A garment including an elastomeric composite laminate around one or more openings for the legs, arms, waist, neck, or the like of a wearer. The garment includes a substrate defining the one or more openings, and an elastomeric composite laminate attached to the substrate adjacent the one or more openings. The elastomeric composite laminate includes reinforcement strands incorporated into an elastomeric adhesive film. In one embodiment, the garment is a pant-like garment with the elastomeric composite laminate adjacent each of the leg openings.
|
21. A pant-like garment comprising:
a chassis including a substrate and defining a waist opening and two leg openings; and
an elastomeric composite attaching a facing sheet to the substrate adjacent each of the leg openings, the elastomeric composite including a plurality of extruded elastic strands adhered to an elastomeric adhesive film;
wherein the elastomeric adhesive film includes about 30% to about 65% by weight base polymer.
7. A pant-like garment comprising:
a chassis including a substrate and defining a waist opening and two leg openings; and
an elastomeric composite attaching a facing sheet to the substrate adjacent each of the leg openings, the elastomeric composite including a plurality of extruded elastic strands at least partially embedded in an elastomeric adhesive film;
wherein the plurality of extruded elastic strands have different sizes or compositions.
1. A pant-like garment comprising:
a chassis including a substrate and defining a waist opening and two leg openings; and
an elastomeric composite attaching a facing sheet to the substrate adjacent each of the leg openings, the elastomeric composite including a plurality of extruded elastic strands adhered to an elastomeric adhesive film;
wherein the plurality of extruded elastic strands make up about 5% to about 50% by weight of the elastomeric composite.
2. The garment of
3. The garment of
4. The garment of
5. The garment of
6. The garment of
8. The garment of
9. The garment of
10. The garment of
11. The garment of
12. The garment of
13. The pant-like garment of
16. The pant-like garment of
20. The pant-like garment of
22. The pant-like garment of
23. The pant-like garment of
24. The pant-like garment of
25. The pant-like garment of
26. The pant-like garment of
27. The pant-like garment of
28. The pant-like garment of
29. The pant-like garment of
30. The pant-like garment of
|
This application is a continuation-in-part application of U.S. patent application Ser. No. 10/187,761 filed 2 Jul. 2002.
This invention is directed to garments having a strand-reinforced elastomeric adhesive film laminate adjacent one or more openings of the garment.
Personal care garments often include elasticized portions to create a gasket-like fit around certain openings, such as waist openings and leg openings. Multiple elastic strands can be attached to the openings to provide fit and comfort and to prevent leakage. Alternatively, elastic laminates can be used in the manufacture of such garments to avoid complicated elastic attachment steps during the garment manufacturing process.
One type of elastomeric laminate is a stretch-bonded laminate that includes elastic strands produced from an extruder and bonded to a facing sheet or sheets using a hot melt adhesive. Laminates including pre-made elastic strands can be processed online but require an elastic attachment adhesive with high add-on in order to reduce strand slippage. The cost of making stretch-bonded laminates can be relatively high due to the cost of the facing sheet or sheets, plus the cost of the elastic strands, plus the cost of the adhesive.
Another type of elastomeric laminate can be made using a vertical filament laminate-stretch-bonded laminate (VFL-SBL) process. However, the VFL-SBL process must be in off-line operation due to process complexity.
One drawback associated with conventional elastic strands and elastic laminates around garment openings are leakage and fit problems, particularly around leg openings when the garment is loaded. Such problems result from weakening tension or uneven tension distribution of the leg elastics. More specifically, elastic tension is weakened during wearing because of strand relaxation and strand slippage at elevated temperatures. To prevent leakage, tension of the leg elastics can be increased by increasing the number of strands or by using a high denier of strands at a higher stretching ratio. However, an increase in leg elastic tension is likely to cause a “red mark” on a wearer's skin because tension of the garment is actually concentrated on the narrow surface of the strand instead of the whole elastic laminate. Plus, the tension on the conventional elastic laminate can not be transported or distributed uniformly during use especially when legs are moving. Also, current elastic strand-based laminates cannot be die-cut to curve and fit the body exactly. Making curved elastic strand laminates in a high-speed assembly process requires very complex and precise control which is associated with large capital investment.
Elastomeric adhesive compositions are multifunctional in the sense that they function as an elastomer in a nonwoven composite while also serving as a hot melt adhesive for bonding substrates. Elastomeric adhesive compositions in the form of elastomeric adhesive films are currently recognized as suitable for use in the manufacture of personal care articles. More particularly, elastomeric adhesive compositions can be used to bond facing materials, such as spunbond, to one another while simultaneously elasticizing the resulting laminate. The resulting laminate can be used to form an elastomeric portion of an absorbent article, such as a region surrounding a waist opening and/or a leg opening.
Non-woven elastic adhesive film laminates may require high output of adhesive add-on to achieve a tension target for product application. High add-on of the film laminate may generate a bulky, thick feel and appearance, and high cost. Furthermore, the high adhesive output requirement for the film formation would make on-line processing even more difficult due to the limitation of hot melt equipment output capacity. Also, such film lamination processes are relatively complex and need more precise control than strand lamination since a film edge thinning effect may cause the film to break during stretching.
Some elastomeric adhesive compositions lose their adhesiveness when the compositions are stretched and then bonded between two nonwoven substrates. The elasticity of these elastomeric adhesive compositions (in terms of tension decay) is negatively affected when laminates including the compositions are aged at elevated temperatures, for example around 130 degrees Fahrenheit, which is commonly experienced under hot boxcar storage conditions. It appears that the poor tension and adhesion of such elastomeric adhesive compositions results from the chosen base polymer, tackifier, and plasticizer chemistries as well as the unbalanced ratio of polymer to low molecular weight species in the formulation.
There is a need or desire for an elastomeric laminate that can be used to create elasticized portions of a personal care garment, wherein the laminate does not display high tension decay or delamination. There is a further need or desire for a personal care garment including elasticized portions that possess a soft feel and comfortable fit, while providing adjustable tension to minimize leakage.
In response to the discussed difficulties and problems encountered in the prior art, a new garment including a strand-reinforced elastomeric adhesive film laminate has been discovered.
The garment of the invention includes one or more openings for a body part such as, for example, a neck opening, a wrist opening, an arm opening, a waist opening, a leg opening, and/or an ankle opening. The garment includes a substrate that defines the opening or openings, with an elastomeric composite laminate attached to the substrate adjacent the opening or openings. The elastomeric composite laminate is used in place of conventional elastic strands or elastic laminates to provide better fit and comfort, less leakage and more tension control for disposable garment applications.
The elastomeric composite laminate is made up of a combination of extruded reinforcing strands and elastomeric adhesive film. The strands may be adhered to, and possibly even partially or wholly embedded in, the elastomeric adhesive film. One surface of the laminate can be attached to the substrate while the other surface of the laminate may include a layer of spunbond or other facing material. Alternatively, a facing material can be laminated along both surfaces of the film prior to attaching the laminate to the substrate. The combination of reinforcing strands and the elastomeric adhesive film significantly and advantageously reduces the rate and extent of tension decay during wear, as well as improving adhesion properties of the spunbond laminates compared to spunbond laminates including elastomeric adhesive film without reinforcing strands. Additionally, the tension on the elastomeric composite laminate is distributed evenly across the width of the laminate instead of being concentrated only on the strands, thus reducing or eliminating red marking and providing a better fit. Furthermore, the reinforcing strands enable the composite tension to be tunable while preserving the soft feel and aesthetic properties of the laminate. Tuning can be achieved by adjusting the output of the strand or film add-on, adjusting the stretching ratio, selection of substrates, as well as polymer formulas. Another benefit of using the elastomeric composite laminate rather than conventional elastics is that the laminate can be die-cut into any shape for better fit and comfort without losing tension.
The garment of the invention may be a personal care garment, medical garment, industrial workwear garment, or the like. In one embodiment, the garment is a pant-like garment with a chassis including a substrate. The chassis defines a waist opening and two leg openings. The elastomeric composite laminate is attached to the substrate adjacent each of the leg openings.
With the foregoing in mind, it is a feature and advantage of the invention to provide a garment having a strand-reinforced elastomeric adhesive film laminate around one or more openings of the garment.
Within the context of this specification, each term or phrase below will include the following meaning or meanings.
“Bonded” refers to the joining, adhering, connecting, attaching, or the like, of at least-two elements. Two elements will be considered to be bonded together when they are bonded directly to one another or indirectly to one another, such as when each is directly bonded to intermediate elements.
“Elastic tension” refers to the amount of force per unit width required to stretch an elastic material (or a selected zone thereof) to a given percent elongation.
“Elastomeric” and “elastic” are used interchangeably to refer to a material or composite that is generally capable of recovering its shape after deformation when the deforming force is removed. Specifically, as used herein, elastic or elastomeric is meant to be that property of any material which, upon application of a biasing force, permits the material to be stretchable to a stretched biased length which is at least about 50 percent greater than its relaxed unbiased length, and that will cause the material to recover at least 40 percent of its elongation upon release of the stretching force. A hypothetical example which would satisfy this definition of an elastomeric material would be a one (1) inch sample of a material which is elongatable to at least 1.50 inches and which, upon being elongated to 1.50 inches and released, will recover to a length of less than 1.30 inches. Many elastic materials may be stretched by much more than 50 percent of their relaxed length, and many of these will recover to substantially their original relaxed length upon release of the stretching force.
“Elongation” refers to the capability of an elastic material to be stretched a certain distance, such that greater elongation refers to an elastic material capable of being stretched a greater distance than an elastic material having lower elongation.
“Extruded” refers to a material that is processed through an extrusion die or a slot coat die connected to an extruder or a melt tank.
“Film” refers to a thermoplastic film made using a film extrusion process, such as a cast film or blown film extrusion process. The term includes apertured films, slit films, and other porous films which constitute liquid transfer films, as well as films which do not transfer liquid.
“Garment” includes personal care garments, medical garments, and the like. The term “disposable garment” includes garments which are typically disposed of after 1-5 uses. The term “personal care garment” includes diapers, training pants, swim wear, absorbent underpants, adult incontinence products, feminine hygiene products, and the like. The term “medical garment” includes medical (i.e., protective and/or surgical) gowns, caps, gloves, drapes, face masks, and the like. The term “industrial workwear garment” includes laboratory coats, cover-alls, and the like.
“Layer” when used in the singular can have the dual meaning of a single element or a plurality of elements.
“Meltblown fiber” refers to fibers formed by extruding a molten thermoplastic material through a plurality of fine, usually circular, die capillaries as molten threads or filaments into converging high velocity gas (e.g., air) streams which attenuate the filaments of molten thermoplastic material to reduce their diameter, which may be to microfiber diameter. Thereafter, the meltblown fibers are carried by the high velocity gas stream and are deposited on a collecting surface to form a web of randomly dispersed meltblown fibers. Such a process is disclosed for example, in U.S. Pat. No. 3,849,241 to Butin et al. Meltblown fibers are microfibers which may be continuous or discontinuous, are generally smaller than about 0.6 denier, and are generally self bonding when deposited onto a collecting surface.
“Nonwoven” and “nonwoven web” refer to materials and webs of material having a structure of individual fibers or filaments which are interlaid, but not in an identifiable manner as in a knitted fabric. The terms “fiber” and “filament” are used herein interchangeably. Nonwoven fabrics or webs have been formed from many processes such as, for example, meltblowing processes, spunbonding processes, air laying processes, and bonded carded web processes. The basis weight of nonwoven fabrics is usually expressed in ounces of material per square yard (osy) or grams per square meter (gsm) and the fiber diameters are usually expressed in microns. (Note that to convert from osy to gsm, multiply osy by 33.91.)
“Polymers” include, but are not limited to, homopolymers, copolymers, such as for example, block, graft, random and alternating copolymers, terpolymers, etc. and blends and modifications thereof. Furthermore, unless otherwise specifically limited, the term “polymer” shall include all possible geometrical configurations of the material. These configurations include, but are not limited to isotactic, syndiotactic and atactic symmetries.
“Spunbond fiber” refers to small diameter fibers which are formed by extruding molten thermoplastic material as filaments from a plurality of fine capillaries of a spinnerette having a circular or other configuration, with the diameter of the extruded filaments then being rapidly reduced as taught, for example, in U.S. Pat. No. 4,340,563 to Appel et al., and U.S. Pat. No. 3,692,618 to Dorschner et al., U.S. Pat. No. 3,802,817 to Matsuki et al., U.S. Pat. Nos. 3,338,992 and 3,341,394 to Kinney, U.S. Pat. No. 3,502,763 to Hartmann, U.S. Pat. No. 3,502,538 to Petersen, and U.S. Pat. No. 3,542,615 to Dobo et al., each of which is incorporated herein in its entirety by reference. Spunbond fibers are quenched and generally not tacky when they are deposited onto a collecting surface. Spunbond fibers are generally continuous and often have average deniers larger than about 0.3, more particularly, between about 0.6 and 10.
“Strand” refers to an article of manufacture whose width is less than a film and is suitable for incorporating into a film, according to the present invention.
“Stretchable” means that a material can be stretched, without breaking, by at least 50% (to at least 150% of its initial (unstretched) length) in at least one direction, suitably by at least 100% (to at least 200% of its initial length), desirably by at least 150% (to at least 250% of its initial length). The term includes elastic materials as well as materials that stretch but do not significantly retract. The percentage stretch of strands and films is calculated by the percentage difference between a primary chill roll speed and a final nip roll speed. For example, in
“Thermoplastic” describes a material that softens and flows when exposed to heat and which substantially returns to a nonsoftened condition when cooled to room temperature.
“Thermoset” describes a material that is capable of becoming permanently cross-linked, and the physical form of the material cannot be changed by heat without the breakdown of chemical bonds.
“Vertical filament stretch-bonded laminate” or “VF SBL” refers to a stretch-bonded laminate made using a continuous vertical filament process, as described herein.
These terms may be defined with additional language in the remaining portions of the specification.
The present invention is directed to a garment 100 having one or more elasticized openings. The opening or openings may include a neck opening 102, a wrist opening 104, an arm opening 106, a waist opening 108, a leg opening 110, and/or an ankle opening 112, as shown in
The garment 100 of the invention may be a personal care garment 114 (FIG. 1), medical garment 116 (FIG. 2), industrial workwear garment 118 (FIGS. 3 and 4), or the like. More particularly, the garment 100 may be a diaper, training pants, swim wear, absorbent underpants, adult incontinence product, feminine hygiene product, protective medical gown, surgical medical gown, cap, gloves, drape, face mask, laboratory coat, or coveralls, for example. For ease of explanation, the following description is in terms of a pant-like garment 100, such as a child's training pant, having the elastic composite laminate 30 adjacent each of the leg openings 110.
Referring to
An elastomeric composite 20 alone is illustrated in FIG. 5. As shown, the elastomeric composite 20 includes an elastomeric adhesive film 22 with a number of elastic reinforcing strands 24 adhered to and partially embedded therein. Tension within the elastomeric composite 20 may be controlled through percentage stretch of the strands 24 prior to adhesion to the elastomeric adhesive film 22, through percentage stretch of the film 22 prior to adhesion to the strands 24, and/or through the amount of strand add-on or thickness, with greater stretch and greater add-on or thickness each resulting in higher tension. Tension can also be controlled through selection of the film composition, selection of the strand composition, and/or by varying strand geometries and/or spacing between strands. It will be appreciated that the strands 24 may be laid out periodically, non-periodically, and in various spacings, groupings, and sizes, according to the effect desired from the composite 20 and the use to which it is put.
As shown in
As another example,
The elastomeric adhesive film 22 is suitably made up of an elastomeric, hot melt, pressure-sensitive adhesive having an adhesive bond strength, as determined by the test method set forth below, of at least 50 grams force per inch (2.54 cm) width, suitably of at least 100 grams force per inch (2.54 cm) width, alternatively of at least 300 grams force per inch (2.54 cm) width, alternatively of at least from about 100 grams force per inch (2.54 cm) width to about 400 grams force per inch width. An example of a suitable elastomeric adhesive film 22 may be made up of 35 wt % PICOLYTE S115 and 65 wt % KRATON G2760. The elastomeric, hot melt, pressure-sensitive adhesive may be applied to a chill roll or similar device, in the form of a strand or ribbon. The strand or ribbon is then stretched and thinned to form the film 22. The film suitably has a thickness of about 0.001 inch (0.025 mm) to about 0.05 inch (1.27 mm), alternatively of from about 0.001 inch (0.025 mm) to about 0.01 inch (0.25 mm), and a width of from about 0.05 inch (1.27 mm) to about 3.0 inches (7.62 cm), alternatively of from about 0.5 inch (1.27 cm) to about 1.5 inches (3.81 cm). The elastomeric, adhesive film 22 may also be capable of imparting barrier properties in an application.
Suitable elastomeric, hot melt, pressure-sensitive adhesives from which the elastomeric adhesive film 22 may be made include elastomeric polymers, tackifying resins, plasticizers, oils and antioxidants.
One particular formulation of the elastomer adhesive film 22 includes a base polymer and a tackifier resin. The composition may also include additional additives. The choice of polymer and tackifier is important, as is the ratio of polymer or copolymers to tackifier. Another important consideration is the ratio of additives to tackifier.
The base polymer suitably has a styrene content of between about 15% and about 45%, or between about 18% and about 30%, by weight of the base polymer. The base polymer may achieve the styrene content either by blending different polymers having different styrene co-monomer levels or by including a single base polymer that has the desired styrene co-monomer level. Generally, the higher the styrene co-monomer level is, the higher the tension is.
The base polymer may include polystyrene-polyethylene-polypropylene-polystyrene (SEPS) block copolymer, styrene-isoprene-styrene (SIS), styrene-butadiene-styrene (SBS) block copolymer, as well as combinations of any of these. One example of a suitable SEPS copolymer is available from Kraton Polymers of Belpre, Ohio, under the trade designation KRATON® G 2760. One example of a suitable SIS copolymer is available from Dexco, a division of Exxon-Mobil, under the trade designation VECTOR™. Suitably, the film composition includes the base polymer in an amount between about 30% and about 65% by weight of the composition.
The tackifier may include hydrocarbons from petroleum distillates, rosin, rosin esters, polyterpenes derived from wood, polyterpenes derived from synthetic chemicals, as well as combinations of any of these. A key element of the film composition is a tackifier. An example of a suitable tackifier is available from Hercules Inc. of Wilmington, Del., under the trade designation PICOLYTE™ S115. Suitably, the composition includes the tackifier in an amount between about 30% and about 70% by weight of the composition.
Other additives may be included in the film composition as well. In addition to the adhesion provided by the tackifier, various additives may provide instantaneous surface tackiness and pressure sensitive characteristics as well as reduced melt viscosity. One example of a particularly suitable low softening point additive is PICOLYTE™ S25 tackifier, available from Hercules Inc., having a softening point in a range around 25 degrees Celsius, or paraffin wax having a melting point of about 65 degrees Celsius may also be used.
Additionally, an antioxidant may be included in the film composition, suitably in an amount between about 0.1% and about 1.0% by weight of the composition. One example of a suitable antioxidant is available from Ciba Specialty Chemicals under the trade designation IRGANOX™ 1010.
The elastomeric adhesive film 22 suitably has an elongation of at least 50 percent, alternatively of at least 150 percent, alternatively of from about 50 percent to about 200 percent, and a tension force of less than about 400 grams force per inch (2.54 cm) width, alternatively of less than about 275 grams force per inch (2.54 cm) width, alternatively of from about 100 grams force per inch (2.54 cm) width to about 250 grams force per inch (2.54 cm) width. Tension force, as used herein, is determined one minute after stretching the film to 100% elongation.
The elastomeric adhesive film 22 is capable not only of introducing a degree of elasticity to facing materials but is also capable of providing a construction adhesive function. That is, the film 22 adheres together the facing materials or other components with which it is in contact. It is also possible that the film does not constrict upon cooling but, instead, tends to retract to approximately its original dimension after being elongated during use in a product.
Materials suitable for use in preparing the elastic reinforcing strands 24 include raw polymers, a mixture of polymers, as well as tackified polymers. More specifically, the elastic reinforcing strands 24 may include diblock, triblock, tetrablock, or other multi-block elastomeric copolymers such as olefinic copolymers, including ethylene-propylene-diene monomer (EPDM), styrene-isoprene-styrene (SIS), styrene-butadiene-styrene (SBS), styrene-ethylene/butylene-styrene (SEBS), or styrene-ethylene/propylene-styrene (SEPS), which may be obtained from the Kraton Polymers of Belpre, Ohio, under the trade designation KRATON® elastomeric resin or from Dexco, a division of Exxon-Mobil, under the trade designation VECTOR® (SIS polymers); polyurethanes, including those available from E. I. Du Pont de Nemours Co., under the trade name LYCRA® polyurethane; polyamides, including polyether block amides available from Ato Chemical Company, under the trade name PEBAX® polyether block amide; polyesters, such as those available from E. I. Du Pont de Nemours Co., under the trade name HYTREL® polyester; polyisoprene; cross-linked polybutadiene; and single-site or metallocene-catalyzed polyolefins having density less than about 0.89 grams/cubic centimeter, available from Dow Chemical Co. under the trade name AFFINITY®. The elastic reinforcing strands 24 may also include a tackifier. The tackifier may include hydrocarbons from petroleum distillates, rosin, rosin esters, polyterpenes derived from wood, polyterpenes derived from synthetic chemicals, as well as combinations of any of these.
A number of block copolymers can also be used to prepare the elastic reinforcing strands 24 used in this invention. Such block copolymers generally include an elastomeric midblock portion B and a thermoplastic endblock portion A. The block copolymers may also be thermoplastic in the sense that they can be melted, formed, and resolidified several times with little or no change in physical properties (assuming a minimum of oxidative degradation). Alternatively, the elastic strands 24 can be made of a polymer that is not thermally processable, such as LYCRA® spandex, available from E. I. Du Pont de Nemours Co., or cross-linked natural rubber in film or fiber form. Thermoset polymers and polymers such as spandex, unlike the thermoplastic polymers, once cross-linked cannot be thermally processed, but can be obtained on a spool or other form and can be stretched and applied to the strands in the same manner as thermoplastic polymers. As another alternative, the elastic strands 24 can be made of a thermoset polymer, such as AFFINITY®, available from Dow Chemical Co., that can be processed like a thermoplastic, i.e. stretched and applied, and then treated with radiation, such as electron beam radiation, gamma radiation, or UV radiation to cross-link the polymer, or use polymers that have functionality built into them such that they can be moisture-cured to cross-link the polymer, thus resulting in a polymer and the enhanced mechanical properties of a thermoset.
Endblock portion A may include a poly(vinylarene), such as polystyrene. Midblock portion B may include a substantially amorphous polyolefin such as polyisoprene, ethylene/propylene polymers, ethylene/butylenes polymers, polybutadiene, and the like, or mixtures thereof.
Suitable block copolymers useful in this invention include at least two substantially polystyrene endblock portions and at least one substantially ethylene/butylenes mid-block portion. A commercially available example of such a linear block copolymer is available from Kraton Polymers under the trade designation KRATON® G1657 elastomeric resin. Another suitable elastomer is KRATON® G2760. Yet another suitable elastomer is an SIS triblock copolymer available from Dexco, a division of Exxon-Mobil, under the trade designation VECTOR®.
The elastic reinforcing strands 24 may also contain blends of elastic and inelastic polymers, or of two or more elastic polymers, provided that the blend exhibits elastic properties. The strands 24 are substantially continuous in length. The strands 24 may have a circular cross-section but, as previously mentioned, may alternatively have other cross-sectional geometries such as elliptical, rectangular, triangular or multi-lobal. In one embodiment, one or more of the elastic reinforcing strands 24 may be in the form of elongated, rectangular strips produced from a film extrusion die having a plurality of slotted openings. Suitably, the strands include make up about 5% to about 50%, or about 10% to about 35%, or about 15% to about 25% by weight of the film and the elastic strands combined.
The elastic composite laminate 30 included in the garment 100 of the invention suitably includes the above-described elastic composites 20 sandwiched between a facing sheet 32 and a substrate 34 of the garment 100, as shown in
The substrate 34 is suitably the outer cover 122, the body side liner 124, or any other material of the garment 100 that forms the opening to which the elastomeric composite laminate 30 is attached. The outer cover 122, for example, desirably includes a material that is substantially liquid impermeable, and can be elastic, stretchable or nonstretchable. The outer cover 122 can be a single layer of liquid impermeable material, but desirably includes a multi-layered laminate structure in which at least one of the layers is liquid impermeable. For instance, the outer cover 122 can include a liquid permeable outer layer and a liquid impermeable inner layer that are suitably joined together by a laminate adhesive (not shown). Suitable laminate adhesives, which can be applied continuously or intermittently as beads, a spray, parallel swirls, or the like, can be obtained from Findley Adhesives, Inc., of Wauwatosa, Wis., U.S.A., or from National Starch and Chemical Company, Bridgewater, N.J., U.S.A. The liquid permeable outer layer can be any suitable material and desirably one that provides a generally cloth-like texture. One example of such a material is a 20 gsm (grams per square meter) spunbond polypropylene nonwoven web. The outer layer may also be made of those materials of which the body-side liner 124 is made. While it is not a necessity for the outer layer to be liquid permeable, it is desired that it provides a relatively cloth-like texture to the wearer.
The inner layer of the outer cover 122 can be both liquid and vapor impermeable, or can be liquid impermeable and vapor permeable. The inner layer is desirably manufactured from a thin plastic film, although other flexible liquid impermeable materials may also be used. The inner layer, or the liquid impermeable outer cover 122 when a single layer, prevents waste material from wetting articles, such as bedsheets and clothing, as well as the wearer and care giver. A suitable liquid impermeable film for use as a liquid impermeable inner layer, or a single layer liquid impermeable outer cover 122, is a 0.2 millimeter polyethylene film commercially available from Huntsman Packaging of Newport News, Va., U.S.A. If the outer cover 122 is a single layer of material, it can be embossed and/or matte finished to provide a more cloth-like appearance. The liquid impermeable material can permit vapors to escape from the interior of the garment, while still preventing liquids from passing through the outer cover 122. A suitable “breathable” material is composed of a microporous polymer film or a nonwoven fabric that has been coated or otherwise treated to impart a desired level of liquid impermeability. A suitable microporous film is a PMP-1 film material commercially available from Mitsui Toatsu Chemicals, Inc., Tokyo, Japan, or an XKO-8044 polyolefin film commercially available from 3M Company, Minneapolis, Minn.
The body side liner 124 suitably overlies the outer cover 122 and absorbent assembly, and may but need not have the same dimensions as the outer cover 122. The body side liner 124 is desirably compliant, soft feeling, and non-irritating to the wearer's skin. Further, the body side liner 124 can be less hydrophilic than the absorbent assembly, to present a relatively dry surface to the wearer and permit liquid to readily penetrate through its thickness.
The body side liner 124 can be manufactured from a wide selection of web materials, such as synthetic fibers (for example, polyester or polypropylene fibers), natural fibers (for example, wood or cotton fibers), a combination of natural and synthetic fibers, porous foams, reticulated foams, apertured plastic films, or the like. Various woven and nonwoven fabrics can be used for the body side liner 124. For example, the body side liner can be composed of a meltblown or spunbonded web of polyolefin fibers. The body side liner can also be a bonded-carded web composed of natural and/or synthetic fibers. The body side liner can be composed of a substantially hydrophobic material, and the hydrophobic material can, optionally, be treated with a surfactant or otherwise processed to impart a desired level of wettability and hydrophilicity. For example, the material can be surface treated with about 0.45 weight percent of a surfactant mixture including AHCOVEL® N-62 available from Uniqema Inc., a division of ICI of New Castle, Del., U.S.A. and GLUCOPON® 220UP available from Cognis Corporation of Ambler, Pa., and produced in Cincinnati, Ohio, in an active ratio of 3:1.
A suitable liquid permeable body side liner 124 is a nonwoven bicomponent web having a basis weight of about 27 gsm. The nonwoven bicomponent can be a spunbond bicomponent web, or a bonded carded bicomponent web. Suitable bicomponent staple fibers include a polyethylene/polypropylene bicomponent fiber available from CHISSO Corporation, Osaka, Japan. In this particular bicomponent fiber, the polypropylene forms the core and the polyethylene forms the sheath of the fiber. Other fiber orientations are possible, such as multi-lobe, side-by-side, end-to-end, or the like.
Pant-like garments, such as the training pant shown in
If the facing sheets 32 and/or substrate 34 are to be applied to the composite 20 without first being stretched, the facing sheets and/or substrate may or may not be capable of being stretched in at least one direction in order to produce an elasticized area. For example, the facing sheets and/or substrate could be necked, or gathered, in order to allow them to be stretched after application of the elastic composite. Various post treatments, such as treatment with grooved rolls, which alter the mechanical properties of the material, are also suitable for use.
A second extruder 48 using a slotted film die 50 produces the elastomeric adhesive film 52, which is fed onto a second chill roller 54 and conveyed to one or more second fly rollers 56 towards the nip 44. The film 52 may be stretched down to a narrower width and thinned by the second fly rollers 56 during its passage to the nip 44. The nip 44 is formed by opposing first and second nip rollers 58, 60. The elastic composite 20 is formed by adhering the strands 38 to the elastomeric adhesive film 52 in the nip 44.
In order to form the elastic composite laminate 30, first and second rolls 66 and 68, respectively, of spunbond facing material or other suitable facing material are fed into the nip 44 on either side of the elastic composite and are bonded by the adhesive present in the elastic composite. The facing material might also be made in situ rather than unrolled from previously-made rolls of material. While illustrated as having two lightweight gatherable spunbond facings, it will be appreciated that only one facing material, or various types of facing materials, may be used. Furthermore, one, or both, of the facing materials may be used as a substrate to form the garment of the invention. The elastic composite laminate 30 can be maintained in a stretched condition by a pair of tensioning rollers 70, 72 downstream of the nip 44 and then relaxed as at Ref. No. 74 (FIG. 10).
The resulting elastic composite laminates 30 are particularly useful in providing elasticity in the garment 100 of the invention. More particularly, the elastic composite laminates provide better fit and comfort, as well as less leakage and more tension control compared to conventional elastic strands and elastic strand laminates. Also, by incorporating the strands within the film, the tension load on the resulting laminate is distributed among the entire width of the elastic composite instead of being concentrated on the individual strands. Furthermore, because the strands are incorporated within the film, the elastic composite laminate can be die-cut into virtually any shape to provide enhanced fit and comfort without losing tension.
The laminates used in the garment of this invention are less likely to undergo tension decay or delamination compared to similar laminates lacking the reinforcing strands, as demonstrated in the example below. The tension retaining capability of the laminates insures product performance and reduces or eliminates leakage during use. Furthermore, the reinforcing strands enable the composite tension to be tunable while preserving the soft feel and aesthetic properties of the laminate. Thus, elastic composite laminates can be produced with a desired fit or gasket-like quality in the garment without causing red marks on a wearer's skin due to excessive tension, while preserving the soft and gentle feel and improved adhesion of the laminate.
Adhesive Bond Strength
The adhesive bond strength of the elastomeric adhesive film of the present invention is determined as follows. A test sample of the elastic composite laminate having dimensions of about 2.0 inches (5.08 cm) wide by about 4.0 inches (10.16 cm) long, or as large as possible tip to this size, is used for testing. The adhesive bond strength is determined through the use of a tensile tester, such as a SINTECH tensile tester commercially available from the Sintech Co., Carry, N.C., Model No. II. A 90 degree peel adhesion test is run in order to determine the grams of force needed to pull apart the first and second layers of facing sheet of the laminate. Specifically, 1.25 inches (3.175 cm) or more of the 4-inch length of the test sample has the first and second layers of facing sheet peeled apart. The first facing sheet is then clamped in the upper jaw of the tensile tester, and the second facing sheet is clamped in the lower jaw of the tensile tester.
The tensile tester is set to the following conditions:
The elongation of an elastic composite laminate according to the present invention is suitably determined as follows. A 1-inch wide by 4-inch long sample of the laminate is provided. The central 3-inch (7.62 cm) area of the sample is marked. The test sample is then stretched to its maximum length, and the distance between the marks is measured and recorded as the “stretched to stop length.” The percent elongation is determined according to the following formula:
{(stretched to stop length(in inches))−3}/3×100
If a 1-inch by 4-inch area is not available, the largest sample possible (but less than 1-inch by 4-inches) is used for testing with the method being adjusted accordingly.
Tension Force
The tension force of an elastic composite laminate according to the present invention is determined on a test sample of the laminate having a width of 1 inch (2.54 cm) and a length of 3 inches (7.62 cm). A test apparatus having a fixed clamp and an adjustable clamp is provided. The adjustable clamp is equipped with a strain gauge commercially available from S. A. Mieier Co. under the trade designation Chatillon DFIS2 digital force gauge. The test apparatus can elongate the test sample to a given length. One longitudinal end of the test sample is clamped in the fixed clamp of the test apparatus with the opposite longitudinal end being clamped in the adjustable clamp fitted with the strain gauge. The test sample is elongated to 90 percent of its elongation (as determined by the test method set forth above). The tension force is read from the digital force gauge after 1 minute. At least three samples of the elasticized area are tested in this manner with the results being averaged and reported as grams force per inch width.
In this example, a strand-reinforced laminate material (sample B) was made in accordance with the invention and the tension decay properties were compared to a control (sample A) having the same elastomeric adhesive film composition without the elastic strands. In each case, the film add-on before stretching to 800% was 80 gsm and the elastomeric adhesive film composition was a mixture of 35 wt % PICOLYTE S115 and 65% KRATON G2760, to which 10% Hercules PICOLYTE S25 was added. More particularly, the elastic adhesive film underwent process elongation of between 500% and 800%, resulting in an output basis weight of between 70 and 120 grams per square meter (gsm) before stretching onto a chill roll having a temperature of 10 to 15 degrees Celsius, from a melt tank having a temperature of up to 400 degrees Fahrenheit.
The control spunbond/film/spunbond laminate sample (sample A) was made without any reinforcing strands. The test sample (sample B) was reinforced with VFL extruded strands of tackified SBL styrenic block copolymer available under the trade designation KRATON® G 2760 from Kraton Polymers, adhered to the elastic adhesive film. The test sample was prepared by extruding the strands and the elastomeric adhesive film on separate chill rolls. The die configuration through which the strands were extruded had 12 holes per inch with a 0.030 inch diameter opening. The output of the strands in terms of grams per minute (gpm) was 29.5 gpm for 120 strands per 10-inch die width, extruded on a chill roll at a speed of 6-8 feet per minute. Following the chill rolls, the strands and film were independently stretched to 700%. Thereafter, the film and strands were combined with spunbond webs on each side and laminated continuously to produce a material with tunable elastic properties.
Key process conditions versus physical properties (tension decay and adhesion) are summarized in Table 1. The tension decay was measured by first measuring the “green” tension at 100% elongation of a 2-inch wide, 5-inch long sample containing 24 strands (no strands in the case of the control sample). The tension reading was recorded from an electronic gauge one minute after clamping. After aging the samples at 130 degrees Fahrenheit for 1 day, the “aged” tension was then measured in the, same manner as the green tension and the resulting aged tension was compared to the green tension to determine whether, or to what extent, tension decay occurred. The tension decay value is calculated by the percent difference between green and aged tension readings. A lower value of tension decay is indicative of improved elastic material performance. The tension decay of the strand-reinforced composite is much lower (12.8%) than in the case of no strands (62%). In either case the formulation has excellent adhesion properties with no indications of delamination after continued aging at 130 degrees Fahrenheit for 2 weeks. By exhibiting no delamination, it is meant that the laminates cannot be peeled apart without facing material failure. In this Example, delamination was visually determined as opposed to carrying out a peel test. Visual observations focused on the presence of any air pockets detected between layers of the laminate.
Tension of the elastic composite is tunable by varying the strand add-on and stretch percentage, with greater add-on and greater stretch both resulting in greater tension. Sample observations further reveal that soft feel and aesthetic properties of the laminates are preserved with the addition of the strands.
TABLE 1
Comparison of Tension Decay and Adhesion Properties
of Novel Elastic Composite Laminates
Green
tension
Aged
Output of
Strand
(grams),
tension
Ten-
extruded
process
2-inch
(grams)
sion
strands
stretch
wide
1 day at
decay
Aged sample
Sample
(gpm)
(%)
sample
130° F.
(%)
observations
A
None
—
340
130
62.0
No
(control)
delamination
B
29.5
700
350
305
12.8
No
(stranded
delamination
com-
posite)
In this example, the strand-reinforced laminate material (sample B) of Example 1 was incorporated into the leg cuff portion of a personal care garment, as indicated by the reference number 30 in FIG. 1. The “in-product” tension properties were evaluated and compared to conventional spunbonded laminates (SBL) and Lycra laminates (including Lycra strands adhered with elastic attachment adhesive). The “in-product” tension values of the elasticized laminate composite portion of the personal care garment are shown in Table 2 and were measured as follows.
The garment was extended flat on a lightbox and clamped at one end while a 1000 gram weight in the form of a bar was attached at the other end, resulting in stretching of the material in the machine direction. Two marks corresponding to a discrete gauge length value in the range of 4-7 inches were placed on the stretched elastic portion. The weight was removed and the retracted elastic laminate composite was cut out from the product, normally as a 1-inch wide strip. The cut elastic strip was mounted in a Chantillon tension gauge and stretched to 90% of gauge length. The tension in grams was recorded after a one-minute waiting period. The elasticized strips were evaluated for tension before and after the product was worn at body temperature in order to evaluate the degree of tension decay as a result of wearing the article. A lower degree of tension decay (as measured by the percentage difference between post-wear and pre-wear) is indicative of a better performing elastic material. Tension measurements before and after wear show a significant drop for conventional SBL laminate control (−22%). The tension drop for the other control of conventional Lycra laminate was significant as well (−10%). However, the laminate made from the strand-reinforced elastomeric adhesive film of the invention had no tension loss and actually gained some tension as a result of wearing at body temperature. The elastic adhesive laminate of the invention with no tension loss provides superior gasketing performance compared to conventional materials.
TABLE 2
Comparative Tension of Laminates
Tension (grams),
Tension (grams),
Material
before wear
after wear
% difference
SBL laminate
127.5
104.5
−22.0
Lycra laminate
120.8
109.4
−10.0
Strand-reinforced
141.5
144.6
+2.1
laminate
It will be appreciated that details of the foregoing embodiments, given for purposes of illustration, are not to be construed as limiting the scope of this invention. Although only a few exemplary embodiments of this invention have been described in detail above, those skilled in the art will readily appreciate that many modifications are possible in the exemplary embodiments without materially departing from the novel teachings and advantages of this invention. Accordingly, all such modifications are intended to be included within the scope of this invention, which is defined in the following claims and all equivalents thereto. Further, it is recognized that many embodiments may be conceived that do not achieve all of the advantages of some embodiments, particularly of the preferred embodiments, yet the absence of a particular advantage shall not be construed to necessarily mean that such an embodiment is outside the scope of the present invention.
Zhou, Peiguang, Neculescu, Cristian M., Garrett, Jr., Lance J.
Patent | Priority | Assignee | Title |
10058460, | Jun 21 2011 | The Procter & Gamble Company | Absorbent article with waistband having contraction |
10167156, | Jul 24 2015 | CURT G JOA, INC | Vacuum commutation apparatus and methods |
10206825, | Apr 29 2011 | The Procter & Gamble Company | Absorbent article with leg gasketing cuff |
10266362, | Feb 21 2007 | Curt G. Joa, Inc. | Single transfer insert placement method and apparatus |
10456302, | May 18 2006 | CURT G JOA, INC | Methods and apparatus for application of nested zero waste ear to traveling web |
10485710, | Mar 18 2015 | The Procter & Gamble Company | Absorbent article with leg cuffs |
10494216, | Jul 24 2015 | Curt G. Joa, Inc. | Vacuum communication apparatus and methods |
10524962, | Mar 18 2015 | THE PROCTER & GAMBLE OMPANY | Absorbent article with waist gasketing element and leg cuffs |
10524963, | Mar 18 2015 | The Procter & Gamble Company | Absorbent article with waist gasketing element and leg cuffs |
10531990, | Mar 18 2015 | The Procter & Gamble Company | Absorbent article with leg cuffs |
10531991, | Mar 18 2015 | The Procter & Gamble Company | Absorbent article with waist gasketing element and leg cuffs |
10537481, | Mar 18 2015 | Procter & Gamble Company | Absorbent article with waist gasketing element and leg cuffs |
10543130, | Mar 18 2015 | The Procter & Gamble Company | Absorbent article with leg cuffs |
10543131, | Mar 18 2015 | The Procter & Gamble Company | Absorbent article with leg cuffs |
10583049, | Mar 18 2015 | The Procter & Gamble Company | Absorbent article with waist gasketing element and leg cuffs |
10588789, | Mar 18 2015 | The Procter & Gamble Company | Absorbent article with leg cuffs |
10588790, | Mar 18 2015 | The Procter & Gamble Company | Absorbent article with leg cuffs |
10588791, | Mar 18 2015 | The Procter & Gamble Company | Absorbent article with waist gasketing element and leg cuffs |
10603226, | Mar 18 2015 | The Procter & Gamble Company | Absorbent article with leg cuffs |
10633207, | Jul 24 2015 | Curt G. Joa, Inc. | Vacuum commutation apparatus and methods |
10675190, | Mar 22 2013 | The Procter and Gamble Company | Disposable absorbent articles |
10702428, | Apr 06 2009 | Curt G. Joa, Inc. | Methods and apparatus for application of nested zero waste ear to traveling web |
10716716, | Mar 18 2015 | The Procter & Gamble Company | Absorbent article with leg cuffs |
10751220, | Feb 20 2012 | CURT G JOA, INC | Method of forming bonds between discrete components of disposable articles |
10792198, | Mar 18 2015 | The Procter & Gamble Company | Absorbent article with leg cuffs |
10806638, | Jun 21 2011 | The Procter & Gamble Company | Absorbent article with a waistband and leg cuff having gathers |
10918534, | Apr 29 2011 | The Procter & Gamble Company | Absorbent article with leg gasketing cuff |
11013642, | May 15 2012 | The Procter & Gamble Company | Disposable absorbent pants with advantageous stretch and manufacturability features, and methods for manufacturing the same |
11034543, | Apr 24 2012 | CURT G JOA, INC | Apparatus and method for applying parallel flared elastics to disposable products and disposable products containing parallel flared elastics |
11458045, | Mar 18 2015 | The Procter & Gamble Company | Absorbent article with leg cuffs |
11478385, | Mar 18 2015 | The Procter & Gamble Company | Absorbent article with waist gasketing element and leg cuffs |
11504282, | Mar 18 2015 | The Procter & Gamble Company | Absorbent article with leg cuffs |
11504283, | Mar 18 2015 | The Procter & Gamble Company | Absorbent article with waist gasketing element and leg cuffs |
11571343, | Apr 29 2011 | The Procter & Gamble Company | Absorbent article with leg gasketing cuff |
11737930, | Feb 27 2020 | Curt G. Joa, Inc. | Configurable single transfer insert placement method and apparatus |
11752044, | Mar 18 2015 | The Procter & Gamble Company | Absorbent article with leg cuffs |
11833012, | Mar 18 2015 | The Procter & Gamble Company | Absorbent article with waist gasketing element and leg cuffs |
11844669, | Mar 18 2015 | The Procter & Gamble Company | Absorbent article with waist gasketing element and leg cuffs |
7316840, | Jul 02 2002 | Kimberly-Clark Worldwide, Inc | Strand-reinforced composite material |
7452436, | Mar 09 2005 | CURT G JOA, INC | Transverse tape application method and apparatus |
7533709, | May 31 2005 | CURT G JOA, INC | High speed vacuum porting |
7537215, | Jun 15 2004 | CURT G JOA, INC | Method and apparatus for securing stretchable film using vacuum |
7618513, | May 31 2005 | CURT G JOA, INC | Web stabilization on a slip and cut applicator |
7638014, | May 21 2004 | CURT G JOA, INC | Method of producing a pants-type diaper |
7640962, | Apr 20 2004 | CURT G JOA, INC | Multiple tape application method and apparatus |
7703599, | Apr 19 2004 | CURT G JOA, INC | Method and apparatus for reversing direction of an article |
7708849, | Apr 20 2004 | CURT C JOA, INC | Apparatus and method for cutting elastic strands between layers of carrier webs |
7717893, | Jun 04 2004 | The Procter & Gamble Company | Absorbent articles comprising a slow recovery elastomer |
7770712, | Feb 17 2006 | CURT G JOA, INC | Article transfer and placement apparatus with active puck |
7780052, | May 18 2006 | CURT G JOA, INC | Trim removal system |
7811403, | Mar 09 2005 | CURT G JOA, INC | Transverse tab application method and apparatus |
7861756, | Apr 20 2004 | Curt G. Joa, Inc. | Staggered cutting knife |
7905872, | Jun 04 2004 | The Procter & Gamble Company; Procter & Gamble Company, The | Absorbent articles comprising a slow recovery stretch laminate |
7909956, | May 21 2004 | Curt G. Joa, Inc. | Method of producing a pants-type diaper |
7975584, | Feb 21 2007 | CURT G JOA, INC | Single transfer insert placement method and apparatus |
8016972, | May 09 2007 | CURT G JOA, INC | Methods and apparatus for application of nested zero waste ear to traveling web |
8029488, | Jan 26 2005 | The Procter & Gamble Company | Disposable pull-on diaper having a low force, slow recovery elastic waist |
8172977, | Apr 06 2009 | CURT G JOA, INC | Methods and apparatus for application of nested zero waste ear to traveling web |
8182624, | Mar 12 2008 | CURT G JOA, INC | Registered stretch laminate and methods for forming a registered stretch laminate |
8226625, | Apr 08 2009 | Procter & Gamble Company, The | Stretchable laminates of nonwoven web(s) and elastic film |
8226626, | Apr 08 2009 | Procter & Gamble Company, The | Stretchable laminates of nonwoven web(s) and elastic film |
8231595, | Apr 08 2009 | Procter & Gamble Company, The | Stretchable laminates of nonwoven web(s) and elastic film |
8293056, | May 18 2006 | Curt G. Joa, Inc. | Trim removal system |
8323257, | Nov 21 2007 | The Procter & Gamble Company | Absorbent articles comprising a slow recovery stretch laminate and method for making the same |
8388594, | Apr 08 2009 | Procter & Gamble Company, The | Stretchable laminates of nonwoven web(s) and elastic film |
8398793, | Jul 20 2007 | CURT G JOA, INC | Apparatus and method for minimizing waste and improving quality and production in web processing operations |
8417374, | Apr 19 2004 | CURT G JOA, INC | Method and apparatus for changing speed or direction of an article |
8419701, | Jan 10 2005 | The Procter & Gamble Company | Absorbent articles with stretch zones comprising slow recovery elastic materials |
8460495, | Dec 30 2009 | CURT G JOA, INC | Method for producing absorbent article with stretch film side panel and application of intermittent discrete components of an absorbent article |
8506544, | Jun 21 2010 | Procter & Gamble Company, The | Disposable absorbent pant with efficient design and convenient single-section side stretch panels |
8557077, | May 21 2004 | Curt G. Joa, Inc. | Method of producing a pants-type diaper |
8656817, | Mar 09 2011 | CURT G JOA, INC | Multi-profile die cutting assembly |
8663411, | Jun 07 2010 | CURT G JOA, INC | Apparatus and method for forming a pant-type diaper with refastenable side seams |
8673098, | Oct 28 2009 | CURT G JOA, INC | Method and apparatus for stretching segmented stretchable film and application of the segmented film to a moving web |
8709191, | May 15 2008 | Kimberly-Clark Worldwide, Inc | Latent elastic composite formed from a multi-layered film |
8794115, | Feb 21 2007 | Curt G. Joa, Inc. | Single transfer insert placement method and apparatus |
8820380, | Jul 21 2011 | CURT G JOA, INC | Differential speed shafted machines and uses therefor, including discontinuous and continuous side by side bonding |
8939957, | Apr 29 2011 | Procter & Gamble Company, The | Absorbent article with leg gasketing cuff |
9017305, | Nov 12 2010 | Procter & Gamble Company, The | Elastomeric compositions that resist force loss and disintegration |
9089453, | Dec 30 2009 | CURT G JOA, INC | Method for producing absorbent article with stretch film side panel and application of intermittent discrete components of an absorbent article |
9089455, | Apr 29 2011 | The Procter & Gamble Company | Absorbent article with leg gasketing cuff |
9283683, | Jul 24 2013 | CURT G JOA, INC | Ventilated vacuum commutation structures |
9289329, | Dec 05 2013 | CURT G JOA, INC | Method for producing pant type diapers |
9327477, | Jan 24 2008 | U S BANK NATIONAL ASSOCIATION, AS COLLATERAL AGENT | Elastomeric materials |
9358161, | Jun 21 2011 | The Procter & Gamble Company | Absorbent article with waistband having contraction |
9387131, | Jul 20 2007 | CURT G JOA, INC | Apparatus and method for minimizing waste and improving quality and production in web processing operations by automated threading and re-threading of web materials |
9433538, | May 18 2006 | CURT G JOA, INC | Methods and apparatus for application of nested zero waste ear to traveling web and formation of articles using a dual cut slip unit |
9498392, | Apr 29 2011 | The Proctor and Gamble Company | Absorbent article with leg gasketing cuff |
9550306, | Feb 21 2007 | CURT G JOA, INC | Single transfer insert placement and apparatus with cross-direction insert placement control |
9566193, | Feb 25 2011 | CURT G JOA, INC | Methods and apparatus for forming disposable products at high speeds with small machine footprint |
9566195, | Jun 21 2011 | The Procter & Gamble Company | Absorbent article with waistband having contraction |
9603752, | Aug 05 2010 | CURT G JOA, INC | Apparatus and method for minimizing waste and improving quality and production in web processing operations by automatic cuff defect correction |
9610203, | Mar 22 2013 | The Procter & Gamble Company | Disposable absorbent articles |
9622918, | Apr 06 2009 | CURT G JOA, INC | Methods and apparatus for application of nested zero waste ear to traveling web |
9669606, | Jan 24 2008 | U S BANK NATIONAL ASSOCIATION, AS COLLATERAL AGENT | Elastomeric materials |
9724248, | May 15 2008 | Kimberly-Clark Worldwide, Inc | Latent elastic composite formed from a multi-layered film |
9737444, | Jun 21 2011 | The Procter & Gamble Company | Absorbent article with a waistband and leg cuffs having gathers |
9809414, | Apr 24 2012 | CURT G JOA, INC | Elastic break brake apparatus and method for minimizing broken elastic rethreading |
9907706, | Feb 25 2011 | Curt G. Joa, Inc. | Methods and apparatus for forming disposable products at high speeds with small machine footprint |
9908739, | Apr 24 2012 | CURT G JOA, INC | Apparatus and method for applying parallel flared elastics to disposable products and disposable products containing parallel flared elastics |
9944487, | Feb 21 2007 | CURT G JOA, INC | Single transfer insert placement method and apparatus |
9950439, | Feb 21 2007 | Curt G. Joa, Inc. | Single transfer insert placement method and apparatus with cross-direction insert placement control |
D684613, | Apr 14 2011 | CURT G JOA, INC | Sliding guard structure |
D703247, | Aug 23 2013 | CURT G JOA, INC | Ventilated vacuum commutation structure |
D703248, | Aug 23 2013 | CURT G JOA, INC | Ventilated vacuum commutation structure |
D703711, | Aug 23 2013 | CURT G JOA, INC | Ventilated vacuum communication structure |
D703712, | Aug 23 2013 | CURT G JOA, INC | Ventilated vacuum commutation structure |
D704237, | Aug 23 2013 | CURT G JOA, INC | Ventilated vacuum commutation structure |
RE48182, | Aug 02 2011 | Curt G. Joa, Inc. | Apparatus and method for minimizing waste and improving quality and production in web processing operations by automatic cuff defect correction |
Patent | Priority | Assignee | Title |
2206761, | |||
2266761, | |||
2357392, | |||
2464301, | |||
2483405, | |||
2957512, | |||
2957852, | |||
3186893, | |||
3338992, | |||
3341394, | |||
3371668, | |||
3391048, | |||
3439085, | |||
3449187, | |||
3468748, | |||
3489148, | |||
3502538, | |||
3502763, | |||
3542615, | |||
3575782, | |||
3616129, | |||
3629047, | |||
3669823, | |||
3673026, | |||
3676242, | |||
3689342, | |||
3692618, | |||
3752613, | |||
3773590, | |||
3802817, | |||
3806289, | |||
3836416, | |||
3838692, | |||
3849241, | |||
3855046, | |||
3857144, | |||
3860003, | |||
3890184, | |||
3904465, | |||
3912567, | |||
3917448, | |||
3932328, | Nov 02 1971 | AVERY INTERNATIONAL CORPORATION, A DE CORP | Hot melt adhesive composition and tape |
3949128, | Aug 22 1972 | Kimberly-Clark Corporation | Product and process for producing a stretchable nonwoven material from a spot bonded continuous filament web |
3949130, | Jan 04 1974 | TUFF SPUN PRODUCTS, INC | Spun bonded fabric, and articles made therefrom |
3973063, | Nov 21 1974 | Mobil Oil Corporation | Spot blocked thermoplastic film laminate |
3978185, | Dec 23 1968 | Exxon Research and Engineering Company | Melt blowing process |
3979050, | Sep 21 1973 | VISKASE CORPORATION, A CORP OF PA | Multi-ply film articles |
4013816, | Nov 20 1975 | Draper Products, Inc. | Stretchable spun-bonded polyolefin web |
4028292, | May 23 1974 | PERMACEL, ROUTE #1, NORTH BRUNSWICK, NEW JERSEY 08902, A NEW JERSEY CORP ; PERMACEL, A NJ CORP | Hot melt adhesive |
4038346, | Mar 31 1975 | The Goodyear Tire & Rubber Company | Tackifier composition and rubber mixture |
4041203, | Sep 06 1972 | Kimberly-Clark Corporation | Nonwoven thermoplastic fabric |
4080348, | May 18 1976 | Johnson & Johnson | Tacky adhesive |
4090385, | Jan 26 1977 | MICREX CORPORATION, A CORP OF MA; MICREX CORPORATION, WALPOLE, MA A CORP OF MA | Material treating apparatus |
4100324, | Mar 26 1974 | Kimberly-Clark Corporation | Nonwoven fabric and method of producing same |
4107364, | Jun 06 1975 | The Procter & Gamble Company | Random laid bonded continuous filament cloth |
4135037, | Jun 15 1977 | Phillips Petroleum Company | Adhesives and laminates |
4148676, | Nov 12 1969 | Bjorksten Research Laboratories, Inc. | Non-woven articles made from continuous filaments coated in high density fog with high turbulence |
4209563, | Jun 06 1975 | The Procter & Gamble Company | Method for making random laid bonded continuous filament cloth |
4211807, | Aug 08 1975 | Polymer Processing Research Institute Ltd.; Sekisui Kagaku Kogyo Kabushiki Kaisha | Reinforced non-woven fabrics and method of making same |
4239578, | Oct 16 1979 | PARAGON TRADE BRANDS, INC | Apparatus for inserting elastic strips during the manufacture of elastic leg disposable diapers |
4241123, | Nov 14 1978 | Non-woven netting | |
4248652, | Mar 30 1978 | INOMONT CORPORATION | Method of making leatherlike materials (A) |
4259220, | Dec 06 1978 | H B FULLER LICENSING & FINANCING, INC A CORPORATION OF DE | Hot melt adhesive for elastic banding |
4285998, | Jul 26 1976 | LEUCADIA, INC , A CORP OF NY ; LEUCADIA, INC , A CORP OF NEW YORK | Reinforced thermoplastic film sheet |
4300562, | Feb 11 1980 | JOHNSON & JOHNSON CONSUMER PRODUCTS, INC , A NJ CORP | Laminated structures having gathered marginal portions |
4302495, | Aug 14 1980 | PROVIDENT NATIONAL BANK, A CORP OF DE | Nonwoven fabric of netting and thermoplastic polymeric microfibers |
4303571, | Jan 17 1980 | ADVANCED ELASTOMER SYSTEMS, L P AES | Film-forming thermoplastic elastomeric polymer compositions |
4304234, | Jun 19 1979 | CARL FREUDENBERG,A BUSINESS ORGANIZATION OF GERMANY | Non-woven fabrics of polyolefin filament and processes of production thereof |
4310594, | Jul 01 1980 | Teijin Limited | Composite sheet structure |
4319572, | Jul 02 1979 | Molnlycke AB | Disposable diaper |
4323534, | Dec 17 1979 | The Procter & Gamble Company | Extrusion process for thermoplastic resin composition for fabric fibers with exceptional strength and good elasticity |
4333782, | Feb 11 1980 | JOHNSON & JOHNSON CONSUMER PRODUCTS, INC , A NJ CORP | Method of making laminated structures having gathered and ungathered marginal portions |
4340558, | May 05 1976 | Colgate-Palmolive Company | Scrim reinforced plastic film |
4340563, | May 05 1980 | Kimberly-Clark Worldwide, Inc | Method for forming nonwoven webs |
4374888, | Sep 25 1981 | Kimberly-Clark Worldwide, Inc | Nonwoven laminate for recreation fabric |
4375446, | May 01 1978 | TOA NENRYO KOGYO K K A CORP OF JAPAN | Process for the production of a nonwoven fabric |
4402688, | Oct 27 1981 | Colgate-Palmolive | Disposable diaper with contoured elastic |
4405397, | Oct 16 1979 | PARAGON TRADE BRANDS, INC | Process for manufacturing elastic leg disposable diapers |
4413623, | Feb 17 1981 | JOHNSON & JOHNSON CONSUMER PRODUCTS, INC , A NJ CORP | Laminated structures having gathered and ungathered marginal portions and method of manufacturing the same |
4417935, | Oct 13 1981 | Paper Converting Machine Company | Method of diaper manufacture |
4418123, | Sep 22 1978 | H B FULLER LICENSING & FINANCING, INC A CORPORATION OF DE | Extrudable self-adhering elastic and method of employing same |
4438167, | Oct 15 1979 | Biax Fiberfilm Corporation | Novel porous fabric |
4440819, | Dec 27 1982 | Hughes Aircraft Company | Interconnection of unidirectional fiber arrays with random fiber networks |
4490427, | Jun 14 1982 | Firma Carl Freudenberg | Adhesive webs and their production |
4496417, | Nov 12 1982 | Graphic Packaging Corporation | Control stretch laminating device |
4507163, | Aug 27 1981 | JOHNSON & JOHNSON CONSUMER PRODUCTS, INC , A NJ CORP | Imparting an inelastic and elastic character to predetermined portions of an elastic web for use in making disposable diapers |
4522863, | Jun 21 1984 | Kimberly-Clark Worldwide, Inc | Soft nonwoven laminate bonded by adhesive on reinforcing scrim |
4525407, | Aug 27 1982 | CHASE MANHATTAN BANK, THE, THE | Elastic composites |
4543099, | Mar 26 1981 | H B FULLER LICENSING & FINANCING, INC A CORPORATION OF DE | Method for imparting elastic properties to a flexible substrate |
4548859, | Oct 12 1984 | The Boeing Company; Boeing Company, the | Breather material and method of coating fabric with silicone rubber |
4552795, | Dec 27 1983 | Minnesota Mining and Manufacturing Co. | Inelastic, heat-elasticizable sheet material |
4555811, | Jun 13 1984 | CHASE MANHATTAN BANK, THE, THE | Extensible microfine fiber laminate |
4572752, | Nov 12 1982 | Graphic Packaging International, Inc | Control stretch laminating device |
4586199, | Dec 21 1982 | Molnlycke AB | Elastic pants |
4606964, | Nov 22 1985 | Kimberly-Clark Worldwide, Inc | Bulked web composite and method of making the same |
4618384, | Sep 09 1983 | Method for applying an elastic band to diapers | |
4626305, | Apr 14 1982 | PARAGON TRADE BRANDS,INC | Disposable diaper and method for incorporation of elastic member into such diaper |
4636419, | Aug 13 1973 | KAYSERSBERG PACKAGING, S A | Net and method of producing same |
4640859, | Dec 27 1983 | Minnesota Mining and Manufacturing Company | Inelastic, heat-elasticizable sheet material for diapers |
4644045, | Mar 14 1986 | FIBERWEB NORTH AMERICA, INC , 545 NORTH PLEASANTBURG DRIVE, GREENVILLE, SC 29607, A CORP OF DE | Method of making spunbonded webs from linear low density polyethylene |
4652487, | Jul 30 1985 | Kimberly-Clark Worldwide, Inc | Gathered fibrous nonwoven elastic web |
4656081, | Apr 25 1983 | Toray Industries, Inc. | Smooth nonwoven sheet |
4657793, | Jul 16 1984 | Ethicon, Inc | Fibrous structures |
4657802, | Jul 30 1985 | Kimberly-Clark Worldwide, Inc | Composite nonwoven elastic web |
4661389, | Mar 27 1984 | LEUCADIA, INC , A CORP OF NY ; LEUCADIA, INC , A CORP OF NEW YORK | Multiple-layer reinforced laminate |
4663220, | Jul 30 1985 | Kimberly-Clark Worldwide, Inc | Polyolefin-containing extrudable compositions and methods for their formation into elastomeric products including microfibers |
4666543, | Aug 06 1982 | Kasasumi Laboratories, Inc. | Hollow fiber device for removing waste material in the blood and a process of manufacture thereof |
4675068, | Nov 28 1984 | FIBRE CONVERTING MACHINERY AB | Arrangement for bonding an elastic ribbon to a plastics web with the aid of an adhesive |
4683877, | Oct 04 1985 | Minnesota Mining and Manufacturing Company | Orthopedic casting article and method |
4687477, | Apr 14 1982 | PARAGON TRADE BRANDS,INC | Disposable diaper and method for incorporation of elastic member into such diaper |
4692368, | Oct 15 1986 | Kimberly-Clark Worldwide, Inc | Elastic spunlaced polyester-meltblown polyetherurethane laminate |
4692371, | Jul 30 1985 | Kimberly-Clark Worldwide, Inc | High temperature method of making elastomeric materials and materials obtained thereby |
4698242, | Aug 12 1985 | National Starch and Chemical Corporation | Thermoplastic elastic adhesive containing polyether block amides |
4704116, | Jul 02 1984 | Kimberly-Clark Worldwide, Inc | Diapers with elasticized side pockets |
4718901, | Oct 24 1984 | NORDSAN HYGIEN AB, A CORP OF SWEDEN | Incontinence diaper |
4719261, | Sep 22 1978 | H B FULLER LICENSING & FINANCING, INC A CORPORATION OF DE | Hot melt adhesive for elastic banding and method for utlizing the same |
4720415, | Jul 30 1985 | Kimberly-Clark Worldwide, Inc | Composite elastomeric material and process for making the same |
4725468, | Feb 06 1986 | MAY COATING TECHNOLOGIES, INC | Method of co-extrusion of different coating materials, including adhesive coating with intermittent non-adhering sections, and products produced thereby |
4726874, | Mar 31 1987 | PARAGON TRADE BRANDS,INC | Waist elastic applicator for diaper or similar article |
4734311, | Jan 16 1985 | Kimberly-Clark Worldwide, Inc | Elasticized non-woven fabric and method of making the same |
4734320, | Apr 24 1986 | Nitto Electric Industrial Co., Ltd. | Stretchable cloth adhesive tape |
4734447, | Sep 24 1985 | Sunstar Giken Kabushiki Kaisha | Hot-melt adhesive |
4735673, | Feb 19 1987 | COLGATE-PALMOLIVE COMPANY, A CORP OF DE | Machine for fastening stretched pieces of elastic band traversely to a continuously moving sheet |
4756942, | Sep 18 1986 | Vitapharm Basel AG | Elastic fabric |
4761198, | Aug 12 1985 | National Starch and Chemical Corporation | Use of a thermoplastic elastic adhesive for elastic banding |
4762582, | Mar 25 1983 | P E A U D O U C E, A FRENCH SOCIETE ANONYME | Continuous process for the manufacture of disposable diapers |
4775579, | Nov 05 1987 | FIBERWEB NORTH AMERICA, INC , | Hydroentangled elastic and nonelastic filaments |
4777080, | Oct 15 1986 | Kimberly-Clark Worldwide, Inc | Elastic abrasion resistant laminate |
4781966, | Oct 15 1986 | UNIVERSITY OF TENNESSEE RESEARCH CORPORATION, THE | Spunlaced polyester-meltblown polyetherester laminate |
4787699, | Sep 01 1987 | HE HOLDINGS, INC , A DELAWARE CORP ; Raytheon Company | Fiber optic terminus |
4789699, | Oct 15 1986 | Kimberly-Clark Worldwide, Inc | Ambient temperature bondable elastomeric nonwoven web |
4795668, | Oct 11 1983 | Minnesota Mining and Manufacturing Company | Bicomponent fibers and webs made therefrom |
4798603, | Oct 16 1987 | Kimberly-Clark Worldwide, Inc | Absorbent article having a hydrophobic transport layer |
4801345, | Sep 15 1980 | PEAUDOUCE SOCIETE ANONYME | Process for manufacturing disposable diapers and diaper briefs, and disposable diapers and diaper briefs obtained by application of this process |
4801482, | Oct 15 1986 | Kimberly-Clark Worldwide, Inc | Elastic nonwoven pad |
4803117, | Mar 24 1986 | Kimberly-Clark Worldwide, Inc | Coformed ethylene-vinyl copolymer elastomeric fibrous webs |
4804577, | Jan 27 1987 | Exxon Chemical Patents Inc. | Melt blown nonwoven web from fiber comprising an elastomer |
4818464, | Aug 30 1984 | Kimberly-Clark Worldwide, Inc | Extrusion process using a central air jet |
4818597, | Jan 27 1988 | Kimberly-Clark Worldwide, Inc | Health care laminate |
4826415, | Oct 21 1986 | Mitsui Chemicals, Inc | Melt blow die |
4842666, | Mar 07 1987 | H B FULLER LICENSING & FINANCING, INC A CORPORATION OF DE | Process for the permanent joining of stretchable threadlike or small ribbonlike elastic elements to a flat substrate, as well as use thereof for producing frilled sections of film or foil strip |
4854985, | Nov 24 1986 | PARAGON TRADE BRANDS,INC | Method for manufacture of an elastic leg diaper |
4854989, | Oct 24 1984 | NORDSAN HYGIEN AB | Method of afixing elastic bands in an incontinence diaper |
4863779, | Mar 24 1986 | Kimberly-Clark Worldwide, Inc | Composite elastomeric material |
4867735, | Oct 01 1987 | First Brands Corporation | Method and apparatus for continuous production of bags from thermoplastic film |
4874447, | Jan 27 1987 | TENNESSEE RESEARCH CORPORATION, THE UNIVERSITY OF | Melt blown nonwoven web from fiber comprising an elastomer |
4879170, | Mar 18 1988 | Kimberly-Clark Worldwide, Inc | Nonwoven fibrous hydraulically entangled elastic coform material and method of formation thereof |
4883482, | Dec 11 1984 | COLGATE-PALMOLIVE COMPANY, A CORP OF DE | Napkin-knickers provided with an improved elastic arrangement |
4883549, | Dec 06 1988 | Kimberly-Clark Worldwide, Inc | Method of attaching a composite elastic material to an article |
4891258, | Dec 22 1987 | Kimberly-Clark Worldwide, Inc | Stretchable absorbent composite |
4892536, | Sep 02 1988 | The Procter & Gamble Company; Procter & Gamble Company, The | Absorbent article having elastic strands |
4892903, | Jul 07 1986 | SHELL ELASTOMERS LLC | Elastomeric fibers, structures fashioned therefrom and elastomeric films |
4900619, | Oct 17 1988 | BBA NONWOVENS SIMPSONVILLE, INC | Translucent housewrap |
4906507, | Mar 13 1987 | Freudenberg Nonwovens Limited Partnership | Composite adhesive webs and their production |
4908247, | Apr 15 1986 | PROCTER & GAMBLE COMPANY, THE, | Article including segment which is elastically shirrable after manufacture |
4908253, | Dec 11 1974 | High strength laminate with barrier layer | |
4910064, | May 25 1988 | TUFF SPUN FABRICS, INC | Stabilized continuous filament web |
4917696, | Jan 19 1983 | PEAUDOUCE, A FRENCH SOCIETY ANONYME | Disposable diaper pantie |
4917746, | Jun 21 1982 | Kimberly-Clark Worldwide, Inc | Apparatus and method for contouring elastic ribbon on disposable garments |
4929492, | Jul 24 1987 | Minnesota Mining and Manufacturing Company | Stretchable insulating fabric |
4935021, | Oct 27 1988 | Paragon Trade Brands, LLC | Disposal diaper with center gathers |
4938821, | Apr 10 1986 | PARAGON TRADE BRANDS,INC | Method and apparatus for manufacture of a diaper with elastic margins |
4939016, | Mar 18 1988 | Kimberly-Clark Worldwide, Inc | Hydraulically entangled nonwoven elastomeric web and method of forming the same |
4940464, | Dec 16 1987 | Kimberly-Clark Worldwide, Inc | Disposable incontinence garment or training pant |
4949668, | Jun 16 1988 | Kimberly-Clark Worldwide, Inc | Apparatus for sprayed adhesive diaper construction |
4965122, | Sep 23 1988 | Kimberly-Clark Worldwide, Inc | Reversibly necked material |
4968313, | Apr 27 1987 | Procter & Gamble Company, The | Diaper with waist band elastic |
4970259, | Aug 16 1989 | SHELL ELASTOMERS LLC | Elastomeric film composition |
4977011, | Sep 19 1988 | Paragon Trade Brands, LLC | Disposable elastic structure |
4981747, | Sep 23 1988 | Kimberly-Clark Worldwide, Inc | Composite elastic material including a reversibly necked material |
4984584, | Jan 16 1987 | Riker Laboratories, Inc. | High elastic modulus bandage |
4994508, | Jul 16 1987 | Asahi Kasei Kogyo Kabushiki Kaisha | Specific hydrogenated block copolymer composition and process for producing the same |
4995928, | Oct 31 1988 | Method and apparatus for forming and transporting elastic ribbons | |
4998929, | Jul 17 1986 | Molnlycke AB | Disposable diaper |
5000806, | Apr 19 1988 | Paper Converting Machine Company | Method and apparatus for applying an elastic strand to a disposable diaper |
5002815, | Feb 02 1988 | Chisso Corporation | Bulky and reinforced non-woven fabric |
5005215, | Nov 09 1989 | Protective article of clothing | |
5013785, | Oct 08 1986 | Mitsui Chemicals, Inc | Pressure-sensitive adhesive composition comprising poly-4-methyl-1-pentene as tackifier |
5028646, | Aug 04 1988 | Minnesota Mining and Manufacturing Company | Pressure-sensitive adhesive composition, tape and diaper closure system |
5032120, | Mar 09 1989 | The Procter & Gamble Company | Disposable absorbent article having improved leg cuffs |
5034008, | Nov 07 1989 | Chicopee | Elasticized absorbent article |
5045133, | Jan 27 1988 | Kimberly-Clark Worldwide, Inc | Health care laminate |
5057368, | Dec 21 1989 | Allied-Signal | Filaments having trilobal or quadrilobal cross-sections |
5060349, | Apr 02 1987 | WALTON, RICHARD C | Compressive treatment of webs |
5069970, | Jan 23 1989 | Allied-Signal Inc. | Fibers and filters containing said fibers |
5073436, | Sep 25 1989 | Propex Operating Company, LLC | Multi-layer composite nonwoven fabrics |
5093422, | Apr 23 1990 | SHELL ELASTOMERS LLC | Low stress relaxation extrudable elastomeric composition |
5096532, | Nov 17 1987 | Kimberly-Clark Worldwide, Inc | Ultrasonic rotary horn |
5100435, | Dec 04 1990 | Kimberly-Clark Worldwide, Inc | Meltblown nonwoven webs made from epoxy/pcl blends |
5108820, | Apr 25 1989 | Mitsui Chemicals, Inc | Soft nonwoven fabric of filaments |
5110403, | May 18 1990 | Kimberly-Clark Worldwide, Inc | High efficiency ultrasonic rotary horn |
5112889, | Aug 31 1987 | Minnesota Mining and Manufacturing Company | Pressure-sensitive adhesive composition, tape and diaper closure system |
5114087, | Sep 21 1990 | SHIMABUN CO , LTD | Fiber combiner for aligning filaments in a planar filament array |
5116662, | Dec 15 1989 | Kimberly-Clark Worldwide, Inc | Multi-direction stretch composite elastic material |
5145727, | Nov 26 1990 | Kimberly-Clark Worldwide, Inc | Multilayer nonwoven composite structure |
5147487, | Jun 29 1989 | Uni-Charm Corporation | Method of manufacturing disposable underpants by applying annular adhesive zones to the backsheet and top sheet for retaining elastic for leg holes |
5149741, | Jul 21 1989 | Findley Adhesives, Inc. | Hot melt construction adhesives for disposable soft goods |
5169706, | Jan 10 1990 | Kimberly-Clark Worldwide, Inc | Low stress relaxation composite elastic material |
5169712, | Aug 23 1991 | RKW SE | Porous film composites |
5176668, | Apr 13 1984 | Kimberly-Clark Worldwide, Inc | Absorbent structure designed for absorbing body fluids |
5176672, | Nov 13 1990 | Kimberly-Clark Worldwide, Inc | Pocket-like diaper or absorbent article |
5178931, | Nov 26 1990 | Kimberly-Clark Worldwide, Inc | Three-layer nonwoven laminiferous structure |
5186779, | Aug 21 1989 | ELASTIC CORPORATION OF AMERICA, INC | Method of making an elastic waistband with releasably secured drawstring |
5188885, | Sep 08 1989 | Kimberly-Clark Worldwide, Inc | Nonwoven fabric laminates |
5192606, | Sep 11 1991 | Kimberly-Clark Worldwide, Inc | Absorbent article having a liner which exhibits improved softness and dryness, and provides for rapid uptake of liquid |
5198281, | Apr 17 1989 | Georgia Tech Research Corporation | Non-woven flexible multiply towpreg fabric |
5200246, | Mar 20 1991 | TUFF SPUN FABRICS, INC , APPLETON, WI | Composite fabrics comprising continuous filaments locked in place by intermingled melt blown fibers and methods and apparatus for making |
5204429, | Aug 07 1987 | Ticona GmbH | Process for the preparation of an olefin polymer |
5209801, | Sep 19 1988 | Paragon Trade Brands, LLC | Method of forming a disposable elastic structure |
5219633, | Mar 20 1991 | Tuff Spun Fabrics, Inc. | Composite fabrics comprising continuous filaments locked in place by intermingled melt blown fibers and methods and apparatus for making |
5226992, | Sep 23 1988 | Kimberly-Clark Worldwide, Inc | Process for forming a composite elastic necked-bonded material |
5229191, | Nov 20 1991 | BBA NONWOVENS SIMPSONVILLE, INC | Composite nonwoven fabrics and method of making same |
5232777, | Dec 23 1987 | Minnesota Mining and Manufacturing Company | Elastic strand construction |
5236430, | Nov 21 1991 | The Procter & Gamble Company | Disposable training pant having fusion-slit side seams |
5236770, | Jul 30 1991 | Carl Freudenberg KG | Nonwoven laminate |
5238733, | Sep 30 1991 | Minnesota Mining and Manufacturing Company | Stretchable nonwoven webs based on multi-layer blown microfibers |
5246433, | Nov 21 1991 | The Procter & Gamble Company | Elasticized disposable training pant and method of making the same |
5252170, | Jul 11 1991 | Shibuya International, Inc. | Web splicing apparatus |
5259902, | Sep 04 1992 | PROCETER & GAMBLE COMPANY, THE | Method for continuously attaching tensioned elastic material to an absorbent article |
5260126, | Jan 10 1990 | Kimberly-Clark Worldwide, Inc | Low stress relaxation elastomeric nonwoven webs and fibers |
5272236, | Oct 15 1991 | DOW CHEMICAL COMPANY, THE | Elastic substantially linear olefin polymers |
5277976, | Oct 07 1991 | Minnesota Mining and Manufacturing Company; MINNESOTA MINING AND MANUFACTURING COMPANY A CORPORATION OF DE | Oriented profile fibers |
5278272, | Oct 15 1991 | DOW CHEMICAL COMPANY, THE | Elastic substantialy linear olefin polymers |
5288791, | Jan 10 1990 | Kimberly-Clark Worldwide, Inc | Low stress relaxation elastomeric fibers |
5290842, | Sep 03 1991 | Avery Dennison Corporation | Pressure-sensitive adhesives based on preferentially tackified immiscible elastomers |
5296080, | Apr 19 1988 | Paper Converting Machine Company | Apparatus for applying an elastic waistband to a disposable diaper |
5304599, | Apr 23 1990 | KRATON POLYMERS U S LLC | Low stress relaxation extrudable elastomeric composition |
5308345, | Nov 28 1989 | GDM SPA | System and method for manufacturing disposable diapers having elastic waistband |
5312500, | Feb 21 1989 | Nippon Petrochemicals Co., Ltd.; Polymer Processing Research Inst., Ltd. | Non-woven fabric and method and apparatus for making the same |
5324580, | Sep 30 1991 | Fiberweb Holdings Limited | Elastomeric meltblown webs |
5332613, | Jun 09 1993 | Kimberly-Clark Worldwide, Inc | High performance elastomeric nonwoven fibrous webs |
5334437, | Sep 23 1992 | XYMID LLC | Spunlaced fabric comprising a nonwoven Batt hydraulically entangled with a warp-like array of composite elastic yarns |
5334446, | Jan 24 1992 | FIBERWEB NORTH AMERICA, INC A CORP OF DELAWARE | Composite elastic nonwoven fabric |
5336545, | Sep 23 1988 | Kimberly-Clark Worldwide, Inc | Composite elastic necked-bonded material |
5336552, | Aug 26 1992 | Kimberly-Clark Worldwide, Inc | Nonwoven fabric made with multicomponent polymeric strands including a blend of polyolefin and ethylene alkyl acrylate copolymer |
5342469, | Jan 08 1993 | STATE STREET BANK AND TRUST COMPANY OF CONNECTICUT, NATIONAL ASSOCIATION; STATE STREET BANK AND TRSUT COMPANY OF CONNECTICUT, NATIONAL ASSOCIATION | Method of making a composite with discontinuous adhesive structure |
5360854, | Dec 05 1988 | Adhesive Technology, Inc. | Hot melt pressure sensitive adhesive composition and applications |
5364382, | May 08 1989 | Kimberly-Clark Worldwide, Inc | Absorbent structure having improved fluid surge management and product incorporating same |
5366793, | Apr 07 1992 | Kimberly-Clark Worldwide, Inc | Anisotropic nonwoven fibrous web |
5376198, | Dec 22 1987 | Kimberly-Clark Worldwide, Inc | Method for making a stretchable absorbent article |
5376430, | Jun 19 1992 | Minnesota Mining and Manufacturing Company; MINNESOTA MINING AND MANUFACTURING COMPANY A CORP OF DELAWARE | Elastic film laminate |
5382400, | Aug 21 1992 | Kimberly-Clark Worldwide, Inc | Nonwoven multicomponent polymeric fabric and method for making same |
5385775, | Dec 09 1991 | Kimberly-Clark Worldwide, Inc | Composite elastic material including an anisotropic elastic fibrous web and process to make the same |
5389173, | Dec 02 1992 | Paper Converting Machine Company | Apparatus and process for making disposable diaper type products |
5389438, | Feb 22 1990 | Minnesota Mining and Manufacturing Company | Repositionable adhesive tape |
5393599, | Jan 24 1992 | BBA NONWOVENS SIMPSONVILLE, INC | Composite nonwoven fabrics |
5399219, | Feb 23 1994 | Kimberly-Clark Worldwide, Inc | Method for making a fastening system for a dynamic fitting diaper |
5405682, | Aug 26 1992 | Kimberly-Clark Worldwide, Inc | Nonwoven fabric made with multicomponent polymeric strands including a blend of polyolefin and elastomeric thermoplastic material |
5407507, | Oct 25 1993 | The Procter & Gamble Company; Procter & Gamble Company, The | Method and apparatus for combining a tensioned elastic member with a moving substrate web |
5411618, | Nov 24 1993 | Paper Converting Machine Company | Method and apparatus for producing waistband-equipped disposable diapers |
5413654, | Sep 13 1990 | Uni-Charm Corporation | Disposable garments and method for attachment of elastic members around leg-holes thereof |
5413849, | Jun 07 1994 | BBA NONWOVENS SIMPSONVILLE, INC | Composite elastic nonwoven fabric |
5415644, | Jul 02 1984 | Kimberly-Clark Worldwide, Inc | Diapers with elasticized side pockets |
5415649, | Oct 31 1990 | Kao Corporation | Disposable diapers |
5415925, | Jun 10 1992 | BBA NONWOVENS SIMPSONVILLE, INC | Gamma structure composite nonwoven fabric comprising at least two nonwoven webs adhesively bonded by a lightweight adhesive web |
5422172, | Aug 11 1993 | Clopay Plastic Products Company, Inc.; CLOPAY PLASTIC PRODUCTS COMPANY, INC | Elastic laminated sheet of an incrementally stretched nonwoven fibrous web and elastomeric film and method |
5425987, | Aug 26 1992 | Kimberly-Clark Worldwide, Inc | Nonwoven fabric made with multicomponent polymeric strands including a blend of polyolefin and elastomeric thermoplastic material |
5429629, | May 08 1989 | Kimberly-Clark Worldwide, Inc | Absorbent structure having improved fluid surge management and product incorporating same |
5429694, | Apr 05 1994 | Paragon Trade Brands, LLC | Apparatus and method for applying tensioned elastic to material |
5429856, | Mar 30 1990 | Minnesota Mining and Manufacturing Company | Composite materials and process |
5431644, | Dec 23 1987 | Minnesota Mining and Manufacturing Company | Elastic strand construction |
5431991, | Jan 24 1992 | BBA NONWOVENS SIMPSONVILLE, INC | Process stable nonwoven fabric |
5447462, | Apr 13 1993 | HBI Branded Apparel Enterprises, LLC | Fabric laminate and garments incorporating same |
5447508, | Mar 30 1993 | Uni-Charm Corporation | Disposable diapers |
5449353, | Oct 31 1990 | Kao Corporation | Disposable diaper |
5464401, | Nov 21 1991 | The Procter & Gamble Company | Elasticized disposable training pant having differential extensibility |
5466410, | Oct 02 1987 | SHAW INDUSTRIES GROUP, INC | Process of making multiple mono-component fiber |
5472775, | Aug 17 1993 | DOW CHEMICAL COMPANY, THE | Elastic materials and articles therefrom |
5476458, | Dec 22 1993 | Kimberly-Clark Worldwide, Inc | Liquid-retaining absorbent garment and method of manufacture |
5476563, | Feb 07 1992 | Yugengaisya Towa | Process of making a door mat |
5484645, | Jun 10 1992 | Fiberweb Holdings Limited | Composite nonwoven fabric and articles produced therefrom |
5486166, | Mar 04 1994 | Kimberly-Clark Worldwide, Inc | Fibrous nonwoven web surge layer for personal care absorbent articles and the like |
5490846, | Mar 04 1994 | Kimberly-Clark Worldwide, Inc | Surge management fibrous nonwoven web for personal care absorbent articles and the like |
5496298, | Dec 28 1993 | Kimberly-Clark Worldwide, Inc | Elastomeric ears for disposable absorbent article |
5498468, | Sep 23 1994 | Kimberly-Clark Worldwide, Inc | Fabrics composed of ribbon-like fibrous material and method to make the same |
5500075, | Apr 26 1994 | Paragon Trade Brands, LLC | Leg elastic applicator which maintains the spacing between the elastics substantially constant |
5501679, | Nov 17 1989 | 3M Innovative Properties Company | Elastomeric laminates with microtextured skin layers |
5509915, | Sep 11 1991 | Kimberly-Clark Worldwide, Inc | Thin absorbent article having rapid uptake of liquid |
5514470, | Sep 23 1988 | Kimberly-Clark Worldwide, Inc | Composite elastic necked-bonded material |
5516476, | Nov 08 1994 | Hills, Inc, | Process for making a fiber containing an additive |
5523146, | Jan 08 1993 | Poly-Bond, Inc. | Composite with discontinuous adhesive structure |
5527300, | Aug 31 1994 | Kimberly-Clark Worldwide, Inc | Absorbent article with high capacity surge management component |
5531850, | Jun 21 1994 | Paragon Trade Brands, LLC | Apparatus and method for applying transverse tensioned elastic |
5534330, | Oct 11 1993 | Lainiere de Picardie S.A. | Thermobonding interlining comprising a layer of fibers intermingled with textured weft yarns and its production method |
5536563, | Dec 01 1994 | Kimberly-Clark Worldwide, Inc | Nonwoven elastomeric material |
5540796, | Aug 03 1994 | Kimberly-Clark Worldwide, Inc | Process for assembling elasticized ear portions |
5540976, | Jan 11 1995 | Kimberly-Clark Worldwide, Inc | Nonwoven laminate with cross directional stretch |
5543206, | Nov 23 1994 | Fiberweb Holdings Limited | Nonwoven composite fabrics |
5545158, | Jun 23 1994 | Kimberly-Clark Worldwide, Inc | Disposable absorbent garment and a continuous, selectively elasticized band joined there to |
5545285, | Mar 07 1988 | Paragon Trade Brands, LLC | Waist elastic applicator for diaper or similar article |
5549964, | Dec 27 1988 | Asahi Kasei Kogyo Kabushiki Kaisha | Stretchable nonwoven fabric and method of manufacturing the same |
5569232, | Feb 28 1994 | The Procter and Gamble Company | Absorbent article with multiple zone structural elastic-like film web extensible waist feature |
5575783, | Sep 28 1992 | The Procter & Gamble Company | Absorbent article with dynamic elastic feature comprising elasticized hip panels |
5576090, | Feb 13 1992 | Daio Paper Corporation | Sheet elastic complex used in sanitary products its manufacturing process, and its usages |
5582668, | Sep 15 1992 | Molnlycke AB | Method and arrangement for mounting elastic elements onto an elongated, moving material web |
5591152, | Jun 13 1991 | The Procter & Gamble Company | Absorbent article with dynamic elastic waist feature having a predisposed resilient flexural hinge |
5591792, | Jan 25 1994 | Mitsubishi Chemical Corporation | Adhesive resin composition |
5595618, | Apr 03 1995 | Kimberly-Clark Worldwide, Inc | Assembly process for a laminated tape |
5597430, | Mar 09 1994 | Mannesmann Aktiengesellschaft | Process and apparatus for manufacturing a body reinforced with fiber-composite material |
5612118, | Dec 20 1994 | Kimberly-Clark Corporation | Elongate, semi-tone printing process and substrates printed thereby |
5614276, | Sep 20 1991 | Hellenic Plastics and Rubber Industry Memelaos Petsetakis, S.A. | Extrusion of materials |
5620780, | Mar 30 1990 | Minnesota Mining and Manufacturing Company | Composite materials and process |
5624740, | Jul 27 1993 | TOWA, YUGENGAISYA | Doormats manufacturing apparatus |
5626573, | Sep 20 1994 | Uni-Charm Corporation | Pants type disposable diaper |
5628856, | Apr 29 1996 | The Procter & Gamble Company; Procter & Gamble Company, The | Method for forming a composite elastic material |
5645672, | Jun 24 1996 | The Proctor & Gamble Company; Procter & Gamble Company, The | Method for forming a composite elastic material |
5652041, | Sep 01 1993 | FREUDENBERG PERFORMANCE MATERIALS LP | Nonwoven composite material and method for making same |
5660664, | Apr 26 1994 | Paragon Trade Brands, LLC | Method of applying leg elastic |
5663228, | Mar 14 1990 | Avery Dennison Corporation | Pressure-sensitive adhesives based on preferentially tackified immiscible elastomers |
5669897, | Jun 03 1993 | The Procter & Gamble Company | Absorbent articles providing sustained dynamic fit |
5680653, | Dec 02 1994 | Kimberly-Clark Worldwide, Inc | Surgical gown cuff and method for making the same |
5681302, | Jun 14 1994 | Minnesota Mining and Manufacturing Company | Elastic sheet-like composite |
5683787, | Dec 18 1992 | Fiberweb Corovin GmbH | Multilayered elastic sheet structure and process for producing a multilayered elastic sheet structure |
5690626, | Sep 30 1993 | Japan Absorbent Technology Institute | Sanitary article with improved fitness |
5691034, | Nov 17 1989 | Elastomeric laminates with microtextured skin layers | |
5693038, | Sep 30 1993 | Japan Absorbent Technology Institute | Sanitary article with improved fitness |
5695849, | Feb 20 1996 | Kimberly-Clark Worldwide, Inc | Elastic, breathable, barrier fabric |
5702378, | Jul 06 1989 | Molnlycke AB | Resilient material and disposable, absorbent article comprising such a material |
5707709, | Apr 27 1993 | Twin ply fabric, uses and manufacture thereof | |
5709921, | Nov 13 1995 | Kimberly-Clark Worldwide, Inc | Controlled hysteresis nonwoven laminates |
5720838, | Jul 27 1993 | Yugengaisya, Towa | Method of manufacturing colored doormats |
5733635, | Nov 21 1995 | JNC Corporation | Laminated non-woven fabric and process for producing the same |
5733822, | Aug 11 1995 | FIBERWEB NORTH AMERICA, INC | Composite nonwoven fabrics |
5735839, | Oct 14 1994 | Kao Corporation | Shorts type disposable diaper |
5736219, | Aug 30 1993 | PGI POLYMER, INC | Absorbent nonwoven fabric |
5746731, | Apr 26 1995 | Uni-Charm Corporation | Disposable undergarment |
5749865, | Aug 02 1995 | Uni-Charm Corporation | Absorbent article of pants type |
5749866, | Feb 28 1994 | The Procter & Gamble Company | Absorbent article with multiple zone structural elastic-like film web extensible waist feature |
5766389, | Dec 29 1995 | Kimberly-Clark Worldwide, Inc | Disposable absorbent article having a registered graphic and process for making |
5766737, | Jul 23 1996 | BBA NONWOVENS SIMPSONVILLE, INC | Nonwoven fabrics having differential aesthetic properties and processes for producing the same |
5769838, | Sep 12 1996 | The Procter & Gamble Company | Disposable pull-on pant |
5769993, | Nov 14 1992 | Amoco Corporation | Process for producing an elastic multilayer web of material |
5772649, | Feb 27 1995 | Panel attachment for absorbent undergarments | |
5773373, | Jun 18 1996 | REEF INDUSTRIES, INC | Reinforced laminate with elastomeric tie layer |
5773374, | May 21 1996 | Minnesota Mining and Manufacturing Company | Composite materials and process |
5788804, | Jul 17 1995 | Liba Maschinenfabrik GmbH | Machine for the production of pre-ready made reinforcement formations |
5789065, | Oct 11 1996 | Kimberly-Clark Worldwide, Inc | Laminated fabric having cross-directional elasticity and method for producing same |
5789328, | Jun 18 1996 | Nippon Petrochemicals Company, Limited; Polymer Processing Research Inst., Ltd. | Bulky nonwoven fabric and method for producing the same |
5789474, | Sep 28 1995 | BANK OF AMERICA, N A | Additive composition and method for increasing the upper service temperature of adhesives |
5790983, | May 16 1995 | Kimberly-Clark Worldwide, Inc | Elasticized top garment |
5800903, | Mar 30 1990 | Minnesota Mining and Manufacturing Company | Composite materials and process |
5804021, | Apr 29 1994 | Kimberly-Clark Worldwide, Inc | Slit elastic fibrous nonwoven laminates and process for forming |
5804286, | Nov 22 1995 | FITESA NONWOVEN, INC | Extensible composite nonwoven fabrics |
5814176, | Feb 06 1996 | Proulx Manufacturing, Inc. | Process for forming double-strand monofilament line for use in flexible line trimmers |
5817087, | Oct 14 1994 | Kao Corporation | Shorts type disposable diaper |
5818719, | Dec 29 1995 | Kimberly-Clark Worldwide, Inc | Apparatus for controlling the registration of two continuously moving layers of material |
5830203, | May 24 1994 | Paragon Trade Brands, LLC | Absorbent article and method of manufacturing the same |
5834089, | Mar 03 1997 | Honeywell International Inc | Additive-containing synthetic filaments, and yarns and carpets including such filaments |
5836931, | Apr 19 1993 | Kao Corporation | Shorts type disposable diaper |
5836932, | Apr 03 1995 | The Procter & Gamble Company | Disposable breathable garment |
5840412, | Mar 26 1990 | Minnesota Mining and Manufacturing Company | Composite materials and process |
5840633, | Nov 25 1994 | Polymer Processing Research Inst., Ltd.; Nippon Petrochemicals Company, Ltd. | Nonwoven fabric and method of making the same |
5846232, | Dec 20 1995 | Kimberly-Clark Worldwide, Inc | Absorbent article containing extensible zones |
5849001, | Feb 02 1995 | Kao Corporation | Porous sheet and absorbent article using the same |
5856387, | Sep 03 1991 | Avery Dennison Corporation | Pressure-sensitive adhesives based on preferentially tackified immiscible elastomers |
5858515, | Dec 17 1996 | Kimberly-Clark Worldwide, Inc | Pattern-unbonded nonwoven web and process for making the same |
5860945, | Dec 31 1996 | Wyeth | Disposable elastic thermal knee wrap |
5865933, | Nov 12 1996 | Milliken Research Corporation | Method for selectively carving color contrasting patterns in textile fabric |
5876392, | Jan 31 1996 | Uni-Charm Corporation | Disposable absorbent pants type undergarment with improved heat sealed edges |
5879776, | Jul 27 1993 | Yugengaisya Towa | Colored doormats, method of manufacturing and manufacturing device |
5882573, | Sep 29 1997 | Illinois Tool Works Inc. | Adhesive dispensing nozzles for producing partial spray patterns and method therefor |
5885656, | Apr 25 1994 | Avgol Nonwoven Industries | Coating selective zones of thin webs to change the pervious character thereof, using a shutter |
5885686, | Aug 26 1994 | Conwed Plastics LLC | Bicomponent elastomeric netting |
5897546, | Aug 02 1995 | Uni-Charm Corporation | Disposable diaper having a fastening system |
5899895, | Nov 19 1993 | The Procter & Gamble Company; Procter & Gamble Company, The | Disposable absorbent article with extensible side panels |
5902540, | Oct 10 1996 | Illinois Tool Works Inc | Meltblowing method and apparatus |
5904298, | Oct 10 1996 | Illinois Tool Works Inc | Meltblowing method and system |
5916206, | Jul 14 1995 | Uni-Charm Corporation | Absorbent pants type undergarment having differently tensioned elastic elements for improved leakage prevention and comfort |
5921973, | Nov 23 1994 | Fiberweb Holdings Limited | Nonwoven fabric useful for preparing elastic composite fabrics |
5930139, | Nov 13 1996 | Kimberly-Clark Worldwide, Inc | Process and apparatus for registration control of material printed at machine product length |
5931581, | May 19 1997 | LASALLE BANK NATIONAL ASSOCIATION | Self-sealable packaging for enclosing articles |
5932039, | Oct 14 1997 | Kimberly-Clark Worldwide, Inc | Process and apparatus for registering a continuously moving, treatable layer with another |
5938648, | Dec 03 1997 | Procter & Gamble Company, The | Absorbent articles exhibiting improved internal environmental conditions |
5941865, | May 07 1996 | Uni-Charm Corporation | Disposable absorbent garment of pants type |
5952252, | Feb 20 1996 | Kimberly-Clark Worldwide, Inc | Fully elastic nonwoven fabric laminate |
5964970, | Oct 14 1997 | Kimberly-Clark Worldwide, Inc | Registration process and apparatus for continuously moving elasticized layers having multiple components |
5964973, | Jan 21 1998 | Kimberly-Clark Worldwide, Inc.; Kimberly-Clark Worldwide, Inc | Method and apparatus for making an elastomeric laminate web |
5990377, | Mar 21 1997 | Kimberly-Clark Worldwide, Inc | Dual-zoned absorbent webs |
5993433, | Oct 20 1997 | Kimberly-Clark Worldwide, Inc | Absorbent article with enhanced elastic design for improved aesthetics and containment |
5997521, | Nov 19 1993 | Procter & Gamble Company, The | Disposable absorbent article with extensible side panels |
6004306, | Nov 19 1993 | The Procter & Gamble Company | Absorbent article with multi-directional extensible side panels |
6033502, | Nov 13 1996 | Kimberly-Clark Worldwide, Inc | Process and apparatus for registering continuously moving stretchable layers |
6045543, | Nov 05 1997 | Kimberly-Clark Worldwide, Inc. | Alignment indicators for use with personal care articles |
6048326, | Dec 31 1996 | Wyeth | Disposable elastic thermal knee wrap |
6057024, | Oct 31 1997 | Kimberly-Clark Worldwide, Inc | Composite elastic material with ribbon-shaped filaments |
6066369, | Jan 27 1998 | REIFENHAUSER GMBH & CO MASCHINENFABRIK | Method of and apparatus for producing a composite web |
6087550, | Nov 09 1995 | H B FULLER COMPANY | Non-woven application for water dispersable copolyester |
6090234, | Jul 15 1996 | Wyeth | Elastic laminates and methods for making the same |
6092002, | Nov 13 1996 | Kimberly-Clark Worldwide, Inc | Variable tension process and apparatus for continuously moving layers |
6093663, | Jul 15 1996 | Wyeth | Structure and method of forming a laminate structure |
6096668, | Sep 15 1997 | Kimberly-Clark Worldwide, Inc. | Elastic film laminates |
6123694, | May 09 1997 | Paragon Trade Brands, LLC | Disposable absorbent article with unitary leg gathers |
6132410, | Feb 12 1999 | Kimberly-Clark Worldwide, Inc | Disposable garment having dryness barriers with expandable attachment to an absorbent |
6149637, | Jan 03 1994 | Procter & Gamble Company, The | Elastomeric disposable absorbent article and method of making same |
6152904, | Nov 22 1996 | Kimberly-Clark Worldwide, Inc | Absorbent articles with controllable fill patterns |
6169848, | Jan 06 2000 | Impact Systems, Inc. | Cross-direction dryer for a machine producing sheet material moving in a machine direction having both gas powered and electric heating portions |
6183587, | Nov 26 1997 | Procter & Gamble Company, The | Method of making sanitary napkin comprising three dimensionally shaped tube of absorbent material |
6183847, | Apr 25 1994 | Avgol Ltd., Nonwoven Industries | Coating selective zones of thin webs to change the pervious character thereof |
6197845, | Jun 15 1998 | H B FULLER COMPANY | Hot melt adhesive compositions for adherence to skin and articles constructed therefrom |
6214476, | Feb 10 1997 | Mitsubishi Chemical Corporation | Adhesive resin compositions, laminates, production method thereof and oriented films |
6217690, | Jan 31 1995 | Kimberly-Clark Worldwide, Inc | Disposable garment manufacture including feeding elastic into a nip |
6231557, | Sep 01 1999 | Kimberly-Clark Worldwide, Inc | Absorbent product containing an elastic absorbent component |
6238379, | Aug 25 1998 | Kimberly-Clark Worldwide, Inc | Absorbent article with increased wet breathability |
6245050, | Nov 09 1995 | Kimberly-Clark Worldwide, Inc | Disposable absorbent article including an elasticized area |
6245168, | Nov 13 1996 | Kimberly-Clark Worldwide, Inc | Process and apparatus for registering continuously moving stretchable layers |
6260211, | Jan 31 1995 | Kimberly-Clark Worldwide, Inc | Disposable garment and related manufacturing equipment and methods |
6279807, | Nov 04 1994 | Roll Systems, Inc. | Method and apparatus for pinless feeding of web to a utilization device |
6290979, | Oct 31 1997 | The Procter & Gamble Company | Web materials with two or more skin care compositions disposed thereon and articles made therefrom |
6310164, | Jul 18 1997 | Mitsu Chemicals INC | Unsaturated copolymers, processes for preparing the same, and compositions containing the same |
6316013, | Aug 23 1999 | Kimberly-Clark Worldwide, Inc | Absorbent article which maintains or improves skin health |
6316687, | Oct 04 1989 | Kimberly-Clark Worldwide, Inc | Disposable diaper having a humidity transfer region, Breathable zone panel and separation layer |
6316688, | Apr 27 1998 | Procter & Gamble Company, The | Sanitary napkin comprising three dimensionally shaped tube of absorbent material |
6320096, | Feb 28 1997 | Uni-Charm Corporation | Disposable training pants for infants with wetness indicator |
6323389, | Oct 03 1997 | Kimberly-Clark Worldwide, Inc | High performance elastic composite materials made from high molecular weight thermoplastic triblock elastomers |
6329459, | Sep 23 1996 | Bridgestone Corporation | Extended syndiotactic polystyrene-elastomeric block copolymers |
6364863, | Aug 25 1995 | Uni-Charm Corporation | Disposable absorbent undergarment |
6365659, | Jun 08 2000 | Toray Industries, Inc. | Polyester composition and film, and production method |
6367089, | Aug 31 1993 | Kimberly-Clark Worldwide, Inc. | Disposable menstrual panty |
6475600, | Dec 23 1998 | Kimberly-Clark Worldwide, Inc | Composite material having stretch and recovery including a layer of an elastic material and a transversely extensible and retractable necked laminate of non-elastic sheet layers |
6537935, | Jan 29 1999 | 3M Innovative Properties Company | High strength nonwoven fabric and process for making |
6645190, | Nov 22 1999 | Kimberly-Clark Worldwide, Inc | Absorbent article with non-irritating refastenable seams |
6657009, | Dec 29 2000 | Kimberly-Clark Worldwide, Inc. | Hot-melt adhesive having improved bonding strength |
6767852, | Dec 28 2000 | Kimberly-Clark Worldwide, Inc | Stretch edge elastic laminate |
20020002021, | |||
20020009940, | |||
20020019616, | |||
20020072561, | |||
20020081423, | |||
20020104608, | |||
20020122953, | |||
20020123538, | |||
20020123726, | |||
20020138063, | |||
20020164465, | |||
20030232928, | |||
20040127128, | |||
CA2165486, | |||
D284036, | Mar 01 1983 | Molnlycke Aktiebolag | Diaper pants |
D331627, | Dec 13 1990 | Uni-Charm Corporation | Diaper pants |
D335707, | Jan 17 1990 | Uni-Charm Corporation | Diaper pants |
D340283, | Aug 31 1990 | Uni-Charm Corporation | Diaper pants |
D414262, | Apr 30 1998 | Procter & Gamble Company, The | Pull-on garment |
DE3423644, | |||
DE3734963, | |||
EP155636, | |||
EP172037, | |||
EP217032, | |||
EP239080, | |||
EP330716, | |||
EP380781, | |||
EP396800, | |||
EP456885, | |||
EP547497, | |||
EP582569, | |||
EP604731, | |||
EP617939, | |||
EP688550, | |||
EP689815, | |||
EP713546, | |||
EP743052, | |||
EP753292, | |||
EP761193, | |||
EP761194, | |||
EP763353, | |||
EP787474, | |||
EP802251, | |||
EP806196, | |||
EP814189, | |||
EP901780, | |||
EP1013251, | |||
GB2244422, | |||
GB2250921, | |||
GB2253131, | |||
GB2267024, | |||
GB2268389, | |||
IS92891, | |||
JP367646, | |||
WO10500, | |||
WO29199, | |||
WO37003, | |||
WO37005, | |||
WO37009, | |||
WO37723, | |||
WO100053, | |||
WO132116, | |||
WO149907, | |||
WO187214, | |||
WO2053667, | |||
WO2053668, | |||
WO2060690, | |||
WO2085624, | |||
WO234184, | |||
WO2004039907, | |||
WO8000676, | |||
WO9003464, | |||
WO9107277, | |||
WO9216371, | |||
WO9315247, | |||
WO9317648, | |||
WO9409736, | |||
WO9503443, | |||
WO9504182, | |||
WO9516425, | |||
WO9516562, | |||
WO9534264, | |||
WO9613989, | |||
WO9623466, | |||
WO9635402, | |||
WO9717046, | |||
WO9814156, | |||
WO9849988, | |||
WO9855062, | |||
WO9917926, | |||
WO9924519, | |||
WO9947590, | |||
WO9960969, | |||
WO9960970, | |||
WO9960971, |
Executed on | Assignor | Assignee | Conveyance | Frame | Reel | Doc |
Dec 26 2002 | Kimberly-Clark Worldwide, Inc. | (assignment on the face of the patent) | / | |||
Jan 28 2003 | ZHOU, PEIGUANG | Kimberly-Clark Worldwide, Inc | ASSIGNMENT OF ASSIGNORS INTEREST SEE DOCUMENT FOR DETAILS | 013926 | /0428 | |
Jan 28 2003 | NECULESCU, CRISTIAN M | Kimberly-Clark Worldwide, Inc | ASSIGNMENT OF ASSIGNORS INTEREST SEE DOCUMENT FOR DETAILS | 013926 | /0428 | |
Jan 28 2003 | GARRETT, LANCE J , JR | Kimberly-Clark Worldwide, Inc | ASSIGNMENT OF ASSIGNORS INTEREST SEE DOCUMENT FOR DETAILS | 013926 | /0428 | |
Jan 01 2015 | Kimberly-Clark Worldwide, Inc | Kimberly-Clark Worldwide, Inc | NAME CHANGE | 034880 | /0742 |
Date | Maintenance Fee Events |
Jan 06 2006 | ASPN: Payor Number Assigned. |
Jun 29 2009 | M1551: Payment of Maintenance Fee, 4th Year, Large Entity. |
Mar 14 2013 | M1552: Payment of Maintenance Fee, 8th Year, Large Entity. |
Jun 27 2017 | M1553: Payment of Maintenance Fee, 12th Year, Large Entity. |
Date | Maintenance Schedule |
Dec 27 2008 | 4 years fee payment window open |
Jun 27 2009 | 6 months grace period start (w surcharge) |
Dec 27 2009 | patent expiry (for year 4) |
Dec 27 2011 | 2 years to revive unintentionally abandoned end. (for year 4) |
Dec 27 2012 | 8 years fee payment window open |
Jun 27 2013 | 6 months grace period start (w surcharge) |
Dec 27 2013 | patent expiry (for year 8) |
Dec 27 2015 | 2 years to revive unintentionally abandoned end. (for year 8) |
Dec 27 2016 | 12 years fee payment window open |
Jun 27 2017 | 6 months grace period start (w surcharge) |
Dec 27 2017 | patent expiry (for year 12) |
Dec 27 2019 | 2 years to revive unintentionally abandoned end. (for year 12) |