An anhydrous, water-resistant cosmetic composition comprising silicone-containing materials, fillers and pigments. This composition may be used as a make-up product or as a hair product.
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0. 18. A cosmetic composition comprising from 2% to 50% of at least one silicone gum, at least one crosslinked silicone, at least one pigment in an amount ranging from 0.5% to 15%, and at least one gelling agent, wherein said at least one silicone gum is of the formula:
##STR00004##
in which
R1, R2, R5 and R6 are each independently chosen from alkyl radicals having from 1 to 6 carbon atoms;
R3 and R4 each independently chosen from alkyl radicals having from 1 to 6 carbon atoms and aryl radicals;
X is chosen from alkyl radicals having from 1 to 6 carbon atoms, hydroxyl radicals, and vinyl radicals; and
n and p are independently chosen so as to give said silicone gum a viscosity of greater than 100,000 mPa•s, and
wherein said composition is anhydrous and water-resistant.
0. 40. A cosmetic composition comprising from 2% to 50% of at least one silicone gum, at least one crosslinked silicone, at least one pigment in an amount ranging from 0.5% to 15%, and at least one modified clay, wherein said at least one silicone gum is of the formula:
##STR00007##
in which
R1, R2, R5 and R6 are each independently chosen from alkyl radicals having from 1 to 6 carbon atoms;
R3 and R4 are each independently chosen from alkyl radicals having from 1 to 6 carbon atoms and aryl radicals;
X is chosen from alkyl radicals having from 1 to 6 carbon atoms, hydroxyl radicals, and vinyl radicals; and
n and p are independently chosen so as to give said silicone gum a viscosity of greater than 100,000 mPa•s, and
wherein said cosmetic composition is anhydrous and water-resistant.
0. 33. A cosmetic composition comprising:
from 2% to 50% of at least one silicone gum;
at least one crosslinked silicone;
at least one filler in an amount up to 30%; and
at least one pigment in an amount ranging from 0.5% to 15%;
wherein said at least one silicone gum is of the formula:
##STR00006##
in which
R1, R2, R5 and R6 are each independently chosen from alkyl radicals having from 1 to 6 carbon atoms;
R3 and R4 are each independently chosen from alkyl radicals having from 1 to 6 carbon atoms and aryl radicals;
X is chosen from alkyl radicals having from 1 to 6 carbon atoms, hydroxyl radicals, and vinyl radicals; and
n and p are independently chosen so as to give said silicone gum a viscosity of greater than 100,000 mPa•s, and
wherein said cosmetic composition is anhydrous and water-resistant.
0. 27. A cosmetic composition comprising:
from 2% to 50% of at least one silicone gum;
at least one crosslinked silicone;
at least one gelling agent;
optionally at least one filler in an amount up to 30%; and
at least one pigment in an amount ranging from 0.5% to 15%;
wherein said at least one silicone gum is of the formula:
##STR00005##
in which
R1, R2, R5 and R6 are each independently chosen from alkyl radicals having from 1 to 6 carbon atoms;
R3 and R4 are each independently chosen from alkyl radicals having from 1 to 6 carbon atoms and aryl radicals;
X is chosen from alkyl radicals having from 1 to 6 carbon atoms, hydroxyl radicals, and vinyl radicals; and
n and p are independently chosen so as to give said silicone gum a viscosity of greater than 100,000 mPa•s, and
wherein said cosmetic composition is anhydrous and water-resistant.
0. 41. A cosmetic composition comprising:
from 2% to 50% of at least one silicone gum;
at least one crosslinked silicone;
at least one modified clay;
optionally at least one filler in an amount up to 30%; and
at least one pigment in an amount ranging from 0.5% to 15%;
wherein said at least one silicone gum is of the formula:
##STR00008##
in which
R1, R2, R5 and R6 are each independently chosen from alkyl radicals having from 1 to 6 carbon atoms;
R3 and R4 are each independently chosen from alkyl radicals having from 1 to 6 carbon atoms and aryl radicals;
X is chosen from alkyl radicals having from 1 to 6 carbon atoms, hydroxyl radicals, and vinyl radicals; and
n and p are independently chosen so as to give said silicone gum a viscosity of greater than 100,000 mPa•s, and
wherein said cosmetic composition is anhydrous and water-resistant, and
wherein said cosmetic composition is a lip composition.
0. 1. A cosmetic composition comprising from 2% to 50% of at least one silicone gum, from 10% to 90% of at least one silicone oil, from 0.5% to 15% of at least one pigment, and from 0 to 30% of at least one filler, wherein said at least one silicone gum is of the formula:
##STR00003##
in which
R1, R2, R5 and R6 each independently represents an alkyl radical having from 1 to 6 carbon atoms;
R3 and R4 each independently represents an alkyl radical having from 1 to 6 carbon atoms or an aryl radical;
X represents an alkyl radical having from 1 to 6 carbon atoms, a hydroxyl radical or a vinyl radical; and
n and p are selected so as to give said silicone gum a viscosity of greater than 100,000 mPa s, and
wherein said composition is anhydrous and water-resistant, and further wherein said composition has cosmetic properties.
0. 2. A composition according to
0. 3. A composition according to
0. 4. A composition according to
0. 5. A composition according to
0. 6. A composition according to
the substituents R1 to R6 and X represent a methyl group, p=0 and n=2700;
the substituents R1 to R6 and X represent a methyl group, p=0 and n=2300;
the substituents R1 to R6 represent a methyl group, the substituent X represents a hydroxyl group, p=0 and n=2700; or
the substituents R1, R2, R5, R6 and X represent a methyl group, and the substituents R3 and R4 represent an aryl group, and p and n are selected such that the molecular weight of the compound is approximately 600,000.
0. 7. A composition according to
0. 8. A composition according to
0. 9. A composition according to
0. 10. A composition according to
0. 11. A composition according to
0. 12. A composition according to
0. 13. A composition according to
0. 14. A composition according to
0. 15. A composition according to
0. 16. A composition according to
0. 17. A composition according to
0. 19. A cosmetic composition according to
0. 20. A cosmetic composition according to
0. 21. A cosmetic composition according to
0. 22. A cosmetic composition according to
0. 23. A cosmetic composition according to
0. 24. A cosmetic composition according to
0. 25. A cosmetic composition according to
0. 26. A cosmetic composition according to
0. 28. A cosmetic composition according to
0. 29. A cosmetic composition according to
0. 30. A cosmetic composition according to
0. 31. A cosmetic composition according to
0. 32. A cosmetic composition according to
0. 34. A cosmetic composition according to
0. 35. A cosmetic composition according to
0. 36. A cosmetic composition according to
0. 37. A cosmetic composition according to
0. 38. A cosmetic composition according to
0. 39. A cosmetic composition according to
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This is a continuation of application Ser. No. 08/882,298, filed Jun. 25, 1997 now U.S. Pat. No. 5,849,316, which is a continuation of application Ser. No. 08/538,046, filed Oct. 2, 1995, now abandoned.
The invention is directed to anhydrous and water-resistant make-up compositions comprising, inter alia, at least one silicone gum.
Water-resistant compositions in water-in-oil or water-in-silicone emulsion form are known in the prior art. The use of such emulsions relies on the fact that after spreading, the water evaporates and the oil or the silicone remains in contact with the skin, giving a water-resistant make-up. However, the application of such compositions has the drawback of leaving the skin with an oily appearance and of giving a greasy feel. The result obtained after application is not really natural, and the make-up shines or becomes shiny.
Another form of water-resistant cosmetic compositions is a composition in which fillers, including pigments, are introduced into a volatile or non-volatile silicone oil. The major drawback of this type of composition lies in the stretching effect on the skin, and in the unpleasant, dry sensation which appears after application. Furthermore, the effect sought in the use of such compositions containing pigments, namely a coloration of the skin, is often not achieved. The very nature of the composition is such that the distribution of the pigments in the composition after spreading is not homogeneous; the pigments spread more or less uniformly and tend to agglomerate in the pores and the folds in the skin. This effect runs counter to the search for a coloration close to that obtained naturally.
In all cases, the compositions obtained have faults both with regard to the stability and with regard to the homogeneity of the dispersion of the pigments. Solutions to these problems have been proposed, such as, for example, the use of water-soluble dyes or of dihydroxyacetone (DHA). In the case of water-soluble dyes, the make-ups obtained are not water-resistant and are not perfectly homogeneous.
Products using DHA are difficult to formulate, on account of the degradation and the incompatibility of DHA with many components usually used in compositions of this type. In addition, a major drawback of DHA, in its use in cosmetic compositions, lies in the development of unpleasant odors during ageing.
An object of the present invention is to provide solutions to the various problems encountered in the applications of the prior art and to propose a cosmetic composition possessing good water resistance and at the same time possessing good cosmetic properties.
The Inventors have been able to show, surprisingly and unexpectedly, that it is possible to obtain anhydrous, water-resistant make-up compositions which are highly homogeneous in particular with regard to spreading, by mixing together pigments and at least a large proportion of silicone gum and a silicone oil.
More particularly, a subject of the present invention is an anhydrous, water-resistant cosmetic composition preferably comprising from 2 to 50% of at least one silicone gum, from 10 to 90% of at least one silicone oil, from 0.5 to 15% of at least one pigment and from 0 to 30% of at least one filler.
The compositions according to the invention have the advantage of being stable over time. They are water-resistant since they are anhydrous, and do not contain any water-soluble dyes or solvent. They also have good staying power and do not cause any pulling effect on the skin.
It has furthermore been observed, surprisingly, that the pigments present in the compositions according to the invention were dispersed therein in an unexpectedly very homogeneous manner. This thus has the additional advantage of giving a very uniform and very homogeneous make-up of the skin.
In the following text, the percentages will always be given by weight of active material relative to the total weight of the composition.
In the compositions according to the invention, the silicone gum is preferably present in a proportion ranging from 2% to 50%, more preferably ranging from 4 to 15% and still more preferably ranging from 6% to 9%.
The silicone gum preferably has a molecular weight not greater than 1,500,000. More preferably, the silicone gum has a molecular weight ranging from 200,000 to 1,000,000.
The silicon gum preferably corresponds to the formula:
##STR00001##
in which:
In general, n and p may have values preferably ranging from 0 to 5000, and more preferably ranging from 0 to 3000.
As silicone gum which may be used according to (the invention, there may preferably be mentioned those for which:
The composition according to the invention preferably also comprises at least one silicone oil, in a proportion preferably ranging from 10 to 90%.
A volatile or non-volatile silicone oil may be used.
There may be mentioned, for example:
According to a preferred embodiment of the invention, the silicone oil and gum are used in the form of a homogeneous premix consisting of the silicone gum solubilized in the silicone oil.
The composition according to the invention preferably also comprises pigments, in a proportion ranging from 0.5 to 15%, and more preferably ranging from 2 to 8%.
The pigments may be white or coloured and inorganic or organic.
The pigments used in the composition according to the invention may or may not be coated.
U.S. Pat. No. 4,578,566, the disclosure of which is incorporated herein by reference, describes a pretreatment of pigments in order to make them hydrophobic, as a solution in order to introduce large proportions thereof into silicone-based compositions, and in order to ensure better dispersion thereof in the composition. This pretreatment is carried out by coating the pigments with a polysiloxane. Obviously, this pretreatment increases not only the preparation time of the compositions but also their cost.
As has been mentioned above, a particular advantage of the invention lies in the fact that the compositions according to the invention allow a homogeneous and stable dispersion to be obtained, even when pigments which have not been precoated are used.
Among the pigments which may preferably be used, there may be mentioned, without any limiting effect, titanium dioxide (TiO2), zinc oxide (ZnO), zirconium dioxide (ZrO2), black, yellow, red and brown iron oxides, cerium dioxide (CeO2) or alternatively the organic pigments known as barium, strontium, calcium and aluminium lakes.
The composition according to the invention preferably contains 0 to 30% of fillers. These fillers may preferably be inorganic or synthetic and lamellar or non-lamellar.
Talc, mica, silica, kaolin, powders of nylon and of polyethylene, Telfon, starch, titanium mica, natural mother of pearl, boron nitride and hollow microspheres such as Expancel from Nobel Industrie may be mentioned.
The composition according to the invention may also comprise constituents usually used in cosmetic compositions of this type. These constituents are preferably chosen as a function of the desired cosmetic effect for the final composition, such as the covering power, the transparency, the matt quality and/or the satiny appearance.
There may be mentioned, without any limiting effects:
The processes for the manufacture of the compositions according to the invention do not differ in any way from the processes conventionally used in cosmetics and with which those skilled in the art are fully familiar.
The compositions according to the invention may be in the form of a product for making up the skin, such as a foundation, a blusher, an eyeshadow or a lipstick, or even in the form of a hair product such as a styling make-up gel.
Examples of compositions according to the invention will now be given by way of example, without any limiting nature being implied.
Make-up gels having the following compositions (in g) were prepared:
Compos. A
Compos. B
Compos. C
A)
Polydimethylsiloxane
67.50
67.50
67.50
at a concentration
of 12-14% in
cyclopentasiloxane
(Q2-1401 from Dow)
B)
TiO2 + iron oxides*
3.36
3.36
3.36
C)
cyclopentadimethyl-
9.50
9.50
—
siloxane
D)
Gelling agent
bentone gel IMP (NL
18.64
19.14
—
Industrie)
bentone gel VS-5 PC
—
28.14
28.14
(Stearinerie Dubois)
E)
Fillers
Expancel
1.00
1.00
1.00
microspheres
Teflon Ceri-dust
—
2.00
—
*Non-coated pigments
A) and B) were mixed together with a spatula and were passed 3 times through a cylinder mill. C), D) and E) were then added with moderate stirring.
Three formulae were obtained, which contained a large proportion of silicone-containing compounds and which made it possible to obtain, after spreading on the skin, a coloured and water-resistant make-up.
Although the pigments used were not precoated, the pigments were fully dispersed in the composition and the make-up obtained was homogeneous.
Self-tanning compositions having the following compositions (in g) were prepared:
Compos. D
Compos. E
Compos. F
A)
Polydimethylsiloxane
67.50
67.50
67.50
at a concentration
of 12-14% in
cyclopentasiloxane
(Q2-1401)
B)
TiO2 + iron oxides*
3.36
3.36
3.36
C)
Crosslinked silicone
20.00
10.00
10.00
powder in a PDMS
(KSG 16 from Shin
Etsu)
bentone gel VS-5 PC
—
10.00
—
(Dubois)
Unitwix (United
—
—
—
Guardian)
D)
Polyvinylidene
1.00
1.00
1.00
E)
Silicone oils
Alkyldimethicone
—
—
5.00
X2-1731 (Dow)
Cyclopentadimethyl-
qs 100
qs 100
qs 100
siloxane
*Non-coated pigments
Thickened gelled creams were obtained, which were easy and pleasant to apply, and which gave a homogeneous and uniform coloration of natural appearance to the skin.
Water-resistant silicone-containing self-tanning compositions having the following compositions (in g) were prepared:
Compos. G
Compos. H
A)
Silcone oil (AK 500,000
10.00
—
from Wacker)
Polydimethylsiloxane at a
6.64
12.30
concentration of 12-14% is
cyclomethicone (Q2-1401 from
Dow)
Polyphenylsiloxane at a
—
40.00
concentration of 15% in
cyclopentadimethylsiloxane
(Silbione 71634 from Rhone-
Poulenc)
B)
TiO2 + iron oxides*
3.36
7.7
C)
Crosslinked silicone powder
20.00
10.00
(KSG 16 from Shin Etsu)
D)
Gelling agent (Bentone gel
—
18.00
VS38 from Rhéox)
E)
Silicone-containing resin
—
5.00
beads (Tospearl 120 from
Toshiba)
F)
Cyclopentadimethylsiloxane
60.00
qs 100
*Non-coated pigments
Coloured and water-resistant self-tanning compositions were obtained in the form of gels.
A lipstick having the following composition was prepared:
Polydimethylsiloxane at a concentration of
70.00
12-14% in cyclomethicone (Q2-1401)
Crosslinked silicone powder in PDMS (KSG 16
10.00
from Shin Etsu)
Cyclopentadimethylsiloxane
10.00
Silicone-coated titanium oxide
2.83
Silicone-coated iron oxides
4.70
D&C red No. 7
0.47
Titanium mica
2.00
A fluid gelled cream of red-pink colour with an iridescent effect was obtained, which was smooth upon application and had good staying power.
A screening tanning fluid having the following composition was prepared:
Polydimethylsiloxane at a concentration
70.00
of 12-14% in cyclomethicone (Q2-1401)
UV screening agents Parsol MCX from BASF
7.00
Hydroxy-4-methoxybenzophenone
2.00
FINSOLV TN (C12-C15 alkyl benzoate) from Finetax
9.00
Jojoba oil
1.00
α-tocopheryl acetate
1.00
Ethanol
4.70
Fragrance
0.30
Crosslinked silicone powder in PDMS (KSG 16
10.00
from Shin Etsu)
TiO2 + iron oxides (non-coated)
1.70
A shiny, smooth brown-coloured tanning fluid was obtained, which was easy to apply and gave a homogeneous and uniform coloration of natural appearance to the skin.
Mellul, Myriam, Thau, Paul, Fehn, Paul, Pinzon, Carlos
| Patent | Priority | Assignee | Title |
| 10888514, | Sep 24 2019 | L Oreal | Cosmetic compositions |
| 11141359, | Mar 30 2018 | L'Oreal | Anhydrous cosmetic composition |
| 7790202, | Apr 09 2007 | MARTELL, HELEN D; MARTELL, SYLVIA P; DAVIS, OLIVIA J | Multi-purpose skin composition |
| 8003120, | Oct 22 2008 | ELC Management LLC | Powder makeup compositions and methods |
| Patent | Priority | Assignee | Title |
| 2230063, | |||
| 2548970, | |||
| 2566722, | |||
| 2578210, | |||
| 2676182, | |||
| 2678878, | |||
| 2678893, | |||
| 2681878, | |||
| 3541205, | |||
| 3600186, | |||
| 3642635, | |||
| 3646214, | |||
| 3836647, | |||
| 3857805, | |||
| 3927199, | |||
| 4005195, | Feb 12 1976 | Procter & Gamble Company, The | Compositions for treating hypercholesterolemia |
| 4005196, | Feb 12 1976 | The Procter & Gamble Company | Vitaminized compositions for treating hypercholesterolemia |
| 4119712, | Jul 25 1977 | Revlon Consumer Products Corporation | Makeup foundations |
| 4192861, | May 05 1978 | National Starch and Chemical Corporation | Hydrocarbon propelled aerosol hair spray compositions |
| 4283384, | Nov 08 1976 | SOCIETE ANONYME DITE: L OREAL | Cosmetic compositions containing polymers produced in the presence of cerium ions |
| 4315910, | Mar 11 1977 | National Starch and Chemical Corporation | Aerosol hair spray compositions |
| 4409203, | Mar 21 1980 | BORDEN CHEMICAL, INC A NEW JERSEY CORPORATION | Non-nitrocellulose non-formaldehyde or formaldehyde resin nail polish employing an acrylate resin as the film former |
| 4421769, | Sep 29 1981 | The Procter & Gamble Company | Skin conditioning composition |
| 4421881, | Mar 23 1981 | DEL LABORATORIES, INC | Nitrocellulose lacquer composition containing gelatin and acrylic copolymers |
| 4425364, | Feb 02 1976 | SOCIETE ANONYME DITE: L OREAL | Compositions containing an organo-silicon compound |
| 4431673, | May 02 1980 | Revlon Consumer Products Corporation | Cosmetic compositions |
| 4486405, | Apr 19 1983 | William H. Rorer, Inc. | Pigmented cosmetic vehicle containing a mixture of alkoxylated surfactants |
| 4515784, | Nov 16 1983 | Richardson-Vicks Inc. | Reducing sebum spreading |
| 4534961, | May 25 1978 | Wax base makeup composition | |
| 4574082, | Jul 29 1983 | Revlon Consumer Products Corporation | One-phase silicone-based cosmetic products containing wax |
| 4578266, | Jul 29 1983 | Revlon Consumer Products Corporation | Silicone-based cosmetic products containing pigment |
| 4601757, | Mar 07 1985 | DeSoto, Inc. | Nonvolatile plasticizers and nail polish containing the same |
| 4649045, | Apr 03 1986 | DeSoto, Inc. | Coating compositions and nail polish compositions including the same |
| 4673570, | Mar 20 1985 | CHURCH & DWIGHT CO , INC | Gelled antiperspirant compositions |
| 4678663, | Feb 06 1984 | Nuetrogena Corporation | Hydroquinone composition having enhanced bio-availability and percutaneous adsorption |
| 4699780, | May 29 1985 | Estee Lauder Inc. | Cosmetic composition |
| 4725495, | Oct 30 1986 | Minnesota Mining and Manufacturing Company | Lipstick sampling device |
| 4725658, | Sep 12 1985 | General Electric Company | Novel silicone-ester waxes |
| 4747419, | Jun 17 1986 | Chesebrough-Pond's, Inc. | Nail polish compositions and means for applying same |
| 4777041, | Aug 07 1986 | REVLON, INC | Wrinkle treatment formulation |
| 4792444, | Jun 14 1985 | Kao Corporation | Cosmetic comprising fluoroalkyl (meth)acrylate copolymers |
| 4795631, | Mar 26 1986 | Chesebrough-Pond's, Inc. | Water based lip color comprising an alkali soluble film-forming agent |
| 4797272, | Nov 15 1985 | ELIZABETH ARDEN COMPANY, A DIVISION OF LEVER BROTHERS COMPANY | Water-in-oil microemulsions for cosmetic uses |
| 4800076, | Mar 13 1987 | JOHNSON & JOHNSON CONSUMER PRODUCTS, INC , A NJ CORP | Skin care compositions |
| 4801447, | Feb 22 1984 | General Electric Company | Water-in-volatile silicone emulsifier concentrates, water-in-volatile silicone emulsions that are useful in personal-care formulations and methods of making same |
| 4803067, | Mar 29 1985 | AUSIMONT S P A | Compositions for cosmetics and dermatology comprising perfluoropolyethers |
| 4826828, | Feb 15 1985 | Avon Products, Inc. | Composition and method for reducing wrinkles |
| 4837011, | Sep 08 1987 | Revlon Consumer Products Corporation | Cosmetic powder employing spherical silica particles |
| 4839163, | Sep 09 1986 | COSMET PRODUCTS, INC , A CORP OF DE | Facial cosmetic liquid containing crystalline silica and colors |
| 4855129, | Nov 25 1986 | Bayer Aktiengesellschaft | Skin-protecting or skin-care composition |
| 4873078, | Apr 22 1988 | INTELLECTUAL PROPERTY HOLDING CO | High-gloss, high-shine lipstick |
| 4888363, | Jul 29 1986 | AVON PRODUCTS, INC , A CORP OF NY | Anhydrous cosmetic preparation |
| 4897261, | May 19 1987 | Shiseido Company Ltd. | Fingernail cosmetic composition |
| 4904698, | Feb 11 1988 | OcuSoft Inc. | Eyelid cleansing composition |
| 4935228, | Dec 28 1987 | L'Oreal S.A. | Lip gloss |
| 4946302, | Jan 31 1989 | Mitsubishi Pencil Co., Ltd. | Liquid applicator with resilient brush mounting |
| 4950468, | Sep 08 1988 | Sunstar Kabushiki Kaisha | Hair treating composition |
| 4954532, | Feb 01 1984 | THE MENTHOLATUM COMPANY | Cosmetic formulaton |
| 4966933, | Aug 02 1988 | Toray Industries, Inc. | Propylene polymer film |
| 4980167, | Jan 31 1989 | Dow Corning Toray Silicone Company, Ltd. | Silicone cosmetic composition |
| 4983388, | Sep 12 1988 | Shin-Etsu Chemical Co., Ltd. | Process of preparing silicone composition, and cosmetic and lustering materials containing silicone composition obtained |
| 4988503, | Jan 24 1990 | Revlon Consumer Products Corporation | Oil-in-water emulsions for foundation makeup composition |
| 4992477, | Apr 04 1988 | Johnson & Johnson Consumer Companies, Inc | Skin moisturizing composition and method of preparing same |
| 4994264, | Dec 15 1989 | Revlon Consumer Products Corporation | Press molded cosmetic composition with pay off |
| 4996239, | Sep 16 1988 | Neutrogena Corporation | Water resistant cream conditioner |
| 5002762, | Mar 16 1988 | The Procter & Gamble Company; Procter & Gamble Company, The | Volatile silicons in household and cosmetic products |
| 5011680, | Mar 13 1985 | Kao Corporation | Solid cosmetic preparation |
| 5013763, | Nov 30 1987 | The Andrew Jergens Company; ANDREW JERGENS COMPANY, THE, 2535 SPRING GROVE AVENUE, CINCINNATI, OHIO A CORP OF DE | Wash-off-resistant skin preparation |
| 5015469, | Jan 12 1988 | Shideido Company Ltd. | Water-in-oil emulsion type cosmetics |
| 5023075, | Oct 10 1989 | Revlon Consumer Products Corporation | Microfine cosmetic powder comprising polymers, silicone, and lecithin |
| 5036108, | Dec 14 1988 | Kao Corporation | Water-in-oil emulsion cosmetic |
| 5045309, | Dec 27 1989 | Quick drying nail polish | |
| 5051489, | Jan 25 1990 | Siltech Inc. | Novel silanol waxes |
| 5053221, | Nov 20 1989 | INTELLECTUAL PROPERTY HOLDING CO | Novel mascara composition having very small particles |
| 5061481, | Mar 20 1989 | Kobayashi Kose Co., Ltd. | Cosmetic composition having acryl-silicone graft copolymer |
| 5063057, | Sep 26 1990 | FD MANAGEMENT, INC | Cosmetic capsules |
| 5073364, | Jun 19 1990 | Revlon Consumer Products Corporation | Pressed powder cosmetic product |
| 5073372, | Nov 30 1990 | RICHARDSON-VICKS INC | Leave-on facial emulsion compositions |
| 5085855, | Jul 18 1990 | MARY KAY INC | Silicone based cosmetic product |
| 5085856, | Jul 25 1990 | FD MANAGEMENT, INC | Cosmetic water-in-oil emulsion lipstick comprising a phospholipid and glycerol fatty acid esters emulsifying system |
| 5089256, | Aug 05 1986 | Wurttembergische Parfumerie-Fabrik GmbH | Process for preparing solid powder formulations having different colors |
| 5093108, | Feb 16 1989 | AMALIA, INC | Quick-drying nail enamel compositions and method for coating a surface |
| 5093111, | Mar 11 1991 | BT COMMERCIAL CORPORATION | Lipstick composition comprising cetearyl isononanoate, a sesquistearate and isopropyl hydroxystearate |
| 5104586, | Mar 23 1989 | Unilever Patent Holdings B.V. | Diesters and their use in waxes |
| 5106609, | Aug 07 1989 | The Procter & Gamble Company | Vehicle systems for use in cosmetic compositions |
| 5106611, | Nov 22 1988 | L'Oreal | Use of modified diorganopolysiloxanes as antioxidants in cosmetics or in dermatology |
| 5106625, | Aug 09 1989 | Kao Corporation | Composition for external application consisting essentially of a dextrin fatty acid ester, a glycerol fatty acid ester and an oil |
| 5108736, | Sep 04 1987 | KOBO PRODUCTS, INC | Method of incorporating cosmetic pigments and bases into products containing oil and water phases |
| 5118496, | Oct 02 1990 | Coated cosmetic materials and method of coating cosmetic materials | |
| 5118507, | Jun 25 1991 | FD MANAGEMENT, INC | Silicone based cosmetic composition |
| 5126126, | Nov 20 1990 | Dow Corning Corporation; DOW CORNING CORPORATION, A MI CORP | Hair fixatives |
| 5141741, | Dec 09 1988 | Lion Corporation | Anti-sunburn skin-care preparation |
| 5143722, | Dec 19 1986 | REVLON CONSUMER PRODUCTS CORPORATION A DE CORP | Cosmetic makeup compositions comprising water-in-oil emulsions containing pigment |
| 5143723, | Nov 23 1988 | ESTEE LAUDER INC , A CORP OF DELAWARE | Colored cosmetic compositions |
| 5158772, | Sep 23 1991 | Unique bacterial polysaccharide polymer gel in cosmetics, pharmaceuticals and foods | |
| 5160738, | Jul 09 1990 | CHESEBROUGH-POND S USA CO , DIVISION OF CONOPCO INC A CORPORATION OF NY | Cosmetic composition |
| 5183588, | Oct 13 1989 | Yves Saint Laurent Parfums | Ternary system based on perfluorinated ethers |
| 5183589, | Mar 31 1989 | AUSIMONT S R L | Stable emulsions of perfluoropolyethers |
| 5196187, | May 10 1990 | CHESEBROUGH-POND S USA CO , A DIVISION OF CONOPCO INC , A CORPORATION OF NY | Cosmetic composition |
| 5206012, | Feb 28 1990 | L Oreal | Combination of hollow microspheres of a thermoplastic synthetic material, hexagonal boron nitride and N-acyl lysine as a homogenization agent for cosmetic compacted powders |
| 5208012, | Jul 31 1991 | SHIZUKA, HARUO | Anti-inflammatory or anti-sunburn cosmetic composition |
| 5210251, | Mar 15 1990 | Kao Corporation | Ester-modified silicone derivative and a cosmetic composition containing the same |
| 5213716, | Jun 21 1989 | Colgate-Palmolive Company | Hair conditioning shampoo containing long chain alcohol component |
| 5213799, | Jan 10 1991 | Goldwell AG | Two-phase cosmetic composition |
| 5216033, | Jun 29 1989 | CHESEBROUGH-POND S USA CO , DIVISION OF CONOPCO, INC | Water-in-oil transparent emulsion for the skin |
| 5219560, | Mar 20 1989 | Kobayashi Kose Co., Ltd. | Cosmetic composition |
| 5223559, | Feb 28 1991 | L Oreal | Cosmetic composition capable of blurring skin defects |
| 5225186, | Jun 21 1990 | REVLON CONSUMER PRODUCTS CORPORATION A DE CORP | High cosmetic powder lipstick composition |
| 5234682, | Jun 21 1990 | Revlon Consumer Products Corporation | Cosmetic compositions |
| 5238678, | Jul 19 1991 | POLA Chemical Industries, Inc. | Double-coat type make-up cosmetic product containing aluminum powder |
| 5246780, | Aug 29 1991 | L Oreal | Coated particle for use in cosmetic preparations and method |
| 5260401, | Feb 19 1992 | SILTECH CORP | Terminal fluorine containing silicone polyester compounds |
| 5262087, | May 01 1991 | Kose Corporation; SHIN-ETSU CHEMICAL CO , LTD | Water-in-oil type emulsified composition |
| 5266321, | Mar 31 1988 | SHIN-ETSU CHEMICAL CO , LTD 50% | Oily make-up cosmetic comprising oil base and silicone gel composition |
| 5268175, | Feb 17 1992 | Indena SpA | Cosmetic and/or pharmaceutical compositions and methods for their use |
| 5271934, | Oct 22 1990 | Revlon Consumer Products Corporation | Encapsulated antiperspirant salts and deodorant/antiperspirants |
| 5283062, | Sep 10 1992 | ELIZABETH ARDEN COMPANY, DIVISION OF CONOPCO, INC | Color cosmetic composition |
| 5288482, | Mar 11 1993 | Dow Corning Corporation | Silicone containing lip care cosmetic composition |
| 5288493, | May 17 1991 | Akzo Nobel N V | Skin care compositions with improved rub-off resistance |
| 5292530, | Jun 02 1991 | Helene Curtis, Inc. | Stable anhydrous topically-active composition and suspending agent therefor |
| 5302380, | Jun 08 1992 | REVLON CONSUMER PRODUCTS CORPORATION A CORP OF DELAWARE | Cosmetic compositions containing atactic polypropylenes and related methods |
| 5302382, | Jun 03 1993 | Dow Corning Corporation | Silicone containing personal care products |
| 5304325, | Nov 13 1991 | HemaGen/PFC | Emulsions containing alkyl- or alkylglycerophosphoryl choline surfactants and methods of use |
| 5306498, | Apr 05 1991 | L'Oreal | Cosmetic composition in the form of a triple emulsion |
| 5310547, | Jun 28 1991 | HSBC BANK, USA AS COLLATERAL AGENT; FD MANAGEMENT, INC | Colored cosmetic sticks |
| 5312968, | Sep 07 1993 | BUFFA, CHARLES W | Fluorine containing guerbet citrate esters |
| 5318775, | Jul 18 1990 | Mary Kay Cosmetics, Inc. | Silicone based cosmetic product |
| 5324506, | Nov 23 1988 | Estee Lauder, Inc. | Colored cosmetic compositions |
| 5328683, | Feb 28 1992 | Dow Corning Toray Silicone Co., Ltd. | Water repellent and method of preparation |
| 5330747, | Feb 03 1993 | Dow Corning Corporation | Cosmetics with enhanced durability |
| 5334372, | Oct 07 1988 | Kao Corporation | Alcohol-modified silicon ester derivative and cosmetic composition containing same |
| 5338536, | Aug 08 1991 | GENERAL ELECTRIC COMPANY, A CORP OF NY | Personal care compositions containing polyalkylsiloxane copolymers |
| 5340569, | Sep 10 1992 | FD MANAGEMENT, INC | Color cosmetic composition |
| 5346642, | Jun 21 1989 | Colgate-Palmolive Company | Hair conditioning shampoo containing long chain alcohol component |
| 5362482, | Dec 20 1988 | Shiseido Company Ltd. | Water-in-oil emulsion solid cosmetic composition |
| 5364325, | Jun 18 1993 | Leveraged weight compounding system | |
| 5364633, | Mar 14 1994 | Dow Corning Corporation | Silicone vesicles and entrapment |
| 5368848, | Apr 04 1990 | SIGNAL INVESTMENT & MANAGEMENT CO , A CORPORATION OF DELAWARE | Cosmetic gel stick compositions |
| 5380527, | Aug 26 1991 | Dow Corning Corporation | Alkylmethylsiloxane mixtures for skin care |
| 5382433, | Oct 25 1989 | Avon Products, Inc. | Pigmented cosmetic compositions and method of making same |
| 5385730, | Jan 26 1989 | Shin-Etsu Chemical Co., Ltd. | Lactone-modified silicone compositions and cosmetic agents or lustering agents containing them |
| 5387417, | Aug 22 1991 | Dow Corning Corporation | Non-greasy petrolatum emulsion |
| 5389365, | Feb 07 1994 | Dow Corning Corporation | Silicone terpolymer containing water-in-oil emulsion derived from unsaturated ethylene oxides |
| 5393526, | Feb 07 1994 | FD MANAGEMENT, INC | Cosmetic compositions |
| 5397566, | Aug 08 1991 | General Electric Company | Personal care compositions containing polyalkylsiloxane copolymers |
| 5412004, | Nov 21 1991 | Kose Corporation; Shin-Etsu Chemical Co., Ltd. | Silicone polymer, paste-like silicone composition, and w/o-type cosmetic composition comprising the same |
| 5413792, | Mar 26 1990 | Dow Corning K.K.; Nippon Kayaku Kabushiki Kaisha | Mucoadhesive polysiloxane paste-like base and preparation |
| 5417967, | Oct 07 1988 | Kao Corporation | Alcohol-modified silicone ester derivative and cosmetic compositions containing same |
| 5430082, | Jan 14 1993 | Dow Corning GmbH | Elastomer-forming composition |
| 5446114, | Dec 15 1994 | SILTECH CORP | Fluorinated dimethicone copolyols |
| 5451610, | Feb 03 1993 | Dow Corning Corporation | Cosmetics with enhanced durability |
| 5462737, | May 23 1994 | STC ENGLISH IDEAS, INC | Chemical composition for lipstick sealant |
| 5466457, | Mar 01 1993 | Beiersdorf Aktiengesellschaft | Cosmetic sticks |
| 5478552, | Jul 16 1993 | Mitsubishi Pencil Kabushiki Kaisha | Liquid cosmetic composition |
| 5486355, | Dec 08 1992 | Church & Dwight Co., Inc. | Homogeneous cosmetic stick products |
| 5488121, | Oct 31 1994 | SILTECH CORP | Di-guerbet esters |
| 5494938, | Jan 25 1990 | COGNIS DEUTSCHLAND GMBH & CO KG | Oil-in-water emulsions |
| 5496544, | Mar 05 1992 | L'Oreal | Powdered cosmetic composition containing a silicone fatty binder |
| 5500138, | Oct 20 1994 | The Procter & Gamble Company; Procter & Gamble Company, The | Fabric softener compositions with improved environmental impact |
| 5500154, | Oct 20 1994 | The Procter & Gamble Company; Procter & Gamble Company, The | Detergent compositions containing enduring perfume |
| 5505937, | Dec 15 1992 | Revlon Consumer Products Corporation | Cosmetic compositions with improved transfer resistance |
| 5512272, | Feb 03 1993 | Dow Corning Corporation | Cosmetics with enhanced durability |
| 5589165, | Dec 28 1993 | Shiseido Co., Ltd. | Cosmetic |
| 5648066, | Oct 03 1995 | Estee Lauder, Inc | Solid silicone compositions and methods for their preparation and use |
| 5665364, | Jul 24 1995 | Procter & Gamble Company, The | Compositions for topical delivery of active ingredients |
| 5725845, | Nov 03 1995 | Revlon Consumer Products Corporation | Transfer resistant cosmetic stick compositions with semi-matte finish |
| 5738841, | Jan 30 1995 | L Oreal | Cosmetic composition comprising a silicone-containing compound and a fatty acid ester |
| 5747017, | May 15 1995 | NICHOLS, ROSEMARIE | Lip cosmetic |
| 5800816, | Oct 25 1994 | Revlon Consumer Products Corporation | Cosmetic compositions |
| 5837223, | Aug 12 1996 | Revlon Consumer Products Corporation | Transfer resistant high lustre cosmetic stick compositions |
| 5849316, | Sep 30 1994 | L'Oreal | Anhydrous and water resistant cosmetic compositions |
| 5902592, | Oct 10 1994 | L'Oreal | Cosmetic composition comprising cyclopentadimethylsiloxane and cyclohexadimethylsiloxane in fatty phase |
| 5911974, | Oct 25 1994 | Revlon Consumer Products Corporation | Cosmetic compositions |
| 5925337, | Mar 01 1990 | L'Oreal | Waterproof composition for covering the eyelashes, and process for the preparation thereof |
| 5965112, | Oct 25 1994 | Revlon Consumer Products Corporation | Cosmetic compositions |
| 5985298, | Oct 25 1994 | Revlon Consumer Products Corporation | Cosmetic compositions |
| 6001374, | May 15 1995 | NICHOLS, ROSEMARIE | Smear-resistant cosmetic |
| 6010709, | May 15 1996 | NICHOLS, ROSEMARIE | Smear-resistant cosmetic |
| 6019962, | Nov 07 1995 | GALLERIA CO | Compositions and methods for improving cosmetic products |
| 6027739, | May 15 1996 | NICHOLS, ROSEMARIE | Smear-resistant cosmetic |
| 6036947, | Aug 12 1996 | Revlon Consumer Products Corporation | Transfer resistant high lustre lipstick compositions |
| 6071503, | Nov 07 1995 | GALLERIA CO | Transfer resistant cosmetic compositions |
| 6074654, | Nov 07 1995 | GALLERIA CO | Transfer resistant cosmetic compositions |
| 6139823, | Nov 07 1995 | GALLERIA CO | Transfer resistant cosmetic compositions |
| 6203809, | May 15 1995 | NICHOLS, ROSEMARIE | Smear-resistant cosmetic |
| 6274152, | Oct 25 1994 | Revlon Consumer Products Corporation | Cosmetic compositions |
| 6395263, | May 15 1995 | Rosemarie, Nichols | Smear-resistant cosmetic |
| 6464964, | Oct 25 1994 | Revlon Consumer Products Corporation | Cosmetic compositions |
| 6509009, | May 15 1995 | NICHOLS, ROSEMARIE | Smear-resistant cosmetic |
| 6562322, | Oct 25 1994 | Revlon Consumer Products Corporation | Cosmetic compositions |
| DE3744352, | |||
| DE3837473, | |||
| DE4025040, | |||
| EP5922, | |||
| EP133963, | |||
| EP151984, | |||
| EP179416, | |||
| EP200839, | |||
| EP205961, | |||
| EP272832, | |||
| EP381166, | |||
| EP381376, | |||
| EP388582, | |||
| EP504966, | |||
| EP515195, | |||
| EP519727, | |||
| EP521647, | |||
| EP548694, | |||
| EP590192, | |||
| EP602905, | |||
| EP610026, | |||
| EP709083, | |||
| EP748622, | |||
| FR2556940, | |||
| FR2638636, | |||
| FR2688134, | |||
| FR2707485, | |||
| GB1476194, | |||
| GB1476195, | |||
| GB1569009, | |||
| GB2027341, | |||
| GB2107186, | |||
| GB2197783, | |||
| GB2198037, | |||
| GB2211081, | |||
| GB2274585, | |||
| GB2294392, | |||
| JP4045155, | |||
| JP5065212, | |||
| JP5221829, | |||
| JP55028906, | |||
| JP59172495, | |||
| JP6024932, | |||
| JP6024933, | |||
| JP6072085, | |||
| JP6107518, | |||
| JP61161211, | |||
| JP6118708, | |||
| JP6165809, | |||
| JP6166611, | |||
| JP63230618, | |||
| JP7267820, | |||
| JP8092034, | |||
| JP8092036, | |||
| JP826936, | |||
| JP881335, | |||
| JPHO61158913, | |||
| JPHO6165809, | |||
| JPHO62298512, | |||
| WO8602001, | |||
| WO9108733, | |||
| WO9219215, | |||
| WO9619185, | |||
| WO9640044, | |||
| WO9701321, | |||
| WO9717057, | |||
| WO9717058, |
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