A magnetooptical recording medium has a first magnetic layer which is an in-plane magnetization film at both room temperature and high temperatures and changed to a perpendicular magnetization film at intermediate temperatures, and a second magnetic layer which is composed of a perpendicular magnetization film. The recording medium enables realization of high S/N reproduction of information recorded at a pitch below the diffraction limit of light with a simple structure, and further improvement in linear recording density and track density.

Patent
   RE38922
Priority
Aug 28 1992
Filed
Nov 03 2000
Issued
Dec 20 2005
Expiry
Aug 26 2013
Assg.orig
Entity
Large
0
23
EXPIRED
1. A magnetooptical recording medium adapted to be heated from a room temperature range to a medium temperature range above the room temperature range and to a high temperature range above the medium temperature range, said medium comprising:
a first magnetic layer, which has an in-plane magnetization at the room temperature range, and which changes to a perpendicular magnetization at the medium temperature range;
a second magnetic layer having a perpendicular magnetization; and
a third magnetic layer, wherein the third magnetic layer is interposed between said first and second magnetic layers, and has a curie temperature lower than those of said first and second magnetic layers, and has an in-plane magnetization at the room temperature range and changes to a perpendicular magnetization at the medium temperature range.
2. A method of reproducing, with a laser beam, information recorded on a magnetooptical recording medium comprising a first magnetic layer, a second magnetic layer having a perpendicular magnetization, and an intermediate layer therebetween having a curie temperature higher than a room temperature range, lower than the curie temperature of the first and second magnetic layers, and in a high temperature range, the first magnetic layer having an in-plane magnetization at the room temperature range, changing to a perpendicular magnetization at a medium temperature range higher than the room temperature range and changing back to an in-plane magnetization at or above the curie temperature of the intermediate layer in the high temperature range higher than the medium temperature range, said method comprising the steps
projecting a laser beam onto the magnetooptical recording medium from a side of the first magnetic layer;
heating the first magnetic layer with the laser beam so that the first magnetic layer has a portion in the room temperature range having in-plane magnetization and a portion in the medium temperature range having a perpendicular magnetization;
heating a portion of the intermediate layer at least to its curie temperature so that a corresponding portion of the first magnetic layer in the high temperature range changes to an in-plane magnetization;
transferring information recorded in the second magnetic layer to the first magnetic layer by exchange coupling through the intermediate layer perpendicular magnetization of the first magnetic layer and magnetization of the second magnetic layer; and
reproducing the recorded information based on the magneto-optic effect of the light reflected from the magnetooptical recording medium.
0. 3. The magnetooptical recording medium of claim 1, wherein the first magnetic layer and the third magnetic layer are magnetically coupled by exchange coupling.


wherein Ms is the saturation magnetization of the magnetic thin film, and Ku is the perpendicular magnetic anisotropy constant. When K⊥ is positive, the magnetic film becomes a perpendicular magnetization film. When K⊥ is negative, the magnetic film becomes an in-plane magnetization film. Here, 2πMs2 is energy of demagnetizing field.

For example, when the magnetic film has temperature dependency of Ms and Ku as shown in FIG. 4, the magnetic film is an in-plane magnetization film since the following equation 2 is established:
Ku<2πMs2, K⊥<0   (2)
However, at the time of information reproduction, Ms of the readout layer decreases since the temperature increases. Thus, 2πMs2 rapidly decreases and becomes smaller than the perpendicular magnetic anisotropy constant Ku, as shown by the following relation 3:
Ku>2πMs2, K⊥>0   (3)
As a result, the readout layer becomes a perpendicular magnetization film.

When the temperature further increases, the relation between 2πMs2 and Ku is again reversed after compensation temperature, and the following relation 4 is again obtained:
Ku<2πMs2, K⊥<0   (4)
As a result, the readout layer again becomes an in-plane magnetization film.

Namely, a state is realized in which the readout layer becomes an in-plane magnetization film in the highest-temperature and low-temperature regions within a portion of the light spot, and the readout layer becomes a perpendicular magnetization film in the medium-temperature region thereof, as shown in FIG. 5. Since the readout layer, which is a perpendicular magnetization film, is magnetically coupled to the recording layer due to exchange coupling therebetween, the direction of magnetization in the readout layer is aligned along a stable direction for the magnetization direction of information recorded in the recording layer. Thus, the information recorded in the recording layer is transferred into the readout layer. The transferred information is converted into an optical signal by magneto-optic effect (magneto-optic effect (polar Kerr effect) of a laser beam reflected from the readout layer) of the readout layer, and detected. Namely, the information is detected by detecting the light reflected from the readout layer. In this case, the magneto-optic effect (polar Kerr effect) would not occur in a portion within the light spot where the readout layer is an in-plane magnetization film.

Thus, as shown in FIG. 5, a masked region for masking magnetization information in the recording layer, and an aperture region for detecting the information are formed within the light spot. Since the aperture region can be formed to have an area smaller than the light spot, signals having a periodicity below the diffraction limit of light can be detected, thereby increasing the linear density.

Since it is also possible to mask a mark on an adjacent track, the density of the adjacent track can be improved.

Although a case of magnetic coupling due to exchange coupling between the readout layer and the recording layer is described above, it is possible that the recording layer is magnetically coupled to the readout layer due to magneto-static coupling at the time of reproduction. When the readout layer and the recording layer are layered directly or with an intermediate layer therebetween, Ku apparently increases due to the exchange coupling force or magnetostatic coupling force applied from the perpendicular magnetization film, and thus the temperature region serving as a perpendicular magnetization film shifts to a lower temperature side, compared with a case where the readout layer and recording layer are not layered. If presetting a perpendicular magnetization temperature region in a single layer film at a slightly higher value, even when the readout layer is layered with the perpendicular magnetization layer, it is possible that the readout layer is an in-plane magnetization film at room temperature and high temperatures, and shifts into a perpendicular magnetization film only in the medium temperature region.

Masking may be achieved at the highest-temperature point or region by disappearance of magnetization in the readout layer. However, the signal level in readout might be slightly reduced because Curie temperature Tc of the readout layer needs to be lower than Curie temperature Tc of the recording layer.

The following is an example of an improved magnetooptical recording medium of the present invention, which contains an intermediate layer between a readout layer and a recording layer as shown in FIG. 6, and thus basically comprises three magnetic film layers.

In this example, the intermediate layer is interposed between the readout layer and the recording layer, and Curie temperature of the intermediate layer is higher than room temperature and lower than Curie temperatures of the readout and recording layers. Material for the intermediate layer may be a rare-earth and iron group amorphous alloy, such as TbFe, GdFe, TbFeCo or GdFeCo, or such an alloy into which a non-magnetic element such as Al, Cu and Cr are added.

When the readout layer and the recording layer are layered, the exchange coupling force from the recording layer acts in a direction to make the spin (magnetization) direction of the readout layer perpendicular. Thus, the perpendicular magnetic anisotropy of the readout layer apparently increases. Although this apparent increase in the perpendicular magnetic anisotropy is omitted in the above description, the effective perpendicular magnetic anisotropy K⊥ will be handled below in consideration of the increase.

Assuming that the thickness of the readout layer is h1, saturation magnetization is Ms, perpendicular magnetic anisotropy constant is Ku, and energy of the interface magnetic domain walls between the readout layer and the recording layer is σW, when the thickness of the interface magnetic domain walls is neglected, an increase in perpendicular magnetic anisotropy of the readout layer due to exchange coupling force is expressed by σW/(4h1).

Thus, the effective perpendicular magnetic anisotropy constant K⊥ is as follows: K = Ku + σ w 4 h1 - 2 π Ms 2 ( 5 )

As shown in FIG. 6, the readout layer is subjected to the exchange coupling force from the recording layer at room temperature (RT), but energy of a demagnetizing field is dominant because of large Ms within a low-temperature region near room temperature. As a result, the following relation 6 is obtained, and the readout layer becomes an in-lane magnetization film. Ku + σ w 4 h1 < 2 π Ms 2 , K < 0 ( 6 )

Similar to the above example, in a portion of the magnetooptical recording medium where the temperature increases due to projection of the readout laser beam, Ms of the readout layer decreases, and thus 2πMs2 rapidly decreases. As a result, the above relation is reversed, as shown by the following relation 7, and the readout layer becomes a perpendicular magnetization film. Ku + σ w 4 h1 > 2 π Ms 2 , K < 0 ( 7 )
However, in a high-temperature region within the light spot, like at room temperature, the readout layer is an in-plane magnetization film.

The intermediate layer functions as a mediator of exchange coupling force from the recording layer to the readout layer, until its Curie temperature is reached, and information in the recording layer is transferred to the readout layer.

However, in the high-temperature portion within the light spot, the temperature of the intermediate layer reaches its Curie temperature. The intermediate layer has such a composition that Curie temperature is reached, or laser power is set so that Curie temperature is reached. In this portion, thus, the exchange coupling force is eliminated, and the perpendicular magnetic anisotropy constant of the readout layer rapidly decreases in appearance. Therefore, the magnetization direction of the readout layer becomes an in-plane direction again (refer to FIG. 6). Namely, the energy of the interface domain walls between the readout layer and the recording layer becomes 0, and the following relation (8) is obtained:
Ku<2πMs2, K⊥<0   (8)
Like the two-layer structure, therefore, only the medium-temperature region becomes an aperture region, thereby realizing super-resolution.

In such a case where the intermediate layer is formed, which has low Curie temperature, the readout layer can be an in-plane magnetization film at room temperature and raised temperatures and be a perpendicular magnetization film at intermediate temperatures therebetween in its layered structure together with the intermediate and recording layers, thought the readout layer has no characteristic that the layer structure in its single layer state returns to an in-plane magnetization film at raised temperatures. Thus, the recording medium comprising the intermediate layer is advantageous in that material can be selected from a wider range.

Since the intermediate layer need not to contribute to the magneto-optic effect, reproduction characteristic do not deteriorate even if Curie temperature is set to a low value.

Although, in the above description, it is assumed for convenience sake that the width of the interface magnetic domain walls between the readout layer and the recording layer can be neglected, the above description applies to a case where the interface magnetic domain walls enter the readout layer to have a thickness which cannot be neglected. However, when the interface magnetic domain walls between the readout layer and the recording layer occur on the side of the readout layer, magnetization of the recording layer is transferred to a portion of the readout layer, as in the state of spin orientation schematically shown in FIGS. 7(a) and 7(b). If the interface magnetic domain walls become too thick, therefore, it is difficult to completely mask magnetization information recorded in the recording layer. It is thus preferable to thicken the readout layer or increase the in-plane anisotropy in the low-temperature region.

Description will now be made of a case where the above magnetooptical recording medium comprising three magnetic films is improved. In this case, the intermediate layer is interposed between the readout layer and the recording layer, and the Curie temperature thereof is higher than room temperature and lower than Curie temperatures of the readout layer and recording layer. In addition to these conditions, the in-plane anisotropy of the intermediate layer at temperature near room temperature must be larger than that of the readout layer. In order to increase in-plane anisotropy, for example, when rare-earth and iron group alloy is used, rare-earth elements or iron group elements may be predominant so that Ms of the intermediate layer at room temperature is increased.

When such an intermediate layer is interposed between the readout layer and the recording layer, the interface magnetic domain walls can be enclosed in the intermediate layer from room temperature to the aperture region, as shown in FIGS. 8(a) and 8(b).

Thus, the readout layer stably becomes an in-plane magnetization film within the low-temperature region, and it is possible to completely mask magnetization information recorded in the recording layer.

If the Curie temperature of the intermediate layer is lower than Curie temperature of the recording layer and higher by a degree which causes no cutting of exchange coupling between the readout layer and the recording layer in the medium-temperature region within the light spot, Ms of the intermediate layer is sufficiently small in the medium-temperature region, and the in-plane anisotropy thereof is decreased, thereby increasing perpendicular magnetic anisotropy. At the readout temperature, even when the intermediate layer itself has no perpendicular magnetic anisotropy, perpendicular magnetic anisotropy can be imparted to the intermediate layer by magnetic coupling force from the recording layer and the readout layer which came to have perpendicular magnetic anisotropy.

In the medium-temperature region, therefore, magnetization of the recording layer is transferred to the readout layer. In the high-temperature region, the temperature of the intermediate layer reaches Curie temperature, and exchange coupling force is eliminated, as described above. As a result, the readout layer becomes an in-plane magnetization film.

As shown in FIG. 9, therefore, the mask region for masking magnetization information recorded in the recording layer, and the aperture region for detecting the magnetization information are formed within the light spot. Since the aperture region can be formed to have an area smaller than the light spot, signals with periodicity below the diffraction limit of light can be detected. Further, as described above, the mask can completely be operated on the front side.

Since a mark on an adjacent track can completely be masked, the density of the adjacent track can further be improved.

In this case, the intermediate layer is preferably formed by using material such as a Gd alloy or the like which has low anisotropy and easily forms interface magnetic domain walls, for example, GdFe, GdFeCo or the like, or the material to which a non-magnetic element such as Al, Cu or Cr is added for decreasing Curie temperature.

The thickness of the intermediate layer may be equal to or more than the thickness of the interface magnetic domain walls between the readout layer as an in-plane magnetization film and the recording layer as a perpendicular magnetization film. On the other hand, if the intermediate layer is too thick, the total thickness of the magnetic layers is increased, thereby necessitating much power for recording. The excessively thick intermediate layer is thus undesirable. The thickness of the intermediate layer is preferably 20 A to 200 A, more preferably 50 A to 150 A.

In regard to the physical properties of the readout layer, the intermediate layer and the recording layer, assuming that the Curie temperatures of the readout layer, the intermediate layer and the recording layer are T1, T3 and T2; the compensation temperature of the readout layer is Tcomp1; the saturation magnetizations of the readout layer, the intermediate layer and the recording layer are Ms1, Ms2 and Ms3, effective perpendicular magnetic anisotropy constants are K⊥1, K⊥3 and K⊥2; and the energy values of perpendicular magnetic anisotropy is Ku1, Ku3 and Ku2; the following equation (9) is obtained:
K⊥=Kui−2πMsi2 (i=1, 2, 3)   (9)
At room temperature, the effective perpendicular magnetic anisotropy constants K⊥1, K⊥3 and K⊥2 may have the following relation:
K⊥3<K⊥1<<K⊥2   (10)
At room temperature, examples satisfying the above relation are as follows:
Ms1<Ms3   (11)
Ms2<Ms3   (12)

In addition, as described above, the Curie temperatures must satisfy the relation (13) below.
RT (room temperature)<Tc3<<Tc1   (13)

FIGS. 10(a) through 10(c)1 show an example of temperature tendencies of saturation magnetization of the readout layer, the intermediate layer and the recording layer, which satisfy the above conditions.

In order to decrease the in-plane anisotropy of the intermediate layer, as described above, Ms may be increased, or energy of perpendicular magnetic anisotropy Ku may be decreased or made negative (in-plane anisotropy) by adding elements such as Co and the like, which increase in-plane anisotropy.

As described above, in the information reproducing method using the magnetooptical recording medium of the present invention, since a reproducable portion within the laser beam spot is located in a narrow zone between a high-temperature portion and a low-temperature portion, it is possible to reproduce information with high resolution even if the information is recorded in higher density. A higher C/N ratio can also be expected because the detecting region is placed in a center of the laser beam spot. The reason for this is explained hereinafter.

Intensity distribution of the laser beam is of a Gaussion type and the intensity at a center thereof is highest. Thus, the closer to the center of the spot a position, where information is reproduced, is, the better the C/N ratio becomes.. Generally, the center of the spot is coincident with the center of temperature distribution of the medium when the recording medium moves. The highest temperature point shifts toward the moving direction of the medium. Therefore, when the highest-temperature point is selected as a detectable area, the detecting area will be deviated from the center of the spot (FIG. 12).

Although the present invention is described in detail below with reference to experimental examples, the present invention is not limited to these experimental examples within the scope of the gist of the invention.

(First Experimental Example)

Targets Si, Tb, Gd, Fe, Co, Al and Cu were installed in a DC magnetron sputtering equipment, and a glass substrate was held on a holder. Thereafter, air was vacuum-exhausted from a chamber to establish a high vacuum level of less than 1×10−5 Pa by using a cryosorption pump.

Ar gas was introduced into the chamber while vacuum-exhausting air, until the level of 0.3 Pa or Ar gas was reached. Then, a SiN layer, which functioned as an interference dielectric film, was deposited to a thickness of 700 Å on the surface of the substrate. A GdFeCo layer was (thickness: 400 Å) was deposited as a readout layer, and a TbFeCo layer (thickness: 400 Å) was deposited as a recording layer. Then, another SiN layer (thickness: 800 Å), which functioned as a protective dielectric film, was deposited to form a magnetooptical recording medium of the present invention having the two-layer structure shown in FIG. 3(a).

When the SiN layer was formed, N2 gas was introduced in addition to the Ar gas and the deposition is performed by DC reactive sputtering. The GdFeCo layer and the TbFeCo layer were formed by applying DC powers to the targets of Gd, Fe, Co and Tb, respectively.

The composition of the GdFeCo layer was adjusted to that its compensation and Curie temperatures were 240° C. and over 400° C., respectively.

The composition of the TbFeCo layer was adjusted to that its compensation and Curie temperatures were less than room temperature and 230° C., respectively.

It was found that Kerr effect (residual Kerr rotation angle), when no magnetic field was applied, appeared only in a temperature range from 130° C. to 180° C., as shown in FIG. 13, and a perpendicular magnetization film was established, by measuring the residual θK at the time of magnetic field=zero as the temperature of the layered films was raised.

(Second Experimental Example)

A magnetooptical recording medium was fabricated, which had the same layer structure as the above first example except that a polycarbonate substrate having a diameter of 130 mm and pregrooves was used.

Results of measurement of recording-reproducing characteristics of the magnetooptical recording medium were as follows. A measuring instrument comprised an objective lens of 0.55 N.A. and a projector for outputting a laser beam of 780 mm wavelength. Power for recording was preset at 8 mW, and linear velocity was 9 m/sec. Then, 6-15 MHz carrier signal was recorded in the recording layer by using a field modulation system in which a magnetic field of ±2000 e was applied stepwise. The dependency of C/N ratio on the recorded mark length was measured. The reproducing power was set to a value (2.5 to 3.5 mW) so that C/N ratio is maximized.

Table 1 shows the C/N ratios of the carrier signals recorded at 15 MHz (mark length: 30 μm), 11.25 MHz (mark length: 0.40 μm), and 9 MHz (mark length: 0.50 μm).

Then, crosstalk with an adjacent track was measured. The crosstalk was expressed as a difference between a reproduced signal in a land portion where a signal with a mark length of 1.0 μm was recorded, and the reproduced signal in an adjacent group portion. Results are shown in Table 1.

(Third Experimental Example)

A magnetooptical recording medium of the present invention comprising a readout layer, a recording layer and an intermediate layer with low Curie temperature provided therebetween was fabricated and evaluated.

The same film forming instrument and film forming method as those employed in the second experiment example were used. A SiN layer as an interference dielectric layer was deposited to a thickness of 830 Å on the surface of a polycarbonate substrate having a diameter of 130 mm and pregrooves. A GdFeCo layer (thickness: 400 Å) was deposited as a readout layer, a TbFeCoAl layer (thickness: 100 Å) was deposited as an intermediate layer, a TbFeCo layer (thickness: 300 Å) was deposited as a recording layer. Then, another SiN layer (thickness: 700 Å) was deposited as a protective dielectric layer to form a magnetooptical recording medium having the structure shown in FIG. 3(b).

When the SiN layer was formed, N2 gas was introduced in addition to the Ar gas, and the deposition was performed by DC reactive sputtering. The GdFeCo layer and the TbFeCo layer were formed by applying DC power to targets of Gd, Fe, Co and Tb, respectively, and utilizing spontaneous sputtering. The compositions of those layers were controlled by adjusting the DC powers applied to the respective targets in sputtering film formation.

The composition of the GdFeCo readout layer was set so that its compensation and Curie temperatures are 250° C. and over 310° C., respectively. The composition of the TbFeCoAl intermediate layer was set so that its Curie temperature is 150° C. The composition of the TbFeCo recording layer was set so that its Curie temperature is 210° C.

The mark length dependency of C/N ratio, and crosstalk were measured by the same method as in the second experimental example. Results are shown in Table 1.

(Fourth to Seventh Experimental Examples)

Magnetooptical recording media of the present invention having a two-layer structure was fabricated by the same film forming equipment as that used in the second and third experimental examples, and the mark length dependency of C/N ratios were measured by the same method. The measured physical property values, C/N ratios and crosstalk are shown in Table 1.

(Eighth and Ninth Experimental Examples)

Magnetooptical recording media of the present invention having a three-layer structure comprising an intermediate layer with low Curie temperature were fabricated by the same film forming instrument as that used in the second to seventh experimental examples. The mark length dependencies of C/N ratios were measured by the same method as in the second to seventh experimental examples. The measured physical property values, C/N ratios and crosstalk of the respective layers are shown in Table 1.

(Tenth Experimental Example)

A magnetooptical recording medium of the present invention having a three-layer structure comprising an intermediate layer with low Curie temperature and in-plane anisotropy which was larger than that of a readout layer in a low-temperature region within an light beam spot, was fabricated by the same method as that employed in the second to ninth experimental examples.

A SiN dielectric layer of 900 Å, a GdFeCo readout layer of 400 Å, a GdFe intermediate layer of 100 Å, a TbFeCo recording layer of 300 Å and a SiN protective layer were successively formed on a glass substrate to form a sample having the structure shown in FIG. 3(b). When each of the SiN layers was formed, a N2 gas was introduced in addition to a Ar gas, and the deposition was performed by DC reactive sputtering. The mixing ratio between the Ar gas and N2 gas was adjusted so that the refractive index is 2.1.

The composition of the GdFeCo readout layer was set so that the layer is RE-rich and has saturation magnetization Ms of 160 emu/cc at room temperature, and its compensation temperature and Curie temperature are 205° and over 300° C., respectively.

The composition of the TbFe intermediate layer was set so that the layer is RE-rich and has a saturation magnetization Ms of 520 emu/cc at room temperature, and its Curie temperature is 150° C.

The composition of the TbFeCo recording layer was set so that the layer is TM-rich and has a saturation magnetization of 200 emu/cc, and its Curie temperature is 220° C.

The dependency of the Kerr rotation angle (θK) on an external magnetic field was measured by applying a semiconductor laser beam of 830 nm to a sample having layers, which were formed on a glass substrate by the above method, from the side of the glass substrate. The measurement was performed by heating the sample from room temperature to about 200° C. FIG. 13 shows the temperature dependency of the Kerr rotation angle (residual Kerr rotation angle: θKR) at the time of external magnetic field=0. It is found from FIG. 13 that the residual Kerr rotation angle θKR is substantially zero from room temperature to about 140° C., then rapidly increases from about 140° C. and becomes zero at about 200° C.

(Eleventh Experimental Example)

A magnetooptical recording film having the same layer structure and layer compositions as those in the tenth experimental example was formed on a polycarbonate substrate with pregrooves to form a magnetooptical recording medium of the present invention.

The dependency of C/N ratio on the recorded mark length and crosstalk were measured by the same method as in the second to ninth experimental examples. Results are shown in Table 1.

(Twelfth Experimental Example)

A SiN dielectric layer of 900 Å, a GdFeCo readout layer of 400 Å, a GdFe intermediate layer of 120 Å, a TbFeCo recording layer of 300 Å, and a SiN protective layer of 700 Å were successively formed on a polycarbonate substrate by the same instrument and method as those employed in the first experimental example to obtain a sample having the structure shown in FIG. 3(b).

The composition of the GdFeCo readout layer was set so that the layer is RE-rich and has a saturation magnetization Ms of 180 emu/cc at room temperature, and its compensation temperature and Curie temperature are 220° C. and over 300° C., respectively.

The composition of the GdFe intermediate layer was set so that the layer is RE-rich and has a saturation magnetization Ms of 680 emu/cc at room temperature, and its Curie temperature is 180° C.

The composition of the TbFeCo recording layer was set to that the layer is TM-rich and has a saturation magnetization Ms of 200 emu/cc at room temperature, and its Curie temperature is 220° C.

TABLE 1
Readout layer Intermediate layer
Thick Ms Tcx×n Tc Thick Ms Tc
Composition e/cc ° C. ° C. Composition e/cc ° C.
Example 1,2 Gd32(Fe55Co45)69 400 240 400<
Example 3 Gd30(Fe60Co40)70 400 250 310< (Tb24(Fe95Co5)76)95Al5 100 100 150
Example 4 Gd28(Fe65Co35)72 350 205 300<
Example 5 (Gd73Tb27)70Co30 300 205 300<
Example 6 Gd28(Fe60Co45)72 400 205 300<
Example 7 (Nd10Gd90)30(Fe60Co40)70 370 300<
Example 8 Gd29(Fe50Co50)71 400 300< (Tb23(Fe94Co6)77)94Cu6 50  80 170
Example 9 Gd28(Fe70Co30)72 360 260 300< Gd40Fe60 80 460 188
Example 10,11 Gd25(Fe60Co40)72 400 180 205 300< Gd45Fe55 100  520 150
Example 12 Gd29(Fe60Co40)71 400 200 220 300< Gd45(Fe90Co10)50Al5 120  680 180
Example 13 Gd27(Fe68Co32)73 400 150 188 300< Gd45(Fe98Co2)55 80 520 170
Example 14 Gd27(Fe65Co35)73 400 160 188 300< Gd40(Fe94Co6)50 90 470 165
Co. Ex. 1,2 Gd27(Fe65Co35)73 400 130 280 300<
Co. Ex. 3 Gd37(Fe60Co40)68 400 270 280 300<
Recording layer C/N (dB)
Thick Ms Tc 0.40 μ Cross-talk
Composition e/cc ° C. 0.30 μ dB 0.50 μ dB
Example 1,2 Tb20(Fe80Co20)50 400 −200 230 30 33 44 −30
Example 3 Tb20(Fe80Co20)50 300 −200 210 36 41 47 −35
Example 4 Tb20(Fe80Co20)50 370 −200 220 30 34 45 −31
Example 5 Tb20(Fe80Co20)50 400 −200 220 30 33 44 −30
Example 6 Dy20(Fe80Co20)50 380 −200 220 31 32 44 −29
Example 7 Tb20(Fe80Co20)50 400 −200 220 30 31 46 −28
Example 8 Tb20(Fe80Co20)50 450 −200 220 35 41 46 −36
Example 9 Tb20(Fe80Co20)50 300 −200 220 39 44 47 −35
Example 10,11 Tb20(Fe80Co20)50 300 −200 220 41 45 48 −40
Example 12 Tb20(Fe80Co20)50 300 −200 220 39 44 48 −41
Example 13 Tb20(Fe80Co20)50 300 −200 220 40 45 48 −40
Example 14 Tb20(Fe80Co20)50 300 −200 220 40 44 48 −41
Co. Ex. 1,2 Tb20(Fe80Co20)50 300 −200 220 20 26 46 −20
Co. Ex. 3 Tb20(Fe80Co20)50 300 −200 220 26 29 47 −21
e/cc = emu/cc

Then, the dependency of C/N ratio on the recorded mark length and crosstalk were measured by the same method as in the second to ninth experimental examples. Results are shown in Table 1.

(Thirteenth Experimental Example)

A SiN dielectric layer of 900 Å, a GdFeCo readout layer of 400 Å, a GdFe intermediate layer of 80 Å, a TbFeCo recording layer of 300 Å, and a SiN protective layer of 700 Å were successively formed on a polycarbonate substrate by the same instrument and method as those employed in the first experimental example to obtain a sample having the structure shown in FIG. 3(b).

The composition of the GdFeCo readout layer was set so that the layer is RE-rich and has a saturation magnetization Ms of 150 emu/cc at room temperature, and its compensation temperature and Curie temperature are 188° C. and over 300° C., respectively.

The composition of the GdFe intermediate layer was set so that the layer is RE-rich and has a saturation magnetization Ms of 520 emu/cc at room temperature, and its Curie temperature is 170° C.

The composition of the TbFeCo recording layer was set so that the layer is TM-rich and has a saturation magnetization Ms of 200 emu/cc at room temperature, and its Curie temperature is 220° C.

Then, the dependency of C/N ratio on the recorded mark length and crosstalk were measured by the same method as in the second to ninth experimental examples. Results are shown in Table 1.

(Fourteenth Experimental Example)

A SiN dielectric layer of 900 Å, a GdFeCo readout layer of 400 Å, a GdFe intermediate layer of 90 Å, a TbFeCo recording layer of 300 Å, and a SiN protective layer of 700 Å were successively formed on a polycarbonate substrate by the same instrument and method as those employed in the first experimental example to obtain a sample having the structure shown in FIG. 3(b).

The composition of the GdFeCo readout layer was set so that the layer is RE-rich and has a saturation magnetization Ms of 160 emu/cc at room temperature, and its compensation temperature and Curie temperature are 188° C. and over 300° C., respectively.

The composition of the GdFe intermediate layer was set so that the layer is RE-rich and has a saturation magnetization Ms of 470 of emu/cc at room temperature, and its Curie temperature is 165° C.

The composition of the TbFeCo recording layer was set so that the layer is TM-rich and has a saturation magnetization Ms of 200 emu/cc at room temperature, and its Curie temperature is 220° C.

Then, the dependency of C/N ratio on the recorded mark length and crosstalk were measured by the same method as in the second to ninth experimental examples. Results are shown in Table 1.

(First Comparative Experimental Example)

A SiN dielectric layer of 900 Å, a GdFeCo readout layer of 400 Å, a TbFeCo recording layer of 300 Å, and a SiN protective layer of 700 Å were successively formed on a polycarbonate substrate by the same instrument and method as those employed in the first experimental example to obtain a sample having the structure shown in FIG. 3(a).

The composition of the GdFeCo readout layer was set so that the layer is RE-rich and has a saturation magnetization Ms of 130 emu/cc at room temperature, and its compensation temperature and Curie temperature are 280° C. and about 300° C., respectively.

The composition of the TbFeCo recording layer was set so that the layer is TM-rich and has a saturation magnetization Ms of 200 emu/cc at room temperature, and its Curie temperature is 220° C.

This sample had the temperature dependency of residual θK as shown in FIG. 15, and did not become again an in-plane magnetization film at high temperatures. As in this comparative example, in a recording medium having a two-layer structure comprising a readout layer and a recording layer in which the compensation temperature and Curie temperature are close to each other, the readout layer cannot be made an in-plane magnetization film at high temperatures.

(Second Comparative Experimental Example)

Layers were formed on a polycarbonate substrate to form a magnetooptical recording medium by the same method as that employed in the second experimental example. Then, the dependency of C/N ratio on the recorded mark length and crosstalk were measured by the same method as in the second to ninth experimental examples. Results are shown in Table 1.

(Third Comparative Experimental Example)

A SiN dielectric layer of 900 Å, a GdFeCo readout layer of 400 Å, a TbFeCo recording layer of 300 Å, and a SiN protective layer of 700 Å were successively formed on a polycarbonate substrate by the same instrument and method as those employed in the first experimental example to obtain a sample having the structure shown in FIG. 3(a).

The composition of the GdFeCo readout layer was set so that the layer is RE-rich and has a saturation magnetization Ms of 180 emu/cc at room temperature, and its compensation temperature and Curie temperature are 290° C. and about 300° C., respectively.

The composition of the TbFeCo recording layer was set so that the layer is TM-rich and has a saturation magnetization Ms of 200 emu/cc at room temperature, and its Curie temperature is 220° C.

Then, the dependency of C/N ratio on the recorded mark length and crosstalk were measured by the same method as in the second to ninth experimental examples. Results are shown in Table 1.

Comparison of the experimental examples 2 to 14 and comparative experimental examples 2 and 3 reveals that the present invention can significantly improve the C/N ratio and crosstalk with a short mark length.

Use of the magnetooptical recording medium and reproducing method of the present invention enable reproduction of a magnetic domain smaller than the diameter of a beam spot by using a simple instrument (conventional instrument) which requires no initialization magnet, and achievement of high-density recording in which the linear recording density and track density are further improved, thereby improving the C/N ratio.

Nishimura, Naoki

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