A substrate-level assembly having a device substrate of semiconductor material with a top face and housing a first integrated device, including a buried cavity formed within the device substrate, and with a membrane suspended over the buried cavity in the proximity of the top face. A capping substrate is coupled to the device substrate above the top face so as to cover the first integrated device in such a manner that a first empty space is provided above the membrane. Electrical-contact elements electrically connect the integrated device with the outside of the substrate-level assembly. In one embodiment, the device substrate integrates at least a further integrated device provided with a respective membrane, and a further empty space, fluidly isolated from the first empty space, is provided over the respective membrane of the further integrated device.
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21. An electronic device, comprising:
a substrate-level an assembly that includes:
a device substrate of semiconductor material, having a top face and housing a including first integrated device provided with an active area adjacent to the top face and second sensor regions;
a capping substrate cap coupled to the device substrate above the top face so as to cover the first integrated device and second sensor regions in such a manner that a first empty space cavity is provided in a position corresponding to the active area above the first sensor region and a second cavity is provided above the second sensor region, the first cavity being separate from the second cavity; and
electrical-contact elements for electrical connection of to the first integrated device and second sensor regions extending outside of the substrate-level assembly first and second cavities; and
a package encasing and mechanically protecting the substrate-level assembly; wherein the package comprises that includes:
a base body mechanically supporting the substrate-level assembly, and
a an insulative coating region configured to coat laterally material that is located on lateral sides of the substrate-level assembly.
1. A substrate-level An assembly, comprising:
a device substrate of semiconductor material, having a top face and housing a first integrated device provided with an active area adjacent to the top face that includes a first buried cavity in the device substrate and a first membrane suspended above the first buried cavity, the device substrate further including a second membrane;
a capping substrate cap coupled to the device substrate above the top face so as to cover the first integrated device in such a manner that and covering an upper portion of the device substrate and forming a first empty space is provided in a position corresponding to the active area between an inner surface of the cap and the first membrane of the device substrate and forming a second empty space between an inner surface of the cap and a surface of the second membrane, the first and second empty spaces being isolated from each other; and
an access duct in the cap that provides fluid connectivity between the first empty space and an environment outside of the assembly; and
electrical-contact elements for electrical connection of the first integrated device device substrate to a location outside of the substrate-level assembly.
51. An assembly comprising:
an article, and
a base substrate having a first surface and a second surface;
a sensor assembly adapted to monitor at least one condition of the article, the sensor assembly comprising:
a first device substrate of semiconductor material, having a top face and housing including a first integrated device provided with sensor region having an active area adjacent to the top face;
a second device substrate of semiconductor material having a first surface and including an integrated circuit, the first device substrate being located on the first substrate of the second device substrate, the integrated circuit being electrically coupled to the first sensor region;
a capping substrate cap coupled to the first device substrate above the top face so as to cover the first integrated device in such a manner sensor region so that a first empty space is provided in a position corresponding to above the active area; and
electrical-contact elements extending from the first surface to the second surface of the base substrate for electrical connection of the first integrated device sensor region and the integrated circuit outside of the substrate-level assembly.
28. A process for manufacturing a substrate-level an assembly, comprising:
providing a device substrate of semiconductor material, having a top face;
forming a first integrated device within sensor region in a top face of the device substrate, and with an active area adjacent to the top facethe first sensor region including a buried cavity and a membrane suspended above the buried cavity;
coupling a capping substrate cap to the device substrate above the top face so as to cover the first integrated device, the coupling comprising forming and form a first empty space in a position corresponding to the active area above the membrane, the cap including a plurality of access ducts that places the first empty space in fluid communication with an environment outside of the assembly, the plurality of access ducts being of different sizes or a different inter-spacing being provided therebetween or a combination of different sizes and different inter-spacing; and
forming electrical-contact elements from the top face of the device substrate to a bottom face of the device substrate for electrical connection of the first integrated device with the outside of the substrate-level assembly.
45. A process for manufacturing an electronic device, comprising:
forming a substrate-level an assembly, the forming including:
providing a device substrate of semiconductor material, having a top face;
forming a first integrated device within the device substrate and with an active area adjacent to the top face buried cavity in a device substrate of semiconductor material, a first membrane being located above the buried cavity;
forming a second buried cavity in the device substrate, a second membrane being located above the second buried cavity;
coupling a capping substrate cap to the device substrate above the top face so as to cover the first integrated device and second membranes, the coupling comprising forming a first empty space in a position corresponding to the active area and a second empty space, the first empty space being located over the first membrane, the second empty space being located over the second membrane, the first empty space being fluidly isolated from the second empty space; and
forming electrical-contact elements in the device substrate for electrical connection of the first integrated device with the outside of the substrate-level assembly; and
encasing the substrate-level assembly in a package, for coating and mechanically protecting the substrate-level assembly;
wherein the encasing comprises providing a base body to support the substrate-level assembly, and coating laterally the substrate-level sides of the assembly with a an insulative coating region material.
2. The assembly of
3. The assembly of claim 1, wherein an access duct is provided within the capping substrate, the access duct being fluidly connected to the first empty space and to the outside of the substrate-level assembly 2 wherein the electrical-contact elements include through vias that are coupled to a respective contact pad on the bottom surface of the device substrate.
4. The assembly of
5. The assembly of
6. The assembly of
7. The assembly of
8. The assembly of
9. The assembly of claim 2, wherein the electrical-contact elements comprise at least one of through vias made through the device substrate and electrical-connection pads formed on a portion of the top face of the device substrate not covered by the capping substrate; and 1 wherein the first integrated device further comprises a buried cavity formed within the device substrate, a membrane suspended over the buried cavity, and device substrate includes transduction elements configured to transform a deformation of the first membrane into electrical signals, the electrical-contact elements being connected coupled to the transduction elements.
10. The assembly of
11. The assembly of
0. 12. The assembly of
13. The assembly of claim 12 1, wherein the capping substrate has at least one further sensor cavity set above the respective active area of the further integrated device, and forming, at least in part, the further empty space; the first empty space and further empty space separated in a fluid-tight manner, at least in part, by a separation portion of the capping substrate placed between the first empty space and the further empty space the second empty space is not in fluid communication with the environment outside the assembly.
14. The assembly of claim 12 1, further comprising a bonding region placed between the device substrate and the capping substrate, and in contact with the top face of the device substrate in such a manner as to surround, without being superimposed thereon, the active area of the first integrated device and the respective active area of the further integrated device; the first empty space and the further empty space being delimited, at least in part, by the bonding region wherein the device substrate includes a second buried cavity and the second membrane is suspended above the second buried cavity.
15. The assembly of claim 12 1, wherein the first integrated device further comprises a buried cavity formed within the device substrate and a membrane suspended over the buried cavity, and the further integrated device comprising a respective buried cavity formed within the device substrate and a respective membrane suspended over the respective buried cavity; and wherein the first integrated device is a pressure sensor, and the further integrated device is an inertial sensor, the inertial sensor comprising an inertial mass arranged on the respective membrane within the further empty space the second membrane is an inertial sensor.
16. The assembly of
17. The assembly of claim 12 1, wherein the first integrated device comprises membrane, the first empty space, and the first buried cavity are part of a pressure sensor, and the further integrated device comprises second membrane, second empty space, and a second buried cavity are part of a reference pressure sensor for the pressure sensor.
18. The assembly of
19. The assembly of claim 18 1, wherein the first integrated device further comprises a buried cavity formed within the device substrate and a membrane suspended over the buried cavity; the first integrated device comprising membrane, the first empty space, and the first buried cavity form a gas sensor and the first membrane including includes a detection material configured to allow detecting the presence of a gaseous material; the membrane being thermally decoupled from the device substrate.
20. The assembly of claim 1 12, wherein the capping substrate includes a layer grown on the device substrate, in particular by electroplating or epitaxial steps; the capping substrate being integral to the device substrate second membrane includes an accelerometer.
22. The device of
a top surface of the capping substrate cap defining part of a first outer face of the package, and
the access duct.
23. The device of
24. The device of
25. The device of claim 21 24, further comprising a circuit die electrically coupled to the substrate-level assembly and encased by the package; the circuit die being mechanically coupled to the base body, and the device substrate being mechanically coupled to the circuit die in a stacked manner wherein the cap includes an access duct that places the first cavity is fluid communication with an environment outside of the assembly.
26. The device of
27. The device of
29. The process of
30. The process of claim 28, further comprising forming in the capping substrate access duct fluidly connected to the first empty space and to the outside of the substrate-level assembly 29, wherein the first empty space is fluidly isolated from the second empty space.
31. The process of
32. The process of
33. The process of
34. The process of
0. 35. The process of
36. The process of
forming in the device substrate at least one further integrated device provided with a respective second sensor region having an active area; and
the coupling further comprising forming a further second empty space in a position corresponding to the respective active area of the further integrated device; second sensor region, the further second empty space being fluidly isolated from the first empty space.
37. The process of
38. The process of
39. The process of claim 36, wherein forming a first integrated device 29 wherein forming the second sensor region comprises forming a buried cavity within the device substrate and a membrane suspended over the buried cavity, and forming a further integrated device comprises forming a respective buried cavity within the device substrate and a respective membrane suspended over the respective buried cavity; and wherein forming a first integrated device comprises forming a pressure sensor, and forming at least one further integrated device comprises the process further comprising forming an inertial sensor that comprises forming an inertial mass on the respective membrane and within the further empty space of the second sensor region.
40. The process of
41. The process of claim 36 29, wherein forming a first integrated device the first sensor region comprises forming a portion of a pressure sensor, and forming at least one further integrated device a second sensor region comprises forming a portion of a reference pressure sensor for the pressure sensor.
42. The process of
43. The process of
44. The process of
46. The process of
a top surface of the capping substrate cap defining part of a first outer face of the package, and
the access duct.
47. The process of
48. The process of
49. The process of
50. The process of
52. The assembly of
53. The assembly of
54. The assembly of
55. The assembly of
56. The assembly of
57. The assembly of
58. The assembly of
59. The assembly of
60. The assembly of
61. The assembly of
62. The assembly of
63. The assembly of
64. The assembly of
65. The assembly of
66. The assembly of
67. The assembly of
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1. Technical Field
The present disclosure relates to a substrate-level assembly (usually known as “wafer-level package”) for an integrated device and, in particular, a sensor device, as well as to a corresponding manufacturing process and the related integrated device.
2. Description of the Related Art
Semiconductor sensors are known (for example, pressure sensors, inertial sensors, microphones, or gas sensors) which are made with microfabrication techniques and whose operation is based upon the presence of a membrane that is suspended over a cavity.
For example, EP 1 577 656, filed in the name of the present applicant, describes a pressure sensor and a manufacturing process thereof. In detail (
European patent application EP 05425028.7, filed in the name of the present applicant on Jan. 25, 2005, describes a piezoresistive accelerometer and a corresponding manufacturing process. In detail (
The inertial mass 11 is deposited through a metal mesh, made, for example, of nickel or steel, having suitable openings in positions corresponding to the areas where the welding paste is to be deposited. Furthermore, the deposition is accompanied by a temperature increase step, during which the inertial mass 11 adheres to the top surface of the membrane 4, assuming, after cooling, the described shape.
The center of gravity of the inertial mass 11 is placed outside of the membrane 4, so that, in use, an acceleration acting on the accelerometer 10 determines a momentum on the inertial mass 11, which causes inclination thereof in a corresponding direction. The displacement of the inertial mass 11 causes a deformation of the membrane 4 and a variation in the resistivity of the piezoresistive elements 5, whence an appropriate detection circuit determines the amount of the acceleration acting on the accelerometer 10.
The aforesaid patent application No. EP 05425028.7 further discloses (
Moreover, MEMS microphone sensors are known, an example of which is shown in
The dimensions of the sensors described are particularly small, namely, in the region of 0.8 mm×0.8 mm×0.3 mm (length×width×thickness), or in the region of 2 mm×2 mm×0.3 mm, so that traditional packaging techniques do not prove advantageous, and in particular packages of a traditional type, of a molded or pre-molded type, prove to be of excessive encumbrance and in any case not optimized for applications, such as automotive or consumer applications, which require size minimization. For example, existing packages for MEMS microphones envisage the use of a rather bulky metallic casing (or made by a combination of FR4 and a metallic material) which protects and electrostatically shields the sensor die. Moreover, packages of the traditional type are not optimized in terms of manufacturing costs.
On the other hand, the tendency to use alternative packaging techniques for integrated devices is known, said techniques enabling a reduction in the overall dimensions of the resulting electronic devices, and a simultaneous reduction in the manufacturing costs. In particular, the so-called “wafer-level packaging” technique is known, which envisages formation of a protection layer directly on top of a layer of semiconductor material housing integrated devices, to mechanically protect the integrated devices.
The present disclosure provides a substrate-level assembly for integrated devices that will enable minimization of the costs of the manufacturing process and of the final dimensions of the corresponding electronic devices.
According to the present disclosure, a substrate-level assembly and a manufacturing process are consequently provided.
In accordance with one embodiment of the present disclosure, a substrate-level assembly is provided that includes a device substrate of semiconductor material having a top face and housing a first integrated device provided with an active area in the proximity of said top face; a capping substrate coupled to the device substrate above said top face so as to cover the first integrated device in such a manner that a first empty space is provided in a position corresponding to the active area; and electrical-contact elements for electrical connection of the first integrated device outside of the substrate-level assembly.
In accordance with another embodiment of the present disclosure, an electronic device is provided that includes the substrate-level assembly described above, and a package encasing and mechanically protecting the substrate-level assembly, the package having a base body mechanically supporting the substrate-level assembly and a coating region configured to coat laterally the substrate-level assembly.
In accordance with another embodiment of the present disclosure, a process for manufacturing a substrate-level assembly is provided, the processing including providing a device substrate of semiconductor material, having a top face; forming a first integrated device within the device substrate and with an active area in the proximity of the top face; coupling a capping substrate to the device substrate above the top face so as to cover the first integrated device, the coupling comprising forming a first empty space in a position corresponding to the active area; and forming electrical-contact elements for electrical connection of the first integrated device with the outside of the substrate-level assembly.
In accordance with another embodiment of the present disclosure, an assembly is provided, the assembly including an article, and a sensor assembly adapted to monitor at least one condition of the article, the sensor assembly including a device substrate of semiconductor material, having a top face and housing a first integrated device provided with an active area in the proximity of the top face; a capping substrate coupled to the device substrate above the top face so as to cover the first integrated device in such a manner that a first empty space is provided in a position corresponding to the active area; and electrical-contact elements for electrical connection of the first integrated device outside of the substrate-level assembly.
For a better understanding of the present disclosure, preferred embodiments thereof are now described, purely by way of non-limiting example and with reference to the attached drawings, wherein:
An integrated device, namely a pressure sensor 1, is formed inside the device substrate 20, as described with reference to
According to an aspect of the present disclosure, a capping substrate 21, made of semiconductor material (for example, silicon), glass, or other ceramic or polymeric material, is (mechanically or electrically or a combination of mechanically and electrically) coupled to the device substrate 20, on top of the top surface 20a, so as to coat and protect the pressure sensor 1 and so as to provide a substrate-level assembly 22 for the pressure sensor 1. In particular, by the expression “substrate-level assembly” is meant herein the composite structure comprising the device substrate 20, the capping substrate 21, and the corresponding electrical input/output connections (made as described hereinafter).
According to an aspect of the present disclosure, the capping substrate 21 is joined to the device substrate 20 via a bonding process, which exploits a bonding region 23 (advantageously a sealing region), set in contact with, and on top of, the top surface 20a, to ensure joining. For example, the bonding region 23 is made of glass frit or a metal or polymeric material. The bonding region 23 has a ring conformation, and surrounds, without being superimposed thereon, the membrane 4 of the pressure sensor 1. Furthermore, the bonding region 23 has a main dimension of extension of between 100 μm and 300 μm, in the case of glass-frit bonding, and smaller than 100 μm, in the case of metal bonding, with a maximum thickness of approximately 10 μm in both cases.
According to an aspect of the present disclosure, a sensor cavity 24 is formed within the capping substrate 21, in a position corresponding to, and in communication with, the membrane 4. The sensor cavity 24 is made, for example, via an anisotropic (or isotropic) chemical etch, starting from a first surface 21a of the capping substrate 21 in contact with the device substrate 20, and has a depth of between 10 μm and 400 μm. Consequently, after joining between the device substrate 20 and the capping substrate 21, an empty space 25 remains over the membrane 4 so as to ensure freedom of movement thereof and so as not to alter deformation thereof as a function of a pressure applied. In particular, the empty space 25 is defined partly by the thickness of the bonding region 23 and partly by the sensor cavity 24 dug in the capping substrate 21, and is delimited partly by the bonding region 23 and partly by the walls of the sensor cavity 24.
Furthermore, a first access duct 26 is formed within the capping substrate 21, starting from a second surface 21b of the capping substrate 21, not in contact with the device substrate 20, and reaching the sensor cavity 24, in such a manner as to be fluidically connected to the empty space 25 and to the outside of the capping substrate 21. For example, the first access duct 26 can be formed via an anisotropic chemical etch or a deep silicon etch or a combination thereof.
Electrical input/output connections are finally provided for electrical connection of the pressure sensor 1 with the outside of the substrate-level assembly 22, in the form of through vias 28a, which traverse the device substrate 20 until the bottom surface 20b is reached, or else in the form of connection pads 28b carried by a portion of the top surface 20a placed externally of the bonding region 23 and the capping substrate 21 so as to be accessible from the outside and enable contact using the “wire-bonding” technique (as illustrated schematically in
In use, a fluid at a given pressure, the value of which must be determined, penetrates within the capping substrate 21 through the first access duct 26, reaches the empty space 25, and acts on the membrane 4, e.g., causing its deformation, which is detected by the transduction elements 5.
In use, the outer surface of the membrane 4 (opposite, i.e., to the buried cavity 3) is set in communication with a fluid at a first pressure through the first access duct 26 made through the capping substrate 21. The internal surface of the membrane 3, instead, is set in communication with a fluid at a second pressure through the second access duct 30. In this way, the membrane 3 deforms as a function of the difference between the first and second pressures so as to enable a differential measurement of pressure.
In use, within the further sensor cavity 24′ a fluid having a given reference pressure is entrapped, whilst the sensor cavity 24 is set in fluid communication with a fluid at a given pressure through the first access duct 26 so as to implement a relative pressure measurement.
In use, the accelerometer 10 detects an acceleration imparted on the monitoring device as a function of the deformation of the respective membrane 4′, due to the displacement of the inertial mass 11. As described above, the separation portion 32 of the capping substrate 21, and the bonding region 23, set between the free spaces 25, 25′ do not enable the fluid under pressure to reach the further sensor cavity 24′.
In general, the device substrate 20 can integrate an arbitrary number of sensor devices, and in this case there is provided a corresponding number of additional free spaces 25′, fluidically isolated from one another, and possibly of additional sensor cavities 24′, separated by additional separation portions 32′ of the capping substrate 21, and of additional access ducts communicating with respective sensor cavities. By way of example, in
According to a further aspect of the present disclosure (
A possible variant of the package 40 envisages,
As shown in
The described substrate-level assembly has the following advantages.
In particular, the manufacturing process of the assembly is optimized in terms of costs and duration, in so far as it is performed directly starting from the device substrate, with process steps that are a continuation of those used for the formation of the integrated sensors. The resulting assemblies have extremely contained dimensions, which are generally in the region of 1.7 mm×1.7 mm×0.8 mm but can reach 1.3 mm×1.3 mm×0.8 mm in the case of just one pressure sensor, and which are generally in the region of 1.7 mm×2.5 mm×0.8 mm, but can reach 1.3 mm×2.5 mm×0.8 mm in the case of the pressure monitoring device (which integrates both the pressure sensor and the accelerometer). In particular, in the latter case, a single substrate-level assembly is advantageously provided for the pressure sensor and for the accelerometer, and said assembly enables an effective fluid isolation between the empty spaces provided above the membrane of the two sensors.
The substrate-level assembly can constitute a complete device made of semiconductor material, in so far as the integrated sensors housed within the device substrate are automatically protected from the back by the device substrate 20 and on the top by the capping substrate 21. However, the use of the package 40 can be advantageous in all the cases where it is not convenient to have a complete integrated device made of semiconductor material (for example, in the case where particular environmental conditions require a further protection from the outside environment). In any case, also the package 40 has small dimensions, in the region of 3 mm×3 mm×1 mm.
Furthermore, the package 40, as well as the substrate-level assembly 22, can be handled and positioned easily, and in particular can be advantageously used as surface-mount devices (SMDs).
The described manufacturing process does not envisage the use of protection gels, as is, instead, required in the case where molded packages of a traditional type are used.
Finally, it is clear that modifications and variations can be made to what is described and illustrated herein, without thereby departing from the scope of the present disclosure, as defined in the attached claims.
In particular, the capping substrate 21 can advantageously be doped in order to increase its conductivity and provide an electrostatic shielding for the sensor(s) integrated within the device substrate 20. To improve this shielding effect (which is important, for example, in the case where the electronic device integrating the substrate-level assembly is a mobile phone), also the bonding region 23 could be made conductive so as to shield the electromagnetic radiations.
The capping substrate 21 can also be realized by means of an epitaxial or galvanic (electroplating) growth on the device substrate 20 instead of being bonded thereto, in order to be integral with the device substrate 20. In this case, the empty space 25 can be provided with standard techniques, e.g., by etching of a sacrificial layer interposed between the device substrate and the grown layer.
Alternatively, as shown in
Furthermore, as shown in
It should be clear that the substrate-level assembly 22 could be encased in the package 40 even with more than one die, integrating other circuits or passive components, in a stacked or side-by-side arrangement, as described previously.
Also, in the substrate-level assembly the device substrate could house other types of micromechanical devices, e.g., not provided with a membrane, having an active area at a top surface thereof that must remain free and/or accessible from the outside of the assembly (or package). In the sensors described, the active area comprises the membrane suspended over the buried cavity.
Joining between the device substrate 20 and the capping substrate 21 can be made via direct or anodic bonding, so without the need to envisage the bonding region 23 on the top surface 20a of the device substrate 20. In this case, the empty space 25 above the membrane 4 is determined just by the sensor cavity 24, which accordingly must be appropriately sized.
Instead, as shown in
Furthermore, above the membrane of the integrated sensors, a single through cavity could be provided (not illustrated), which traverses the entire thickness of the capping substrate 21 and is consequently accessible from outside the substrate-level assembly 22.
The capping substrate 21 could be patterned also on the outer and exposed side (second surface 21b), e.g., for realizing a first access duct with a different shape (having a larger section towards the outside).
Even though
In addition, further types of sensors can be integrated within the device substrate 20. For example, a gas sensor can be integrated therein, which also bases its operation upon the presence of a membrane suspended over a cavity. Also for said sensor a respective first access duct 26 must be provided to enable entry of a fluid within the substrate-level assembly 22. In detail, the suspended membrane 4 is covered by a layer of sensing material, depending on the chemical(s) it is desired to detect. The membrane is important to guarantee a thermal decoupling with the substrate device 20 during the assembling steps. The silicon cap acts as a protection for the gas sensor, and can be covered with a sticky foil or any other laminated film during a storage period, in order to prevent dust and moisture from damaging the sensor. It is advantageous that the electrical input/output connections (e.g., the connection pads 28b) are arranged outside the capping substrate 21 and covered by the coating 44, so that any kind of damages is avoided due to the presence of the fluid to be detected within the first empty space 25 (especially in case of a humidity sensor).
The deformation of the membrane 4 of the integrated sensors could be detected with capacitive, instead of piezoresistive, techniques in a known way which is not described in detail.
The inertial mass 11 could have a shape different from the one described and illustrated; in any case, it is configured so as to be affected by the accelerations imparted on the integrated device, and to undergo a consequent displacement.
Finally, it is clear that the pressure monitoring device described can be used for other applications. For example, in the automotive field, it can be used for monitoring the pressure of the air-bag, for checking the pressure of failure of an ABS system, or for monitoring the pressure of the oil or the pressure of injection of the fuel.
Other possible applications are in the medical field, where the pressure sensor can be used for monitoring blood pressure, or in ink-jet applications. In the latter case, an ink chamber can be provided within the capping substrate 21; the first access duct 26 acts as a nozzle, offering a way out for the ink contained within the empty space 25 when heated by an appositely provided circuitry, which can be implemented in the suspended membrane. In particular, in this application, the presence of a flared access duct to the empty space 25 could be advantageous to facilitate ink expulsion. Accordingly, the manufacturing process of the capping substrate 21 could envisage a first etching, of a wet type, to provide the sensor cavity 24 having sloping lateral walls and a tapered section towards the outside, and a second etching, of a dry type, to provide the first access duct 26, having rectilinear walls and a smaller section.
The various embodiments described above can be combined to provide further embodiments. All of the U.S. patents, U.S. patent application publications, U.S. patent applications, foreign patents, foreign patent applications and non-patent publications referred to in this specification and/or listed in the Application Data Sheet are incorporated herein by reference, in their entirety. Aspects of the embodiments can be modified, if necessary to employ concepts of the various patents, applications and publications to provide yet further embodiments.
These and other changes can be made to the embodiments in light of the above-detailed description. In general, in the following claims, the terms used should not be construed to limit the claims to the specific embodiments disclosed in the specification and the claims, but should be construed to include all possible embodiments along with the full scope of equivalents to which such claims are entitled. Accordingly, the claims are not limited by the disclosure.
Baldo, Lorenzo, Vigna, Benedetto, Combi, Chantal, Lasalandra, Ernesto, Ziglioli, Federico Giovanni, Magugliani, Manuela, Riva, Caterina
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