A transparent substrate and a method of producing the same suitable especially for an optical system for an optical data recording medium using a linearly polarized light as a data reading light such as magneto-optical recording medium drive unit and an optical data recording medium for reading data using a linearly polarized light.
|
16. A method of producing an optical data recording medium comprising the step of molding a transparent substrate by injecting a melt plastic material to die surfaces with a part of the cavity surface thereof formed by the signal side of a stamper, wherein said die is formed with a cold slug well and has a gate width less than 1 mm, said melt plastic material being injected at a low rate first rates in the beginning and end of injection and at a high second rate during intermediate time, the the first rates being smaller than the second rate.
1. An optical data recording medium comprising a transparent substrate, and a selected one of a recording film and a reflection film on one side of the transparent substrate for recording and/or reproducing data by radiating a light beam on said selected one of the recording film and the reflection film, wherein a given principal dielectric axis of the transparent substrate is set in regular manner within ±5 degrees of at least a selected one of the direction parallel, perpendicular and 45 degrees to a scanning direction of the light beam.
0. 28. A method of producing an optical data recording medium, comprising a step of molding a transparent plastic substrate by injecting a molten plastic material into a die cavity of an injecting die, the infecting die having an injecting gate for injecting molten plastic material into the die cavity, the die cavity having a die cavity surface, the die cavity surface including a signal information recording pattern side of a stamper, wherein a temperature of said molten plastic material passing through said injecting gate is so controlled as to attain a viscosity of the molten plastic material of less than 2000 poise.
0. 36. An optical data recording medium, comprising at least one layer, said at least one layer including a recording film or reflecting film, on a surface of a transparent substrate, said recording medium being adapted to have a linearly polarized light irradiated thereon, from the transparent substrate side, for reproducing information, wherein a signal-to-noise ratio of a reproduced signal from said optical data recording medium becomes a local maximum when a plane of polarization of the linearly polarized light is selected in one of a direction parallel, perpendicular or 45°C to a principal dielectric axis of the transparent substrate.
0. 22. A method of producing an optical data recording medium, comprising a step of molding a transparent substrate by injecting a molten plastic material into a die cavity of an injecting die, the injecting die having an injecting gate, said die cavity having a die cavity surface, with a part of the cavity surface thereof being formed of a signal side of a stamper, wherein said injecting die is provided with said injecting gate connected to said cavity at a center of said cavity, in plan view, and a sprue is connected to said cavity; wherein a temperature distribution along the cavity surface around the sprue is not more than ±5°C C.; and wherein a temperature Tc of the cavity surface of said die is so adjusted that Tg-80≦Tc≦Tg, where Tg is a glass transition temperature of the plastic material.
0. 29. A method of producing an optical data recording medium, including a step of molding a transparent plastic substrate by injecting a molten plastic material into a die cavity of an injecting die, the injecting die having an injecting gate, said die cavity having a die cavity surface, with a part of the die cavity surface including a signal information recording pattern side of a stamper, the injecting gate being connected to the die cavity for injecting molten plastic material into the die cavity through the injecting gate, wherein the injecting gate has a gate width of less than 1 mm, said molten plastic material is injected into the cavity in 0.2-1 sec, and a principal dielectric axis of the transparent plastic substrate formed is aligned with a reference direction or perpendicular to said reference direction.
10. An optical data recording system comprising:
an optical data recording medium including a transparent substrate; and a selected one of a recording film and a reflection film on one side of the transparent substrate for recording and/or reproducing data by radiating a light beam on said selected one of the recording film and the reflection film, said transparent substrate having a reference principal dielectric axis that is arranged regularly in a desired direction and an optical unit for emitting a linearly polarized light beam as said light beam, wherein the principal dielectric axis of the transparent substrate of the optical data recording medium a plane of polarization of said linearly polarized light beam is set within ±5 degrees of at least one of the directions parallel, perpendicular and 45 degrees to a scanning direction of said light beam the principal dielectric axis of the transparent substrate of the optical data recording medium.
0. 33. A method of producing an optical data recording medium, comprising a step of molding a transparent substrate by injecting a molten plastic material into a die cavity of an injecting die, the injecting die having an injecting gate for injecting molten plastic material, into the die cavity, the die cavity having a die cavity surface, the die cavity surface having a part thereof formed by a signal side of a stamper, wherein said injecting die further includes a sprue connected to said injecting gate and provided at a center of the cavity surface, in plan view; wherein a temperature distribution along a circumference of the cavity surface, around the sprue, is not more than ±5°C C.; and wherein a temperature Tc of the cavity surface is so adjusted to satisfy the relation Tg-80≦Tc≦Tg, where Tg is a glass transition temperature of the plastic material.
0. 21. An optical data recording system comprising:
an optical data recording medium including a transparent substrate in the form of a disk, whereby the recording medium is an optical data recording disk, and a selected one of a recording film and a reflection film on one side of the transparent substrate for recording and/or reproducing data by radiating a linearly polarized light beam on said selected one of the recording film and the reflection film, a given principal dielectric axis of the transparent substrate being set within ±3 degrees of each of a radial direction and a circumferential direction of the transparent substrate in the form of a disk; and an optical unit for emitting a linearly polarized light as said light beam, wherein a plane of polarization of said linearly polarized light beam is set within ±5 degrees of a selected one of directions parallel, perpendicular and 45 degrees to the principal dielectric axis of the transparent substrate of the optical data recording medium.
0. 17. An optical data recording system comprising:
an optical data recording medium including a transparent substrate in the form of a disk, whereby the recording medium is an optical data recording disk, and a selected one of a recording film and a reflection film on one side of the transparent substrate for recording and/or reproducing data by radiating a linearly polarized light beam on said selected one of the recording film and the reflection film, a given principal dielectric axis of the transparent substrate being set within ±3 degrees of at least one of a radial direction, a circumferential direction and a direction of thickness of the transparent substrate; and an optical unit for emitting a linearly polarized light as said light beam, wherein a plane of polarization of said linearly polarized light beam is set within ±5 degrees of a selected one of directions parallel, perpendicular and 45 degrees to the principal dielectric axis of the transparent substrate of the optical data recording medium.
0. 19. An optical data recording system comprising:
an optical data recording medium including a transparent substrate in the form of a disk, whereby the recording medium is an optical data recording disk, and a selected one of a recording film and a reflection film on one side of the transparent substrate for recording and/or reproducing data by radiating a linearly polarized light beam on said selected one of the recording film and the reflection film, a given principal dielectric axis of the transparent substrate being set within ±3 degrees of at least one of a radial direction, a circumferential direction and a direction 45 degrees to the radial direction of the transparent substrate in the form of a disk; and an optical unit for emitting a linearly polarized light as said light beam, wherein a plane of polarization of said linearly polarized light beam is set within ±5 degrees of a selected one of directions parallel, perpendicular and 45 degrees to the principal dielectric axis of the transparent substrate of the optical data recording medium.
0. 20. An optical data recording system comprising:
an optical data recording medium including a transparent substrate that is rectangular and in the form of a card, whereby the recording medium is an optical data recording card, and a selected one of a recording film and a reflection film on one side of the transparent substrate for recording and/or reproducing data by radiating a linearly polarized light beam on said selected one of the recording film and the reflection film; wherein the rectangular transparent substrate has an outer peripheral longitudinal line; and wherein a given principal dielectric axis of the transparent substrate is set within ±3 degrees of at least a selected one of a direction parallel to the outer peripheral longitudinal line, a direction perpendicular to the direction parallel to the outer peripheral longitudinal line, and a direction 45 degrees to the direction parallel to the outer peripheral longitudinal line of the transparent substrate; and an optical unit for emitting a linearly polarized light as said light beam, wherein a plane of polarization of said linearly polarized light beam is set within ±5 degrees of a selected one of directions parallel, perpendicular and 45 degrees to the principal dielectric axis of the transparent substrate of the optical data recording medium.
0. 34. An optical data recording medium having at least one layer, said at least one layer including a recording film or reflecting film, on a surface of a transparent substrate, said recording film or reflecting film being adapted to reproduce a recorded information by irradiating a linearly polarized light, as a data reading light, at said recording film or reflecting film, from the transparent substrate side of the medium; and wherein a shift of direction of the irradiating linearly polarized light, due to the transparent substrate, is β in formula (
where δ is a retardation by a single pass of said linearly polarized light, generated by birefringence of the transparent substrate, and θk (in degrees) is a magneto-optical rotational angle (Kerr rotational angle) of a reflected light from said recording film or reflecting film, obtained by irradiating the recording film or the reflecting film with the linearly polarized light.
2. An optical data recording medium according to
3. An optical data recording medium according to
4. An optical data recording medium according to
5. An optical data recording medium according to
6. An optical data recording medium according to
7. An optical data recording medium according to
8. An optical data recording medium according to
9. An optical data recording medium according to
11. An optical data recording system according to
12. An optical recording system according to
13. An optical data recording system according to claim 16 10, wherein the transparent substrate is in the form of a disk, whereby the recording medium is an optical data recording disk.
14. An optical data recording system according to
15. An optical data recording system according to
0. 18. An optical data recording system according to
0. 23. A method of producing an optical data recording medium according to
0. 24. A method of producing an optical data recording medium according to
0. 25. A method of producing an optical data recording medium according to
0. 26. A method of producing an optical data recording medium according to
0. 27. A method of producing an optical data recording medium according to
0. 30. A method of producing an optical data recording medium according to
0. 31. A method of producing an optical data recording medium according to
0. 32. A method of producing an optical data recording medium according to
0. 35. An optical data recording medium according to
0. 37. An optical data recording medium according to
0. 38. An optical data recording medium according to
|
A first embodiment of the present invention is shown in
The disk-shaped recording medium, as shown in
The transparent substrate 2 is formed by injection-molding polycarbonate resin or acrylic resin or polyalkyl methacrylic resin or the like thermoplastic resin. The signal pattern 1 is transferred in spiral or concentric form around the rotational center of the disk-shaped recording medium on one side of the transparent substrate 2 at the same time as the injection molding of the transparent substrate 2. This transparent substrate 2 has a principal dielectric axis extending radially (direction x--x) and in the direction (direction y--y) perpendicular thereto of the transparent substrate 2 as shown in FIG. 1. The direction y--y is along the direction of scanning of the light beam against the disk recording medium, along which the signal pattern is formed. The directions of the principal dielectric axis, as shown in detail in
The recording film 3 is formed with a given recording material well known as a magneto-optical recording film, a phase-change type recording film or a write once type recording film. Also, in the case of a read-only disk such as a compact disk, the recording film may be replaced with a reflection film.
The transparent substrate for an optical data recording medium according to the present invention is preferably used especially for an optical data recording medium such as a magneto-optical recording medium with linearly polarized light as a data reading light. Such an alloy as TeFeCo may be used as a magneto-optical recording material. The recording film 3 may of course be configured, instead of a single layer of a magneto-optical recording material, of a lamination of this magneto-optical recording material and an enhancement film for improving the reproduction sensitivity or a lamination of these materials and a protective film with equal effect.
In the optical data recording medium according to the first embodiment described above, the principal dielectric axis of the transparent substrate is adjusted within ±5 degree or less or preferably ±3 degree to the direction of scanning the light beam against the optical data recording medium or the direction perpendicular thereto or to a direction at 45 degree to the scanning direction of the light beam. If the polarization plane of the recording/reproducing light is adjusted to the scanning direction of the light beam or the direction perpendicular thereto or a direction 45 degree to the scanning direction of the light beam, the deviation of the polarization plane of the recording/reproducing light from the principal dielectric axis of the transparent substrate is capable of being set in a range within ±5 degree, or preferably ±3 degree. As a result, practical application is realized of a drive unit that can read data at a high S/N ratio from an optical data recording medium having a transparent substrate made of a high retardation material.
Explanation will now be made about a method of producing the transparent substrate 2 according to the first embodiment.
The side of the fixed die 11 facing the movable die 12 is formed with a recess 14 making up a part of the cavity. A sprue 16 communicating with an injection port 15 is formed at the central part of the recess 14.
The side of the movable die 12 facing the fixed die 11 is mounted with a stamper 17 carrying a pattern reverse to the signal pattern desired for transfer to the transparent substrate. The center of the reverse pattern is fixed on the stamper holder 18 in such a manner as to register with the center of the recess 14. The stamper 17 and the recess 14 combine to form a donut-shaped cavity 19 in plain view.
The punch 13 is slidably mounted on the part of the movable die 12 facing the sprue 16. A center gate 20 is configured by appropriately adjusting the clearance d between the forward outer peripheral part of the punch 13 and the inner surface of the recess 14. The thickness of the center gate 20 is adjusted to 1 mm or less, or preferably to 0.1 mm to 0.6 mm. The forward inner peripheral part of the punch 13, on the other hand, is formed with a cold slug well 21 as a recess for storing the low-temperature melt plastic in initial stages of injection. The capacity of this cold slug well 21, which is preferably large for aligning the principal dielectric axes, is more preferably in the range from ½ to 1/7, or most preferably 1/5 of the capacity of the sprue 16 in order to reduce fuel loss for heating the resin material and the dies.
Before the melt plastic is injected into the cavity 19, the resin temperature is controlled to attain 500 to 2000 poise of viscosity of the melt plastic material. Also, the temperature of the dies 14 and 17 are adjusted in such a manner that the temperature distribution along the circumference of the cavity surfaces 14, 17 around the sprue 16 is not more than ±5°C C., and that the temperature Tc of the cavity surfaces 14, 17 of the dies holds the relations Tg -80≦Tc≦Tg where Tg is the transmission temperature of the resin.
The melt plastic is not necessary injected into the cavity 19 at a fixed rate from start and end of injection, but may be subjected to a multi-stage injection rate control as described below. First, the melt plastic material is injected at a comparatively low rate, and the resin cooled while being passed through the sprue 16 is stored in the cold slug well 21. Then, the resin is injected at a comparatively high rate in order to prevent the resin temperature from decreasing while the melt plastic material is being filled in the cavity 19. Finally, the injection rate is reduced in order to prevent backlash of resin at the cavity end. This multi-stage control of injection rate is not limited to three stages described above, but any desired number of stages may be set as required. For the purpose of improved productivity, however, it is desirable to set the injection rate to 0.2 to 1.0 sec in any case.
In
As obviously seen from this graph, the transparent substrate according to the present invention has a deviation of the principal dielectric axis from the radial line not more than ±1 degree along the inner and outer peripheries. In contrast, the transparent substrate of the first cited case is such that one of the two examples has a deviation of the principal dielectric axis not more than ±2 degree from the radial line, while the other example has a deflection as much as ±2.5 degree. In the case of the transparent substrate of the second cited case, the deviation of the principal dielectric axis from the radial line reaches about ±3.5 degree. It will therefore be understood that the transparent substrate of the present invention facilitates the adjustment of the polarization plane of the reading light, thereby making it possible to reduce the S/N ratio of the detection signal.
A second embodiment of the present invention is shown in FIG. 6. In the second embodiment, the present invention is applied to a card-like recording medium.
This card-like recording medium has a part of the transparent substrate 32 carrying a predetermined indication 31 or the like as shown in
This card-like recording medium is scanned in the longitudinal direction of the transparent substrate 3 (direction x--x), along which the signal pattern is formed. The principal dielectric axis of this transparent substrate 32 is allowed in the range of ±5 degree, or preferably ±3 degree around the longitudinal direction (direction x--x) of the transparent substrate 32 or the direction perpendicular thereto (direction y--y). The same transparent substrate material and recording film material as in the first embodiment described above may be used in the embodiment under consideration.
The optical data recording medium according to the second embodiment explained above has the same effect as that according to the first embodiment.
A method of producing the transparent substrate 32 according to the second embodiment will be explained below.
The side of the fixed die 41 that faces the die 42 is formed with a rectangular recess 44 in plan view making up a part of the cavity. The part of the gate member 43 which communicates with an end of the recess 44 is formed with a sprue 46 extending from the injection port 45.
The side of the movable die 42 facing the fixed die 41 is mounted with a stamper 47 formed with an inverted pattern of the desired information recording pattern to be transferred to the transparent substrate. This stamper 47 and the recess 44 combine to make up a rectangular cavity 48 in plan view.
The gate member 43 is arranged on the resin injection side of the movable die 42, and has a cold slug well 49 formed as a recess at the part thereof facing the sprue 46. The part of the gate member 43 that is in contact with the movable die 42 and the inner surface of the recess 44 of the fixed die 41 make up a gate 50.
The temperature conditions of the dies 41, 42 the temperature conditions of the melt plastic material injected into the dies 41, 42, the gate thickness d, capacity of the cold slug well 49 and the injection rate in multi-stage control, are all set in the same manner as in the first embodiment.
Variations in principal dielectric axis were compared among the transparent substrate (the invention) according to the second embodiment molded using a die of
Now, explanation will be made of an embodiment of an optical system for an optical data recording medium in which data is optically recorded and or reproduced by use of an optical data recording medium prepared from a transparent substrate of resin according to the above-mentioned mentioned embodiment. An optical circuit of an optical system for an optical data recording medium according to the present invention is shown in the diagram of FIG. 8. As shown in the diagram, the optical circuit of the optical system for the optical data recording medium according to the present invention includes an incident path 55 mainly having a laser 51, a half prism 52, a converging lens 53 and an optical data recording medium 54, and a reflection path 58 having the optical data recording medium 54, a converging lens 53, a half prism 52, a polarization beam splitter 56 and detectors 57, 57a.
The laser 51 takes the form of a semiconductor laser or a laser equipped with a linear polarizer. The linearly polarized light is radiated to the optical data recording medium 54 through the incident light path 55.
The optical data recording medium 54, on the other hand, is formed of a recording film (magnetic film) 54b on one side of the transparent substrate 2 (32), and is arranged on the incident light path 55 in such a manner that the transparent substrate 2 (32) faces the converging lens 53 with the recording film 54b disposed on the back of the converging lens 53. The transparent substrate 2 (32) may take the form of a material very small in retardation such as glass or epoxy resin an injection mold of a thermoplastic resin, very large in retardation such as polycarbonate resin, acrylic resin or polyalkyl methacrylic resin.
The converging lens 53 is arranged in such a way that the linearly polarized light entering from the incident light path 55 is focused on the recording film 54b of the optical data recording medium 54.
In the incident light path 55 configured as above, the plane of polarization of the linearly polarized light radiated from the laser 51 is adjusted in such direction as to reduce the noise component of the detection signal attributable to the retardation taking the direction of the principal dielectric axis of the transparent substrate 2 (32) into consideration. Specifically, the plane of polarization of the linearly polarized light is adjusted to a direction parallel, perpendicular or 45 degree to the principal dielectric axis of the transparent substrate 2 (32). In this way, the noise component of the detection signal attributable to the retardation is reduced to zero. Even in a highgrade system, the intensity ratio of the noise component is allowable up to about 20 dB for practical purposes. Therefore, the plane of polarization of the linearly polarized light may be adjusted within ±3 degree around the direction parallel, perpendicular or 45 degree to the principal dielectric axis of the transparent substrate 2 (32). Further, in the case of low- or middle-grate system of which the intensity ratio of the noise component is allowable up to about 40 dB, the plane of polarization may be adjusted within ±5 degree.
Assume that the transparent substrate 2 (32) is disk-shaped and is molded by injection of thermoplastic resin. In view of a method of injection molding normally employed, it is well known that the principal dielectric axis is positioned along the radial direction (direction x--x) of the disk, the peripheral direction (direction y--y) perpendicular thereto and along the thickness (direction z--z) as shown in FIG. 15. In this case, the plane of polarization of the linearly polarized light may be adjusted around the direction x--x, y--y or 45 degree thereto.
These angles of the polarization plane of the linearly polarized light against the principal dielectric axes may be applied to a transparent substrate having a principal dielectric axis of a given direction by measuring the principal dielectric axis of the transparent substrate involved in advance.
The polarization light beam splitter 56 is made up of an analyzer and is positioned at an appropriate angle to the reflection light path 58. Also, the detectors 57, 57a are arranged on two light paths divided by the polarization light bean splitter 56.
Explanation will be now made about the reason why the noise component of the detection signal detected by the detectors 57, 57a can be reduced without regard to the magnitude of retardation of the transparent substrate 2 (32) in the above-described optical system for an optical data recording medium.
The laser 51 takes the form of a semiconductor laser or a laser equipped with a linear polarizer. The linearly polarized light is adapted to enter the optical data recording medium through the incident light path 55. Also, the polarized light beam splitter 56 is made up of an analyzer and set at an appropriate angle to the reflection light path 58.
First, as shown in
The first term of the equation (1) above represents a bias component unrelated to the sign of the Kerr rotation angle θ, the second term the noise component due to the retardation, and the third term a signal component representing the change in θk that can be produced as a signal. As a result, the noise component of the second term may be removed by adjusting the plane of polarization of the data reading light so that sin (2α+2β)=0 or sin2δ=0.
As seen from the third term of the equation (1) above, the signal intensity may be maximized by adjusting the angle α to 45 degree.
Also, the bias component may be removed by subtracting the light intensity I(α) from 1(-α) entering the two detectors 57, 57a as shown in the equation (2) below.
The equations (1) and (2) hold for the light component that is transmitted through the center of the converging lens 53 and entering at right angle to the transparent substrate 2 (32) of the optical data recording medium 54, but not for the light component that enters diagonally to the transparent substrate 2 (32) from the peripheral parts of the converging lens 53. The effect of retardation on the light components entering diagonally will be studied below.
The effect of retardation on the incident light component entering the transparent substrate diagonally from the peripheral part of the converging lens 53 is determined by assuming an index ellipsoid (normal ellipsoid) given by the function of the main refraction index specific to the transparent substrate material within the transparent substrate 2 (32) as shown in
This index ellipsoid E is assumed within the transparent substrate 2 (32) as shown in
When the peripheral directions (with incident angle θ constant in
The reasonableness of the foregoing assumption will be studied below with reference to FIG. 12. In
It is known that when the light is transmitted through the converging lens 53, the plane of incident polarized light changes from E to E' as shown in FIG. 13. In
Since the points P and Q exist on the same periphery of the lens, the values of θ3 in
When the angles β and -β hold this relationship, the sum thereof results in the first term of equation (1) being zero. As described above, the light converged at the converging lens 53 contains diagonal incident light components entering from all directions with the intensity of each incident light estimated to be substantially fixed. Therefore, the above-mentioned relationship between P and Q holds for all the light-transmitted parts on the converging lens 53. As a consequence, the integration about all the light-transmitted part on the converging lens 53 makes the first term of equation (2) zero, thus removing the noise component attributable to the retardation of diagonal incident light components.
In the case where the incident light is not parallel to the principal dielectric axis as shown by E in
The magnitude of the noise due to retardation of the optical circuit according to the present invention was computed for the differential detection method on the assumption that the intensity distribution of the recording/reproducing light is Gaussian using the equations (1) to (4). The result shown in
In this graph, the abscissa represents the angle between the plane of polarization of the recording/reproducing light linearly polarized and the principal dielectric axis of the transparent substrate, and the ordinate the level of the detection signal. Also, the solid line indicates the case in which the analyzer angle of the polarized light beam splitter is set to 45 degree and the dashed line the case in which the analyzer angle of the polarized light beam splitter is set to 70 degree.
As obvious from this graph, regardless of the analyzer angle, the noise component of the detection signal is reduced to zero by setting the angle between the plane of polarization of the recording/reproducing light and the principal dielectric axis of the transparent substrate to zero, 45 degree or 90 degree. It has also be found from this graph that if the deflection between the plane of polarization of the recording/reproducing light and the principal dielectric axis of the transparent substrate is held within ±3 degree, the noise levels of the detection signal is substantially the same as in the case where the light enters a transparent substrate of glass without adjusting the plane of polarization of the linearly polarized light.
Explanation was made above with reference to an embodiment in which the principal dielectric axis of the transparent substrate is adjusted within ±3 degree of the direction along, perpendicular or 45 degree to the scanning of a light beam on the optical data recording medium. The present invention is not confined to such a case, but the principal dielectric axis may alternatively adjusted within ±3 degree of any reference direction set on the optical data recording medium under a predetermined rule or perpendicular thereto or 45 degree to the scanning direction of the light beam.
Shimizu, Mitsuru, Sugiyama, Toshinori, Ikegaki, Tetsurou, Tuburaya, Yoshitane
Patent | Priority | Assignee | Title |
6555195, | Sep 18 1998 | Roehm GmbH & Co. KG | Shaping tool for information carrier disc blanks |
7789656, | Mar 28 2008 | Premier Image Technology(China) Ltd.; Hon Hai Precision Industry Co., Ltd. | Injection molding device |
Patent | Priority | Assignee | Title |
4120922, | Dec 29 1964 | Method for molding | |
4397805, | Aug 28 1978 | Discovision Associates | Method for making a video disc |
4627952, | Sep 03 1982 | Celanese Corporation | Injection molding process |
4743409, | Nov 13 1984 | Sekisui Kagaku Kogyo Kabushiki Kaisha | Process for preparing a substrate for optical recording media |
4764331, | Jan 26 1984 | Daicel Chemical Industries, Ltd. | Large diameter optical disk substrate made of polycarbonate |
4766021, | Mar 12 1986 | BASF Aktiengesellschaft | Optical recording medium |
4877666, | Aug 11 1987 | HOECHST AKTIENGESELLSCHAFT, FEDERAL REPUBLIC OF GERMANY | Magneto-optic substrates |
4959252, | Sep 29 1986 | Rhone-Poulenc Chimie | Highly oriented thermotropic optical disc member |
Executed on | Assignor | Assignee | Conveyance | Frame | Reel | Doc |
Date | Maintenance Fee Events |
Date | Maintenance Schedule |
May 28 2005 | 4 years fee payment window open |
Nov 28 2005 | 6 months grace period start (w surcharge) |
May 28 2006 | patent expiry (for year 4) |
May 28 2008 | 2 years to revive unintentionally abandoned end. (for year 4) |
May 28 2009 | 8 years fee payment window open |
Nov 28 2009 | 6 months grace period start (w surcharge) |
May 28 2010 | patent expiry (for year 8) |
May 28 2012 | 2 years to revive unintentionally abandoned end. (for year 8) |
May 28 2013 | 12 years fee payment window open |
Nov 28 2013 | 6 months grace period start (w surcharge) |
May 28 2014 | patent expiry (for year 12) |
May 28 2016 | 2 years to revive unintentionally abandoned end. (for year 12) |