A metallic porous body includes a number of protrusions formed on obverse and reverse sides of a metal sheet so as to protrude alternately with one another; each of the protrusions being formed into an truncated-shape wherein an opening portion punched out in the direction from the upper-side bottom to the lower-side bottom is formed in the upper-side bottom of each protrusion, and a vertical distance (d) between the upper-side bottom on the obverse side and the upper-side bottom on the reverse side, and a height (e) of a punched portion have a relation: 0.3<e/d<0.9, thereby attaining a metallic porous body without a burr or a edged convex portion on its outside surface, with a large number of fine pores arranged at fine pitch and a light-weight and robust skeleton.
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1. A metallic porous body comprising:
a number of protrusions formed on obverse and reverse sides of a metal sheet so as to protrude alternately with one another; each of the protrusions being formed into an angular-truncated-pyramidal shape so that an area of an upper-side bottom thereof is smaller than an area of lower-side bottom thereof;
wherein an opening portion having a shape as a polygon in a plan view and punched out in the direction from the upper-side bottom to the lower-side bottom is formed in the upper-side bottom of each protrusion, and
a vertical distance (d) between the upper-side bottom on the obverse side and the upper-side bottom on the reverse side, and a height (e) of a punched portion have a relation: 0.3<e/d<0.9.
3. A metallic porous body having a large number of independent opening portions comprising:
a number of protrusions formed on obverse and reverse sides of a metal sheet so as to protrude alternately with one another; each of the protrusions being formed into a triangular-truncated-pyramidal shape so that an area of an upper-side bottom thereof is smaller than an area of lower-side bottom thereof;
wherein an opening portion having a shape as a triangle in a plan view and punched in the direction from the upper-side bottom to the lower-side bottom is formed in the upper-side bottom of each protrusion,
the opening portion includes a triangular-pyramidal small concave portion which is concavely formed in a central portion of the upper-side bottom, and a triangular-throwing-knife shaped opening directed to three corner portions of the upper-side bottom in a central portion of the small concave portion, the small concave portion being formed into a petal-like shape downwardly spreading with three petal-shaped pieces, and
an extension direction of one side of the triangle of the protrusion conforms to the direction of the long side of the metallic porous body.
2. A metallic porous body having a large number of independent opening portions comprising:
a number of protrusions formed on obverse and reverse sides of a metal sheet so as to protrude alternately with one another; each of the protrusions being formed into a rhombic-truncated-pyramidal shape so that an area of an upper-side bottom thereof is smaller than an area of lower-side bottom thereof;
wherein an opening portion having a shape as a rhomboid in a plan view and punched in the direction from the upper-side bottom to the lower-side bottom is formed in the upper-side bottom of each protrusion,
the opening portion includes a rhombic-pyramidal small concave portion which is concavely formed in a central portion of the upper-side bottom, and a cross-throwing-knife shaped opening directed to four corner portions of the upper-side bottom in a central portion of the small concave portion, the small concave portion being formed into a petal-like shape downwardly spreading with four petal-shaped pieces, and
an extension direction of one of two diagonal lines individually connecting between mutually opposing apexes of the rhomboid of the protrusion conforms to the direction of the long side of the metallic porous body.
4. The metallic porous body according to
5. The metallic porous body according to
6. The metallic porous body according to
7. The metallic porous body according to
8. The metallic porous body according to
9. The metallic porous body according to
10. The metallic porous body according to
11. The metallic porous body according to
12. The metallic porous body according to
13. The metallic porous body according to
14. The metallic porous body according to
15. The metallic porous body according to
16. The metallic porous body according to
17. The metallic porous body according to
18. The metallic porous body according to
19. The metallic porous body according to
20. The metallic porous body according to
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This Nonprovisional application claims priority under 35 U.S.C. § 119 (a) on Patent Application No(s). 2002-364607 and 2003-355027 filed in JAPAN on Dec. 17, 2002 and Oct. 15, 2003, the entire contents of which are hereby incorporated by reference.
1. Field of the Invention
The present invention relates to a metallic porous body, which is usable as electrodes of electrochemical devices, such as batteries and capacitors, or as various filter materials.
2. Description of the Related Art
In the field of, for example, electric and electrochemical devices, such as capacitors and fuel batteries, two-dimensional or three-dimensional metallic porous bodies are used as electrode base materials. Similar metallic porous bodies are also used as materials of various filters, such as air filters and oil mist filters. Typical examples of such two-dimensional metallic porous bodies are, for example, pore-formed steel sheets, so-called “punching metals”, formed by punching metal sheets such as copper foils and steel sheets, and expand metals stretched and formed to a mesh state.
Typical example of three-dimensional metallic porous body includes foamed metals. Generally, the foamed metals are created by the steps of plating a metal such as nickel over urethan foam having lattice-state pores, sintering the plated formation in a reductant ambient, and removing the urethan foam. Fabric metals also can be fabricated in steps similar to the above, in which plating is performed over a non-woven fabric formed by knitting nylon or the like thin fibers.
For use as electrode base materials for electrochemical devices, such as batteries, porous bodies are required to be formed so as to easily extract electricity. Conventionally, three-dimensional metallic porous bodies such as foamed metals are generally used. However, three-dimensional metallic porous bodies are more costly because of using urethane, compared with two-dimensional metallic porous bodies. In addition, processing steps of sintering involves high fabrication costs. Furthermore, the three-dimensional metallic porous bodies require high strength by increasing the sizes of fibers and skeletons, resulting in increasing of weight, reducing in filling amount of active substances, and lowering capacity of batteries.
To solve the problems in a case where a three-dimensional metallic porous body of the type described above is used as an electrode base material, Patent Document 1 (Japanese Unexamined Patent Application Publication JP-9-265991,A (1997)) proposes that a base material with metallic fibers are attached on upper and lower portions of a metal sheet is used for an electric collector. Patent Document 2 (Japanese Unexamined Patent Application Publication JP-10-106580,A (1998)) proposes a manufacturing method in which a metal sheet for a base material is applied with a depressing pressure in an embossing process to provide burrs on individual apexes of concave and convex portions. Patent Document 3 (Japanese Unexamined Patent Application Publication JP-9-7603,A (1997)) proposes usage of a base material formed of a corrugated metal sheet.
However, in the case where a metal sheet is applied with a depressing pressure in an embossing process to form concave and convex portions and in the case where a metal sheet is corrugated, then burrs and sharp convex portions are likely to be formed on the surface of the base material. In addition, in the case of forming edged portions on the surface of the base material, it is difficult to finish the base-material fabrication with one processing step. In other words, the above case requires two or more processing steps of forming concave and convex portions and then forming burrs or corrugating. When machining steps are thus increased, the base material has accumulated strain and hence becomes liable to fracture, consequently leading to deterioration in the production yield. To prevent strain, an additional heat treatment process is required, thereby increasing the fabrication costs. Further, when fabricating a continuous base material, the base material should be wound. However, when the surface of the material has corrugations and/or edged protrusions, the material are likely to be hooked during winding, thereby leading to deterioration in the production yield. Concurrently, care needs to be taken when handling the fabricated base material.
An object of the present invention is to provide a, metallic porous body that has a three-dimensional structure in a cross-sectional view, that does not have at all a burr or a edged convex portion on its outside surface, that has a large number of fine pores arranged at fine pitch, and that has a light-weight and robust skeleton.
As shown in
As shown in
As shown in
Also in each of the patterns shown in
Preferably, a thickness h of the metal sheet 2 before processing is 10 to 50 μm. A thickness d of the metallic porous body 1 including the protrusions 3 is preferably ranged from 0.06 to 1.2 mm. The metal sheet 2 preferably has a unit weight ranged from 50 to 450 g/m2. As shown in
In the manufacture of a metallic porous body 1, as a pair of embossing rollers 12a and 12b for press-forming a metal sheet 2, as shown in
As shown in
In more detail, as shown in
Then, as shown in
In addition, as shown in
When the metal sheet 2 is fed to an opposing gap S of the embossing rollers 12a and 12b, triangular-truncated-pyramidal protrusions 3 protruding alternately with one another on the obverse and reverse surfaces of the metal sheet 2 are each formed with such a posture as that an extension direction of one side (n) of the triangle of the triangular-truncated-pyramidal protrusion 3 conforms to the direction of the long side of the metal body 2.
In respect of advantageous effects, as shown in
As shown in
By punch-forming the punched burr 7 from the upper-side bottom 5 toward the lower-side bottom 6, a sharp metal convex portion can be prevented from being formed on the surface of the metallic porous body 1, consequently enabling prevention of such problems of causing fracture of the metallic porous body 1 because of being caught by a doctor blade in the course of continuous coating of the active-substance containing paste and/or of disabling uniform coating. In addition, e/d should be set to 0.3 to 0.9 because of the relationship between the thickness (d) of the base material 1 and the height (e) of the punched portion. Unless otherwise the ratio is thus set, the end of the punched burr 7 formed in the direction from the upper-side bottom 5 of the protrusion 3 to the lower-side bottom 6 thereof may probably be formed to unexpectedly over-extend from the outermost surface of the lower-side bottom 6, depending on the forming angle, length, and the like factor. When e/d is 0.3 or lower, the distance from the active substance is increased, thereby resulting in reduction of electric collection efficiency. When e/d is higher than 0.9, a case can occur in which the punched burr 7 is caught during handling, thereby potentially leading to reduction in work efficiency and hence deteriorating the production yield.
The thickness of the metal sheet 2 constituting the metallic porous body 1 is preferably ranged from 10 to 50 μm. With a thickness smaller than 10 μm, the strength of the metallic porous body 1 after processing is low, thereby disabling a robust skeletal formation to be obtained. With a thickness larger than 50 μm, the volume of the metal portion taking place in the metallic porous body 1 after formation is large, so that the fill factor of the active substance is reduced, thereby inducing battery-capacity reduction.
The thickness (d) of the metallic porous body 1 including the rectangular-truncated-pyramidal protrusions 3 is preferably in the range of from 0.06 to 1.2 mm. With a thickness smaller than 0.06 mm, a sufficient amount of the active substance cannot be filled since processing steps using a press, a calendar, or the like after the active substance has been filled. With a thickness larger than 1.2 mm, the distance between the active substance and the metal sheet 2 is increased, so that the active-substance utilization ratio is reduced, and hence the battery capacity is reduced.
The weight of the metal sheet 2 is determined to be 50 to 450 g/m2. With a weight less than 50 g/m2, a sufficient strength required for a battery electrode cannot be maintained. With a weight greater than 450 g/m2, the weight of the metal portion taking place after formation, the fill amount of the active substance is reduced. In this view, the weight of the metal sheet 2 is determined to be 50 to 450 g/m2, more preferably 75 to 425 g/m2.
An angle θ between a portion punched downwardly of the protrusion 3 and a flat portion of the upper-side bottom 5 is preferably greater than 0° and smaller than 90°. The angle 0° means that the opening portion 8 is not punched. With the angle θ being set to 20°, the porosity can be increased, efficiency of filling the active-substance can be improved, and the active-substance utilization ratio can be improved, the metallic porous body 1 becomes feasible as electrode base materials of electrochemical devices, such as batteries and capacitors and the like. With the angle being set larger than 90°, it makes it difficult to perform the forming process itself for the metallic porous body 1, or increased labor costs are required, consequently leading to increased fabrication costs. In addition, the utilization ratio of the active substance filled into the central portion of the punched portion is reduced, so that the metallic porous body 1 becomes unsuitable as electrode base materials of electrochemical devices.
As shown in
As shown in
This application is based on two applications No. 2002-364607 filed Dec. 17, 2002 in Japan and No. 2003-355027 filed Oct. 15, 2003 in Japan, each disclosure of which is incorporated herein by reference.
Hereinafter, preferred embodiments will be described with reference to drawings.
(First Embodiment)
On the upper-side bottom 5 of the each protrusion 3, a rectangle-shaped pore 8 (opening portion) having a punched burr 7 toward the lower-side bottom 6 and having an upper-side opening portion of which the shape is square. In more detail, the opening portion 8 is formed of a small concave portion 9, which is concavely formed in a central portion of the upper-side bottom 5, and a cross-throwing-knife shaped (sharp-cross shaped) opening 10 punched toward the lower-side bottom 6 in a central portion of the small concave portion 9. The small concave portion 9 is formed into a petal-like shape spreading with four petal-shaped pieces. In this embodiment, the longitudinal and lateral size of the opening portion 8, that is, the longitudinal and lateral size of the small concave portion 9 is 0.65×0.65 mm.
As shown in
As shown in
As shown in
As shown in
To show the concave and convex state of the surface of the base material 1 obtained in the manner described above,
As described above, in the base material 1, which is the metallic porous body, according to the present embodiment, the embossing process is performed on the obverse and reverse surfaces thereof so that the protrusions 3 are formed opposite to one another, and the opening portions 8 are individually provided in the central portions of the protrusions 3, so that when the metal sheet 2 has a thickness of, for example, 25 μm, the sectional formation thereof can be formed into a three-dimensional structure up to a thickness of about 440 μm (d: refer to
In addition to the above, by punch-forming the punched burr 7 from the upper-side bottom 5 toward the lower-side bottom 6, a sharp metal convex portion can be prevented from being formed on the surface of the base material 1, consequently enabling prevention of such problems of causing fracture of the base material 1 because of being hooked by a doctor blade in the course of continuous coating of the active-substance containing paste and/or of disabling uniform coating. Further, an advantage can be obtained in that shorting can be prevented since such a case can be avoided in which the base material 1 is exposed as well to a post-formation electrode surface. In this case, e/d should be set to 0.3 to 0.9 because of the relationship between the thickness (d) of the base material 1 and the height (e) of the punched portion. Unless otherwise the ratio is thus set, the end of the punched burr 7 formed in the direction from the upper-side bottom 5 of the protrusion 3 to the lower-side bottom 6 thereof may probably be formed to unexpectedly over-extend from the outermost surface of the lower-side bottom 6, depending on the forming angle, length, and the like factor. In addition, when e/d is 0.3 or lower, the distance from the active substance is increased, thereby resulting in reduction of electric collection efficiency. When e/d is higher than 0.9, a case can occur in which the punched burr 7 is caught during handling, thereby potentially leading to reduction in work efficiency and hence deteriorating the production yield. In view of the above, e/d is preferably in the range of from 0.3 to 0.9, and more preferably in the range of from 0.4 to 0.8.
The thickness of the metal sheet 2 is preferably ranged from 10 to 50 μm. With a thickness smaller than 10 μm, the strength of the base material 1 after processing is low, thereby disabling a robust skeletal formation to be obtained. With a thickness larger than 50 μm, the volume of the metal portion taking place in the base material 1 after formation is large, so that the fill factor of the active substance is reduced, thereby inducing battery-capacity reduction.
The thickness (d) of the base material 1 including the rectangular-truncated-pyramidal protrusions 3 is preferably in the range of from 0.06 to 1.2 mm. With a thickness smaller than 0.06 mm, a sufficient amount of the active substance cannot be filled since processing steps using a press, a calendar, or the like after the active substance has been filled. With a thickness larger than 1.2 mm, the distance between the active substance and the metal sheet is increased, so that the active-substance utilization ratio is reduced, and hence the battery capacity is reduced.
The weight of the metal sheet 2 is determined to be 50 to 450 g/m2. With a weight less than 50 g/m2, a sufficient strength required for a battery electrode cannot be maintained. With a weight greater than 450 g/m2, the weight of the metal portion taking place after formation, the fill amount of the active substance is reduced. In this view, the weight of the metal sheet 2 is determined to be 50 to 450 g/m2, more preferably 75 to 425 g/m2.
In the manner of using the above-described specially shaped embossing rollers 12a and 12b to fabricate the base material 1, the lengthy base material 1 can be fabricated with one machining step, so that fabrication costs can be reduced. Notwithstanding that the section is the three-dimensional formation, since neither burr nor sharp convex portion occurs, winding is easy, and the base material 1 can be produced with a high production yield. Since one push-in forming step can accomplish the fabrication, strains do not easily occur; therefore, the obtained base material 1 has a robust skeleton and a high tensile strength.
(Second Embodiment)
On the upper-side bottom 5 of the each protrusion 3, a rhomboid-shaped opening portion 8 punched in the direction from the upper-side bottom 5 to the lower-side bottom 6 in a plan view. In more detail, the opening portion 8 is formed of a small concave portion 9, which is concavely formed in a central portion of the upper-side bottom 5, and a cross-throwing-knife shaped (or, sharp-cross shaped) opening 10 punched toward the lower-side bottom 6 in a central portion of the small concave portion 9. The small concave portion 9 is formed into a petal-like shape spreading with four petal-shaped pieces. In this embodiment, the lengths of the diagonal lines (k and m) of the opening portion 8, that is, the diagonal-line lengths (k and m) of the small concave portion 9 are: k=0.4 mm and m=0.6 mm. The thickness d of the metallic porous body 1 is 0.44 mm. The height e of a punched portion, which is defined by a flat portion of the upper-side bottom 5 and a lower end portion of the burr 7, is 0.24 mm, and e/d is 0.55. The weight of the metal body 2 after formation of the protrusions is 215 g/m2.
In addition to the above, in the present embodiment, attention is called to the fact that the extension direction of one of the two diagonal lines (i and j) individually connecting between mutually opposing apexes of the rhomboid of the protrusion 3 conforms to the direction of the long side of the metallic porous body 1.
Thus, the arrangement is made such that one of the diagonal lines of the rhomboid-shaped protrusion 3 conforms to the direction of the long side of the metallic porous body 1, that is, the direction of feeding the metal body 2, which is the base material, to an opposing gap S between embossing rollers 12a and 12b. Thereby, the extension directions of the individual sides constituting the rhomboid-shaped protrusion 3 is caused not to conform to the direction of feeding the metal body 2 into the opposing gap S between the embossing rollers 12a and 12b. As such, compared with the case in which, as shown in
As shown in
As shown in
As shown in
(Third Embodiment)
On the upper-side bottom 5 of the each protrusion 3, a triangle-shaped opening portion 8 punched in the direction from the upper-side bottom 5 to the lower-side bottom 6 in a plan view. The opening portion 8 is formed of a small concave portion 9, which is concavely formed in a central portion of the upper-side bottom 5, and a throwing-knife shaped (or, sharp-Y shaped) opening 10 having tri-directional cuts and punched toward the lower-side bottom 6 in a central portion of the small concave portion 9. The small concave portion 9 is formed into a petal-like shape spreading with three petal-shaped pieces. In this embodiment, a length n of one side of the small concave portion 9 is 0.85 mm. As shown in
Thus, the arrangement is made such that the each protrusion 3 is formed into the triangular-truncated-pyramidal shape, the extension direction of one side (the extension direction of a side n, in
As shown in
As shown in
As shown in
Table 1 shows elongation percentages in the direction of the long side of the metallic porous bodies 1 of the individual embodiments 1 to 3. In more specific, the each metallic porous body 1 was obtained in the manner that, as shown in
TABLE 1
Elongation
percentage
First Embodiment
2.7%
Second Embodiment
1.4%
Third Embodiment
0.5%
From Table 1, it can be known that, as in the first embodiment, when the extension directions of the individual sides constituting the rectangle-shaped convex portion 3 conform to the direction of feeding the metal body 2 to the embossing rollers 12a and 12b, the elongation percentage in the direction of the long side of the metal body 2 is higher than those of the second and third embodiments, and it is therefore difficult to form the metallic porous body 1 with high accuracy.
In comparison to the first above, however, it can be known that the elongation percentage is low and the metallic porous body 1 can be fabricated with high accuracy as in the case of the second embodiment where the extension direction of one of the two diagonal lines i and j (the extension direction of the diagonal line j, in
While the embodiments described above each have the protrusions 3 each having the shape such as the rectangular-truncated-pyramidal shape or triangular-truncated-pyramidal shape, the shape of the protrusion 3 or the opening portion 8, for example, is not limited to that shape. The shape may be a polygonal shape, such as a pentagonal shape or hexagonal shape.
The metallic porous body of the present invention is a porous base material having a large number of independent fine pores, so that it can be used with various filters such as air filters and oil mist filters. In addition, the porous body can be used for a carrier of industrial deodorizing catalyst.
Although the present invention has been fully described in connection with the preferred embodiments thereof and the accompanying drawings, it is to be noted that various changes and modifications are apparent to those skilled in the art. Such changes and modifications are to be understood as included within the scope of the present invention as defined by the appended claims unless they depart therefrom.
Fukunaga, Hiroshi, Kishimi, Mitsuhiro, Morishima, Masao, Yamashita, Toshihiko
Patent | Priority | Assignee | Title |
7332245, | Jun 21 2002 | HITACHI MAXELL ENERGY, LTD | Electrode for electrochemical devices and battery using the same |
7399423, | Jul 25 2002 | Dai Nippon Insatsu Kabushiki Kaisha | Thin film support substrate for use in hydrogen production filter and production method of hydrogen production filter |
7744990, | Jul 25 2002 | Dai Nippon Insatsu Kabushiki Kaisha | Thin film support substrate for use in hydrogen production filter and production method of hydrogen production filter |
7870931, | Feb 02 2006 | Autoneum Technologies AG; Autoneum Management AG | Sound-absorbing insulation element with strengthening embossments |
8043519, | Jul 25 2002 | Dai Nippon Insatsu Kabushiki Kaisha | Thin film support substrate for use in hydrogen production filter and production method of hydrogen production filter |
8085525, | Nov 14 2005 | Panasonic Corporation | Electric double layer capacitor including current collector having a plurality of apertures therein |
8562847, | Jul 25 2002 | Dai Nippon Insatsu Kabushiki Kaisha | Thin film support substrate for use in hydrogen production filter and production method of hydrogen production filter |
8756812, | Oct 29 2004 | Air cooled heat shield |
Patent | Priority | Assignee | Title |
5824435, | Jun 22 1995 | Matsushita Electric Industrial Co., Ltd. | Non-sintered type nickel electrode |
5902692, | Oct 30 1996 | Sulzer Hexis AG | Battery with planar high temperature fuel cells |
6455201, | Oct 03 1996 | Katayama Special Industries, Ltd. | Method of manufacturing battery electrode substrate and battery electrode substrate |
6555246, | Feb 02 1999 | AUTONEUM INTERNATIONAL AG | Method of producing a sound-absorbent insulating element and insulating element produced according to this method |
EP840388, | |||
EP926752, | |||
EP1289034, | |||
JP10106580, | |||
JP9265991, | |||
JP97603, | |||
WO101212, | |||
WO191212, |
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