A light hardening device is provided for hardening a light hardenable mass applied for dental purposes that has a first light emitting diode for emitting light at a range of intensities corresponding to a set of wavelengths which at most only partially overlap a range of light sensitivities of a photo initiator comprised in the mass. The light hardening device also includes a second light emitting diode for emitting light at a range of intensities corresponding to a set of wavelengths which overlap the set of photo initiator light sensitivities to a relatively greater extent than the partial overlap of the range of first light emitting diode intensities with the range of photo initiator light sensitivities.
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14. A method for polymerizing a light hardenable mass applied for dental purposes with a light hardening device, the light hardenable mass having a photo initiator actuable to initiate hardening of the mass upon irradiation of the photo initiator with light and the photo initiator being sensitive to light across a range of sensitivities which vary from one to another at different wavelengths of a set of photo initiator wavelengths, the photoinitiator having a maximum spectral sensitivity of approximately 470 nm, and the light hardening device having two first and second light emitting diodes having differing emission spectrums, which overlap sensitivities of the photoinitiator at different emission spectrums, wherein the first light emitting diode has an emission maximum at approximately 505 nm and has only partial overlap with the sensitivity of the photoinitiator; wherein the second light emitting diode has an emission maximum of approximately 460 nm and has greater overlap than the first light emitting diode with the sensitivity of the photoinitiator; the method comprising:
irradiating the mass with a first light emitting diode of the light hardening device during a first time period such that the first light emitting diode emits light in an emission spectrum which at most only partially overlaps the sensitivity spectrum of a photo initiator of the mass.
1. A light hardening device for hardening a light hardenable mass applied for dental purposes, the light hardenable mass having a photo initiator actuable to initiate hardening of the mass upon irradiation of the photo initiator with light and the photo initiator being sensitive to light across a range of sensitivities which vary from one another at different wavelengths of a set of photo initiator wavelengths, the photoinitiator having a maximum spectral sensitivity of approximately 470 nm, the light hardening device comprising:
a first light emitting diode for emitting light at a range of intensities which vary from one another at different wavelengths of a set of first light emitting diode wavelengths, the range of first light emitting diode intensities overlapping the range of, photo initiator light sensitivities at most only partially; and
a second light emitting diode for emitting light at a range of intensities which vary from one another at different wavelengths of a set of second light emitting diode wavelengths, the range of second light emitting diode intensities overlapping the range of photo initiator light sensitivities to a relatively greater extent than the partial overlap of the range of first light emitting diode intensities with the range of photo initiator light sensitivities; and
a control device, wherein the first light emitting diode and the second light emitting diode can be actuated at different times and with different radiation intensities by the control device;
wherein the first light emitting diode has an emission maximum at approximately 505 nm and has only partial overlap with the sensitivity of the photoinitiator;
wherein the second light emitting diode has an emission maximum of approximately 460 nm and has greater overlap than the first light emitting diode with the sensitivity of the photoinitiator; and
wherein the first light emitting diode partially hardens the light hardenable mass and wherein the second light emitting diode completely hardens the light hardenable mass.
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This application claims foreign priority benefits under 35 U.S.C. §119(a)-(d) from German patent application Ser. No. P 101 55 034.0 filed Nov. 9, 2001. In addition, this application claims the benefit under 35 U.S.C. §119(e) of U.S. provisional patent application Ser. No. 60/344,139 filed Dec. 21, 2001.
The present invention relates to a light hardening device as well as a method for polymerization of polymerizable masses. Light hardening devices of this type are used, for example, if light polymerizable masses or material are to be hardened in a focused manner.
The polymerizable materials which can be hardened by light hardening devices, as is conventionally known, are, for example, cements, an excess amount of which must be applied to complete the application task. The oversupply or excess amount of cement is extremely hard after the complete hardening of the mass or material, and a high degree of effort is required in order to remove this excess material with suitable dental instruments such as, for example, by milling. Moreover, the removal of hardened excess material causes a high wearing away of the scraping or sharpening instruments or, respectively, the milling instruments.
It has been proposed, for example, to use two photo initiators, which have different spectral sensitivity maximums, and to harden the mass or material completely with lamps or lights having the corresponding emission spectrum.
It has further been proposed in the prior art, with respect to photo polymerizable materials which comprise two different photo initiators, to initially activate the first photo initiator by irradiation thereof by an appropriate wavelength so as to thereby partially harden the material, to thereafter remove the excess material, and subsequently, via a second photo initiator, to undertake the complete hardening of the material. Such systems have, however, not found full acceptance due to the considerable effort required to deploy two photo initiators and the switching over work required to switch between the double systems to effect the partial hardening of the material is difficult to control. Therefore, the excess material is typically removed after the complete hardening of the material which requires, however, a considerable effort.
The present invention offers a solution to the challenge of providing a light hardening apparatus as well as a method for polymerization which permits the realization of an improved material cohesiveness to be achieved by light hardening while nonetheless offering more flexibility to use different polymerizable masses or material.
The light hardening device of the present invention, or, respectively, the inventive method, uses simple means to offer the possibility to completely harden the polymerizable mass or material in a step-wise manner whereby, in the first step, a partially polymerized, easily workable material is created and, in a second step, the finished, completely hardened material is created.
In accordance with the present invention, it is particularly advantageous that a removal of the excess material is possible in spite of the sole use of a single photo initiator to realize a partial polymerization. In this connection, a spectral overlapping between the emission spectrum of a light emitting diode and the sensitivity spectrum of the photo initiator is used to advantage. It is particularly advantageous, in this connection, that one can also work with commercially available, cost favorable dental masses or materials—that is, no special masses or materials requiring two photo initiators need be used. This provides a significant cost advantage alone for the reason that the photo polymerizable masses or material can be polymerized with solely a single photo initiator which can be manufactured in a standardized manner in comparatively large amounts, which leads to significant cost savings with respect to the production and storage of such material. In contrast, special masses are substantially more difficult to work with and more expensive for the reason alone that the storability or shelf life of such special masses is not unlimited.
In contrast, it is particularly advantageous that the light hardening device of the present invention is able to effect polymerization of a photo polymerizable mass or material with solely a single photo initiator. In accordance with the present invention, a system comprising a single light hardening apparatus or device can be used in combination with the photo polymerizable mass or material.
Surprisingly, it has been discovered that the partial overlapping between the emissions spectrum of the first light emitting diode and the sensitivity spectrum of the photo initiator provides the possibility to achieve a partial hardening of the mass or material in a manner such that, during a pause in the hardening process, excess material can be removed while not foreclosing undertaking a further hardening following the pause in the hardening process.
The relationship between the intensities of the light output during the first time period and the light output during the second time period can be accommodated to a wide range of requirements as can the duration of the first and second time periods as well. Advantageously, the emissions intensity of the first light emitting diode is set at at least 100 mW/cm2 while the light intensity of the light emitting diode is set at at least 300 mW/cm2 and is preferably set at 600 to 1,000 mW/cm2. In connection with a high light intensity of the first light emitting diode and/or a relatively long first time period, the partially polymerized material is somewhat firmer so that the removal of excess material can also be undertaken mechanically with commercially available dental instruments while, in connection with a relatively lower light intensity and/or a relatively shorter first time period, a sculpting or, respectively, a working of the mass or material can be undertaken.
It is, in any event, important that the spectrum of the first light emitting diode and the sensitivity of the photo initiator are clearly differentiated from one another and, especially, that the maxima of the two parameters have clearly differentiated wavelengths.
Preferably, the intensity maximum of the first light emitting diode is chosen such that its wavelength is greater than the wavelength of the sensitivity maximum of the photo initiator. For example, camphor quinone can be used as a photo initiator and the first light emitting diode can be configured as a green light emitting diode. The wavelength maxima values are then between around 470 and 505 nanometers; therefore, the wavelength is clearly different than that of the photo initiator.
In accordance with a particularly advantageous configuration of the present invention, the second light emitting diode is chosen such that its emission maximum coincides with the sensitivity maximum of the photo initiator while, at the same time, the spectrums are, to the greatest extent possible, coincidental with one another.
It is to be understood, however, that in lieu of a light emitting diode or a plurality of light emitting diodes, at least one group of LEDs or, respectively, so-called pads, can be deployed. U.S. patent applications 10/139,308, 10/139,308, and 10/177,014 are, in this regard, fully incorporated by reference herein.
Further advantages, details, and features of the present invention are set forth in the following description of an embodiment of the present invention described in connection with the drawings, in which:
The light hardening device 10 shown in
In accordance with the present invention, several light emitting diodes or LEDs are provided, whereby the term “light emitting diodes” includes as well the concept of laser diodes and other fixed body light emitters. In
Although only a light emitting diode 12 and a light emitting diode 14 are illustrated, it is to be understood that, in practice, a multiple arrangement of identical light emitting diodes can be used which are commonly actuated and operated as a group.
In accordance with the present invention, it is advantageous if the light emitting diodes 12 and 14 are controlled by a control device 18 which is schematically shown in
In
In accordance with the present invention, an overlapping region 22 exists between the camphor quinone spectrum 20 and the spectrum of the green light emitting diode 12. The overlapping region lies substantially between 460 and 500 nanometers. By actuation of the green light emitting diode 12, the camphor quinone 20 in the dental mass is partially excited so that a pre-hardening of the dental material results.
As is also illustrated in
The diagram in
With further regard to the surface, the overlapping region 22 between the green light emitting diode 12 and the camphor quinone 20 comprises approximately one-fourth of the total surface of the spectrum of the camphor quinone. Such a dimensional relationship has shown itself to be particularly favorable for the realization of a partial polymerization.
The desired hardness also permits itself to be easily adjusted by adjustment of the duration of the light irradiation. As seen in
The blue light emitting diode is thereafter actuated with a light emitting intensity of 1,000 mW/cm2 during a second time period 28.
In the illustrated embodiment of the present invention, the two time periods 24 and 26 have been selected to be of the same duration. It is to be understood, however, that the time periods can be accommodated to the requirements of the situation.
The present invention is, of course, in no way restricted to the specific disclosure of the specification and drawings, but also encompasses any modifications within the scope of the appended claims.
Rohner, Gottfried, Plank, Wolfgang, Burtscher, Peter
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