A process for forming electrically conductive circuitry on a metallic nonconductive substrate or insulating layer which includes the steps of providing a nonconductive ceramic substrate having a metallic component and which can dissociate into its constituent components to provide dissociated metal bonded to the ceramic substrate upon application of laser energy. Laser energy in then applied to predetermined areas of the surface of the nonconductive ceramic substrate to provide dissociated metallic conductors in the predetermined areas. The disclosed process further includes the formation of metallized through holes by application of laser energy to the nonconductive ceramic substrate to form a through hole, whereby dissociated metal in formed on the inside of the through hole. The disclosed process also includes the capability to down trim a thick film or thin film resistor which is conductively coupled between two areas of metallization. Laser energy is applied to a portion of the thick film or thin film resistor and to a portion of the metallic nonconductive ceramic substrate in a predetermined pattern to provide a continuous dissociated metallic conductor which passes through the thick film or thin film resistor and is conductively connected to one of two areas of electrically conductive metallization.

Patent
   4817269
Priority
Sep 14 1987
Filed
Sep 14 1987
Issued
Apr 04 1989
Expiry
Sep 14 2007
Assg.orig
Entity
unknown
0
5
EXPIRED
1. A process for forming electrically conductive elements on a ceramic substrate comprising the steps of:
providing a nonconductive ceramic substrate having a metallic component and which can dissociate into its constituent components to provide dissociated metal bonded to the ceramic substrate upon application of laser energy; and
applying laser energy to predetermined areas of the surface of the nonconductive ceramic substrate to provide dissociated metallic conductors in the predetermined areas.
13. A process of forming electrically conductive metallization on or through a nonconductive ceramic substrate or ceramic insulating layer of a hybrid microcircuit, said process comprising the steps of:
providing a nonconductive ceramic substrate or ceramic insulating layer having a metallic component which dissociates into its constituent components upon the application of laser energy, said metallic component rebonding to said substrate or insulating layer upon the removal of said laser energy; and
dissociating predetermined portions of said substrate or insulating layer to provide electrically conductive metallization comprising dissociated metallic conductors thereon or therethrough.
11. A process of forming electrically conductive metallization on or through a nonconductive ceramic substrate or ceramic insulating layer of a hybrid microcircuit, said process comprising the steps of:
providing a nonconductive ceramic substrate or ceramic insulating layer having a metallic component which dissociates into its constituent components upon the application of laser energy, said metallic component rebonding to said substrate or insulating layer;
applying laser energy to predefined areas of the surface of said substrate or insulating layer to dissociate said metallic component from said substrate or insulating layer; and
removing said laser energy from said predefined areas to allow said metallic component to rebond to the surface of said substrate or insulating layer, said rebonded metallic component forming electrically conductive metallization on said surface.
6. A process for forming electrically conductive elements on a ceramic substrate comprising the steps of:
providing a nonconductive ceramic substrate having a metallic component and which can dissociate into its constituent components to provide dissociated metal bonded to the ceramic substrate upon application of laser energy;
forming at least two areas of electrically conductive metallization on the surface of said conductive ceramic substrate;
forming a thick film or thin film resistor on the surface of said nonconductive substrate between two areas of said electrically conductive metallization; and
applying laser energy to a portion of the thick film or thin film resistor and to a portion of the metallic nonconductive ceramic substrate in a predetermined pattern to provide a continuous dissociated metallic conductor which passes through said thick film or thin film resistor and is conductively connected to one of said two areas of electrically conductive metallization.
2. The process of claim 1 wherein the step of providing a metallic nonconductive ceramic substrate includes the step of providing an aluminum nitride ceramic substrate.
3. The process of claim 1 wherein the step of applying laser energy includes the step of applying laser energy provided by a YAG laser.
4. The process of claim 1 wherein the step of applying laser energy includes the step of applying laser energy provided by a carbon dioxide laser.
5. The process of claim 1 wherein the step of applying laser energy includes the step of applying laser energy to said substrate to form a through hole in the ceramic substrate, whereby dissociated metal is formed on the inside of the through hole.
7. The process of claim 6 wherein the step of providing a metallic nonconductive ceramic substrate includes the step of providing an aluminum nitride ceramic substrate.
8. The process of claim 6 the step of applying laser energy includes the step of applying laser energy provided by a YAG laser.
9. The process of claim 6 wherein the step of applying laser energy includes the step of applying laser energy provided by a carbon dioxide laser.
10. The process of claim 6 wherein said predetermined pattern includes a linear portion which passes through and extends beyond the thin film or thick film resistor and further includes linear portions which extend from the ends of such linear portion to one of said two areas of electrically conductive metallization.
12. The process of claim 11 further comprising the steps of:
forming a thick film or thin film resistor on the surface of said substrate or insulating layer between predetermined areas of said electrically conductive metallization; and
applying and removing said laser energy to the surface of said substrate or insulating layer below said resistor so as to short circuit a portion thereof to decrease the resistance value thereof.

The disclosed invention relates to the formation of electrically conductive circuitry on a nonconductive substrate, and is more particularly directed to a technique for selectively dissociating the localized portions of an aluminum nitride ceramic substrate or insulating layer to form electrically conductive circuitry thereon.

Hybrid circuit structures, also known as hybrid microcircuits, implement the interconnection and packaging of discrete circuit devices, and may include one or more nonconductive ceramic substrates or layers for supporting circuit elements, which may be mounted on both sides of the microcircuit. Conductor runs for interconnecting circuit elements are formed on the surfaces of the substrate or subsequent layers, and metallized vias may be provided for interconnecting circuitry on the two sides of a ceramic substrate or between layers.

Conductor runs, for example, can be formed by thick film screen printing or thin film metallization techniques, and via metallization can be provided by thick film screen printing techniques. However, as is well known, such techniques take time and require several steps. For example, thick film screen printing requires the preparation and use of silk screens and the application of conductive paste, while thin film metallization requires chemical vapor deposition, masking and etching.

A further consideration with conductor runs formed with known techniques is the inability to trim resistors to decrease resistance values. Generally, trimming of resistors with present techniques can only increase resistance values.

It would therefore be an advantage to provide a simplified process for forming electrically conductive circuitry on a nonconductive ceramic substrate or insulating layer.

Another advantage would be to provide a process for forming electrically conductive circuitry on a nonconductive ceramic substrate or insulating layer which avoids thick film and thin film metallization processes.

It would also be an advantage to provide a process for forming electrically conductive circuitry on a nonconductive ceramic substrate or insulating layer which avoids the application of conductive material thereto.

A further advantage would be to provide a process for forming electrically conductive circuitry on a nonconductive ceramic substrate or insulating layer which allows for trimming resistors to decrease resistance values.

A still further advantage would be to provide a process for metallizing vias through insulating layers or metallic nonconductive substrates.

The foregoing and other advantages and features are provided in a process for forming electrically conductive circuitry on a metallic nonconductive substrate or insulating layer which includes the step of providing a nonconductive ceramic substrate having a metallic component and which can dissociate into its constituent components to provide dissociated metal bonded to the ceramic substrate upon application of laser energy. Laser energy in then applied to predetermined areas of the surface of the nonconductive ceramic substrate to provide dissociated metallic conductors in the predetermined areas.

A further aspect of the invention is the formation of metallized through holes by application of laser energy to the nonconductive ceramic substrate to form a through hole, whereby dissociated metal in formed on the inside of the through hole.

Still another aspect of the invention is the capability to down trim a thick film or thin film resistor which is conductively coupled between two areas of metallization. Laser energy is applied to a portion of the thick film or thin film resistor and to a portion of the metallic nonconductive ceramic substrate in a predetermined pattern to provide a continuous dissociated metallic conductor which passes through the thick film or thin film resistor and is conductively connected to one of two areas of electrically conductive metallization.

The advantages and features of the disclosed invention will readily be appreciated by persons skilled in the art from the following detailed description when read in conjunction with the drawing wherein:

FIG. 1 is a schematic illustration of a conductive structure made pursuant to the process of the invention.

FIG. 2 is a schematic illustration of a conductive structure made pursuant to the process of the invention for trimming a resistor to decrease its resistance value.

FIG. 3 is a schematic illustration of metal-coated through hole made pursuant to the process of the invention.

In the following detailed description and in the several figures of the drawing, like elements are identified with like reference numerals.

Referring now to FIG. 1, shown therein is a plan view schematically illustrating a nonconductive ceramic substrate or insulating layer 11, for example an aluminum nitride ceramic substrate, of a hybrid circuit. The substrate 11 has a circuit device 13 mounted thereon, and further has bonding pads 15, 17, 19, 21 distributed about its periphery. The bonding pads 15, 17, 19, 21 are metallized using known thick or thin film metallization techniques, as is a conductor trace 23. Pursuant to well-known techniques, wire bonds 25 are utilized to conductively connect terminals of the circuit device 13 to the bonding pads 15, 17, 19, 21 and the conductor trace 23.

The aluminum nitride ceramic substrate 11 of FIG. 1 further includes bonding pads 27, 29 and conductor traces 31, 33. These pads and traces 27, 29, 31, 33 comprise dissociated aluminum bonded to the aluminum nitride ceramic substrate 11. Such dissociated aluminum bonding pads and conductor traces are formed by applying laser energy to the regions of the ceramic substrate 11 where such bonding pads and conductor traces 27, 29, 31, 33 are to be formed. By way of example, the laser energy may be provided by a yttrium aluminum garnet (YAG) laser or by a carbon dioxide (CO2) laser. The laser beam is controlled to scan the regions where the aluminum is to be dissociated from the substrate and which form the metallized interconnect pads and traces 27, 29, 31, 33. A very fine line trace is achieved, having a dimension on the order of 0.001 inch in width. This permits the formation of microcircuits which have a greater circuit density than microcircuits formed with conventional processing techniques.

By way of particular example, a YAG laser may be utilized to form the pads and traces 27, 29, 31, 33 with the following parameters:

Equipment: ESI Model 44 YAG Laser

Power Setting: 14.5 amps

Pulse Rate: 2000 pps

Speed: 4 mm/sec.

A particular advantage of the disclosed dissociative process is that it provides the capability of metallizing specific locations after other metallization has already been formed, for example by thick film or thin film techniques. Thus, the disclosed dissociative process can be advantageously utilized to add bonding pads and conductor traces to already fabricated circuits or prototype circuits.

A particular application of the capability of metallizing specific locations is illustrated in FIG. 2, which shows an aluminum nitride ceramic substrate 111, for example, having a thin film resistor 113 formed thereon. The thin film resistor 113 is illustrated as being coupled between two conductor pads 115, 117. A U-shaped dissociated aluminum conductor 119 extends from the conductor pad 115 and traverses the thin film resistor at a location spaced from the conductor pad 115. As a result of the dissociated aluminum conductor 119, the resistance value of the thin film resistor 113 has been reduced relative to its original resistance value, since the resistive material between the dissociated aluminum conductor 119 and the conductor pad 115 is effectively short circuited. Thus, the disclosed dissociation process can be used to trim resistors to decrease resistance values. Heretofore, the process of decreasing thick or thin film resistors formed in hybrid microcircuits was not possible with conventional resistor trimming techniques.

It is to be understood that the resistors can also be trimmed to increase their value using the laser. This is generally accomplished by using a laser to cut through a portion of the resistor in the shape of an "U", where the ends of the legs of the "U" are at an edge of the resistor. Such cut which effectively reduces the amount of resistor material.

Referring now to FIG. 3, illustrated therein is a further use of the metal dissociating process of the present invention. A through hole 213 is formed in an aluminum nitride ceramic substrate 211, for example, by a laser. As a result of the laser energy, dissociated aluminum is formed on the inside surface of the through hole and around the openings thereof. Thus, a conductive through hole is formed without first forming a hole in the ceramic substrate 211 and then metallizing the hole as is done with known processes. Through holes formed in this manner can be utilized to interconnect circuitry on both sides of an aluminum nitride ceramic substrate or insulating layer.

The foregoing has been a disclosure of a metal dissociating process which provides several advantages and features including the capability of forming dissociated metal conductors quickly and easily without the use of known thick film or thin film metallization techniques. Further, the disclosed metal dissociating process provides for trimming resistors to decrease resistance values. Also, the dissociating process can be utilized to produce metallized through holes simply by forming a hole with a laser.

This process makes it possible to process surface layer interconnect metallization and metallize via through holes by programming a laser to directly write the conductor lines and form metallized vias. This process may be performed before or after other metallization techniques have been employed to form bonding pads or resistors or the like. A significant increase in processing speed is achieved and laborious and costly screen printing and deposition, etching and masking processes are eliminated by employing the process of the present invention. Also, resistor trimming can be performed to decrease resistor values using the present invention.

Although the foregoing has been a description and illustration of specific embodiments of the invention, various modifications and changes thereto can be made by persons skilled in the art without departing from the scope and spirit of the invention as defined by the following claims. In particular, although aluminum nitride has been disclosed in the exemplary embodiment of the inventions, the present invention is not limited to only aluminum nitride substrates or insulating layers, but encompasses other nonconductive metallic materials which dissociate in the manner described herein.

Root, Randolph E., Vu, Thanh T.

Patent Priority Assignee Title
Patent Priority Assignee Title
4321073, Oct 15 1980 Hughes Electronics Corporation Method and apparatus for forming metal coating on glass fiber
4490210, Jan 24 1984 International Business Machines Corporation Laser induced dry chemical etching of metals
4694138, Feb 10 1984 Kabushiki Kaisha Toshiba Method of forming conductor path
4715117, Apr 03 1985 Ibiden Kabushiki Kaisha Ceramic wiring board and its production
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Sep 14 1987Hughes Aircraft Company(assignment on the face of the patent)
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