A semiconductor device typified by a wireless tag, which has improved mechanical strength, can be formed by a more simple process at a low cost and prevent radio waves from being shielded, and a manufacturing method of the semiconductor device. According to the invention, a wireless tag includes a thin film integrated circuit formed of an isolated TFT having a thin film semiconductor film. The wireless tag may be attached directly to an object, or attached to a flexible support such as plastic and paper before being attached to an object. The wireless tag of the invention may include an antenna as well as the thin film integrated circuit. The antenna allows to communicate signals between a reader/writer and the thin film integrated circuit, and to supply a power source voltage from the reader/writer to the thin film integrated circuit.
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15. A semiconductor device comprising:
a flexible substrate;
a first antenna provided on the flexible substrate;
a second antenna provided on the flexible substrate; and
a integrated circuit provided between the first antenna and the second antenna, the integrated circuit being electrically connected to the first antenna,
wherein the flexible substrate is folded along a fold line so that the second antenna is electrically connected to the first antenna.
1. A semiconductor device comprising:
a flexible substrate;
a first antenna provided over the flexible substrate;
a second antenna provided over the flexible substrate; and
an integrated circuit provided over the flexible substrate, the integrated circuit being electrically connected to the first antenna,
wherein the flexible substrate is configured to be folded along a fold line so that the second antenna is electrically coupled connected to the first antenna.
8. A semiconductor device comprising:
a flexible substrate;
a first antenna provided over the flexible substrate;
a second antenna provided over the flexible substrate; and
and integrated circuit provided over the flexible substrate, integrated circuit being electrically connected to the first antenna,
wherein the flexible substrate is configured to be folded along a fold line so that the second antenna is electrically connected to the first antenna, and
wherein the integrated circuit comprises a transistor comprising a semiconductor film.
22. A semiconductor device comprising:
a flexible substrate;
a first antenna provided on the flexible substrate; and
a second antenna provided on the flexible substrate; and
an integrated circuit provided between the first antenna and the second antenna, the integrated circuit being electrically connected to the first antenna,
wherein the flexible substrate is folded along a fold line so that the second antenna is electrically connected to the first antenna, and
wherein the integrated circuit comprises a transistor comprising a semiconductor film.
2. The semiconductor device according to
wherein a part of the integrated circuit is provided over the first antenna.
3. The semiconductor device according to
wherein the first antenna includes a first terminal, and the second antenna includes a second terminal, and
wherein the first terminal and the second terminal are electrically connected.
4. The semiconductor device according to
5. The semiconductor device according to
wherein a part of the first antenna is covered with an insulating resin.
6. The semiconductor device according to
7. The semiconductor device according to
wherein the flexible substrate is configured to be folded so that the first antenna, the second antenna and the integrated circuit are put inside the flexible substrate.
9. The semiconductor device according to
wherein a part of the integrated circuit is provided over the first antenna.
10. The semiconductor device according to
wherein the first antenna includes a first terminal, and the second antenna includes a second terminal, and
wherein the first terminal and the second terminal are electrically connected.
11. The semiconductor device according to
12. The semiconductor device according to
wherein a part of the first antenna is covered with an insulating resin.
13. The semiconductor device according to
14. The semiconductor device according to
wherein the flexible substrate is configured to be folded so that the first antenna, the second antenna and the integrated circuit are put inside the flexible substrate.
16. The semiconductor device according to
wherein a part of the integrated circuit is provided between the first antenna and the second antenna.
17. The semiconductor device according to
wherein the first antenna includes a first terminal, and the second antenna includes a second terminal, and
wherein the first terminal and the second terminal are electrically connected.
18. The semiconductor device according to
19. The semiconductor device according to
wherein a part of the first antenna is covered with an insulating resin.
20. The semiconductor device according to
21. The semiconductor device according to
wherein the flexible substrate is configured to be folded so that the first antenna, the second antenna and the integrated circuit are put inside the flexible substrate.
23. The semiconductor device according to
wherein a part of the integrated circuit is provided between the first antenna and the second antenna.
24. The semiconductor device according to
wherein the first antenna includes a first terminal, and the second antenna includes a second terminal, and
wherein the first terminal and the second terminal are electrically connected.
25. The semiconductor device according to
26. The semiconductor device according to
27. The semiconductor device according to
28. The semiconductor device according to
wherein the flexible substrate is configured to be folded so that the first antenna, the second antenna and the integrated circuit are put inside the flexible substrate.
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1. Field of the Invention
The present invention relates to a semiconductor device capable of communicating wirelessly and a manufacturing method of the semiconductor device.
2. Description of the Related Art
A semiconductor device typified by a wireless tag capable of wirelessly communicating identification data or the like has been put into practical use in various fields, and the market thereof is likely to further increase as a new type of communication information terminal. The wireless tag is also called an RFID (Radio Frequency Identification) tag or an IC tag. The wireless tag in practical use usually has an antenna and an IC chip formed by using a semiconductor substrate.
An AC signal received by an antenna is rectified by a rectifier element such as a diode in a wireless tag, and then sent to the subsequent stages. In general, a transistor is used as the diode for rectification. A signal from the wireless tag can be read from the change in the impedance of the antenna caused by controlling a voltage applied to the antenna in the wireless tag. A transistor is also used as a switching element for controlling a voltage applied to the antenna.
In the case of such a transistor used as a diode or a switching element being formed by using a semiconductor substrate, there is a problem in that a large amount of current flows between a P-type base region and a drain region of the transistor depending on the polarity of an AC signal. The mechanism thereof is specifically described with reference to
Accordingly, in the case of a potential supplied from the antenna 7005 to the N-type region 7003 being higher than the ground potential, a current does not flow easily from the N-type region 7003 to the P-type base region 7001. Meanwhile, in the case of a potential supplied from the antenna 7005 to the N-type region 7003 being lower than the ground potential, a current flows easily from the P-type base region 7001 to the N-type region 7003, which may lead to the degradation or even destruction of the transistor 7002.
In order to solve the aforementioned problem, Patent Document 1 discloses a structure in which a guard band applied with a bias through high resistance is provided at the periphery of a MOSFET.
[Patent Document 1] Japanese Patent Laid-Open No. 2000-299440
In the case of Patent Document 1, however, a guard band prevents high integration, and an increase in chip size is inevitable. Since the cost per area of a semiconductor substrate is higher than that of a glass substrate, the increase in chip size leads to an increase in cost per chip.
In addition, the wireless tag may be attached to a flexible material such as paper and plastic depending on the application, though the semiconductor substrate has a lower mechanical strength as compared with the aforementioned materials. Reduction in the area of the wireless tag itself allows the mechanical strength to increase to some extent. However, in that case, it is difficult to maintain the circuit scale and antenna gain. Particularly when the antenna gain is reduced, the communication distance is reduced and the application of the wireless tag is undesirably limited. Therefore, in view of the circuit scale of an IC chip and the antenna gain, the area of the wireless tag cannot be reduced randomly, leading to limit to the improvement of mechanical strength.
Further in the case of an IC chip formed by using a semiconductor substrate, the semiconductor substrate functions as a conductor to shield radio waves. Thus, there is a problem in that signals are easily attenuated depending on the direction of transmitted radio waves.
In view of the foregoing problems, the invention provides a semiconductor device typified by a wireless tag, which has improved mechanical strength, can be formed by a more simple process at a low cost and prevent radio waves from being shielded. The invention further provides a manufacturing method of the semiconductor device.
According to the invention, a device using an integrated circuit (hereinafter referred to as a thin film integrated circuit) formed of isolated TFTs (thin film transistors) each having a semiconductor thin film is referred to as a semiconductor device. Such a semiconductor device is used for a wireless tag (also called a wireless chip). The wireless tag may be attached directly to an object or may be attached onto a flexible support such as plastic and paper before being attached to the object. The wireless tag according to the invention can include an antenna as well as a thin film integrated circuit. The antenna allows to communicate signals between a reader/writer and a thin film integrated circuit, and to supply a power source voltage from the reader/writer to the thin film integrated circuit.
The antenna may be formed integrally with the thin film integrated circuit to be attached to an object or a flexible support. Alternatively, the antenna may be formed separately from the thin film integrated circuit to be attached to an object or a flexible support with the thin film integrated circuit. Instead, the antenna may be formed onto an object or a flexible support in advance, and the thin film integrated circuit may be attached to the object or the flexible support so as to be electrically connected to the antenna.
The thin film integrated circuit can be attached by various methods: a method in which a thin film integrated circuit is formed over a high heat resistant substrate with a metal oxide film interposed therebetween, and the metal oxide film is weakened by crystallization, thereby the thin film integrated circuit is peeled off to be attached; a method in which a thin film integrated circuit is formed over a high heat resistant substrate with an amorphous silicon film containing hydrogen interposed therebetween, and the amorphous silicon film is removed by laser irradiation or etching, thereby the thin film integrated circuit is peeled off from the substrate to be attached; a method in which a thin film integrated circuit is formed on a high heat resistant substrate, and the substrate is removed mechanically or by etching with the use of solution or gas, thereby the thin film integrated circuit is peeled off from the substrate to be attached; and the like.
The wireless tag of the invention may include a substrate that is removed when peeling off a thin film integrated circuit.
In addition, thin film integrated circuits formed separately may be attached and stacked to increase the circuit scale and the memory capacity. A thin film integrated circuit is drastically reduced in thickness as compared with an IC chip formed by using a semiconductor substrate. Therefore, the mechanical strength of the wireless tag can be maintained to some extent even when a plurality of thin film integrated circuits are stacked. The stacked thin film integrated circuits can be connected to each other by any known method such as flip chip technology, TAB (Tape Automated Bonding), and wire bonding.
Since the wireless tag of the invention uses a thin film integrated circuit formed of an isolated TFT, a parasitic diode is not easily formed between a substrate and the TFT, which differs from a transistor formed on a semiconductor substrate. Accordingly, a large amount of current does not flow into a drain region depending on the potential of an AC signal supplied to a source region or the drain region, which prevents the degradation or destruction.
By attaching the wireless tag directly to an object or onto a flexible support, the form of the wireless tag can be modified depending on the form of the object, resulting in increased versatility.
The wireless tag of the invention can have improved mechanical strength while not making the area thereof smaller than that of a conventional wireless tag using a semiconductor substrate. As a result, it becomes easy to ensure the antenna gain, increase the communication distance, and increase the versatility of the wireless tag.
In general, a wireless tag uses radio waves with a frequency of 13.56 MHz or 2.45 GHz. Therefore, in order to be widely used, a wireless tag is required to be formed so as to detect radio waves with these frequencies.
The wireless tag of the invention has the advantage in that radio waves are less shielded in a thin film integrated circuit as compared with in an IC chip formed by using a semiconductor substrate, thereby signal attenuation due to shielded radio waves can be prevented. Accordingly, the diameter of an antenna can be reduced as compared with in the case of an IC chip.
Without requiring a semiconductor substrate, the cost of the wireless tag can be drastically reduced. For example, the case of using a silicon substrate with a diameter of 12 inches is compared with the case of using a glass substrate with a size of 730×920 mm2. The silicon substrate has an area of about 73000 mm2 whereas the glass substrate has an area of about 672000 mm2, that is, the glass substrate is about 9.2 times as large as the silicon substrate. On the glass substrate with an area of about 672000 mm2, about 672000 wireless tags each having an area of 1 mm square can be formed when taking no account of margin for cutting the substrate, which is about 9.2 times as many as the wireless tags formed on the silicon substrate. In the case of using the glass substrate with a size of 730×920 mm2, which requires fewer manufacturing steps, the amount of capital investment in mass production of wireless tags can be reduced to one-third of that in the case of using the silicon substrate with a diameter of 12 inches. Further, according to the invention, after a thin film integrated circuit is peeled off from a glass substrate, the glass substrate can be reused. Therefore, the cost in the case of using the glass substrate can be significantly reduced as compared with in the case of using the silicon substrate, even taking into account the cost of repairing a broken glass substrate or cleaning a surface of the glass substrate. The invention also relates to a wireless tag in which a thin film integrated circuit formed on a substrate is not peeled off yet. In the case of shipping such a wireless tag before being peeled off, the cost of the glass substrate used as a material influences the cost of the wireless tag largely. However, the glass substrate with a size of 730×920 mm2 costs about half as much as the silicon substrate with a diameter of 12 inches.
As is evident from the foregoing, a wireless tag using a glass substrate with a size of 730×920 mm2 costs only about one-thirtieth as much as a wireless tag using a silicon substrate with a diameter of 12 inches. Since the wireless tag is expected to be used as the disposable one, the wireless tag of the invention that can cost much less is quite effective for such application.
The wireless tag of the invention includes a thin film integrated circuit that operates with an AC signal supplied from an antenna. The wireless tag of the invention may also include an antenna as well as the thin film integrated circuit. In that case, the antenna may be formed integrally with or separately from the thin film integrated circuit. The thin film integrated circuit may be attached directly to an object or may be attached to a flexible support before being attached to the object. A configuration of the wireless tag of the invention is described with reference to
Although the thin film integrated circuit 101 and the antenna 102 are attached directly to the object 103 in
The droplet ejection means a method of forming a predetermined pattern by ejecting from pores a droplet containing a predetermined composition, and includes ink-jet printing and the like.
Although the thin film integrated circuit 111 is attached so as to be stacked on the antenna 112 in
In addition, the order of stacking the thin film integrated circuit 111 and the antenna 112 is not limited to the one shown in
Furthermore, although only the antenna 112 is attached to the flexible support 114 in
Also in
Alternatively, the thin film integrated circuit 121 may be formed on a support that is prepared separately, and then attached onto the object 123. In that case, the attachment of the wireless tag to the object can be more simplified, resulting in increased versatility of the wireless tag.
In the case of a flexible support being used, a wireless tag can be formed so that an antenna or a thin film integrated circuit is surrounded by or put in the flexible support. A configuration of a wireless tag formed by using a folded support is described with reference to
In
In order to prevent the overlapped portion of the antenna 201 from being connected by folding, the antenna 201 and the thin film integrated circuit 205 may be covered with resin or the like with insulating properties.
Depending on the thickness of the support 202, the support 202 is compressed at a periphery 208 of the dashed line 203 as the fold line, and the antenna 201 is broken. In order to prevent the breaking of the antenna 201, a depression 209 may be formed along the dashed line 203 as the fold line inside the support 202 as shown in
In addition, as shown in
Note that in order to prevent the breaking, the antenna desirably crosses the fold line at as few points as possible. Instead, the antenna may be formed so as not to cross the fold line to prevent the breaking.
In a thin film integrated circuit according to the invention, radio waves are less shielded as compared with in an IC chip formed by using a semiconductor substrate. Therefore, even when the thin film integrated circuit is put in or surrounded by the antenna 201 as shown in
Although one side of the wireless tag is closed by folding the support in
In addition, the antenna 201 crosses the dashed line 203 as the fold line in
In the case of
Alternatively, the overlapped portion in folding the antennas 321 and 322 may be insulated with an insulating film used in a thin film integrated circuit.
Although the two antennas are connected by folding the support in
Next, an example of a functional configuration of the wireless tag of the invention is described with reference to
Reference numeral 400 denotes an antenna and 401 denotes a thin film integrated circuit. The antenna 401 includes an antenna coil 402 and a capacitor 403 formed in the antenna coil 402. The thin film integrated circuit 401 includes a demodulation circuit 409, a modulation circuit 404, a rectification circuit 405, a microprocessor 406, a memory 407, and a switch 408 for supplying a load to the antenna 400. Note that the memory 407 is not limited to one and a plurality of memories may be provided.
A signal transmitted from a reader/writer as radio waves is converted into an AC electrical signal by electromagnetic induction in the antenna coil 402. The AC electrical signal is demodulated in the demodulation circuit 409 and transmitted to the microprocessor 406 in the subsequent stage. Further, a power source voltage is generated by the AC electrical signal in the rectification circuit 405, and supplied to the microprocessor 406 in the subsequent stage.
In the microprocessor 406, various types of processing are performed in accordance with inputted signals. The memory 407 can be used not only for storing program, data and the like used in the microprocessor 406 but also as a work area in processing. A signal transmitted from the microprocessor 406 to the modulation circuit 404 is modulated into an AC electrical signal. The switch 408 can apply a load to the antenna coil 402 in accordance with the AC electrical signal from the modulation circuit 404. The reader/writer receives the load applied to the antenna coil 402 by radio waves, thereby reading a signal from the microprocessor 406 effectively.
The aforementioned configuration of the wireless tag shown in
A manufacturing method of the wireless tag of the invention is described with reference to
First, as shown in
After the metal film 501 being formed, an oxide film 502 as an insulating film is laminated thereon without being exposed to the atmosphere. The oxide film 502 is formed of a silicon oxide film with a thickness of 150 to 300 nm. In the case of the sputtering being adopted, the deposition is performed also on an edge of the first substrate 500. Therefore, in order to prevent the oxide film 502 from remaining on the first substrate 500 in the subsequent peeling step, it is preferable to selectively remove the metal film 501 and the oxide film 502 that are formed on the edge of the first substrate 500 by O2 ashing and the like.
When forming the oxide film 502, presputtering is performed as the preliminary step of the sputtering, in which a target and the substrate are blocked off to generate plasma. The presputtering is performed by using Ar at a flow rate of 10 sccm and O2 at a flow rate of 30 sccm while maintaining the first substrate 500 at a temperature of 270° C. and a deposition power at 3 kW. By the presputtering, an ultrathin metal oxide film 503 with a thickness of a few nanometers (3 nm herein) is formed between the metal film 501 and the oxide film 502. The metal oxide film 503 is obtained by oxidizing a surface of the metal film 501, thus the metal oxide film 503 is formed of tungsten oxide in
Although the metal oxide film 503 is formed by presputtering in
After the oxide film 502 being formed, a base film 504 as an insulating film is formed by PCVD. The base film 504 is formed of a silicon oxynitride film with a thickness of about 100 nm. Then, after the base film 504 being formed, a semiconductor film 505 is formed without being exposed to the atmosphere. The semiconductor film 505 is formed so as to have a thickness of 20 to 200 nm (preferably 40 to 170 nm). Note that the semiconductor film 505 may be an amorphous semiconductor, a microcrystalline semiconductor (including a semi-amorphous semiconductor), or a polycrystalline semiconductor. In addition, not only silicon but also silicon germanium may be used as a semiconductor. In the case of the silicon germanium being used, germanium preferably has a concentration of about 0.01 to 4.5 atomic %.
The semiconductor film 505 may be crystallized by a known method such as thermal crystallization using an electric furnace, laser crystallization using laser light, and a lamp anneal crystallization using infrared light. Alternatively, crystallization using a catalytic element may also be performed based on the method disclosed in Japanese Patent Laid-Open No. 7-130652.
It is possible to obtain a crystal with a large grain size when second to fourth harmonics of a fundamental harmonic are used with a continuous wave solid-state laser. Typically, it is preferable to use the second harmonic (532 nm) or the third harmonic (355 nm) of an Nd:YVO4 laser (fundamental harmonic: 1064 nm). More specifically, laser light emitted from a continuous wave YVO4 laser is converted to the harmonic with a non-linear optical element to obtain laser light having an output of 10 W. More preferably, the laser light is formed so as to be a rectangular shape or an elliptical shape by an optical system, and irradiated on a surface of the semiconductor film 505. At this time, an energy density of about 0.01 to 100 MW/cm2 (preferably 0.1 to 10 MW/cm2) is required. The laser light is irradiated at a scan rate of about 10 to 2000 cm/sec.
Alternatively, the laser crystallization may be performed by using pulsed laser light with a oscillation frequency of 10 MHz or more which is a much higher frequency than that of tens to hundreds of Hz of a normally used pulsed laser. It is said that it takes tens to hundreds of nsec to completely solidify a semiconductor film after irradiating pulsed laser light thereto. Accordingly, by using the aforementioned frequency range, pulsed laser light can be irradiated before a semiconductor film dissolved by the preceding laser light becomes solidified. Thus, solid-liquid interface can be sequentially moved in a semiconductor film, thereby forming a semiconductor film having crystal grains that are sequentially grown in the scan direction. More specifically, a group of crystal grains each having a grain width of 10 to 30 μm in the scan direction and 1 to 5 μm in the direction perpendicular to the scan direction can be obtained. Accordingly, single crystal grains extending along the scan direction are formed, and a semiconductor film with few crystal grain boundaries at least in the channel length of a TFT can be achieved.
In the laser crystallization, continuous wave fundamental laser light and continuous wave harmonic laser light may be irradiated, or continuous wave fundamental laser light and harmonic pulsed laser light may be irradiated.
The laser irradiation may be performed in an inert gas atmosphere such as a noble gas and an inert gas such as nitrogen. According to this, unevenness of a surface of a semiconductor due to laser irradiation can be suppressed, which prevents variations in threshold caused by variations in interface state density.
According to the aforementioned laser irradiation to the semiconductor film 505, the crystallinity of the semiconductor film can be much improved. Note that as the semiconductor film 505, a polycrystalline semiconductor may be formed in advance by sputtering, plasma CVD, thermal CVD and the like.
Although the semiconductor film is crystallized in
The semi-amorphous semiconductor is a semiconductor having an intermediate structure between amorphous and crystalline (including single crystalline and polycrystalline) structures. This semiconductor has a third state that is stable in free energy, and it is a kind of a crystalline semiconductor that has a short range order and a lattice distortion. The semi-amorphous semiconductor film with crystal grains of 0.5 to 20 nm can be dispersed in an amorphous semiconductor and Raman spectrum is shifted to the lower frequency band than 520 cm−1. The semi-amorphous semiconductor has an x-ray diffraction pattern with peaks at (111) and (220) that are considered to be due to Si crystal lattice. Further, the semiconductor is mixed with at least 1 atom % of hydrogen or halogen as the neutralizing agent for dangling bond. Such a semiconductor is called herein a semi-amorphous semiconductor (SAS) for convenience. When a noble gas element such as helium, argon, krypton, or neon is mixed into an SAS, the lattice distortion is increased and the stability is thus enhanced, leading to a high quality SAS.
Subsequently, the semiconductor film 505 is patterned to form island-shaped semiconductor films 507 and 508 with which various semiconductor elements typified by a TFT are formed. Although the island-shaped semiconductor films 507 and 508 are formed directly on the base film 504 in
In
After the gate insulating film 511 being formed, the island-shaped semiconductor films 507 and 508 may be hydrogenated by heat treatment at a temperature of 300 to 450° C. for 1 to 12 hours in an atmosphere containing 3 to 100% of hydrogen. The hydrogenation may also be performed by plasma hydrogenation (using hydrogen excited by plasma). This hydrogenation step allows to terminate dangling bonds of the semiconductor film by thermally excited hydrogen. In addition, even when a defect occurs in a semiconductor film by bending a flexible support on which a semiconductor element is attached in the subsequent step, since the semiconductor film includes hydrogen with a concentration of 1×1019 to 5×1021 atoms/cm3 by the hydrogenation, the defect can be terminated by hydrogen included in the semiconductor film. Further, the semiconductor film may include halogen to terminate the defect.
The manufacturing method of the TFT is not limited to the aforementioned one.
Subsequently, a first interlayer insulating film 514 is formed so as to cover the TFTs 509 and 510. After contact holes are formed in the gate insulating film 511 and the first interlayer insulating film 514, wirings 515 to 518 are formed directly on the first interlayer insulating film 514 so as to be connected to the TFTs 509 and 510 through the contact holes.
Then, a second interlayer insulating film 519 is formed on the first interlayer insulating film 514 so as to cover the wirings 515 to 518. After a contact hole is formed in the second interlayer insulating film 519, a connecting terminal 520 is formed directly on the second interlayer insulating film 519 so as to be connected to the wiring 518 through the contact hole. The first interlayer insulating film 514 and the second interlayer insulating film 519 may be formed of an organic resin film, an inorganic insulating film, an insulating film that is formed of a siloxane based material and includes Si—O—Si bonding (hereinafter a siloxane based insulating film), and the like. The siloxane based insulating film may include a hydrogen substituent as well as a material that has one or more substituents selected from fluorine, an alkyl group, and aromatic hydrocarbon. The siloxane based insulating film has heat resistance to a wire using a material having a high melting point such as gold, thus it is effectively used for wire bonding.
Next, as shown in
A plastic substrate can be used for the flexible second substrate 523, for example. As the plastic substrate, ARTON (product of JSR) formed of polynorbornene having a polar group can be used. It is also possible to use polyester typified by polyethylene terephthalate (PET), polyether sulfone (PES), polyethylene naphthalate (PEN), polycarbonate (PC), nylon, polyether ether ketone (PEEK), polysulfone (PSF), polyether imide (PEI), polyarylate (PAR), polybutylene terephthalate (PBT), polyimide, acrylonitrile butadiene styrene resin, polyvinyl chloride, polypropylene, polyvinyl acetate, acrylic resin and the like. The second substrate 523 desirably has high thermal conductivity of about 2 to 30 W/mK in order to diffuse the heat generated from a thin film integrated circuit.
A method of increasing the adhesiveness specifically includes a method of attaching to the surface of the second substrate 523 a metal or a metal compound for increasing the adhesiveness of a conductive film or an insulating film by catalysis, a method of attaching to the surface of the second substrate 523 an organic insulating film, a metal, or a metal compound with increased adhesiveness to a conductive film or an insulating film, a method of applying plasma treatment to the surface of the second substrate 523 in an atmospheric pressure or a reduced pressure to modify the surface, and the like. The metal with increased adhesiveness to a conductive film or an insulating film includes titan and titan oxide as well as a 3d transition element such as Sc, Ti, V, Cr, Mn, Fe, Co, Ni, Cu, and Zn. The metal compound includes the oxide, nitride, and oxynitride of these metals. The organic insulating film includes polyimide, a siloxane based insulating film and the like. The siloxane based insulating film may include a hydrogen substituent as well as a material that has one or more substituents selected from fluorine, an alkyl group, and aromatic hydrocarbon.
In the case where the metal or the metal compound attached to the second substrate 523 has conductivity, the sheet resistance thereof is controlled in order not to prevent normal operation of the antenna 522. Specifically, the metal or the metal compound with conductivity is controlled to have an average thickness of 1 to 10 nm for example, or the metal or the metal compound is insulated partially or entirely by oxidization. Alternatively, the metal or the metal compound may be selectively removed by etching except for a region required to have increased adhesiveness. Instead, the metal or the metal compound is not attached to the entire surface of the substrate but selectively attached only to a predetermined region by droplet ejection, printing, sol-gel method and the like. Note that the metal or the metal compound formed on the surface of the second substrate 523 is not required to be a completely continuous film and may be dispersed to some extent.
In this embodiment mode, a photocatalyst such as ZnO and TiO2 is attached to the surface of the second substrate 523 to increase the adhesiveness by a photocatalytic reaction. More specifically, ZnO or TiO2 dispersed in a solvent is sprayed on the surface of the second substrate 523. Alternatively, a ZnO compound or a Ti compound is attached to the surface of the second substrate 523 and then oxidized or processed by sol-gel method, thereby ZnO or TiO2 can be attached to the surface of the second substrate 523. Subsequently, by droplet ejection or various printing methods, the antenna 522 is formed on the surface of the second substrate 523 to which the pretreatment for increasing the adhesiveness has been performed. More specifically, the antenna 522 can be formed of a conductive material including one or more metals selected from Ag, Au, Cu, and Pd or metal compounds. It is also possible to use a conductive material including one or more metals selected from Cr, Mo, Ti, Ta, W, and Al or metal compounds as long as the aggregation thereof can be suppressed to be dispersed in a solution by a dispersant. Further, when a deposition of a conductive material by droplet ejection or various printing methods is performed plural times, a gate electrode with laminated conductive films can also be obtained. Alternatively, conductive particles of Cu coated with Ag can be employed as well.
In the case of the droplet ejection being adopted, the conductive material dispersed in an organic or inorganic solvent is ejected from a nozzle, then dried or baked at a room temperature to obtain the antenna 522. For example, in the case of polycarbonate being used for the second substrate 523, a solution of tetradecane dispersed with Ag is ejected and baked at a temperature of about 200° C. for 1 minute to 50 hours to remove the solvent, thereby the antenna 522 is formed. Note that Ag is preferably used for the antenna 522 since it costs less than Au and can meet environmental standards more easily than Cu. In the case of an organic solvent being used, the solvent can be removed efficiently by performing the baking in an oxide atmosphere, and the resistance of the antenna 522 can thus be further lowered.
After the solution in which the conductive material is dispersed is ejected, the ejected conductive material is pressed before baking, thereby the density of the conductive material in the antenna 522 can be increased and the film thickness can be controlled. Accordingly, the flexibility of the antenna 522 can be increased while the resistance can be further lowered.
In the case of the droplet ejection being adopted, patterning accuracy depends on the ejection rate per droplet, the surface tension of the solution, the water-shedding properties of the surface of the second substrate 523 to which a droplet is ejected, and the like. Therefore, these conditions are preferably optimized in accordance with a predetermined patterning accuracy.
Then, as shown in
Although the first substrate 500 and the second substrate 523 are attached with the anisotropic conductive resin 525 in
Next, preparatory step for the peel-off is conducted so that the adhesiveness between the metal oxide film 503 and the oxide film 502 or the adhesiveness between the metal oxide film 503 and the metal film 501 is partially weakened. Specifically, the preparatory step for the peel-off is performed by locally applying pressure from outside on the region to be peeled off along the periphery thereof so as to partially damage inside or an edge of the metal oxide film 503. In
Then, the metal film 501 and the oxide film 502 are physically detached, thereby the first substrate 500 is peeled off. The peel-off is started from a region in which the adhesiveness between the metal oxide film 503 and the metal film 501 or the adhesiveness between the metal oxide film 503 and the oxide film 502 is partially weakened in the preceding step.
According to the peel-off, the metal oxide film 503 is separated partially from the metal film 501, partially from the oxide film 502, and the metal oxide film 503 itself is partially separated into two sides. Thus, the semiconductor elements (the TFTs 509 and 510 herein) are detached from the first substrate 500 while being attached to the second substrate 523. The peel-off can be performed by relatively small force (for example, man's hand, air pressure of gas sprayed from a nozzle, ultrasonic waves or the like).
In the case of the rigidity of the first substrate 500 being low, the first substrate 500 may be damaged or the semiconductor elements may be overloaded in peeling. In that case, a third substrate may be additionally provided to add rigidity to the first substrate 500. More specifically, the third substrate is attached to the first substrate 500 with a two-sided tape, an adhesive and the like. For the third substrate, a substrate having higher rigidity than that of the first substrate 500, such as a quartz substrate and a semiconductor substrate, is preferably to be used.
Subsequently, as shown in
An adhesive may be used as the protective layer 530 and the semiconductor elements such as the TFTs 509 and 510 may be covered with a substrate that is additionally provided. In that case, the thin film integrated circuit using the semiconductor elements such as the TFTs 509 and 510 is disposed between the second substrate 523 and the substrate attached to the protective layer 530. For the adhesive, various types of curable adhesive, for example, a photocurable adhesive such as a reaction curable adhesive, a heat curable adhesive and a UV curable adhesive, or an anaerobic adhesive can be utilized.
Although the metal film 501 is formed of tungsten in
According to the aforementioned manufacturing method, the thin film integrated circuit can be drastically reduced in thickness to have a total thickness of 0.3 to 3 μm, and typically about 2 μm. In addition, by using the flexible substrate typified by a plastic substrate, mechanical strength of the wireless tag can be increased while reducing the thickness. Note that the thickness of the thin film integrated circuit includes the thickness of the insulating film formed between the metal oxide film and the semiconductor element and the thickness of the interlayer insulating film covering the semiconductor element as well as the thickness of the semiconductor element itself. Thus, the thickness of the thin film integrated circuit does not include the thicknesses of the second substrate 523 functioning as a support, the protective layer 530, the anisotropic conductive resin 525, and the antenna 522. The thin film integrated circuit occupies an area of 5 mm square or less, and more preferably 0.3 to 4 mm square.
When the thin film integrated circuit is disposed at the center of the total thickness of the protective layer 530, the anisotropic conductive resin 525 and the antenna 522 laminated over the second substrate 523, mechanical strength of the thin film integrated circuit can be increased. More specifically, on the assumption that the total thickness of the protective layer 530, the thin film integrated circuit, the anisotropic conductive resin 525, and the antenna 522 is d, the thicknesses of the protective layer 530, the anisotropic conductive resin 525 and the antenna 522 are preferably controlled so that the distance x between the second substrate 523 and the center of the thin film integrated circuit in the direction of the thickness satisfies the following formula 1.
Before the TFTs 509 and 510 are covered with the first interlayer insulating film 514, they may be covered with a silicon nitride film or a silicon nitride oxide film that is prepared separately. According to this, the TFTs 509 and 510 are covered with the base film 504 and the silicon nitride film or the silicon nitride oxide film. Therefore, an alkaline metal such as Na or an alkaline earth metal can be prevented from diffusing into a semiconductor film used for the semiconductor element and adversely affecting characteristics of the semiconductor element.
In the case where in order to maintain the flexibility of the wireless tag, an organic resin is used for the protective layer 530 that is in contact with the oxide film 502 and the metal oxide film 503, when a silicon nitride film or a silicon nitride oxide film is used as the base film 504, an alkaline metal such as Na or an alkaline earth metal can be prevented from diffusing from the organic resin into the semiconductor film through the oxide film 502.
A serial number marked on a semiconductor film or an insulating film used in the wireless tag allows to determine the distribution route thereof to some extent even when an IC card which does not store image data in a ROM yet is transferred to a third party due to theft or the like. In that case, it is more effective to mark the serial number on a position that cannot be erased unless a semiconductor device is decomposed to the extent that cannot be recomposed.
Further,
Further,
The attachment of a thin film integrated circuit is not limited to the one using a metal oxide film as shown in
For example, in the case of an amorphous silicon film being removed by etching, an amorphous silicon film with a thickness of about 1 μm is formed on a high heat resistant substrate. Then, on the amorphous silicon film, a silicon oxide film with a thickness of 100 nm is formed as a base film, and semiconductor elements such as TFTs are formed on the base film. After the semiconductor element is covered with a protective film such as an inorganic insulating film, an organic resin film and a siloxane based insulating film, the semiconductor elements are separated from each other by scribing so as to separate thin film integrated circuits from each other. The scribing is not required to be performed to the depth that separates the substrate but only required to be performed to the depth that separates the base film. Subsequently, the amorphous silicon film is etched by fluorine halide such as ClF3 and removed. The fluorine halide may be either a gas or a liquid. In that case, in order to protect the semiconductor elements from the fluorine halide, a silicon nitride film or a silicon nitride oxide film is preferably formed between the amorphous silicon film and the semiconductor elements. When the silicon nitride film or the silicon nitride oxide film is provided, an alkaline metal such as Na or an alkaline earth metal can be prevented from diffusing into semiconductor films used for the semiconductor elements and adversely affecting characteristics of the semiconductor elements. Through the aforementioned steps, the thin film integrated circuit can be peeled off from the substrate. The peeled thin film integrated circuit can be attached directly to a flexible support or an object.
In the case where an object has a curved surface and thus a support of a wireless tag attached to the curved surface is bent to have a curved surface drawn by a generating line such as pyramidal surface and a cylindrical surface, the direction of the generating line is preferably the same as that of carriers moving in TFTs. According to such a structure, it is possible to prevent characteristics of TFTs from being adversely affected by the bent support. In addition, when island-shaped semiconductor films occupy 5 to 30% of the area in a thin film integrated circuit, it is possible to further prevent characteristics of TFTs from being adversely affected by the bent support.
Described in this embodiment is an example of forming a plurality of wireless tags by using a large substrate.
Then, as shown in
In this embodiment, applications of the wireless tag of the invention are described.
The wireless tag of the invention can be applied to various fields. For example, the wireless tag of the invention can be attached to a product label to control the flow of product.
As shown in
Identification data of the product 1104 can be wirelessly read from the wireless tag 1102 attached to the label 1103 as shown in
For example, in the case of a nonvolatile memory being used as a memory of a thin film integrated circuit in the wireless tag 1102, the distribution process of the product 1104 can be recorded. In addition, when the production process of the product is recorded, a wholesaler, a retailer and a consumer can easily find out a production area, a producer, a date of manufacture, a processing method and the like.
This embodiment shows only an example of the application of the wireless tag of the invention. The application of the wireless tag of the invention is not limited to the one shown in
In this embodiment, applications of the wireless tag of the invention are described.
When a thin film integrated circuit in the wireless tag of the invention includes a memory such as a ROM in which data cannot be rewritten, it is possible to prevent forgery of bills, checks, family registers, resident cards, traveler's checks, passports and the like. Further, when the wireless tag is used for foods whose commercial value depends crucially on a production area, a producer and the like, the forgery of production area, producer and the like can be prevented at low cost.
Since the wireless tag of the invention is inexpensive and small, it is effectively used as the disposable one that is thrown away by a consumer. In particular, the inexpensive and small wireless tag of the invention is quite effective for a product increase in the price of which by a few yens or a few tens of yens has an effect on sales.
The form of the wireless tag of the invention can be changed to some extent in accordance with the form of an object attached with the wireless tag. In addition, the wireless tag of the invention can exhibit improved mechanical strength as compared with a wireless tag using an IC chip. Thus, the application range of the wireless tag of the invention is not limited to the one shown in this embodiment, and other various applications are possible.
This application is based on Japanese Patent Application serial No. 2003-414848 filed in Japan Patent Office on Dec. 12, 2003, and Japanese Patent Application serial No. 2004-009529 filed in Japan Patent Office on Jan. 16, 2004, the contents of which are hereby incorporated by reference.
Although the present invention has been fully described by way of Embodiment Modes and Embodiments with reference to the accompanying drawings, it is to be understood that various changes and modifications will be apparent to those skilled in the art. Therefore, unless such changes and modifications depart from the scope of the present invention hereinafter defined, they should be constructed as being included therein.
Yamazaki, Shunpei, Akiba, Mai, Koyama, Jun
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