An existing stacked capacitor fabrication process is modified to construct a three-dimensional stacked container capacitor. The present invention develops the container capacitor by etching an opening (or contact opening) into a low etch rate oxide. The contact opening is used as a form for deposited polysilicon that conforms to the sides of the opening walls. Within the thin poly lining of the oxide container a high etch-rate oxide, such as ozone TEOS, is deposited over the entire structure thereby bridging across the top of the oxide container. The high etch-rate oxide is planarized back to the thin poly and the resulting exposed poly is then removed to separate neighboring containers. The two oxides, having different etch rates, are then etched thereby leaving a free-standing poly container cell with 100% (or all) of the higher etch rate oxide removed and a pre-determined oxide surrounding the container still intact.

Patent
   RE39665
Priority
Mar 13 1992
Filed
Dec 12 2001
Issued
May 29 2007
Expiry
Mar 13 2012
Assg.orig
Entity
unknown
0
15
EXPIRED
0. 61. A process for fabricating a capacitor on a substrate, said process comprising the steps of:
providing a first insulating layer on said substrate, said first insulating layer having an opening therein forming a container;
forming a generally conformal first conductive layer, over said first insulating layer and in said container;
forming a second insulating layer over the entire said first conductive layer; and
removing a portion of said second insulating layer overlying an uppermost portion of portion of said first conductive layer through use of chemical mechanical planarization until said uppermost portion of said first conductive layer is exposed.
0. 66. A process for fabricating a dram containing storage capacitor on a silicon substrate having an existing topography including active areas, word lines and digit lines, said process comprising the steps of:
providing a first insulating layer having a first etch rate, over said existing topography;
forming an opening into said first insulating layer, said opening thereby forming a container;
forming a conformal first conductive layer over said first insulating layer and said container, thereby lining said container;
forming a second insulating layer, having a second etch rate, over the entire said first conductive layer; and
removing said second insulating layer through use of chemical mechanical planarization until an uppermost portion of said conductive layer is exposed.
0. 71. A process for fabricating a dram container storage capacitor on a silicon substrate having an existing topography including active areas, word lines and digit lines, said process comprising the steps of:
providing a first insulating layer, having a first etch rate, over said existing topography;
forming an opening into said first insulating layer, said opening thereby forming a container;
forming a conformal first conductive layer over said first insulating layer and said container, thereby lining said container;
forming a second insulating layer, having a second etch rate, over the entire said first conductive layer; and
removing said second insulating layer through use of chemical mechanical planarization until an uppermost portion of said first conductive layer is exposed;
removing at least a portion of said upper portion of said first conductive layer until said first insulating layer is exposed, thereby forming a conductive container having inner and outer walls.
0. 1. A process for fabricating a uniform and repeatable conductive container structure on a starting substrate's existing topography, said process comprising the steps of:
a) forming a blanketing first insulating layer, having a first etch rate, over said existing topography;
b) patterning and etching an opening into said first insulating layer, said opening thereby forming a container form;
c) forming a conformal first conductive layer superjacent said first insulating layer and said container form thereby lining said container form;
d) forming a blanketing second insulating layer, having a second etch rate, superjacent said first conductive layer;
e) removing said second insulating layer via chemical mechanical planarization until upper portion of said first conductive layer is exposed;
f) removing said exposed first conductive upper layer until underlying said first insulating layer is exposed thereby separating said first conductive layer into individual said conductive containers having inner and outer walls;
g) removing said first and said second insulating layers such that said second insulating layer is completely removed thereby exposing the entire inner walls of said conductive container and said first insulating layer is partially removed thereby exposing an upper portion of said outer walls of said conductive container, wherein the partially remaining first insulating layer provides insulation between said underlying substrate topography and subsequently formed layers;
h) forming a third insulating layer superjacent and coextensive said exposed walls and inner bottom portion of said container and said partially remaining first insulating layer; and
i) forming a second conductive layer superjacent and coextensive said third insulating layer.
0. 2. A process as recited in claim 1, wherein said first insulating layer is planarized prior to said step of patterning and etching an opening into said first insulating layer.
0. 3. A process as recited in claim 1, wherein said second insulating layer is a sacrificial layer conducive to said chemical mechanical planarization.
0. 4. A process as recited in claim 1, wherein said first and said second insulating layers are oxides.
0. 5. A process as recited in claim 1, wherein said first insulating layer etch rate is a lower etch rate than said second insulating layer etch rate.
0. 6. A process as recited in claim 5, wherein the etch rate ratio between said second insulating layer etch rate and said first insulating layer etch rate is a ratio of 2:1 or greater.
0. 7. A process as recited in claim 5, wherein the etch rate ratio between said second insulating layer etch rate and said first insulating layer etch rate is a ratio of 4:1.
0. 8. A process as recited in claim 1, wherein said first and said second conductive layers are doped polysilicon.
0. 9. A process as recited in claim 8, wherein said doped polysilicon is formed by insitu doped chemical vapor deposition.
0. 10. A process as recited in claim 1, wherein said first, said second and said third insulating layers are formed by chemical vapor deposition.
0. 11. A process for fabricating a uniform and repeatable conductive container structure on a starting substrate's existing topography, said process comprising the steps of:
a) forming a blanketing first insulating layer, having a first etch rate, over said existing topography;
b) patterning and etching an opening into said first insulating layer, said opening thereby forming a container form;
c) forming a conformal first conductive layer superjacent said first insulating layer and said container form thereby lining said container form;
d) forming a blanketing second insulating layer, having a second etch rate, superjacent said first conductive layer;
e) removing said second insulating layer until upper portion of said first conductive layer is exposed;
f) removing said exposed first conductive upper layer via chemical mechanical planarization until underlying said first insulating layer is exposed thereby separating said first conductive layer into individual said conductive containers having inner and outer walls;
g) removing said first and second insulating layers such that said second insulating layer is completely removed thereby exposing the entire inner walls of said conductive container and said first insulating layer is partially removed thereby exposing an upper portion of said outer walls of said conductive container, wherein the partially remaining first insulating layer provides insulation between said underlying substrate topography and subsequently formed layers;
h) forming a third insulating layer superjacent and coextensive said exposed walls and inner bottom portion of said container and said partially remaining first insulating layer; and
i) forming a second conductive layer superjacent and coextensive said third insulating layer.
0. 12. A process as recited in claim 1, wherein said first insulating layer is planarized prior to said step of patterning and etching an opening into said first insulating layer.
0. 13. A process as recited in claim 1, wherein said second insulating layer is a sacrificial layer that is planarized by chemical mechanical planarization.
0. 14. A process as recited in claim 1, wherein said first and said second insulating layers are oxides.
0. 15. A process as recited in claim 1, wherein said first insulating layer etch rate is a lower etch rate than said second insulating layer etch rate.
0. 16. A process as recited in claim 15, wherein the etch rate ratio between said second insulating layer etch rate and said first insulating layer etch rate is a ratio of 2:1 or greater.
0. 17. A process as recited in claim 15, wherein the etch rate ratio between said second insulating layer etch rate and said first insulating layer etch rate is a ratio of 4:1.
0. 18. A process as recited in claim 1, wherein said first and said second conductive layers are doped polysilicon.
0. 19. A process as recited in claim 18, wherein said doped polysilicon is formed by insitu doped chemical vapor deposition.
0. 20. A process as recited in claim 1, wherein said first, said second and said third insulating layers are formed by chemical vapor deposition.
0. 21. A process for fabricating a uniform and repeatable conductive container structure on a starting substrate's existing topography, said process comprising the steps of:
a) forming a blanketing first insulating layer, having a first etch rate, over said existing topography;
b) patterning and etching an opening into said first insulating layer, said opening thereby forming a container form;
c) forming a conformal first conductive layer superjacent said first insulating layer and said container form thereby lining said container form;
d) forming a blanketing second insulating layer, having a second etch rate, superjacent said first conductive layer;
e) removing said second insulating layer via chemical mechanical planarization until upper portion of said first conductive layer is exposed;
f) removing said exposed first conductive upper layer via chemical mechanical planarization until underlying said first insulating layer is exposed thereby separating said first conductive layer into individual said conductive containers having inner and outer walls;
g) removing said first and said second insulating layers such that said second insulating layer is completely removed thereby exposing the entire inner walls of said conductive container and said first insulating layer is partially removed thereby exposing an upper portion of said outer walls of said conductive container, wherein the partially remaining first insulating layer provides insulation between said underlying substrate topography and subsequently formed layers;
h) forming a third insulating layer superjacent and coextensive said exposed walls and inner bottom portion of said container and said partially remaining first insulating layer; and
i) forming a second conductive layer superjacent and coextensive said third insulating layer.
0. 22. A process as recited in claim 21, wherein said first insulating layer is planarized prior to said step of patterning and etching an opening into said first insulating layer.
0. 23. A process as recited in claim 21, wherein said second insulating layer is a sacrificial layer conducive to said chemical mechanical planarization.
0. 24. A process as recited in claim 21, wherein said first and said second insulating layers are oxides.
0. 25. A process as recited in claim 21, wherein said first insulating layer etch rate is a lower etch rate than said second insulating layer etch rate.
0. 26. A process as recited in claim 25, wherein the etch rate ratio between said second insulating layer etch rate and said first insulating layer etch rate is a ratio of 2:1 or greater.
0. 27. A process as recited in claim 25, wherein the etch rate ratio between said second insulating layer etch rate and said first insulating layer etch rate is a ratio ob 4:1.
0. 28. A process as recited in claim 21, wherein said first and said second conductive layers are doped polysilicon.
0. 29. A process as recited in claim 28, wherein said doped polysilicon is formed by insitu doped chemical vapor deposition.
0. 30. A process as recited in claim 21, wherein said first, said second and said third insulating layers are formed by chemical vapor deposition.
0. 31. A process for fabricating a dram container storage capacitor on a silicon substrate having active areas, word lines and digit lines, said process comprising the following sequence of steps:
a) forming a blanketing first insulating layer, having a first etch rate, over said existing topography;
b) patterning and etching an opening into said first insulating layer, said opening thereby forming a container form;
c) forming a conformal first conductive layer superjacent said first insulating layer and said container form thereby lining said container form;
d) forming a blanketing second insulating layer, having a second etch rate, superjacent said first conductive layer;
e) removing said second insulating layer via chemical mechanical planarization until upper portion of said first conductive layer is exposed;
f) removing said exposed first conductive upper layer until underlying said first insulating layer is exposed thereby separating said first conductive layer into individual said container storage capacitors having inner and outer walls;
g) removing said first and said second insulating layers such that said second insulating layer is completely removed thereby exposing the entire inner walls of said container storage capacitor and said first insulating layer is partially removed thereby exposing an upper portion of said outer walls of said container storage capacitor, wherein the partially remaining first insulating layer provides insulation between said underlying substrate topography and subsequently formed layers;
h) forming a third insulating layer superjacent and coextensive said exposed walls and inner bottom portion of said capacitor and said partially remaining first insulating layer; and
i) forming a second conductive layer superjacent and coextensive said third insulating layer.
0. 32. A process as recited in claim 31, wherein said first insulating layer is planarized prior to said step of patterning and etching an opening into said first insulating layer.
0. 33. A process as recited in claim 31, wherein said second insulating layer is a sacrificial layer conductive to said chemical mechanical planarization.
0. 34. A process as recited in claim 31, wherein said first and said second insulating layers are oxides.
0. 35. A process as recited in claim 31, wherein said first insulating layer etch rate is a lower etch rate than said second insulating layer etch rate.
0. 36. A process as recited in claim 35, wherein the etch rate ratio between said second insulating layer etch rate and said first insulating layer etch rate is a ratio of 2:1 or greater.
0. 37. A process as recited in claim 35, wherein the etch rate ratio between said second insulating layer etch rate and said first insulating layer etch rate is a ratio of 4:1.
0. 38. A process as recited in claim 31, wherein said first and said second conductive layers are doped polysilicon.
0. 39. A process as recited in claim 38, wherein said doped polysilicon is formed by insitu doped chemical vapor deposition.
0. 40. A process as recited in claim 31, wherein said first, said second and said third insulating layers are formed by chemical vapor deposition.
0. 41. A process for fabricating a dram container storage capacitor on a silicon substrate having active areas, word lines and digit lines, said process comprising the following sequence of steps:
a) forming a blanketing first insulating layer, having a first etch rate, over said existing topography;
b) patterning and etching an opening into said first insulating layer, said opening thereby forming a container form;
c) forming a conformal first conductive layer superjacent said first insulating layer and said container form thereby lining said container form,
d) forming a blanketing second insulating layer, having a second etch rate, superjacent said first conductive layer;
e) removing said second insulating layer until upper portion of said first conductive layer is exposed;
f) removing said exposed first conductive upper layer via chemical mechanical planarization until underlying said first insulating layer is exposed thereby separating said first conductive layer into individual said container storage capacitors having inner and outer walls;
g) removing said first and said second insulating layers such that said second insulating layer is completely removed thereby exposing the entire inner walls of said container storage capacitor and said first insulating layer is partially removed thereby exposing an upper portion of said outer walls of said container storage capacitor, wherein the partially remaining first insulating layer provides insulation between said underlying substrate topography and subsequently formed layers;
h) forming a third insulating layer superjacent and coextensive said exposed walls and inner bottom portion of said capacitor and said partially remaining first insulating layer; and
i) forming a second conductive layer superjacent and coextensive said third insulating layer.
0. 42. A process as recited in claim 41, wherein said first insulating layer is planarized prior to said step of patterning and etching an opening into said first insulating layer.
0. 43. A process as recited in claim 41, wherein said second insulating layer is a sacrificial layer that is planarized by chemical mechanical planarization.
0. 44. A process as recited in claim 41, wherein said first and said second insulating layers are oxides.
0. 45. A process as recited in claim 41, wherein said first insulating layer etch rate is a lower etch rate than said second insulating layer etch rate.
0. 46. A process as recited in claim 45, wherein the etch rate ratio between said second insulating layer etch rate and said first insulating layer etch rate is a ratio of 2:1 or greater.
0. 47. A process as recited in claim 45, wherein the etch rate ratio between said second insulating layer etch rate and said first insulating layer etch rate is a ratio of 4:1.
0. 48. A process as recited in claim 41, wherein said first and said second conductive layers are doped polysilicon.
0. 49. A process as recited in claim 48, wherein said doped polysilicon is formed by insitu doped chemical vapor deposition.
0. 50. A process as recited in claim 41, wherein said first, said second and said third insulating layers are formed by chemical vapor deposition.
0. 51. A process for fabricating a dram container storage capacitor on a silicon substrate having active areas, word lines and digit lines, said process comprising the following sequence of steps:
a) forming a blanketing first insulating layer, having a first etch rate, over said existing topography;
b) patterning and etching an opening into said first insulating layer, said opening thereby forming a container form;
c) forming a conformal first conductive layer superjacent said first insulating layer and said container form thereby lining said container form;
d) forming a blanketing second insulating layer, having a second etch rate, superjacent said first conductive layer;
e) removing said second insulating layer via chemical mechanical planarization until upper portion of said first conductive layer is exposed;
f) removing said exposed first conductive upper layer via chemical mechanical planarization until underlying said first insulating layer is exposed thereby separating said first conductive layer into individual said container storage capacitors having inner and outer walls;
g) removing said first and said second insulating layers such that said second insulating layer is completely removed thereby exposing the entire inner walls of said container storage capacitor and said first insulating layer is partially removed thereby exposing an upper portion of said outer walls of said container storage capacitor, wherein the partially remaining first insulating layer provides insulation between said underlying substrate topography and subsequently formed layers;
h) forming a third insulating layer superjacent and coextensive said exposed walls and inner bottom portion of said capacitor and said partially remaining first insulating layer; and
i) forming a second conductive layer superjacent and coextensive said third insulating layer.
0. 52. A process as recited in claim 51, wherein said first insulating layer is planarized prior to said step of patterning and etching an opening into said first insulating layer.
0. 53. A process as recited in claim 51, wherein said second insulating layer is a sacrificial layer conducive to said chemical mechanical planarization.
0. 54. A process as recited in claim 51, wherein said first and said second insulating layers are oxides.
0. 55. A process as recited in claim 51, wherein said first insulating layer etch rate is a lower etch rate than said second insulating layer etch rate.
0. 56. A process as recited in claim 55, wherein the etch rate ratio between said second insulating layer etch rate and said first insulating layer etch rate is a ratio of 2:1 or greater.
0. 57. A process as recited in claim 55, wherein the etch rate ratio between said second insulating layer etch rate and said first insulating layer etch rate is a ratio of 4:1.
0. 58. A process as recited in claim 51, wherein said first and said second conductive layers are doped polysilicon.
0. 59. A process as recited in claim 58, wherein said doped polysilicon is formed by insitu doped chemical vapor deposition.
0. 60. A process as recited in claim 51, wherein said first, said second and said third insulating layers are formed by chemical vapor deposition.
0. 62. The process of claim 61, further comprising the step of removing at least a portion of said upper portion of said first conductive layer until said first insulating layer is exposed.
0. 63. The process of claim 61, wherein said second insulating layer is a sacrificial layer conducive to said chemical mechanical planarization.
0. 64. The process of claim 61, wherein said first and said second insulating layers are oxides.
0. 65. The method of claim 61, wherein said first insulating layer is subject to a first etch rate and said second insulating layer is subject to a second etch rate, and wherein said first etch rate is a lower etch rate than said second etch rate.
0. 67. The process of claim 66, further comprising the step of removing at least a portion of said upper portion of said first conductive layer until said first insulating layer is exposed, thereby forming a conductive container having inner and outer walls.
0. 68. The process of claim 66, wherein said second insulating layer is a sacrificial layer conducive to said chemical mechanical planarization.
0. 69. The process of claim 66, wherein said first and said second insulating layers are oxides.
0. 70. The process of claim 66, wherein said first insulating layer etch rate is a lower etch rate than said second insulating layer etch rate.

of , thereby forming individual containers 51 residing in contact openings 22 and exposing underlying oxide 21. The areas of poly 23 that are removed may be accomplished by performing a poly etch selective to oxide, which could be a timed wet etch or an optimized CMP poly etch. A very significant advantage of this process flow when a CMP etch step is utilized is that the inside of the future container 51 is protected from ‘slurry’ contamination that is inherent in the CMP step which proves difficult to remove in high aspect ratio storage containers (0.5μ inside diameter by 1.5μ high).

Referring now to FIG. 6, both oxides 21 and 31, which have different etch rates, are now exposed. At this point, an oxide etch is performed such that oxide 31 is completely removed from inside container 51 while a portion of oxide 21 remains at the base of container 51 and thereby providing an insulating layer between the underlying topography and subsequent layers. A An etch rate ratio of 2:1 or greater between (a ratio of 4:1 is preferred) oxide 31 and oxide 22 21 provides sufficient process margin to ensure all of high etch rate oxide 31 inside container 51 is removed during the single etch step, while a portion of oxide 22 21 remains to provide adequate insulation from subsequently formed layers.

Referring now to FIG. 7, when using this structure to form a capacitor storage node plate container 51, and the remaining portion of oxide 21 is coated with a capacitor cell dielectric 71. And, finally Finally a second conformal poly layer 72 is placed to onto blanket cell dielectric 71 and serves as a common capacitor cell plate to the entire array of containers 51. From this point on, the wafer is completed using conventional fabrication process steps.

FIG. 8 depicts a cross-section of the present invention integrated into a stacked capacitor process on starting substrate 81. Container 51 connects to diffusion area 82 and thereby serves as a storage node container plate. Diffusion area 82 is accessed by word line 85 (separated by gate insulator 83) which in turn spans the channel's active area between diffusion areas 82. The poly of container 51 is doped to the same conductivity type as underlying diffusion region 82 to insure a good ohmic contact.

It is to be understood that although the present invention has been described with reference to a preferred embodiment, various modifications, known to those skilled in the art, may be made to the structures and process steps presented herein without departing from the invention as recited in the several claims appended hereto.

Walker, Michael A., Dennison, Charles H.

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