the sample gas pressure in the first chamber to drop from P₁ to P₂. There is no requirement that P2 be a specific pressure other than P2 be less than P1 and selected to appropriately measure ##EQU9##

As shown in FIG. 2, P1 is greater than about one-half of the pipeline gas pressure in the pipeline while P2 is less than about one-half of the pipeline gas pressure in the pipeline. Substituting Eq. (5) into Eq. (4) and solving for the mass flow rate of the sample gas 18, ω_m, results in: ##EQU10##

Now, the mass flow rate of the pipeline gas 12 is given by: ##EQU11## where f_t is the frequency signal that the turbine meter 10 communicates to control system 16, and K_t is the turbine meter calibration constant relating turbine frequency f_t to volumetric flow rate (i.e. cycles/unit volume).

Using the real gas law and the virial equations of state, Eq. (7) becomes: ##EQU12## where P_L is the absolute pressure of pipeline gas 12. Dividing Eq. (8) by Eq. (5) results in: ##EQU13##

From Eq. (9), it is apparent that the effects of supercompressibility, first represented by the second pressure virial coefficient b, are minimized if P₁ is approximately equal to P_L /2. The accuracy of the invention is not compromised significantly provided that the starting pressure P₁ is within a few percent of half the pipeline pressure P_L because the second virial coefficient b is of the order 10-3.

Referring to FIG. 4, the starting P₁ and the stopping P₂ pressures are determined by a resistor string 56. The pressure sensor 36 senses the pressure in the first chamber 20 (or in the first section 43 or the hollow coil 20' if the embodiment shown in FIG. 3 is used) and communicates the data to an associated sample and hold circuit 58 and to the control system 16. The control system 16 determines when the sample gas 18 pressure in the first chamber 20 stabilizes at a maximum pressure, i.e. at the pipeline gas 12 pressure P_L, and sends a signal 45 indicating that maximum pressure to the sample and hold circuit 58. The sample and hold circuit 58 memorizes the value of the maximum pressure in the first chamber 20' for each sampling cycle 24. The circuit 58 is cleared at the end of each sampling cycle 24 after it receives a signal that the first solenoid valve 22 has opened.

An output voltage 60 from the sample and hole circuit 58 represents the maximum chamber pressure (i.e. P_L) and leads to the grounded resistor string 56. The output voltage 60 is split by the resistors 62, 64, and 66. The output voltage 60 drops across resistor 62 to the P₁ reference voltage 68 and further drops across resistor 64 to the P₂ reference voltage 60. The resistance of the resistor 62, R1, is equivalent to the sum of the resistance of resistors 64 and 66, R2+R3 , so that the starting pressure P₁ is P_L /2. A ratio ##EQU14## is then represented by ##EQU15##

The P₁ and P₂ reference voltages (68 and 70) are stored in a comparator 72 which compares these values to a signal from the pressure sensor 36. When the pressure sensor 36 signals that the pressure in the first chamber 20 has dropped to P₁, the comparator 72 activates the timer 34. When the pressure drops to P₂, the comparator 72 signals the timer 34 to stop.

Equation (9) can then be written as: ##EQU16## and since higher order terms are very small, Eq. (10) can be reduced to: ##EQU17## where S is a splitting ratio. ##EQU18## by reinserting ##EQU19## for K_ρ and, as in Eq. (5), ##EQU20## Equation (11) can be simplified to: ##EQU21## where K_x is a constant equal to ##EQU22## and C_f is a correction factor dependent on pipeline gas pressure, temperature, and composition. The second term ##EQU23## in Eq. (11) is an error correction term and is significant at high pressures. For methane gas, b is about 0.0024 and c is about 3.1×10-6 when pressure is measured in bars. If P_L is 30 bar (i.e. 440 psia), the error associated with the second term is about 0.25%.

The error associated by the second term ##EQU24## in Eq. (11) can be reduced by determining values for b and c. It is convenient to rewrite the second term ##EQU25## in terms of the third density virial coefficient C: ##EQU26##

The value of b can be determined by a second measurement at low absolute pressure. For low absolute pressure, the total derivative of pressure with respect to time ##EQU27## can be written in the form of Eq. (4) but neglecting the third viral coefficient c: ##EQU28## where P_Y1 is a low pressure. The sample gas 18 mass flow rates ω_m in Eqs. (4) and (13) are the same as selected by the flow controller 26. The second virial coefficient b can be estimated by combining and simplifying Eqs. (4) and (13): ##EQU29## where P₁ is the total pressure derivative at P₁ and P_Y1 is the total pressure derivative at low pressure. Equation (14) can be expressed in terms of pressures and time interval measurements: ##EQU30## where t_Y is the time interval for a pressure decay at low pressure (i.e. P_Y1 -P_Y2) and is determined in a manner similar to the internal t_m. There is no requirement that P_Y1 or P_Y2 be a specific pressure other than P_Y2 be less than P_Y1.

Equations (14) and (15) assume that the volume in which the pressure drops P₁ -P₂ and P_Y1 -P_Y2 occur is constant. This assumption is true if the pressure drops are both measured in the first chamber 20 (or in the first section 43 of the hollow coil 20' if the embodiment shown in FIG. 3 is used), but at different times.

Referring to FIG. 5, it may be preferable in some circumstances to use a second fixed-volume chamber 73 downstream of the first chamber 20 and measure the low pressure drop (P_Y1 -P_Y2) in the second chamber 73. In FIG. 5, the sample gas 18 pressure is reduced significantly as the sample gas 18 flows from the first chamber 20 to the second chamber 73 by an in-line pressure regulator 38. A third solenoid valve 71 is located in line between the pressure regulator 38 and the second chamber 73. A pressure sensor 69 measures the sample gas pressure in the second chamber 73. The timer 34 measures the time interval t_Y for the pressure to decay from P_Y1 to P_Y2 in the second chamber 73. An advantage of the of configuration shown in FIG. 5 is a reduction in waiting time for the sample gas pressure to decay to the low pressure P_Y1. If the configuration shown in FIG. 5 is used and the volume of the second chamber 73 is different than the volume of the first chamber 20 (or the volume of the first section 43 of the hollow coil 20' if the embodiment shown in FIG. 3 is used), Eqs. (14) and (15) should be replaced with: ##EQU31## where V is the volume of the first chamber 20 (or the volume of the first section 43 of the hollow coil 20' if the embodiment shown in FIG. 3 is used) and V_Y is the volume of the second chamber 73.

For the natural gas, which usually consists of 80% or more natural gas, the value of ##EQU32## in Eq. (12) can be approximated by a relationship in the form of KP² where K is a constant and P is pressure. In Table 1 are listed values of c and of ##EQU33## for pure methane and also for mixtures containing 80% methane each at 45° F. and 81° F. The values in Table 1 were obtained from published data, such as the Brugge Data from Texas A&M, and from interpolating the published data using thermodynamic mixing rules for virial coefficients.

TABLE 1
______________________________________
c        c         C/4(RT)2
C/4(RT)2
@280° K.
@300° K.
@280° K.
@300° K.
Mixture    cm6 /mol2
cm6 /mol2
106 acm-2
106 acm-2
______________________________________
Methane (CH4)
2649     2438      1.256  1.007
Ethane (C2 H6)
10774    10392
80% CH4 ;
3714     3463      1.761  1.431
20% C2 H6
Carbon Dioxide
5636     4927
(CO2)
80% CH4 ;
3130     2844      1.484  1.175
20% (CO2)
Nitrogen (N2)
1451     1443
80% CH4 ;
2371     2211      1.124  0.913
20% N2
______________________________________

The splitting ratio ##EQU34## is computed in real time by the control system 16 in accordance with Eq. (11). In the calculation, K_P, K_t, and V are constants stored within the control system 16 and the turbine frequency f_t, and the time interval t_m are communicated to the control system 16 for each sampling cycle 24. The second virial coefficient b is estimated by measuring the time interval t_Y for a pressure decay at low pressure and using Eq. (15) or (17), whichever is appropriate. The third virial coefficient c is estimated using data from Table 1. Finally, P_L is measured by the pressure sensor 36 and relayed to the control system 16.

Referring generally to FIG. 6, the method and apparatus described above can be used with the method and apparatus described hereafter, which is much like the method and apparatus for determining the energy content of the flow of pipeline gas that is described in U.S. Pat. No. 4,125,123 issued to Clingman on Nov. 14, 1978.

For saturated hydrocarbon gas, the amount of air required to completely combust gas at maximum flame temperature, i.e. stoichiometric combustion, is precisely proportional to the energy released during combustion. If the gas being combusted is a saturated hydrocarbon, the energy flow rate of the sample gas 18 is represented by: ##EQU35## where K_sto is the stoichiometric proportionalit_Y constant, and ω_air is the air flow rate. Likewise, the energy flow rate of the gas 12 through the pipeline 14 is represented by: ##EQU36## where S is the splitting ratio as defined in Eq. (11).

Equation (19) can be simplified to: ##EQU37## where K_x is a constant equal to ##EQU38## and C_f is a correction factor dependent on pipeline gas pressure, temperature, and composition.

In accordance with Eq. 19, the apparatus shown in FIG. 6 determines the energy flow rate of the pipeline gas 12 through the pipeline 14.

Referring in particular to FIG. 6, the sample gas 18 flows to a burner 74 at a flow rate maintained by the flow controller 26. Air is supplied to the burner 74 by an air hose 76 and the sample gas 18 is burned above the burner 74. A temperature sensor 78, which communicates to the control system 16, monitors flame temperature. The air flowing through the air hose 76 is monitored by an air mass flow meter 80. Air mass flow meters are old in the art and are accurate at ambient conditions. The air flow is adjusted by an air valve 82, which also communicates with the control system 16, until the sample gas 18 burns at maximum flame temperature. When the flame burns at the maximum flame temperature, the energy flow rate of the pipeline gas 12 can be determined.

The energy flow rate of the pipeline gas 12 is calculated in the control system 16 in accordance with Eq. (19). The value K_sto in Eq. (19) is a constant and stored in the control system 16. The splitting ratio S is computed for each sampling cycle 24 as described above. And, the air mass flow rate ω_air is measured by the air flow meter 80 and communicated to the control system 16 for each sampling cycle 24.

U.S. Pat. No. 4,125,123 issued to Clingman discloses a method for determining the energy content (energy/volume) of a pipeline gas at standard operating conditions. It is well known in the art that the volumetric flow rate adjusted for standard operating conditions can be determined by dividing energy flow rate (energy/time) by energy content (energy/volume).

Many modifications and variations of the preferred embodiment that are within the spirit and scope of the invention will be apparent to those with ordinary skill in the art.

Claims

1. An apparatus to be used with a linear flow meter to measure a ratio of a mass flow rate of a pipeline gas through a pipeline compared to a mass flow rate of a sample gas tapped from the pipeline, the apparatus comprising:

a chamber having a section with a fixed volume for containing the sample gas, the sample gas being maintained at substantially the same temperature as the pipeline gas in the pipeline when contained in the chamber section;

means for routing the sample gas to the chamber section;

a valve for controlling the flow of sample gas to the chamber section;

a flow controller for flowing the sample gas from the chamber section at a selected rate;

a pressure sensor for measuring the sample gas pressure in the chamber section;

means for closing the valve when the sample gas pressure in the chamber section reaches the pressure of the pipeline gas in the pipeline; and

a timer for measuring a time interval for the sample gas to flow from the chamber section at the selected rate beginning when the sample gas pressure in the chamber section drops below a first pressure, and ending when the sample gas pressure in the chamber section drops below a second pressure, the first pressure being greater than about one-half of the pipeline gas pressure in the pipeline and the second pressure being less than about one-half of the pipeline gas pressure in the pipeline; and

a controller which receives a signal from the timer and a signal from the linear flow meter representing the volumetric flow of the pipeline gas through the pipeline and derives the ratio of the mass flow rate of the pipeline gas through the pipeline compared to the mass flow rate of the sample gas.

2. An apparatus as recited in claim 1 further comprising means for quickly reducing the sample gas pressure in the chamber section from the pipeline gas pressure to the first pressure.

3. An apparatus as recited in claim 2 wherein the means for quickly reducing the sample gas pressure in the chamber section from the pipeline gas pressure to the first pressure comprises a second section in the chamber.

4. An apparatus as recited in claim 1 further comprising a pressure regulator for reducing the pressure of the sample gas before the sample gas flows to the flow controller.

5. An apparatus as recited in claim 1 wherein the controller calculates the mass flow ratio in accordance with the following function: ##EQU39## where K_x is a constant, f_t is a signal from linear flow meter, t_m is the time interval and C_f is a correction factor dependent on the pipeline gas pressure, temperature and composition.

6. An apparatus as recited in claim 5 further comprising a second chamber located such that the sample gas flows through the second chamber before it flows to the flow controller.

7. An apparatus to be used with a linear flow meter for measuring the energy flow rate of a pipeline gas through a pipeline, the apparatus comprising:

a chamber having a section with a fixed volume for containing the sample gas, the sample gas being maintained at substantially the same temperature as the pipeline gas in the pipeline when contained in the chamber section;

means for routing the sample gas to the chamber section;

a valve for controlling the flow of sample gas to the chamber section;

a flow controller for flowing the sample gas from the chamber section at a selected rate;

a pressure sensor for measuring the sample gas pressure in the chamber section;

means for closing the valve when the sample gas pressure in the chamber section reaches the pressure of the pipeline gas in the pipeline;

a timer for measuring a time interval for the sample gas to flow from the chamber section at the selected rate beginning when the sample gas pressure in the chamber section drops below a first pressure, and ending when the sample gas pressure in the chamber section drops below a second pressure, the first pressure being greater than about one-half of the pipeline gas pressure in the pipeline and the second pressure being less than about one-half of the pipeline gas pressure in the pipeline;

a sample gas energy flow rate meter for measuring the energy flow rate of the sample gas; and

a controller which receives a signal from the timer, the linear flow meter which represents the volumetric flow of the pipeline gas through the pipeline the sample gas energy flow rate meter and derives the energy flow rate of the pipeline gas through this pipeline.

8. An apparatus as recited in claim 7 wherein the sample gas energy flow rate meter comprises:

a burner for burning the sample gas with air to form a flame; and

means for maximizing the flame temperature.

9. An apparatus as recited in claim 8 further comprising an air mass flow meter for measuring the air mass flow rate of the air burning the sample gas.

10. An apparatus as recited in claim 9 wherein the controller calculates the energy flow rate in accordance with the following function: ##EQU40## where K_x is a constant, f_t is a signal from the linear flow meter, t_m is the time interval, ω_air is the air mass flow rate and C_f is a correction factor dependent on the pipeline gas pressure, temperature, and composition.

11. A method for measuring a mass flow ratio ##EQU41## of a pipeline gas through a pipeline compared to a sample gas tapped from the pipeline, the method comprising the steps of:

measuring the volumetric flow rate of the pipeline gas through the pipeline with a linear flow meter;

flowing the sample gas to a chamber having a section with a fixed volume;

maintaining the temperature of the sample gas at substantially the same temperature as the pipeline gas in the pipeline when the sample gas is in the chamber section;

stopping the flow of sample gas to the chamber section when the pressure in the chamber section reaches the pressure of the pipeline gas in the pipeline;

flowing the sample gas from the chamber section after the flow of the sample gas to the chamber section is stopped, thereby reducing the sample gas pressure in the chamber section;

timing the interval of time t_m for the sample gas to flow from the chamber section at a selected rate beginning when the sample gas pressure in the chamber section drops below a first pressure and ending when the sample gas pressure in the chamber section drops below a second pressure wherein the first pressure is greater than about one-half of the pipeline gas pressure in the pipeline and the second pressure is less than about one-half of the pipeline gas pressure in the pipeline; and

deriving the mass flow ratio ##EQU42## of the pipeline gas through the pipeline compared to the sample gas tapped from the pipeline from a signal f_t from the linear flow meter that is related to the volumetric flow rate of the pipeline gas, and the time interval t_m.

12. A method as recited in claim 11 wherein the mass flow ratio is derived in a control system.

13. A method as recited in claim 12 wherein the control system calculates the mass flow ratio in accordance with the following function: ##EQU43## where K_x is a constant, f_t is a signal from the linear flow meter, t_m is the time interval and C_f is a correction factor dependent on the pipeline gas pressure, temperature and composition.

14. A method as in claim 13 further comprising the steps of:

flowing the sample gas to a second chamber of fixed volume;

stopping the flow of sample gas to the second chamber when the pressure of the sample gas in the second chamber is greater than or equal to a third pressure;

flowing the sample gas from the second chamber after the flow of the sample gas to the second chamber is stopped, thereby reducing the sample gas pressure in the second chamber;

timing the interval of time for the sample gas to flow from the second chamber at the selected rate beginning when the sample gas pressure in the second chamber drops below a third pressure and ending when the sample gas pressure in the second chamber section drops below a fourth pressure; and

determining a value for the correction factor C_f in accordance with the following function: ##EQU44## where P_L is the pipeline gas pressure, c is estimated using data stored in the control system and b is estimated in accordance with the following function: ##EQU45## where v₁ is the volume of the chamber section, v₂ is the volume of the second chamber, P₁ is the first pressure, P₂ is the second pressure, P₃ is the third pressure, P₄ is the fourth pressure, t_m is the time interval for the pressure in the chamber section to drop from P₁ to P₂, and t_Y is the time interval for the pressure in the second chamber to drop from P₃ to P₄.

15. A method for measuring the energy flow rate of a pipeline gas through a pipeline, the method comprising:

measuring the volumetric flow rate of the pipeline gas through the pipeline with a linear flow meter;

flowing the sample gas to a chamber having a section with a fixed volume;

maintaining the temperature of the sample gas at substantially the same temperature as the pipeline gas in the pipeline when the sample gas is in the chamber section;

stopping the flow of sample gas to the chamber section when the pressure in the chamber section reaches the pressure of the pipeline gas in the pipeline;

flowing sample gas from the chamber section at a selected rate after the flow of sample gas to the chamber section is stopped, thereby reducing the sample gas pressure in the chamber section;

timing the interval of time t_m for the sample gas to flow from the chamber section at a selected rate beginning when the sample gas pressure in the chamber section drops below a first pressure and ending when the sample gas pressure in the chamber section drops below a second pressure wherein the first pressure is greater than about one-half of the pipeline gas pressure in the pipeline and the second pressure is less than about one-half of the pipeline gas pressure in the pipeline;

measuring the energy flow rate of the sample gas; and

determining the energy flow rate of the pipeline gas through the pipeline from a signal f_t from the linear flow meter that is related to the volumetric flow rate of the pipeline gas, the time interval t_m, and the energy flow rate of the sample gas.

16. A method as recited in claim 15 wherein the energy flow rate of the sample gas is measured by:

burning the sample gas flowing from the chamber with air; and

adjusting the air flow so that the sample gas burns at maximum flame temperature.

17. A method as recited in claim 15 wherein the energy flow rate of the pipeline gas is determined in a control system.

18. A method as recited in claim 17 further comprising the step of measuring the air mass flow rate of air burning the sample gas.

19. A method as recited in claim 18 wherein the control system calculates the energy flow rate in accordance with the following function: ##EQU46## where K_x is a constant, f_t is a signal form the linear flow meter, t_m is the time interval, ω_air is the air mass flow rate and C_f is a correction factor dependent on the pipeline gas pressure, temperature and composition.

20. A method as recited in claim 19 further comprising the steps of:

flowing the sample gas to a second chamber of fixed volume;

stopping the flow of sample gas to the second chamber when the pressure of the sample gas in the second chamber is greater than or equal to a third pressure;

flowing the sample gas from the second chamber after the flow of the sample gas to the second chamber is stopped, thereby reducing the sample gas pressure in the second chamber;

timing the interval of time for the sample gas to flow from the second chamber at the selected rate beginning when the sample gas pressure in the second chamber drops below a third pressure and ending when the sample gas pressure in the second chamber section drops below a forth pressure; and

determining a value for the correction factor C_f in accordance with the following function: ##EQU47## where P_L is the pipeline gas pressure, c is estimated using data stored in the control system and b is estimated in accordance with the following function: ##EQU48## where v₁ is the volume of the chamber section, v₂ is the volume of the second chamber, P₁ is the first pressure, P₂ is the second pressure, P₃ is the third pressure, P₄ is the fourth pressure, t_m is the time interval for the pressure in the chamber section to drop from P₁ to P₂, and t_Y is the time interval for the pressure in the second chamber to drop from P₃ to P₄.

21. An apparatus that measures a ratio of a mass flow rate of a pipeline gas through a pipeline compared to a mass flow rate of a sample gas tapped from the pipeline for use with a linear flow meter measuring the volumetric flow of the pipeline gas through the pipeline, the apparatus comprising:

a chamber having a section with a fixed volume for containing the sample gas, the sample gas being maintained at substantially the same temperature as the pipeline gas in the pipeline when contained in the chamber section;

a pressure sensor for measuring the pressure of the sample gas in the chamber section;

a first line connected to the pipeline for routing the sample gas to the chamber section;

a valve mounted in the first line for controlling the flow of the sample gas to the chamber section;

a flow controller for flowing the sample gas from the chamber at a selected rate;

a second line for routing the sample gas away from the chamber to the flow controller;

a control for closing the valve when the sample gas pressure in the chamber section reaches the pressure of the pipeline gas in the pipeline;

a timer for measuring a time interval for the sample gas to flow from the chamber section at the selected rate beginning when the sample gas pressure in the chamber section drops below a first pressure, and ending when the sample gas pressure in the chamber section drops below a second pressure, the first pressure being greater than about one-half of the pipeline gas pressure in the pipeline and the second pressure being less than about one-half of the pipeline gas pressure in the pipeline;

a third line for routing the sample gas away from the flow controller; and

a control system for receiving signals from the pressure sensor, the timer and the linear flow meter and for computing the ratio of the mass flow rate of the pipeline gas through the pipeline compared to the mass flow rate of the sample gas.

22. An apparatus as recited in claim 21 further comprising a second chamber of fixed volume located in the second line so that the sample gas flows through the second chamber before it flows to the flow controller.

23. An apparatus as recited in claim 22 further comprising a pressure regulator located in the second line for reducing the sample gas pressure before the sample gas flows to the second chamber.

24. An apparatus as recited in claim 21 wherein the chamber has a second section located downstream of the chamber section with the fixed-volume and further comprising a second valve for controlling the flow of the sample gas from the fixed-volume chamber section to the second chamber section.

25. An apparatus for measuring the energy flow rate of a pipeline gas through a pipeline, the apparatus to be used with a linear flow meter measuring the volumetric flow of the pipeline gas through the pipeline, the apparatus comprising:

a chamber having a section with a fixed volume for containing the sample gas, the sample gas being maintained at substantially the same temperature as the pipeline gas in the pipeline when contained in the chamber section;

a pressure sensor for measuring the pressure of the sample gas in the chamber section;

a first line connected to the pipeline for routing the sample gas to the chamber section;

a valve mounted in the first line for controlling the flow of the sample gas to the chamber section;

a flow controller for flowing the sample gas from the chamber at a selected rate;

a second line for routing the sample gas away from the chamber to the flow controller;

a control for closing the valve when the sample gas pressure in the chamber section reaches the pressure of the pipeline gas in the pipeline;

a timer for measuring a time interval for the sample gas to flow from the chamber section at the selected rate beginning when the sample gas pressure in the chamber section drops below a first pressure, and ending when the sample gas pressure in the chamber section drops below a second pressure, the first pressure being greater than about one-half of the pipeline gas pressure in the pipeline and the second pressure being less than about one-half of the pipeline gas pressure in the pipeline;

a burner for burning the sample gas with an air flow to form a flame;

a third line for routing the sample gas away from the flow controller to the burner;

a temperature sensor for measuring the flame temperature;

an air conduit for routing the air flow to the burner;

an air valve located in the air conduit for adjusting the air flow through the air conduit;

an air mass flow meter for measuring an air mass flow rate through the air conduit; and

a control system for receiving signals from the pressure sensor, the timer, the linear flow meter, the air mass flow meter and the temperature sensor, for communicating with the air valve to adjust the air flow so that the flame burns at the maximum temperature, and for computing the energy flow rate of the pipeline gas flowing through the pipeline.

26. An apparatus as recited in claim 25 further comprising a second chamber of fixed volume located in the second line so that the sample gas flows through the second chamber before it flows to the flow controller.

27. An apparatus as recited in claim 26 further comprising a pressure regulator located in the second line for reducing the sample gas pressure before the sample gas flows to the second chamber.

28. An apparatus as recited in claim 25 wherein the chamber has a second section located downstream of the chamber section with the fixed-volume and further comprising a second valve for controlling the flow of the sample gas from the fixed-volume chamber section to the second chamber section.

29. An apparatus to be used with a linear flow meter to measure a ratio of a mass flow rate of a pipeline gas through a pipeline compared to a mass flow rate of a sample gas tapped from the pipeline, the apparatus comprising:

a chamber having a section with a fixed volume v for containing the sample gas, the sample gas being maintained at substantially the same temperature as the pipeline gas in the pipeline when contained in the chamber section;

means for routing the sample gas to the chamber section;

a valve for controlling the flow of sample gas to the chamber section;

a flow controller for flowing the sample gas from the chamber section at a selected rate;

a pressure sensor for measuring the sample gas pressure in the chamber section;

means for closing the valve when the sample gas pressure in the chamber section reaches the pressure P_L of the pipeline gas in the pipeline; and

means for determining a time rate of change of pressure in the chamber section for a condition where the pressure in the chamber section is about one-half of pressure P_L of the pipeline gas in the pipeline ##EQU49## a control system which receives a signal f_t representing volumetric flow through the pipeline from the linear flow meter, and signals from the pressure sensor, and computes the ratio ##EQU50## of the mass flow rate of the pipeline gas through the pipeline compared to the mass flow rate of the sample gas by the following relationship: ##EQU51## where K_t is a calibration constant for the linear flow meter, b is a second pressure virial coefficient of the gas and c is a third pressure virial coefficient of the gas.

30. A method for measuring a mass flow ratio ##EQU52## of a pipeline gas through a pipeline compared to a sample gas tapped from the pipeline, the method comprising the steps of:

measuring the volumetric flow rate of the pipeline gas through the pipeline with a linear flow meter;

flowing the sample gas to a chamber having a section with a fixed volume v;

maintaining the temperature of the sample gas at substantially the same temperature as the pipeline gas in the pipeline when the sample gas is in the chamber section;

stopping the flow of sample gas to the chamber section when the pressure in the chamber section reaches the pressure P_L of the pipeline gas in the pipeline;

flowing the sample gas from the chamber section after the flow of the sample gas to the chamber section is stopped, thereby reducing the sample gas pressure in the chamber section;

determining the time rate of change of pressure in the chamber section for a condition where the pressure in the chamber section in about one-half of pressure P_L of the pipeline gas in the pipeline ##EQU53## and deriving the mass flow ratio ##EQU54## of the pipeline gas through the pipeline compared to the sample gas tapped from the pipeline by solving the following relationship: ##EQU55## where f_t is a signal from the linear flow meter representing the volumetric flow rate of the gas through the pipeline, K_t is a calibration constant for the linear flow meter, b is a second virial coefficient of the gas, and c is a third virial coefficient of the gas.

31. A method for monitoring the energy flow rate of a pipeline gas through a pipeline and representing the flow of the pipeline gas in terms of an adjusted volumetric flow rate which corresponds to a volumetric flow rate at a defined pressure and temperature, the method comprising:

measuring the volumetric flow rate of the pipeline gas through the pipeline with a linear flow meter;

flowing sample gas to a chamber having a section with a fixed volume;

maintaining the temperature of the sample gas at substantially the same temperature as the pipeline gas in the pipeline when the sample gas is in the chamber section;

stopping the flow of sample gas to the chamber section when the pressure in the chamber section reaches the pressure of the pipeline gas in the pipeline;

flowing sample gas from the chamber section at a selected rate after the flow of sample gas to the chamber section is stopped, thereby reducing the sample gas pressure in the chamber section;

timing the interval of time t_m for the sample gas to flow from the chamber section at a selected rate beginning when the sample gas pressure in the chamber section drops below the first pressure and ending when the sample gas pressure in the chamber section drops below a second pressure;

measuring the energy flow rate of the sample gas;

measuring the energy content per unit volume of the sample gas; and

determining the adjusted volumetric flow rate of the pipeline gas through the pipeline from the volumetric flow rate of the pipeline gas measured by the linear meter, the time interval t_m, the energy flow rate of the sample gas, and the energy content per unit volume of the sample gas.

32. An apparatus to be used with a control system and a linear flow meter measuring a volumetric flow rate of a pipeline gas flowing through a pipeline, for monitoring the energy flow rate of the pipeline gas through the pipeline and representing the flow of the pipeline gas in terms of an adjusted volumetric flow rate that corresponds to a volumetric flow rate at a defined pressure and temperature, the apparatus comprising:

a chamber having a section with a fixed volume for containing the sample gas, the sample gas being maintained at substantially the same temperature as the pipeline gas in the pipeline when contained in the chamber section;

means for routing the sample gas to the chamber section;

a valve for controlling the flow of sample gas to the chamber section;

a flow controller for flowing the sample gas from the chamber section at a selected rate;

a pressure sensor for measuring the sample gas pressure in the chamber section;

means for closing the valve when the sample gas pressure in the chamber section reaches the pressure of the pipeline gas in the pipeline;

a timer for measuring a time interval for the sample gas to flow from the chamber section at the selected rate beginning when the sample gas pressure in the chamber section drops below a first pressure and ending when the sample gas pressure in the chamber section drops below a second pressure;

a sample gas energy flow rate meter for measuring the energy flow rate of the sample gas; and

means for determining the energy content per unit volume of the sample gas;

wherein the control system calculates the adjusted volumetric flow rate of the pipeline gas through the pipeline from the volumetric flow rate measured by the linear flow meter, the time interval, the energy flow rate of the sample gas, and the energy content per unit volume of the sample gas.

33. An apparatus to be used with a linear flow meter to measure a ratio of a mass flow rate of a pipeline gas through a pipeline compared to a mass flow rate of a sample gas tapped from the pipeline, the apparatus comprising:

a chamber having a section with a fixed volume for containing the sample gas, the sample gas being maintained at substantially the same temperature as the pipeline gas in the pipeline when contained in the chamber section;

means for routing the sample gas to the chamber section;

a valve for controlling the flow of sample gas to the chamber section;

a flow controller for flowing the sample gas from the chamber section at a selected rate;

a pressure sensor for measuring the sample gas pressure in the chamber section;

means for closing the valve when the sample gas pressure in the chamber section reaches the pressure of the pipeline gas in the pipeline; and

a timer for measuring a time interval for the sample gas to flow from the chamber section at the selected rate beginning when the sample gas pressure in the chamber section drops below a first pressure, and ending when the sample gas pressure in the chamber section drops below a second pressure, the first pressure being equal to one-half of the pipeline gas pressure in the pipeline and the second pressure being less than the first pressure; and

a controller which receives a signal from the timer and a signal from the linear flow meter representing the volumetric flow of the pipeline gas through the pipeline and derives the ratio of the mass flow rate of the pipeline gas through the pipeline compared to the mass flow rate of the sample gas.

34. An apparatus to be used with a flow meter that generates a signal representing flow rate of gas in a pipeline, said apparatus measuring a ratio of a mass flow rate of the gas in the pipeline to a mass flow rate of a sample gas tapped from the pipeline, the apparatus comprising:

a chamber having a known volume for receiving the sample gas, the sample gas being maintained at substantially the same temperature as the pipeline gas;

means for controlling the flow of the sample gas from said chamber, said means generating at least one signal indicative of mass flow rate of the sample gas; and

a controller which receives the signal from the flow meter and at least one signal from the means for controlling the flow of the sample gas, said controller being operable in response thereto, to calculate the ratio of the mass flow rate of the gas through the pipeline to the mass flow rate of the sample gas. 35. An apparatus as recited in claim 34, further comprising means for reducing the sample gas pressure in the chamber from a pipeline gas pressure to a pressure for measuring mass flow rate of the sample gas. 36. An apparatus as recited in claim 35, wherein the means for reducing the sample gas pressure comprises a second chamber communicating with said first-mentioned chamber. 37. An apparatus as recited in claim 36, further comprising a pressure regulator in a path of flow between the first-mentioned chamber and the second chamber for reducing the pressure of the sample gas before the sample gas flows to a flow controller. 38. An apparatus as recited in claim 34, wherein the gas in the pipeline is at pipeline pressure, and wherein the means for controlling the flow of the sample gas generates at least one signal indicative of a time interval in response to a decrease in pressure of the sample gas in the chamber from a first predetermined pressure to a second predetermined pressure, wherein said first predetermined pressure is greater than one-half of the pipeline pressure and wherein said second predetermined pressure is less than one-half of the pipeline pressure. 39. A method for measuring the energy flow of a gas through a pipeline, the method comprising:

measuring the volumetric flow rate of gas through the pipeline;

capturing in a chamber of predetermined volume, a sample of the gas in the pipeline at substantially the same temperature and pressure as the gas in the pipeline;

measuring the energy contained in the sample of the gas in the chamber of predetermined volume;

calculating the energy flow of gas in the pipeline in response to the volumetric flow rate of pipeline gas in the pipeline, and in response to the energy measured in the sample of the gas from the pipeline.

40. The method of claim 39, wherein the step of measuring the volumetric flow rate of gas through the pipeline further comprises:

measuring a ratio of the mass flow rate of gas in the pipeline to the mass flow rate of the sample of gas in the chamber of predetermined volume by:

flowing at least a portion of the sample of gas out of the chamber of predetermined volume; and

measuring a time interval (t_m) corresponding to a predetermined pressure change, said pressure change resulting from the flowing of the portion of the sample of gas out of the chamber. 41. The method of claim 39, wherein the step of measuring the volumetric flow rate of gas through the pipeline further comprises measuring a signal (f_t) from a turbine flow meter in the pipeline and multiplying by a constant (K_t) to determine the volumetric flow rate of the pipeline gas in the pipeline. 42. The method of claim 41, wherein the step of measuring the energy contained in the sample of gas includes the step of measuring the volume of air required to combust the sample of gas at a maximum flame temperature. 43. The method of claim 39, wherein the step of measuring the energy contained in the sample of the gas in the chamber of predetermined volume further includes measuring the energy flow rate of the sample of gas flowed out of the chamber of predetermined volume. 44. The claim of claim 43, wherein the step of measuring the energy flow rate of the sample of gas further includes the steps of:

burning said sample of the gas with air; and

adjusting the flow of the air to obtain maximum flame temperature; and

measuring the flow rate of air (ω_air) at maximum flame

temperature. 45. The method of claim 44, wherein the step of measuring volumetric flow rate further comprises:

measuring a ratio of the mass flow rate of gas in the pipeline to the mass flow rate of the sample of gas in the chamber of predetermined volume by:

flowing at least a portion of the sample of gas out of the chamber of predetermined volume; and

measuring a time interval (t_m) corresponding to a predetermined pressure change, said predetermined pressure change resulting from the flowing of the portion of the sample of gas out of the chamber.

46. The method of claim 45, wherein the step of measuring the volumetric flow rate of the pipeline gas further comprises the step of adjusting the volumetric flow rate of the pipeline gas to standard operating conditions in response to the ratio of the mass flow rates, and in response to the flow rate of air (ω_air) at maximum flame

temperature. 47. Apparatus for measuring the energy flow of a gas through a pipeline, the apparatus comprising:

a pipeline flow meter that measures the volumetric flow rate of gas through the pipeline and generates a signal indicative thereof;

means including a chamber of predetermined volume for receiving a sample of the gas in the pipeline at substantially the same temperature as the gas in the pipeline;

means for combusting the sample of the gas from the chamber of predetermined volume and generating a signal indicative of energy content of said sample of gas;

wherein said chamber receives successive samples of gas and wherein said samples are combusted by said means for combusting; and

means responsive to the signals from the pipeline flow meter and from the combusting means for calculating the energy flow of gas in the pipeline.