The film for back surface of flip-chip semiconductor according to the present invention is a film for back surface of flip-chip semiconductor to be formed on a back surface of a semiconductor element having been flip-chip connected onto an adherend, wherein a tensile storage elastic modulus at 23° C. after thermal curing is 10 gpa or more and not more than 50 gpa. According to the film for back surface of flip-chip semiconductor of the present invention, since it is formed on the back surface of a semiconductor element having been flip-chip connected onto an adherend, it fulfills a function to protect the semiconductor element. In addition, since the film for back surface of flip-chip semiconductor according to the present invention has a tensile storage elastic modulus at 23° C. after thermal curing of 10 gpa or more, a warp of the semiconductor element generated at the time of flip-chip connection of a semiconductor element onto an adherend can be effectively suppressed or prevented.
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1. A film for back surface of flip-chip semiconductor, which is to be formed on a back surface of a semiconductor element flip-chip connected onto an adherend, comprising at least a layer formed of at least a thermosetting resin component and a thermoplastic resin component having a glass transition temperature of 25° C. or higher and not higher than 200° C.,
wherein a tensile storage elastic modulus at 23° C. after thermal curing is 10 gpa or more and not more than 50 gpa.
2. The film for back surface of flip-chip semiconductor according to
3. The film for back surface of flip-chip semiconductor according to
4. The film for back surface of flip-chip semiconductor according to
5. The film for back surface of flip-chip semiconductor according to
6. The film for back surface of flip-chip semiconductor according to
7. The film for back surface of flip-chip semiconductor according to
8. The film for back surface of flip-chip semiconductor according to
9. The film for back surface of flip-chip semiconductor according to
10. A dicing tape-integrated film for back surface of semiconductor, which comprises:
a dicing tape including a base material and a pressure-sensitive adhesive layer laminated on the base material; and
the film for back surface of flip-chip semiconductor according to
wherein the film for back surface of flip-chip semiconductor is laminated on the pressure-sensitive adhesive layer.
11. A method for manufacturing a semiconductor device using the dicing tape-integrated film for back surface of semiconductor according to
a step of sticking a semiconductor wafer onto the film for back surface of flip-chip semiconductor in the dicing tape-integrated film for back surface of semiconductor;
a step of dicing the semiconductor wafer to form a semiconductor element;
a step of peeling off the semiconductor element together with the film for back surface of flip-chip semiconductor from the pressure-sensitive adhesive layer of the dicing tape; and
a step of flip-chip connecting the semiconductor element onto an adherend.
12. The method for manufacturing a semiconductor device according to
13. A flip-chip semiconductor device manufactured by the method for manufacturing a semiconductor device according to
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The present invention relates to a film for back surface of flip-chip semiconductor and a dicing tape-integrated film for back surface of semiconductor. The film for back surface of flip-chip semiconductor is used for the purposes of protecting a back surface of a semiconductor element such as a semiconductor chip, etc. and improving strength thereof, and the like. In addition, the present invention relates to a method for manufacturing a semiconductor device using a dicing tape-integrated film for back surface of semiconductor and a flip-chip-mounted semiconductor device.
In recent years, thinning and miniaturization of a semiconductor device and its package have been increasingly demanded. Therefore, as the semiconductor device and its package, flip-chip semiconductor devices in which a semiconductor element such as a semiconductor chip, etc. is mounted (flip-chip connected) on a substrate by means of flip-chip bonding have been widely utilized. In such flip-chip connection, a semiconductor chip is fixed to a substrate in a form where a circuit face of the semiconductor chip is opposed to an electrode-formed face of the substrate. In such a semiconductor device or the like, there may be the case where the back surface of the semiconductor chip is protected with a protective film to prevent the semiconductor chip from damaging or the like.
However, for the purpose of protecting the back surface of a semiconductor chip with the foregoing protective film, it is required to add a new step of sticking a protective film onto a back surface of a semiconductor chip obtained in a dicing step. As a result, the number of processing steps increases, so that the manufacturing costs and the like increase. In addition, the recent tendency toward thinning may possibly bring about a problem in that the semiconductor chips are damaged in a picking-up step of the semiconductor chips. Accordingly, until the picking-up step, semiconductor wafers or semiconductor chips are required to be reinforced for the purpose of increasing the mechanical strength thereof. In particular, there may be the case where a warp is generated on the semiconductor chip due to thinning of the semiconductor chip, and suppression or prevention thereof is demanded.
Patent Document 1: JP-A-2008-166451
Patent Document 2: JP-A-2008-006386
Patent Document 3: JP-A-2007-261035
Patent Document 4: JP-A-2007-250970
Patent Document 5: JP-A-2007-158026
Patent Document 6: JP-A-2004-221169
Patent Document 7: JP-A-2004-214288
Patent Document 8: JP-A-2004-142430
Patent Document 9: JP-A-2004-072108
Patent Document 10: JP-A-2004-063551
However, for the purpose of protecting the back surface of a semiconductor chip with the foregoing protective film, it is required to add a new step of sticking a protective film onto a back surface of a semiconductor chip obtained in a dicing step. As a result, the number of processing steps increases, so that the manufacturing costs and the like increase. In addition, the recent tendency toward thinning may possibly bring about a problem in that the semiconductor chips are damaged in a picking-up step of the semiconductor chips. Accordingly, until the picking-up step, semiconductor wafers or semiconductor chips are required to be reinforced for the purpose of increasing the mechanical strength thereof. In particular, there may be the case where a warp is generated on the semiconductor chip due to thinning of the semiconductor chip, and suppression or prevention thereof is demanded.
In view of the foregoing problems, the present invention has been made, and an object thereof is to provide a film for back surface of flip-chip semiconductor and a dicing tape-integrated film for back surface of semiconductor, each of which is able to suppress or prevent the generation of a warp on a semiconductor element having been flip-chip connected onto an adherend.
In addition, another object of the present invention is to provide a method for manufacturing a semiconductor device in which a semiconductor element can be flip-chip connected onto an adherend while suppressing the generation of a warp, resulting in making it possible to improve the yield.
In order to solve the foregoing conventional problems, the inventors of the present application have made extensive and intensive investigations. As a result, it has been found that by controlling a tensile storage elastic modulus at 23° C. after thermal curing, the generation of a warp on a semiconductor element having been flip-chip connected onto an adherend can be reduced, leading to accomplishment of the present invention.
Specifically, the film for back surface of flip-chip semiconductor according to the present invention is a film for back surface of flip-chip semiconductor, which is to be formed on a back surface of a semiconductor element flip-chip connected onto an adherend, wherein a tensile storage elastic modulus at 23° C. after thermal curing is 10 GPa or more and not more than 50 GPa.
In flip-chip mounting, it is general that a molding resin for encapsulating the whole of a semiconductor package is not used, but only a bump connecting portion between an adhered and a semiconductor element is encapsulated with an encapsulating resin called an underfill. Therefore, the back surface of the semiconductor element is bared. Here, for example, at the time of thermal curing of the encapsulating resin, there may be the case where a stress is applied to the semiconductor element due to the cure shrinkage, and a warp is generated due to this stress on the semiconductor element. In particular, in thin semiconductor elements having a thickness of not more than 300 μm (furthermore, a thickness of not more than 200 μm), the generation of such a warp becomes remarkable.
According to the film for back surface of flip-chip semiconductor according to the present invention, when it is formed on the back surface of a semiconductor element having been flip-chip connected onto an adherend, it fulfills a function to protect the semiconductor element. In addition, since the film for back surface of flip-chip semiconductor according to the present invention has a tensile storage elastic modulus at 23° C. after thermal curing of 10 GPa or more, at the time of thermal curing of an encapsulating resin as described above, even if the encapsulating resin is about to shrink, the shrinkage can be suppressed or prevented. As result, a warp of the semiconductor element can be effectively suppressed or prevented. In addition, by regulating the tensile storage elastic modulus to be not more than 50 GPa, cracking of the package (PKG: flip-chip semiconductor device) at the time of reflow can be suppressed. Incidentally, the back surface of the semiconductor element as referred to herein means a face (non-circuit face) on the opposite side to a face on which a circuit is formed (circuit face).
The film for back surface of flip-chip semiconductor is preferably formed of at least a thermosetting resin component.
Here, the film for back surface of flip-chip semiconductor according to a preferred embodiment of the present invention (hereinafter also referred to as “first embodiment”) includes at least a layer formed of at least a thermosetting resin component and a thermoplastic resin component having a glass transition temperature of 25° C. or higher and not higher than 200° C.
The film for back surface of flip-chip semiconductor according to the present embodiment is formed of at least a thermosetting resin component and a thermoplastic resin component, and a glass transition temperature of the thermoplastic resin component is 25° C. or higher, and therefore, when thermally cured upon heating, its mechanical strength can be increased. Consequently, even if a stress to be caused due to cure shrinkage of the encapsulating resin is applied to the semiconductor element, the film for back surface of flip-chip semiconductor after thermal curing can resist the stress, and a warp of the semiconductor element can be effectively suppressed or prevented. On the contrary, by regulating the glass transition temperature to be not higher than 200° C., cracking of the package (PKG: flip-chip semiconductor device) at the time of reflow can be suppressed.
A blending proportion of the thermoplastic resin component having a glass transition temperature of from 25° C. to 200° C. preferably falls within the range of 5% by weight or more and not more than 40% by weight relative to a total amount of the resin components. By regulating the blending proportion of the thermoplastic resin having a glass transition temperature of from 25° C. to 200° C. to be 5% by weight or more relative to a total amount of the resin components constituting the film for back surface of flip-chip semiconductor, the mechanical strength at the time of thermal curing can be made favorable. On the other hand, by regulating the foregoing blending proportion to be not more than 40% by weight, it is possible to prevent the occurrence of insufficient thermal curing upon heating.
The thermoplastic resin component having a glass transition temperature of from 25° C. to 200° C. preferably includes an acrylic resin having a glass transition temperature of 25° C. or higher and not higher than 200° C.
In addition, the film for back surface of flip-chip semiconductor according to another preferred embodiment of the present invention (hereinafter also referred to as “second embodiment”) includes at least a layer formed of at least a thermosetting resin component and containing no thermoplastic resin component.
The film for back surface of flip-chip semiconductor according to the present embodiment includes at least a layer which is formed of at least a thermosetting resin component and does not contain a thermoplastic resin component, and therefore, at the time of thermal curing of an encapsulating resin as described above, even if the encapsulating resin is about to shrink, the shrinkage can be suppressed or prevented. As result, a warp of the semiconductor element can be effectively suppressed or prevented.
The thermosetting resin component is preferably an epoxy resin.
In addition, in the embodiment in which the film for back surface of flip-chip semiconductor includes at least a layer formed of at least a thermosetting resin component and containing no thermoplastic resin component, the thermosetting resin component preferably contains a liquid epoxy resin in an amount of 60% by weight or more relative to a total amount of the thermosetting resin component.
The film for back surface of flip-chip semiconductor includes a layer which is formed of at least a thermosetting resin component and does not contain a thermoplastic resin component, and therefore, when heated, its mechanical strength is increased by thermal curing. Consequently, at the time of thermal curing of an encapsulating resin as described above, even if the encapsulating resin is about to shrink, the shrinkage can be suppressed or prevented. Furthermore, by incorporating a liquid epoxy resin in an amount of 60% by weight or more relative to the total amount of the thermosetting resin component into the thermosetting resin component, it is possible to suppress or prevent the generation of cracking on the film for back surface of flip-chip semiconductor after thermal curing. Incidentally, the liquid epoxy resin includes not only the case where when an epoxy resin is used solely, it is a liquid at 25° C., but also the case where when two or more kinds thereof are used in combination, the epoxy resin component is a liquid at 25° C.
It is preferable that a coloring agent is further added to the film for back surface of flip-chip semiconductor according to the present invention. Consequently, the film for back surface of flip-chip semiconductor can be colored, thereby making it possible to impart excellent discrimination.
A thickness of the film for back surface of flip-chip semiconductor preferably falls within the range of from 2 μm to 500 μm. By regulating the thickness to be 2 μm or more, it is possible to improve the mechanical strength of the film, thereby ensuring favorable self-supporting properties. On the other hand, by regulating the thickness to be not more than 500 μm, it is possible to realize thinning of a semiconductor device composed of a semiconductor element having been flip-chip mounted on an adherend. Incidentally, a more preferred range of the thickness of the film for back surface of flip-chip semiconductor is from 2 to 200 μm. In addition, in the case where the film for back surface of flip-chip semiconductor includes at least a layer formed of at least a thermosetting resin component and containing no thermoplastic resin component, it is also a preferred embodiment that the thickness of the film for back surface of flip-chip semiconductor is from 5 to 500 μm.
A thickness of the semiconductor element preferably falls within the range of from 20 μm to 300 μm.
In addition, the dicing tape-integrated film for back surface of semiconductor according to the present invention is a dicing tape-integrated film for back surface of semiconductor which includes a dicing tape including a base material and a pressure-sensitive adhesive layer laminated on the base material; and the foregoing film for back surface of flip-chip semiconductor laminated on the dicing tape, wherein the dicing tape-integrated film for back surface of semiconductor is laminated on the pressure-sensitive adhesive layer.
In the dicing tape-integrated film for back surface of semiconductor having the foregoing configuration, the dicing tape and the film for back surface of flip-chip semiconductor are integrally formed, and therefore, the film can also be subjected to a dicing step of dicing a semiconductor wafer to fabricate a semiconductor element and a subsequent picking-up step. That is, at the time of sticking the dicing tape onto the back surface of the semiconductor wafer prior to the dicing step, the film for back surface of semiconductor can also be stuck, and therefore, a step of sticking only the film for back surface of semiconductor (a sticking step of the film for back surface of semiconductor) is not necessary. As a result, it may be contrived to decrease the number of processing steps. Moreover, since the film for back surface of semiconductor protects the back surface of the semiconductor wafer or the semiconductor element formed by dicing, it is possible to reduce or prevent the generation of damage (cracking, chipping, or the like) of the semiconductor element in the dicing step or subsequent steps (picking-up step and the like). As a result, it may be contrived to improve a manufacturing yield of flip-chip semiconductor device.
In addition, the method for manufacturing a semiconductor device according to the present invention is a method for manufacturing a semiconductor device using the foregoing dicing tape-integrated film for back surface of semiconductor, which includes a step of sticking a semiconductor wafer onto the film for back surface of flip-chip semiconductor in the dicing tape-integrated film for back surface of semiconductor; a step of dicing the semiconductor wafer to form a semiconductor element; a step of peeling off the semiconductor element together with the film for back surface of flip-chip semiconductor from the pressure-sensitive adhesive layer of the dicing tape; and a step of flip-chip connecting the semiconductor element onto an adherend.
In the foregoing method, the dicing tape-integrated film for back surface of semiconductor is stuck onto the back surface of the semiconductor wafer, and therefore, a step of sticking only the film for back surface of semiconductor (a sticking step of the film for back surface of semiconductor) is not necessary. In addition, in dicing of the semiconductor wafer or picking-up of the semiconductor element formed by dicing, the semiconductor wafer and the back surface of the semiconductor element are protected by the film for back surface of semiconductor, and therefore, the generation of damage or the like can be prevented. As a result, a flip-chip semiconductor device can be manufactured while improving a manufacturing yield.
In the step of flip-chip connection, it is preferable to include a step of encapsulating an encapsulating resin in a gap between the semiconductor element flip-chip bonded onto the adherend and the adherend, followed by thermally curing the encapsulating resin.
At the time of thermal curing of the encapsulating resin, there may be the case where a stress is applied to the semiconductor element due to the cure shrinkage, and a warp is generated on the semiconductor element due to this stress. In particular, in thin semiconductor elements having a thickness of not more than 300 μm (furthermore, a thickness of not more than 200 μm), the generation of such a warp becomes remarkable. However, in the foregoing method, since a film for back surface of flip-chip semiconductor having a tensile storage elastic modulus at 23° C. after thermal curing of 10 GPa or more is used, at the time of thermal curing of the encapsulating resin, even if the encapsulating resin is about to shrink, it is able to resist its shrinkage force. Consequently, even if a stress to be caused due to cure shrinkage of the encapsulating resin is applied to the semiconductor element, the semiconductor element does not substantially bend or does not bend at all, so that the generation of a warp of the semiconductor element can be suppressed or prevented. In addition, in the foregoing first embodiment, since the film for back surface of flip-chip semiconductor formed of at least a thermosetting resin component and a thermoplastic resin component having a glass transition temperature of from 25° C. to 200° C. is used, when thermally cured upon heating, its mechanical strength can be increased. Consequently, even if a stress to be caused due to cure shrinkage of the encapsulating resin is applied to the semiconductor element, the film for back surface of flip-chip semiconductor after thermal curing can resist the stress, and a warp of the semiconductor element can be effectively suppressed or prevented. In addition, in the foregoing second embodiment, since the film for back surface of flip-chip semiconductor formed of at least a thermosetting resin component and containing no thermoplastic resin component is used, at the time of thermal curing of the encapsulating resin, the mechanical strength of the film for back surface of semiconductor can also be improved by thermally curing the film for back surface of semiconductor. As a result, even if a stress to be caused due to cure shrinkage of the encapsulating resin is applied to the semiconductor element, the film for back surface of flip-chip semiconductor can resist the stress, and a warp of the semiconductor element can be effectively suppressed or prevented. Furthermore, when the film for back surface of flip-chip semiconductor is a film containing 60% by weight or more of a liquid epoxy resin in the thermosetting resin component, cracking is not generated even after thermal curing. As a result, it is possible to manufacture a semiconductor device with excellent reliability.
In addition, the semiconductor device according to the present invention is one manufactured by the manufacturing method of a semiconductor device as described above.
According to the film for back surface of flip-chip semiconductor of the present invention, since it is formed on the back surface of a semiconductor element having been flip-chip connected onto an adherend, it fulfills a function to protect the semiconductor element. In addition, since the film for back surface of flip-chip semiconductor according to the present invention has a tensile storage elastic modulus at 23° C. after thermal curing of 10 GPa or more, a warp of the semiconductor element generated at the time of flip-chip connection of the semiconductor element onto the adherend can be effectively suppressed or prevented.
In addition, since the film for flip-chip semiconductor according to the first embodiment of the present invention is formed of at least a thermosetting resin component and a thermoplastic resin component having a glass transition temperature of from 25° C. to 200° C., when thermally cured upon heating, its mechanical strength can be increased. Therefore, even if a stress to be caused due to cure shrinkage of the encapsulating resin is applied to the semiconductor element, the film for back surface of flip-chip semiconductor after thermal curing can resist the stress, and a warp of the semiconductor element can be effectively suppressed or prevented.
In addition, since the film for flip-chip semiconductor according to the second embodiment of the present invention includes at least a layer formed of at least a thermosetting resin component and containing no thermoplastic resin component, even if the encapsulating resin is about to cause cure shrinkage due to thermal curing, it has mechanical strength so as to resist this after thermal curing. As a result, a warp of the semiconductor element to be generated at the time of flip-chip connection of the semiconductor element onto the adherend can be effectively suppressed or prevented. In addition, when the thermosetting resin component contains a liquid epoxy resin in an amount of 60% by weight or more relative to a total amount thereof, the generation of cracking can be suppressed or prevented even after thermal curing.
In addition, according to the dicing tape-integrated film for back surface of semiconductor according to the present invention, the dicing tape and the film for back surface of flip-chip semiconductor are integrally formed with each other, and therefore, it can also be subjected to a dicing step of dicing a semiconductor wafer to fabricate a semiconductor element and a subsequent picking-up step. As a result, a step of sticking only the film for back surface of semiconductor (a sticking step of the film for back surface of semiconductor) is not necessary. Furthermore, in the subsequent dicing step or picking-up step, the film for back surface of semiconductor is stuck onto the back surface of the semiconductor wafer or the back surface of the semiconductor element formed by dicing, and therefore, the semiconductor wafer or semiconductor element can be effectively protected, and the generation of damage of the semiconductor element can be suppressed or prevented. In addition, at the time of flip-chip connection of the semiconductor element onto the adherend, the generation of a warp of the semiconductor element can be prevented.
Furthermore, according to the method for manufacturing a semiconductor device of the present invention, the dicing tape-integrated film for back surface of semiconductor is stuck onto the back surface of the semiconductor wafer, and therefore, a step of sticking only the film for back surface of semiconductor is not necessary. In addition, in dicing of the semiconductor wafer or picking-up of the semiconductor element formed by dicing, the back surface of each of the semiconductor wafer and the semiconductor element is protected by the film for back surface of semiconductor, and therefore, the generation of damage or the like can be prevented. In addition, at the time of flip-chip connection of the semiconductor element onto the adherend, the generation of a warp of the semiconductor element can be prevented. As a result, a flip-chip semiconductor device can be manufactured while improving a manufacturing yield.
An embodiment of the present invention is described by reference to
(Dicing Tape-Integrated Film for Back Surface of Semiconductor)
As shown in
(Film for Back Surface of Flip-Chip Semiconductor)
The film 2 for back surface of semiconductor has a film-shaped form. The film 2 for back surface of semiconductor is usually in an uncured state (inclusive of a semi-cured state) in a form of the dicing tape-integrated film for back surface of semiconductor as a product, and after sticking the dicing tape-integrated film for back surface of semiconductor onto the semiconductor wafer, the film 2 for back surface of semiconductor is thermally cured (detail of which are described later).
The film 2 for back surface of semiconductor according to the present embodiment has such a characteristic that its tensile storage elastic modulus at 23° C. after thermal curing is 10 GPa or more and not more than 50 GPa. When the tensile storage elastic modulus is 10 GPa or more, even if the semiconductor element having been flip-chip connected onto the adherend is of a thin type (for example, even if the thickness is not more than 300 μm, and further not more than 200 μm), its warp can be effectively suppressed or prevented. In the flip-chip connection, after flip-chip bonding the semiconductor element onto the adherend, only a connecting portion between the adherend and the semiconductor element is encapsulated with an encapsulating material (an encapsulating resin called an underfill, or the like). Furthermore, while the encapsulating material is thermally cured, a stress is applied to the semiconductor element by cure shrinkage of the encapsulating material on that occasion, or the like. However, in the film 2 for back surface of semiconductor according to the present embodiment, the tensile storage elastic modulus is 10 GPa or more, and therefore, at the time of thermal curing of the encapsulating material, even if the encapsulating material is about to shrink, the film 2 for back surface of semiconductor according to the present embodiment is able to resist the stress applied to the semiconductor element. As a result, the generation of a warp of the semiconductor element can be suppressed or prevented. In addition, by regulating the tensile storage elastic modulus to be not more than 50 GPa, cracking of the package at the time of reflow can be suppressed. A lower limit value of the tensile storage elastic modulus of the film 2 for back surface of semiconductor at 23° C. after thermal curing is preferably 12 GPa or more (more preferably 14 GPa or more). In addition, an upper limit value thereof is preferably not more than 40 GPa (more preferably not more than 30 GPa).
Here, though the film 2 for back surface of semiconductor may be a single layer or a laminated film in which plural layers are laminated, in the case where the film 2 for back surface of semiconductor is a laminated film, it is sufficient that the tensile storage elastic modulus is in the range of from 10 GPa to 50 GPa as a whole of the laminated film. In addition, the tensile storage elastic modulus of the film 2 for back surface of semiconductor can be controlled by the kind of a resin component and its content, the kind of a filler (filling material) and its (filling) content, or the like.
Incidentally, as for a tensile storage elastic modulus E′ of the film 2 for back surface of semiconductor at 23° C. after thermal curing, a film for back surface of semiconductor is fabricated without being laminated onto the dicing tape 3, cured upon heating at 165° C. for 2 hours, and then measured in a tensile mode under conditions of a sample width of 10 mm, a sample length of 22.5 mm, a sample thickness of 0.2 mm, a frequency of 1 Hz, and a temperature elevating rate of 10° C./minute in a nitrogen atmosphere at a prescribed temperature (23° C.) using a dynamic viscoelasticity measuring apparatus “Solid Analyzer RS A2”, manufactured by Rheometrics Co., Ltd., and the measured elastic modulus can be regarded as a value of the tensile storage elastic modulus E′.
The film 2 for back surface of semiconductor is preferably formed of at least a thermosetting resin component. By forming the film 2 for back surface of semiconductor from at least a thermosetting resin component, the film for back surface of semiconductor is capable of effectively exhibiting a function as an adhesive layer.
Examples of the thermosetting resin component include, in addition to epoxy resins and phenol resins, amino resins, unsaturated polyester resins, polyurethane resins, silicone resins, thermosetting polyimide resins, and the like. The thermosetting resin component can be used solely or in combination of two or more kinds thereof. As the thermosetting resin component, epoxy resins having a low content of ionic impurities and the like, which corrode the semiconductor element, are especially suitable. In addition, a phenol resin can be suitably used as a curing agent of the epoxy resin.
The epoxy resin is not particularly limited so far as it is generally useful for an adhesive composition. For example, bifunctional epoxy resin or polyfunctional epoxy resins such as a bisphenol A type epoxy resin, a bisphenol F type epoxy resin, a bisphenol S type epoxy resin, a brominated bisphenol A type epoxy resin, a hydrogenated bisphenol A type epoxy resin, a bisphenol AF type epoxy resin, a biphenyl type epoxy resin, a naphthalene type epoxy resin, a fluorene type epoxy resin, a phenol novolak type epoxy resin, an o-cresol novolak type epoxy resin, a trishydroxyphenylmethane type epoxy resin, a tetraphenylolethane type epoxy resin, etc., or epoxy resins such as a hydantoin type epoxy resin, a trisglycidylisocyanurate type epoxy resin, a glycidylamine type epoxy resin, etc. can be used.
As the epoxy resin, among those exemplified above, a novolak type epoxy resin, a biphenyl type epoxy resin, a trishydroxyphenylmethane type epoxy resin, and a tetraphenylolethane type epoxy resin are especially preferable. This is because these epoxy resins are rich in reactivity with a phenol resin as a curing agent and excellent in heat resistance, or the like.
Furthermore, the phenol resin acts as a curing agent of the epoxy resin, and examples thereof include novolak type phenol resins such as a phenol novolak resin, a phenol aralkyl resin, a cresol novolak resin, a tert-butylphenol novolak resin, a nonylphenol novolak resin, etc.; resol type phenol resins; polyoxystyrenes such as poly-p-oxystyrene, etc., and the like. The phenol resin can be used solely or in combination of two or more kinds thereof. Among these phenol resins, a phenol novolak resin and a phenol aralkyl resin are especially preferable. This is because connection reliability of the semiconductor device can be improved.
As for a blending proportion of the epoxy resin and the phenol resin, for example, the resins are suitably blended such that a hydroxyl group in the phenol resin is from 0.5 equivalents to 2.0 equivalents per equivalent of the epoxy group in the epoxy resin component. The blending proportion is more suitably from 0.8 equivalents to 1.2 equivalents. That is, this is because when the blending proportion falls outside the foregoing range, a curing reaction does not proceed sufficiently, and the characteristics of the epoxy resin cured product are liable to be deteriorated.
A thermal curing-accelerating catalyst for the epoxy resin and the phenol resin is not particularly limited, and it can be properly selected and used among known thermal curing-accelerating catalysts. The thermal curing-accelerating catalyst can be used solely or in combination of two or more kinds thereof. As the thermal curing-accelerating catalyst, for example, an amine based curing accelerator, a phosphorus based curing accelerator, an imidazole based curing accelerator, a boron based curing accelerator, a phosphorus-boron based curing accelerator, and the like can be used.
The amine based curing accelerator is not particularly limited, and examples thereof include monoethanolamine trifluoroborate (manufactured by Stella Chemifa Corporation), dicyandiamide (manufactured by Nacalai Tesque, Inc.), and the like.
The phosphorus based curing accelerator is not particularly limited, and examples thereof include triorganophosphines such as triphenylphosphine, tributylphosphine, tri(p-methylphenyl)phosphine, tri(nonylphenyl)phosphine, diphenyltolylphosphine, etc.; and tetraphenylphosphonium bromide (a trade name: TPP-PB), methyltriphenylphosphonium (a trade name: TPP-MB), methyltriphenylphosphonium chloride (a trade name: TPP-MC), methoxymethyltriphenylphosphonium (a trade name: TPP-MOC), benzyltriphenylphosphonium chloride (a trade name: TPP-ZC), and the like (all of which are manufactured by Hokko Chemical Industry Co., Ltd.). In addition, the triphenylphosphine based compound is preferably a compound which is substantially insoluble in epoxy resins. When the compound is insoluble in epoxy resins, it is possible to suppress the excessive progress of thermal curing. As a heat-curing catalyst which has a triphenylphosphine structure and which is substantially insoluble in epoxy resins, for example, methyltriphenylphosphonium (a trade name: TPP-MB) and the like can be exemplified. Incidentally, the term “insoluble” means that the heat-curing catalyst composed of a triphenylphosphine based compound is insoluble in a solvent composed of an epoxy resin, and in more detail, the catalyst does not dissolve in the solvent in an amount of 10% by weight or more at a temperature in the range of from 10 to 40° C.
Examples of the imidazole based curing accelerator includes 2-methylimidazole (a trade name: 2MZ), 2-undecylimidazole (a trade name: C11-Z), 2-heptadecylimidazole (a trade name: C17Z), 1,2-dimethylimidazole (a trade name: 1,2DMZ), 2-ethyl-4-methylimidazole (a trade name: 2E4MZ), 2-phenylimidazole (a trade name: 2PZ), 2-phenyl-4-methylimidazole (a trade name: 2P4MZ), 1-benzyl-2-methylimidazole (a trade name: 1B2MZ), 1-benzyl-2-phenylimidazole (a trade name: 1B2PZ), 1-cyanoethyl-2-methylimidazole (a trade name: 2MZ-CN), 1-cyanoethyl-2-undecylimidazole (a trade name: C11Z-CN), 1-cyanoethyl-2-phenylimidazolium trimellitate (a trade name: 2PZCNS-PW), 2,4-diamino-6-[2′-methylimidazolyl-(1′)]-ethyl-s-triazine (a trade name: 2MZ-A), 2,4-diamino-6-[2′-undecylimidazolyl-(1′)]-ethyl-s-triazine (a trade name: C11Z-A), 2,4-diamino-6-[2′-ethyl-4′-methylimidazolyl-(1′)]-ethyl-s-triazine (a trade name: 2E4MZ-A), a 2,4-diamino-6-[2′-methylimidazolyl-(1′)]-ethyl-s-triazine isocyanuric acid adduct (a trade name: 2MA-OK), 2-phenyl-4,5-dihydroxymethylimidazole (a trade name: 2PHZ-PW), 2-phenyl-4-methyl-5-hydroxymethylimidazole (a trade name: 2P4 MHZ-PW), and the like (all of which are manufactured by Shikoku Chemicals Corporation).
The boron based curing accelerator is not particularly limited, and examples thereof include trichloroborane and the like.
The phosphorus-boron based curing accelerator is not particularly limited, and examples thereof include tetraphenylphosphonium tetraphenyl borate (a trade name: TPP-K), tetraphenylphosphonium tetra-p-triborate (a trade name: TPP-MK), benzyltriphenylphosphonium tetraphenyl borate (a trade name: TPP-ZK), triphenylphosphine triphenylborane (a trade name: TPP-S), and the like (all of which are manufactured by Hokko Chemical Industry Co., Ltd.).
A blending proportion of the thermal curing-accelerating catalyst is preferably within the range of from 0.01 to 10 parts by weight, more preferably within the range of from 0.02 to 5 parts by weight, and especially preferably within the range of from 0.05 to 3 parts by weight based on 100 parts by weight of the thermosetting resin. By regulating the blending proportion of the thermal curing-accelerating catalyst to 10 parts by weight or more based on 100 parts by weight of the thermosetting resin, the tensile storage elastic modulus at 23° C. after thermal curing can be made to 10 GPa or more. In addition, at the time of thermal curing of the encapsulating resin, the film for back surface of semiconductor can be sufficiently thermally cured and is surely adhered and fixed onto the back surface of the semiconductor element. Thus, it becomes possible to manufacture a flip-chip semiconductor device which is free from peeling off. On the other hand, by regulating the blending proportion of the thermal curing-accelerating catalyst to not more than 0.01 parts by weight based on 100 parts by weight of the thermosetting resin, the generation of curing inhibition can be prevented.
In addition, the film 2 for back surface of semiconductor may also be formed of at least a thermosetting resin component and a thermoplastic resin component. In particular, as a preferred embodiment (first embodiment), it is preferable to form the film 2 for back surface of semiconductor by at least a thermosetting resin component and a thermoplastic resin component having a glass transition temperature (Tg) of from 25° C. to 200° C. When the film 2 for back surface of semiconductor is formed of at least a thermosetting resin component and a thermoplastic resin component having a glass transition temperature (Tg) of from 25° C. to 200° C., even if the semiconductor element having been flip-chip connected onto the adherend is of a thin type (for example, even if the thickness is not more than 300 μm and further not more than 200 μm), its warp can be effectively suppressed or prevented. In the flip-chip connection, after flip-chip bonding the semiconductor element onto the adherend, only a connecting portion between the adherend and the semiconductor element is encapsulated with an encapsulating material (an encapsulating resin called an underfill, or the like). Furthermore, while the encapsulating material is thermally cured, a stress is applied to the semiconductor element by cure shrinkage of the encapsulating material on that occasion, or the like. However, when the film 2 for back surface of semiconductor according to the present embodiment is thermally cured upon heating, it becomes provided with mechanical strength so as to resist a stress which is applied to the semiconductor element to be caused due to cure shrinkage of the encapsulating resin. As a result, the generation of a warp of the semiconductor element can be suppressed or prevented. Incidentally, a lower limit value of the Tg is preferably 26° C. or higher, more preferably 27° C. or higher, and still more preferably 28° C. or higher. In addition, an upper limit value of the Tg is preferably not higher than 150° C., and it is more preferable that it becomes successively lower as not higher than 120° C., not higher than 100° C., not higher than 80° C., or not higher than 50° C. Incidentally, the glass transition temperature of the thermoplastic resin component can be controlled by the kind of a monomer and its proportion, the kind of a curing catalyst, or the like. The glass transition temperature of the thermoplastic resin component can be measured by a method of thermo mechanical analysis (TMA).
Here, though the film for back surface of semiconductor according to the present embodiment may be a single layer or a laminated film in which plural layers are laminated, in the case where the film for back surface of semiconductor is a laminated film, it is sufficient that at least one of the layers is a layer formed of at least the thermosetting resin component and the thermoplastic resin component having a glass transition temperature of from 25° C. to 200° C. as described above.
Examples of the thermoplastic resin component include natural rubber, butyl rubber, isoprene rubber, chloroprene rubber, an ethylene-vinyl acetate copolymer, an ethylene-acrylic acid copolymer, an ethylene-acrylic acid ester copolymer, a polybutadiene resin, a polycarbonate resin, a thermoplastic polyimide resin, a polyamide resin such as 6-nylon, 6,6-nylon, etc., a phenoxy resin, an acrylic resin, a saturated polyester resin such as PET (polyethylene terephthalate), PBT (polybutylene terephthalate), etc., a polyamide-imide resin, a fluorine resin, and the like. The thermoplastic resin component can be used solely or in combination of two or more kinds thereof. Among these thermoplastic resin components, an acrylic resin which contains a small amount of ionic impurities, has high heat resistance, and is capable of securing reliability of a semiconductor element is especially preferable. In addition, examples of the thermoplastic resin component having a Tg of from 25° C. to 200° C. include the thermoplastic resin components exemplified above, in which a glass transition temperature is from 25° C. to 200° C. Such a thermoplastic resin component having a Tg of from 25° C. to 200° C. can be used solely or in combination of two or more kinds thereof. Among these thermoplastic resin components having a g of from 25° C. to 200° C., an acrylic resin having a Tg of from 25° C. to 200° C., which contains a small amount of ionic impurities, has high heat resistance, and is capable of securing reliability of a semiconductor element, is especially preferable. By using an acrylic resin having a Tg of 25° C. or higher, even if the acrylic resin is used, the tensile storage elastic modulus (at 23° C. after thermal curing) of the film for back surface of semiconductor can be increased, thereby making it possible to control the tensile storage elastic modulus to 10 GPa or more. When the Tg is higher than 200° C., there may be the inconvenient case where cracking of the package is generated at the time of reflow. Incidentally, the Tg of the acrylic resin can be controlled by the kind of a monomer and its proportion, the kind of a curing catalyst, or the like. The Tg of the acrylic resin is a value measured by thermo mechanical analysis (TMA).
The acrylic resin is not particularly limited, and examples thereof include polymers composed of, as a component(s), one kind or two or more kinds of esters of acrylic acid or methacrylic acid having a linear or branched alkyl group having a carbon number of not more than 30 (preferably a carbon number of from 4 to 18, more preferably a carbon number of from 6 to 10, and especially preferably a carbon number of 8 or 9), and the like. That is, the acrylic resin as referred to in the present invention has a broad meaning of also including a methacrylic resin. Examples of the alkyl group include a methyl group, an ethyl group, a propyl group, an isopropyl group, an n-butyl group, a t-butyl group, an isobutyl group, a pentyl group, an isopentyl group, a hexyl group, a heptyl group, a 2-ethylhexyl group, an octyl group, an isooctyl group, a nonyl group, an isononyl group, a decyl group, an isodecyl group, an undecyl group, a dodecyl group (lauryl group), a tridecyl group, a tetradecyl group, a stearyl group, an octadecyl group, and the like.
As the acrylic resin (acrylic rubber) having a Tg of from 25° C. to 200° C., an acrylic resin composed of, as a main monomer, an acrylic acid ester or a methacrylic acid ester can be used. That is, the acrylic resin as referred to in the present invention has a broad meaning of also including a methacrylic resin. In the acrylic resin, though the acrylic acid ester or methacrylic acid ester as the main monomer is variable depending upon the kind of other monomer or its proportion, or the like, it is not particularly limited so far as it is able to regulate the Tg of the acrylic resin as a polymer to from 25° C. to 200° C. Specifically, for example, an alkyl ester of acrylic acid or methacrylic acid having a linear or branched alkyl group having a carbon number of not more than 30 (for example, a carbon number of from 1 to 30) is suitable. Examples of the alkyl group include a methyl group, an ethyl group, a propyl group, an isopropyl group, an n-butyl group, a t-butyl group, an isobutyl group, a pentyl group, an isopentyl group, a hexyl group, a heptyl group, a 2-ethylhexyl group, an octyl group, an isooctyl group, a nonyl group, an isononyl group, a decyl group, an isodecyl group, an undecyl group, a dodecyl group (lauryl group), a tridecyl group, a tetradecyl group, a stearyl group, an octadecyl group, and the like. As such an alkyl group, an alkyl group having a carbon number of from 2 to 18 is especially suitable. The acrylic acid ester or methacrylic acid ester can be used solely or in combination of two or more kinds thereof.
A lower limit value of the Tg of the acrylic resin is preferably 26° C. or higher, more preferably 27° C. or higher, and still more preferably 28° C. or higher. In addition, an upper limit value of the Tg is preferably not higher than 150° C., and it is more preferable that it becomes successively lower as not higher than 120° C., not higher than 100° C., not higher than 80° C., or not higher than 50° C. The glass transition temperature of the acrylic resin can be measured by a method of thermo mechanical analysis (TMA).
In the case of using an acrylic resin having a Tg of from 25° C. to 200° C., a blending proportion of the acrylic resin is preferably from 1 to 60% by weight, and more preferably from 5 to 40% by weight relative to a total amount of the thermoplastic resin components having a Tg of from 25° C. to 200° C.
In addition, other monomer for forming the acrylic resin (monomer other than the alkyl ester of acrylic acid or methacrylic acid) is not particularly limited, and examples thereof include carboxyl group-containing monomers such as acrylic acid, methacrylic acid, carboxyethyl acrylate, carboxypentyl acrylate, itaconic acid, maleic acid, fumaric acid, crotonic acid, etc.; acid anhydride monomers such as maleic anhydride, itaconic anhydride, etc.; hydroxyl group-containing monomers such as 2-hydroxyethyl (meth)acrylate, 2-hydroxypropyl (meth)acrylate, 4-hydroxybutyl (meth)acrylate, 6-hydroxyhexyl (meth)acrylate, 8-hydroxyoctyl (meth)acrylate, 10-hydroxydecyl (meth)acrylate, 12-hydroxylauryl (meth)acrylate, (4-hydroxymethylcyclohexyl)-methyl acrylate, etc.; sulfonic acid group-containing monomers such as styrenesulfonic acid, allylsulfonic acid, 2-(meth)acrylamido-2-methylpropanesulfonic acid, (meth)acrylamidopropanesulfonic acid, sulfopropyl (meth)acrylate, (meth)acryloyloxynaphthalenesulfonic acid, etc.; phosphoric acid group-containing monomers such as 2-hydroxyethylacryloyl phosphate, etc.; and the like. Incidentally, the (meth)acrylic acid as referred herein means acrylic acid and/or methacrylic acid, and the term “(meth)” as referred to in the present invention has the same meanings in all of the occurrences.
In the acrylic resin having a Tg of from 25° C. to 200° C., a proportion of the acrylic acid ester or methacrylic acid ester as a main monomer can be, for example, properly selected within the range of from 50% by weight to 100% by weight, and preferably from 55% by weight to 95% by weight (more preferably from 60% by weight to 90% by weight) relative to a total amount of the monomers.
In the case of using a thermoplastic resin component having a Tg of from 25° C. to 200° C., a thermoplastic resin component having a Tg of lower than 25° C. or a thermoplastic resin component having a Tg exceeding 200° C. may be included in the thermoplastic resin component. In that case, a proportion of the thermoplastic resin component having a Tg of from 25° C. to 200° C. can be properly selected within the range of 50% by weight or more (for example, from 50% by weight to 100% by weight), preferably 80% by weight or more (for example, from 80% by weight to 100% by weight), and more preferably 90% by weight or more (for example, from 90% by weight to 100% by weight) relative to a total amount of the thermoplastic resin components. Incidentally, if a thermoplastic resin component having a Tg of lower than 25° C. is used in combination, there may be the case where the elastic modulus of the wafer back surface protective film is lowered. In consequence, it is suitable that the proportion of the thermoplastic resin component having a Tg of lower than 25° C. is small as far as possible, and it is especially suitable that the thermoplastic resin component having a Tg of lower than 25° C. is not used at all. In addition, if the thermoplastic resin component having a Tg exceeding 200° C. is used in combination, there may be the inconvenient case where cracking of the package is generated at the time of reflow. In consequence, it is suitable that the proportion of the thermoplastic resin component having a Tg exceeding 200° C. is small as far as possible, and it is especially suitable that the thermoplastic resin component having a Tg exceeding 200° C. is not used at all. From these standpoints, it is especially preferable that the thermoplastic resin component having a Tg of from 25° C. to 200° C. is used in a proportion of 100% by weight relative to a total amount of the thermoplastic resin components.
A blending proportion of the thermoplastic resin component having a Tg of from 25° C. to 200° c. is preferably within the range of 5% by weight or more and not more than 40% by weight relative to a total amount of the resin components of the film for back surface of flip-chip semiconductor. By regulating the blending proportion of the thermoplastic resin component to 5% by weight or more relative to a total amount of the resin components, the mechanical strength at the time of thermal curing can be made favorable. On the other hand, by regulating the blending proportion to not more than 40% by weight, it is possible to prevent the occurrence of insufficient thermal curing upon heating.
In addition, as another preferred embodiment (second embodiment), the film 2 for back surface of semiconductor can also include at least a layer formed of at least a thermosetting resin component and containing no thermoplastic resin component. According to this, by using a thermosetting resin component but not using a thermoplastic resin component for a resin composition of the film 2 of back surface of semiconductor, even if the semiconductor element having been flip-chip connected onto the adherend is of a thin type (for example, even if the thickness is not more than 300 μm, and further not more than 200 μm), its warp can be effectively suppressed or prevented. In the flip-chip connection, after flip-chip bonding the semiconductor element onto the adherend, only a connecting portion between the adherend and the semiconductor element is encapsulated with an encapsulating material (an encapsulating resin called an underfill, or the like). Furthermore, while the encapsulating material is thermally cured, a stress is applied to the semiconductor element by cure shrinkage of the encapsulating material on that occasion, or the like, and a warp is generated. However, when the film for back surface of semiconductor is formed of only a thermosetting resin component without using a thermoplastic resin component, at the time of thermal curing of the encapsulating resin as described above, even if the encapsulating resin is about to shrink, the film 2 for back surface of semiconductor according to the present embodiment is thermally cured upon heating and becomes provided with mechanical strength so as to resist a stress which is applied to the semiconductor element to be caused due to cure shrinkage of the encapsulating resin. As a result, its shrinkage can be suppressed or prevented. As a result, a warp of the semiconductor element can be effectively suppressed or prevented.
Here, the film for back surface of semiconductor according to the present embodiment may be a single layer or a laminated film in which plural layers are laminated. In the case where the film for back surface of semiconductor is a laminated film, it is sufficient that at least one of the layers is a layer formed of at least a thermosetting resin component and containing no thermoplastic resin component. Incidentally, examples of the thermosetting resin component and the thermoplastic resin component include those exemplified above.
In addition, in the present embodiment, it is preferable that the thermosetting resin component contains at least a liquid epoxy resin. The liquid epoxy resin is not particularly limited so far as it exhibits fluidity at 25° C. Specifically, for example, those which are selected from bifunctional epoxy resins or polyfunctional epoxy resins such as a bisphenol A type epoxy resin, a bisphenol F type epoxy resin, a bisphenol S type epoxy resin, a brominated bisphenol A type epoxy resin, a hydrogenated bisphenol A type epoxy resin, a bisphenol AF type epoxy resin, a biphenyl type epoxy resin, a naphthalene type epoxy resin, a fluorene type epoxy resin, a phenol novolak type epoxy resin, an o-cresol novolak type epoxy resin, a trishydroxyphenylmethane type epoxy resin, a tetraphenylolethane type epoxy resin, etc., or epoxy resins such as a hydantoin type epoxy resin, a trisglycidylisocyanurate type epoxy resin, a glycidylamine type epoxy resin, etc., and exhibit fluidity at 25° C., can be used. These liquid epoxy resins can be used solely or in combination of two or more kinds thereof. In the case of using two or more kinds of these liquid epoxy resins in combination, it is preferable that the whole of the epoxy resin component is in a liquid state at 25° C. Incidentally, as the liquid epoxy resin, among those exemplified above, a novolak type epoxy resin, a biphenyl type epoxy resin, a trishydroxyphenylmethane type epoxy resin, and a tetraphenylolethane type epoxy resin are especially preferable. This is because these liquid epoxy resins are rich in reactivity with a phenol resin as a curing agent and excellent in heat resistance, or the like. In addition, the term “exhibit fluidity” as referred to in the present invention means the case where a viscosity at 25° C. is not more than 100,000 Pa·s. The viscosity is a value measured by a B type viscometer (temperature: 23° C.).
In the thermosetting resin component, in addition to the liquid epoxy resin, a thermosetting resin component which is generally used for an adhesive composition can be used in combination without being particularly limited. Examples of the thermosetting resin component include, in addition to the above-exemplified epoxy resins which are, however, a solid at ordinary temperature (25° C.) and phenol resins, thermosetting resin components such as amino resins, unsaturated polyester resins, polyurethane resins, silicone resins, thermosetting polyimide resins, etc. These thermosetting resin components can be used solely or in combination of two or more kinds thereof. In addition, a phenol resin can be suitably used as a curing agent of the liquid epoxy resin.
A blending proportion of the liquid epoxy resin is preferably 60% by weight or more, more preferably from 60 to 90% by weight, and still more preferably from 65 to 80% by weight relative to a total amount of the thermosetting resin components. By regulating the blending proportion of the liquid epoxy resin to 60% by weight or more, the generation of cracking in the film 2 for back surface of semiconductor after thermal curing can be prevented.
In the case where a liquid epoxy resin and a phenol resin are contained in the thermosetting resin component, as for a blending proportion of the both resins, for example, the resins are suitably blended in such a manner that a hydroxyl group in the phenol resin is from 0.5 equivalents to 2.0 equivalents per equivalent of an epoxy group in the liquid epoxy resin component. The blending proportion is more suitably from 0.8 equivalents to 1.2 equivalents. That is, this is because when the blending proportion of the both resins falls outside the foregoing range, a curing reaction does not proceed sufficiently, and the characteristics of the epoxy resin cured product are liable to be deteriorated.
The film 2 for back surface of semiconductor can be formed of, for example, a resin composition containing an epoxy resin and a phenol resin, or a resin composition containing an epoxy resin, a phenol resin, and an acrylic resin. These resins have a small amount of ionic impurities and have high heat resistance, and therefore, they are able to secure reliability of the semiconductor element. In that case, though a blending ratio thereof is not particularly limited, for example, in the case where an acrylic resin is contained, a mixing amount of the epoxy resin and the phenol resin can be properly selected within the range of from 10 parts by weight to 200 parts by weight based on 100 parts by weight of the acrylic resin component.
In addition, the film 2 for back surface of semiconductor can also be, for example, formed of a resin composition containing an epoxy resin, a phenol resin, and a thermoplastic resin component having a Tg of from 25° C. to 200° C., and furthermore, it can also be formed of a resin composition containing an epoxy resin, a phenol resin, and an acrylic resin having a Tg of from 25° C. to 200° C. These resins have a small amount of ionic impurities and have high heat resistance, and therefore, they are able to secure reliability of the semiconductor element. In that case, though a blending ratio thereof is not particularly limited, for example, a mixing amount of the epoxy resin and the phenol resin can be properly selected within the range of from 10 parts by weight to 200 parts by weight based on 100 parts by weight of the thermoplastic resin component having a Tg of from 25° C. to 200° C. (for example, an acrylic resin component having a Tg of from 25° C. to 200° C.).
In addition, the film 2 for back surface of semiconductor can also be, for example, formed of a thermosetting resin component containing an epoxy resin and a phenol resin. These resins have a small amount of ionic impurities and have high heat resistance, and therefore, they are able to secure reliability of the semiconductor element. In that case, though a blending ratio thereof is not particularly limited, for example, a mixing amount of the epoxy resin and the phenol resin can be properly selected within the range of from 10 parts by weight to 200 parts by weight based on 100 parts by weight of all of the resin components. In addition, though a blending ratio in the case where the film 2 for back surface of semiconductor is formed of a thermosetting resin component containing a liquid epoxy resin and a phenol resin is not particularly limited, for example, a mixing amount of the liquid epoxy resin and the phenol resin can be properly selected within the range of from 10 parts by weight to 200 parts by weight based on 100 parts by weight of all of the resin components.
It is important that the film 2 for back surface of semiconductor has adhesiveness (adhesion) to the back surface (circuit-non-formed face) of the semiconductor wafer. That is, it is important that the film 2 for back surface of semiconductor per se is an adhesive layer. The film 2 for back surface of semiconductor as such an adhesive layer can be, for example, formed of a resin composition containing an epoxy resin as the thermosetting resin component. For the purpose of crosslinking the film 2 for back surface of semiconductor to some extent in advance, a polyfunctional compound capable of reacting with a molecular chain terminal functional group or the like of a polymer is preferably added as a crosslinking agent at the time of fabrication. According to this, it is possible to contrive to enhance adhesive characteristics under high temperatures and to improve heat resistance.
An adhesive force of the film for back surface of semiconductor to the semiconductor wafer (23° C., peeling angle: 180°, peeling rate: 300 mm/min) is preferably in the range of from 0.5 N/20 mm to 15 N/20 mm, and more preferably in the range of from 0.7 N/20 mm to 10 N/20 mm. By regulating the adhesive force to 0.5 N/20 mm or more, the film for back surface of semiconductor is stuck to the semiconductor wafer or the semiconductor element with excellent adhesion and can be prevented from the generation of lifting or the like. In addition, at the time of dicing of the semiconductor wafer, the generation of chip flying out can be prevented. On the other hand, by regulating the adhesive force to not more than 15 N/20 mm, the film for back surface of semiconductor can be easily peeled off from the dicing tape.
The crosslinking agent is not particularly limited, and known crosslinking agents can be used. Specifically, examples thereof include, in addition to isocyanate based crosslinking agents, epoxy based crosslinking agents, melamine based crosslinking agents, and peroxide based crosslinking agents, urea based crosslinking agents, metal alkoxide based crosslinking agents, metal chelate based crosslinking agents, metal salt based crosslinking agents, carbodiimide based crosslinking agents, oxazoline based crosslinking agents, aziridine based crosslinking agents, amine based crosslinking agents, and the like. As the crosslinking agent, isocyanate based crosslinking agents and epoxy based crosslinking agents are suitable. In addition, the crosslinking agent can be used solely or in combination of two or more kinds thereof.
Examples of the isocyanate based crosslinking agent include lower aliphatic polyisocyanates such as 1,2-ethylene diisocyanate, 1,4-butylene diisocyanate, 1,6-hexamethylene diisocyanate, etc.; alicyclic polyisocyanates such as cyclopentylene diisocyanate, cyclohexylene diisocyanate, isophorone diisocyanate, hydrogenated tolylene diisocyanate, hydrogenated xylylene diisocyanate, etc.; aromatic polyisocyanates such as 2,4-tolylene diisocyanate, 2,6-tolylene diisocyanate, 4,4′-diphenylmethane diisocyanate, xylylene diisocyanate, etc.; and the like. Besides, a trimethylolpropane/tolylene diisocyanate trimer adduct (a trade name: “COLONATE L”, manufactured by Nippon Polyurethane Industry Co., Ltd.), a trimethylolpropane/hexamethylene diisocyanate trimer adduct (a trade name “COLONATE HL”, manufactured by Nippon Polyurethane Industry Co., Ltd.), and the like are also used. In addition, examples of the epoxy based crosslinking agent include N,N,N′,N′-tetraglycidyl-m-xylenediamine, diglycidylaniline, 1,3-bis(N,N-glycidylaminomethyl)cyclohexane, 1,6-hexanediol diglycidyl ether, neopentyl glycol diglycidyl ether, ethylene glycol diglycidyl ether, propylene glycol diglycidyl ether, polyethylene glycol diglycidyl ether, polypropylene glycol diglycidyl ether, sorbitol polyglycidyl ether, glycerol polyglycidyl ether, pentaerythritol polyglycidyl ether, polyglycerol polyglycidyl ether, sorbitan polyglycidyl ether, trimethylolpropane polyglycidyl ether, diglycidyl adipate, diglycidyl o-phthalate, triglycidyl-tris(2-hydroxyethyl)isocyanurate, resorcin diglycidyl ether, and bisphenol-S-diglycidyl ether; and besides, epoxy based resins having two or more epoxy groups in a molecule thereof; and the like.
Incidentally, a use amount of the crosslinking agent is not particularly limited and can be properly selected depending upon a degree of crosslinking. Specifically, it is suitable that the use amount of the crosslinking agent is usually not more than 7 parts by weight (for example, from 0.05 parts by weight to 7 parts by weight) based on 100 parts by weight of the polymer component (particularly, a polymer having a functional group at the molecular chain end). What the use amount of the crosslinking agent is more than 7 parts by weight based on 100 parts by weight of the polymer component is not preferable because the adhesive force is lowered. Incidentally, from the viewpoint of improving the cohesive force, the use amount of the crosslinking agent is preferably 0.05 parts by weight or more based on 100 parts by weight of the polymer component.
Incidentally, in the present invention, instead of the use of the crosslinking agent or together with the use of the crosslinking agent, it is also possible to perform a crosslinking treatment upon irradiation with electron beams, ultraviolet rays, or the like.
The film 2 for back surface of semiconductor is preferably colored. According to this, an excellent appearance can be exhibited, and it becomes possible to make a semiconductor device having a value-added appearance. Specifically, for example, as a semiconductor device, it is possible to classify products thereof by using different colors. In the case where the film 2 for back surface of semiconductor is colored (the case where the film is neither colorless nor transparent), the color shown by coloring is not particularly limited, but for example, it is preferably dark color such as a black, blue or red color, etc., and a black color is especially suitable.
In the present embodiment, the dark color basically means a dark color having L*, as defined in the L*a*b* color space, of not more than 60 (from 0 to 60) [preferably not more than 50 (from 0 to 50), and more preferably not more than 40 (from 0 to 40)].
In addition, the black color basically means a black based color having L*, as defined in the L*a*b* color space, of not more than 35 (from 0 to 35) [preferably not more than 30 (from 0 to 30), and more preferably not more than 25 (from 0 to 25)]. Incidentally, in the black color, each of a* and b*, as defined in the L*a*b* color space, can be suitably selected according to the value of L*. For example, it is suitable that both of a* and b* fall within the range of preferably from −10 to 10, more preferably from −5 to 5, and especially preferably from −3 to 3 (above all, 0 or substantially 0).
Incidentally, in the present embodiment, L*, a*, and b* as defined in the L*a*b* color space can be determined by a measurement with a color difference meter (a trade name: “CR-200”, manufactured by Minolta Camera Co., Ltd; color difference meter). Incidentally, the L*a*b* color space is a color space recommended by the Commission Internationale de l'Eclairage (CIE) in 1976, and means a color space called CIE1976 (L*a*b*) color space. Also, the L*a*b* color space is defined in JIS Z8729 in the Japanese Industrial Standards.
At the time of coloring of the film 2 for back surface of semiconductor, a colorant (coloring agent) can be used according to an objective color. As such a colorant, various dark-colored colorants such as black-colored colorants, blue-colored colorants, red-colored colorants, etc. can be suitably used, and black-colored colorants are especially suitable. The colorant may be any of a pigment, a dye, or the like. The colorant can be used solely or in combination of two or more kinds thereof. Incidentally, as the dye, it is possible to use any form of a dye including an acid dye, a reactive dye, a direct dye, a disperse dye, a cationic dye, and the like. In addition, the pigment is not particularly limited, too with respect to its form and can be properly selected and used among known pigments.
In particular, when a dye is used as the colorant, the dye becomes in a state where it is dispersed uniformly or substantially uniformly by dissolution in the film for back surface of semiconductor, so that the film for back surface of semiconductor (in its turn, the dicing tape-integrated film for back surface of semiconductor) having a uniform or substantially uniform color density can be easily manufactured. Accordingly, when a dye is used as the colorant, the film for back surface of semiconductor in the dicing tape-integrated film for back surface of semiconductor can be allowed to have a uniform or substantially uniform color density and can be enhanced with respect to marking properties and appearance properties.
The black-colored colorant is not particularly limited and can be, for example, properly selected from inorganic black-colored pigments and black-colored dyes. In addition, the black-colored colorant may be a colorant mixture in which a cyan-colored colorant (blue-green colorant), a magenta-colored colorant (red-purple colorant), and a yellow-colored colorant (yellow colorant) are mixed. The black-colored colorant can be used solely or in a combination of two or more kinds thereof. As a matter of course, the black-colored colorant can be used in combination with a colorant of a color other than black.
Specifically, examples of the black-colored colorant include carbon black (such as furnace black, channel black, acetylene black, thermal black, lamp black, etc.), graphite, copper oxide, manganese dioxide, azo based pigments (such as azomethine azo black, etc.), aniline black, perylene black, titanium black, cyanine black, active charcoal, ferrite (such as non-magnetic ferrite, magnetic ferrite, etc.), magnetite, chromium oxide, iron oxide, molybdenum disulfide, a chromium complex, a composite oxide based black pigment, an anthraquinone based organic black pigment, and the like.
In the present invention, as the black-colored colorant, black-colored dyes such as C.I. Solvent Black 3, C.I. Solvent Black 7, C.I. Solvent Black 22, C.I. Solvent Black 27, C.I. Solvent Black 29, C.I. Solvent Black 34, C.I. Solvent Black 43, C.I. Solvent Black 70, C.I. Direct Black 17, C.I. Direct Black 19, C.I. Direct Black 22, C.I. Direct Black 32, C.I. Direct Black C.I. Direct Black 38, C.I. Direct Black 51, C.I. Direct Black 71, C.I. Acid Black 1, C.I. Acid Black 2, C.I. Acid Black 24, C.I. Acid Black 26, C.I. Acid Black 31, C.I. Acid Black 48, C.I. Acid Black 52, C.I. Acid Black 107, C.I. Acid Black 109, C.I. Acid Black 110, C.I. Acid Black 119, C.I. Acid Black 154, C.I. Disperse Black 1, C.I. Disperse Black 3, C.I. Disperse Black 10, C.I. Disperse Black 24, etc.; black-colored pigments such as C.I. Disperse Black 1, C.I. Disperse Black 7, etc.; and the like can also be utilized.
As such black-colored colorants, for example, a trade name “Oil Black BY”, a trade name “Oil Black BS”, a trade name “Oil Black HBB”, a trade name “Oil Black 803”, a trade name “Oil Black 860”, a trade name “Oil Black 5970”, a trade name “Oil Black 5906”, and a trade name “Oil Black 5905” (all of which are manufactured by Orient Chemical Industries Co., Ltd.), and the like are commercially available.
Examples of colorants other than the black-colored colorant include cyan-colored colorants, magenta-colored colorants, and yellow-colored colorants. Examples of the cyan-colored colorant include cyan-colored dyes such as C.I. Solvent Blue 25, C.I. Solvent Blue 36, C.I. Solvent Blue 60, C.I. Solvent Blue 70, C.I. Solvent Blue 93, C.I. Solvent Blue 95, C.I. Acid Blue 6, C.I. Acid Blue 45, etc.; cyan-colored pigments such as C.I. Pigment Blue 1, C.I. Pigment Blue 2, C.I. Pigment Blue 3, C.I. Pigment Blue 15, C.I. Pigment Blue 15:1, C.I. Pigment Blue 15:2, C.I. Pigment Blue 15:3, C.I. Pigment Blue 15:4, C.I. Pigment Blue 15:5, C.I. Pigment Blue 15:6, C.I. Pigment Blue 16, C.I. Pigment Blue 17, C.I. Pigment Blue 17:1, C.I. Pigment Blue 18, C.I. Pigment Blue 22, C.I. Pigment Blue 25, C.I. Pigment Blue 56, C.I. Pigment Blue 60, C.I. Pigment Blue 63, C.I. Pigment Blue 65, C.I. Pigment Blue 66, C.I. Vat Blue 4, C.I. Vat Blue 60, C.I. Pigment Green 7, etc.; and the like.
In addition, among the magenta-colored colorants, examples of magenta-colored dyes include C.I. Solvent Red 1, C.I. Solvent Red 3, C.I. Solvent Red 8, C.I. Solvent Red 23, C.I. Solvent Red 24, C.I. Solvent Red 25, C.I. Solvent Red 27, C.I. Solvent Red 30, C.I. Solvent Red 49, C.I. Solvent Red 52, C.I. Solvent Red 58, C.I. Solvent Red 63, C.I. Solvent Red 81, C.I. Solvent Red 82, C.I. Solvent Red 83, C.I. Solvent Red 84, C.I. Solvent Red 100, C.I. Solvent Red 109, C.I. Solvent Red 111, C.I. Solvent Red 121, C.I. Solvent Red 122, C.I. Disperse Red 9, C.I. Solvent Violet 8, C.I. Solvent Violet 13, C.I. Solvent Violet 14, C.I. Solvent Violet 21, C.I. Solvent Violet 27, C.I. Disperse Violet 1, C.I. Basic Red 1, C.I. Basic Red 2, C.I. Basic Red 9, C.I. Basic Red 12, C.I. Basic Red 13, C.I. Basic Red 14, C.I. Basic Red 15, C.I. Basic Red 17, C.I. Basic Red 18, C.I. Basic Red 22, C.I. Basic Red 23, C.I. Basic Red 24, C.I. Basic Red 27, C.I. Basic Red 29, C.I. Basic Red 32, C.I. Basic Red 34, C.I. Basic Red 35, C.I. Basic Red 36, C.I. Basic Red 37, C.I. Basic Red 38, C.I. Basic Red 39, C.I. Basic Red 40, C.I. Basic Violet 1, C.I. Basic Violet 3, C.I. Basic Violet 7, C.I. Basic Violet 10, C.I. Basic Violet 14, C.I. Basic Violet 15, C.I. Basic Violet 21, C.I. Basic Violet 25, C.I. Basic Violet 26, C.I. Basic Violet 27, C.I. Basic Violet 28, and the like.
Among the magenta-colored colorants, examples of magenta-colored pigments include C.I. Pigment Red 1, C.I. Pigment Red 2, C.I. Pigment Red 3, C.I. Pigment Red 4, C.I. Pigment Red 5, C.I. Pigment Red 6, C.I. Pigment Red 7, C.I. Pigment Red 8, C.I. Pigment Red 9, C.I. Pigment Red 10, C.I. Pigment Red 11, C.I. Pigment Red 12, C.I. Pigment Red 13, C.I. Pigment Red 14, C.I. Pigment Red 15, C.I. Pigment Red 16, C.I. Pigment Red 17, C.I. Pigment Red 18, C.I. Pigment Red 19, C.I. Pigment Red 21, C.I. Pigment Red 22, C.I. Pigment Red 23, C.I. Pigment Red 30, C.I. Pigment Red 31, C.I. Pigment Red 32, C.I. Pigment Red 37, C.I. Pigment Red 38, C.I. Pigment Red 39, C.I. Pigment Red 40, C.I. Pigment Red 41, C.I. Pigment Red 42, C.I. Pigment Red 48:1, C.I. Pigment Red 48:2, C.I. Pigment Red 48:3, C.I. Pigment Red 48:4, C.I. Pigment Red 49, C.I. Pigment Red 49:1, C.I. Pigment Red 50, C.I. Pigment Red 51, C.I. Pigment Red 52, C.I. Pigment Red 52:2, C.I. Pigment Red 53:1, C.I. Pigment Red 54, C.I. Pigment Red 55, C.I. Pigment Red 56, C.I. Pigment Red 57:1, C.I. Pigment Red 58, C.I. Pigment Red 60, C.I. Pigment Red 60:1, C.I. Pigment Red 63, C.I. Pigment Red 63:1, C.I. Pigment Red 63:2, C.I. Pigment Red 64, C.I. Pigment Red 64:1, C.I. Pigment Red 67, C.I. Pigment Red 68, C.I. Pigment Red 81, C.I. Pigment Red 83, C.I. Pigment Red 87, C.I. Pigment Red 88, C.I. Pigment Red 89, C.I. Pigment Red 90, C.I. Pigment Red 92, C.I. Pigment Red 101, C.I. Pigment Red 104, C.I. Pigment Red 105, C.I. Pigment Red 106, C.I. Pigment Red 108, C.I. Pigment Red 112, C.I. Pigment Red 114, C.I. Pigment Red 122, C.I. Pigment Red 123, C.I. Pigment Red 139, C.I. Pigment Red 144, C.I. Pigment Red 146, C.I. Pigment Red 147, C.I. Pigment Red 149, C.I. Pigment Red 150, C.I. Pigment Red 151, C.I. Pigment Red 163, C.I. Pigment Red 166, C.I. Pigment Red 168, C.I. Pigment Red 170, C.I. Pigment Red 171, C.I. Pigment Red 172, C.I. Pigment Red 175, C.I. Pigment Red 176, C.I. Pigment Red 177, C.I. Pigment Red 178, C.I. Pigment Red 179, C.I. Pigment Red 184, C.I. Pigment Red 185, C.I. Pigment Red 187, C.I. Pigment Red 190, C.I. Pigment Red 193, C.I. Pigment Red 202, C.I. Pigment Red 206, C.I. Pigment Red 207, C.I. Pigment Red 209, C.I. Pigment Red 219, C.I. Pigment Red 222, C.I. Pigment Red 224, C.I. Pigment Red 238, C.I. Pigment Red 245, C.I. Pigment Violet 3, C.I. Pigment Violet 9, C.I. Pigment Violet 19, C.I. Pigment Violet 23, C.I. Pigment Violet 31, C.I. Pigment Violet 32, C.I. Pigment Violet 33, C.I. Pigment Violet 36, C.I. Pigment Violet 38, C.I. Pigment Violet 43, C.I. Pigment Violet 50, C.I. Vat Red 1, C.I. Vat Red 2, C.I. Vat Red 10, C.I. Vat Red 13, C.I. Vat Red 15, C.I. Vat Red 23, C.I. Vat Red 29, C.I. Vat Red 35, and the like.
In addition, examples of the yellow-colored colorant include yellow-colored dyes such as C.I. Solvent Yellow 19, C.I. Solvent Yellow 44, C.I. Solvent Yellow 77, C.I. Solvent Yellow 79, C.I. Solvent Yellow 81, C.I. Solvent Yellow 82, C.I. Solvent Yellow 93, C.I. Solvent Yellow 98, C.I. Solvent Yellow 103, C.I. Solvent Yellow 104, C.I. Solvent Yellow 112, C.I. Solvent Yellow 162, etc.; yellow-colored pigments such as C.I. Pigment Orange 31, C.I. Pigment Orange 43, C.I. Pigment Yellow 1, C.I. Pigment Yellow 2, C.I. Pigment Yellow 3, C.I. Pigment Yellow 4, C.I. Pigment Yellow 5, C.I. Pigment Yellow 6, C.I. Pigment Yellow 7, C.I. Pigment Yellow 10, C.I. Pigment Yellow 11, C.I. Pigment Yellow 12, C.I. Pigment Yellow 13, C.I. Pigment Yellow 14, C.I. Pigment Yellow 15, C.I. Pigment Yellow 16, C.I. Pigment Yellow 17, C.I. Pigment Yellow 23, C.I. Pigment Yellow 24, C.I. Pigment Yellow 34, C.I. Pigment Yellow 35, C.I. Pigment Yellow 37, C.I. Pigment Yellow 42, C.I. Pigment Yellow 53, C.I. Pigment Yellow 55, C.I. Pigment Yellow 65, C.I. Pigment Yellow 73, C.I. Pigment Yellow 74, C.I. Pigment Yellow 75, C.I. Pigment Yellow 81, C.I. Pigment Yellow 83, C.I. Pigment Yellow 93, C.I. Pigment Yellow 94, C.I. Pigment Yellow 95, C.I. Pigment Yellow 97, C.I. Pigment Yellow 98, C.I. Pigment Yellow 100, C.I. Pigment Yellow 101, C.I. Pigment Yellow 104, C.I. Pigment Yellow 108, C.I. Pigment Yellow 109, C.I. Pigment Yellow 110, C.I. Pigment Yellow 113, C.I. Pigment Yellow 114, C.I. Pigment Yellow 116, C.I. Pigment Yellow 117, C.I. Pigment Yellow 120, C.I. Pigment Yellow 128, C.I. Pigment Yellow 129, C.I. Pigment Yellow 133, C.I. Pigment Yellow 138, C.I. Pigment Yellow 139, C.I. Pigment Yellow 147, C.I. Pigment Yellow 150, C.I. Pigment Yellow 151, C.I. Pigment Yellow 153, C.I. Pigment Yellow 154, C.I. Pigment Yellow 155, C.I. Pigment Yellow 156, C.I. Pigment Yellow 167, C.I. Pigment Yellow 172, C.I. Pigment Yellow 173, C.I. Pigment Yellow 180, C.I. Pigment Yellow 185, C.I. Pigment Yellow 195, C.I. Vat Yellow 1, C.I. Vat Yellow 3, C.I. Vat Yellow 20, etc.; and the like.
Various colorants such as cyan-colored colorants, magenta-colored colorants, yellow-colored colorants, etc. can be used solely or in combination of two or more kinds thereof, respectively. Incidentally, in the case where two or more kinds of various colorants such as cyan-colored colorants, magenta-colored colorants, yellow-colored colorants, etc. are used, a mixing proportion (or blending proportion) of these colorants is not particularly limited and can be properly selected according to the kind of each colorant, an objective color, and the like.
In the case where the film 2 for back surface of semiconductor is colored, its colored form is not particularly limited. The film for back surface of semiconductor may be, for example, a single-layer film-shaped material having a coloring agent added thereto. In addition, the film may be a laminated film in which at least a resin layer formed of at least a thermosetting resin component and a coloring agent layer are laminated. Incidentally, in the case where the film 2 for back surface of semiconductor is a laminated film of the resin layer and the coloring agent layer, the film 2 for back surface of semiconductor in a laminated form preferably has a laminated form of resin layer/coloring agent layer/resin layer. In that case, the two resin layers on the both sides of the coloring agent layer may be a resin layer having the same composition or may be a resin layer having a different composition from each other.
The film 2 for back surface of semiconductor can be preferably blended with other additives according to the need. Examples of the other additives include, in addition to a filler, a flame retardant, a silane coupling agent, and an ion trapping agent, an extender, an anti-aging agent, an antioxidant, a surfactant, and the like.
Though the filler may be either an inorganic filler or an organic filler, it is suitably an inorganic filler. By blending a filler such as an inorganic filler, etc., it is possible to contrive to impart electric conductivity to the film for back surface of semiconductor or improve the thermal conductivity, or to adjust the elastic modulus, or the like. Incidentally, the film 2 for back surface of semiconductor may be electrically conductive or non-electrically conductive. Examples of the inorganic filler include various inorganic powders composed of silica, clay, gypsum, calcium carbonate, barium sulfate, alumina oxide, beryllium oxide, ceramics such as silicon carbide, silicon nitride, etc., metals or alloys such as aluminum, copper, silver, gold, nickel, chromium, lead, tin, zinc, palladium, solder, etc., carbon, and the like. The filler can be used solely or in combination of two or more kinds thereof. Above all, the filler is suitably silica, especially fused silica. Incidentally, an average particle diameter of the inorganic filler is preferably within the range of from 0.1 μm to 80 μm. The average particle diameter of the inorganic filler can be measured, for example, by a laser diffraction type particle size distribution measurement apparatus.
A blending amount of the filler (particularly, inorganic filler) is preferably not more than 80 parts by weight (from 0 part by weight to 80 parts by weight), and especially suitably from 0 part by weight to 70 parts by weight based on 100 parts by weight of the organic resin component.
In addition, examples of the flame retardant include antimony trioxide, antimony pentoxide, brominated epoxy resins, and the like. The flame retardant can be used solely or in combination of two or more kinds thereof. Examples of the silane coupling agent include β-(3,4-epoxycyclohexyl)ethyltrimethoxysilane, γ-glycidoxypropyltrimethoxysilane, γ-glycidoxypropylmethyldiethoxysilane, and the like. The silane coupling agent can be used solely or in combination of two or more kinds thereof. Examples of the ion trapping agent include hydrotalcites, bismuth hydroxide, and the like. The ion trapping agent can be used solely or in combination of two or more kinds thereof.
The film 2 for back surface of semiconductor can be, for example, formed utilizing a customary method in which a thermosetting resin component such as an epoxy resin, etc. and optionally a thermoplastic resin component such as an acrylic resin, etc. (for example, a thermoplastic resin having a Tg of from 25° C. to 200° C., such as an acrylic resin having a Tg of from 25° C. to 200° C., etc.), and also optionally a solvent or other additives and the like are mixed to prepare a resin composition, which is then formed into a film-shaped layer. Specifically, a film-shaped layer (adhesive layer) as the film for back surface of semiconductor can be, for example, formed by a method of coating the foregoing resin composition on the pressure-sensitive adhesive layer 32 of the dicing tape; a method of coating the foregoing resin composition on an appropriate separator (such as release paper, etc.) to form a resin layer (or an adhesive layer), which is then transferred (transcribed) onto the pressure-sensitive adhesive layer 32, or the like. Incidentally, the foregoing resin composition may be either a solution or a dispersion liquid.
Incidentally, in the case where the film 2 for back surface of semiconductor is formed of a resin composition containing a thermosetting resin component such as an epoxy resin, etc., the film 2 for back surface of semiconductor is in a state where the thermosetting resin component is uncured or partially cured at a stage before the film is applied onto a semiconductor wafer. In that case, after the film is applied onto the semiconductor wafer (specifically, in general, at the time of curing the encapsulating material in a flip-chip bonding step), the thermosetting resin component in the film for back surface of semiconductor is cured completely or substantially completely.
In this way, even if the film 2 for back surface of semiconductor contains a thermosetting resin component, the thermosetting resin component is in an uncured or partially cured state. Therefore, a gel fraction of the film 2 for back surface of semiconductor is not particularly limited, but for example, it can be properly selected within the range of not more than 50% by weight (from 0% by weight to 50% by weight). Suitably, the gel fraction of the film 2 for back surface of semiconductor is preferably not more than 30% by weight (from 0% by weight to 30% by weight), and especially preferably not more than 10% by weight (from 0% by weight to 10% by weight). As for a method of measuring the gel fraction of the film 2 for back surface of semiconductor, the measurement can be conducted by the following measuring method.
<Measuring Method of Gel Fraction>
About 0.1 g of a sample is sampled from the film 2 for back surface of semiconductor and precisely weighed (weight of sample), and after the sample is wrapped in a mesh-type sheet, it is dipped in about 50 mL of toluene at room temperature for one week. Thereafter, a solvent-insoluble matter (contents in the mesh-type sheet) is taken out of the toluene and dried at 130° C. for about 2 hours, the solvent-insoluble matter after drying is weighed (weight after dipping and drying), and a gel fraction (% by weight) is then calculated according to the following expression (a).
Gel fraction (% by weight)=[(Weight after dipping and drying)/(Weight of sample)]×100 (a)
Incidentally, the gel fraction of the film 2 for back surface of semiconductor can be controlled by the kind of a resin component and its content and the kind of a crosslinking agent and its content, and besides, heating temperature, heating time, and the like.
In the present invention, in the case where the film 2 for back surface of semiconductor is a film-shaped material formed of a resin composition containing a thermosetting resin component such as an epoxy resin, etc., adhesion to the semiconductor wafer can be effectively exhibited.
Incidentally, since cutting water is used in the dicing step of the semiconductor wafer, there may be the case where the film 2 for back surface semiconductor absorbs moisture to have a moisture content of a normal state or more. When flip-chip bonding is performed in such a high-moisture content state, there may be the case where water vapor remains at an adhesive interface between the film 2 for back surface of semiconductor and the semiconductor wafer or its processed body (semiconductor), thereby generating lifting. In consequence, by configuring the film 2 for back surface of semiconductor in such a manner that a core material with high moisture permeability is interposed by adhesive layers, water vapor diffuses, thereby making it possible to avoid such a problem. From such a viewpoint, a multilayered structure in which the film 2 for back surface of semiconductor is formed on one surface or both surfaces of the core material may be used as the film for back surface of semiconductor. Examples of the core material include films (for example, polyimide films, polyester films, polyethylene terephthalate films, polyethylene naphthalate films, polycarbonate films, etc.), resin substrates reinforced with a glass fiber or a plastic-made nonwoven fiber, silicon substrates, glass substrates, and the like.
A thickness (total thickness in the case of the laminated film) of the film 2 for back surface of semiconductor is not particularly limited, but it can be, for example, properly selected within the range of from about 2 to 500 μm, and preferably from about 2 μm to 200 μm. Furthermore, the thickness is preferably from about 4 μm to 160 μm, more preferably from about 6 μm to 100 μm, and especially, preferably about 10 μm to 80 μm. In addition, in the case where the film 2 for back surface of semiconductor includes at least a layer formed of at least a thermosetting resin component and containing no thermoplastic resin component, it is also a preferred embodiment to regulate its thickness to from 5 to 500 μm.
Suitably, a tensile storage elastic modulus of the film 2 for back surface of semiconductor in an uncured state at 23° C. is preferably 1 GPa or more (for example, from 1 GPa to 50 GPa), more preferably 2 GPa or more, and especially preferably 3 GPa or more. When the tensile storage elastic modulus is 1 GPa or more, sticking of the film for back surface of semiconductor to a support can be effectively suppressed or prevented at the time when after the semiconductor chip is peeled off from the pressure-sensitive adhesive layer 32 of the dicing tape together with the film 2 for back surface of semiconductor, the film 2 for back surface of semiconductor is placed on the support, and transportation or the like is performed. Incidentally, the support is, for example, a top tape, a bottom tape, or the like in a carrier tape. Incidentally, in the case where the film 2 for back surface of semiconductor is formed of a resin composition containing a thermosetting resin component, as described above, the thermosetting resin component is usually in an uncured or partially cured state, so that the tensile storage elastic modulus of the film for back surface of semiconductor at 23° C. is in general a tensile storage elastic modulus at 23° C. in a state where the thermosetting resin component is uncured or partially cured.
Here, the film 2 for back surface of semiconductor may be either a single layer or a laminated film where plural layers are laminated. In the case of a laminated film, it is sufficient that the tensile storage elastic modulus of the whole laminated film is in the range of 1 GPa or more (for example, from 10 GPa to 50 GPa). In addition, the tensile storage elastic modulus (at 23° C.) of the film for back surface of semiconductor in an uncured state can be controlled by properly setting up the kind of a resin component (a thermoplastic resin or a thermosetting resin) and its amount, or the kind of a filler such as a silica filler, etc. and its amount, or the like. Incidentally, in the case where the film for back surface of semiconductor is a laminated film where plural layers are laminated (in the case where the film for back surface of semiconductor has a laminated layer form), as the laminated layer form, for example, a laminated layer form composed of a wafer adhesive layer and a laser marking layer, and the like can be exemplified. In addition, between the wafer adhesive layer and the laser marking layer, other layers (an interlayer, a light-shielding layer, a reinforcing layer, a colored layer, a base material layer, an electromagnetic wave-shielding layer, a thermally conductive layer, a pressure-sensitive adhesive layer, etc.) may be provided. Incidentally, the wafer adhesive layer is a layer which exhibits excellent adhesion (adhesiveness) to a wafer and is a layer which comes into contact with the back surface of the wafer. On the other hand, the laser marking layer is a layer which exhibits excellent laser marking properties and is a layer which is utilized at the time of performing laser marking on the back surface of a semiconductor chip.
Incidentally, as for the tensile storage elastic modulus, the film 2 for back surface of semiconductor in an uncured state is fabricated without being laminated on the dicing tape 3 and then measured in a tensile mode under conditions of a sample width of 10 mm, a sample length of 22.5 mm, a sample thickness of 0.2 mm, a frequency of 1 Hz, and a temperature elevating rate of 10° C./minute in a nitrogen atmosphere at a prescribed temperature (23° C.) using a dynamic viscoelasticity measuring apparatus “Solid Analyzer RS A2”, manufactured by Rheometrics Co., Ltd., and the measured elastic modulus is regarded as a value of the tensile storage elastic modulus.
Preferably, the film 2 for back surface of semiconductor is protected with a separator (release liner) (not illustrated). The separator has a function as a protective material for protecting the film for back surface of semiconductor until it is put into practical use. In addition, the separator can be further used as a supporting base material at the time of transferring the film 2 for back surface of semiconductor onto the pressure-sensitive adhesive layer 32 on the base material of the dicing tape. The separator is peeled off when a semiconductor wafer is stuck onto the film for back surface of semiconductor of the dicing tape-integrated film 1 for back surface of semiconductor. As the separator, polyethylene, polypropylene, and a plastic film (such as polyethylene terephthalate, etc.) or paper or the like, the surface of which is coated with a release agent such as a fluorine based release agent, a long-chain alkyl acrylate based release agent, etc., can also be used. Incidentally, the separator can be formed by a conventionally known method. In addition, a thickness or the like of the separator is not particularly limited.
In the case where the film 2 for back surface semiconductor is not laminated on the dicing tape 3, the film 2 for back surface of semiconductor may be wound up in a rolled form using one separator having a release layer on both surfaces thereof, or it may be protected with a separator having a release layer on both surfaces thereof or may be protected with a separator having a release layer on at least one surface thereof.
(Dicing Tape)
The dicing tape 3 is configured such that the pressure-sensitive adhesive layer 32 is formed on the base material 31. In this way, it is sufficient that the dicing tape 3 has a configuration in which the base material 31 and the pressure-sensitive adhesive layer 32 are laminated. The base material (supporting base material) 31 can be used as a supporting parent body for the pressure-sensitive adhesive layer 32 or the like. The base material 31 preferably has radiation-transmitting properties. As the base material 31, for example, proper thin materials, for example, paper based base materials such as paper, etc.; fiber based base materials such as fabrics, nonwoven fabrics, felts, nets, etc.; metal based base materials such as metal foils, metal plates, etc.; plastic base materials such as plastic films or sheets, etc.; rubber based base materials such as rubber sheets, etc.; foamed bodies such as foamed sheets, etc.; and laminates thereof [particularly, laminates of a plastic based base material with other base material, laminates of plastic films (or sheets) each other, etc.]; and the like can be used. In the present invention, as the base material, plastic based base materials such as plastic films or sheets, etc. can be suitably employed. Examples of raw materials for such plastic materials include olefin based resins such as polyethylene (PE), polypropylene (PP), an ethylene-propylene copolymer, etc.; copolymers composed of ethylene as a monomer component, such as an ethylene-vinyl acetate copolymer (EVA), an ionomer resin, an ethylene-(meth)acrylic acid copolymer, an ethylene-(meth)acrylic acid ester (random or alternating) copolymer, etc.; polyesters such as polyethylene terephthalate (PET), polyethylene naphthalate (PEN), polybutylene terephthalate (PBT), etc.; acrylic resins; polyvinyl chloride (PVC); polyurethanes; polycarbonates; polyphenylene sulfide (PPS); amide based resins such as polyamides (nylon), wholly aromatic polyamides (aramid), etc.; polyetheretherketones (PEEK); polyimides; polyetherimides; polyvinylidene chloride; ABS (acrylonitrile-butadiene-styrene copolymer); cellulose based resins; silicone resins; fluorinated resins; and the like.
In addition, examples of the material for the base material 31 include polymers such as crosslinked materials of the foregoing resins, and the like. The plastic film may be used without being stretched or may be used after being subjected to a uniaxial or biaxial stretching treatment, if desired. According to the resin sheet to which thermal contraction properties have been imparted by a stretching treatment or the like, an adhered area between the pressure-sensitive adhesive layer 32 and the film 2 for back surface of semiconductor is reduced by thermal contraction of the base material 31 after dicing, so that it is possible to contrive to make it easy to recover the semiconductor chip.
In order to enhance adhesion to an adjacent layer, holding properties, and the like, the surface of the base material 31 may be subjected to a customary surface treatment, for example, an oxidation treatment by a chemical or physical treatment such as a chromate treatment, ozone exposure, flame exposure, exposure to high-voltage electric shock, an ionized radiation treatment, etc., a coating treatment with an undercoating agent, or the like.
As the base material 31, the same kind or different kinds of materials can be properly selected and used. If desired, a blend of several kinds of materials can be used. In addition, in order to impart antistatic ability to the base material 31, a vapor deposition layer of an electrically conductive substance having a thickness of from about 30 to 500 angstroms, which is composed of a metal, an alloy, or an oxide thereof, can be formed on the base material 31. The base material 31 may be a single layer or a laminated layer of two or more layers.
A thickness (total thickness in the case of a laminated layer) of the base material 31 is not particularly limited, and it can be properly selected depending upon strength, flexibility, intended purpose of use, or the like. For example, the thickness is generally not more than about 1,000 μm (for example, from about 1 μm to 1,000 μm), preferably from about 10 μm to 500 μm, more preferably from about 20 μm to 300 μm, and especially preferably from about 30 μm to 200 μm. However, it should not be construed that the thickness of the base material 31 is limited thereto. In addition, in the case where film for back surface of flip-chip semiconductor includes at least a layer formed of at least a thermosetting resin component and containing no thermoplastic resin component, it is also a preferred embodiment to regulate the thickness of the base material to from about 1 μm to 500 μm, preferably from about 3 μm to 300 μm, and more preferably from about 5 μm to 250 μm.
Incidentally, the base material 31 may contain various additives (a coloring agent, a filler, a plasticizer, an anti-aging agent, an antioxidant, a surfactant, a flame retardant, etc.) within the range where the effects and the like of the present invention are not impaired.
The pressure-sensitive adhesive layer 32 is formed of a pressure-sensitive adhesive and has pressure-sensitive adhesiveness. Such a pressure-sensitive adhesive is not particularly limited, and it can be properly selected among known pressure-sensitive adhesives. Specifically, as the pressure-sensitive adhesive, for example, those having the foregoing characteristics can be properly selected and used among known pressure-sensitive adhesives such as acrylic pressure-sensitive adhesives, rubber based pressure-sensitive adhesives, vinyl alkyl ether based pressure-sensitive adhesives, silicone based pressure-sensitive adhesives, polyester based pressure-sensitive adhesives, polyamide based pressure-sensitive adhesives, urethane based pressure-sensitive adhesives, fluorine based pressure-sensitive adhesives, styrene-diene block copolymer based pressure-sensitive adhesives, creep characteristics-improved pressure-sensitive adhesives prepared by blending a heat fusible resin having a melting point of not higher than about 200° C. in the foregoing pressure-sensitive adhesive (see, for example, JP-A-56-61468, JP-A-61-174857, JP-A-63-17981, JP-A-56-13040, and the like). In addition, radiation-curable pressure-sensitive adhesives (or energy ray-curable pressure-sensitive adhesives) and thermally expandable pressure-sensitive adhesives can also be used as the pressure-sensitive adhesive. The pressure-sensitive adhesive can be used solely or in combination of two or more kinds thereof.
As the pressure-sensitive adhesive, acrylic pressure-sensitive adhesives and rubber based pressure-sensitive adhesives can be suitably used, with acrylic pressure-sensitive adhesives being especially suitable. Examples of the acrylic pressure-sensitive adhesive include acrylic pressure-sensitive adhesives containing, as a base polymer, an acrylic polymer (homopolymer or copolymer) using one or two or more kinds of alkyl (meth)acrylates as a monomer component.
Examples of the alkyl (meth)acrylate in the acrylic pressure-sensitive adhesive include alkyl (meth)acrylates such as methyl (meth)acrylate, ethyl (meth)acrylate, propyl (meth)acrylate, isopropyl (meth)acrylate, butyl (meth)acrylate, isobutyl (meth)acrylate, s-butyl (meth)acrylate, t-butyl (meth)acrylate, pentyl (meth)acrylate, hexyl (meth)acrylate, heptyl (meth)acrylate, octyl (meth)acrylate, 2-ethylhexyl (meth)acrylate, isooctyl (meth)acrylate, nonyl (meth)acrylate, isononyl (meth)acrylate, decyl (meth)acrylate, isodecyl (meth)acrylate, undecyl (meth)acrylate, dodecyl (meth)acrylate, tridecyl (meth)acrylate, tetradecyl (meth)acrylate, pentadecyl (meth)acrylate, hexadecyl (meth)acrylate, heptadecyl (meth)acrylate, octadecyl (meth)acrylate, nonadecyl (meth)acrylate, eicosyl (meth)acrylate, etc. As the alkyl (meth)acrylate, alkyl (meth)acrylates in which a carbon number of an alkyl group thereof is from 4 to 18 are suitable. Incidentally, the alkyl group of the alkyl (meth)acrylate may be either linear or branched.
Incidentally, for the purpose of improving cohesive force, heat resistance, crosslinking properties, and the like, the acrylic polymer may contain a unit corresponding to other monomer component copolymerizable with the alkyl (meth)acrylate (copolymerizable monomer component), if desired. Examples of such a copolymerizable monomer component include carboxyl group-containing monomers such as (meth)acrylic acid (acrylic acid and methacrylic acid), carboxyethyl acrylate, carboxypentyl acrylate, itaconic acid, maleic acid, fumaric acid, crotonic acid, etc.; acid anhydride group-containing monomers such as maleic anhydride, itaconic anhydride, etc.; hydroxyl group-containing monomers such as hydroxyethyl (meth)acrylate, hydroxypropyl (meth)acrylate, hydroxybutyl (meth)acrylate, hydroxyhexyl (meth)acrylate, hydroxyoctyl (meth)acrylate, hydroxydecyl (meth)acrylate, hydroxylauryl (meth)acrylate, (4-hydroxymethylcyclohexyl)methyl methacrylate, etc.; sulfonic acid group-containing monomers such as styrenesulfonic acid, allylsulfonic acid, 2-(meth)acrylamido-2-methylpropanesulfonic acid, (meth)acrylamidopropanesulfonic acid, sulfopropyl (meth)acrylate, (meth)acryloyloxynaphthalenesulfonic acid, etc.; phosphoric acid group-containing monomers such as 2-hydroxyethyl acryloylphosphate, etc.; (N-substituted) amide based monomers such as (meth)acrylamide, N,N-dimethyl(meth)acrylamide, N-butyl(meth)acrylamide, N-methylol(meth)acrylamide, N-methylolpropane(meth)acrylamide, etc.; aminoalkyl (meth)acrylate based monomers such as aminoethyl (meth)acrylate, N,N-dimethylaminoethyl (meth)acrylate, t-butylaminoethyl (meth)acrylate, etc.; alkoxyalkyl (meth)acrylate based monomers such as methoxyethyl (meth)acrylate, ethoxyethyl (meth)acrylate, etc.; cyanoacrylate monomers such as acrylonitrile, methacrylonitrile, etc.; epoxy group-containing acrylic monomers such as glycidyl (meth)acrylate, etc.; styrene based monomers such as styrene, α-methylstyrene, etc.; vinyl ester based monomers such as vinyl acetate, vinyl propionate, etc.; olefin based monomers such as isoprene, butadiene, isobutylene, etc.; vinyl ether based monomers such as vinyl ether, etc.; nitrogen-containing monomers such as N-vinylpyrrolidone, methylvinylpyrrolidone, vinylpyridine, vinylpiperidone, vinylpyrimidine, vinylpiperazine, vinylpyrazine, vinylpyrrole, vinylimidazole, vinyloxazole, vinylmorpholine, N-vinylcarbonamides, N-vinylcaprolactam, etc.; maleimide based monomers such as N-cyclohexylmaleimide, N-isopropylmaleimide, N-laurylmaleimide, N-phenylmaleimide, etc.; itaconimide based monomers such as N-methylitaconimide, N-ethylitaconimide, N-butylitaconimide, N-octylitaconimide, N-2-ethylhexylitaconimide, N-cyclohexylitaconimide, N-laurylitaconimide, etc.; succinimide based monomers such as N-(meth)acryloyloxymethylenesuccinimide, N-(meth)acryloyl-6-oxyhexamethylenesuccinimide, N-(meth)acryloyl-8-oxyoctamethylenesuccinimide, etc.; glycol based acrylic ester monomers such as polyethylene glycol (meth)acrylate, polypropylene glycol (meth)acrylate, methoxyethylene glycol (meth)acrylate, methoxypolypropylene glycol (meth)acrylate, etc.; acrylate based monomers having a hetero ring, a halogen atom, a silicone atom, or the like, such as tetrahydrofurfuryl (meth)acrylate, fluoro(meth)acrylate, silicone (meth)acrylate, etc.; polyfunctional monomers such as hexanediol di(meth)acrylate, (poly)ethylene glycol di(meth)acrylate, (poly)propylene glycol di(meth)acrylate, neopentylglycol di(meth)acrylate, pentaerythritol di(meth)acrylate, trimethylolpropane tri(meth)acrylate, pentaerythritol tri(meth)acrylate, dipentaerythritol hexa(meth)acrylate, epoxy acrylate, polyester acrylate, urethane acrylate, divinylbenzene, butyl di(meth)acrylate, hexyl di(meth)acrylate, etc.; and the like. These copolymerizable monomer components can be used solely or in combination of two or kinds thereof.
In the case of using a radiation-curable pressure-sensitive adhesive (or energy ray-curable pressure-sensitive adhesive) as the pressure-sensitive adhesive, examples of the radiation-curable pressure-sensitive adhesive (composition) include an internal type radiation-curable pressure-sensitive adhesive composed of, as a base polymer, a polymer having a radical reactive carbon-carbon double bond in a polymer side chain, main chain or main chain terminal thereof; a radiation-curable pressure-sensitive adhesive having an ultraviolet ray-curable monomer component or oligomer component blended in a pressure-sensitive adhesive; and the like. In addition, in the case of using a thermally expandable pressure-sensitive adhesive as the pressure-sensitive adhesive, examples of the thermally expandable pressure-sensitive adhesive include a thermally expandable pressure-sensitive adhesive containing a pressure-sensitive adhesive and a foaming agent (especially thermally expandable microspheres); and the like.
In the present invention, the pressure-sensitive adhesive layer 32 may contain various additives (for example, a tackifying resin, a coloring agent, a thickener, an extender, a filler, a plasticizer, an anti-aging agent, an antioxidant, a surfactant, a crosslinking agent, etc.) within the range where the effects of the present invention are not impaired.
The crosslinking agent can be used for the purposes of adjusting a pressure-sensitive adhesive force before irradiation with ultraviolet rays, adjusting a pressure-sensitive adhesive force after irradiation with ultraviolet rays, and the like. By using the crosslinking agent, external crosslinking can be achieved. The crosslinking agent is not particularly limited, and known crosslinking agents can be used. Specifically, examples of the crosslinking agent include, in addition to isocyanate based crosslinking agents, epoxy based crosslinking agents, melamine based crosslinking agents, and peroxide based crosslinking agents, urea based crosslinking agents, metal alkoxide based crosslinking agents, metal chelate based crosslinking agents, metal salt based crosslinking agents, carbodiimide based crosslinking agents, oxazoline based crosslinking agents, aziridine based crosslinking agents, amine based crosslinking agents, and the like, with isocyanate based crosslinking agents and epoxy based crosslinking agents being suitable. The crosslinking agent can be used solely or in combination of two or more kinds thereof. Incidentally, though a use amount of the crosslinking agent is not particularly limited, it is properly determined depending upon a balance with a base polymer (particularly, an acrylic polymer) to be crosslinked and further depending upon a use application as the pressure-sensitive adhesive. In general, the crosslinking agent is blended in an amount of preferably not more than about 20 parts by weight, and more preferably from 0.1 parts by weight to 10 parts by weight based on 100 parts by weight of the base polymer.
Examples of the isocyanate based crosslinking agent include lower aliphatic polyisocyanates such as 1,2-ethylene diisocyanate, 1,4-butylene diisocyanate, 1,6-hexamethylene diisocyanate, etc.; alicyclic polyisocyanates such as cyclopentylene diisocyanate, cyclohexylene diisocyanate, isophorone diisocyanate, hydrogenated tolylene diisocyanate, hydrogenated xylylene diisocyanate, etc.; aromatic polyisocyanates such as 2,4-tolylene diisocyanate, 2,6-tolylene diisocyanate, 4,4′-diphenylmethane diisocyanate, xylylene diisocyanate, etc.; and the like. Besides, a trimethylolpropane/tolylene diisocyanate trimer adduct (a trade name: “COLONATE L”, manufactured by Nippon Polyurethane Industry Co., Ltd.), a trimethylolpropane/hexamethylene diisocyanate trimer adduct (a trade name: “COLONATE HL”, manufactured by Nippon Polyurethane Industry Co., Ltd.), and the like are also used. In addition, examples of the epoxy based crosslinking agent include N,N,N′,N′-tetraglycidyl-m-xylenediamine, diglycidylaniline, 1,3-bis(N,N-glycidylaminomethyl)cyclohexane, 1,6-hexanediol diglycidyl ether, neopentyl glycol diglycidyl ether, ethylene glycol diglycidyl ether, propylene glycol diglycidyl ether, polyethylene glycol diglycidyl ether, polypropylene glycol diglycidyl ether, sorbitol polyglycidyl ether, glycerol polyglycidyl ether, pentaerythritol polyglycidyl ether, polyglycerol polyglycidyl ether, sorbitan polyglycidyl ether, trimethylolpropane polyglycidyl ether, diglycidyl adipate, diglycidyl o-phthalate, triglycidyl-tris(2-hydroxyethyl) isocyanurate, resorcin diglycidyl ether, and bisphenol-S-diglycidyl ether; and besides, epoxy based resins having two or more epoxy groups in a molecule thereof; and the like.
Incidentally, in the present invention, in place of the use of the crosslinking agent or along with the crosslinking agent, it is also possible to apply a crosslinking treatment upon irradiation with electron beams or ultraviolet rays.
The pressure-sensitive adhesive layer 32 can be, for example, formed by utilizing a customary method including mixing a pressure-sensitive adhesive and optional solvent and other additives, followed by forming into a sheet-shaped layer. Specifically, the pressure-sensitive adhesive layer 32 can be, for example, formed by a method of coating a mixture containing a pressure-sensitive adhesive and optional solvent and other additives on the base material 31; a method of coating the foregoing mixture on an appropriate separator (a release paper, etc.) to form the pressure-sensitive adhesive layer 32 and then transferring (transcribing) it onto the base material 31; or the like.
A thickness of the pressure-sensitive adhesive layer 32 is not particularly limited, and for example, it is from about 5 μm to 300 μm (preferably from 5 μm to 200 μm, more preferably from 5 μm to 100 μm, still more preferably from 5 μm to 80 μm, yet still more preferably from 15 μm to 50 μm, and especially preferably from 7 μm to 50 μm). When the thickness of the pressure-sensitive adhesive layer 32 falls within the foregoing range, an appropriate pressure-sensitive adhesive force can be revealed. Incidentally, the pressure-sensitive adhesive layer 32 may be of either a single layer structure or a multilayer structure.
The adhesive force of the pressure-sensitive adhesive layer 32 of the dicing tape 3 to the film 2 for back surface of flip-chip semiconductor (23° C., peeling angle: 180°, peeling rate: 300 mm/min) is preferably in the range of from 0.02 N/20 mm to 10 N/20 mm, and more preferably in the range of from 0.05 N/20 mm to 5 N/20 mm. By regulating the adhesive force to 0.02 N/20 mm or more, at the time of dicing of the semiconductor wafer, the generation of chip flying out can be prevented. On the other hand, by regulating the adhesive force to not more than 10 N/20 mm, at the time of picking-up of the semiconductor element, it is possible to prevent the generation of the matter that peeling of the subject semiconductor element becomes difficult, or that the pressure-sensitive adhesive remains.
Incidentally, in the present invention, the film 2 for back surface of semiconductor or the dicing tape-integrated film 1 for back surface of semiconductor can be allowed to have antistatic ability. According to this, the circuit can be prevented from breaking down due to the generation of electrostatic energy at the time of adhesion and at the time of peeling off or the like, or due to charging of a semiconductor wafer or the like by the electrostatic energy. Imparting of the antistatic ability can be performed by an appropriate manner such as a method of adding an antistatic agent or an electrically conductive substance to the base material 31, the pressure-sensitive adhesive layer 32, or the film 2 for back surface of semiconductor, a method of providing an electrically conductive layer composed of a charge transfer complex, a metal film, or the like on the base material 31, etc. As these systems, a system in which an impurity ion having a concern of changing the quality of the semiconductor wafer is difficult to generate is preferable. Examples of the electrically conductive substance (electrically conductive filler) to be blended for the purpose of imparting electrical conductivity, improving thermal conductivity, or the like include a spherical, acicular, or flaky metal powder of silver, aluminum, gold, copper, nickel, an electrically conductive alloy, or the like; a metal oxide such as alumina, etc.; amorphous carbon black; graphite; and the like. However, the film 2 for back surface of semiconductor is preferably non-electrically conductive from the standpoint of having no electric leakage.
In addition, the film 2 for back surface of semiconductor or the dicing tape-integrated film 1 for back surface of semiconductor may be formed in a form where it is wound as a roll or may be formed in a state where the sheet (film) is laminated. For example, in the case where the film has a form in which it is wound as a roll, the film 2 for back surface of semiconductor or the dicing tape-integrated film 1 for back surface of semiconductor is wound as a roll by protecting with a separator according to the need, whereby the film can be fabricated as the film 2 for back surface of semiconductor or the dicing tape-integrated film 1 for back surface of semiconductor in a state or form where it is wound as a roll. Incidentally, the dicing tape-integrated film 1 for back surface of semiconductor in a state or form where it is wound as a roll may be constituted of the base material 31, the pressure-sensitive adhesive layer 32 formed on one surface of the base material 31, the film for back surface of semiconductor formed on the pressure-sensitive adhesive layer 32, and a release-treated layer (rear surface treated layer) formed on the other surface of the base material 31.
Incidentally, a thickness of the dicing tape-integrated film 1 for back surface of semiconductor (total thickness of a thickness of the film for back surface of semiconductor and a thickness of the dicing tape composed of the base material 31 and the pressure-sensitive adhesive layer 32) can be, for example, selected within the range of from 8 μm to 1,500 μm, and the thickness is preferably from 20 μm to 850 μm (more preferably from 31 μm to 500 μm, and especially preferably from 47 μm to 330 μm).
In this way, in the dicing tape-integrated film 1 for back surface of semiconductor, by controlling a ratio of the thickness of the film 2 for back surface of semiconductor to the thickness of the pressure-sensitive adhesive layer 32 of the dicing tape 3 or a ratio of the thickness of the film 2 for back surface of semiconductor to the thickness of the dicing tape 3 (total thickness of the base material 31 and the pressure-sensitive adhesive layer 32), dicing properties at the time of a dicing step, picking-up properties at the time of a picking-up step, and the like can be improved, and the dicing tape-integrated film 1 for back surface of semiconductor can be effectively utilized from the dicing step of the semiconductor wafer to the flip-chip bonding step of the semiconductor chip.
(Manufacturing Method of Dicing Tape-Integrated Film for Back Surface of Semiconductor)
The manufacturing method of a dicing tape-integrated film for back surface of semiconductor according to the present embodiment is described while referring to the dicing tape-integrated film 1 for back surface of semiconductor as an example. First of all, the base material 31 can be fabricated by a conventionally known film-forming method. Examples of the subject film-forming method include a calendar film-forming method, a casting method in an organic solvent, an inflation extrusion method in a closed system, a T-die extrusion method, a co-extrusion method, a dry laminating method, and the like.
Subsequently, a pressure-sensitive adhesive composition is coated on the base material 31 and then dried (optionally, further crosslinked under heating) to form the pressure-sensitive adhesive layer 32. Examples of a coating system include roll coating, screen coating, gravure coating, and the like. Incidentally, the pressure-sensitive adhesive composition may be coated directly on the base material 31 to form the pressure-sensitive adhesive layer 32 on the base material 31; or the pressure-sensitive adhesive composition may be coated on a release paper, a surface of which has been subjected to a release treatment, or the like, to form the pressure-sensitive adhesive layer 32, followed by transferring the subject pressure-sensitive adhesive layer 32 onto the base material 31 to form the pressure-sensitive adhesive layer 32 on the base material 31. In this way, the pressure-sensitive adhesive layer 32 is formed on, the base material 31, thereby fabricating the dicing tape 3.
On the other hand, a forming material for forming the film 2 for back surface of semiconductor is coated on a release paper so as to have a prescribed thickness after drying, and further dried under a prescribed condition (in the case that thermal curing is necessary, or the like, subjected to a heat treatment for drying according to the need), thereby forming a coated layer. This coated layer is transferred onto the pressure-sensitive adhesive layer 32, thereby forming the film 2 for back surface of semiconductor on the pressure-sensitive adhesive layer 32. Incidentally, the film 2 for back surface of semiconductor can also be formed on the pressure-sensitive adhesive layer 32 by coating a forming material for forming the film 2 for back surface of semiconductor directly on the pressure-sensitive adhesive layer 32, followed by drying under a prescribed condition (in the case that thermal curing is necessary, or the like, performing a heat treatment for drying according to the need). According to the above, the dicing tape-integrated film 1 for back surface of semiconductor according to the present invention can be obtained. Incidentally, in the case of performing thermal curing at the time of forming the film 2 for back surface of semiconductor, though it is important to perform the thermal curing to such an extent that the film is in a partially cured state, it is preferable that the thermal curing is not performed.
Incidentally, in the case where the film 2 for back surface of semiconductor is not integrated with the dicing tape 3 but is a single body, it can be fabricated in the same method as the fabrication method of the film 2 for back surface of semiconductor as described above. Specifically, the film 2 for back surface of semiconductor can be fabricated by coating a forming material for forming the film 2 for back surface of semiconductor on a release paper so as to have a prescribed thickness after drying and further drying it under a prescribed condition (in the case that thermal curing is necessary, or the like, performing a heat treatment for drying according to the need), thereby forming a coated layer.
The film 2 for back surface of semiconductor or the dicing tape-integrated film 1 for back surface of semiconductor according to the present invention can be suitably used at the time of manufacturing a semiconductor device including a flip-chip connection step. That is, the film 2 for back surface of semiconductor or the dicing tape-integrated film 1 for back surface of semiconductor according to the present invention is used at the time of manufacturing a flip-chip mounted semiconductor device, and thus, the flip-chip mounted semiconductor device is manufactured in a state or form where the film 2 for back surface of semiconductor or the dicing tape-integrated film 1 for back surface of semiconductor is stuck onto the back surface of a semiconductor chip. In consequence, the film 2 for back surface of semiconductor or the dicing tape-integrated film 1 for back surface of semiconductor according to the present invention can be used for a flip-chip mounted semiconductor device (a semiconductor device in a state or form where the semiconductor chip is fixed to an adherend such as a substrate, etc. by a flip-chip bonding method).
(Semiconductor Wafer)
The semiconductor wafer is not particularly limited so far as it is a known or customary semiconductor wafer and can be properly selected and used among semiconductor wafers made of various raw materials. In the present invention, as the semiconductor wafer, a silicon wafer can be suitably used.
(Manufacturing Method of Semiconductor Device)
The method for manufacturing a semiconductor device according to the present embodiment is hereunder described by referring to
According to the manufacturing method of a semiconductor device as described above, a semiconductor device can be manufactured using the dicing tape-integrated film 1 for back surface of semiconductor. Specifically, the method includes at least a step of sticking a semiconductor wafer 4 onto the dicing tape-integrated film 1 for back surface of semiconductor; a step of dicing the semiconductor wafer 4; a step of picking up a semiconductor element 5 obtained by dicing; and a step of flip-chip connecting the semiconductor element 5 onto an adherend 6.
[Mounting Step]
First of all, as shown in
[Dicing Step]
Subsequently, as shown in
Incidentally, in the case where the dicing tape-integrated film 1 for back surface of semiconductor is expanded, the expansion can be performed using a conventionally known expanding apparatus. The expanding apparatus has a doughnut-shaped outer ring capable of pushing the dicing tape-integrated film 1 for back surface of semiconductor downward via a dicing ring; and an inner ring which has a diameter smaller than the outer ring and supports the dicing tape-integrated film for back surface of semiconductor. Owing to this expanding step, it is possible to prevent damaging of adjacent semiconductor chips to each other in a picking-up step as described later.
[Picking-Up Step]
In order to collect the semiconductor chips 5 adhered and fixed onto the dicing tape-integrated film 1 for back surface of semiconductor, picking-up of the semiconductor chip 5 is performed as shown in
[Flip-Chip Connecting Step]
As shown in
As the adherend 6, various substrates such as lead frames, circuit boards (wiring circuit boards, etc.), etc. can be used. Though a material of such a substrate is not particularly limited, examples thereof include ceramic substrates and plastic substrates. Examples of the plastic substrate include epoxy substrates, bismaleimide triazine substrates, polyimide substrates, and the like.
In the flip-chip bonding step (flip-chip connecting step), a material of the bump or the electrically conductive material is not particularly limited. Examples thereof include solders (alloys) such as tin-lead based metal materials, tin-silver based metal materials, tin-silver-copper based metal materials, tin-zinc based metal materials, tin-zinc-bismuth based metal materials, etc.; and gold based metal materials; copper based metal materials; and the like.
Incidentally, in the flip-chip bonding step, the electrically conductive material is melted to connect the bump on the circuit face side of the semiconductor chip 5 and the electrically conductive material on the surface of the adherend 6 to each other. A temperature at the time of melting of this electrically conductive material is usually about 260° C. (for example, from 250° C. to 300° C.). The dicing tape-integrated film for back surface of semiconductor according to the present invention can be allowed to have heat resistance such that it is capable of enduring high temperatures in this flip-chip bonding step by forming the film for back surface of semiconductor by an epoxy resin or the like.
In the present step (after the flip-chip bonding step), it is preferable to wash an opposing face (electrode-formed face) between the semiconductor chip 5 and the adherend 6 or a gap therebetween. A washing liquid to be used for the subject washing is not particularly limited, and examples thereof include organic washing liquids and aqueous washing liquids. The film for back surface of semiconductor in the dicing tape-integrated film for back surface of semiconductor according to the present invention has solvent resistance against the washing liquids and does not substantially have solubility in these washing liquids. Therefore, as described above, various washing liquids can be used as the washing liquid, and the washing can be achieved by a conventional method without requiring a special washing liquid.
Subsequently, an encapsulation step is performed for encapsulating the gap between the flip-chip bonded semiconductor chip 5 and the adherend 6. The encapsulation step is performed using an encapsulating resin. At that time, though the encapsulation condition is not particularly limited, the thermal curing of the encapsulating resin is usually carried out upon heating at 175° C. for from 60 seconds to 90 seconds. However, it should not be construed that the present invention is limited thereto, and for example, the curing can be performed at from 165 to 185° C. for a few minutes. In the heat treatment in this step, not only the thermal curing of the encapsulating resin but the thermal curing of the film 2 for back surface of semiconductor is carried out at the same time. According to this, the mechanical strength of the film 2 for back surface of semiconductor can be increased. Here, the encapsulating resin causes cure shrinkage due to the heat treatment in this step with the progress of thermal curing. However, even if a stress is applied to the semiconductor chip 5 due to the cure shrinkage of the encapsulating resin, since the tensile storage elastic modulus of the film for back surface of semiconductor is 10 GPa or more, the film can resist that stress, so that a flip-chip bonded semiconductor chip can be obtained in a state where the semiconductor element does not substantially generate a warp or does not generate a warp at all. In addition, according to the subject step, the film 2 for back surface of semiconductor can be completely or substantially completely thermally cured and can be stuck onto the back surface of a semiconductor element with excellent adhesion. Furthermore, the film 2 for back surface of semiconductor according to the present invention can be thermally cured together with the encapsulating material at the time of the encapsulation step even when the film is in an uncured state, so that it is not necessary to newly add a step of thermally curing the film 2 for back surface of semiconductor.
The encapsulating resin is not particularly limited so far as it is a resin having insulating properties (an insulating resin). Though the encapsulating resin can be properly selected and used among known encapsulating materials such as encapsulating resins, etc., it is more preferably an insulating resin having elasticity. Examples of the encapsulating resin include resin compositions containing an epoxy resin; and the like. Examples of the epoxy resin include the epoxy resins as exemplified above; and the like. In addition, the encapsulating resin composed of a resin composition containing an epoxy resin may contain, in addition to an epoxy resin, a thermosetting resin other than the epoxy resin (a phenol resin, etc.), or a thermoplastic resin as a resin component. Incidentally, the phenol resin can also be utilized as a curing agent of the epoxy resin, and examples of such a phenol resin include the phenol resins as exemplified above; and the like.
According to the semiconductor device (flip-chip mounted semiconductor device) manufactured using the dicing tape-integrated film 1 for back surface of semiconductor or the film 2 for back surface semiconductor, the film for back surface of semiconductor is stuck onto the back surface of the semiconductor chip, and therefore, marking of every kind can be applied with excellent visibility. In particular, even if the marking method is a laser marking method, marking can be applied with an excellent contrast ratio, and information of every kind (literal information, graphical information, etc.) applied by laser marking can be observed with good visibility. Incidentally, at the time of performing laser marking, a known laser marking apparatus can be utilized. In addition, as the laser, various lasers such as a gas laser, a solid laser, a liquid laser, etc. can be utilized. Specifically, the gas laser is not particularly limited, and known gas lasers can be utilized. Of these, a carbon oxide laser (CO2 laser) and an excimer laser (ArF laser, KrF laser, XeCl laser, XeF laser, etc.) are suitable. In addition, the solid laser is not particularly limited, and known solid lasers can be utilized. Of these, a YAG laser (Nd:YAG laser, etc.) and a YVO4 laser are suitable.
Since the semiconductor device manufactured using the dicing tape-integrated film for back surface of semiconductor or the film for back surface of semiconductor according to the present invention is a semiconductor device mounted by the flip-chip mounting system, the device has a thinned and miniaturized shape as compared with a semiconductor device mounted by the die bonding mounting system. Therefore, the semiconductor devices can be suitably used as various electronic instruments or electronic parts or materials or members thereof. Specifically, examples of the electronic instrument in which the flip-chip mounted semiconductor devices according to the present invention are utilized include so-called “mobile phones” and “PHS”, small-sized computers [for example, so-called “PDA” (personal digital assistant), so-called “laptop personal computer”, so-called “Net Book (trademark)”, so-called “wearable computers”, etc.], small-sized electronic instruments having a “mobile phone” and a computer integrated with each other, so-called “Digital Camera (trademark)”, so-called “digital video cameras”, small-sized television sets, small-sized game machines, small-sized digital audio players, so-called “electronic notepads”, so-called “electronic dictionaries”, electronic device terminals for so-called “electronic books”, mobile electronic instruments (portable electronic devices) such as small-sized digital type watches, etc., and the like. As a matter of course, electronic instruments (stationary type ones, etc.) other than mobile ones (for example, so-called “desktop personal computers”, thin type television sets, electronic instruments for recording and reproduction (hard disk recorders, DVD players, etc.), projectors, micromachines, and the like) may also be mentioned. In addition, electronic parts, or materials or members of electronic instruments or electronic parts, are not particularly limited, and examples thereof include parts for so-called “CPU” and members for various storage devices (so-called “memories”, hard disks, etc.).
The present invention is hereunder described in detail by reference to the following Examples. However, it should be construed that the present invention is not limited to the following Examples so far as the gist thereof is not deviated. In addition, all parts in each of the Examples are made on a weight basis unless otherwise indicated.
<Fabrication of Film for Back Surface of Flip-Chip Semiconductor>
900 parts of an epoxy resin (a trade name: “EPIKOTE 1004”, manufactured by JER Co., Ltd.), 6,177 parts of spherical silica (a trade name: “SO-25R”, manufactured by Admatechs Company Limited), 4 parts of a dye (a trade name: “OIL BLACK BS”, manufactured by Orient Chemical Industries Co., Ltd.), and 90 parts of a curing-accelerating catalyst (a trade name: “2PHZ-PW”, manufactured by Shikoku Chemicals Corporation) based on 100 parts of an acrylic acid ester-based polymer composed mainly of ethyl acrylate and methyl methacrylate (a trade name: “PARACRON W-197CM”, manufactured by Negami Chemical Industrial Co., Ltd.) were dissolved in methyl ethyl ketone to prepare a solution of a resin composition having a solid content concentration of 23.6% by weight.
This solution of the resin composition was applied on, as a release liner (separator), a 50 μm-thick release-treated film composed of a polyethylene terephthalate film, which had been subjected to a silicone release treatment, and then dried at 130° C. for 2 minutes to prepare a film A for back surface of flip-chip semiconductor having a thickness (average thickness) of 80 μm.
<Fabrication of Dicing Tape-Integrated Film for Back Surface of Semiconductor>
The foregoing film A for back surface of flip-chip semiconductor was stuck onto a pressure-sensitive adhesive layer of a dicing tape (a trade name: “V-8-T”, manufactured by Nitto Denko Corporation, average thickness of base material: 65 μm, average thickness of pressure-sensitive adhesive layer: 10 μm) using a hand roller, thereby fabricating a dicing tape-integrated film for back surface of semiconductor.
<Fabrication of Film for Back Surface of Flip-Chip Semiconductor>
900 parts of an epoxy resin (a trade name: “EPIKOTE 1004”, manufactured by JER Co., Ltd.), 4,360 parts of spherical silica (a trade name: “SO-25R”, manufactured by Admatechs Company Limited), 4 parts of a dye (a trade name: “OIL GREEN 502”, manufactured by Orient Chemical Industries Co., Ltd.), and 90 parts of a curing-accelerating catalyst (a trade name: “2PHZ-PW”, manufactured by Shikoku Chemicals Corporation) based on 100 parts of an acrylic acid ester based polymer composed mainly of ethyl acrylate and methyl methacrylate (a trade name: “PARACRON W-197CM”, manufactured by Negami Chemical Industrial Co., Ltd.) were dissolved in methyl ethyl ketone to prepare a solution of a resin composition having a solid content concentration of 23.6% by weight.
This solution of the resin composition was applied on, as a release liner (separator), a 50 μm-thick release-treated film composed of a polyethylene terephthalate film, which had been subjected to a silicone release treatment, and then dried at 130° C. for 2 minutes to prepare a film B for back surface of flip-chip semiconductor having a thickness (average thickness) of 80 μm.
<Fabrication of Dicing Tape-Integrated Film for Back Surface of Semiconductor>
The foregoing film B for back surface of flip-chip semiconductor was stuck onto a pressure-sensitive adhesive layer of a dicing tape (a trade name: “V-8-T”, manufactured by Nitto Denko Corporation, average thickness of base material: 65 μm, average thickness of pressure-sensitive adhesive layer: 10 μm) using a hand roller, thereby fabricating a dicing tape-integrated film for back surface of semiconductor.
<Fabrication of Film for Back Surface of Flip-Chip Semiconductor>
75 parts of an epoxy resin (a trade name: “EPIKOTE 1004”, manufactured by JER Co., Ltd.), 75 parts of a phenol resin (a trade name: “MIREX XLC-4L”, manufactured by Mitsui Chemicals, Inc.), 1,000 parts of spherical silica (a trade name: “SO-25R”, manufactured by Admatechs Company Limited), and 4 parts of a dye (a trade name: “OIL BLACK BS”, manufactured by Orient Chemical Industries Co., Ltd.) based on 100 parts of an acrylic acid ester based polymer composed mainly of ethyl acrylate and methyl methacrylate (a trade name: “PARACRON W-197CM”, manufactured by Negami Chemical Industrial Co., Ltd.) were dissolved in methyl ethyl ketone to prepare a solution of a resin composition having a solid content concentration of 23.6% by weight.
This solution of the resin composition was applied on, as a release liner (separator), a 50 μm-thick release-treated film composed of a polyethylene terephthalate film, which had been subjected to a silicone release treatment, and then dried at 130° C. for 2 minutes to prepare a film C for back surface of flip-chip semiconductor having a thickness (average thickness) of 80 μm.
<Fabrication of Dicing Tape-Integrated Film for Back Surface of Semiconductor>
The foregoing film C for back surface of flip-chip semiconductor was stuck onto a pressure-sensitive adhesive layer of a dicing tape (a trade name: “V-8-T”, manufactured by Nitto Denko Corporation, average thickness of base material: 65 μm, average thickness of pressure-sensitive adhesive layer: 10 μm) using a hand roller, thereby fabricating a dicing tape-integrated film for back surface of semiconductor.
(Tensile Storage Elastic Modulus)
Each of the films for back surface of flip-chip semiconductor fabricated in the respective Examples and Comparative Example was thermally cured by a heat treatment under a condition at 165° C. for 2 hours. Subsequently, a strip-shaped sample having a length of 22.5 mm, a width of 10 mm, and a thickness of 0.2 mm was cut out from each of the films for back surface of flip-chip semiconductor after thermal curing by using a cutter knife. Furthermore, a value measured under a condition at a frequency of 1 Hz and a temperature elevating rate of 10° C./minute in a nitrogen atmosphere at a prescribed temperature (23° C.) using a dynamic viscoelasticity measuring apparatus “Solid Analyzer RS A2”, manufactured by Rheometrics Co., Ltd. was designated as a tensile storage elastic modulus E′.
(Warp Amount of Semiconductor Package)
The presence or absence of the generation of a warp of the semiconductor chip was evaluated by measuring a warp amount of the semiconductor chip.
That is, first of all, after peeling off the separator from the dicing tape-integrated film for back surface of semiconductor, a semiconductor wafer (diameter: 8 inches, thickness: 200 μm; a silicon mirror wafer) was stuck onto the film for back surface of semiconductor by means of roll press bonding at 70° C. Furthermore, dicing of the semiconductor wafer was performed. The dicing was performed as full cutting so as to have a chip size of 10 mm square. Incidentally, a sticking condition and a dicing condition are as follows.
[Sticking Condition]
Sticking apparatus: A trade name: “MA-3000III”, manufactured by Nitto Seiki Co., Ltd.
Sticking speed: 10 mm/min
Sticking pressure: 0.15 MPa
Stage temperature at the time of sticking: 70° C.
[Dicing Condition]
Dicing apparatus: A trade name: “DFD-6361”, manufactured by DISCO Corporation
Dicing ring: “2-8-1” (manufactured by DISCO Corporation)
Dicing speed: 30 mm/sec
Dicing blade:
Dicing blade rotation number:
Cutting system: Step cutting
Wafer chip size: 10.0 mm square
Subsequently, the semiconductor chip obtained by dicing was picked up from the pressure-sensitive adhesive layer together with the film for back surface of flip-chip semiconductor by pushing up from the dicing tape side of the dicing tape-integrated film for back surface of semiconductor with a needle. A picking-up condition is as follows.
[Picking-Up Condition]
Picking-up apparatus: A trade name: “SPA-300”, manufactured by Shinkawa Co., Ltd.
Number of picking-up needles: 9 needles
Pushing-up speed of needle: 20 mm/s
Pushing-up distance of needle: 500 μm
Picking-up time: 1 second
Dicing tape expanding amount: 3 mm
Subsequently, the semiconductor chip was flip-chip bonded onto a BT substrate [BT RESIN (bismaleimide triazine based resin), manufactured by Mitsubishi Gas Chemical Company, Inc.]. At that time, the circuit face of the semiconductor chip was made opposite to the BT substrate, thereby bringing the bump formed on the circuit face of the semiconductor chip into contact with an electrically conductive material for (solder) for joining as adhered onto a connecting pad of the BT substrate, and the temperature was elevated to 260° C. while pressing, to melt the electrically conductive material, followed by cooling to room temperature. Furthermore, an underfill material as an encapsulating resin was injected into a gap between the semiconductor chip and the BT substrate. At that time, a thickness of the underfill (encapsulating material) was 20 μm. Subsequently, the semiconductor package was heated under a condition at 165° C. for 2 hours and then measured for a warp amount thereof.
As for the measurement of the warp amount, first of all, the semiconductor package was placed on a flat plate such that the BT substrate was faced downward, and a height of the BT substrate lifting up from the flat plate, namely a warp amount (μm) was measured. The measurement was carried out under a condition at a measuring speed of 1.5 mm/s and a load of 1 g by using a contact type surface roughness tester (DEKTAK8, manufactured by Veeco Instruments Inc.). As a result of the measurement, the case where the warp amount was not more than 100 μm is evaluated as “∘”, and the case where the warp amount exceeded 100 μm is evaluated as “x”. The results are shown in the following Table 1.
TABLE 1
Tensile storage
Thickness of film
elastic
for back surface
Warp amount of
modulus
of semiconductor
semiconductor
(GPa)
(μm)
package
Example 1
14
80
∘
Example 2
10
80
∘
Comparative
8
80
x
Example 1
(Results)
As is noted from Table 1, it was confirmed that as shown in Examples 1 and 2, in the films for back surface of semiconductor having a tensile storage elastic modulus at 23° C. after thermal curing of 10 GPa or more, all of the warp amounts of the semiconductor packages could be suppressed to not more than 100 μm. On the other hand, as shown in Comparative Example 1, in the film for back surface of semiconductor having the foregoing tensile storage elastic modulus of 8 GPa, the warp amount of the semiconductor package could not be reduced to not more than 100 μm.
<Fabrication of Film for Back Surface of Flip-Chip Semiconductor>
900 parts of an epoxy resin (a trade name: “EPIKOTE 1004”, manufactured by JER Co., Ltd.), 6,177 parts of spherical silica (a trade name: “SO-25R”, manufactured by Admatechs Company Limited), 4 parts of a dye (a trade name: “OIL BLACK BS”, manufactured by Orient Chemical Industries Co., Ltd.), and 90 parts of a thermal curing-accelerating catalyst (a trade name: “2PHZ-PW”, manufactured by Shikoku Chemicals Corporation) based on 100 parts of an acrylic acid ester based polymer composed mainly of ethyl acrylate and methyl methacrylate (a trade name: SG-708MT, manufactured by Nagase ChemiteX Corporation for a thermoplastic resin component, glass transition temperature: 28° C.) were dissolved in methyl ethyl ketone to prepare a solution of a resin composition having a solid content concentration of 23.6% by weight.
This solution of the resin composition was applied on, as a release liner (separator), a 50 μm-thick release-treated film composed of a polyethylene terephthalate film, which had been subjected to a silicone release treatment, and then dried at 130° C. for 2 minutes to prepare a film D for back surface of flip-chip semiconductor having a thickness (average thickness) of 30 μm.
<Fabrication of Dicing Tape-Integrated Film for Back Surface of Semiconductor>
The foregoing film D for back surface of flip-chip semiconductor was stuck onto a pressure-sensitive adhesive layer of a dicing tape (a trade name: “V-8-T”, manufactured by Nitto Denko Corporation, average thickness of base material: 65 μm, average thickness of pressure-sensitive adhesive layer: 10 μm) using a hand roller, thereby fabricating a dicing tape-integrated film for back surface of semiconductor.
<Fabrication of Film for Back Surface of Flip-Chip Semiconductor>
900 parts of an epoxy resin (a trade name: “EPIKOTE 1004”, manufactured by JER Co., Ltd.), 6,177 parts of spherical silica (a trade name: “SO-25R”, manufactured by Admatechs Company Limited), 4 parts of a dye (a trade name: “OIL GREEN 502”, manufactured by Orient Chemical Industries Co., Ltd.), and 90 parts of a thermal curing-accelerating catalyst (a trade name: “2PHZ-PW”, manufactured by Shikoku Chemicals Corporation) based on 100 parts of an acrylic acid ester based polymer composed mainly of ethyl acrylate and methyl methacrylate (a trade name: SG-P26TEA, manufactured by Nagase ChemiteX Corporation for a thermoplastic resin component, glass transition temperature: 38° C.) were dissolved in methyl ethyl ketone to prepare a solution of a resin composition having a solid content concentration of 23.6% by weight.
This solution of the resin composition was applied on, as a release liner (separator), a 50 μm-thick release-treated film composed of a polyethylene terephthalate film, which had been subjected to a silicone release treatment, and then dried at 130° C. for 2 minutes to prepare a film E for back surface of flip-chip semiconductor having a thickness (average thickness) of 30 μm.
<Fabrication of Dicing Tape-Integrated Film for Back Surface of Semiconductor>
The foregoing film E for back surface of flip-chip semiconductor was stuck onto a pressure-sensitive adhesive layer of a dicing tape (a trade name: “V-8-T”, manufactured by Nitto Denko Corporation, average thickness of base material: 65 μm, average thickness of pressure-sensitive adhesive layer: 10 μm) using a hand roller, thereby fabricating a dicing tape-integrated film for back surface of semiconductor.
<Fabrication of Film for Back Surface of Flip-Chip Semiconductor>
900 parts of an epoxy resin (a trade name: “EPIKOTE 1004”, manufactured by JER Co., Ltd.), 6,177 parts of spherical silica (a trade name: “SO-25R”, manufactured by Admatechs Company Limited), and 4 parts of a dye (a trade name: “OIL BLACK BS”, manufactured by Orient Chemical Industries Co., Ltd.) based on 100 parts of an acrylic acid ester based polymer composed mainly of ethyl acrylate and methyl methacrylate (a trade name: SG-80H, manufactured by Nagase ChemiteX Corporation for a thermoplastic resin component, glass transition temperature: 11° C.) were dissolved in methyl ethyl ketone to prepare a solution of a resin composition having a solid content concentration of 23.6% by weight.
This solution of the resin composition was applied on, as a release liner (separator), a 50 μm-thick release-treated film composed of a polyethylene terephthalate film, which had been subjected to a silicone release treatment, and then dried at 130° C. for 2 minutes to prepare a film F for back surface of flip-chip semiconductor having a thickness (average thickness) of 30 μm.
<Fabrication of Dicing Tape-Integrated Film for Back Surface of Semiconductor>
The foregoing film F for back surface of flip-chip semiconductor was stuck onto a pressure-sensitive adhesive layer of a dicing tape (a trade name: “V-8-T”, manufactured by Nitto Denko Corporation, average thickness of base material: 65 μm, average thickness of pressure-sensitive adhesive layer: 10 μm) using a hand roller, thereby fabricating a dicing tape-integrated film for back surface of semiconductor.
(Tensile Storage Elastic Modulus)
Each of the films for back surface of flip-chip semiconductor fabricated in the respective Examples and Comparative Example was thermally cured by a heat treatment under a condition at 165° C. for 2 hours. Subsequently, a strip-shaped sample having a length of 22.5 mm, a width of 10 mm, and a thickness of 0.2 mm was cut out from each of the films for back surface of flip-chip semiconductor after thermal curing by using a cutter knife. Furthermore, a value measured under a condition at a frequency of 1 Hz and a temperature elevating rate of 10° C./minute in a nitrogen atmosphere at a prescribed temperature (23° C.) using a dynamic viscoelasticity measuring apparatus “Solid Analyzer RS A2”, manufactured by Rheometrics Co., Ltd. was designated as a tensile storage elastic modulus E′.
(Warp Amount of Semiconductor Package)
The presence or absence of the generation of a warp of the semiconductor chip was evaluated by measuring a warp amount of the semiconductor chip.
That is, first of all, after peeling off the separator from the dicing tape-integrated film for back surface of semiconductor, a semiconductor wafer (diameter: 8 inches, thickness: 200 μm; a silicon mirror wafer) was stuck onto the film for back surface of semiconductor by means of roll press bonding at 70° C. Furthermore, dicing of the semiconductor wafer was performed. The dicing was performed as full cutting so as to have a chip size of 10 mm square. Incidentally, a sticking condition and a dicing condition are as follows.
[Sticking Condition]
Sticking apparatus: A trade name: “MA-3000III”, manufactured by Nitto Seiki Co., Ltd.
Sticking speed: 10 mm/min
Sticking pressure: 0.15 MPa
Stage temperature at the time of sticking: 70° C.
[Dicing Condition]
Dicing apparatus: A trade name: “DFD-6361”, manufactured by DISCO Corporation
Dicing ring: “2-8-1” (manufactured by DISCO Corporation)
Dicing speed: 30 mm/sec
Dicing blade:
Dicing blade rotation number:
Cutting system: Step cutting
Wafer chip size: 10.0 mm square
Subsequently, the semiconductor chip obtained by dicing was picked up from the pressure-sensitive adhesive layer together with the film for back surface of flip-chip semiconductor by pushing up from the dicing tape side of the dicing tape-integrated film for back surface of semiconductor with a needle. A picking-up condition is as follows.
[Picking-Up Condition]
Picking-up apparatus: A trade name: “SPA-300”, manufactured by Shinkawa Co., Ltd.
Number of picking-up needles: 9 needles
Pushing-up speed of needle: 20 mm/s
Pushing-up distance of needle: 500 μm
Picking-up time: 1 second
Dicing tape expanding amount: 3 mm
Subsequently, the semiconductor chip was flip-chip bonded onto a BT substrate [BT RESIN (bismaleimide triazine based resin), manufactured by Mitsubishi Gas Chemical Company, Inc.]. At that time, the circuit face of the semiconductor chip was made opposite to the BT substrate, thereby bringing the bump formed on the circuit face of the semiconductor chip into contact with an electrically conductive material for (solder) for joining as adhered onto a connecting pad of the BT substrate, and the temperature was elevated to 260° C. while pressing, to melt the electrically conductive material, followed by cooling to room temperature. Furthermore, an underfill material as an encapsulating resin was injected into a gap between the semiconductor chip and the BT substrate. At that time, a thickness of the underfill (encapsulating material) was 20 μm. Subsequently, the semiconductor package was heated under a condition at 165° C. for 2 hours and then measured for a warp amount thereof.
As for the measurement of the warp amount, first of all, the semiconductor package was placed on a flat plate such that the BT substrate was faced downward, and a height of the BT substrate lifting up from the flat plate, namely a warp amount (μm) was measured. The measurement was carried out under a condition at a measuring speed of 1.5 mm/s and a load of 1 g by using a contact type surface roughness tester (DEKTAK8, manufactured by Veeco Instruments Inc.). As a result of the measurement, the case where the warp amount was not more than 100 μm is evaluated as “∘”, and the case where the warp amount exceeded 100 μm is evaluated as “x”. The results are shown in the following Table 2.
TABLE 2
Glass
transition
temperature Tg
Thickness of
of
Tensile
film
thermoplastic
storage
for back
Warp
resin
elastic
surface of
amount of
component
modulus
semiconductor
semiconductor
(° C.)
(GPa)
(μm)
package
Example 3
28
13
30
∘
Example 4
38
14
30
∘
Comparative
11
7
30
x
Example 2
(Results)
As is noted from Table 2, it was confirmed that as shown in Examples 3 and 4, in the films for back surface of semiconductor containing, as a constituent component, a thermoplastic resin component having a glass transition temperature of 25° C. or higher, all of the warp amounts of the semiconductor packages could be suppressed to not more than 100 μm. On the other hand, as shown in Comparative Example 2, in the film for back surface of semiconductor containing, as a constituent component, a thermoplastic resin having the foregoing glass transition temperature of lower than 25° C., the warp amount of the semiconductor package could not be reduced to not more than 100 μm.
<Fabrication of Film for Back Surface of Flip-Chip Semiconductor>
100 parts of an epoxy resin (a trade name: “EPIKOTE 834”, manufactured by JER Co., Ltd.), 840 parts of spherical silica (a trade name: “SO-25R”, manufactured by Admatechs Company Limited), 4 parts of a dye (a trade name: “OIL BLACK BS”, manufactured by Orient Chemical Industries Co., Ltd.), and 10 parts of a thermal curing-accelerating catalyst (a trade name: “2PHZ-PW”, manufactured by Shikoku Chemicals Corporation) based on 100 parts of a phenoxy resin (a trade name: “EPIKOTE 4250”, manufactured by JER Co., Ltd.) were dissolved in methyl ethyl ketone to prepare a solution of a resin composition having a solid content concentration of 23.6% by weight.
This solution of the resin composition was applied on, as a release liner (separator), a 50 μm-thick release-treated film composed of a polyethylene terephthalate film, which had been subjected to a silicone release treatment, and then dried at 130° C. for 2 minutes to prepare a film G for back surface of flip-chip semiconductor having a thickness (average thickness) of 80 μm.
<Fabrication of Dicing Tape-Integrated Film for Back Surface of Semiconductor>
The foregoing film G for back surface of flip-chip semiconductor was stuck onto a pressure-sensitive adhesive layer of a dicing tape (a trade name: “V-8-T”, manufactured by Nitto Denko Corporation, average thickness of base material: 65 μm, average thickness of pressure-sensitive adhesive layer: 10 μm) using a hand roller, thereby fabricating a dicing tape-integrated film for back surface of semiconductor.
<Fabrication of Film for Back Surface of Flip-Chip Semiconductor>
150 parts of an epoxy resin (a trade name: “EPIKOTE 834”, manufactured by JER Co., Ltd.), 1,060 parts of spherical silica (a trade name: “SO-25R”, manufactured by Admatechs Company Limited), 4 parts of a dye (a trade name: “OIL BLACK BS”, manufactured by Orient Chemical Industries Co., Ltd.), and 15 parts of a thermal curing-accelerating catalyst (a trade name: “2PHZ-PW”, manufactured by Shikoku Chemicals Corporation) based on 100 parts of a phenoxy resin (a trade name: “EPIKOTE 4250”, manufactured by JER Co., Ltd.) were dissolved in methyl ethyl ketone to prepare a solution of a resin composition having a solid content concentration of 23.6% by weight.
This solution of the resin composition was applied on, as a release liner (separator), a 50 μm-thick release-treated film composed of a polyethylene terephthalate film, which had been subjected to a silicone release treatment, and then dried at 130° C. for 2 minutes to prepare a film H for back surface of flip-chip semiconductor having a thickness (average thickness) of 80 μm.
<Fabrication of Dicing Tape-Integrated Film for Back Surface of Semiconductor>
The foregoing film H for back surface of flip-chip semiconductor was stuck onto a pressure-sensitive adhesive layer of a dicing tape (a trade name: “V-8-T”, manufactured by Nitto Denko Corporation, average thickness of base material: 65 μm, average thickness of pressure-sensitive adhesive layer: 10 μm) using a hand roller, thereby fabricating a dicing tape-integrated film for back surface of semiconductor.
<Fabrication of Film for Back Surface of Flip-Chip Semiconductor>
75 parts of an epoxy resin (a trade name: “EPIKOTE 1004”, manufactured by JER Co., Ltd.), 75 parts of a phenol resin (a trade name: “MIREX XLC-4L”, manufactured by Mitsui Chemicals, Inc.), 1,000 parts of spherical silica (a trade name: “SO-25R”, manufactured by Admatechs Company Limited), and 4 parts of a dye (a trade name: “OIL BLACK BS”, manufactured by Orient Chemical Industries Co., Ltd.) based on 100 parts of an acrylic acid ester based polymer composed mainly of ethyl acrylate and methyl methacrylate (a trade name: “PARACRON W-197CM”, manufactured by Negami Chemical Industrial Co., Ltd.) were dissolved in methyl ethyl ketone to prepare a solution of a resin composition having a solid content concentration of 23.6% by weight.
This solution of the resin composition was applied on, as a release liner (separator), a 50 μm-thick release-treated film composed of a polyethylene terephthalate film, which had been subjected to a silicone release treatment, and then dried at 130° C. for 2 minutes to prepare a film I for back surface of flip-chip semiconductor having a thickness (average thickness) of 80 μm.
<Fabrication of Dicing Tape-Integrated Film for Back Surface of Semiconductor>
The foregoing film I for back surface of flip-chip semiconductor was stuck onto a pressure-sensitive adhesive layer of a dicing tape (a trade name: “V-8-T”, manufactured by Nitto Denko Corporation, average thickness of base material: 65 μm, average thickness of pressure-sensitive adhesive layer: 10 μm) using a hand roller, thereby fabricating a dicing tape-integrated film for back surface of semiconductor.
(Tensile Storage Elastic Modulus)
Each of the films for back surface of flip-chip semiconductor fabricated in the respective Examples and Comparative Example was thermally cured by a heat treatment under a condition at 165° C. for 2 hours. Subsequently, a strip-shaped sample having a length of 22.5 mm, a width of 10 mm, and a thickness of 0.2 mm was cut out from each of the films for back surface of flip-chip semiconductor after thermal curing by using a cutter knife. Furthermore, a value measured under a condition at a frequency of 1 Hz and a temperature elevating rate of 10° C./minute in a nitrogen atmosphere at a prescribed temperature (23° C.) using a dynamic viscoelasticity measuring apparatus “Solid Analyzer RS A2”, manufactured by Rheometrics Co., Ltd. was designated as a tensile storage elastic modulus E′.
(Warp Amount of Semiconductor Package)
The presence or absence of the generation of a warp of the semiconductor chip was evaluated by measuring a warp amount of the semiconductor chip.
That is, first of all, after peeling off the separator from the dicing tape-integrated film for back surface of semiconductor, a semiconductor wafer (diameter: 8 inches, thickness: 200 μm; a silicon mirror wafer) was stuck onto the film for back surface of semiconductor by means of roll press bonding at 70° C. Furthermore, dicing of the semiconductor wafer was performed. The dicing was performed as full cutting so as to have a chip size of 10 mm square. Incidentally, a sticking condition and a dicing condition are as follows.
[Sticking Condition]
Sticking apparatus: A trade name: “MA-3000III”, manufactured by Nitto Seiki Co., Ltd.
Sticking speed: 10 mm/min
Sticking pressure: 0.15 MPa
Stage temperature at the time of sticking: 70° C.
[Dicing Condition]
Dicing apparatus: A trade name: “DFD-6361”, manufactured by DISCO Corporation
Dicing ring: “2-8-1” (manufactured by DISCO Corporation)
Dicing speed: 30 mm/sec
Dicing blade:
Dicing blade rotation number:
Cutting system: Step cutting
Wafer chip size: 10.0 mm square
Subsequently, the semiconductor chip obtained by dicing was picked up from the pressure-sensitive adhesive layer together with the film for back surface of flip-chip semiconductor by pushing up from the dicing tape side of the dicing tape-integrated film for back surface of semiconductor with a needle. A picking-up condition is as follows.
[Picking-Up Condition]
Picking-up apparatus: A trade name: “SPA-300”, manufactured by Shinkawa Co., Ltd.
Number of picking-up needles: 9 needles
Pushing-up speed of needle: 20 mm/s
Pushing-up distance of needle: 500 μm
Picking-up time: 1 second
Dicing tape expanding amount: 3 mm
Subsequently, the semiconductor chip was flip-chip bonded onto a BT substrate [BT RESIN (bismaleimide triazine based resin), manufactured by Mitsubishi Gas Chemical Company, Inc.]. At that time, the circuit face of the semiconductor chip was made opposite to the BT substrate, thereby bringing the bump formed on the circuit face of the semiconductor chip into contact with an electrically conductive material for (solder) for joining as adhered onto a connecting pad of the BT substrate, and the temperature was elevated to 260° C. while pressing, to melt the electrically conductive material, followed by cooling to room temperature. Furthermore, an underfill material as an encapsulating resin was injected into a gap between the semiconductor chip and the BT substrate. At that time, a thickness of the underfill (encapsulating material) was 20 μm. Subsequently, the semiconductor package was heated under a condition at 165° C. for 2 hours and then measured for a warp amount thereof.
As for the measurement of the warp amount, first of all, the semiconductor package was placed on a flat plate such that the BT substrate was faced downward, and a height of the BT substrate lifting up from the flat plate, namely a warp amount (μm) was measured. The measurement was carried out under a condition at a measuring speed of 1.5 mm/s and a load of 1 g by using a contact type surface roughness tester (DEKTAK8, manufactured by Veeco Instruments Inc.). As a result of the measurement, the case where the warp amount was not more than 100 μm is evaluated as “∘”, and the case where the warp amount exceeded 100 μm is evaluated as “x”. The results are shown in the following Table 3.
TABLE 3
Blending
Thickness of
proportion
Tensile
film
of
storage
for back
Warp
thermosetting
modulus
surface of
amount of
resin
elastic
semiconductor
semiconductor
(wt %)
(GPa)
(μm)
package
Example 5
100
10
80
∘
Example 6
100
11
80
∘
Comparative
60
8
80
x
Example 3
*: The blending proportion of the thermosetting resin is a value calculated according to the expression: [(Blending amount of thermosetting resin)/((Blending amount of thermosetting resin) + (Blending amount of thermoplastic resin))] × 100.
(Results)
As is noted from Table 3, it was confirmed that as shown in Examples 5 and 6, in the films for back surface of flip-chip semiconductor in which the resin composition was composed only of a thermosetting resin, all of the warp amounts of the semiconductor packages could be suppressed to not more than 100 μm. On the other hand, as shown in Comparative Example 3, in the film for back surface of flip-chip semiconductor in which both a thermosetting resin component and a thermoplastic resin component were used for the resin composition, the warp amount of the semiconductor package could not be reduced to not more than 100 μm.
<Fabrication of Film for Back Surface of Flip-Chip Semiconductor>
150 parts of a liquid epoxy resin (a trade name: “EPIKOTE 834”, manufactured by JER Co., Ltd.), 693 parts of spherical silica (a trade name: “SO-25R”, manufactured by Admatechs Company Limited), 4 parts of a dye (a trade name: “OIL BLACK BS”, manufactured by Orient Chemical Industries Co., Ltd.), and 6.7 parts of a thermal curing-accelerating catalyst (a trade name: “2PHZ-PW”, manufactured by Shikoku Chemicals Corporation) based on 100 parts of a phenoxy resin (a trade name: “EPIKOTE 4250”, manufactured by JER Co., Ltd.) were dissolved in methyl ethyl ketone to prepare a solution of a resin composition having a solid content concentration of 23.6% by weight. Incidentally, as a result of the measurement by the Gardner Holdt method, a viscosity of the foregoing liquid epoxy resin at 25° C. was P.
This solution of the resin composition was applied on, as a release liner (separator), a 50 μm-thick release-treated film composed of a polyethylene terephthalate film, which had been subjected to a silicone release treatment, and then dried at 130° C. for 2 minutes to prepare a film J for back surface of flip-chip semiconductor having a thickness (average thickness) of 80 μm.
<Fabrication of Dicing Tape-Integrated Film for Back Surface of Semiconductor>
The foregoing film J for back surface of flip-chip semiconductor was stuck onto a pressure-sensitive adhesive layer of a dicing tape (a trade name: “V-8-T”, manufactured by Nitto Denko Corporation, average thickness of base material: 65 μm, average thickness of pressure-sensitive adhesive layer: 10 μm) using a hand roller, thereby fabricating a dicing tape-integrated film for back surface of semiconductor.
<Fabrication of Film for Back Surface of Flip-Chip Semiconductor>
400 parts of a liquid epoxy resin (a trade name: “EPIKOTE 834”, manufactured by JER Co., Ltd.), 2,160 parts of spherical silica (a trade name: “SO-25R”, manufactured by Admatechs Company Limited), 4 parts of a dye (a trade name: “OIL BLACK BS”, manufactured by Orient Chemical Industries Co., Ltd.), and 40 parts of a thermal curing-accelerating catalyst (a trade name: “2PHZ-PW”, manufactured by Shikoku Chemicals Corporation) based on 100 parts of a phenoxy resin (a trade name: “EPIKOTE 4250”, manufactured by JER Co., Ltd.) were dissolved in methyl ethyl ketone to prepare a solution of a resin composition having a solid content concentration of 23.6% by weight.
This solution of the resin composition was applied on, as a release liner (separator), a 50 μm-thick release-treated film composed of a polyethylene terephthalate film, which had been subjected to a silicone release treatment, and then dried at 130° C. for 2 minutes to prepare a film K for back surface of flip-chip semiconductor having a thickness (average thickness) of 80 μm.
<Fabrication of Dicing Tape-Integrated Film for Back Surface of Semiconductor>
The foregoing film K for back surface of flip-chip semiconductor was stuck onto a pressure-sensitive adhesive layer of a dicing tape (a trade name: “V-8-T”, manufactured by Nitto Denko Corporation, average thickness of base material: 65 μm, average thickness of pressure-sensitive adhesive layer: 10 μm) using a hand roller, thereby fabricating a dicing tape-integrated film for back surface of semiconductor.
(Tensile Storage Elastic Modulus)
Each of the films for back surface of flip-chip semiconductor fabricated in the respective Examples was thermally cured by a heat treatment under a condition at 165° C. for 2 hours. Subsequently, a strip-shaped sample having a length of 22.5 mm, a width of 10 mm, and a thickness of 0.2 mm was cut out from each of the films for back surface of flip-chip semiconductor after thermal curing by using a cutter knife. Furthermore, a value measured under a condition at a frequency of 1 Hz and a temperature elevating rate of 10° C./minute in a nitrogen atmosphere at a prescribed temperature (23° C.) using a dynamic viscoelasticity measuring apparatus “Solid Analyzer RS A2”, manufactured by Rheometrics Co., Ltd. was designated as a tensile storage elastic modulus E′.
(Warp Amount of Semiconductor Package and Presence or Absence of Cracking)
The presence or absence of the generation of a warp of the semiconductor chip was evaluated by measuring a warp amount of the semiconductor chip.
That is, first of all, after peeling off the separator from the dicing tape-integrated film for back surface of semiconductor, a semiconductor wafer (diameter: 8 inches, thickness: 200 μm; a silicon mirror wafer) was stuck onto the film for back surface of semiconductor by means of roll press bonding at 70° C. Furthermore, dicing of the semiconductor wafer was performed. The dicing was performed as full cutting so as to have a chip size of 10 mm square. Incidentally, a sticking condition and a dicing condition are as follows.
[Sticking Condition]
Sticking apparatus: A trade name: “MA-3000III”, manufactured by Nitto Seiki Co., Ltd.
Sticking speed: 10 mm/min
Sticking pressure: 0.15 MPa
Stage temperature at the time of sticking: 70° C.
[Dicing Condition]
Dicing apparatus: A trade name: “DFD-6361”, manufactured by DISCO Corporation
Dicing ring: “2-8-1” (manufactured by DISCO Corporation)
Dicing speed: 30 mm/sec
Dicing blade:
Dicing blade rotation number:
Cutting system: Step cutting
Wafer chip size: 10.0 mm square
Subsequently, the semiconductor chip obtained by dicing was picked up from the pressure-sensitive adhesive layer together with the film for back surface of flip-chip semiconductor by pushing up from the dicing tape side of the dicing tape-integrated film for back surface of semiconductor with a needle. A picking-up condition is as follows.
[Picking-Up Condition]
Picking-up apparatus: A trade name: “SPA-300”, manufactured by Shinkawa Co., Ltd.
Number of picking-up needles: 9 needles
Pushing-up speed of needle: 20 mm/s
Pushing-up distance of needle: 500 μm
Picking-up time: 1 second
Dicing tape expanding amount: 3 mm
Subsequently, the semiconductor chip was flip-chip bonded onto a BT substrate [BT RESIN (bismaleimide triazine based resin), manufactured by Mitsubishi Gas Chemical Company, Inc.]. At that time, the circuit face of the semiconductor chip was made opposite to the BT substrate, thereby bringing the bump formed on the circuit face of the semiconductor chip into contact with an electrically conductive material for (solder) for joining as adhered onto a connecting pad of the BT substrate, and the temperature was elevated to 260° C. while pressing, to melt the electrically conductive material, followed by cooling to room temperature. Furthermore, an underfill material as an encapsulating resin was injected into a gap between the semiconductor chip and the BT substrate. At that time, a thickness of the underfill (encapsulating material) was 20 μm. Subsequently, the semiconductor package was heated under a condition at 165° C. for 2 hours and then measured for a warp amount thereof.
As for the measurement of the warp amount, first of all, the semiconductor package was placed on a flat plate such that the BT substrate was faced downward, and a height of the BT substrate lifting up from the flat plate, namely a warp amount (μm) was measured. The measurement was carried out under a condition at a measuring speed of 1.5 mm/s and a load of 1 g by using a contact type surface roughness tester (DEKTAK8, manufactured by Veeco Instruments Inc.). As a result of the measurement, the case where the warp amount was not more than 100 μm is evaluated as “∘”, and the case where the warp amount exceeded 100 μm is evaluated as “x”. In addition, whether or not cracking was generated on the film for back surface of flip-chip semiconductor stuck onto the back surface of the semiconductor chip was visually confirmed. The case where the generation of cracking was not confirmed is evaluated as “∘”, and the case where the generation of cracking was confirmed is evaluated as “x”. The results are shown in the following Table 4.
TABLE 4
Presence
or absence
of the
Blending
generation
proportion
of cracking
of liquid
Thickness
on film
epoxy
of film
for back
resin in
Tensile
for back
surface of
Warp
thermosetting
storage
surface of
semi-
amount of
resin
elastic
semi-
conductor
semi-
component
modulus
conductor
after
conductor
(wt %)
(GPa)
(μm)
thermal curing
package
Example 7
60
10
80
∘
∘
Example 8
80
11
80
∘
∘
Example 5
50
10
80
x
∘
(Results)
As is noted from Table 4, it was confirmed that in the films for back surface of flip-chip semiconductor in which the resin composition was composed only of a thermosetting resin component and did not contain a thermoplastic resin component, all of the warp amounts of the semiconductor packages could be suppressed to not more than 100 μm. In addition, by regulating the lending proportion of the liquid epoxy resin in the thermosetting resin component to 60% by weight or more, the generation of cracking on the film for back surface of flip-chip semiconductor after thermal curing could also be prevented. On the other hand, even in Example 5, though the warp amount of the semiconductor package would be reduced to not more than 100 μm, it was confirmed that cracking was generated on the film for back surface of flip-chip semiconductor after thermal curing.
While the present invention has been described in detail and with reference to specific embodiments thereof, it will be apparent to one skilled in the art that various changes and modifications can be made therein without departing from the scope thereof.
This application is based on Japanese patent application No. 2010-096286 filed Apr. 19, 2010, Japanese patent application No. 2010-096290 filed Apr. 19, 2010, Japanese patent application No. 2010-096291 filed Apr. 19, 2010, and Japanese patent application No. 2010-096294 filed Apr. 19, 2010, the entire contents thereof being hereby incorporated by reference.
Industrial Applicability
According to the film for back surface of flip-chip semiconductor according to the present invention, since it is formed on the back surface of a semiconductor element having been flip-chip connected onto an adherend, it fulfills a function to protect the semiconductor element. In addition, since the film for back surface of flip-chip semiconductor according to the present invention has a tensile storage elastic modulus at 23° C. after thermal curing of 10 GPa or more, a warp of the semiconductor element generated at the time of flip-chip connection of the semiconductor element onto the adherend can be effectively suppressed or prevented.
Explanations of Reference Numerals and Signs
1: Dicing tape-integrated film for back surface of semiconductor
2: Film for back surface of semiconductor
3: Dicing tape
31: Base material
32: Pressure-sensitive adhesive layer
33: Portion corresponding to sticking portion of semiconductor wafer
4: Semiconductor wafer
5: Semiconductor chip
51: Bump formed on the circuit face side of semiconductor chip 5
6: Adherend
61: Electrically conductive material for joining as adhered onto connecting pad of adherend 6
Takamoto, Naohide, Shiga, Goji
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