A display panel comprises a plurality of arranged pixels of organic EL devices, each having a pair of electrodes and a luminescent layer containing an organic EL material and sandwiched between the electrodes. The plurality of arranged pixels include fluorescent pixels of organic EL devices formed by mainly using a fluorescent material and phosphorescent pixels of organic EL devices formed by mainly using a phosphorescent material. A display apparatus comprises a controller for controlling the display panel, including correcting the difference between the electroluminescent characteristics of the fluorescent pixels and those of the phosphorescent pixels.
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2. A display apparatus comprising:
(a) a display panel comprising a plurality of pixels of organic electroluminescent devices, the plurality of pixels including fluorescent pixels and phosphorescent pixels; and
(b) a controller display control section which supplies signals to the plurality of pixels, a signal supplied to the fluorescent pixels being different from a signal supplied to the phosphorescent pixels,
wherein a timing of falling edge of the signal supplied to the phosphorescent pixels being is earlier than that of the signal supplied to the fluorescent pixels.
1. A display apparatus comprising:
(a) a display panel comprising a plurality of pixels of organic electroluminescent devices and a plurality of data lines for supplying video signals to each of the plurality of pixels, the plurality of pixels including fluorescent pixels and phosphorescent pixels which are arranged along the plurality of data lines, each of the plurality of pixels including:
an organic electroluminescent device,
a first transistor which supplies a current to the organic electroluminescent device,
a second transistor which is electrically connected to a gate electrode of the first transistor and electrically connected to one of the data lines, and
a hold capacitance which is electrically connected to the gate electrode of the first transistor for holding a voltage corresponding to a supplied video signal; and
(b) a controller display control section which corrects the video signals and supplies the corrected video signals to the plurality of pixels through the data lines, a signal supplied to the fluorescent pixels being different from a signal supplied to the phosphorescent pixels such that a difference of efficiency of electroluminescence between the fluorescent pixels and the phosphorescent pixels is compensated.
0. 3. The display apparatus according to claim 1, wherein the data signals are supplied from the display control section to the plurality of pixels via a latch.
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This The present application is a reissue of U.S. Pat. No. 7,221,333 B2, which issued from application Ser. No. 11/517,404, filed Sep. 8, 2006. The present application is a division of Application No. 11/171,189, filed Jul. 1, 2005, now which issued as U.S. Pat. No. 7,126,285 on Oct. 24, 2006, which in turn, is a division of Application No. 10/438,029, filed May 15, 2003, now which issued as U.S. Pat. No. 7,012,377 on Mar. 14, 2006. The present application claims priority of JP2002-159000, filed in Japan on May 31, 2002.
1. Field of the Invention
This invention relates to a display panel and a display apparatus. More particularly, this invention relates to a display panel comprising, a plurality of pixels formed by using organic electroluminescent devices (organic EL devices) and also to a display system comprising such a display panel.
2. Related Background Art
Organic EL devices are characterized by field luminescence of a thin film multilayer structure capable of emitting light to an enhanced degree of luminance. Organic EL devices can emit light highly efficiently if a low voltage is applied thereto particularly when the number of functional organic layers including at least a luminescent layer of an organic luminescent material is increased (“Applied Physics Letters,” Vol. 51, 1987, p. 913; Vol. 65, 1989, p. 3610). Each device has a basic structure of anode/hole transport layer/luminescent layer (containing an organic luminescent material)/cathode. In the course of time, an alternative basic structure of anode/hole transport layer/luminescent layer/electron transport layer/cathode was proposed to further improve the efficiency. Meanwhile, efforts have been made to improve the emission efficiency by arranging a blocking layer between the luminescent layer and the electron transport layer for the purpose of blocking carriers passing through the luminescent layer or by arranging a metal thin film as electron injection layer between the cathode and the electron transport layer so that carriers may be injected with a low voltage.
In recent years, attention has been paid to luminescent devices including those made of an Ir complex to utilize the luminescence of triplet excitons showing a high occupancy ratio of 75% (single excitons being responsible for the remaining 25%) of electrons and holes injected from electrodes (“Applied Physics Letters,” Vol. 75, 1999, p. 5). Fluorescence is used for luminescence caused by transition from an excited state of singlet, whereas phosphorescence is used for luminescence caused by transition from an excited state of triplet.
For example, the chemical compound having the structural formula shown below is an EL material Alq3 developed by C. W. Tang et al. of Kodak Co. and adapted to mainly use fluorescence. Alq3 emits green light and is adapted to produce fluorescence from a singlet state.
##STR00001##
On the other hand, the compound having the structural formula shown below is an electroluminescent material Ir(ppy)3 that was developed by M. A. Baldo et al. of Princeton University and emits green light just as Alq3. It is adapted to produce phosphorescence from a triplet state and can provide efficiency several times greater than that of Alq3.
##STR00002##
Organic EL devices such as those described above are adapted to field luminescence to an enhanced degree of luminance when an electric current flowing between electrodes or from a thin film transistor (to be referred simply as TFT hereinafter) is used. Therefore, they are expected to find applications in the field of high density display apparatus. Full-color thin film displays can be realized by using organic EL devices that are adapted to emit red, green and blue (RGB) lights.
While the devices of display apparatus that utilize fluorescence as described above show a low efficiency, they response quickly when they decrease light. Some of them (typically made of an electroluminescent material such as Alq3) show a light decreasing delay of about tens of several nano-seconds.
On the other hand, while the devices of display apparatus that utilize phosphorescence as described above show a high efficiency, some of them (typically made of an electroluminescent material such as Ir(ppy)3) show a light decreasing delay between about 0.8 micro-seconds and several milliseconds.
The luminescence efficiency of a phosphorescent material can remarkably differ from that of a fluorescent material in the initial states because of the respective modes of energy transition of excitons.
In the case of electroluminescence attributable to phosphorescence, carriers are firstly excited to a state above the lowest excited state of singlet and the lowest excited state of triplet. Subsequently, an internal conversion from the lowest excited state of singlet to the lowest excited state of triplet takes place and carriers tend to go back to the ground state, emitting luminescence energy. On the other hand, in the case of electroluminescence attributable to fluorescence, while excitation occurs as in the case of electroluminescence attributable to phosphorescence, carriers that are excited to above the lowest excited state of triplet emit energy as heat. In view of the above described mechanisms of electroluminescence, it may be so concluded that electroluminescence attributable to phosphorescence and electroluminescence attributable to fluorescence differ from each other particularly in terms of service life and the difference of service life is caused by the difference of energy transition among molecules and the resultant difference in terms of emission of heat and morphological changes.
Thus, due to the difference of electroluminescent characteristics between fluorescent materials and phosphorescent materials, efforts have been paid to develop high luminance high quality display panels by arranging pixels made of a single or identical material, which may be a fluorescent material or a phosphorescent material, on the display panel. These days, display apparatus formed by using such display panels are required to perform better than ever.
In view of the above identified circumstances, therefore the object of the present invention is to provide a high luminance high quality multi-color display panel formed by using organic EL devices and also a display apparatus realized by using such a display panel.
The inventors of the present invention have noticed that a full-color display panel can be made to show a higher luminance and a higher image quality by using both a fluorescent material and a phosphorescent material because electroluminescent materials of different colors show different efficiencies and are required to show different degrees of luminance because of the visual sense of man.
Thus, the present invention provide a display panel comprising a plurality of arranged pixels of organic electroluminescent devices, each having a pair of electrodes and a luminescent layer containing an organic electroluminescent material and sandwiched between the electrodes;
said plurality of arranged pixels including fluorescent pixels of organic electroluminescent devices formed by mainly using a fluorescent material as organic electroluminescent material and phosphorescent pixels of organic electroluminescent devices formed by mainly using a phosphorescent material as organic electroluminescent material.
Now, the present invention will be described in greater detail by referring to the accompanying drawings that illustrate preferred embodiments of the invention.
It has been noticed that it is difficult to raise the efficiency of red organic EL devices. However, it is now possible to reduce the difference of efficiency among pixels by using fluorescent pixels and phosphorescent pixels to form a display panel particularly when phosphorescent pixels are used only for red. Therefore, for a full-color display using RGB, for example, it is now possible to make all the pixels show an enhanced degree of luminance and at the same time maintain a well balanced state among the organic EL devices of the three primary colors in terms of luminance. Thus, it is possible to provide a high luminance high quality display panel that can display full-color images.
A display panel comprising both fluorescent pixels and phosphorescent pixels can be prepared by patterning a single substrate by means of a known patterning technique so as to form fluorescent pixels and phosphorescent pixels on the same substrate. Alternatively, such a display panel can be prepared by laying a first display section that is formed by arranging only a plurality of fluorescent pixels on a substrate on a second display section that is formed by arranging only a plurality of phosphorescent pixels on another substrate. It should be noted that, when first and second display sections are used, one of the display sections needs to be transparent at the parts thereof that respectively correspond to the pixels of the other display section so that the light from the other display section may be transmitted through the former display section. Additionally, the process of preparing a display panel by using first and second display sections can be simpler than the process of preparing a display panel by forming fluorescent pixels or phosphorescent pixels and subsequently forming phosphorescent pixels or fluorescent pixels, whichever appropriate, on a same single substrate by using a patterning technique.
Preferably, the area of a fluorescent pixel is greater than that of a phosphorescent pixel. As pointed out earlier, phosphorescence can be several times more efficient than fluorescence. In other words, the luminance of phosphorescent pixels per unit area is much greater than that of fluorescent pixels per unit area. Therefore, the difference of luminance can be reduced by differentiating the area of a fluorescent pixel and that of a phosphorescent pixel. More preferably, the ratio of the area of a fluorescent pixel to the area of a phosphorescent pixel is inversely proportional to the ratio of the efficiency of fluorescence of a fluorescent pixel to that of phosphorescence of a phosphorescent pixel. With this arrangement, the difference of luminance can be minimized. The area of the fluorescent pixels and that of the phosphorescent pixels can be differentiated either by a technique of adjusting the area of the organic layers formed at the time of patterning operation so as to differentiate the areas of two different types of electroluminescence or by a technique of differentiating the open areas of two different types of electroluminescence by arranging a shielding section or the like.
When pixels showing different durations of after glow relative to a display signal coexist on a single display panel 1, a specific display color may become noticeable and subsequently disappear.
Additionally, as shown in
Thus, according to the invention, there is provided a display apparatus comprising not only a display panel but also a control means for inputting different signals for the fluorescent pixels and those for the phosphorescent pixels showing different electroluminescent characteristics. With this arrangement, it is possible to supply signals, taking the respective electroluminescent characteristics into consideration.
More specifically, the after glow of a specific color due to the difference of light decreasing timing can be prevented from occurring by delaying the timing of the falling edge of a video signal and/or that of the falling edge of a signal showing a polarity opposite to that of the video signal for the fluorescent pixels relative to the counterparts for the phosphorescent pixels.
More preferably, the control means is provided with a memory means for storing the arrangement and driving conditions of the fluorescent pixels and those of the phosphorescent pixels so that signals that are appropriately corrected by considering the electroluminescent characteristics of the fluorescent pixels and those of the phosphorescent pixels can be input to the pixels. The driving conditions specifically include the voltage to be used for driving the pixels and the time series waveform of the applied voltage.
With the above described arrangement, a higher voltage may be applied to the fluorescent pixels so that any difference of luminance may be eliminated and the difference of efficiency of electroluminescence between the fluorescent pixels and the phosphorescent pixels may be corrected on the basis of the arrangement and driving conditions stored in the memory means regardless of the difference of efficiency of electroluminescence. Additionally, it is possible to store the ratio of the efficiency of electroluminescence of a fluorescent pixel to that of a phosphorescent pixel after a predetermined period of time of operation in a memory means and determine the ratio of the voltages to be applied to the respective pixels after the predetermined period of time in order to correct the difference of service life. With this arrangement, the change in the difference of electroluminescence efficiency ratio after a predetermined period of time that is attributable to the difference of electroluminescence service life can be addressed properly so that the effect of preventing any difference of luminance between the two different types of pixels can be maintained for a long period of time.
(First Embodiment)
The embodiment of display apparatus according to the invention and illustrated in
In
The pixels on the display panel 1 of
With this arrangement, the pixel light decreasing time can differ among the pixels on a same scan line. More specifically, a phosphorescent pixel and a fluorescent pixel arranged on a same scan line show a difference of light decreasing time of Td1 as shown in
This difference is corrected by making the falling edge of the video signal of the phosphorescent pixel 32 come earlier than that of the video signal of the fluorescent pixel by the time period of Td1. In other words, the operation of signal switching to horizontal blank HBLK is made to come earlier for the phosphorescent pixel than for the fluorescent pixel by Td1 as illustrated in
Now, the part of the circuit adapted to correct the difference of the initial efficiencies of electroluminescence of the two different pixels will be described below.
As pointed out above, the initial efficiency of electroluminescence of the fluorescent pixels 31, 33 and that of the phosphorescent pixel 32 remarkably differ from each other because of the difference of internal energy transition.
In order to equalize the ratio of electroluminescence to that of visually sensed intensity of the pixels of the two different types, the voltage of video signal is modified by using different magnifications that are determined respectively for the phosphorescent pixel 32 and the fluorescent pixels 31, 33 before it is applied to the horizontal video signal latch 4.
The magnifications to be used for the video signal are read with the video signal as shown in
It is known that the luminance of an organic EL device relative to the electric current falls with time. A phosphorescent pixel 32 and a fluorescent pixel 31 or 33 are different from each other in terms of the fall of luminance with time.
For the initial stages, the ratio of the efficiency of electroluminescence of the phosphorescent pixel 32 to that of the fluorescent pixel 31 or 33 is defined to be equal to 1:3 as shown in
(Second Embodiment)
This embodiment has a configuration substantially same as that of First Embodiment shown in
With this arrangement, the light decreasing time of pixels differs on a scan line basis and the difference of light decreasing time is equal to Td1 as shown in
To correct the difference, the delay Td1 of the falling edge for light decreasing phosphorescent pixels is reduced to the area of the pixel and made equal to Td2, which is equal to Td1 in
Now, the part of the circuit adapted to correct the difference of the initial efficiencies of electroluminescence of the two different pixels will be described below.
As pointed out above, the initial efficiency of electroluminescence of the fluorescent pixels 31, 33 and that of the phosphorescent pixel 32 remarkably differ from each other because of the difference of internal energy transition.
In order to equalize the ratio of electroluminescence to that of visually sensed intensity of the pixels of the two different types, the voltage of video signal is modified by using different magnifications that are determined respectively for the phosphorescent pixel 32 and the fluorescent pixels 31, 33 before it is applied to the horizontal video signal latch 4.
The magnifications to be used for the video signal are read with the video signal and the video signal is multiplied by the predetermined magnifications before it is fed to the horizontal video signal latch 4. The video signal latched to the horizontal video signal latch 4 is then supplied from the TFT 93 in the pixel to the organic EL device 94 as electric current at the timing given by the V shift register 2 in a manner as described earlier. For example, a video signal multiplied by a magnification of 3 as shown in
It is known that the luminance of an organic EL device relative to the electric current falls with time. As pointed out earlier, a phosphorescent pixel 32 and a fluorescent pixel 33 are different from each other in terms of the fall of luminance with time. For the initial stages, the ratio of the efficiency of electroluminescence of the phosphorescent pixel 32 to that of the fluorescent pixel 33 is defined to be equal to 1:3 as shown in
(Third Embodiment)
As shown in
The light decreasing time of the first display section differs from that of the second display section to give rise to a difference of light decreasing time Td1 as shown in
In order to correct the difference, the falling edge of the video signal applied to the first display section 1-1 for fluorescence for the operation of signal switching to horizontal blank HBLK is delayed by a time period of Td1 from the falling edge of the video signal applied to the second display section 1-2 for phosphorescence.
Either the timing of a first device hold signal or that of a second device hold signal is given as video signal hold signal to the display section that is to be operated. A circuit for generating a time difference as shown in
As shown in
Now, the part of the circuit adapted to correct the difference of the initial efficiencies of electroluminescence of the two different pixels will be described below.
As pointed out above, the initial efficiency of electroluminescence of the first display section 1-1 for fluorescence and that of the second display section 1-2 for phosphorescence remarkably differ from each other because of the difference of internal energy transition.
In order to equalize the ratio of electroluminescence of the two display sections to that of visually sensed intensity of the pixels of the display sections, the voltage of video signal is modified by using different magnifications that are determined respectively for the fluorescent pixels of the first display section 1-1 and the phosphorescent pixels of the second display section 1-2 before it is applied to the horizontal video signal latch 4.
The magnifications to be used for the video signal are read with the video signal and the video signal is multiplied by the predetermined magnifications before it is fed to the horizontal video signal latch 4. The video signal latched to the horizontal video signal latch 4 is then supplied from the TFT 93 in the pixel to the organic EL device 94 as electric current at the timing given by the V shift register 2 in a manner as described earlier. For example, a video signal multiplied by a. magnification of 3 as shown in
It is known that the luminance of an organic EL device relative to the electric current falls with time. As pointed out earlier, a phosphorescent pixel 32 and a fluorescent pixel 33 are different from each other in terms of the fall of luminance with time. For the initial stages, the ratio of the magnification applicable to the efficiency of electroluminescence of a phosphorescent pixel 32 to that applicable to the efficiency of electroluminescence of a fluorescent pixel 33 is specified to be equal to 1:3 as shown in
As described above, the present invention provides a display panel comprising phosphorescent devices formed by using a highly efficient triplet material and fluorescent devices formed by using a singlet material that can be selected from a number of currently available materials and a display panel comprising a first display section formed by using only phosphorescent devices and a second display section formed by using only fluorescent devices, the first display section and the second display section being arranged on a same display substrate (glass substrate, TFT substrate). A display panel according to the present invention can display high luminance high quality full-color images.
According to the invention, there is also provided a display apparatus comprising such a display panel and a control means having in combination a function of shifting the timing of the falling edge of a signal and a function of correcting the difference of efficiency of electroluminescence and the difference of service life for electroluminescence on the basis of the data stored in a memory means. Such a display apparatus can reduce any after glow, uneven displays in the initial stages of operation and changes with time of the displayed image so as to display images with good gradations. The video signal conversion memory and the controller may be arranged on the substrate that carries the display panel or on some other places without changing their effects.
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