A capacitor structure includes a deep trench, a contact plug, a spacer and a metal-insulator-metal film. The deep trench extends into a crown oxide substrate, and the contact plug is disposed entirely below the crown oxide substrate. The spacer lines the deep trench, and the metal-insulator-metal film is disposed in the deep trench.
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1. A capacitor structure comprising:
a deep trench extending into a crown oxide;
a contact plug disposed entirely below the crown oxide;
a spacer lining the deep trench, wherein the deep trench comprises a first sidewall along the crown oxide, a second sidewall along the contact plug, and a bottom, and wherein the spacer lines the first and second sidewalls of the deep trench; and
a metal-insulator-metal film disposed in the deep trench.
14. A memory device comprising:
a semiconductor substrate having a dynamic random access memory (DRAM) device;
an etch stop layer over the DRAM device;
a crown oxide over the etch stop layer;
a contact plug disposed entirely below the crown oxide;
a deep trench extending into the crown oxide, the deep trench comprising a pair of first sidewalls along the crown oxide and a pair of second sidewalls along the contact plug and a bottom;
a spacer lining the first sidewalls and the second sidewalls of the deep trench; and
a metal-insulator-metal film disposed in the deep trench.
3. The capacitor structure according to
4. The capacitor structure according to
5. The capacitor structure according to
7. The capacitor structure according to
9. The capacitor structure according to
10. The capacitor structure according to
11. The capacitor structure according to
13. The capacitor structure according to
15. The memory device according to
17. The memory device according to
19. The memory device according to
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Dynamic random access memory (DRAM) circuits are widely used in graphic and processor applications for storing data. The DRAM circuit includes a number of memory cells, and each cell has a capacitor and a transfer transistor. The capacitor stores binary data, while the transfer transistor retains the charge. In the read cycle, the transfer transistor interrogates the cells through bit lines. A field effect transistor is commonly used as the transfer transistor. The capacitor generally includes two electrodes separated by a barrier, for example, insulating material, to provide isolation.
Memory cells are likely to appear in two types, which include a deep trench (DT) capacitor formed in the substrate under the transfer transistors and a cell having a stacked capacitor that is built over and between transfer transistors. The physical size of electronic devices is ever reducing, and, as a result, the number of memory cells on a DRAM chip has increased dramatically in a short period. In the case of DT capacitor, the deep trench is made smaller to conserve space on the substrate for other components. The downsizing can lead to a significant reduction in the perimeter of the deep trench, and the electrical charge capability of the capacitor is strongly associated with the surface area.
Aspects of the present disclosure are best understood from the following detailed description when read with the accompanying figures. It is noted that, in accordance with the standard practice in the industry, various features are not drawn to scale. In fact, the dimensions of the various features may be arbitrarily increased or reduced for clarity of discussion.
The following disclosure provides many different embodiments, or examples, for implementing different features of the provided subject matter. Specific examples of components and arrangements are described below to simplify the present disclosure. These are, of course, merely examples and are not intended to be limiting. For example, the formation of a first feature over or on a second feature in the description that follows may include embodiments in which the first and second features are formed in direct contact, and may also include embodiments in which additional features may be formed between the first and second features, such that the first and second features may not be in direct contact. In addition, the present disclosure may repeat reference numerals and/or letters in the various examples. This repetition is for the purpose of simplicity and clarity and does not in itself dictate a relationship between the various embodiments and/or configurations discussed.
Further, spatially relative terms, such as “beneath,” “below,” “lower,” “above,” “upper” and the like, may be used herein for ease of description to describe one element or feature's relationship to another element(s) or feature(s) as illustrated in the figures. The spatially relative terms are intended to encompass different orientations of the device in use or operation in addition to the orientation depicted in the figures. The apparatus may be otherwise oriented (rotated 90 degrees or at other orientations) and the spatially relative descriptors used herein may likewise be interpreted accordingly.
Compact integrated circuits provide many advantages, for example, reduction in signal propagation time and noise susceptibility, higher clock frequencies and larger circuit real estate. Meanwhile, memory cell electrodes must provide sufficient surface area for electrical charge. The surface area is directly proportional to the charge holding capacity, referred to as capacitance. In order to increase surface area, deep trench technique has been developed to boost capacitance in a given area. The fabrication of deep trenches in substrate is a means of making charge storage cells, known as DT capacitors. In a metal-insulator-metal (MIM) capacitor, which is linear in its response characteristics and therefore commonly used in the logic device instead of poly-insulator-poly (PIP) capacitor, the deep trench is lined with dielectric material, and the surface area of the dielectric film is directly proportional to the capacitance. However, some adverse effects have been discovered in the deep trench capacitor which is one of the fundamental components required to design a feasible device.
The depth of deep trenches increases, while the width remains mostly unchanged. As a result, it leads to a high aspect ratio, which is defined as the ratio of the depth of the etched structure relative to its width (i.e., if in a plan view, the structure is square or rectangular) or to its diameter (i.e., if in a plan view, the structure is circular or elliptical in shape). The profile and shape control of the deep trench is very important for the subsequent process because multiple films are conformingly deposited to the deep trench. The deep trench etching process can be relatively complex. Etching is performed in equipment where gaseous species, usually containing Cl2, F and Br, are ionised. A commonly seen issue is leakage when the films are crammed to a narrow corner.
In high capacity dynamic memories where data may be stored as a few hundred or fewer individual electrons, the storage mechanism is inevitably highly transitory. Leakage of a few electrons alone can alter data states of a stored bit, for example, 1 to 0 or 0 to 1. At the same time, high refresh rates are required to prevent data corruption. In turn, significant time as well as power is consumed due to high refresh rates, and a mostly undesired scenario where the memory access time increases. Such situation can severely compromise potential performance. Furthermore, even with the provision of redundant circuitry for a chip design, improper formation of a relatively small number of elements on the chip (where the number of such elements greatly jumps to provide desired increase of integration density and memory capacity) can result in a chip which ultimately fails to achieve its full function.
A dynamic random access memory (DRAM) cell may comprise any desired type, number, and combination of components, and these structures may be formed using any suitable process technique (e.g., processes similar to those used to fabricate integrated circuits). Also, it should be understood that the capacitor structure and, further, that the disclosed embodiments may find use in any application where it is desired to provide a smooth lamination or where a spacer is needed in trenches.
Attention is now invited to
Still referring to
Subsequently, conventional photolithographic techniques and anisotropic plasma etching are used to etch through the First ILD layer 26 until exposing the underlying source/drain areas 17 to form contact openings for capacitor nodes and for the shared bit-line contacts. A conducting layer is deposited and fills the contact openings to form first conducting plugs 24 for capacitors and a second contact plug 25 for the bit lines. The conducting layer is composed of tungsten or tungsten alloys and deposited by LPCVD to a thickness sufficient to fill the contact openings. As shown in
Next, deep trenches 1 are formed in the crown oxide 40 aligned over the first contact plugs 24. The deep trenches 1 are etched using conventional photolithrographic techniques to recess the crown oxide 40, and the crown oxide 40 defines the height of the deep trenches 1. A spacer 5 lines the sidewalls of the deep trenches 1 and a metal-insulator-metal film 3 is conformingly deposited over the deep trenches 1. Materials of the spacer 5 may be, for example, silicon nitride (SiN) or the like. The metal-insulator-metal film 3 includes a bottom electrode layer contacting the first contact plugs 24, a capacitor dielectric layer and a top electrode layer overlying the bottom electrode layer in succession.
Still referring to
Another contact opening is then formed through the second ILD oxide layer 50, the crown oxide 40 and the second etch stop layer 30, exposing the underlying second contact plug 25. Conductive materials are filled into the contact opening to form the bit-line conducting plug 60 that is electrically connected to the second contact plug 25 on the substrate 10. Materials of the bit-line conducting plug 60 include but not limited to tungsten, tungsten alloys, copper or copper alloys.
A conductive layer 70 is deposited on the second ILD layer 50 and patterned, forming a bitline in the memory cell region. The bitline is conductor line of copper or copper alloys. The bitline can electrically connect to the source/drain areas 17 through the bit-line contact plug 60 and the second contact plug 25.
Attention is now invited to
Still referring to
It should be understood that spacer 5 does not cover the entire surface of the deep trench 1 but portions thereof. As shown in
Likewise, the acute angle created between the bottom 1c and the sidewall of the first contact plug 24 is attenuated. Because of selective etching of the spacer 5, in addition to non-uniform thickness, a portion of the spacer 5 is retained at the acute angle. The acute corner is therefore transformed into an obtuse angle, leaving a more opened bottom to fill in. The bottom electrode layer is conformal to the topology created by the spacer 5, and therefore when the capacitor dielectric layer and the top electrode are deposited, the acute angles will not be reproduced and capacitor leakage can be minimized to an even greater extent. The smoothness of the metal-insulator-metal film 3 ensures the functionality of the capacitor.
Turning now to
As set forth in block S110 in
Returning to
As set forth in block S130, the crown oxide is etched to form a plurality of deep trenches. This is illustrated in
As set forth in block S140, a spacer is applied in the deep trenches. This is illustrated in
Next, as set forth in block S150, the spacer is selectively etched. This is illustrated in
Referring now to
Although not shown, it should be understood that further processing can be carried out to the DRAM cell, which includes but not limited to forming a bitline contact plug over the remaining contact plug, depositing a second ILD layer exceeding the depth of the deep trenches, and forming a conductive layer as the bitline.
The instant disclosure provides a deep trench capacitor structure with modified deep trench profile. More specifically, a spacer is deposited before the deposition of a metal-insulator-metal film. Because of the high aspect ratio of deep trenches, after etch back process, the bottom of the trench is slightly curved and, sub-trenches are created between sidewall and the bottom. However, the width of the deep trenches can hardly broaden due to limited space, and therefore each deep trench should provide its maximum capacity without altering existing dimension. In this regard, the spacer fills in the sub-trenches with limited effect to the aspect ratio of the deep trench because the spacer is not uniform in thickness and discrete. The spacer modifies the contour of the deep trench to a cup having rounded corner such that the metal-insulator-metal film does not cram or jam at the corner, and the chance of capacitor leakage can be greatly reduced. The capacitance stability can be ensured and data loss can be avoided.
In some embodiments, a capacitor structure includes a deep trench, a contact plug, a spacer and a metal-insulator-metal film. The deep trench extends into a crown oxide substrate, and the contact plug is disposed entirely below the crown oxide substrate. The spacer lines the deep trench, and the metal-insulator-metal film is disposed in the deep trench.
In some embodiments, a memory device includes a semiconductor substrate having dynamic random access memory (DRAM) device. A stop layer is disposed over the DRAM device. A crown oxide is disposed over the etch stop layer, and a deep trench extends into the crown oxide. The deep trench includes a first and second sidewalls and a bottom. A spacer lines the first and second sidewalls of the deep trench, and a metal-insulator-metal film is disposed in the deep trench.
In some embodiments, a method includes forming an etch stop layer over an interlevel dielectric layer. Next, a crown oxide is formed on the etch stop layer. Subsequently, the crown oxide is etched to form a plurality of deep trenches. A spacer is then applied in the deep trenches. The spacer is selectively etched, and finally a metal-insulator-metal film is deposited in the deep trenches.
The foregoing outlines features of several embodiments so that those skilled in the art may better understand the aspects of the present disclosure. Those skilled in the art should appreciate that they may readily use the present disclosure as a basis for designing or modifying other processes and structures for carrying out the same purposes and/or achieving the same advantages of the embodiments introduced herein. Those skilled in the art should also realize that such equivalent constructions do not depart from the spirit and scope of the present disclosure, and that they may make various changes, substitutions, and alterations herein without departing from the spirit and scope of the present disclosure.
Wu, Chang-Ming, Liu, Shih-Chang, Min, Chung-Chiang, Yang, Tsung-Hsueh
Patent | Priority | Assignee | Title |
10497436, | Nov 27 2017 | Taiwan Semiconductor Manufacturing Co., Ltd. | Memory device and fabrication thereof |
10886380, | Jul 04 2017 | CHANGXIN MEMORY TECHNOLOGIES, INC | Semiconductor storage device and method for forming a profile of a capacitor thereof |
11011224, | Nov 27 2017 | Taiwan Semiconductor Manufacturing Co., Ltd. | Memory device and method for forming the same |
11017852, | Nov 27 2017 | Taiwan Semiconductor Manufacturing Co., Ltd. | Method of forming memory device |
11777035, | Aug 02 2016 | Taiwan Semiconductor Manufacturing Company, Ltd | Multi-layer film device and method |
Patent | Priority | Assignee | Title |
20020011618, | |||
20100127316, |
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Mar 31 2015 | LIU, SHIH-CHANG | TAIWAN SEMICONDUCTOR MANUFACTURING CO , LTD | ASSIGNMENT OF ASSIGNORS INTEREST SEE DOCUMENT FOR DETAILS | 035590 | /0692 |
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